CA2070942A1 - Field emission electron device employing a modulatable diamond semiconductor emitter - Google Patents

Field emission electron device employing a modulatable diamond semiconductor emitter

Info

Publication number
CA2070942A1
CA2070942A1 CA002070942A CA2070942A CA2070942A1 CA 2070942 A1 CA2070942 A1 CA 2070942A1 CA 002070942 A CA002070942 A CA 002070942A CA 2070942 A CA2070942 A CA 2070942A CA 2070942 A1 CA2070942 A1 CA 2070942A1
Authority
CA
Canada
Prior art keywords
layer
electron emitter
diamond semiconductor
conductive
major surface
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002070942A
Other languages
French (fr)
Inventor
Robert C. Kane
James E. Jaskie
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Motorola Solutions Inc
Original Assignee
Motorola Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Motorola Inc filed Critical Motorola Inc
Publication of CA2070942A1 publication Critical patent/CA2070942A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J1/00Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
    • H01J1/02Main electrodes
    • H01J1/30Cold cathodes, e.g. field-emissive cathode
    • H01J1/304Field-emissive cathodes
    • H01J1/3042Field-emissive cathodes microengineered, e.g. Spindt-type
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J3/00Details of electron-optical or ion-optical arrangements or of ion traps common to two or more basic types of discharge tubes or lamps
    • H01J3/02Electron guns
    • H01J3/021Electron guns using a field emission, photo emission, or secondary emission electron source
    • H01J3/022Electron guns using a field emission, photo emission, or secondary emission electron source with microengineered cathode, e.g. Spindt-type
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J2201/00Electrodes common to discharge tubes
    • H01J2201/30Cold cathodes
    • H01J2201/304Field emission cathodes
    • H01J2201/30446Field emission cathodes characterised by the emitter material
    • H01J2201/30453Carbon types
    • H01J2201/30457Diamond
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J2201/00Electrodes common to discharge tubes
    • H01J2201/30Cold cathodes
    • H01J2201/319Circuit elements associated with the emitters by direct integration

Abstract

A FIELD EMISSION ELECTRON DEVICE EMPLOYING
A MODULATABLE DIAMOND SEMICONDUCTOR EMITTER

Abstract of the Disclosure A field emission device having a diamond semiconductor electron emitter with an exposed surface exhibiting a low/negative electron affinity which is operably controlled by modulation of a junction depletion region. Application of a suitable operating voltage to a device gate electrode modulates the depletion width to control availability of electrons transiting the bulk of the electron emitter for emission at the exposed surface.

Description

~r.
A FIELD EMISSION ELECTRON DEVICE EMPLOYING
A MODULATABLE DIAMOND SEMICONDUCTOR EMITTER

Field of the Invention The present invention relates generally to field emission electron devices and more particularly to a field emission electron device employing an electron emitter with an emitting surface exhibiting low/negative electron affinity.

Ba~q~ L~L~ 0 Field emission devices and field emission electron emitters are known in the art. Typically, these prior art structures employ preferentially shaped electron emitters wherein an emitting tip/edge having a geometric discontinuity of small radius of curvature is formed. The desire for such a tip/edge feature is obviated by the need to provide for very strong electric field enhancement near the region of the electron emitter so that electrons may be extracted. In an attempt to increase the susceptibility to emit electrons techniques have been employed to provide work-function lowering materials, such as cesium, onto the surface of/directly into the bulk of electron emitters.
The need for emitting tips/edges with small radius of curvature imposes a restriction on repeatable realization of electron emitters. The technique of applying special materials to the surface of/in the bulk of emitters introduces operational instabilities due to the difficulty in maintaining the materials at/in the electron emitter.
Electron emitters of the prior art and field emission devices employing electron emitters of the prior art also suffer from damage incurred as a result of ion bombardment at the electron emitter. In the presence of very low . .
" ~ : . . ..
" . ~
' ' :

, ~ ~3 ~

residual gas pressures the emitters are still subjected to occasional ion attack which may damage the emitting tip/edge and render it useless.
Some other prior art field emission electron emitters do not employ tips/edges of small radius of curvature.
However, such structures exhibit electron emission characteristics which impose significant limitations on emitter utility such as, for example, effectively controlling the emission current and emission trajectory.
Accordingly, there exists a need for a field emission device and a field emission electron emitter which overcomes at least some of the shortcomings of the prior art.

Summa~y of ~hP Inventio~

This need and others are substantially met through provision of an electrically modulatable electron emitter including a diamond semiconductor electron emitter having an emitting surface for emitting electrons and a major surface, and a layer of conductive/semiconductive material disposed at least partially on the major surface of the diamond semiconductor electron emitter.
This need and others are further met through a method of producing an electrically modulatable electron emitter including the steps of forming a diamond semiconductor electron emitter with an emitting surface for emitting electrons and a major surface, and forming a layer of conductive/semiconductive material in contact with the major surface of the diamond semiconductor electron emitter such that an electron depletion region, and a depletion region width associated therewith, is formed at an interface between the diamond semiconductor electron emitter and the layer of conductive/semiconductive material.
This need and others are still further met through provision of a field emission device including a supporting substrate having a major surface, a first layer of . , .

selectively patterned conductive/semiconductive material disposed on the major surface of the supporting substrate, a first selectively shaped diamond semiconductor electron emitter having a major surface and at least an emitting surface, the diamond shaped semiconductor electron emitter being disposed on the first layer of selectively patterned conductive/semiconductive material, a layer of insulator material disposed on the major surface of the supporting substrate and a part of the major surface of the diamond semiconductor electron emitter, a second layer of conductive/semiconductive material disposed on the layer of insulator material and in physical contact with the major surface of the diamond semiconductor electron emitter such that a junction having a depletion region, and a depletion region width associated therewith, is formed at the interface corresponding thereto, and an anode distally disposed with respect to the emitting surface of the diamond semiconductor electron emitter for collecting emitted electrons.

