CA2315029A1 - Hydrogen gas-extraction module - Google Patents

Hydrogen gas-extraction module Download PDF

Info

Publication number
CA2315029A1
CA2315029A1 CA002315029A CA2315029A CA2315029A1 CA 2315029 A1 CA2315029 A1 CA 2315029A1 CA 002315029 A CA002315029 A CA 002315029A CA 2315029 A CA2315029 A CA 2315029A CA 2315029 A1 CA2315029 A1 CA 2315029A1
Authority
CA
Canada
Prior art keywords
metal substrate
hydrogen
hydrogen gas
porous metal
intermediate layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002315029A
Other languages
French (fr)
Other versions
CA2315029C (en
Inventor
Yi Hua Ma
Peter P. Mardilovich
Ying She
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Worcester Polytechnic Institute
Original Assignee
Worcester Polytechnic Institute
Yi Hua Ma
Peter P. Mardilovich
Ying She
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Worcester Polytechnic Institute, Yi Hua Ma, Peter P. Mardilovich, Ying She filed Critical Worcester Polytechnic Institute
Publication of CA2315029A1 publication Critical patent/CA2315029A1/en
Application granted granted Critical
Publication of CA2315029C publication Critical patent/CA2315029C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/1216—Three or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0069—Inorganic membrane manufacture by deposition from the liquid phase, e.g. electrochemical deposition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0072—Inorganic membrane manufacture by deposition from the gaseous phase, e.g. sputtering, CVD, PVD
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/108—Inorganic support material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B01D71/0223—Group 8, 9 or 10 metals
    • B01D71/02231—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
    • C01B3/505—Membranes containing palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/08—Specific temperatures applied
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/08—Specific temperatures applied
    • B01D2323/081—Heating
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C01B2203/041—In-situ membrane purification during hydrogen production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/047—Composition of the impurity the impurity being carbon monoxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S55/00—Gas separation
    • Y10S55/05—Methods of making filter

Abstract

A hydrogen gas-extraction module includes an intermediate layer bonded between a porous metal substrate and a membrane layer that is selectively permeable to hydrogen. The metal substrate includes a substantial concentration of a first metal at a surface of the metal substrate, and the intermediate layer includes an oxide of this first metal.
In one embodiment, where the module is designed to selectively extract hydrogen at high temperatures, the porous metal substrate comprises stainless steel, and the membrane layer includes palladium or a palladium/silver alloy. A method for fabricating a hydrogen gas-extraction membrane includes reacting the porous metal substrate with an oxidizing agent to form a ceramic intermediate layer on a surface of the porous metal substrate and covering the ceramic coating with the membrane layer that is selectively permeable to hydrogen.
CA002315029A 1997-12-15 1998-12-11 Hydrogen gas-extraction module Expired - Fee Related CA2315029C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US99101797A 1997-12-15 1997-12-15
US08/991,017 1997-12-15
US09/139,218 US6152987A (en) 1997-12-15 1998-08-24 Hydrogen gas-extraction module and method of fabrication
US09/139,218 1998-08-24
PCT/US1998/026466 WO1999030806A1 (en) 1997-12-15 1998-12-11 Hydrogen gas-extraction module

Publications (2)

Publication Number Publication Date
CA2315029A1 true CA2315029A1 (en) 1999-06-24
CA2315029C CA2315029C (en) 2008-12-09

Family

ID=26836991

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002315029A Expired - Fee Related CA2315029C (en) 1997-12-15 1998-12-11 Hydrogen gas-extraction module

Country Status (8)

Country Link
US (1) US6152987A (en)
EP (1) EP1042049B1 (en)
AT (1) ATE234661T1 (en)
AU (1) AU1725199A (en)
CA (1) CA2315029C (en)
DE (1) DE69812416T2 (en)
ES (1) ES2195429T3 (en)
WO (1) WO1999030806A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8366805B2 (en) 2007-04-05 2013-02-05 Worcester Polytechnic Institute Composite structures with porous anodic oxide layers and methods of fabrication
US8652239B2 (en) 2010-05-03 2014-02-18 Worcester Polytechnic Institute High permeance sulfur tolerant Pd/Cu alloy membranes

