CA2354566A1 - Compositions comprenant du 1,1,1,3,3-pentafluorobutane et utilisation de ces compositions - Google Patents

Compositions comprenant du 1,1,1,3,3-pentafluorobutane et utilisation de ces compositions Download PDF

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Publication number
CA2354566A1
CA2354566A1 CA002354566A CA2354566A CA2354566A1 CA 2354566 A1 CA2354566 A1 CA 2354566A1 CA 002354566 A CA002354566 A CA 002354566A CA 2354566 A CA2354566 A CA 2354566A CA 2354566 A1 CA2354566 A1 CA 2354566A1
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Prior art keywords
compositions according
pentafluorobutane
azeotropic
weight
solvent
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Granted
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CA002354566A
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CA2354566C (fr
Inventor
Pierre Dournel
Pierre Barthelemy
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Solvay SA
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Solvay (Societe Anonyme)
Pierre Dournel
Pierre Barthelemy
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Priority claimed from PCT/EP1998/008160 external-priority patent/WO1999031214A1/fr
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Publication of CA2354566A1 publication Critical patent/CA2354566A1/fr
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/261Alcohols; Phenols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02Materials undergoing a change of physical state when used
    • C09K5/04Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C09K5/045Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50Solvents
    • C11D7/5004Organic solvents
    • C11D7/5013Organic solvents containing nitrogen
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50Solvents
    • C11D7/5004Organic solvents
    • C11D7/5018Halogenated solvents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50Solvents
    • C11D7/5036Azeotropic mixtures containing halogenated solvents
    • C11D7/504Azeotropic mixtures containing halogenated solvents all solvents being halogenated hydrocarbons
    • C11D7/5054Mixtures of (hydro)chlorofluorocarbons and (hydro) fluorocarbons
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50Solvents
    • C11D7/5036Azeotropic mixtures containing halogenated solvents
    • C11D7/504Azeotropic mixtures containing halogenated solvents all solvents being halogenated hydrocarbons
    • C11D7/5063Halogenated hydrocarbons containing heteroatoms, e.g. fluoro alcohols
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50Solvents
    • C11D7/5036Azeotropic mixtures containing halogenated solvents
    • C11D7/5068Mixtures of halogenated and non-halogenated solvents
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • C23G5/02Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
    • C23G5/028Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons
    • C23G5/02803Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons containing fluorine
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G11/00Selection of substances for use as fixing agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/102Alcohols
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/104Carboxylic acid esters
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/108Aldehydes or ketones
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/11Ethers
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/11Ethers
    • C09K2205/112Halogenated ethers
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/12Hydrocarbons
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/12Hydrocarbons
    • C09K2205/128Perfluorinated hydrocarbons
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    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/132Components containing nitrogen
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    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/22All components of a mixture being fluoro compounds
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    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/32The mixture being azeotropic
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    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/40Replacement mixtures
    • C09K2205/41Type R11
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/24Hydrocarbons
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/263Ethers
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/264Aldehydes; Ketones; Acetals or ketals
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    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/266Esters or carbonates
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    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/28Organic compounds containing halogen
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    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3281Heterocyclic compounds

Abstract

Compositions comprenant du 1,1,1,3,3-pentafluorobutane et plus de 5% en poids d'au moins un composé fluoré ininflammable et leur utilisation.

Claims (11)

1 - Compositions comprenant du 1,1,1,3,3-pentafluorobutane et plus de 5 % en poids d'au moins un composé fluoré ininflammable qui ne présente pas de point d'éclair déterminé selon la norme ISO 1523 sélectionné parmi les hydrofluorocarbures comprenant au moins 5 atomes de carbone, les perfluorocarbures, les amines fluorées et les éthers fluorés.
2 - Compositions selon la revendication 1 comprenant en outre au moins un solvant organique non fluoré.
3 - Compositions selon la revendication 2 dans lesquelles le solvant organique non fluoré est sélectionné parmi les hydrocarbures, les hydrocarbures halogénés, les esters ou cétones aliphatiques, alicycliques ou aromatiques, les alcools ou les éthers.
4 - Compositions selon la revendication 2 ou 3, dans lesquelles le solvant organique non fluoré est l'acétate d'éthyle, le 1,2-dichloréthylène, le méthanol, l'éthanol, l'isopropanol ou l'isobutanol.
5 - Compositions selon l'une quelconque des revendications 2 à 4 comprenant du 1,1,1,3,3 pentafluorobutane et un solvant organique non fluoré
dans des proportions dans lesquelles ils forment un azéotrope ou un pseudo-azéotrope.
6 - Compositions selon l'une quelconque des revendications 1 à 5 comprenant un néant tensioactif, de préférence de type imidazoline ou alkylbenzénesulfonate.
7 - Compositions selon l'une quelconque des revendications 1 à 6 dans lesquelles le compost fluoré ininflammable est le 2,3-dihydrodécafluoropentane (HFC-43-10mee), la perfluorotriéthylamine, le perfluorobutyl-méthyléther, le perfluoropentane ou le perfluorohexane.
8 - Compositions selon l'une quelconque des revendications 1 à 7 comprenant du 1,1,1,3,3-pentafluorobutane et au moins un perfluorocarbure dans des proportions dans lesquelles ils forment un azéotrope ou un pseudo-azéotrope.
9 - Composition selon la revendication 8 comprenant un mélange azéotropique ou pseudo-azéotropique, constitué essentiellement de 40 à 80 % en poids de 1,1,1,3,3-pentafluorobutane et de 20 à 60 % en poids de perfluorohexane ou comprenant un mélange azéotropique ou pseudo-azéotropique constitué essentiellement de 13 à 50 % en poids de 1,1,1,3,3-pentafluorobutane et de 50 à 87 % en poids de perfluoropentane
10 - Utilisation des compositions selon l'une quelconque des revendications 1 à 9, dans des applications solvant, agent de séchage, solvant de dégraissage, agent de fixation de toners, réfrigérant ou fluide caloporteur.
11 - Utilisation selon la revendication 10 comme produit de remplacement du CFC-11 (trichlorofluorométhane) ou comme produit de remplacement du CFC-113 (1,1,2-trichlorotrifluoroéthane).
CA2354566A 1998-12-12 1999-12-10 Compositions comprenant du 1,1,1,3,3-pentafluorobutane et utilisation de ces compositions Expired - Fee Related CA2354566C (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
PCT/EP1998/008160 WO1999031214A1 (fr) 1997-12-15 1998-12-12 Compositions comprenant du perfluorobutyl methyl ether et utilisation de ces compositions
EPPCT/EP98/08160 1998-12-12
EP99200762 1999-03-12
EP99200762.5 1999-03-12
PCT/EP1999/009798 WO2000036046A1 (fr) 1998-12-12 1999-12-10 Compositions comprenant du 1,1,1,3,3-pentafluorobutane et utilisation de ces compositions

Publications (2)

Publication Number Publication Date
CA2354566A1 true CA2354566A1 (fr) 2000-06-22
CA2354566C CA2354566C (fr) 2010-04-27

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CA2354566A Expired - Fee Related CA2354566C (fr) 1998-12-12 1999-12-10 Compositions comprenant du 1,1,1,3,3-pentafluorobutane et utilisation de ces compositions

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US (5) US6660709B1 (fr)
EP (1) EP1141166B1 (fr)
JP (1) JP4298924B2 (fr)
KR (1) KR100637261B1 (fr)
CN (1) CN1191319C (fr)
AT (1) ATE273361T1 (fr)
AU (1) AU769440B2 (fr)
BR (1) BR9916132B1 (fr)
CA (1) CA2354566C (fr)
CZ (1) CZ301391B6 (fr)
DE (1) DE69919398T2 (fr)
ES (1) ES2228135T3 (fr)
HK (1) HK1044349B (fr)
HU (1) HUP0104496A3 (fr)
IL (2) IL143673A0 (fr)
MX (1) MXPA01005872A (fr)
MY (1) MY124709A (fr)
PL (1) PL192248B1 (fr)
RU (1) RU2236484C2 (fr)
TW (2) TWI237657B (fr)
WO (1) WO2000036046A1 (fr)

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