CA2051716A1 - Copper hydroxide dry flowable bactericide/fungicide and method of making and using same - Google Patents
Copper hydroxide dry flowable bactericide/fungicide and method of making and using sameInfo
- Publication number
- CA2051716A1 CA2051716A1 CA002051716A CA2051716A CA2051716A1 CA 2051716 A1 CA2051716 A1 CA 2051716A1 CA 002051716 A CA002051716 A CA 002051716A CA 2051716 A CA2051716 A CA 2051716A CA 2051716 A1 CA2051716 A1 CA 2051716A1
- Authority
- CA
- Canada
- Prior art keywords
- approximately
- weight
- fungicide
- bactericide
- total weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
Abstract
There is disclosed a granular copper hydroxide dry flowable bactericide/fungicide having improved biological activity and a method for making and using same. A
bactericide/fungicide is made by forming a homogeneous aqueous slurry containing between approximately 5% and 20%
by weight (based on the total weight of all dry ingredients) of a first dispersant selected from the group consisting of partially neutralized polyacrylic acid having a pH of between approximately 5 and 10 and an average molecular weight of between approximately 1,000 and 10,000 and lignin sulfonate, between approximately 0% and 5% by weight (based on the total weight of all dry ingredients) of a second dispersant for bentonite clay, between approximately 40% and 80% by weight (based on the total weight of all dry ingredients) phosphate stabilized cupric hydroxide and between approximately 6% and 30% by weight (based on the total weight of all dry ingredients) bentonite clay; and spray drying the slurry to thereby form a dry free flowing granular bactericide/fungicide product. The slurry can also include antifoam and wetting agents. Other partially neutralized polycarboxylic acid polymers useful as the first dispersant are also disclosed.
bactericide/fungicide is made by forming a homogeneous aqueous slurry containing between approximately 5% and 20%
by weight (based on the total weight of all dry ingredients) of a first dispersant selected from the group consisting of partially neutralized polyacrylic acid having a pH of between approximately 5 and 10 and an average molecular weight of between approximately 1,000 and 10,000 and lignin sulfonate, between approximately 0% and 5% by weight (based on the total weight of all dry ingredients) of a second dispersant for bentonite clay, between approximately 40% and 80% by weight (based on the total weight of all dry ingredients) phosphate stabilized cupric hydroxide and between approximately 6% and 30% by weight (based on the total weight of all dry ingredients) bentonite clay; and spray drying the slurry to thereby form a dry free flowing granular bactericide/fungicide product. The slurry can also include antifoam and wetting agents. Other partially neutralized polycarboxylic acid polymers useful as the first dispersant are also disclosed.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US59128890A | 1990-10-01 | 1990-10-01 | |
US591,288 | 1990-10-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2051716A1 true CA2051716A1 (en) | 1992-04-02 |
CA2051716C CA2051716C (en) | 2002-05-14 |
Family
ID=24365877
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002051716A Expired - Lifetime CA2051716C (en) | 1990-10-01 | 1991-09-18 | Copper hydroxide dry flowable bactericide/fungicide and method of making and using same |