Families Citing this family (123)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6319306B1 (en) 2000-03-23 2001-11-20 Idatech, Llc Hydrogen-selective metal membrane modules and method of forming the same
US7195663B2 (en) 1996-10-30 2007-03-27 Idatech, Llc Hydrogen purification membranes, components and fuel processing systems containing the same
US6221117B1 (en) 1996-10-30 2001-04-24 Idatech, Llc Hydrogen producing fuel processing system
US6547858B1 (en) 1999-03-22 2003-04-15 Idatech, Llc Hydrogen-permeable metal membrane and hydrogen purification assemblies containing the same
US6152995A (en) * 1999-03-22 2000-11-28 Idatech Llc Hydrogen-permeable metal membrane and method for producing the same
CH694150A5 (en) * 1998-11-10 2004-08-13 Ati Properties Inc A Delaware Hydrogen separation membrane.
US6602325B1 (en) 1999-10-21 2003-08-05 Ati Properties, Inc. Fluid separation assembly
DE19936548B4 (en) * 1999-08-03 2004-03-04 Alstom Power Energy Recovery Gmbh Process and plant for the thermal cracking of hydrocarbons, in particular for the production of olefins
US6315820B1 (en) * 1999-10-19 2001-11-13 Ford Global Technologies, Inc. Method of manufacturing thin metal alloy foils
US6715546B2 (en) 2000-04-24 2004-04-06 Shell Oil Company In situ production of synthesis gas from a hydrocarbon containing formation through a heat source wellbore
NZ522206A (en) 2000-04-24 2004-05-28 Shell Int Research Method for the production of hydrocarbons and synthesis gas from a hydrocarbon - containing formation
US6698515B2 (en) 2000-04-24 2004-03-02 Shell Oil Company In situ thermal processing of a coal formation using a relatively slow heating rate
US6715548B2 (en) 2000-04-24 2004-04-06 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce nitrogen containing formation fluids
US6588504B2 (en) 2000-04-24 2003-07-08 Shell Oil Company In situ thermal processing of a coal formation to produce nitrogen and/or sulfur containing formation fluids
DE10039596C2 (en) * 2000-08-12 2003-03-27 Omg Ag & Co Kg Supported metal membrane, process for its manufacture and use
JP3882567B2 (en) * 2000-11-24 2007-02-21 住友電気工業株式会社 Material separation structure
US6475268B2 (en) * 2000-12-22 2002-11-05 Ford Global Technologies, Inc. Supported membrane for hydrogen separation
FR2820988B1 (en) * 2001-02-19 2003-04-25 Cie D Etudes Des Technologies COMPOSITE STRUCTURES OF SELECTIVELY HYDROGEN PERMEABLE MEMBRANES AND COMBUSTIBLE GAS PROCESSORS USING THE SAME
US7867300B2 (en) 2001-03-02 2011-01-11 Intelligent Energy, Inc. Ammonia-based hydrogen generation apparatus and method for using same
CA2439586C (en) 2001-03-02 2012-02-28 Mesosystems Technology, Inc. Ammonia-based hydrogen generation apparatus and method for using same
US7922781B2 (en) 2001-03-02 2011-04-12 Chellappa Anand S Hydrogen generation apparatus and method for using same
US6913736B2 (en) * 2001-03-30 2005-07-05 Siemens Westinghouse Power Corporation Metal gas separation membrane module design
US6991032B2 (en) 2001-04-24 2006-01-31 Shell Oil Company In situ thermal processing of an oil shale formation using a pattern of heat sources
US6888014B2 (en) * 2001-07-24 2005-05-03 Panagin Pharmaceuticals Inc. Dammarane sapogenins, their use as anti-cancer agents, and a process for producing same
DE10135390A1 (en) * 2001-07-25 2003-02-20 Fraunhofer Ges Forschung Metallic solution-diffusion membrane, used for separating and purifying hydrogen for use in the electronics, metals and chemical industry, consists of a macroporous base body with a thin metallic membrane layer
WO2003036039A1 (en) 2001-10-24 2003-05-01 Shell Internationale Research Maatschappij B.V. In situ production of a blending agent from a hydrocarbon containing formation
US20050241477A1 (en) * 2002-03-05 2005-11-03 Mundschau Michael V Hydrogen transport membranes
US7001446B2 (en) * 2002-03-05 2006-02-21 Eltron Research, Inc. Dense, layered membranes for hydrogen separation
AU2003220048A1 (en) * 2002-03-05 2003-09-22 Eltron Research, Inc. Hydrogen transport membranes
US8101243B2 (en) * 2002-04-03 2012-01-24 Colorado School Of Mines Method of making sulfur-resistant composite metal membranes
