CA2442157A1 - Low odor insulation binder from phosphite terminated polyacrylic acid - Google Patents
Low odor insulation binder from phosphite terminated polyacrylic acid Download PDFInfo
- Publication number
- CA2442157A1 CA2442157A1 CA 2442157 CA2442157A CA2442157A1 CA 2442157 A1 CA2442157 A1 CA 2442157A1 CA 2442157 CA2442157 CA 2442157 CA 2442157 A CA2442157 A CA 2442157A CA 2442157 A1 CA2442157 A1 CA 2442157A1
- Authority
- CA
- Canada
- Prior art keywords
- sodium
- polyacrylic acid
- binder
- agent
- phosphite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/285—Acrylic resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2926—Coated or impregnated inorganic fiber fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2926—Coated or impregnated inorganic fiber fabric
- Y10T442/2992—Coated or impregnated glass fiber fabric
Abstract
A binder composition, obtained by polymerizing acrylic acid monomer in water in the presence of a cure accelerator comprising an alkali metal salt of a phosphorous-containing inorganic acid to form a low molecular weight polyacrylic acid and subsequently reacting said low molecular weight polyacrylic acid with a polyhydroxy crosslinking agent in a crosslinking ste p to make a composition suitable for use as a component in a binder for fiberglass. A significant improvement involves conducting the crosslinking step in the absence of added catalyst. Moreover, satisfactory results are obtained in the absence of conventional undesirable sulfur odors.
Claims (20)
1. In a process for preparing a binder composition, which comprises the steps of;
forming a polyacrylic acid by polymerizing acrylic acid monomer in water in the presence of regulating agent to terminate the formation of polyacrylic acid, said regulating agent comprising sodium hypophosphite to form a phosphate regulated low molecular weight polyacrylic acid, wherein said regulating agent acts as a crosslinking agent in a subsequent reaction step; and subsequently reacting said low molecular weight polyacrylic acid with a polyhydroxy crosslinking agent in a crosslinking step to make a composition suitable for use as a component in a binder for fiberglass.
forming a polyacrylic acid by polymerizing acrylic acid monomer in water in the presence of regulating agent to terminate the formation of polyacrylic acid, said regulating agent comprising sodium hypophosphite to form a phosphate regulated low molecular weight polyacrylic acid, wherein said regulating agent acts as a crosslinking agent in a subsequent reaction step; and subsequently reacting said low molecular weight polyacrylic acid with a polyhydroxy crosslinking agent in a crosslinking step to make a composition suitable for use as a component in a binder for fiberglass.
2. The process of claim 1, wherein said regulating agent further comprises a constituent selected from the group consisting of sodium phosphite, potassium phosphite, disodium pyrophosphate, tetrasodium pyrophosphate, sodium tripolyphosphate, sodium hexametaphosphate, potassium phosphate, potassium polymetaphosphate, potassium polyphosphate, potassium, tripolyphosphate, sodium trimetaphosphate, sodium tetrametaphosphate, and mixtures thereof.
3. The process of claim 2, wherein said regulating agent is selected from the group consisting of sodium, hypophosphite, sodium, phosphite, and mixtures thereof.
4. The process of claim 1, wherein seed low molecular weight polyacrylic acid has weight-average molecular weight ranging from 1000 through 10,000.
5. The process of claim 4, wherein the polyacrylic acid molecular weight is between 2000 and 6000.
6. The process of claim 1, wherein the polyhydroxy crosslinking agent is selected from the group consisting of triethanolamine, glycerol, trimethylolpropane, 1,2,4-butanetriol, ethyleneglycol, 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, pentaerythritol, sorbitol, and mixtures thereof.
7. The process of claim 6, wherein said polyhydroxy crosslinking agent is selected from the group consisting of triethanolamine and glycerol.
8. The process of claim 1, wherein the molar ratio of hydroxyl groups in the polyhydroxy crosslinking agent to carbocylic acid groups in the polyacrylic acid ranges from 0.4 to 0.6.
9. The process of claim 8, wherein said molar ratio ranges from about 0.47 to about 0.52.
10. The process of claim 1, further comprising the step of diluting said composition suitable for use as a binder component with sufficient water to provide a binder mixture comprising up to 98 wt-% water.
11. The process of claim 10, wherein said binder mixture comprises about 50 to 60 wt-% water.
12. The process of claim 10, further comprising the step of adding a hydrolyzed silane coupling agent to said binder mixture.
13. The process of claim 12, wherein the weight of hydrolyzed silane coupling, agent added is from 0.01 to 10 wt-% based upon the weight of said composition suitable for use as a binder component.
14. The process of claim 10, further comprising the step of adding a mineral oil dust suppressing anent to said binder mixture.
15. The process of claim 14, wherein the weight of mineral oil dust suppressing agent added is up to 20 wt-% based upon the weight of said composition suitable for use as a binder component.
16. The process of claim 10, wherein the weight of said composition suitable for use as a binder component ranges from 2 wt-% to 30 wt-% of said binder mixture.
17. A composition suitable for use as a component in a binder for fiberglass, comprising:
a polyacrylic acid polymerized from an acrylic acid monomer in the presence of phosphite based regulating agent to form a phosphite regulated low molecular weight polyacrylic acid, said regulating agent being suitable for use as a crosslinking agent in a subsequent reaction step, and crosslinked by a polyhydroxy crosslinking agent.
a polyacrylic acid polymerized from an acrylic acid monomer in the presence of phosphite based regulating agent to form a phosphite regulated low molecular weight polyacrylic acid, said regulating agent being suitable for use as a crosslinking agent in a subsequent reaction step, and crosslinked by a polyhydroxy crosslinking agent.
18. The composition of claim 17, wherein said phosphite based regulating agent further comprises a constituent selected from the group consisting of, sodium phosphite, potassium phosphite, disodium pyrophosphate, tetrasodium pyrophosphate, sodium tripolyphosphate, sodium hexametaphosphate, potassium phosphate, potassium polymetaphosphate, potassium polyphosphate, potassium tripolyphosphate, sodium trimetaphosphate, sodium tetrametaphosphate, and mixtures thereof.
19. The composition of claim 18, wherein said phosphate based regulating agent is selected from the group consisting of sodium hypophosphite, sodium phosphate, and mixtures thereof.
20. A fiberglass insulation product, comprising:
glass fibers; and a polyacrylic acid binder polymerized from an acrylic acid monomer in the presence of a regulating agent comprising sodium hypophosphite to form, a phosphate regulated low molecular weight polyacrylic acid said regulating agent being suitable for use as a crosslinking agent in a subsequent reaction step, and crosslinked by a polyhydroxy crosslinking agent.
glass fibers; and a polyacrylic acid binder polymerized from an acrylic acid monomer in the presence of a regulating agent comprising sodium hypophosphite to form, a phosphate regulated low molecular weight polyacrylic acid said regulating agent being suitable for use as a crosslinking agent in a subsequent reaction step, and crosslinked by a polyhydroxy crosslinking agent.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/814,034 US6933349B2 (en) | 2001-03-21 | 2001-03-21 | Low odor insulation binder from phosphite terminated polyacrylic acid |
US09/814,034 | 2001-03-21 | ||
PCT/US2002/008866 WO2002077038A2 (en) | 2001-03-21 | 2002-03-21 | Low odor insulation binder from phosphite terminated polyacrylic acid |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2442157A1 true CA2442157A1 (en) | 2002-10-03 |
CA2442157C CA2442157C (en) | 2012-02-07 |
Family
ID=25214032
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2442157 Expired - Lifetime CA2442157C (en) | 2001-03-21 | 2002-03-21 | Low odor insulation binder from phosphite terminated polyacrylic acid |
Country Status (6)
Country | Link |
---|---|
US (4) | US6933349B2 (en) |
AU (1) | AU2002244331B2 (en) |
CA (1) | CA2442157C (en) |
MX (1) | MX243530B (en) |
NZ (1) | NZ528219A (en) |
WO (1) | WO2002077038A2 (en) |
Families Citing this family (59)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040002567A1 (en) * | 2002-06-27 | 2004-01-01 | Liang Chen | Odor free molding media having a polycarboxylic acid binder |
US7399818B2 (en) * | 2004-03-16 | 2008-07-15 | Rohm And Haas Company | Curable composition and use thereof |
US20050214534A1 (en) * | 2004-03-29 | 2005-09-29 | Adamo Joseph R | Extended curable compositions for use as binders |
US8163664B2 (en) * | 2004-07-30 | 2012-04-24 | Owens Corning Intellectual Capital, Llc | Fiberglass products for reducing the flammability of mattresses |
US20060244818A1 (en) * | 2005-04-28 | 2006-11-02 | Comotiv Systems, Inc. | Web-based conferencing system |
AU2006202621A1 (en) * | 2005-06-30 | 2007-01-18 | Rohm And Haas Company | A curable composition |
US20070198637A1 (en) * | 2006-01-04 | 2007-08-23 | Scott Deboy | Conferencing system with data file management |
US20070156829A1 (en) * | 2006-01-05 | 2007-07-05 | Scott Deboy | Messaging system with secure access |
US20070239827A1 (en) * | 2006-02-13 | 2007-10-11 | Scott Deboy | Global chat system |
US20070286366A1 (en) * | 2006-03-17 | 2007-12-13 | Scott Deboy | Chat presence system |
US7989367B2 (en) * | 2006-06-30 | 2011-08-02 | Georgia-Pacific Chemicals Llc | Reducing formaldehyde emissions from fiberglass insulation |
US20070276910A1 (en) * | 2006-05-23 | 2007-11-29 | Scott Deboy | Conferencing system with desktop sharing |
US20070282793A1 (en) * | 2006-06-01 | 2007-12-06 | Majors Kenneth D | Computer desktop sharing |
US8173219B2 (en) * | 2006-06-09 | 2012-05-08 | Georgia-Pacific Chemicals Llc | Porous fiberglass materials having reduced formaldehyde emissions |
US20080005245A1 (en) * | 2006-06-30 | 2008-01-03 | Scott Deboy | Conferencing system with firewall |
US8043383B2 (en) * | 2006-06-30 | 2011-10-25 | Georgia-Pacific Chemicals Llc | Reducing formaldehyde emissions |
US20080043964A1 (en) * | 2006-07-14 | 2008-02-21 | Majors Kenneth D | Audio conferencing bridge |
US20080021968A1 (en) * | 2006-07-19 | 2008-01-24 | Majors Kenneth D | Low bandwidth chat system |
US20080066001A1 (en) * | 2006-09-13 | 2008-03-13 | Majors Kenneth D | Conferencing system with linked chat |
US20080065999A1 (en) * | 2006-09-13 | 2008-03-13 | Majors Kenneth D | Conferencing system with document access |
US20080065727A1 (en) * | 2006-09-13 | 2008-03-13 | Majors Kenneth D | Conferencing system with improved access |
US8357746B2 (en) * | 2007-05-03 | 2013-01-22 | Johns Manville | Binding of fibrous material utilizing a water soluble Michael adduct crosslinking agent and polycarboxylic acid |
FR2924719B1 (en) | 2007-12-05 | 2010-09-10 | Saint Gobain Isover | SIZING COMPOSITION FOR MINERAL WOOL COMPRISING MONOSACCHARIDE AND / OR POLYSACCHARIDE AND POLYCARBOXYLIC ORGANIC ACID, AND INSULATING PRODUCTS OBTAINED |
FR2935707B1 (en) | 2008-09-11 | 2012-07-20 | Saint Gobain Isover | SIZING COMPOSITION FOR MINERAL WOOL BASED ON HYDROGEN SUGAR AND INSULATING PRODUCTS OBTAINED |
US9718729B2 (en) * | 2009-05-15 | 2017-08-01 | Owens Corning Intellectual Capital, Llc | Biocides for bio-based binders, fibrous insulation products and wash water systems |
US20110003522A1 (en) * | 2009-05-15 | 2011-01-06 | Liang Chen | Bio-based aqueous binder for fiberglass insulation materials and non-woven mats |
US8864893B2 (en) | 2009-10-09 | 2014-10-21 | Owens Corning Intellectual Capital, Llc | Bio-based binders for insulation and non-woven mats |
FR2946352B1 (en) | 2009-06-04 | 2012-11-09 | Saint Gobain Isover | MINERAL WOOL SIZING COMPOSITION COMPRISING A SACCHARIDE, A POLYCARBOXYLIC ORGANIC ACID AND A REACTIVE SILICONE, AND INSULATING PRODUCTS OBTAINED |
US20110021101A1 (en) * | 2009-06-29 | 2011-01-27 | Hawkins Christopher M | Modified starch based binder |
US20110223364A1 (en) * | 2009-10-09 | 2011-09-15 | Hawkins Christopher M | Insulative products having bio-based binders |
FR2951189B1 (en) | 2009-10-13 | 2011-12-09 | Saint Gobain Isover | SIZING COMPOSITION FOR MINERAL WOOL COMPRISING A REDUCING SUGAR AND A METAL SALT OF INORGANIC ACID, AND INSULATING PRODUCTS OBTAINED |
FR2964099B1 (en) | 2010-08-30 | 2012-08-17 | Saint Gobain Isover | SIZING COMPOSITION FOR MINERAL WOOL COMPRISING A NON-REDUCING SUGAR AND A METAL SALT OF INORGANIC ACID, AND INSULATING PRODUCTS OBTAINED. |
FR2966822B1 (en) | 2010-11-02 | 2017-12-22 | Saint-Gobain Technical Fabrics Europe | BINDER FOR MAT OF FIBERS, IN PARTICULAR MINERALS, AND PRODUCTS OBTAINED |
FR2968008B1 (en) | 2010-11-30 | 2014-01-31 | Saint Gobain Isover | SIZING COMPOSITION FOR FIBERS, ESPECIALLY MINERAL, COMPRISING NON-REDUCING SUGAR AND AMMONIUM SALT OF INORGANIC ACID, AND RESULTING PRODUCTS |
WO2012138723A1 (en) | 2011-04-07 | 2012-10-11 | Cargill, Incorporated | Bio-based binders including carbohydrates and a pre-reacted product of an alcohol or polyol and a monomeric or polymeric polycarboxylic acid |
FR2975689B1 (en) | 2011-05-25 | 2014-02-28 | Saint Gobain Isover | FORMALDEHYDE - FREE SIZING COMPOSITION FOR FIBERS, ESPECIALLY MINERAL, AND RESULTING PRODUCTS. |
FR2975690B1 (en) | 2011-05-25 | 2014-06-13 | Saint Gobain Isover | FORMALDEHYDE - FREE SIZING COMPOSITION FOR FIBERS, ESPECIALLY MINERAL, AND RESULTING PRODUCTS. |
CA2837073C (en) * | 2011-05-27 | 2020-04-07 | Cargill, Incorporated | Bio-based binder systems |
FR2976585B1 (en) | 2011-06-17 | 2013-06-07 | Saint Gobain Adfors | BINDER FOR MAT OF MINERAL AND / OR ORGANIC FIBERS AND PRODUCTS OBTAINED |
FR2976583B1 (en) | 2011-06-17 | 2013-06-07 | Saint Gobain Adfors | BINDER FOR MAT OF MINERAL AND / OR ORGANIC FIBERS AND PRODUCTS OBTAINED |
FR2976582B1 (en) | 2011-06-17 | 2014-12-26 | Saint Gobain Isover | SOWING COMPOSITION FOR MINERAL WOOL WITH LOW EMISSION OF VOLATILE ORGANIC COMPOUNDS, AND INSULATING PRODUCTS OBTAINED. |
FR2976584B1 (en) | 2011-06-17 | 2014-12-12 | Saint Gobain Isover | SIZING COMPOSITION FOR MINERAL WOOL BASED ON SALT OF LIGNOSULPHONIC ACID AND OLIGOSACCHARIDE, AND INSULATING PRODUCTS OBTAINED |
US9957409B2 (en) | 2011-07-21 | 2018-05-01 | Owens Corning Intellectual Capital, Llc | Binder compositions with polyvalent phosphorus crosslinking agents |
FR2978446B1 (en) | 2011-07-27 | 2015-06-05 | Saint Gobain Isover | SIZING COMPOSITION FOR MINERAL WOOL BASED ON MALTITOL AND INSULATING PRODUCTS OBTAINED |
FR2978768B1 (en) | 2011-08-05 | 2014-11-28 | Saint Gobain Isover | SINKING COMPOSITION FOR MINERAL WOOL BASED ON SUCROSE REDUCER AND HYDROGEN SACCHARIDE, AND INSULATING PRODUCTS OBTAINED |
FR2985725B1 (en) | 2012-01-17 | 2015-06-26 | Saint Gobain Isover | SIZING COMPOSITION FOR FIBERS, ESPECIALLY MINERAL, BASED ON HUMIC AND / OR FULVIC ACID, AND RESULTING INSULATING PRODUCTS. |
EP2679624A1 (en) * | 2012-06-29 | 2014-01-01 | URSA Insulation, S.A. | Formaldehyde-free binder and use for mineral wool insulation products |
FR3010404B1 (en) | 2013-09-09 | 2015-10-09 | Saint Gobain Isover | SIZING COMPOSITION FOR MINERAL WOOL AND INSULATING PRODUCTS OBTAINED. |
FR3019815B1 (en) | 2014-04-15 | 2016-05-06 | Saint Gobain Isover | SIZING COMPOSITION BASED ON NON-REDUCING SACCHARIDE AND HYDROGEN SACCHARIDE, AND INSULATING PRODUCTS OBTAINED. |
WO2016120576A1 (en) | 2015-01-30 | 2016-08-04 | Saint-Gobain Isover | Sizing composition for mineral wool, comprising lignosulfonate and a carbonyl compound, and resulting insulating products |
EP3250533B1 (en) | 2015-01-30 | 2022-03-09 | Saint-Gobain Adfors | Mineral fibre mats comprising a binder based on lignosulfonate and a carbonyl compound |
CA2989590C (en) | 2015-06-16 | 2023-07-04 | Owens Corning Intellectual Capital, Llc | Highly hydrolytically stable loose-fill insulation |
MX2018015009A (en) | 2016-06-06 | 2019-05-13 | Owens Corning Intellectual Capital Llc | Binder system. |
FR3062131B1 (en) | 2017-01-23 | 2020-06-26 | Saint-Gobain Isover | SIZING COMPOSITION FOR MINERAL WOOL BASED ON HYDROGEN SUGAR AND INSULATING PRODUCTS OBTAINED. |
US10247667B2 (en) * | 2017-04-26 | 2019-04-02 | Fibremark Solutions Limited | Photon marker system for fiber material |
CN111201275B (en) | 2017-10-09 | 2022-07-01 | 欧文斯科宁知识产权资产有限公司 | Aqueous adhesive composition |
CN111194366B (en) | 2017-10-09 | 2023-04-11 | 欧文斯科宁知识产权资产有限公司 | Aqueous adhesive composition |
US11813833B2 (en) | 2019-12-09 | 2023-11-14 | Owens Corning Intellectual Capital, Llc | Fiberglass insulation product |
CN111533467A (en) * | 2020-06-09 | 2020-08-14 | 巨石集团有限公司 | Impregnating compound for glass fiber direct roving and preparation method, product and application thereof |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3792141A (en) * | 1972-05-26 | 1974-02-12 | W Offutt | Method of structural fabrication |
US5077361A (en) | 1989-06-26 | 1991-12-31 | Rohm And Haas Company | Low molecular weight water soluble phosphinate and phosphonate containing polymers |
US5661213A (en) | 1992-08-06 | 1997-08-26 | Rohm And Haas Company | Curable aqueous composition and use as fiberglass nonwoven binder |
US5294686A (en) | 1993-03-29 | 1994-03-15 | Rohm And Haas Company | Process for efficient utilization of chain transfer agent |
US5364894A (en) * | 1993-03-31 | 1994-11-15 | Tremco, Inc. | Emulsification of asphalt and modified asphalt with primary emulsifier polymers comprised of acrylic acid type monomers |
US5318990A (en) | 1993-06-21 | 1994-06-07 | Owens-Corning Fiberglas Technology Inc. | Fibrous glass binders |
US5340868A (en) | 1993-06-21 | 1994-08-23 | Owens-Corning Fiberglass Technology Inc. | Fibrous glass binders |
US5427587A (en) * | 1993-10-22 | 1995-06-27 | Rohm And Haas Company | Method for strengthening cellulosic substrates |
US6207737B1 (en) | 1994-03-14 | 2001-03-27 | Ppg Industries Ohio, Inc. | Glass fiber sizing, sized glass fibers and polyolefin reinforced articles |
US5670585A (en) | 1995-06-13 | 1997-09-23 | Schuller International, Inc. | Use of polyacrylic acid and other polymers as additives in fiberglass formaldehyde based binders |
US5720796A (en) | 1995-08-08 | 1998-02-24 | W. R. Grace & Co.-Conn. | Process of using roll press grinding aid for granulated blast furnace slag |
US5578371A (en) | 1995-08-25 | 1996-11-26 | Schuller International, Inc. | Phenol/formaldehyde fiberglass binder compositions exhibiting reduced emissions |
CA2190235A1 (en) | 1995-11-20 | 1997-05-21 | Barry Weinstein | High alkali-containing cleaning concentrates |
US6218483B1 (en) | 1996-05-06 | 2001-04-17 | Rohm And Haas Company | Powder coating of epoxy resin, imidazole-epoxy resin catalyst or polyamine, polyamine powder and amine scavenger |
FR2751335B1 (en) | 1996-07-19 | 1998-08-21 | Coatex Sa | PROCESS FOR OBTAINING WATER-SOLUBLE POLYMERS, POLYMERS OBTAINED AND USES THEREOF |
US5858549A (en) | 1997-01-07 | 1999-01-12 | National Starch And Chemical Investment Holding Corporation | (Hydroxyalkyl)urea crosslinking agents |
US5866664A (en) | 1997-02-03 | 1999-02-02 | Rohm And Haas Company | Process for preparing phosphonate-terminated polymers |
US5932665A (en) | 1997-02-06 | 1999-08-03 | Johns Manville International, Inc. | Polycarboxy polymer acid binders having reduced cure temperatures |
TW408152B (en) | 1997-04-25 | 2000-10-11 | Rohm & Haas | Formaldehyde-free curable composition and method for bonding heat-resistant fibers of a nonwoven material by using the composition |
US5977232A (en) | 1997-08-01 | 1999-11-02 | Rohm And Haas Company | Formaldehyde-free, accelerated cure, aqueous composition for bonding glass fiber heat-resistant nonwovens |
US5840822A (en) | 1997-09-02 | 1998-11-24 | National Starch And Chemical Investment Holding Corporation | Mono(hydroxyalkyl)urea and oxazolidone crosslinking agents |
AU4190299A (en) * | 1998-05-28 | 1999-12-13 | Owens Corning | Corrosion inhibiting composition for polyacrylic acid based binders |
EP0990727A1 (en) | 1998-10-02 | 2000-04-05 | Johns Manville International Inc. | Polycarboxy/polyol fiberglass binder |
US6331350B1 (en) | 1998-10-02 | 2001-12-18 | Johns Manville International, Inc. | Polycarboxy/polyol fiberglass binder of low pH |
EP0990728A1 (en) | 1998-10-02 | 2000-04-05 | Johns Manville International Inc. | Low molecular weight polycarboxy/polyol fiberglass binder |
US6194512B1 (en) | 1999-06-28 | 2001-02-27 | Owens Corning Fiberglas Technology, Inc. | Phenol/formaldehyde and polyacrylic acid co-binder and low emissions process for making the same |
-
2001
- 2001-03-21 US US09/814,034 patent/US6933349B2/en not_active Expired - Lifetime
-
2002
- 2002-03-21 NZ NZ528219A patent/NZ528219A/en not_active IP Right Cessation
- 2002-03-21 WO PCT/US2002/008866 patent/WO2002077038A2/en active IP Right Grant
- 2002-03-21 AU AU2002244331A patent/AU2002244331B2/en not_active Ceased
- 2002-03-21 MX MXPA03008450 patent/MX243530B/en active IP Right Grant
- 2002-03-21 CA CA 2442157 patent/CA2442157C/en not_active Expired - Lifetime
-
2004
- 2004-07-14 US US10/890,693 patent/US20050032985A1/en not_active Abandoned
- 2004-11-02 US US10/979,667 patent/US20050095937A1/en not_active Abandoned
-
2013
- 2013-07-29 US US13/952,921 patent/US20140001395A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
MX243530B (en) | 2007-01-29 |
WO2002077038B1 (en) | 2003-06-19 |
WO2002077038A2 (en) | 2002-10-03 |
US20030008978A1 (en) | 2003-01-09 |
NZ528219A (en) | 2005-02-25 |
US20140001395A1 (en) | 2014-01-02 |
US20050095937A1 (en) | 2005-05-05 |
WO2002077038A3 (en) | 2003-04-24 |
CA2442157C (en) | 2012-02-07 |
AU2002244331B2 (en) | 2007-08-09 |
US6933349B2 (en) | 2005-08-23 |
MXPA03008450A (en) | 2004-05-21 |
US20050032985A1 (en) | 2005-02-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2442157A1 (en) | Low odor insulation binder from phosphite terminated polyacrylic acid | |
AU2002244331A1 (en) | Low odor insulation binder from phosphite terminated polyacrylic acid | |
KR101822042B1 (en) | Polymerizable compositions, cured products obtained therewith, and use of these materials | |
CN108912928B (en) | Preparation method of flame-retardant and waterproof water-based core-shell acrylate resin coating and paint | |
US20090023883A1 (en) | Phosphorous-containing organic polymerisable silanes and silicic acid polycondensates produced therewith | |
JP2009503218A5 (en) | ||
DE4423811C1 (en) | Hydrolyzable and polymerizable silanes, process for their preparation and their use | |
GB2093458A (en) | Polymerisable tertiary phosphate derivatives useful as fillers for human hard tissues | |
US3194724A (en) | Coated blocks | |
DE2142596C3 (en) | Process for silylating styrene polymers | |
US2394642A (en) | Silicic acid esters | |
US7432385B2 (en) | Phosphorous-containing, organic polymerisable silanes and silicic acid polycondensates produced therewith | |
JP4500811B2 (en) | Silane-modified aqueous dispersion polymer having storage stability | |
DE10016324A1 (en) | Ormocere, process for their manufacture and use | |
HK1034529A1 (en) | Organopolysiloxane materials which can be cross-linked by cleaving alcohols into elastomers. | |
JP3045471B2 (en) | Reactive organic-inorganic composite particles | |
DE50005347D1 (en) | METHOD FOR PRODUCING A SOLUTION OF DIEN POLYMERISATES IN VINYLAROMATIC COMPOUNDS, AND FOR PRODUCING IMPACT TEETH VINYLAROMATIC POLYMERS BY POLYMERIZING THIS SOLUTION | |
CN111072316A (en) | PMMA-aluminum hydroxide-organophosphorus acrylic composite base material and preparation method thereof | |
DE59707367D1 (en) | METHOD FOR PRODUCING LOW-VISCUS, AQUEOUS POLYMER DISPERSIONS WITH POLYMER CONTENT OF AT LEAST 50 VOL% | |
JP2000500804A (en) | Hybrid phenolic resin | |
Imoto et al. | Vinyl polymerization, 366. Polymerization of methyl methacrylate initiated with a hydrolyzed product of poly [bis (2‐chloroethyl) vinylphosphonate] | |
JPH06122742A (en) | Polymerizable compositions and use of these compositions to seal underground environment | |
Yu et al. | Synthesis of PMMA/Polysiloxane Core-Shell Latex | |
JP3541075B2 (en) | Method for producing polymethylsiloxane resin | |
CA1077639A (en) | Semisolid polymerizable compositions, method of preparing the same and thermoset products thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKEX | Expiry |
Effective date: 20220321 |