Country Status (22)
Country | Link |
---|---|
US (2) | US5298253A (en) |
EP (1) | EP0480614B1 (en) |
JP (1) | JPH04264012A (en) |
KR (1) | KR100195670B1 (en) |
CN (1) | CN1043719C (en) |
AT (1) | ATE146339T1 (en) |
AU (1) | AU650054B2 (en) |
BR (1) | BR9104147A (en) |
CA (1) | CA2051716C (en) |
DE (1) | DE69123688T2 (en) |
ES (1) | ES2095299T3 (en) |
GR (1) | GR3022818T3 (en) |
HU (1) | HU214214B (en) |
IL (1) | IL99569A (en) |
MX (1) | MX9101386A (en) |
MY (1) | MY107233A (en) |
NZ (1) | NZ239968A (en) |
OA (1) | OA09516A (en) |
PH (1) | PH31001A (en) |
PT (1) | PT99125B (en) |
TW (1) | TW217377B (en) |
ZA (1) | ZA917487B (en) |
Families Citing this family (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2051716C (en) * | 1990-10-01 | 2002-05-14 | James H. Lefiles | Copper hydroxide dry flowable bactericide/fungicide and method of making and using same |
US6471976B1 (en) | 1990-10-01 | 2002-10-29 | Evelyn J. Taylor | Copper complex bactericide/fungicide and method of making same |
ZA931681B (en) * | 1992-04-03 | 1993-12-07 | Griffin Corp | Copper complex bactericide/fungicide and method of making same |
IT1275043B (en) * | 1994-07-21 | 1997-07-29 | Agerbioss Snc Di Zanin R & C | METHOD AND RELATED PRODUCT FOR THE DEFENSE OF PLANTS FROM VEGETABLE PARASITES |
NO314114B1 (en) * | 2001-06-21 | 2003-02-03 | Nordox Ind As | Granulated material for biocide applications |
DE10297803B4 (en) * | 2002-11-12 | 2012-03-29 | Nordox Industrier As | Granulated copper oxide for antifouling coatings |
US20100068299A1 (en) * | 2003-01-27 | 2010-03-18 | Van Der Krieken Wilhelmus Maria | Lignosulfonate compositions for control of plant pathogens |
US20040208980A1 (en) * | 2003-04-16 | 2004-10-21 | Unilever Bestfoods North America | Ambient stable starch product |
US7402296B2 (en) * | 2004-09-02 | 2008-07-22 | E.I. Du Pont De Nemours And Company | Method for stabilizing copper hydroxide |
US8317864B2 (en) * | 2004-10-20 | 2012-11-27 | The Board Of Trustees Of The Leland Stanford Junior University | Systems and methods for posterior dynamic stabilization of the spine |
US8277488B2 (en) * | 2004-10-20 | 2012-10-02 | Vertiflex, Inc. | Interspinous spacer |
US8152837B2 (en) | 2004-10-20 | 2012-04-10 | The Board Of Trustees Of The Leland Stanford Junior University | Systems and methods for posterior dynamic stabilization of the spine |
US9023084B2 (en) * | 2004-10-20 | 2015-05-05 | The Board Of Trustees Of The Leland Stanford Junior University | Systems and methods for stabilizing the motion or adjusting the position of the spine |
US8123807B2 (en) * | 2004-10-20 | 2012-02-28 | Vertiflex, Inc. | Systems and methods for posterior dynamic stabilization of the spine |
US8945183B2 (en) * | 2004-10-20 | 2015-02-03 | Vertiflex, Inc. | Interspinous process spacer instrument system with deployment indicator |
US8123782B2 (en) * | 2004-10-20 | 2012-02-28 | Vertiflex, Inc. | Interspinous spacer |
US8613747B2 (en) * | 2004-10-20 | 2013-12-24 | Vertiflex, Inc. | Spacer insertion instrument |
US9119680B2 (en) | 2004-10-20 | 2015-09-01 | Vertiflex, Inc. | Interspinous spacer |
US8167944B2 (en) | 2004-10-20 | 2012-05-01 | The Board Of Trustees Of The Leland Stanford Junior University | Systems and methods for posterior dynamic stabilization of the spine |
US8425559B2 (en) | 2004-10-20 | 2013-04-23 | Vertiflex, Inc. | Systems and methods for posterior dynamic stabilization of the spine |
US8409282B2 (en) | 2004-10-20 | 2013-04-02 | Vertiflex, Inc. | Systems and methods for posterior dynamic stabilization of the spine |
US8273108B2 (en) * | 2004-10-20 | 2012-09-25 | Vertiflex, Inc. | Interspinous spacer |
US8012207B2 (en) * | 2004-10-20 | 2011-09-06 | Vertiflex, Inc. | Systems and methods for posterior dynamic stabilization of the spine |
US9161783B2 (en) | 2004-10-20 | 2015-10-20 | Vertiflex, Inc. | Interspinous spacer |
US7763074B2 (en) | 2004-10-20 | 2010-07-27 | The Board Of Trustees Of The Leland Stanford Junior University | Systems and methods for posterior dynamic stabilization of the spine |
US8128662B2 (en) | 2004-10-20 | 2012-03-06 | Vertiflex, Inc. | Minimally invasive tooling for delivery of interspinous spacer |
WO2009086010A2 (en) | 2004-12-06 | 2009-07-09 | Vertiflex, Inc. | Spacer insertion instrument |
KR20080031360A (en) * | 2005-07-04 | 2008-04-08 | 쉬드-케미아크티엔게젤샤프트 | Layered silicate slurries having a high solids content |
EP1961306A4 (en) * | 2005-12-16 | 2012-03-28 | Riken | Bactericide for agricultural and horticultural use containing inorganic copper compound as active ingredient |
WO2007123531A1 (en) * | 2006-04-25 | 2007-11-01 | Albaugh, Inc. | Copper-based fungicide/bactericide |
US8221796B2 (en) | 2006-04-25 | 2012-07-17 | Albaugh, Inc. | Copper-based fungicide/bactericide |
US8192766B2 (en) * | 2006-04-25 | 2012-06-05 | Albaugh, Inc. | Copper-based fungicide/bactericide |
US8845726B2 (en) | 2006-10-18 | 2014-09-30 | Vertiflex, Inc. | Dilator |
CA2684461C (en) | 2007-04-16 | 2015-06-30 | Vertiflex Inc. | Interspinous spacer |
US20110052720A1 (en) * | 2007-12-20 | 2011-03-03 | Wim Van Der Krieken | Compositions for the control of plant pathogens and for use as plant fertilizer |
EP2244670B1 (en) | 2008-01-15 | 2017-09-13 | Vertiflex, Inc. | Interspinous spacer |
US8221791B1 (en) | 2008-12-10 | 2012-07-17 | University Of Central Florida Research Foundation, Inc. | Silica-based antibacterial and antifungal nanoformulation |
US9150453B1 (en) | 2009-12-03 | 2015-10-06 | Bowen Li | Antimicrobial exfoliated vermiculite composite material and methods for preparing the same |
US8740948B2 (en) | 2009-12-15 | 2014-06-03 | Vertiflex, Inc. | Spinal spacer for cervical and other vertebra, and associated systems and methods |
MX2012011104A (en) | 2010-03-30 | 2012-11-29 | Univ Central Florida Res Found | Multifunctional silica-based compositions and gels, methods of making them, and methods of using them. |
US9491946B2 (en) | 2011-11-01 | 2016-11-15 | University Of Central Florida Research Foundation, Inc. | Ag loaded silica nanoparticle/nanogel formulation, methods of making, and methods of use |
US9675303B2 (en) | 2013-03-15 | 2017-06-13 | Vertiflex, Inc. | Visualization systems, instruments and methods of using the same in spinal decompression procedures |
US9781936B2 (en) | 2013-10-09 | 2017-10-10 | University Of Central Florida Research Foundation, Inc. | Compositions, methods of making a composition, and methods of use |
US9215877B2 (en) | 2014-02-05 | 2015-12-22 | University Of Central Florida Research Foundation, Inc. | Compositions including a vacancy-engineered(VE)-ZnO nanocomposite, methods of making a composition , method of using a composition |
AU2015256024B2 (en) | 2014-05-07 | 2020-03-05 | Vertiflex, Inc. | Spinal nerve decompression systems, dilation systems, and methods of using the same |
CN104757020A (en) * | 2015-03-30 | 2015-07-08 | 深圳诺普信农化股份有限公司 | Cupric hydroxide dry suspending agent and preparation method thereof |
WO2016166020A1 (en) * | 2015-04-16 | 2016-10-20 | Basf Se | Attenuation of phytotoxicity of multisite fungicides by high-molecular-weight dispersants |
US10767118B2 (en) | 2016-01-08 | 2020-09-08 | Innophos, Inc. | Scavenger compositions for sulfur species |
DE102016004627A1 (en) * | 2016-04-15 | 2017-10-19 | Spiess-Urania Chemicals Gmbh | Fungicides-Bactericidal pesticide |
US20210329910A1 (en) * | 2017-06-22 | 2021-10-28 | Bayer Cropscience Lp | Composition for stabilizing at least one agrochemical active ingredient |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US24324A (en) * | 1859-06-07 | Improvement in sewing-machines | ||
GB493148A (en) * | 1937-04-06 | 1938-10-04 | Ernest Charles Large | Improvements relating to fungicidal compositions |
FR914962A (en) * | 1945-04-27 | 1946-10-23 | Cuprous anticryptogamic porridge | |
FR916489A (en) * | 1945-06-15 | 1946-12-06 | Gignoux & Cie | Process for the protection of precipitated copper salts |
FR943010A (en) * | 1947-03-11 | 1949-02-24 | Cuprous hydroxide bentonite anticryptogamic slurry | |
FR966315A (en) * | 1948-05-07 | 1950-10-06 | Cuprous anticryptogamic porridge | |
USRE24324E (en) * | 1951-05-05 | 1957-05-28 | Method of making stable cupric | |
GB880270A (en) * | 1959-04-27 | 1961-10-18 | Ici Ltd | Improvements in or relating to fungicidal compositions |
NL276056A (en) * | 1961-03-18 | |||
US3428731A (en) * | 1965-10-19 | 1969-02-18 | Mary A Furness | Stable dispersions of finely divided phosphate-process cupric hydroxide |
US3954967A (en) * | 1971-08-05 | 1976-05-04 | Vanguard Chemical Company, Inc. | Method of producing microcolloidal aqueous emulsions of unsaturated organic insecticidal compounds |
FR2225017A6 (en) * | 1973-04-04 | 1974-10-31 | Flimon Jacques | |
US4003994A (en) * | 1973-05-15 | 1977-01-18 | Texaco Trinidad, Inc. | Copper-alkaline earth metal fungicidal compositions |
US4048324A (en) * | 1973-12-28 | 1977-09-13 | Armand Kohn | Fungicidal composition and method |
US4043324A (en) * | 1976-02-13 | 1977-08-23 | Shaw Iv Alexander F | Chiropractic analytic technique with a liquid crystal sheet |
DE2805106A1 (en) * | 1978-02-07 | 1979-08-16 | Hoechst Ag | MICROCAPSULES MADE OF POLYVINYL ALCOHOL WITH LIQUID, WATER-INSOLUBLE FILLING MATERIAL AND PROCESS FOR THEIR PRODUCTION |
DE2807293A1 (en) * | 1978-02-21 | 1979-08-23 | Bp Chem Int Ltd | HOMOGENOUS, LIQUID, PREPARATION COMPRISING A CUPRAMMONIUM COMPLEX |
US4227911A (en) * | 1978-10-10 | 1980-10-14 | Conklin Company, Inc. | Wetting agent and use thereof in agriculture |
DE2847441A1 (en) * | 1978-11-02 | 1980-05-22 | Basf Ag | IMIDAZOLE COPPER COMPLEX CONNECTIONS |
GR75196B (en) * | 1980-05-03 | 1984-07-13 | Basf Ag | |
JPS5842843B2 (en) * | 1981-03-27 | 1983-09-22 | 花王株式会社 | Dispersant for aqueous suspension biocide |
US4418056A (en) * | 1982-12-27 | 1983-11-29 | Cuproquim S.A. | Process for making cupric hydroxide |
DE3702769A1 (en) * | 1987-01-30 | 1988-08-11 | Shell Agrar Gmbh & Co Kg | FUNGICIDAL AGENT |