WO2003084628A2 (en) * 2002-04-03 2003-10-16 Colorado School Of Mines Process for preparing palladium alloy composite membranes for use in hydrogen separation, palladium alloy composite membranes and products incorporating or made from the membranes
US7527661B2 (en) 2005-04-18 2009-05-05 Intelligent Energy, Inc. Compact devices for generating pure hydrogen
US8172913B2 (en) 2002-04-23 2012-05-08 Vencill Thomas R Array of planar membrane modules for producing hydrogen
WO2003101629A1 (en) 2002-05-29 2003-12-11 The Board Of Trustees Of The Leland Stanford Junior University Sub-micron electrolyte thin film on nano-porous substrate by oxidation of metal film
EP1534627A2 (en) * 2002-09-05 2005-06-01 Shell Internationale Researchmaatschappij B.V. Apparatus and process for production of high purity hydrogen
US7201782B2 (en) 2002-09-16 2007-04-10 Hewlett-Packard Development Company, L.P. Gas generation system
US7341609B2 (en) * 2002-10-03 2008-03-11 Genesis Fueltech, Inc. Reforming and hydrogen purification system
EP1556580A1 (en) 2002-10-24 2005-07-27 Shell Internationale Researchmaatschappij B.V. Temperature limited heaters for heating subsurface formations or wellbores
US7175694B2 (en) * 2003-03-21 2007-02-13 Worcester Polytechnic Institute Composite gas separation modules having intermediate porous metal layers
CA2519774A1 (en) * 2003-03-21 2004-10-07 Worcester Polytechnic Institute Method for fabricating composite gas separation modules
CA2519766A1 (en) * 2003-03-21 2004-10-07 Worcester Polytechnic Institute Method for curing defects in the fabrication of a composite gas separation module
US7560170B2 (en) * 2003-04-04 2009-07-14 Intelligent Energy, Inc. Surface modification of porous metal substrates using cold spray
US7077889B2 (en) * 2003-04-04 2006-07-18 Intelligent Engery, Inc. Surface modification of porous metal substrates
US7121342B2 (en) 2003-04-24 2006-10-17 Shell Oil Company Thermal processes for subsurface formations
CA2524369A1 (en) * 2003-05-02 2004-11-18 Worcester Polytechnic Institute Composite gas separation modules having high tamman temperature intermediate layers
US7125440B2 (en) * 2003-06-04 2006-10-24 Bossard Peter R Composite structure for high efficiency hydrogen separation and its associated methods of manufacture and use
US7749305B1 (en) 2003-06-04 2010-07-06 Bossard Peter R Composite structure for high efficiency hydrogen separation containing preformed nano-particles in a bonded layer
US8075958B2 (en) * 2003-07-29 2011-12-13 Intelligent Energy, Inc. Methods for providing thin hydrogen separation membranes and associated uses
US7022165B2 (en) * 2003-08-29 2006-04-04 The Regents Of The University Of California Tubular hydrogen permeable metal foil membrane and method of fabrication
US7018446B2 (en) * 2003-09-24 2006-03-28 Siemens Westinghouse Power Corporation Metal gas separation membrane
TWI232888B (en) * 2003-11-25 2005-05-21 Min-Hung Lei Method for producing supported palladium membrane for purification of high purity hydrogen
CN1628898B (en) * 2003-12-19 2012-08-29 雷敏宏 Preparation method of support type palladium film used for high purity hydrogen purification
US7252692B2 (en) * 2004-01-21 2007-08-07 Min-Hon Rei Process and reactor module for quick start hydrogen production
US8002875B1 (en) 2004-02-02 2011-08-23 Bossard Peter R System and method for separating hydrogen gas from a mixed gas source using composite structure tubes
WO2005075060A1 (en) * 2004-02-02 2005-08-18 Bossard Peter R Composite structure for high efficiency hydrogen separation and its associated methods of manufacture and use
US7490665B2 (en) 2004-04-23 2009-02-17 Shell Oil Company Variable frequency temperature limited heaters
US7727596B2 (en) * 2004-07-21 2010-06-01 Worcester Polytechnic Institute Method for fabricating a composite gas separation module
US7297183B2 (en) 2004-09-20 2007-11-20 Idatech, Llc Hydrogen purification devices, components, and fuel processing systems containing the same
EP1789172A1 (en) * 2004-09-21 2007-05-30 Worcester Polytechnic Institute Membrane enhanced reactor
AU2005286952B2 (en) * 2004-09-21 2009-06-11 Worcester Polytechnic Institute Membrane steam reformer
