CA1112375A - Method of treating a monocrystalline body - Google Patents

Method of treating a monocrystalline body

Info

Publication number
CA1112375A
CA1112375A CA311,348A CA311348A CA1112375A CA 1112375 A CA1112375 A CA 1112375A CA 311348 A CA311348 A CA 311348A CA 1112375 A CA1112375 A CA 1112375A
Authority
CA
Canada
Prior art keywords
layer
treatment
monocrystalline
substratum
thickness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA311,348A
Other languages
French (fr)
Inventor
Simon G. Kroon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koninklijke Philips NV
Original Assignee
Philips Gloeilampenfabrieken NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Philips Gloeilampenfabrieken NV filed Critical Philips Gloeilampenfabrieken NV
Application granted granted Critical
Publication of CA1112375A publication Critical patent/CA1112375A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B11/00Measuring arrangements characterised by the use of optical techniques
    • G01B11/02Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness
    • G01B11/06Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material
    • G01B11/0616Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material of coating
    • G01B11/0683Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material of coating measurement during deposition or removal of the layer
    • CCHEMISTRY; METALLURGY
    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B25/00Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
    • C30B25/02Epitaxial-layer growth
    • C30B25/16Controlling or regulating

Abstract

ABSTRACT:

A method in which a monocrystalline body is subjected in a gas atmosphere to a treatment changing the thickness of the body, in which the thickness of the body is controlled by means of a measuring member which is subjected to the same treatment and which measuring member, on its side which is subjected to the treatment, consists of a monocrystalline layer and an adjoining substratum of a material having a refractive index differing of that the monocrystal-line layer material, characterized in that a measur-ing member is used in the manufacture of which the sub-stratum is provided on a free surface of the mono-crystalline layer.

Description

3'~5 The invention relates to a method in which a monocrystalline body is subjected in a gas atmos-phere to a treatment changing the thickness of the body, in which the thickness of the body is controlled ~y means of a measuring member which is subjected to the same treatment and which measuring member, on the side which is subjected to the treatment, consists of .
a monocrystalline layer and an adjoining substratum of a material having an index of refraction differ-ing from that of the monocrystalline material of the layer, and to a body obtained by means of the method, The treatment changiny the thickness of the body is a process in which silicon is deposited epitaxially from the gaseous phase on a monocrystal-line silicon substrate. Furthermore a measuringmember is used which has been obtained by implant-ation of nitrogen ions in a monocrystalline silicon body so that a monocrystalline silicon layer is formed on a substratum of silicon nitride with the remainder 20 of the silicon body on the other side of the silicon .
nitride substratum. :~

., ...:

:;

-. .

- \

16.6.78 ~ 7~'~

Informativn o.n the thlckness of -khe ~pi~
taxial layer is ob-tained :from lnterference r11easule-ments, This may be i.nterfere:nce of radiation or:Lgi-nating from the monocrystalline layer directly erna~
nating from the layer with raclla-t:Lon which is first reflected by the substratum.
`Alternatively, inter:ference may be measure~d .
of incident laser ligh~ which is pa:rtly reflected by :: the surface of the monocrystalliLle layer and partly . : 10 by the substratum.
In order to obtain a clecisive interference pat-tern :it is necessary for the monocrystalline la.yer to be Or a quality which is comparable to that of the body to be treated.
i5 ~ It is al.so desirable ~or the substratum of the~1neasuring member to be homogeneous in composition and thi.ckness a.nd also~or the thickness:of the mono-crys:talline layer~to:he~constant.
: A good~quality~of the monocrysta.l.liIle layer ` and the substrate, however, is difficul-t to reali~e ::
~ with the above-described kllown method.
:
; For examp~e, in order to obtain a sat-isfac-torlly re~lect~ng;substratul71 by impla:ntationf a higl dose of ions to~be implanted is necessary, which ions 25~ have~to~b;e ~mplanted at higll ener~y so tha-t a compa~
ratively:large number of crystal lamages oc.cur wh.ich . : . : ~ ~ .

, Pl-IN 8893 16.6,78 3'~

do no-t all d:i.sappea:r aga:i:ll by the:r~al tre.ltlne:rll, and by wh.ic:h -the mea~sLlring melllbe:r arld the body to be treat-ecl arc d~ fficu:l.t -to comp.lre.
[n gena:ral. -th-3 i.mp].antat;ion depth is not larg~e so th.at in -the case oi'-tr~atmen-ts in ~ ich :re--ductions in thickness occur the duration Or con-trol.
is restric-ted.
, The reac-tion between -the materia] of tha measllri1l.g membcr and the i.mpla.:nted :i ons o:Etan.:is al-so insuffic-ieJlt so tha-t the inte:rface between the mo-nocrystalLina layar and the subs1;ratl.lm and also the reflection at that area is poorly de:E`lnad One of the objects of the invan-tion i.s to a~oid the above~lnent:ioned disadvantages at laast -to a considerable extent. The invention is based inter a:lia on the recognition of' tha fact that the forma-tion of the substratum on the monocrys-tal]ine layer is to be preferred over the formatio~l on the substra-tunl in a monocrystallina boclyO
According to tlle invention, the nletllod nlen~
tioned in tha precambla :is therefore chQra.c-ter:ized in that a measur:ing member is used iIl tha manu~acture oI` which the substratum is provi.ded on a E`ree surfa.ca of` the morlocrystal.line layar.
By mealls of -the me-thod. according to the in--ventioll, -tha substral,unl can be prov:ided. in a usua]

-.. . .

. l~, .

.

P~IN 8~93 16.6.78 mallner ~:i.t.hout the mo:nc)c:rys-talline Iayer be:i.ng damaged.
As a ITlaterlal for -the substratum may be cllo~
sen, fo:r e~amp:le, silicon diox:ide, s:il.icon ni-tri.de or s:ilicon carb:ide w.h.:i.ch can easi:l.y be obta:ined i:n the form of layers o:~ homogeneous compositi.on and thick-. ness.
; O.f course 9 -the thicknes~ o~ the monocrys-- talline layer may also be chosen wit;hin wide lirm.its.
The measuring member is pre*erab:l.y used in ;~ 10 the epita~ial deposit;ion oI` a layer of semiconductor `~ rnaterial on a subs-trate as a treatrnent which causes the thickness of the body to increase.
Howe~rer, by menns of t:he rnethod accord.ing to the invention, a treatmen-t 9 ~or e~ample e-tching, causing the thickness o:~ t;:he body to decrease can al-. so be controlled.
Successire etchin~ and epita~ial treatrnents can also be controlled in the descr:ibed manner.
rneasu:ring mernber for use in the method :20: according to the in.vention can be obtained in a corn-paratively simple mamlcr by epitaxially depositing the monocrystalli.ne layer on a subst:rate di~er:ing :
from~the mono~crystalline layer at least as regards conductivity properties, then prov:idhlg the substra~-25~ tum;and removing~the Iast-lr~lelltioned substrate.
The last~m:entioned substrate is preferably ~ ::: ::
:

PMN 8~93 1G.6.78 v~

removed b~ ~e~lns o~ an etclling l)rocess whicl~ is se-lect~ve w:it,h :respect, t;o t;he monocrystall:irle laye:L.
Suc:tl e-tchi.ng processes can easl:L.y he in-dicated ~ in the treatmeJlt semicon~luc-tor ma-teria:L is transported belongillg to -the-.gr,c)1.ljo consis-t:ing of si~
licon a:nd :CII-V compounds. As a substratulll i.s pre~
I ~erably used a 1.ayer of silicon ni-tr:ide or of si.licon di.oxide and i.n order to i:ncrease the rigidi-ty of the measuring mernber, a layer o~ po.lysilicon is provi.ded on the substratum, The :inven-tion also relates to a monocrysta:L~
: line body trea-t;ed by mean.s o~ -the method according to the invention.
The :i.nvention w:ill now be described in greater detail with reference -to an example and the accompan.ying drawingO
~igs. 1 and 2 of the draw:ing are d.iagram-ma-tio sectional views o:f a measu:ring n1einber used in the method according to the i.nvention`in successive , stages o:i^ its manufacture.
In -the exall1ple.~ a monocrystalline silicon body is subject;ed in a gas a-tmosphere to trea-tments changing the thicknes.s o~ the body. The thic~ness O.r the body is controlled by means of a measuri.ng member 1 wh.ich i~s sub;jected to the sarrle t:reatments, : The measuri.llg melnber 1 on i.t.s side which is subjected to the treatme1lt cvnsists o~ a monocrystal.~
, ...