3rief Descriptio~ of the Drawings FIG. lA is a side elevational depiction of an embodiment of a field emission device in accordance with the present invention.
FIG. lB is a second depiction of the embodiment described in FIG. lA.
FIG. 2 is a partial perspective view of a field emission device in accordance with the present invention.
FIG. 3A is a side elevational depic-tion of another ~-embodiment of a field emission device in accordance with the present invention.
FIG. 3B is a second depiction of the embodiment described in FIG. 3A.
FIG. 4 is a partial perspective view of a field emission device in accordance with the present invention.

: ~ .
., FIG. 5 is a partial perspective view of a modified field emission device similar to FIG. 4.

Detailed PeScription of the Preferred_~m~Qdiments Referring now to FIG. lA there is depicted a side elevational cross-sectional view of an embodiment of a field emission device 100 in accordance with the present invention. A supporting substrate 101 having a major surface is provided. A selectively shaped diamond semiconductor electron emitter 102 having a major surface 130 and an emitting surface 120, for emitting electrons, is disposed on the major surface of supporting substrate 101. Electron emitter 102 is selectively shaped, in a first method of realizing the diamond emitters, by initially growing a layer of diamond directly onto the major surface of supporting substrate 101 and subsequently selectively etching some of the diamond layer to selectively shape diamond semiconductor electron emitter 102. A layer 103 of insulator material is deposited on exposed parts of the major surface of supporting substrate 101 and disposed on major surface 130 of diamond semiconductor electron emitter 102. A layer 104 of conductive/semiconductive material is deposited on layer 103 and disposed on at least a part of major surface 130 of diamond semiconductor electron emitter 102.
A junction having a depletion region 110, and a depletion region width associated therewith, is formed at the interface between diamond semiconductor electron emitter 102 and layer 104 disposed thereon. An anode 108 is distally disposed with respect to emitting surface 120 of diamond semiconductor electron emitter 102 to collect emitted electrons, depicted by arrows 109. Whil~ diamond semiconductor electron emitter 102, and device 100, is illustrated as being generally perpendicular to supporting substrate 101, it should be understood that field emission device 100 could alternatively be formed, generally as .

.
' '; ~' ': : `

.

described herein, in a horizontal position on a nonconducting supporting substrate FIG. lA further depicts a first externally provided voltage source 106 operably coupled to layer 104 of conductive/semiconductive material. Voltage source 106 provides a variable voltage to layer 104 which will cause the width of junction depletion region 110 to vary correspondingly. This modulation of the width of junction depletion region 110 results in modulation of the electrons made available at emitting surface 120 of diamond semiconductor electron emitter 102.
A second externally provided voltage source 107 is operably coupled to anode 108 so that emitted electrons 109 are collected at anode 108. Voltage source 107 further provides an accelerating electric field in the region between anode 108 and emitting surface 120 of diamond semiconductor electron emitter 102. This electric field is utilized to remove electrons residing at/near emitting surface 120 of diamond semiconductor electron emitter 102 and sweep them into the free-space region between anode 108 and emitting surface 120 of diamond semiconductor electron emitter 102. In the absence of any accelerating electric field, electrons will not transit the region between anode 108 and diamond semiconductor electron emitter 102.
A third externally provided voltage source 105 is operably coupled to supporting substrate 101. Alternatively, supporting substrate 101 may be operably coupled to a ground reference potential corresponding to 0.0 volts in place of voltage source 105.
FIG. lB depicts structure 100 wherein electrons arrive at emitting surface 120 of diamond semiconductor electron emitter 102 by transitting the bulk of the diamond semiconductor and are subsequently swept away from emitting surface 120 by any accelerating electric field. However, modulation of the width of junction depletion region llO is shown to effectively control the availability of electrons at emitting surface 120. By so doing electron emission rates .

are effectively modulated. Increasing the magnitude of the voltage operably coupled to layer 104 results in an increase in the width of junction depletion region 110. Since junction depletion region 110 is substantially void of conduction band electrons and since electrons transiting the bulk of the diamond semiconductor do not traverse junction depletion region 110, it is possible to stop the flow of electrons to emitting surface 120 by applying a voltage of appropriate magnitude to layer 104, in which case field emission device 100 is effectively placed in the OFF mode and electron emission is cut-off. FIG. lB depicts the width of junction depletion region 110 as being so extensive as to effectively traverse the entire width of diamond semiconductor electron emitter 102.
It is one object of the diamond semiconductor of the present invention to provide a field emission electron device which does not suffer from the breakdown mechanisms inherent in the structures of the prior art wherein very high electric fields must be generated at the electron emitter in order to induce electron emission. The diamond semiconductor material employed for the electron emitter in the present invention exhibits an electron affinity of less than 1.0 electron volts corresponding to one crystallographic plane and an electron affinity of less than 0.0 electron volts corresponding to yet another crystallographic plane. A desired electron affinity is attained by depositing the diamond semiconductor material with emitting surface 120 lying in the chosen crystallographic plane. As such, much smaller magnitude electric fields may be employed to achieve substantial electron emission than is the case with electron emitters of the prior art. Further, there is no need to provide geometric discontinuities of small radius of curvature as required in prior art embodiments.
FIG. 2 is a partial perspective view of an embodiment of a field emission device 200 in accordance with the present invention wherein features corresponding to those .
- : , - '; . :
.. . . .