JP2008513339A (en) * 2004-09-21 2008-05-01 ウスター ポリテクニック インスティチュート Reactor and method for steam reforming
RU2305587C2 (en) * 2004-10-25 2007-09-10 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" (ООО "ЮРД-Центр") Composite oxygen-conducting diaphragm
US7546873B2 (en) 2005-04-22 2009-06-16 Shell Oil Company Low temperature barriers for use with in situ processes
JP2007000858A (en) * 2005-05-23 2007-01-11 Kobe Steel Ltd Hydrogen permeation member and its manufacturing method
US7611565B1 (en) * 2005-10-20 2009-11-03 Los Alamos National Security, Llc Device for hydrogen separation and method
NZ567657A (en) 2005-10-24 2012-04-27 Shell Int Research Methods of hydrotreating a liquid stream to remove clogging compounds
US20090000480A1 (en) * 2005-12-23 2009-01-01 Zissis Dardas Composite Palladium Membrane Having Long-Term Stability for Hydrogen Separation
US7947116B2 (en) * 2006-02-06 2011-05-24 Eltron Research & Development, Inc. Hydrogen separation process
RU2455381C2 (en) 2006-04-21 2012-07-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. High-strength alloys
IL175270A0 (en) * 2006-04-26 2006-09-05 Acktar Ltd Composite inorganic membrane for separation in fluid systems
WO2008041968A2 (en) * 2006-09-28 2008-04-10 Utc Power Corporation Pd membrane having improved h2-permeance, and method of making
EP2074284A4 (en) 2006-10-20 2017-03-15 Shell Internationale Research Maatschappij B.V. Heating hydrocarbon containing formations in a line drive staged process
TW200846282A (en) 2006-11-30 2008-12-01 Shell Int Research Systems and processes for producing hydrogen and carbon dioxide
EP2125166B1 (en) * 2007-02-20 2014-06-25 Shell Internationale Research Maatschappij B.V. A method of reconditioning a gas separation membrane
JP4975494B2 (en) * 2007-03-23 2012-07-11 富士通株式会社 Imaging device
CN101285203B (en) 2007-04-13 2011-04-20 碧氢科技开发股份有限公司 Pd-containing plating solution and uses thereof
AU2008242799B2 (en) 2007-04-20 2012-01-19 Shell Internationale Research Maatschappij B.V. Parallel heater system for subsurface formations
US8133302B2 (en) * 2007-06-14 2012-03-13 Exxonmobil Upstream Research Company Process for purification of hydrocarbons
US9044715B2 (en) * 2007-08-22 2015-06-02 Colorado School Of Mines Unsupported palladium alloy membranes and methods of making same
KR20100087717A (en) 2007-10-19 2010-08-05 쉘 인터내셔날 리써취 마트샤피지 비.브이. Irregular spacing of heat sources for treating hydrocarbon containing formations
CA2711362A1 (en) * 2008-01-16 2009-07-23 Shell Internationale Research Maatschappij B.V. A system and process for making hydrogen from a hydrocarbon stream
US20090260823A1 (en) 2008-04-18 2009-10-22 Robert George Prince-Wright Mines and tunnels for use in treating subsurface hydrocarbon containing formations
US20090277331A1 (en) * 2008-05-09 2009-11-12 Membrane Reactor Technologies Ltd. Hydrogen separation composite membrane module and the method of production thereof
EP2282970A1 (en) * 2008-05-15 2011-02-16 Shell Internationale Research Maatschappij B.V. Method for recovering a natural gas contaminated with high levels of co2
US8881806B2 (en) 2008-10-13 2014-11-11 Shell Oil Company Systems and methods for treating a subsurface formation with electrical conductors
EP2228120A1 (en) 2009-03-09 2010-09-15 Shell Internationale Research Maatschappij B.V. Operation of more than one furnace
US8448707B2 (en) 2009-04-10 2013-05-28 Shell Oil Company Non-conducting heater casings
US7901854B2 (en) * 2009-05-08 2011-03-08 Taiwan Semiconductor Manufacturing Co., Ltd. Wafer edge exposure unit
US8632922B2 (en) * 2009-06-16 2014-01-21 Shell Oil Company Systems and processes for operating fuel cell systems
US8563186B2 (en) * 2009-06-16 2013-10-22 Shell Oil Company Systems and processes of operating fuel cell systems
US8795912B2 (en) * 2009-06-16 2014-08-05 Shell Oil Company Systems and processes for operating fuel cell systems
AU2010291148B2 (en) 2009-09-04 2014-05-08 Shell Internationale Research Maatschappij B.V. Process to prepare a diluted hydrogen gas mixture
US8900344B2 (en) 2010-03-22 2014-12-02 T3 Scientific Llc Hydrogen selective protective coating, coated article and method