~ .

.

.

PIJN ~89~, 16.6.78 3~

line layer-2 aild an acl.joinil1g subst:rcltu1rl 3 of a : Ma-terial havlng an i:ndex of ref`:l~actio:tl dif:~er:ingl`~om that o:~ tlle rnol1.ocrysi;alli.n.e Layer oI` material.
. ~ccorclingr to the invelltion a measuring Inem-ber is used in the manufactLIre~ of wlli.cll the subsl;ra-tum JS provided on a free surface of the sllicon layer 2.
~ The measurin~ member 1 is obtained by de-positing ep.i-taxial:Ly a 3/um -thick monocrystalline layer 2 o:f the n type on a disc-shaped substrate Ll of monocrystall-Lne silicon of -the n type having a cliameter o* 5 cm and a thickness of 200/um.
~. substraturrl 3 o~ silicon nitride (0.3/urn thick) or silicon dioxide (0.45/um thicl~) is provid~-ed on layer 2 and then a 200/um thic~ high-ohmic polysilicon layer 5 is provided :~ The substrate 4 i.s thell relllovecl by me~alls of an etching process which etches s~leo-tively ~ith :
: respec-t -to the monocrystalline layer 2, . Silicon has a refracti.~e .index o~ 3.42, si-l:icon n:i-tride a refractive index of 2.00.
The disc-shaped substrate ll :i9 then severed in the usual man.ner to form measuring members havillg : an area of 7 mm x 7 mm.
25~ ~ ~ Conventionally used methods rnay be applied ~ ~ :

: ~ : ~ 7 : ::

::: :

P~-IN 8893 ~ 3'~'~ 16,6,7 i:rl the treatlnell-ts challglng the tlL:Lckness alld :i:n. th.e manu.racture in the measurin.g mem'ber.
The sa:i.cl selecti~e etch-ing process may 'be carried out in a su:itablc etching bath, if deslred electrochemically, i:~ desired succeeding a parti.. al mechanical removal of the. substrate 4.
In the present example, the body -to be :: ; . -treated and.. the measuring mernber are~ placed in a re-actor and are successively subjected to an etching treatment ln an atrrlosphere containing hydrogen chLo-ride a~ld then to an epitaxial treatment in an atmos--' phere containing silicon tetraohLori.de.
Increase and decrease o.~ the thickness are reco:rdcd in the us~lal mal~ler by Irleasuring the inten-sity o~ the radiati.on emanating from the monocr~stal-line layer. The tiMe difference between the recording : ~ :
o:~ tw~ successive intensi-ty maxima corresponds to a-n ncrease~or decrease of the thickness wh~i.ch depends, : besides on the wa~elength of the recorded radiation, ~ also on the emanating angle of the radiati.on an.d in particular on the refrac,t:ive index of the mater:ial : o~ the layer.
It has:be~en ~ound that changes in thickness o~:approximal,ely 6/um correspondi~ng to 20 cycles of 25~ appro~imately 0i3/um in the intensit~ variations can ' '' :be~;recorded.

:: ~:: . : . - :- - - .

~,~ l'HN ~)3 1 6 L 6 . 7 8 L;mits are imposed upon -the number of cyc:Lc?s of` intensity variatiolls by the banclwLdt;h oL` the record-ed radlat:ion, the scatter by the sllbstra-tunl and ab30rp-t:ion of the radia-t;lon in the grrowlng material, Besides by recordiIlg emit-ted, in the case of silicon infrared, radiat:ions, reflec tion of :Laser radiation can a:l so be measured in which less extinc-tion occurs when the layer thickness :increases.
The invent ion is not res tric ted to the example descr:ibecl.
For example, illsteacl of an amorphous sub-stra tur1l f`or example silicon nitr:icle, a monocrys tal-line substra tum, f`or example of sapph:ire, may alter~
nat ive ly b e u s e d O
The thickness eontrol described may be used in a process to control the growth ra-te o f an epi-taxial layer .
n addition to sLlicon~ f-or example, I~ V-compounds can be grown by means of the rne thod acco rd-~
ing to the inventi on.
l`he ma terial o ~ the body to be treated may, bu t ne e d no t ne c e s s ari ly b e e qu al t o tha t o f the mono -:: ` : :
c ry~s t~l l ine l ay e r o f the me a su rirlg m emb e r .

g :~ ~: ~ :: : ` :

:

Claims (7)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS
1. A method in which a monocrystalline body is subjected in a gas atmosphere to a treatment changing the thickness of the body, in which the thickness of the body is controlled by means of a measuring member which is subjected to the same treatment and which measuring member, on the side which is subjected to the treatment, consists of a monocrystalline layer and an adjoining substratum of a material having a refractive index differing from that of the mono-crystalline layer material, characterized in that in the manufacture of the measuring member the sub-stratum is provided on a free surface of the mono-crystalline layer.
2. A method as claimed in Claim 1, charac-terized in that the measuring member is used in the epitaxial deposition of a layer of semiconductor material on a substrate as a treatment which causes the thickness of the body to increase.
3. A method as claimed in Claim 1, charac-terized in that the measuring member is obtained by depositing the monocrystalline layer epitaxially on a substrate differing from the monocrystalline layer at least as regards conductivity properties, then providing the substratum and removing the last-mentioned substrate.
4. A method as claimed in Claim 3, charac-terized in that the last-mentioned substrate is removed by means of an etching process which etches selectively with respect to the monocrystalline layer.
5. A method as claimed in Claim 1, charac-terized in that a layer of silicon nitride or silicon dioxide is used as a substratum.
6. A method as claimed in Claim 5, charac-terized in that a layer of polysilicon is provided on the substratum.
7. A method as claimed in Claim 1, 3 or 5, characterized in that during the treatment semi-conductor material is transported which belongs to the group consisting of silicon and III-V compounds.
CA311,348A 1977-09-16 1978-09-14 Method of treating a monocrystalline body Expired CA1112375A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL7710164A NL7710164A (en) 1977-09-16 1977-09-16 METHOD OF TREATING A SINGLE CRYSTAL LINE BODY.
NL7710164 1977-09-16

Publications (1)

Publication Number Publication Date
CA1112375A true CA1112375A (en) 1981-11-10

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ID=19829190

Family Applications (1)

Application Number Title Priority Date Filing Date
CA311,348A Expired CA1112375A (en) 1977-09-16 1978-09-14 Method of treating a monocrystalline body

Country Status (8)

Country Link
US (1) US4177094A (en)
JP (1) JPS5453684A (en)
CA (1) CA1112375A (en)
DE (1) DE2839535C2 (en)
FR (1) FR2403647A1 (en)
GB (1) GB2005011B (en)
IT (1) IT1099071B (en)
NL (1) NL7710164A (en)

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Also Published As

Publication number Publication date
US4177094A (en) 1979-12-04
GB2005011B (en) 1982-02-10
GB2005011A (en) 1979-04-11
JPS5652876B2 (en) 1981-12-15
DE2839535A1 (en) 1979-03-29
DE2839535C2 (en) 1985-08-08
IT7827637A0 (en) 1978-09-13
NL7710164A (en) 1979-03-20
FR2403647A1 (en) 1979-04-13
IT1099071B (en) 1985-09-18
JPS5453684A (en) 1979-04-27
FR2403647B1 (en) 1982-11-19

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