CA2250176A1 - Temporary wet strength polymers from oxidized reaction product of polyhydroxy polymer and 1,2-disubstituted carboxylic alkene - Google Patents
Temporary wet strength polymers from oxidized reaction product of polyhydroxy polymer and 1,2-disubstituted carboxylic alkeneInfo
- Publication number
- CA2250176A1 CA2250176A1 CA002250176A CA2250176A CA2250176A1 CA 2250176 A1 CA2250176 A1 CA 2250176A1 CA 002250176 A CA002250176 A CA 002250176A CA 2250176 A CA2250176 A CA 2250176A CA 2250176 A1 CA2250176 A1 CA 2250176A1
- Authority
- CA
- Canada
- Prior art keywords
- wet strength
- polymer
- temporary wet
- reaction product
- polyhydroxy polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 title abstract 8
- 150000001336 alkenes Chemical class 0.000 title 1
- 239000007795 chemical reaction product Substances 0.000 title 1
- -1 alkene compound Chemical class 0.000 abstract 1
- 125000002843 carboxylic acid group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000004676 glycans Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229920001282 polysaccharide Polymers 0.000 abstract 1
- 239000005017 polysaccharide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
- C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
- C07H13/04—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals attached to acyclic carbon atoms
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
- D21H21/20—Wet strength agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/02—Esters
- C08B31/04—Esters of organic acids, e.g. alkenyl-succinated starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
Abstract
A temporary wet strength polymer and compositions for paper products, e.g.
toilet tissue, is disclosed. The temporary wet strength polymer is the oxidation product of an esterified polyhydroxy polymer, more preferably of an esterified polysaccharide. The esterified polymer compound is formed by reacting the polyhydroxy polymer with a 1,2-disubstituted alkene compound that has at least one carboxylic acid group. The temporary wet strength polymer provides paper products having an initial wet strength that enables use of the product in the moistened condition, along with a suitable wet strength decay rate.
toilet tissue, is disclosed. The temporary wet strength polymer is the oxidation product of an esterified polyhydroxy polymer, more preferably of an esterified polysaccharide. The esterified polymer compound is formed by reacting the polyhydroxy polymer with a 1,2-disubstituted alkene compound that has at least one carboxylic acid group. The temporary wet strength polymer provides paper products having an initial wet strength that enables use of the product in the moistened condition, along with a suitable wet strength decay rate.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/624,764 US5656746A (en) | 1996-03-28 | 1996-03-28 | Temporary wet strength polymers from oxidized reaction product of polyhydroxy polymer and 1,2-disubstituted carboxylic alkene |
US08/624,764 | 1996-03-28 | ||
PCT/US1997/004833 WO1997036051A2 (en) | 1996-03-28 | 1997-03-25 | Temporary wet strength polymers from oxidized reaction product of polyhydroxy polymer and 1,2-disubstituted carboxylic alkene |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2250176A1 true CA2250176A1 (en) | 1997-10-02 |
CA2250176C CA2250176C (en) | 2005-10-25 |
Family
ID=24503227
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002250176A Expired - Fee Related CA2250176C (en) | 1996-03-28 | 1997-03-25 | Temporary wet strength polymers from oxidized reaction product of polyhydroxy polymer and 1,2-disubstituted carboxylic alkene |
Country Status (12)
Country | Link |
---|---|
US (1) | US5656746A (en) |
EP (1) | EP0890000B1 (en) |
JP (1) | JP3233287B2 (en) |
KR (1) | KR100282740B1 (en) |
AT (1) | ATE197827T1 (en) |
AU (1) | AU2545497A (en) |
BR (1) | BR9708439A (en) |
CA (1) | CA2250176C (en) |
DE (1) | DE69703616T2 (en) |
ES (1) | ES2152661T3 (en) |
WO (1) | WO1997036051A2 (en) |
ZA (1) | ZA972564B (en) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2179320T3 (en) | 1996-03-28 | 2003-01-16 | Procter & Gamble | PAPER PRODUCTS THAT HAVE RESISTANCE IN MOISTURE FROM CELLULOSICAL FIBERS FUNCTIONED WITH ALDEHYDE AND POLYMERS. |