US4732762A (en) * | 1983-03-07 | 1988-03-22 | Metropolitan Mosquito Control District | Timed release pest control composition and means |
DE3608681A1 (en) * | 1986-03-15 | 1987-09-17 | Basf Ag | COPPER CONTAINER FOR CONTROLLING MUSHROOMS AND BACTERIA |
US5047424A (en) * | 1988-10-03 | 1991-09-10 | Safer, Inc. | Environmentally safe insecticide |
CA2051716C (en) * | 1990-10-01 | 2002-05-14 | James H. Lefiles | Copper hydroxide dry flowable bactericide/fungicide and method of making and using same |
FR2668031B1 (en) * | 1990-10-19 | 1997-01-31 | Nippon Oils & Fats Co Ltd | BORDELAIS BOUILLIES AND THEIR PREPARATION PROCESS. |
-
1991
- 1991-09-18 CA CA002051716A patent/CA2051716C/en not_active Expired - Lifetime
- 1991-09-19 ZA ZA917487A patent/ZA917487B/en unknown
- 1991-09-26 IL IL9956991A patent/IL99569A/en not_active IP Right Cessation
- 1991-09-26 AU AU84802/91A patent/AU650054B2/en not_active Expired
- 1991-09-26 BR BR919104147A patent/BR9104147A/en not_active IP Right Cessation
- 1991-09-26 OA OA60077A patent/OA09516A/en unknown
- 1991-09-27 NZ NZ239968A patent/NZ239968A/en not_active IP Right Cessation
- 1991-09-29 CN CN91109431A patent/CN1043719C/en not_active Expired - Lifetime
- 1991-09-30 KR KR1019910017088A patent/KR100195670B1/en not_active IP Right Cessation
- 1991-09-30 TW TW080107692A patent/TW217377B/zh active
- 1991-09-30 PT PT99125A patent/PT99125B/en not_active IP Right Cessation
- 1991-09-30 PH PH43220A patent/PH31001A/en unknown
- 1991-09-30 MY MYPI91001804A patent/MY107233A/en unknown
- 1991-10-01 ES ES91308993T patent/ES2095299T3/en not_active Expired - Lifetime
- 1991-10-01 EP EP91308993A patent/EP0480614B1/en not_active Expired - Lifetime
- 1991-10-01 AT AT91308993T patent/ATE146339T1/en not_active IP Right Cessation
- 1991-10-01 DE DE69123688T patent/DE69123688T2/en not_active Expired - Lifetime
- 1991-10-01 HU HU913134A patent/HU214214B/en not_active IP Right Cessation
- 1991-10-01 JP JP3280706A patent/JPH04264012A/en active Pending
- 1991-10-01 MX MX9101386A patent/MX9101386A/en unknown
-
1992
- 1992-08-11 US US07/928,148 patent/US5298253A/en not_active Expired - Lifetime
-
1994
- 1994-03-22 US US08/215,510 patent/US5462738A/en not_active Expired - Lifetime
-
1997
- 1997-03-17 GR GR970400492T patent/GR3022818T3/en unknown
Also Published As
Publication number | Publication date |
---|---|
CN1043719C (en) | 1999-06-23 |
TW217377B (en) | 1993-12-11 |
HU214214B (en) | 1998-01-28 |
BR9104147A (en) | 1992-06-02 |
IL99569A (en) | 1996-01-31 |
GR3022818T3 (en) | 1997-06-30 |
KR920007537A (en) | 1992-05-27 |
EP0480614A1 (en) | 1992-04-15 |
DE69123688D1 (en) | 1997-01-30 |
CA2051716C (en) | 2002-05-14 |
EP0480614B1 (en) | 1996-12-18 |
HU913134D0 (en) | 1992-01-28 |
IL99569A0 (en) | 1992-08-18 |
ATE146339T1 (en) | 1997-01-15 |
OA09516A (en) | 1992-11-15 |
US5298253A (en) | 1994-03-29 |
KR100195670B1 (en) | 1999-06-15 |
US5462738A (en) | 1995-10-31 |
ZA917487B (en) | 1993-03-19 |
PH31001A (en) | 1997-12-23 |
DE69123688T2 (en) | 1997-04-17 |
ES2095299T3 (en) | 1997-02-16 |
HUT61157A (en) | 1992-12-28 |
MX9101386A (en) | 1992-06-05 |
NZ239968A (en) | 1993-06-25 |
MY107233A (en) | 1995-10-31 |
PT99125B (en) | 1999-03-31 |
CN1060383A (en) | 1992-04-22 |
AU8480291A (en) | 1992-04-02 |
AU650054B2 (en) | 1994-06-09 |
JPH04264012A (en) | 1992-09-18 |
PT99125A (en) | 1992-08-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKEX | Expiry |