.

first described in FIGS. lA & lB are similarly referenced beginning with the numeral "2". Device 200 includes a plurality of diamond semiconductor electron emitters 202 disposed as an array of electron emitters within a single structure. Device operation is essentially similar to that described previously wherein electron emission is substantia]ly controlled by providing a modulating voltage to a layer 204 of conductive/semiconductive material as described previously with reference to FIG. lB. Emitted electrons are collected by an anode 208.
FIG. 3A is a side elevational cross sectional depiction of another embodiment of a field emission device 300 employing a diamond semiconductor electron emitter 302 in accordance with the present invention and wherein features corresponding to features previously identified with reference to FIGS. lA & lB are similarly referenced beginning with the numeral "3". In device 300, diamond semiconductor electron emitter 302 is disposed on a first layer 315 of conductive/semiconductive material which is selectively patterned subsequent to deposition on the major surface of supporting substrate 301. Alternatively, the major surface of supporting substrate 301 may be selectively exposed by providing a patterned mask layer, and layer 315 of conductive/semiconductive material selectively deposited onto the selectively exposed part of the major surface of the supporting substrate. Both techniques are commonly employed in the known art. In this embodiment a second layer 304 of conductive/semiconductive material corresponds to and performs the same function as layer 104 of conductive/semiconductive material described previously with reference to FIG. lA.
FIG. 3A further depicts an anode 308 comprising a plurality of layers including a substantially optically transparent faceplate 311 having a surface, a layer of cathodoluminescent material 312 disposed on the surface of faceplate 311, and a conductive layer 313 disposed on cathodoluminescent layer 312. Emitted electrons, depicted by :
, 8 ~ 3~ r~

arrows 309, traversing the region between emitting surface 320 of dlamond semiconductor electron emitter 302 and distally disposed anode 308 imparts energy to active sites within cathodoluminescent layer 312 to stimulate photon emission, depicted by arrows 314, which is observed through substantially optically transparent faceplate 311.
FIG. 3B is a side elevational cross-sectional depiction of device 300 functioning as described previously with reference to FIG. lB. Voltage supplies 305, 306 and 307 are connected and operate as previously described. In device 300, electron emission from diamond semiconductor electron emitter 302 is effectively modulated by applying an appropriate externally provided voltage to layer 304 of conductive/semiconductive material to modulate the width of junction depletion region 310. Modulation of electron emission modulates photon emission from cathodoluminescent layer 312 to produce a visual display.
Referring now to FIG. 4 there is depicted a partial perspective view of a device 400 wherein features corresponding to features previously identified with reference to FIG. 3A & 3B are similarly referenced beginning with the numeral "4". In device 400, a selectively patterned first layer 415 of conductive/semiconductive material is realized as a plurality of electrically independent stripes.
Similarly in device 400 a second layer 404 of conductive/semiconductive material is selectively patterned as a plurality of stripes. It should be understood that the term strips is herein defined to encompass any shapes utilized for specific applications, including but not limited to regions or areas, in which layers 415 and 404 are constructed with electrically separate portions. So formed, each of a plurality of diamond semiconductor electron emitters 402 are selectively placed in the ON/OFF mode and electron emission controlled through provision of selecting the voltage applied to each of the electrically independent stripes. By so doing selected regions of a cathodoluminescent layer 412 are induced to emit photons 9 ~ 3~3r~i~

resulting in the formation of an image observable through a substantially optically transparent faceplate 411.
Referring now to FIG. 5 there is depicted a partial perspective view of a device 500 wherein features corresponding to features previously identified with reference to FIG. 4 are similarly referenced beginning with the numeral "5". Device 500, further depicts an anode 508 comprising a plurality of layers including a substantially optically transparent faceplate 511 having a surface, a conductive layer 513 disposed on the surface of faceplate 511, and a layer of cathodoluminescent material 512 disposed on conductive layer 513. It will of course be understood that in this specific embodiment conductive layer 513 is formed of substantially optically transparent material so 15 that photons emitted by cathodoluminescent layer 512 are -.
observable through faceplate 511 and conductive layer 513.
Thus, improved electron emitters are disclosed which include diamond semiconductor material for the electron emitter, which exhibits an electron affinity of less than 1.0 electron volts corresponding to one crystallographic plane and an electron affinity of less than 0.0 electron volts corresponding to yet another crystallographic plane.
As such, much smaller magnitude electric fields may be employed to achieve substantial electron emission than is the case with electron emitters of the prior art. Because of this reduced electron affinity the electron emitters are not limited to geometric formations, such as tips/edges of small radius of curvature, that incur damage as a result of ion bombardment. Further, in the presence of very low residual gas pressures the emitters are not subjected to ion attack which damages the emitting tip/edge and renders it useless.
While we have shown and described specific embodiments of the present invention, further modifications and improvements will occur to those skilled in the art. We desire it to be understood, therefore, that this invention is not limited to the particular forms shown and we intend ' ' ; " ~', , ;~ r,~

in the append claims to cover all modifications that do not depart from the spirit and scope of this invention.

, ~ , : , , - : :

Claims (50)