US5895804A (en) * | 1997-10-27 | 1999-04-20 | National Starch And Chemical Investment Holding Corporation | Thermosetting polysaccharides |
US6127593A (en) * | 1997-11-25 | 2000-10-03 | The Procter & Gamble Company | Flushable fibrous structures |
US6511579B1 (en) * | 1998-06-12 | 2003-01-28 | Fort James Corporation | Method of making a paper web having a high internal void volume of secondary fibers and a product made by the process |
US6398911B1 (en) | 2000-01-21 | 2002-06-04 | Kimberly-Clark Worldwide, Inc. | Modified polysaccharides containing polysiloxane moieties |
US6517678B1 (en) | 2000-01-20 | 2003-02-11 | Kimberly-Clark Worldwide, Inc. | Modified polysaccharides containing amphiphillic hydrocarbon moieties |
US6896769B2 (en) | 1999-01-25 | 2005-05-24 | Kimberly-Clark Worldwide, Inc. | Modified condensation polymers containing azetidinium groups in conjunction with amphiphilic hydrocarbon moieties |
US6596126B1 (en) * | 1999-01-25 | 2003-07-22 | Kimberly-Clark Worldwide, Inc. | Modified polysaccharides containing aliphatic hydrocarbon moieties |
US6265052B1 (en) | 1999-02-09 | 2001-07-24 | The Procter & Gamble Company | Tissue paper |
ATE324384T1 (en) | 1999-02-24 | 2006-05-15 | Sca Hygiene Prod Gmbh | OXIDIZED CELLULOSE-CONTAINING FIBER MATERIALS AND PRODUCTS MADE THEREFROM |
DE19953590A1 (en) * | 1999-11-08 | 2001-05-17 | Sca Hygiene Prod Gmbh | Cellulose-containing fibrous material, for tissue papers and tissue products used in personal grooming and hygiene, includes hydroxy groups oxidized at the glucose units to aldehyde and/or carboxy groups |
DE19953589B4 (en) | 1999-11-08 | 2005-05-25 | Sca Hygiene Products Gmbh | Polysaccharide with functional groups, process for its preparation and products made therefrom |
DE19953591A1 (en) * | 1999-11-08 | 2001-05-17 | Sca Hygiene Prod Gmbh | Metal-crosslinkable oxidized cellulose-containing fibrous materials and products made from them |
US6465602B2 (en) | 2000-01-20 | 2002-10-15 | Kimberly-Clark Worldwide, Inc. | Modified condensation polymers having azetidinium groups and containing polysiloxane moieties |
US6683129B1 (en) * | 2000-03-31 | 2004-01-27 | National Starch And Chemical Investment Holding Corporation | Salt sensitive aqueous emulsions |
US20030008591A1 (en) * | 2001-06-18 | 2003-01-09 | Parsons John C. | Water dispersible, salt sensitive nonwoven materials |
GB2382592A (en) * | 2001-11-30 | 2003-06-04 | Sca Hygiene Prod Gmbh | Use of ozone to enhance the wet strength of fibrous cellulosic material |
US20030131958A1 (en) * | 2001-11-30 | 2003-07-17 | Thomas Jaschinski | Use of ozone for increasing the wet strength of paper and nonwoven |
US7125469B2 (en) * | 2003-10-16 | 2006-10-24 | The Procter & Gamble Company | Temporary wet strength resins |
US7320831B2 (en) * | 2005-05-03 | 2008-01-22 | Celanese International Corporation | Salt-sensitive vinyl acetate binder compositions and fibrous article incorporating same |
US7329705B2 (en) | 2005-05-03 | 2008-02-12 | Celanese International Corporation | Salt-sensitive binder compositions with N-alkyl acrylamide and fibrous articles incorporating same |
US7989545B2 (en) * | 2006-01-25 | 2011-08-02 | Celanese International Corporations | Salt-sensitive binders for nonwoven webs and method of making same |
WO2010005986A1 (en) * | 2008-07-08 | 2010-01-14 | Gilead Sciences, Inc. | Salts of hiv inhibitor compounds |
JP2011062269A (en) * | 2009-09-16 | 2011-03-31 | Nippon Paper Crecia Co Ltd | Tissue paper serving also as mask, and tissue paper type mask |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB688291A (en) * | 1950-06-15 | 1953-03-04 | Nat Starch Products Inc | Starch product of improved properties and method of making the same |
BE669912A (en) * | 1964-09-29 | 1966-01-17 | ||
US3505312A (en) * | 1969-03-27 | 1970-04-07 | Eastman Kodak Co | Method of manufacture of high phthalyl content cellulose acetate phthalate |
JPS4819231B1 (en) * | 1970-03-06 | 1973-06-12 | ||
JPS4917367B1 (en) * | 1970-04-07 | 1974-04-30 | ||
JPS4917482B1 (en) * | 1970-06-17 | 1974-05-01 | ||
US4026928A (en) * | 1970-10-27 | 1977-05-31 | Arco Polymers, Inc. | Low molecular weight vinyl polymers and process for preparing |
US3870702A (en) * | 1971-03-19 | 1975-03-11 | Shinetsu Chemical Co | Cellulose ether compositions useful as enteric coatings |
US3933746A (en) * | 1973-06-14 | 1976-01-20 | Ball Corporation | Photopolymerizable polymers having anhydride-containing groups |
US4212704A (en) * | 1975-04-10 | 1980-07-15 | Grain Processing Corporation | Composition and production process for Fourdrinier fiberboard |
JPS549619A (en) * | 1977-06-23 | 1979-01-24 | Oji Paper Co | Photosensitive composition |
US4226981A (en) * | 1977-09-28 | 1980-10-07 | Shin-Etsu Chemical Co., Ltd. | Ether-ester derivatives of cellulose and their applications |
US4283553A (en) * | 1979-09-24 | 1981-08-11 | Ivanchev Sergei S | Hydroperoxide derivatives of hydroxyethylated compounds and method of producing same |
CA1278898C (en) * | 1985-10-28 | 1991-01-08 | Haruo Tanaka | Process for producing resin for paper coating |
US5238686A (en) * | 1986-03-27 | 1993-08-24 | Kinaform Technology, Inc. | Sustained-release pharmaceutical preparation |
JPH0790670B2 (en) * | 1987-02-04 | 1995-10-04 | 富士写真フイルム株式会社 | Plate surface protective agent for lithographic printing plates |
US5028655A (en) * | 1987-12-15 | 1991-07-02 | Union Oil Company Of California | Fast cure, zero formaldehyde binder for cellulose |
US4939200A (en) * | 1988-01-28 | 1990-07-03 | Union Oil Company Of California | Fast curing binder for cellulose |
US4820307A (en) * | 1988-06-16 | 1989-04-11 | The United States Of America As Represented By The Secretary Of Agriculture | Catalysts and processes for formaldehyde-free durable press finishing of cotton textiles with polycarboxylic acids |
IT1230576B (en) * | 1988-10-20 | 1991-10-28 | Angeli Inst Spa | ORAL PHARMACEUTICAL FORMULATIONS WITH SELECTIVE LIBERATION IN THE COLON |
US5104923A (en) * | 1989-03-31 | 1992-04-14 | Union Oil Company Of California | Binders for imparting high wet strength to nonwovens |
US5026559A (en) * | 1989-04-03 | 1991-06-25 | Kinaform Technology, Inc. | Sustained-release pharmaceutical preparation |
US4983401A (en) * | 1989-05-22 | 1991-01-08 | Kinaform Technology, Inc. | Sustained release pharmaceutical preparations having pH controlled membrane coatings |
US5102668A (en) * | 1990-10-05 | 1992-04-07 | Kingaform Technology, Inc. | Sustained release pharmaceutical preparation using diffusion barriers whose permeabilities change in response to changing pH |
-
1996
- 1996-03-28 US US08/624,764 patent/US5656746A/en not_active Expired - Fee Related
-
1997
- 1997-03-25 DE DE69703616T patent/DE69703616T2/en not_active Expired - Fee Related
- 1997-03-25 EP EP97916986A patent/EP0890000B1/en not_active Expired - Lifetime
- 1997-03-25 AT AT97916986T patent/ATE197827T1/en not_active IP Right Cessation
- 1997-03-25 JP JP53456597A patent/JP3233287B2/en not_active Expired - Fee Related
- 1997-03-25 AU AU25454/97A patent/AU2545497A/en not_active Abandoned
- 1997-03-25 KR KR1019980707719A patent/KR100282740B1/en not_active IP Right Cessation
- 1997-03-25 WO PCT/US1997/004833 patent/WO1997036051A2/en active IP Right Grant
- 1997-03-25 ZA ZA9702564A patent/ZA972564B/en unknown
- 1997-03-25 BR BR9708439A patent/BR9708439A/en not_active IP Right Cessation
- 1997-03-25 CA CA002250176A patent/CA2250176C/en not_active Expired - Fee Related
- 1997-03-25 ES ES97916986T patent/ES2152661T3/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0890000A1 (en) | 1999-01-13 |
ES2152661T3 (en) | 2001-02-01 |
CA2250176C (en) | 2005-10-25 |
US5656746A (en) | 1997-08-12 |
WO1997036051A2 (en) | 1997-10-02 |
KR100282740B1 (en) | 2001-02-15 |
DE69703616T2 (en) | 2001-05-17 |
ATE197827T1 (en) | 2000-12-15 |
DE69703616D1 (en) | 2001-01-04 |
BR9708439A (en) | 1999-08-03 |
EP0890000B1 (en) | 2000-11-29 |
ZA972564B (en) | 1997-10-17 |
JP3233287B2 (en) | 2001-11-26 |
JPH11507099A (en) | 1999-06-22 |
KR20000005089A (en) | 2000-01-25 |
AU2545497A (en) | 1997-10-17 |
WO1997036051A3 (en) | 1997-11-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |