CA2275624A1 - Nickel/ruthenium catalyst and method for aqueous phase reactions - Google Patents
Nickel/ruthenium catalyst and method for aqueous phase reactions Download PDFInfo
- Publication number
- CA2275624A1 CA2275624A1 CA002275624A CA2275624A CA2275624A1 CA 2275624 A1 CA2275624 A1 CA 2275624A1 CA 002275624 A CA002275624 A CA 002275624A CA 2275624 A CA2275624 A CA 2275624A CA 2275624 A1 CA2275624 A1 CA 2275624A1
- Authority
- CA
- Canada
- Prior art keywords
- nickel
- aqueous phase
- ruthenium catalyst
- phase reactions
- phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/892—Nickel and noble metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
- C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
- C01B2203/107—Platinum catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1088—Non-supported catalysts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C10J2300/0986—Catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
The present invention is a method of hydrogenation using a catalyst in the form of a plurality of porous particles wherein each particle is a support having nickel metal catalytic phase or reduced nickel deposited thereon in a first dispersed phase and an additional ruthenium metal deposited onto the support in a second dispersed phase. The additional ruthenium metal is effective in retarding or reducing agglomeration or sintering of the nickel metal catalytic phase thereby increasing the life time of the catalyst during hydrogenation reactions.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/775,337 | 1996-12-19 | ||
US08/775,337 US5814112A (en) | 1992-06-05 | 1996-12-19 | Nickel/ruthenium catalyst and method for aqueous phase reactions |
PCT/US1997/024176 WO1998026869A1 (en) | 1996-12-19 | 1997-12-18 | Nickel/ruthenium catalyst and method for aqueous phase reactions |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2275624A1 true CA2275624A1 (en) | 1998-06-25 |
CA2275624C CA2275624C (en) | 2004-05-11 |
Family
ID=25104089
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002275624A Expired - Lifetime CA2275624C (en) | 1996-12-19 | 1997-12-18 | Nickel/ruthenium catalyst and method for aqueous phase reactions |
Country Status (6)
Country | Link |
---|---|
US (1) | US5814112A (en) |
CN (1) | CN1246077A (en) |
AU (1) | AU727906B2 (en) |
BR (1) | BR9713764A (en) |
CA (1) | CA2275624C (en) |
WO (1) | WO1998026869A1 (en) |
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6376113B1 (en) | 1998-11-12 | 2002-04-23 | Idatech, Llc | Integrated fuel cell system |
US6783741B2 (en) | 1996-10-30 | 2004-08-31 | Idatech, Llc | Fuel processing system |
US6152995A (en) | 1999-03-22 | 2000-11-28 | Idatech Llc | Hydrogen-permeable metal membrane and method for producing the same |
US6221117B1 (en) | 1996-10-30 | 2001-04-24 | Idatech, Llc | Hydrogen producing fuel processing system |
US7195663B2 (en) | 1996-10-30 | 2007-03-27 | Idatech, Llc | Hydrogen purification membranes, components and fuel processing systems containing the same |
US6547858B1 (en) | 1999-03-22 | 2003-04-15 | Idatech, Llc | Hydrogen-permeable metal membrane and hydrogen purification assemblies containing the same |
US5997594A (en) * | 1996-10-30 | 1999-12-07 | Northwest Power Systems, Llc | Steam reformer with internal hydrogen purification |
US6537352B2 (en) | 1996-10-30 | 2003-03-25 | Idatech, Llc | Hydrogen purification membranes, components and fuel processing systems containing the same |
US5977013A (en) * | 1996-12-19 | 1999-11-02 | Battelle Memorial Institute | Catalyst and method for aqueous phase reactions |
AU742830B2 (en) * | 1997-11-27 | 2002-01-10 | Idemitsu Kosan Co. Ltd | Alumina-supported ruthenium catalyst |
KR101516812B1 (en) * | 1998-02-16 | 2015-04-30 | 스미또모 가가꾸 가부시끼가이샤 | Process for producing chlorine |
US6767389B2 (en) * | 1999-03-22 | 2004-07-27 | Idatech, Llc | Hydrogen-selective metal membranes, membrane modules, purification assemblies and methods of forming the same |
US6596057B2 (en) | 1999-03-22 | 2003-07-22 | Idatech, Llc | Hydrogen-selective metal membranes, membrane modules, purification assemblies and methods of forming the same |
US6841512B1 (en) * | 1999-04-12 | 2005-01-11 | Ovonic Battery Company, Inc. | Finely divided metal catalyst and method for making same |
US6570043B2 (en) | 1999-09-03 | 2003-05-27 | Battelle Memorial Institute | Converting sugars to sugar alcohols by aqueous phase catalytic hydrogenation |
US6235797B1 (en) * | 1999-09-03 | 2001-05-22 | Battelle Memorial Institute | Ruthenium on rutile catalyst, catalytic system, and method for aqueous phase hydrogenations |
US6900361B2 (en) | 2001-05-08 | 2005-05-31 | Battelle Memorial Institute | Process for lactose conversion to polyols |
US6699457B2 (en) * | 2001-11-29 | 2004-03-02 | Wisconsin Alumni Research Foundation | Low-temperature hydrogen production from oxygenated hydrocarbons |
CA2467443C (en) * | 2001-11-29 | 2012-01-10 | Wisconsin Alumni Research Foundation | Low-temperature hydrogen production from oxygenated hydrocarbons |
EP1465836A2 (en) | 2001-12-21 | 2004-10-13 | Battelle Memorial Institute | Structures containing carbon nanotubes and a porous support, methods of making the same, and related uses |
US6713519B2 (en) | 2001-12-21 | 2004-03-30 | Battelle Memorial Institute | Carbon nanotube-containing catalysts, methods of making, and reactions catalyzed over nanotube catalysts |
CN1310851C (en) * | 2002-05-10 | 2007-04-18 | 威斯康星旧生研究基金会 | Low-temperature hydrocarbon production from oxygenated hydrocarbons |
ATE527230T1 (en) | 2004-12-23 | 2011-10-15 | Shell Int Research | METHOD FOR HYDROGENING A LACTONE OR A CARBOXYLIC ACID OR AN ESTER HAVING A GAMMA CARBONYL GROUP |
CN1683293A (en) * | 2005-03-01 | 2005-10-19 | 大成多元醇投资有限公司 | Process for producing diatomic alcohol and polyol from cracking sorbierite |
CN101583424A (en) * | 2005-04-21 | 2009-11-18 | 国际壳牌研究有限公司 | Hydrogenation catalyst and hydrogenation method |
WO2007035467A2 (en) | 2005-09-16 | 2007-03-29 | Idatech, Llc | Self-regulating feedstock delivery systems and hydrogen-generating fuel processing assemblies and fuel cell systems incorporating the same |
US7601302B2 (en) | 2005-09-16 | 2009-10-13 | Idatech, Llc | Self-regulating feedstock delivery systems and hydrogen-generating fuel processing assemblies and fuel cell systems incorporating the same |
US20070135301A1 (en) * | 2005-12-08 | 2007-06-14 | Sud-Chemie Inc. | Catalyst for the production of polyols by hydrogenolysis of carbohydrates |
MX2008012951A (en) * | 2006-04-13 | 2008-10-15 | Shell Int Research | Process for hydrogenating an aldehyde. |
US7972420B2 (en) | 2006-05-22 | 2011-07-05 | Idatech, Llc | Hydrogen-processing assemblies and hydrogen-producing systems and fuel cell systems including the same |
US7939051B2 (en) | 2006-05-23 | 2011-05-10 | Idatech, Llc | Hydrogen-producing fuel processing assemblies, heating assemblies, and methods of operating the same |
WO2008122029A1 (en) * | 2007-04-02 | 2008-10-09 | Inventure Chemical, Inc. | Simultaneous esterification and alcohol ysis/hydrolysis of oil-containing materials with cellulosic and peptidic content |
US7943792B2 (en) * | 2007-04-02 | 2011-05-17 | Inventure Chemical Inc. | Production of biodiesel, cellulosic sugars, and peptides from the simultaneous esterification and alcoholysis/hydrolysis of materials with oil-containing substituents including phospholipids and peptidic content |
US8262752B2 (en) | 2007-12-17 | 2012-09-11 | Idatech, Llc | Systems and methods for reliable feedstock delivery at variable delivery rates |
AR072446A1 (en) * | 2008-03-02 | 2010-09-01 | Dow Global Technologies Inc | IMPROVED HYDROGENATION PROCESS |
GB0814784D0 (en) * | 2008-08-13 | 2008-09-17 | Johnson Matthey Plc | Chemical process |
US7777085B2 (en) * | 2008-10-01 | 2010-08-17 | Inventure Chemical, Inc. | Method for conversion of oil-containing algae to 1,3-propanediol |
ITMI20090481A1 (en) * | 2009-03-27 | 2010-09-28 | Mariacarla Branca | PROCEDURE FOR THE PRODUCTION OF A GAS CONTAINING METHANE FROM CARBONIAL MATERIALS |
AU2010250769A1 (en) * | 2009-05-20 | 2011-12-08 | Ramot At Tel-Aviv University Ltd. | Catalytic gasification of organic matter in supercritical water |
EP2462100A1 (en) | 2009-08-07 | 2012-06-13 | Shell Internationale Research Maatschappij B.V. | Process for hydrogenation |
US8580978B2 (en) | 2009-08-07 | 2013-11-12 | Shell Oil Company | Process for preparing a hydroxyacid or hydroxyester |
US9012680B2 (en) | 2009-08-07 | 2015-04-21 | Shell Oil Company | Process for preparing an ester |
AU2011229428B2 (en) * | 2010-03-19 | 2014-07-03 | Haldor Topsoe A/S | Reforming catalyst |
WO2012079179A1 (en) * | 2010-12-17 | 2012-06-21 | Lakehead University | Methods, systems and catalysts for supercritical water reforming feedstock into methane |
GB2508511B (en) * | 2012-11-30 | 2017-02-22 | Johnson Matthey Plc | Bimetallic catalyst |
CN105189470A (en) | 2013-03-15 | 2015-12-23 | 赛格提斯公司 | Method of manufacture of octanedioic acid, precursors, and derivatives |
WO2017103009A2 (en) * | 2015-12-17 | 2017-06-22 | Shell Internationale Research Maatschappij B.V. | Hydrogenation or hydrogenolysis of an oxygenate |
US10476093B2 (en) | 2016-04-15 | 2019-11-12 | Chung-Hsin Electric & Machinery Mfg. Corp. | Membrane modules for hydrogen separation and fuel processors and fuel cell systems including the same |
US11712655B2 (en) | 2020-11-30 | 2023-08-01 | H2 Powertech, Llc | Membrane-based hydrogen purifiers |
CN113275562A (en) * | 2021-05-21 | 2021-08-20 | 中国科学技术大学 | RuNi alloy nano composite material, preparation method and application thereof |
CN115646487B (en) * | 2022-10-12 | 2023-05-23 | 中国矿业大学 | High-activity Ru-M/alpha-Al 2 O 3 Catalyst, preparation method and application thereof |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL134685C (en) * | 1960-06-08 | |||
FR1573174A (en) * | 1968-04-10 | 1969-07-04 | ||
US3912787A (en) * | 1972-07-26 | 1975-10-14 | Phillips Petroleum Co | Selective partial hydrogenation of aromatics |
US4104201A (en) * | 1974-09-06 | 1978-08-01 | British Gas Corporation | Catalytic steam reforming and catalysts therefor |
US4146741A (en) * | 1977-08-15 | 1979-03-27 | E. I. Du Pont De Nemours And Company | Conversion of furan to 1,4-butanediol and tetrahydrofuran |
US4239499A (en) * | 1977-11-15 | 1980-12-16 | Engelhard Minerals And Chemicals Corporation | Production of a fuel gas and synthetic natural gas from methanol |
US4251394A (en) * | 1978-08-25 | 1981-02-17 | Exxon Research & Engineering Co. | Coprecipitated copper-nickel-silica catalysts, preparation and use thereof |
AU632476B2 (en) * | 1988-03-15 | 1993-01-07 | Battelle Memorial Institute | Method for catalytic destruction of organic materials |
DE4128834A1 (en) * | 1991-08-30 | 1993-03-04 | Zahnradfabrik Friedrichshafen | GEAR CHANGE GEARBOX WITH ONE CONTROL UNIT |
DE69320343T2 (en) * | 1992-06-05 | 1999-04-15 | Battelle Memorial Institute | Method for the catalytic conversion of organic materials into a product gas |
US5395813A (en) * | 1993-05-11 | 1995-03-07 | Exxon Research And Engineering Company | Particulate solids for catalyst supports and heat transfer materials |
-
1996
- 1996-12-19 US US08/775,337 patent/US5814112A/en not_active Expired - Lifetime
-
1997
- 1997-12-18 AU AU57273/98A patent/AU727906B2/en not_active Ceased
- 1997-12-18 CN CN97181764A patent/CN1246077A/en active Pending
- 1997-12-18 WO PCT/US1997/024176 patent/WO1998026869A1/en active IP Right Grant
- 1997-12-18 CA CA002275624A patent/CA2275624C/en not_active Expired - Lifetime
- 1997-12-18 BR BR9713764-2A patent/BR9713764A/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
CN1246077A (en) | 2000-03-01 |
US5814112A (en) | 1998-09-29 |
CA2275624C (en) | 2004-05-11 |
WO1998026869A1 (en) | 1998-06-25 |
AU727906B2 (en) | 2001-01-04 |
BR9713764A (en) | 2000-02-01 |
AU5727398A (en) | 1998-07-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKEX | Expiry |
Effective date: 20171218 |