1. An electrically modulatable electron emitter comprising:
a diamond semiconductor electron emitter having an emitting surface for emitting electrons and a major surface;
and a layer of conductive/semiconductive material disposed at least partially on the major surface of the diamond semiconductor electron emitter and forming a junction depletion region therewith.
2. The electron emitter of claim 1 wherein the diamond semiconductor electron emitter is disposed on a supporting substrate.
3. The electron emitter of claim 1 wherein at least a part of the emitting surface exhibits an electron affinity of less than 1 electron volt.
4. The electron emitter of claim 1 wherein at least a part of the emitting surface exhibits an electron affinity of less than zero volts.
5. An electrically modulatable electron emitter comprising:
a diamond semiconductor electron emitter having a bulk of diamond semiconductor material with an emitting surface for emitting electrons and a major surface;
a layer of conductive/semiconductive material at least partially disposed on the major surface of the diamond semiconductor electron emitter such that a junction having a depletion region, and a depletion region width associated therewith, is formed at the interface corresponding thereto and a voltage source operably coupled to the layer of conductive/semiconductive material, such that modulation of the voltage source causes modulation of the junction depletion region width and effectively controls electrons transiting the bulk of the diamond semiconductor material to the emitting surface.
6. The electron emitter of claim 5 wherein the diamond semiconductor electron emitter is disposed on a supporting substrate.
7. The electron emitter of claim 5 wherein at least a part of the emitting surface exhibits an electron affinity of less than 1 electron volt.
8. The electron emitter of claim 5 wherein at least a part of the emitting surface exhibits an electron affinity of less than zero volts.
9. A field emission device comprising:
a supporting substrate having a major surface;
a selectively shaped diamond semiconductor electron emitter having a major surface and an emitting surface, the diamond semiconductor electron emitter being disposed on the major surface of the supporting substrate;
a layer of insulator material disposed on the major surface of the supporting substrate and on a part of the major surface of the diamond semiconductor electron emitter;
and a layer of conductive/semiconductive material disposed on the layer of insulator material and in physical contact with a part of the major surface of the diamond semiconductor electron emitter, such that a junction having a depletion region, and a depletion region width associated therewith, is formed at the interface corresponding thereto.
10. The field emission device of claim 9 and further comprising a plurality of selectively shaped diamond semiconductor electron emitters.
11. The field emission device of claim 9 wherein the layer of conductive/semiconductive material is selectively formed as a plurality of electrically independent stripes.
12. The field emission device of claim 9 wherein at least a part of the emitting surface of the electron emitter exhibits an electron affinity of less than 1 electron volt.
13. The field emission device of claim 9 wherein at least a part of the emitting surface of the electron emitter exhibits an electron affinity of less than zero volts.
14. A field emission device comprising:
a supporting substrate having a major surface;
a first layer of selectively patterned conductive/semiconductive material disposed on the major surface of the supporting substrate;
a selectively shaped diamond semiconductor electron emitter having a major surface and an emitting surface, the diamond semiconductor electron emitter being disposed on the first layer of selectively patterned conductive/semiconductive material;
a layer of insulator material disposed on the major surface of the supporting substrate and at least a part of the major surface of the diamond semiconductor electron emitter; and a second layer of conductive/semiconductive material disposed on the layer of insulator material and in physical contact with the major surface of the diamond semiconductor electron emitter, such that a junction having a depletion region and having a depletion region width associated therewith is formed at the interface between the layer of conductive/semiconductive material and the diamond semiconductor electron emitter major surface.
15. The field emission device of claim 14 wherein the first layer of conductive/semiconductive material is selectively formed as a plurality of electrically independent stripes.
16 The field emission device of claim 14 wherein the second layer of conductive/semiconductive material is selectively formed as a plurality of electrically independent stripes.
17. The field emission device of claim 14 wherein at least a part of the emitting surface of the diamond semiconductor electron emitter exhibits an electron affinity of less than 1 electron volt.
18. The field emission device of claim 14 wherein at least a part of the emitting surface of the diamond semiconductor electron emitter exhibits an electron affinity of less than zero volts.
19. A field emission device comprising:
a supporting substrate having a major surface;
a first layer of selectively patterned conductive/semiconductive material disposed on the major surface of the supporting substrate;
a first selectively shaped diamond semiconductor electron emitter having a major surface and an emitting surface, the diamond shaped semiconductor electron emitter being disposed on the first layer of selectively patterned conductive/semiconductive material;
a layer of insulator material disposed on the major surface of the supporting substrate and a part of the major surface of the diamond semiconductor electron emitter;

a second layer of conductive/semiconductive material disposed on the layer of insulator material and in physical contact with the major surface of the diamond semiconductor electron emitter such that a junction having a depletion region, and a depletion region width associated therewith, is formed at the interface corresponding thereto; and an anode distally disposed with respect to the emitting surface of the diamond semiconductor electron emitter for collecting emitted electrons.
20. The field emission device of claim 19 wherein the first layer of conductive/semiconductive material is selectively formed as a plurality of electrically independent stripes.
21. The field emission device of claim 19 wherein the second layer of conductive/semiconductive material is selectively formed as a plurality of electrically independent stripes.
22. The field emission device of claim 19 wherein at least a part of the emitting surface of the diamond semiconductor electron emitter exhibits an electron affinity of less than 1 electron volt.
23. The field emission device of claim 19 wherein at least a part of the emitting surface of the diamond semiconductor electron emitter exhibits an electron affinity of less than zero volts.
24. The field emission device of claim 19 wherein the anode electrode includes a substantially optically transparent faceplate having a surface, a layer of cathodoluminescent material disposed on the surface of the faceplate, and a conductive layer disposed on the layer of cathodoluminescent material.
25. The field emission device of claim 19 wherein the anode electrode includes a substantially optically transparent faceplate having a surface, a conductive layer disposed on the surface of the faceplate, and a layer of cathodoluminescent material disposed on the conductive layer.
26. A field emission device comprising:
a supporting substrate having a major surface;
a first selectively shaped diamond semiconductor electron emitter having a major surface and an emitting surface, the diamond semiconductor electron emitter being disposed on the major surface of the supporting substrate;
a layer of insulator material disposed on the major surface of the supporting substrate and a part of the major surface of the diamond semiconductor electron emitter;
a layer of conductive/semiconductive material disposed on the layer of insulator material and in physical contact with the major surface of the diamond semiconductor electron emitter such that a junction having a depletion region, and having an associated depletion region width, is formed at the interface between the layer of conductive/semiconductive material and the diamond semiconductor electron emitter major surface; and an anode distally disposed with respect to the emitting surface of the diamond semiconductor electron emitter for collecting emitted electrons.
27. The field emission device of claim 26 wherein the anode electrode includes a substantially optically transparent faceplate having a surface, a layer of cathodoluminescent material disposed on the surface of the faceplate, and a conductive layer disposed on the layer of cathodoluminescent material.
28. The field emission device of claim 26 wherein at least a part of the emitting surface of the diamond semiconductor electron emitter exhibits an electron affinity of less than 1 electron volt.
29. The electron emitter of claim 26 wherein at least a part of the emitting surface of the diamond semiconductor electron emitter exhibits an electron affinity of less than zero volts.
30. A field emission device comprising:
a supporting substrate having a major surface;
a first selectively shaped diamond semiconductor electron emitter having a bulk with a major surface and an emitting surface, the diamond semiconductor electron emitter being disposed on a part of the major surface of the supporting substrate;
a layer of insulator material disposed on the major surface of the supporting substrate and a part of the major surface of the diamond semiconductor electron emitter;
a layer of conductive/semiconductive material disposed on the layer of insulator material and in physical contact with the major surface of the diamond semiconductor electron emitter such that a junction having a depletion region, and having a depletion region width associated therewith, is formed at the interface between the layer of conductive/semiconductive material and the diamond semiconductor electron emitter major surface and extending into the bulk of the diamond semiconductor electron emitter;
and a first externally provided voltage source operably coupled to the layer of conductive/semiconductive material and modulating the width of the junction depletion region, such that modulation of the junction width effectively controls the availability of electrons at the emitting surface of the diamond semiconductor electron emitter.
31. The field emission device of claim 30 wherein at least a part of the emitting surface of the diamond semiconductor electron emitter exhibits an electron affinity of less than 1 electron volt.
32. The field emission device of claim 30 wherein at least a part of the emitting surface of the diamond semiconductor electron emitter exhibits an electron affinity of less than zero volts.
33. A field emission device comprising:
a supporting substrate having a major surface;
a first selectively shaped diamond semiconductor electron emitter having a bulk with a major surface and an emitting surface, the diamond semiconductor electron emitter being disposed on a part of the major surface of the supporting substrate;
a layer of insulator material disposed on the major surface of the supporting substrate and a part of the major surface of the diamond semiconductor electron emitter;
a layer of conductive/semiconductive material disposed on the layer of insulator material and in physical contact with the major surface of the diamond semiconductor electron emitter such that a junction having a depletion region, and having a depletion region width associated therewith, is formed at the interface between the layer of conductive/semiconductive material and the diamond semiconductor electron emitter major surface and extending into the bulk of the diamond semiconductor electron emitter;

a voltage source operably coupled to the layer of conductive/semiconductive material for modulating the width of the junction depletion region; and an anode for collecting electrons emitted from the diamond semiconductor electron emitter emitting surface, such that modulation of the junction width effectively controls the availability of electrons at the emitting surface of the diamond semiconductor electron emitter.
34. The field emission device of claim 33 wherein the anode electrode includes a substantially optically transparent faceplate having a surface, and a layer of cathodoluminescent material disposed on the surface of the faceplate, and a conductive layer disposed on the layer of cathodoluminescent material.
35. The field emission device of claim 33 wherein the anode electrode includes a substantially optically transparent faceplate having a surface, a conductive layer disposed on the surface of the faceplate, and a layer of cathodoluminescent material disposed on the conductive layer.
36. The field emission device of claim 33 wherein at least a part of the emitting surface of the diamond semiconductor electron emitter exhibits an electron affinity of less than 1 electron volt.
37. The field emission device of claim 33 wherein at least a part of the emitting surface of the diamond semiconductor electron emitter exhibits an electron affinity of less than zero volts.
38. A field emission device comprising:
a supporting substrate having a major surface a first layer of selectively patterned conductive/semiconductive material disposed on the major surface of the supporting substrate;
a selectively shaped diamond semiconductor electron emitter having a major surface and an emitting surface, the diamond semiconductor electron emitter being disposed on the first layer of selectively patterned conductive/semiconductive material;
a layer of insulator material disposed on the major surface of the supporting substrate and a part of the major surface of the diamond semiconductor electron emitter;
a second layer of conductive/semiconductive material disposed on the layer of insulator material and in physical contact with the major surface of the diamond semiconductor electron emitter such that a junction having a depletion region, and a depletion region width associated therewith, is formed at the interface corresponding thereto;
a voltage source operably coupled to the second layer of conductive/semiconductive material for modulating the width of the junction depletion region; and an anode for collecting electrons emitted from the emitting surface of the diamond semiconductor electron emitter, such that modulation of the junction width effectively controls the availability of electrons at the emitting surface of the diamond semiconductor electron emitter.
39. The field emission device of claim 38 wherein the first layer of conductive/semiconductive material is selectively formed as a plurality of electrically independent stripes
40. The field emission device of claim 38 wherein the second layer of conductive/semiconductive material is selectively formed as a plurality of electrically independent stripes.
41. The field emission device of claim 38 wherein the anode electrode includes a substantially optically transparent faceplate having a surface, a layer of cathodoluminescent material disposed on the surface of the faceplate, and a conductive layer disposed on the layer of cathodoluminescent material.
42. The field emission device of claim 38 wherein the anode electrode includes a substantially optically transparent faceplate having a surface, a conductive layer disposed on the surface of the faceplate, and a layer of cathodoluminescent material disposed on the conductive layer.
43. The field emission device of claim 38 wherein at least a part of the emitting surface of the diamond semiconductor electron emitter exhibits an electron affinity of less than 1 electron volt.
44. The field emission device of claim 38 wherein at least a part of the emitting surface of the diamond semiconductor electron emitter exhibits an electron affinity of less than zero volts.
45. A method of producing an electrically modulatable electron emitter comprising the steps of:
forming a diamond semiconductor electron emitter with an emitting surface for emitting electrons and a major surface; and forming a layer of conductive/semiconductive material in contact with the major surface of the diamond semiconductor electron emitter such that an electron depletion region, and a depletion region width associated therewith, is formed at an interface between the diamond semiconductor electron emitter and the layer of conductive/semiconductive material.
46. A method of producing an electrically modulatable electron emitter as set forth in claim 45 including in addition the step of coupling a voltage source to the layer of conductive/semiconductive material, such that modulation of the voltage source causes modulation of the depletion region width and effectively controls electrons transiting the bulk of the diamond semiconductor material to the emitting surface.
47. A method of producing a field emission device comprising the steps of:
forming a selectively shaped diamond semiconductor electron emitter with a major surface and an emitting surface;
forming a layer of conductive/semiconductive material in physical contact with the major surface of the diamond semiconductor electron emitter such that a junction having a depletion region, and a depletion region width associated therewith, is formed at an interface between the diamond semiconductor electron emitter and the layer of conductive/semiconductive material; and forming an anode distally disposed with respect to the emitting surface of the diamond semiconductor electron emitter for collecting emitted electrons.from the emitting surface of the diamond semiconductor electron emitter, such that modulation of the junction width effectively controls the availability of electrons at the emitting surface of the diamond semiconductor electron emitter.
48. A method of producing a field emission device as claimed in claim 47 including in addition the step of coupling a voltage source to the layer of conductive/semiconductive material for modulating the width of the junction depletion region.
49. A method of producing a field emission device as claimed in claim 47 wherein the step of forming the anode includes forming a substantially optically transparent faceplate having a surface, disposing a layer of cathodoluminescent material on the surface of the faceplate, and disposing a conductive layer on the layer of cathodoluminescent material.
50. A method of producing a field emission device as claimed in claim 47 wherein the step of forming the anode includes forming a substantially optically transparent faceplate having a surface, disposing a conductive layer on the surface of the faceplate, and disposing a layer of cathodoluminescent material on the conductive layer.
CA002070942A 1991-08-20 1992-06-10 Field emission electron device employing a modulatable diamond semiconductor emitter Abandoned CA2070942A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/747,564 1991-08-20
US07/747,564 US5138237A (en) 1991-08-20 1991-08-20 Field emission electron device employing a modulatable diamond semiconductor emitter

Publications (1)

Publication Number Publication Date
CA2070942A1 true CA2070942A1 (en) 1993-02-21

Family

ID=25005652

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002070942A Abandoned CA2070942A1 (en) 1991-08-20 1992-06-10 Field emission electron device employing a modulatable diamond semiconductor emitter

Country Status (5)

Country Link
US (1) US5138237A (en)
EP (1) EP0528390A1 (en)
JP (1) JPH05205612A (en)
CN (1) CN1069825A (en)
CA (1) CA2070942A1 (en)

Families Citing this family (78)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3255960B2 (en) * 1991-09-30 2002-02-12 株式会社神戸製鋼所 Cold cathode emitter element
US5199918A (en) * 1991-11-07 1993-04-06 Microelectronics And Computer Technology Corporation Method of forming field emitter device with diamond emission tips
US5536193A (en) * 1991-11-07 1996-07-16 Microelectronics And Computer Technology Corporation Method of making wide band gap field emitter
US5397428A (en) * 1991-12-20 1995-03-14 The University Of North Carolina At Chapel Hill Nucleation enhancement for chemical vapor deposition of diamond
US5675216A (en) 1992-03-16 1997-10-07 Microelectronics And Computer Technololgy Corp. Amorphic diamond film flat field emission cathode
US5763997A (en) 1992-03-16 1998-06-09 Si Diamond Technology, Inc. Field emission display device
US6127773A (en) 1992-03-16 2000-10-03 Si Diamond Technology, Inc. Amorphic diamond film flat field emission cathode
US5543684A (en) 1992-03-16 1996-08-06 Microelectronics And Computer Technology Corporation Flat panel display based on diamond thin films
US5449970A (en) 1992-03-16 1995-09-12 Microelectronics And Computer Technology Corporation Diode structure flat panel display
US5600200A (en) 1992-03-16 1997-02-04 Microelectronics And Computer Technology Corporation Wire-mesh cathode
US5679043A (en) 1992-03-16 1997-10-21 Microelectronics And Computer Technology Corporation Method of making a field emitter
US5289086A (en) * 1992-05-04 1994-02-22 Motorola, Inc. Electron device employing a diamond film electron source
JP3353943B2 (en) * 1992-06-01 2002-12-09 モトローラ・インコーポレイテッド Inversion mode electron emitter
US5278475A (en) * 1992-06-01 1994-01-11 Motorola, Inc. Cathodoluminescent display apparatus and method for realization using diamond crystallites
JPH08505259A (en) * 1992-12-23 1996-06-04 エスアイ ダイアモンド テクノロジー,インコーポレイテッド Flat panel display with triode structure using flat field emission cathode
KR100307384B1 (en) * 1993-01-19 2001-12-17 레오니드 다니로비치 카르포브 Field emitter
US5340997A (en) * 1993-09-20 1994-08-23 Hewlett-Packard Company Electrostatically shielded field emission microelectronic device
US5747815A (en) * 1993-09-22 1998-05-05 Northrop Grumman Corporation Micro-miniature ionizer for gas sensor applications and method of making micro-miniature ionizer
JP3269065B2 (en) * 1993-09-24 2002-03-25 住友電気工業株式会社 Electronic device
US5844252A (en) * 1993-09-24 1998-12-01 Sumitomo Electric Industries, Ltd. Field emission devices having diamond field emitter, methods for making same, and methods for fabricating porous diamond
AU1043895A (en) 1993-11-04 1995-05-23 Microelectronics And Computer Technology Corporation Methods for fabricating flat panel display systems and components
US5545946A (en) * 1993-12-17 1996-08-13 Motorola Field emission display with getter in vacuum chamber
US5602439A (en) * 1994-02-14 1997-02-11 The Regents Of The University Of California, Office Of Technology Transfer Diamond-graphite field emitters
US5578901A (en) * 1994-02-14 1996-11-26 E. I. Du Pont De Nemours And Company Diamond fiber field emitters
EP0675519A1 (en) * 1994-03-30 1995-10-04 AT&T Corp. Apparatus comprising field emitters
US5550426A (en) * 1994-06-30 1996-08-27 Motorola Field emission device
US5631196A (en) * 1994-07-18 1997-05-20 Motorola Method for making inversion mode diamond electron source
KR100314830B1 (en) * 1994-07-27 2002-02-28 김순택 Method for fabricating field emission display device
US6204834B1 (en) 1994-08-17 2001-03-20 Si Diamond Technology, Inc. System and method for achieving uniform screen brightness within a matrix display
US5504385A (en) * 1994-08-31 1996-04-02 At&T Corp. Spaced-gate emission device and method for making same
EP0700065B1 (en) * 1994-08-31 2001-09-19 AT&T Corp. Field emission device and method for making same
US5531880A (en) * 1994-09-13 1996-07-02 Microelectronics And Computer Technology Corporation Method for producing thin, uniform powder phosphor for display screens
US5623180A (en) * 1994-10-31 1997-04-22 Lucent Technologies Inc. Electron field emitters comprising particles cooled with low voltage emitting material
US5637950A (en) 1994-10-31 1997-06-10 Lucent Technologies Inc. Field emission devices employing enhanced diamond field emitters
US5592053A (en) * 1994-12-06 1997-01-07 Kobe Steel Usa, Inc. Diamond target electron beam device
US5616368A (en) * 1995-01-31 1997-04-01 Lucent Technologies Inc. Field emission devices employing activated diamond particle emitters and methods for making same
US5709577A (en) * 1994-12-22 1998-01-20 Lucent Technologies Inc. Method of making field emission devices employing ultra-fine diamond particle emitters
US5751262A (en) 1995-01-24 1998-05-12 Micron Display Technology, Inc. Method and apparatus for testing emissive cathodes
US5561340A (en) * 1995-01-31 1996-10-01 Lucent Technologies Inc. Field emission display having corrugated support pillars and method for manufacturing
US5598056A (en) * 1995-01-31 1997-01-28 Lucent Technologies Inc. Multilayer pillar structure for improved field emission devices
US6296740B1 (en) 1995-04-24 2001-10-02 Si Diamond Technology, Inc. Pretreatment process for a surface texturing process
US5628659A (en) * 1995-04-24 1997-05-13 Microelectronics And Computer Corporation Method of making a field emission electron source with random micro-tip structures
US5679895A (en) * 1995-05-01 1997-10-21 Kobe Steel Usa, Inc. Diamond field emission acceleration sensor
US5647998A (en) * 1995-06-13 1997-07-15 Advanced Vision Technologies, Inc. Fabrication process for laminar composite lateral field-emission cathode
US5703380A (en) * 1995-06-13 1997-12-30 Advanced Vision Technologies Inc. Laminar composite lateral field-emission cathode
US6060839A (en) * 1995-08-09 2000-05-09 Thermotrex Corporation Thin diamond electron beam amplifier
JP2782587B2 (en) * 1995-08-25 1998-08-06 工業技術院長 Cold electron emission device
US5648699A (en) 1995-11-09 1997-07-15 Lucent Technologies Inc. Field emission devices employing improved emitters on metal foil and methods for making such devices
KR0181256B1 (en) * 1996-02-01 1999-03-20 김은영 Method of manufacturing diamond tip
DE69731231T2 (en) 1996-06-25 2005-03-03 Vanderbilt University, Nashville STRUCTURES, ARRANGEMENTS AND DEVICES WITH VACUUM FIELD EMISSION MICROSPITES AND METHOD FOR THE PRODUCTION THEREOF
JP3026484B2 (en) * 1996-08-23 2000-03-27 日本電気株式会社 Field emission cold cathode
US6020677A (en) * 1996-11-13 2000-02-01 E. I. Du Pont De Nemours And Company Carbon cone and carbon whisker field emitters
US6498349B1 (en) 1997-02-05 2002-12-24 Ut-Battelle Electrostatically focused addressable field emission array chips (AFEA's) for high-speed massively parallel maskless digital E-beam direct write lithography and scanning electron microscopy
US5892231A (en) * 1997-02-05 1999-04-06 Lockheed Martin Energy Research Corporation Virtual mask digital electron beam lithography
US5888113A (en) * 1997-03-27 1999-03-30 Universities Research Association, Inc. Process for making a cesiated diamond film field emitter and field emitter formed therefrom
US6351254B2 (en) * 1998-07-06 2002-02-26 The Regents Of The University Of California Junction-based field emission structure for field emission display
US6630772B1 (en) 1998-09-21 2003-10-07 Agere Systems Inc. Device comprising carbon nanotube field emitter structure and process for forming device
US6441550B1 (en) 1998-10-12 2002-08-27 Extreme Devices Inc. Carbon-based field emission electron device for high current density applications
US6181055B1 (en) 1998-10-12 2001-01-30 Extreme Devices, Inc. Multilayer carbon-based field emission electron device for high current density applications
CN1289449A (en) * 1998-11-30 2001-03-28 皇家菲利浦电子有限公司 Discharge lamp
US6250984B1 (en) 1999-01-25 2001-06-26 Agere Systems Guardian Corp. Article comprising enhanced nanotube emitter structure and process for fabricating article
US6283812B1 (en) 1999-01-25 2001-09-04 Agere Systems Guardian Corp. Process for fabricating article comprising aligned truncated carbon nanotubes
US6741019B1 (en) 1999-10-18 2004-05-25 Agere Systems, Inc. Article comprising aligned nanowires
US6876724B2 (en) * 2000-10-06 2005-04-05 The University Of North Carolina - Chapel Hill Large-area individually addressable multi-beam x-ray system and method of forming same
US7227924B2 (en) * 2000-10-06 2007-06-05 The University Of North Carolina At Chapel Hill Computed tomography scanning system and method using a field emission x-ray source
US6553096B1 (en) 2000-10-06 2003-04-22 The University Of North Carolina Chapel Hill X-ray generating mechanism using electron field emission cathode
US7082182B2 (en) * 2000-10-06 2006-07-25 The University Of North Carolina At Chapel Hill Computed tomography system for imaging of human and small animal
US7085351B2 (en) * 2000-10-06 2006-08-01 University Of North Carolina At Chapel Hill Method and apparatus for controlling electron beam current
CN1652283B (en) * 2005-01-01 2011-01-12 中国海洋大学 Field emitting electronic source device and its preparing process
US8155262B2 (en) * 2005-04-25 2012-04-10 The University Of North Carolina At Chapel Hill Methods, systems, and computer program products for multiplexing computed tomography
US8189893B2 (en) * 2006-05-19 2012-05-29 The University Of North Carolina At Chapel Hill Methods, systems, and computer program products for binary multiplexing x-ray radiography
WO2009012453A1 (en) * 2007-07-19 2009-01-22 The University Of North Carolina At Chapel Hill Stationary x-ray digital breast tomosynthesis systems and related methods
US8600003B2 (en) * 2009-01-16 2013-12-03 The University Of North Carolina At Chapel Hill Compact microbeam radiation therapy systems and methods for cancer treatment and research
RU2446506C1 (en) * 2010-07-12 2012-03-27 Борис Исаакович Горфинкель Cell with field emission and method of its production
US8358739B2 (en) 2010-09-03 2013-01-22 The University Of North Carolina At Chapel Hill Systems and methods for temporal multiplexing X-ray imaging
US9782136B2 (en) 2014-06-17 2017-10-10 The University Of North Carolina At Chapel Hill Intraoral tomosynthesis systems, methods, and computer readable media for dental imaging
US10980494B2 (en) 2014-10-20 2021-04-20 The University Of North Carolina At Chapel Hill Systems and related methods for stationary digital chest tomosynthesis (s-DCT) imaging
US10835199B2 (en) 2016-02-01 2020-11-17 The University Of North Carolina At Chapel Hill Optical geometry calibration devices, systems, and related methods for three dimensional x-ray imaging

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5325632B2 (en) * 1973-03-22 1978-07-27
US3970887A (en) * 1974-06-19 1976-07-20 Micro-Bit Corporation Micro-structure field emission electron source
JPS5436828B2 (en) * 1974-08-16 1979-11-12
US3921022A (en) * 1974-09-03 1975-11-18 Rca Corp Field emitting device and method of making same
US4084942A (en) * 1975-08-27 1978-04-18 Villalobos Humberto Fernandez Ultrasharp diamond edges and points and method of making
NL7604569A (en) * 1976-04-29 1977-11-01 Philips Nv FIELD EMITTERING DEVICE AND PROCEDURE FOR FORMING THIS.
US4513308A (en) * 1982-09-23 1985-04-23 The United States Of America As Represented By The Secretary Of The Navy p-n Junction controlled field emitter array cathode
US4780684A (en) * 1987-10-22 1988-10-25 Hughes Aircraft Company Microwave integrated distributed amplifier with field emission triodes
JPH0260024A (en) * 1988-08-24 1990-02-28 Canon Inc Electron emission element
JPH0275902A (en) * 1988-09-13 1990-03-15 Seiko Instr Inc Diamond probe and its forming method
JPH0296532A (en) * 1988-10-03 1990-04-09 Akiomi Yamaguchi Water soluble extract from pittosporaceae plant effective against diabetes mellitus and liver disease and production thereof
DE68926090D1 (en) * 1988-10-17 1996-05-02 Matsushita Electric Ind Co Ltd Field emission cathodes
US4990766A (en) * 1989-05-22 1991-02-05 Murasa International Solid state electron amplifier
US5064396A (en) * 1990-01-29 1991-11-12 Coloray Display Corporation Method of manufacturing an electric field producing structure including a field emission cathode
US5007873A (en) * 1990-02-09 1991-04-16 Motorola, Inc. Non-planar field emission device having an emitter formed with a substantially normal vapor deposition process

Also Published As

Publication number Publication date
EP0528390A1 (en) 1993-02-24
US5138237A (en) 1992-08-11
JPH05205612A (en) 1993-08-13
CN1069825A (en) 1993-03-10

Similar Documents

Publication Publication Date Title
US5138237A (en) Field emission electron device employing a modulatable diamond semiconductor emitter
US5278475A (en) Cathodoluminescent display apparatus and method for realization using diamond crystallites
US5473218A (en) Diamond cold cathode using patterned metal for electron emission control
US7629736B2 (en) Method and device for preventing junction leakage in field emission devices
EP0523494B1 (en) An electron device employing a low/negative electron affinity electron source
US5757344A (en) Cold cathode emitter element
CA1194082A (en) Cathode ray tube with semiconductor cathode having deflection electrodes
US7264978B2 (en) Field emission type cold cathode and method of manufacturing the cold cathode
US5140219A (en) Field emission display device employing an integral planar field emission control device
US5289086A (en) Electron device employing a diamond film electron source
EP0644570B1 (en) An electrostatically shielded field emission microelectronic device
KR101009983B1 (en) Electron emission display
US5430348A (en) Inversion mode diamond electron source
US5719406A (en) Field emission device having a charge bleed-off barrier
US5929560A (en) Field emission display having an ion shield
US5804909A (en) Edge emission field emission device
JP3776314B2 (en) Structure and manufacture of a flat panel display with spacers including laterally divided surface electrodes
US5631196A (en) Method for making inversion mode diamond electron source
US5973445A (en) Device and method for efficient positioning of a getter
KR20020051592A (en) Triode - type field emission device with carbon nanotube cathode, triode - type RF vacuum device and field emission display using it
US5773920A (en) Graded electron affinity semiconductor field emitter
JP3320603B2 (en) Field emission cold cathode device and method of manufacturing the same
KR100286450B1 (en) Field emission emitter and method of manufacturing the same
KR19990053066A (en) Manufacturing Method of Field Emission Array with Ultra-Closed Gate and Emitter

Legal Events

Date Code Title Description
FZDE Dead