US8518151B2 (en) 2010-03-24 2013-08-27 L'Air Liquide Societe Anonyme pour l'Etude el l'Exploitation des Procedes Georges Claude Porous hollow fiber supported dense membrane for hydrogen production, separation, or purification
JP5882295B2 (en) * 2010-03-26 2016-03-09 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー Method and apparatus for forming a supported gas separation membrane
US9127523B2 (en) 2010-04-09 2015-09-08 Shell Oil Company Barrier methods for use in subsurface hydrocarbon formations
US8875788B2 (en) 2010-04-09 2014-11-04 Shell Oil Company Low temperature inductive heating of subsurface formations
US8631866B2 (en) 2010-04-09 2014-01-21 Shell Oil Company Leak detection in circulated fluid systems for heating subsurface formations
US8701769B2 (en) 2010-04-09 2014-04-22 Shell Oil Company Methods for treating hydrocarbon formations based on geology
US8778058B2 (en) 2010-07-16 2014-07-15 Colorado School Of Mines Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same
WO2012030212A1 (en) * 2010-08-30 2012-03-08 Stichting Energieonderzoek Centrum Nederland New seeding method for deposit of thin selective membrane layers
CN101983757B (en) * 2010-12-06 2012-12-19 西北有色金属研究院 Palladium composite membrane taking multihole FeAlCr as substrate and preparation method thereof
NL2006245C2 (en) 2011-02-18 2012-08-21 Stichting Energie MEMBRANE REACTOR AND PROCESS FOR THE PRODUCTION OF A GASEOUS PRODUCT WITH SUCH REACTOR.
US9016370B2 (en) 2011-04-08 2015-04-28 Shell Oil Company Partial solution mining of hydrocarbon containing layers prior to in situ heat treatment
CA2850741A1 (en) 2011-10-07 2013-04-11 Manuel Alberto GONZALEZ Thermal expansion accommodation for circulated fluid systems used to heat subsurface formations
TWI442966B (en) * 2011-12-16 2014-07-01 Ind Tech Res Inst Methods of fabricating porous media and inorganic selective film
CN103998119B (en) * 2011-12-20 2016-10-19 国际壳牌研究有限公司 The method manufacturing composition metal gas separation membrane
EP2794079A1 (en) * 2011-12-20 2014-10-29 Shell Internationale Research Maatschappij B.V. A method of preparing a palladium- silver alloy gas separation membrane using mechanical surface activation
WO2013112133A1 (en) 2012-01-23 2013-08-01 Genie Ip B.V. Heater pattern for in situ thermal processing of a subsurface hydrocarbon containing formation
US9605524B2 (en) 2012-01-23 2017-03-28 Genie Ip B.V. Heater pattern for in situ thermal processing of a subsurface hydrocarbon containing formation
JP2014097443A (en) * 2012-11-13 2014-05-29 Tomyeng Corp Hydrogen separation membrane, hydrogen separator, and organic hydride system
KR101475679B1 (en) * 2012-12-14 2014-12-23 한국에너지기술연구원 Hydrogen membrane module for carbon dioxide capture
KR20150018923A (en) * 2013-08-09 2015-02-25 삼성전자주식회사 Separation membrane, hydrogen separation membrane including separation membrane and device including hydrogen separation membrane
US9732422B2 (en) 2015-01-23 2017-08-15 United Technologies Corporation Method of coating metallic powder particles
EP3271048A4 (en) * 2015-03-18 2018-12-05 Shell International Research Maatschappij B.V. Method of making a gold on palladium gas separation membrane
US10159969B2 (en) * 2015-03-31 2018-12-25 Colorado School Of Mines Ammonia synthesis at moderate conditions using hydrogen permeable membrane reactors
US10476093B2 (en) 2016-04-15 2019-11-12 Chung-Hsin Electric & Machinery Mfg. Corp. Membrane modules for hydrogen separation and fuel processors and fuel cell systems including the same
CA2946264A1 (en) 2016-10-25 2018-04-25 Nova Chemicals Corporation Use of semipermeable membranes in cracking coils
AT15581U1 (en) * 2016-12-09 2018-03-15 Plansee Se membrane tube
KR102578522B1 (en) * 2017-06-30 2023-09-15 커먼웰쓰 사이언티픽 앤드 인더스트리얼 리서치 오가니제이션 Methods for bonding and sealing vanadium-based membranes to metal connection sections
WO2021048351A2 (en) 2019-09-11 2021-03-18 Michiel Cramwinckel Process to convert a waste polymer product to a gaseous product
US11712655B2 (en) 2020-11-30 2023-08-01 H2 Powertech, Llc Membrane-based hydrogen purifiers
GB2602332B (en) * 2020-12-23 2023-08-30 Hydrogen Mem Tech As Membrane attachment technique

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2958391A (en) * 1958-02-24 1960-11-01 Universal Oil Prod Co Purification of hydrogen utilizing hydrogen-permeable membranes
US3241298A (en) * 1962-11-26 1966-03-22 Union Carbide Corp Method for making a fine porosity filter element
US3413777A (en) * 1965-06-22 1968-12-03 Engelhard Min & Chem Hydrogen diffusion and method for producing same
US3428476A (en) * 1965-06-22 1969-02-18 Engelhard Min & Chem Method for producing hydrogen diffusion cells
DE3273613D1 (en) * 1981-12-11 1986-11-13 Kernforschungsanlage Juelich Hydrogen diffusion membrane and process for separating hydrogen from gas mixtures by diffusion
SU1058587A1 (en) * 1982-07-12 1983-12-07 Всесоюзный Ордена Трудового Красного Знамени Научно-Исследовательский Проектно-Конструкторский И Технологический Институт Источников Тока Method of producing membrane elements
DE3332345C2 (en) * 1983-09-08 1986-08-07 Doduco KG Dr. Eugen Dürrwächter, 7530 Pforzheim Filter material made of metal mesh
DE3332346A1 (en) * 1983-09-08 1985-04-04 Kernforschungsanlage Jülich GmbH, 5170 Jülich HYDROGEN PERMEATION WALL, METHOD FOR PRODUCING THE SAME AND THE USE THEREOF
JPS61138516A (en) * 1984-12-10 1986-06-26 Matsushita Electric Ind Co Ltd Permselective compound membrane for gas
US4902307A (en) * 1988-11-18 1990-02-20 California Institute Of Technology Synthesis of SiO2 membrane on porous support and method of use of same
JPH0317026A (en) * 1989-06-13 1991-01-25 Agency Of Ind Science & Technol Dehydrogenation
US5049167A (en) * 1989-12-13 1991-09-17 Membrane Technology & Research, Inc. Multilayer interfacial composite membrane
US5139541A (en) * 1990-08-10 1992-08-18 Bend Research, Inc. Hydrogen-permeable composite metal membrane
CA2048849A1 (en) * 1990-08-10 1992-02-11 David J. Edlund Thermally stable composite hydrogen-permeable metal membranes
US5217506A (en) * 1990-08-10 1993-06-08 Bend Research, Inc. Hydrogen-permeable composite metal membrane and uses thereof
US5498278A (en) * 1990-08-10 1996-03-12 Bend Research, Inc. Composite hydrogen separation element and module
US5393325A (en) * 1990-08-10 1995-02-28 Bend Research, Inc. Composite hydrogen separation metal membrane
JP3045329B2 (en) * 1991-04-25 2000-05-29 三菱化工機株式会社 Method for producing hydrogen separation membrane
JP2960998B2 (en) * 1991-09-25 1999-10-12 三菱重工業株式会社 Hydrogen gas separation membrane
US5258339A (en) * 1992-03-12 1993-11-02 Worcester Polytechnic Institute Formation of zeolite membranes from sols
US5205841A (en) * 1992-04-03 1993-04-27 Tpc Technologies, Inc. Apparatus and method for extracting hydrogen
JP3402515B2 (en) * 1994-05-23 2003-05-06 日本碍子株式会社 Hydrogen separator, hydrogen separator using the same, and method for producing hydrogen separator
US5738708A (en) * 1995-06-07 1998-04-14 The Regents Of The University Of California Office Of Technology Transfer Composite metal membrane

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8366805B2 (en) 2007-04-05 2013-02-05 Worcester Polytechnic Institute Composite structures with porous anodic oxide layers and methods of fabrication
US8652239B2 (en) 2010-05-03 2014-02-18 Worcester Polytechnic Institute High permeance sulfur tolerant Pd/Cu alloy membranes

Also Published As

Publication number Publication date
AU1725199A (en) 1999-07-05
ES2195429T3 (en) 2003-12-01
WO1999030806A1 (en) 1999-06-24
ATE234661T1 (en) 2003-04-15
EP1042049B1 (en) 2003-03-19
CA2315029C (en) 2008-12-09
US6152987A (en) 2000-11-28
DE69812416D1 (en) 2003-04-24
EP1042049A1 (en) 2000-10-11
DE69812416T2 (en) 2004-01-08

Similar Documents

Publication Publication Date Title
CA2315029A1 (en) Hydrogen gas-extraction module
EP0290331A3 (en) Superconducting composite
TW333711B (en) Fabrication process of semiconductor substrate
EP0757377A3 (en) Semiconductor substrate and fabrication method for the same
EP0872880A3 (en) Method for forming a platinum group metal layer for a capacitor
ES2156655A1 (en) Metal coated substrates
ZA200402096B (en) Planar ceramic membrane assembly and oxidation reactor system
CA2318161A1 (en) Microfabricated aperture-based sensor
EP1394884A3 (en) Electrolyte membrane for fuel cell operable in medium temperature range, fuel cell using the same, and manufacturing methods therefor
NO961739L (en) Method of making thin metal membranes
WO2002066144A3 (en) Composite structures of membranes that are selectively permeable to hydrogen and combustible gas processors using same
MY115115A (en) Method of manufacturing semiconductor article
WO2003038924A3 (en) Fuel cell using variable porosity gas diffusion material and method of operation
WO2003021067A3 (en) Masking glass
EP1736241A4 (en) Exhaust gas-purifying catalyst
ATE214355T1 (en) HEAVY DUTY THERMAL, HEAT-REFLECTING COVERING
AU1290102A (en) Gas diffusion electrode
WO2000038238A8 (en) Reduced diffusion of a mobile ion from a metal oxide ceramic into the substrate
EP1947685A3 (en) Semiconductor device having fluorine-added carbon dielectric film and method of fabricating the same
WO2003012172A3 (en) Method and device for producing a textured metal strip
TW338186B (en) Lead frame and manufacturing method therefor
TW338729B (en) Hot roll stainless steel tape and the manufacturing method
EP0341964A3 (en) Silicon micro sensor and manufacturing method therefor
AU2001293014A1 (en) Filter element with porous nickel-based alloy substrate and metal oxide membrane
AU1461595A (en) Method of making a catalyst

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed