CA2445415A1 - In situ recovery from a oil shale formation - Google Patents
In situ recovery from a oil shale formation Download PDFInfo
- Publication number
- CA2445415A1 CA2445415A1 CA002445415A CA2445415A CA2445415A1 CA 2445415 A1 CA2445415 A1 CA 2445415A1 CA 002445415 A CA002445415 A CA 002445415A CA 2445415 A CA2445415 A CA 2445415A CA 2445415 A1 CA2445415 A1 CA 2445415A1
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- Prior art keywords
- formation
- condensable hydrocarbons
- heat
- heat sources
- weight
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Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
- E21B43/243—Combustion in situ
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
- E21B43/2401—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection by means of electricity
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
- E21B43/243—Combustion in situ
- E21B43/247—Combustion in situ in association with fracturing processes or crevice forming processes
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/30—Specific pattern of wells, e.g. optimizing the spacing of wells
Abstract
An oil shale formation may be treated using an in situ thermal process. Heat may be provided to a formation from a heat source in the formation. Hydrocarbons within the formation may be pyrolyzed. Hydrocarbons, H2, and/or other formation fluids may be produced from the formation. In some embodiments, the formation may include a relatively impermeable portion and/ or a relatively permeable portion.
Claims
WHAT IS CLAIMED IS:
1. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least one portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
controlling the heat from the one or more heat sources such that an average temperature within at least a majority of the selected section of the formation is less than about 375 °C; and producing a mixture from the formation.
2. The method of claim 1, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
3. The method of claim 1, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
4. The method of claim 1, wherein the one or more heat sources comprise electrical heaters.
5. The method of claim 1, wherein the one or more heat sources comprise surface burners.
6. The method of claim 1, wherein the one or more heat sources comprise flameless distributed combustors.
7. The method of claim 1, wherein the one or more heat sources comprise natural distributed combustors.
8. The method of claim 1, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
9. The method of claim 1, further comprising controlling a pressure within at least a majority of the selected section of the formation with a valve coupled to at least one of the one or more heat sources.
10. The method of claim 1, further comprising controlling a pressure within at least a majority of the selected section of the formation with a valve coupled to a production well located in the formation.
11. The method of claim 1, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
12. The method of claim 1, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity(C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
13. The method of claim 1, wherein allowing the heat to transfer from the one or more heat sources to the selected section comprises transferring heat substantially by conduction.
14. The method of claim 1, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
15. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons having an API
gravity of at least about 25°.
16. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
17. The method of claim 1, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
18. The method of claim 1, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
19. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
20. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
21. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
22. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
23. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
24. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
25. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
26. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein about % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
27. The method of claim 1, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, and wherein greater than about 10 % by volume of the non-condensable component comprises hydrogen and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
28. The method of claim 1, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
29. The method of claim 1, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
30. The method of claim 1, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
31. The method of claim 1, further comprising controlling formation conditions such that the produced mixture comprises a partial pressure of H2 within the mixture greater than about 0.5 bars.
32. The method of claim 31, wherein the partial pressure of H2 is measured when the mixture is at a production well.
33. The method of claim 1, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
34. The method of claim 1, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
35. The method of claim 1, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
36. The method of claim 1, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
37. The method of claim 1, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
38. The method of claim 1, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
39. The method of claim 1, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
40. The method of claim 1, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
41. The method of claim 40, wherein at least about 20 heat sources are disposed in the formation for each production well.
42. The method of claim 1, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
43. The method of claim 1, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
44. The method of claim 1, further comprising separating the produced mixture into a gas stream and a liquid stream.
45. The method of claim 1, further comprising separating the produced mixture into a gas stream and a liquid stream and separating the liquid stream into an aqueous stream and a non-aqueous stream.
46. The method of claim 1, wherein the produced mixture comprises H2S, the method further comprising separating a portion of the H2S from non-condensable hydrocarbons.
47. The method of claim 1, wherein the produced mixture comprises CO2, the method further comprising separating a portion of the CO2 from non-condensable hydrocarbons.
48. The method of claim 1, wherein the mixture is produced from a production well, wherein the heating is controlled such that the mixture can be produced from the formation as a vapor.
49. The method of claim 1, wherein the mixture is produced from a production well, the method further comprising heating a wellbore of the production well to inhibit condensation of the mixture within the wellbore.
50. The method of claim 1, wherein the mixture is produced from a production well, wherein a wellbore of the production well comprises a heater element configured to heat the formation adjacent to the wellbore, and further comprising heating the formation with the heater element to produce the mixture, wherein the mixture comprises a large non-condensable hydrocarbon gas component and H2.
51. The method of claim 1, wherein the minimum pyrolysis temperature is about 270 °C.
52. The method of claim 1, further comprising maintaining the pressure within the formation above about 2.0 bars absolute to inhibit production of fluids having carbon numbers above 25.
53. The method of claim 1, further comprising controlling pressure within the formation in a range from about atmospheric pressure to about 100 bars, as measured at a wellhead of a production well, to control an amount of condensable hydrocarbons within the produced mixture, wherein the pressure is reduced to increase production of condensable hydrocarbons, and wherein the pressure is increased to increase production of non-condensable hydrocarbons.
54. The method of claim 1, further comprising controlling pressure within the formation in a range from about atmospheric pressure to about 100 bars, as measured at a wellhead of a production well, to control an API gravity of condensable hydrocarbons within the produced mixture, wherein the pressure is reduced to decrease the API
gravity, and wherein the pressure is increased to reduce the API gravity.
55. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from at least the portion to a selected section of the formation substantially by conduction of heat;
pyrolyzing at least some hydrocarbons within the selected section of the formation; and producing a mixture from the formation.
56. The method of claim 55, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
57. The method of claim 55, wherein the one or more heat sources comprise electrical heaters.
58. The method of claim 55, wherein the one or more heat sources comprise surface burners.
59. The method of claim 55, wherein the one or more heat sources comprise flameless distributed combustors.
60. The method of claim 55, wherein the one or more heat sources comprise natural distributed combustors.
61. The method of claim 55, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
62. The method of claim 55, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1.0 ° C per day during pyrolysis.
63. The method of claim 55, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
64. The method of claim 55, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
65. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons having an API
gravity of at least about 25°.
66. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
67. The method of claim 55, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
68. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
69. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
70. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
71. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
72. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
73. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises mufti-ring aromatics with more than two rings.
74. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
75. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
76. The method of claim 55, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
77. The method of claim 55, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
78. The method of claim 55, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
79. The method of claim 55, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
80. The method of claim 55, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
81. The method of claim 80, wherein the partial pressure of H2 is measured when the mixture is at a production well.
82. The method of claim 55, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
83. The method of claim 55, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
84. The method of claim 55, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
85. The method of claim 55, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
86. The method of claim 55, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
87. The method of claim 55, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
88. The method of claim 55, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
89. The method of claim 55, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
90. The method of claim 89, wherein at least about 20 heat sources are disposed in the formation for each production well.
91. The method of claim 55, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
92. The method of claim 55, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
93. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
controlling the heat from the one or more heat sources such that an average temperature within at least a majority of the selected section of the formation is less than about 370 °C such that production of a substantial amount of hydrocarbons having carbon numbers greater than 25 is inhibited;
controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least 2.0 bars; and producing a mixture from the formation, wherein about 0.1 % by weight of the produced mixture to about 15 % by weight of the produced mixture are olefins, and wherein an average carbon number of the produced mixture is greater than 1 and less than about 25.
94. The method of claim 93, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
95. The method of claim 93, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
96. The method of claim 93, wherein the one or more heat sources comprise electrical heaters.
97. The method of claim 93, wherein the one or more heat sources comprise surface burners.
98. The method of claim 93, wherein the one or more heat sources comprise flameless distributed combustors.
99. The method of claim 93, wherein the one or more heat sources comprise natural distributed combustors.
100. The method of claim 93, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
101. The method of claim 93, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
102. The method of claim 93, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
103. The method of claim 93, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
104. The method of claim 93, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
105. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
106. The method of claim 93, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
107. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
108. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
109. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
110. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
111. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
112. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
113. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
114. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
115. The method of claim 93, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
116. The method of claim 93, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
117. The method of claim 93, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
118. The method of claim 93, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
119. The method of claim 118, wherein the partial pressure of H2 is measured when the mixture is at a production well.
120. The method of claim 93, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
121. The method of claim 93, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
122. The method of claim 93, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
123. The method of claim 93, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
124. The method of claim 93, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
125. The method of claim 93, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
126. The method of claim 93, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
127. The method of claim 126, wherein at least about 20 heat sources are disposed in the formation for each production well.
128. The method of claim 93, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
129. The method of claim 93, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
130. The method of claim 93, further comprising separating the produced mixture into a gas stream and a liquid stream.
131. The method of claim 93, further comprising separating the produced mixture into a gas stream and a liquid stream and separating the liquid stream into an aqueous stream and a non-aqueous stream.
132. The method of claim 93, wherein the produced mixture comprises H2S, the method further comprising separating a portion of the H2S from non-condensable hydrocarbons.
133. The method of claim 93, wherein the produced mixture comprises CO2, the method further comprising separating a portion of the CO2 from non-condensable hydrocarbons.
134. The method of claim 93, wherein the mixture is produced from a production well, wherein the heating is controlled such that the mixture can be produced from the formation as a vapor.
135. The method of claim 93, wherein the mixture is produced from a production well, the method further comprising heating a wellbore of the production well to inhibit condensation of the mixture within the wellbore.
136. The method of claim 93, wherein the mixture is produced from a production well, wherein a wellbore of the production well comprises a heater element configured to heat the formation adjacent to the wellbore, and further comprising heating the formation with the heater element to produce the mixture, wherein the produced mixture comprise a large non-condensable hydrocarbon gas component and H2.
137. The method of claim 93, wherein the minimum pyrolysis temperature is about 270 °C.
138. The method of claim 93, further comprising maintaining the pressure within the formation above about 2.0 bars absolute to inhibit production of fluids having carbon numbers above 25.
139. The method of claim 93, further comprising controlling pressure within the formation in a range from about atmospheric pressure to about 100 bars absolute, as measured at a wellhead of a production well, to control an amount of condensable fluids within the produced mixture, wherein the pressure is reduced to increase production of condensable fluids, and wherein the pressure is increased to increase production of non-condensable fluids.
140. The method of claim 93, further comprising controlling pressure within the formation in a range from about atmospheric pressure to about 100 bars absolute, as measured at a wellhead of a production well, to control an API gravity of condensable fluids within the produced mixture, wherein the pressure is reduced to decrease the API
gravity, and wherein the pressure is increased to reduce the API gravity.
141. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute; and producing a mixture from the formation.
142. The method of claim 141, wherein controlling the pressure comprises controlling the pressure with a valve coupled to at least one of the one or more heat sources.
143. The method of claim 141, wherein controlling the pressure comprises controlling the pressure with a valve coupled to a production well located in the formation.
144. The method of claim 141, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
145. The method of claim 141, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
146. The method of claim 141, wherein the one or more heat sources comprise electrical heaters.
147. The method of claim 141, wherein the one or more heat sources comprise surface burners.
148. The method of claim 141, wherein the one or more heat sources comprise flameless distributed combustors.
149. The method of claim 141, wherein the one or more heat sources comprise natural distributed combustors.
150. The method of claim 141, further comprising controlling a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
151. The method of claim 141, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
152. The method of claim 141, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the.equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
153. The method of claim 141, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
154. The method of claim 141, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
155. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
156. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
157. The method of claim 141, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
158. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
159. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
160. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
161. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
162. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
163. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
164. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
165. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
166. The method of claim 141, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
167. The method of claim 141, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
168. The method of claim 141, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
169. The method of claim 141, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
170. The method of claim 169, wherein the partial pressure of H2 is measured when the mixture is at a production well.
171. The method of claim 141, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
172. The method of claim 141, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
173. The method of claim 141, further comprising:
providing hydrogen (Hz) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
174. The method of claim 141, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
175. The method of claim 141, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
176. The method of claim 141, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
177. The method of claim 141, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
178. The method of claim 141, wherein producing the mixture from the formation comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
179. The method of claim 178, wherein at least about 20 heat sources are disposed in the formation for each production well.
180. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute;
controlling the heat from the one or more heat sources such that an average temperature within at least a majority of the selected section of the formation is less than about 375°C; and producing a mixture from the formation.
181. The method of claim 180, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
182. The method of claim 180, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
183. The method of claim 180, wherein the one or more heat sources comprise electrical heaters.
184. The method of claim 180, wherein the one or more heat sources comprise surface burners.
185. The method of claim 180, wherein the one or more heat sources comprise flameless distributed combustors.
186. The method of claim 180, wherein the one or more heat sources comprise natural distributed combustors.
187. The method of claim 180, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
188. The method of claim 180, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1°C per day during pyrolysis.
189. The method of claim 180, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10°C/day.
190. The method of claim 180, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
191. The method of claim 180, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m°C).
192. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
193. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
194. The method of claim 180, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
195. The method of claim 180, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
196. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
197. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
198. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
199. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
200. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
201. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises mufti-ring aromatics with more than two rings.
202. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
203. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
204. The method of claim 180, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
205. The method of claim 180, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
206. The method of claim 180, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
207. The method of claim 180, wherein controlling the heat further comprises controlling the heat such that coke production is inhibited.
208. The method of claim 180, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of HZ within the mixture is greater than about 0.5 bars.
209. The method of claim 208, wherein the partial pressure of HZ is measured when the mixture is at a production well.
210. The method of claim 180, further comprising altering the pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
211. The method of claim 180, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
212. The method of claim 180, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
213. The method of claim 180, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
214. The method of claim 180, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
215. The method of claim 180, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
216. The method of claim 180, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
217. The method of claim 180, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
218. The method of claim 217, wherein at least about 20 heat sources are disposed in the formation for each production well.
219. The method of claim 180, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
220. The method of claim 180, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
221. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
producing a mixture from the formation, wherein at least a portion of the mixture is produced during the pyrolysis and the mixture moves through the formation in a vapor phase; and maintaining a pressure within at least a majority of the selected section above about 2.0 bars absolute.
222. The method of claim 221, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at (east the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
223. The method of claim 221, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
224. The method of claim 221, wherein the one or more heat sources comprise electrical heaters.
225. The method of claim 221, wherein the one or more heat sources comprise surface burners.
226. The method of claim 221, wherein the one or more heat sources comprise flameless distributed combustors.
227. The method of claim 221, wherein the one or more heat sources comprise natural distributed combustors.
228. The method of claim 221, further comprising controlling the pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
229. The method of claim 221, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1°C per day during pyrolysis.
230. The method of claim 221, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) ofthe oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
231. The method of claim 221, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
232. The method of claim 221, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m°C).
233. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
234. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
235. The method of claim 221, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
236. The method of claim 221, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
237. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
238. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
239. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
240. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
241. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
242. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
243. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
244. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
245. The method of claim 221, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
246. The method of claim 221, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
247. The method of claim 221, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
248. The method of claim 221, wherein the pressure is measured at a wellhead of a production well.
249. The method of claim 221, wherein the pressure is measured at a location within a wellbore of the production well.
250. The method of claim 221, wherein the pressure is maintained below about 100 bars absolute.
251. The method of claim 221, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
252. The method of claim 251, wherein the partial pressure of H2 is measured when the mixture is at a production well.
253. The method of claim 221, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
254. The method of claim 221, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
255. The method of claim 221, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
256. The method of claim 221, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
257. The method of claim 221, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
258. The method of claim 221, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
259. The method of claim 221, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
260. The method of claim 221, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
261. The method of claim 260, wherein at least about 20 heat sources are disposed in the formation for each production well.
262. The method of claim 221, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
263. The method of claim 221, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
264. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
maintaining a pressure within at least a majority of the selected section of the formation above 2.0 bars absolute; and producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity higher than an API gravity of condensable hydrocarbons in a mixture producible from the formation at the same temperature and at atmospheric pressure.
265. The method of claim 264, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
266. The method of claim 264, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
267. The method of claim 264, wherein the one or more heat sources comprise electrical heaters.
268. The method of claim 264, wherein the one or more heat sources comprise surface burners.
269. The method of claim 264, wherein the one or more heat sources comprise flameless distributed combustors.
270. The method of claim 264, wherein the one or more heat sources comprise natural distributed combustors.
271. The method of claim 264, further comprising controlling the pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
272. The method of claim 264, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1°C per day during pyrolysis.
273. The method of claim 264, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (Cv), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*Cv*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10°C/day.
274. The method of claim 264, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
275. The method of claim 264, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m°C).
276. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
277. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
278. The method of claim 264, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
279. The method of claim 264, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
280. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
281. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
282. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
283. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
284. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
285. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
286. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
287. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
288. The method of claim 264, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
289. The method of claim 264, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
290. The method of claim 264, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
291. The method of claim 264, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
292. The method of claim 264, wherein a partial pressure of H2 is measured when the mixture is at a production well.
293. The method of claim 264, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
294. The method of claim 264, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
295. The method of claim 264, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
296. The method of claim 264, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
297. The method of claim 264, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
298. The method of claim 264, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
299. The method of claim 264, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
300. The method of claim 264, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
301. The method of claim 300, wherein at least about 20 heat sources are disposed in the formation for each production well.
302. The method of claim 264, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
303. The method of claim 264, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
304. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
maintaining a pressure within at least a majority of the selected section of the formation to above 2.0 bars absolute; and producing a fluid from the formation, wherein condensable hydrocarbons within the fluid comprise an atomic hydrogen to atomic carbon ratio of greater than about 1.75.
305. The method of claim 304, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
306. The method of claim 304, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
307. The method of claim 304, wherein the one or more heat sources comprise electrical heaters.
308. The method of claim 304, wherein the one or more heat sources comprise surface burners.
309. The method of claim 304, wherein the one or more heat sources comprise flameless distributed combustors.
310. The method of claim 304, wherein the one or more heat sources comprise natural distributed combustors.
311. The method of claim 304, further comprising controlling the pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
312. The method of claim 304, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1°C per day during pyrolysis.
313. The method of claim 304, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (Cv), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*Cv*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10°C/day.
314. The method of claim 304, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
315. The method of claim 304, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m°C).
316. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
317. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
318. The method of claim 304, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
319. The method of claim 304, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
320. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
321. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
322. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
323. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
324. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
325. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
326. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
327. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
328. The method of claim 304, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
329. The method of claim 304, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
330. The method of claim 304, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
331. The method of claim 304, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
332. The method of claim 304, wherein a partial pressure of H2 is measured when the mixture is at a production well.
333. The method of claim 304, further comprising altering the pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
334. The method of claim 304, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
335. The method of claim 304, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
336. The method of claim 304, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
337. The method of claim 304, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
338. The method of claim 304, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
339. The method of claim 304, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
340. The method of claim 304, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
341. The method of claim 340, wherein at least about 20 heat sources are disposed in the formation for each production well.
342. The method of claim 304, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
343. The method of claim 304, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
344. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
maintaining a pressure within at least a majority of the selected section of the formation to above 2.0 bars absolute; and producing a mixture from the formation, wherein the produced mixture comprises a higher amount of non-condensable components as compared to non-condensable components producible from the formation under the same temperature conditions and at atmospheric pressure.
345. The method of claim 344, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
346. The method of claim 344, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
347. The method of claim 344, wherein the one or more heat sources comprise electrical heaters.
348. The method of claim 344, wherein the one or more heat sources comprise surface burners.
349. The method of claim 344, wherein the one or more heat sources comprise flameless distributed combustors.
350. The method of claim 344, wherein the one or more heat sources comprise natural distributed combustors.
351. The method of claim 344, further comprising controlling the pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
352. The method of claim 344, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1°C per day during pyrolysis.
353. The method of claim 344, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
354. The method of claim 344, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
355. The method of claim 344, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
356. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
357. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
358. The method of claim 344, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
359. The method of claim 344, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
360. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
361. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
362. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
363. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
364. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
365. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
366. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
367. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
368. The method of claim 344, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
369. The method of claim 344, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
370. The method of claim 344, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
371. The method of claim 344, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
372. The method of claim 344, wherein a partial pressure of H2 is measured when the mixture is at a production well.
373. The method of claim 344, further comprising altering the pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
374. The method of claim 344, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
375. The method of claim 344, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
376. The method of claim 344, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
377. The method of claim 344, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
378. The method of claim 344, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
379. The method of claim 344, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
380. The method of claim 379, wherein at least about 20 heat sources are disposed in the formation for each production well.
381. The method of claim 344, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
382. The method of claim 344, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
383. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation such that superimposed heat from the one or more heat sources pyrolyzes at least about 20 % by weight of hydrocarbons within the selected section of the formation; and producing a mixture from the formation.
384. The method of claim 383, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
385. The method of claim 383, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
386. The method of claim 383, wherein the one or more heat sources comprise electrical heaters.
387. The method of claim 383, wherein the one or more heat sources comprise surface burners.
388. The method of claim 383, wherein the one or more heat sources comprise flameless distributed combustors.
389. The method of claim 383, wherein the one or more heat sources comprise natural distributed combustors.
390. The method of claim 383, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
391. The method of claim 383, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
392. The method of claim 383, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
393. The method of claim 383, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
394. The method of claim 383, wherein providing heat from the one or more heat sources comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
395. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
396. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
397. The method of claim 383, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
398. The method of claim 383, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
399. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
400. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
401. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
402. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
403. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
404. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
405. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
406. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
407. The method of claim 383, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
408. The method of claim 383, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
409. The method of claim 383, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
410. The method of claim 383, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
411. The method of claim 383, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
412. The method of claim 383, wherein a partial pressure of H2 is measured when the mixture is at a production well.
413. The method of claim 383, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
414. The method of claim 383, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
415. The method of claim 383, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
416. The method of claim 383, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
417. The method of claim 383, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
418. The method of claim 383, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
419. The method of claim 383, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
420. The method of claim 383, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
421. The method of claim 420, wherein at least about 20 heat sources are disposed in the formation for each production well.
422. The method of claim 383, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
423. The method of claim 383, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
424. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation such that superimposed heat from the one or more heat sources pyrolyzes at least about 20 % of hydrocarbons within the selected section of the formation; and producing a mixture from the formation, wherein the mixture comprises a condensable component having an API gravity of at least about 25°.
425. The method of claim 424, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
426. The method of claim 424, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
427. The method of claim 424, wherein the one or more heat sources comprise electrical heaters.
428. The method of claim 424, wherein the one or more heat sources comprise surface burners.
429. The method of claim 424, wherein the one or more heat sources comprise flameless distributed combustors.
430. The method of claim 424, wherein the one or more heat sources comprise natural distributed combustors.
431. The method of claim 424, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
432. The method of claim 424, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
433. The method of claim 424, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
434. The method of claim 424, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
435. The method of claim 424, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
436. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
437. The method of claim 424, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
438. The method of claim 424, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
439. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
440. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
441. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
442. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
443. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
444. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
445. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
446. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
447. The method of claim 424, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
448. The method of claim 424, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
449. The method of claim 424, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
450. The method of claim 424, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
451. The method of claim 424, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
452. The method of claim 424, wherein a partial pressure of H2 is measured when the mixture is at a production well.
453. The method of claim 424, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
454. The method of claim 424, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
455. The method of claim 424, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
456. The method of claim 424, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
457. The method of claim 424, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
458. The method of claim 424, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
459. The method of claim 424, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
460. The method of claim 424, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
461. The method of claim 460, wherein at least about 20 heat sources are disposed in the formation for each production well.
462. The method of claim 424, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
463. The method of claim 424, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
464. A method of treating a layer of an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the layer, wherein the one or more heat sources are positioned proximate an edge of the layer;
allowing the heat to transfer from the one or more heat sources to a selected section of the layer such that superimposed heat from the one or more heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation; and producing a mixture from the formation.
465. The method of claim 464, wherein the one or more heat sources are laterally spaced from a center of the layer.
466. The method of claim 464, wherein the one or more heat sources are positioned in a staggered line.
467. The method of claim 464, wherein the one or more heat sources positioned proximate the edge of the layer can increase an amount of hydrocarbons produced per unit of energy input to the one or more heat sources.
468. The method of claim 464, wherein the one or more heat sources positioned proximate the edge of the layer can increase the volume of formation undergoing pyrolysis per unit of energy input to the one or more heat sources.
469. The method of claim 464, wherein the one or more heat sources comprise electrical heaters.
470. The method of claim 464, wherein the one or more heat sources comprise surface burners.
471. The method of claim 464, wherein the one or more heat sources comprise flameless distributed combustors.
472. The method of claim 464, wherein the one or more heat sources comprise natural distributed combustors.
473. The method of claim 464, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
474. The method of claim 464, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1.0°C per day during pyrolysis.
475. The method of claim 464, wherein providing heat from the one or more heat sources to at least the portion of the layer comprises:
heating a selected volume (.NU.) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C .NU.), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*.NU.*C .NU.*.rho. .beta.
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho. .beta. is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
476. The method of claim 464, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
477. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
478. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
479. The method of claim 464, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
480. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
481. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
482. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
483. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
484. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
485. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
486. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
487. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
488. The method of claim 464, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
489. The method of claim 464, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
490. The method of claim 464, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
491. The method of claim 464, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
492. The method of claim 464, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
493. The method of claim 492, wherein the partial pressure of H2 is measured when the mixture is at a production well.
494. The method of claim 464, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
495. The method of claim 464, further comprising controlling formation conditions, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
496. The method of claim 464, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
497. The method of claim 464, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
498. The method of claim 464, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
499. The method of claim 464, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
500. The method of claim 464, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
501. The method of claim 464, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
502. The method of claim 501, wherein at least about 20 heat sources are disposed in the formation for each production well.
503. The method of claim 464, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
504. The method of claim 464, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
505. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure; and producing a mixture from the formation.
506. The method of claim 505, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
507. The method of claim 505, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
508. The method of claim 505, wherein the one or more heat sources comprise electrical heaters.
509. The method of claim 505, wherein the one or more heat sources comprise surface burners.
510. The method of claim 505, wherein the one or more heat sources comprise flameless distributed combustors.
511. The method of claim 505, wherein the one or more heat sources comprise natural distributed combustors.
512. The method of claim 505, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
513. The method of claim 505, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (.NU.) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C .NU.), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C .NU. *.rho. .beta.
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p .beta. is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
514. The method of claim 505, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
515. The method of claim 505, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
516. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
517. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
518. The method of claim 505, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
519. The method of claim 505, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
520. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
521. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
522. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
523. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
524. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
525. The method of Maim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
526. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
527. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
528. The method of claim 505, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
529. The method of claim 505, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
530. The method of claim 505, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
531. The method of claim 505, wherein the controlled pressure is at least about 2.0 bars absolute.
532. The method of claim 505, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
533. The method of claim 505, wherein a partial pressure of H2 is measured when the mixture is at a production well.
534. The method of claim 505, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
535. The method of claim 505, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
536. The method of claim 505, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
537. The method of claim 505, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
538. The method of claim 505, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
539. The method of claim 505, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
540. The method of claim 505, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
541. The method of claim 505, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
542. The method of claim 541, wherein at least about 20 heat sources are disposed in the formation for each production well.
543. The method of claim 505, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
544. The method of claim 505, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
545. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation to raise an average temperature within the selected section to, or above, a temperature that will pyrolyze hydrocarbons within the selected section;
producing a mixture from the formation; and controlling API gravity of the produced mixture to be greater than about 25 degrees API by controlling average pressure and average temperature in the selected section such that the average pressure in the selected section is greater than the pressure (p) set forth in the following equation for an assessed average temperature (T) in the selected section:
p = e [-44000/T + 67]
where p is measured in psia and T is measured in ~ Kelvin.
546. The method of claim 545, wherein the API gravity of the produced mixture is controlled to be greater than about 30 degrees API, and wherein the equation is:
p = e[-31000/T + 51]
547. The method of claim 545, wherein the API gravity of the produced mixture is controlled to be greater than about 35 degrees API, and wherein the equation is:
p = e [-22000/T + 38]
548. The method of claim 545, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
549. The method of claim 545, wherein controlling the average temperature comprises maintaining a temperature in the selected section within a pyrolysis temperature range.
550. The method of claim 545, wherein the one or more heat sources comprise electrical heaters.
551. The method of claim 545, wherein the one or more heat sources comprise surface burners.
552. The method of claim 545, wherein the one or more heat sources comprise flameless distributed combustors.
553. The method of claim 545, wherein the one or more heat sources comprise natural distributed combustors.
554. The method of claim 545, further comprising controlling a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
555. The method of claim 545, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
556. The method of claim 545, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
557. The method of claim 545, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
558. The method of claim 545, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
559. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
560. The method of claim 545, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
561. The method of claim 545, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
562. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
563. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
564. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
565. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
566. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
567. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
568. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
569. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
570. The method of claim 545, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
571. The method of claim 545, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
572. The method of claim 545, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
573. The method of claim 545, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
574. The method of claim 545, wherein a partial pressure of H2 is measured when the mixture is at a production well.
575. The method of claim 545, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
576. The method of claim 545, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
577. The method of claim 545, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
578. The method of claim 545, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
579. The method of claim 545, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
580. The method of claim 545, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
581. The method of claim 545, wherein the heat is controlled to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
582. The method of claim 545, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
583. The method of claim 582, wherein at least about 20 heat sources are disposed in the formation for each production well.
584. The method of claim 545, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
585. The method of claim 545, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
586. A method of treating an oil shale formation in situ, comprising:
providing heat to at least a portion of an oil shale formation such that a temperature (T) in a substantial part of the heated portion exceeds 270 °C and hydrocarbons are pyrolyzed within the heated portion of the formation;
controlling a pressure (p) within at least a substantial part of the heated portion of the formation;
wherein p bar > e [(-A/T)+B-2.6744];
wherein p is the pressure in bars absolute and T is the temperature in degrees K, and A and B are parameters that are larger than 10 and are selected in relation to the characteristics and composition of the oil shale formation and on the required olefin content and carbon number of the pyrolyzed hydrocarbon fluids; and producing pyrolyzed hydrocarbon fluids from the heated portion of the formation.
587. The method of claim 586, wherein A is greater than 14000 and B is greater than about 25 and a majority of the produced pyrolyzed hydrocarbon fluids have an average carbon number lower than 25 and comprise less than about 10 % by weight of olefins.
588. The method of claim 586, wherein T is less than about 390 °C, p is greater than about 1.4 bars, A is greater than about 44000, and b is greater than about 67, and a majority of the produced pyrolyzed hydrocarbon fluids have an average carbon number less than 25 and comprise less than 10 % by weight of olefins.
589. The method of claim 586, wherein T is less than about 390 °C, p is greater than about 2 bars, A is less than about 57000, and b is less than about 83, and a majority of the produced pyrolyzed hydrocarbon fluids have an average carbon number lower than about 21.
590. The method of claim 586, further comprising controlling the heat such that an average heating rate of the heated portion is less than about 3°C per day during pyrolysis.
591. The method of claim 586, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
592. The method of claim 586, wherein heat is transferred substantially by conduction from the one or more heat sources to the heated portion of the formation.
593. The method of claim 586, wherein heat is transferred substantially by conduction from the one or more heat sources to the heated portion of the formation such that the thermal conductivity of at least part of the heated portion is substantially uniformly modified to a value greater than about 0.6 W/m °C and the permeability of said part increases substantially uniformly to a value greater than 1 Darcy.
594. The method of claim 586, further comprising controlling formation conditions to produce a mixture of hydrocarbon fluids and H2, wherein a partial pressure of H2 within the mixture flowing through the formation is greater than 0.5 bars.
595. The method of claim 594, further comprising, hydrogenating a portion of the produced pyrolyzed hydrocarbon fluids with at least a portion of the produced hydrogen and heating the fluids with heat from hydrogenation.
596. The method of claim 586, wherein the substantially gaseous pyrolyzed hydrocarbon fluids are produced from a production well, the method further comprising heating a wellbore of the production well to inhibit condensation of the hydrocarbon fluids within the wellbore.
597. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation to raise an average temperature within the selected section to, or above, a temperature that will pyrolyze hydrocarbons within the selected section;
producing a mixture from the formation; and controlling a weight percentage of olefins of the produced mixture to be less than about 20 % by weight by controlling average pressure and average temperature in the selected section such that the average pressure in the selected section is greater than the pressure (p) set forth in the following equation for an assessed average temperature (T) in the selected section:
p = e [-57000/T + 83]
where p is measured in psia and T is measured in ° Kelvin.
598. The method of claim 597, wherein the weight percentage of olefins of the produced mixture is controlled to be less than about 10 % by weight, and wherein the equation is:
p = e [-16000/T + 28].
599. The method of claim 597, wherein the weight percentage of olefins of the produced mixture is controlled to be less than about 5 % by weight, and wherein the equation is:
p = e [-12000/T + 22].
600. The method of claim 597, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
601. The method of claim 597, wherein the one or more heat sources comprise electrical heaters.
602. The method of claim 597, wherein the one or more heat sources comprise surface burners.
603. The method of claim 597, wherein the one or more heat sources comprise flameless distributed combustors.
604. The method of claim 597, wherein the one or more heat sources comprise natural distributed combustors.
605. The method of claim 597, further comprising controlling a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
606. The method of claim 605, wherein controlling an average temperature comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
607. The method of claim 597, further comprising controlling the heat such that an average heating rate of the selected section is less than about 3.0 °C per day during pyrolysis.
608. The method of claim 597, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
609. The method of claim 597, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
610. The method of claim 597, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
611. The method of claim 597, wherein providing heat from the one or more heat sources comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
612. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
613. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
614. The method of claim 597, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
615. The method of claim 597, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
616. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
617. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
618. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
619. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
620. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
621. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
622. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
623. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
624. The method of claim 597, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
625. The method of claim 597, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
626. The method of claim 597, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
627. The method of claim 597, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
628. The method of claim 597, wherein a partial pressure of H2 is measured when the mixture is at a production well.
629. The method of claim 597, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
630. The method of claim 597, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
631. The method of claim 597, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
632. The method of claim 597, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
633. The method of claim 597, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
634. The method of claim 597, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
635. The method of claim 597, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
636. The method of claim 597, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
637. The method of claim 636, wherein at least about 20 heat sources are disposed in the formation for each production well.
638. The method of claim 597, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
639. The method of claim 597, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
640. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation to raise an average temperature within the selected section to, or above, a temperature that will pyrolyze hydrocarbons within the selected section;
producing a mixture from the formation; and controlling hydrocarbons having carbon numbers greater than 25 of the produced mixture to be less than about 25 % by weight by controlling average pressure and average temperature in the selected section such that the average pressure in the selected section is greater than the pressure (p) set forth in the following equation for an assessed average temperature (T) in the selected section:
p = e [-14000/T + 25]
where p is measured in psia and T is measured in ° Kelvin.
641. The method of claim 640, wherein the hydrocarbons having carbon numbers greater than 25 of the produced mixture is controlled to be less than about 20 % by weight, and wherein the equation is:
p = e [-16000/T + 28].
642. The method of claim 640, wherein the hydrocarbons having carbon numbers greater than 25 of the produced mixture is controlled to be less than about 15 % by weight, and wherein the equation is:
p = e[-18000/T + 32].
643. The method of claim 640, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
644. The method of claim 640, wherein the one or more heat sources comprise electrical heaters.
645. The method of claim 640, wherein the one or more heat sources comprise surface burners.
646. The method of claim 640, wherein the one or more heat sources comprise flameless distributed combustors.
647. The method of claim 640, wherein the one or more heat sources comprise natural distributed combustors.
648. The method of claim 640, further comprising controlling a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
649. The method of claim 648, wherein controlling the temperature comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
650. The method of claim 640, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
651. The method of claim 640, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v,*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
652. The method of claim 640, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
653. The method of claim 640, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
654. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
655. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
656. The method of claim 640, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
657. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
658. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
659. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
660. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
661. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
662. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
663. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
664. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
665. The method of claim 640, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
666. The method of claim 640, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
667. The method of claim 640, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
668. The method of claim 640, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
669. The method of claim 640, wherein a partial pressure of H2 is measured when the mixture is at a production well.
670. The method of claim 640, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
671. The method of claim 640, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
672. The method of claim 640, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
673. The method of claim 640, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
674. The method of claim 640, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
675. The method of claim 640, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
676. The method of claim 640, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
677. The method of claim 676, wherein at least about 20 heat sources are disposed in the formation for each production well.
678. The method of claim 640, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
679. The method of claim 640, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
680. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation to raise an average temperature within the selected section to, or above, a temperature that will pyrolyze hydrocarbons within the selected section;
producing a mixture from the formation; and controlling an atomic hydrogen to carbon ratio of the produced mixture to be greater than about 1.7 by controlling average pressure and average temperature in the selected section such that the average pressure in the selected section is greater than the pressure (p) set forth in the following equation for an assessed average temperature (T) in the selected section:
p = e[-38000/T + 61]
where p is measured in psia and T is measured in ° Kelvin.
681. The method. of claim 680, wherein the atomic hydrogen to carbon ratio of the produced mixture is controlled to be greater than about 1.8, and wherein the equation is:
p = e[-13000/T + 24].
682. The method of claim 680, wherein the atomic hydrogen to carbon ratio of the produced mixture is controlled to be greater than about 1.9, and wherein the equation is:
p = e[-8000/T + 18]
683. The method of claim 680, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
684. The method of claim 680, wherein the one or more heat sources comprise electrical heaters.
685. The method of claim 680, wherein the one or more heat sources comprise surface burners.
686. The method of claim 680, wherein the one or more heat sources comprise flameless distributed combustors.
687. The method of claim 680, wherein the one or more heat sources comprise natural distributed combustors.
688. The method of claim 680, further comprising controlling a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
689. The method of claim 688, wherein controlling the temperature comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
690. The method of claim 680, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
691. The method of claim 680, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
692. The method of claim 680, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
693. The method of claim 680, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
694. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
695. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
696. The method of claim 680, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
697. The method of claim 680, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
698. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
699. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
700. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
701. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
702. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
703. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises mufti-ring aromatics with more than two rings.
704. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
705. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
706. The method of claim 680, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
707. The method of claim 680, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
708. The method of claim 680, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
709. The method of claim 680, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
710. The method of claim 680, wherein a partial pressure of H2 is measured when the mixture is at a production well.
711. The method of claim 680, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
712. The method of claim 680, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
713. The method of claim 680, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
714. The method of claim 680, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
715. The method of claim 680, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
716. The method of claim 680, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
717. The method of claim 680, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
718. The method of claim 680, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
719. The method of claim 718, wherein at least about 20 heat sources are disposed in the formation for each production well.
720. The method of claim 680, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
721. The method of claim 680, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
722. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least one portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
controlling a pressure-temperature relationship within at least the selected section of the formation by selected energy input into the one or more heat sources and by pressure release from the selected section through wellbores of the one or more heat sources; and producing a mixture from the formation.
723. The method of claim 722, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
724. The method of claim 722, wherein the one or more heat sources comprise at least two heat sources.
725. The method of claim 722, wherein the one or more heat sources comprise surface burners.
726. The method of claim 722, wherein the one or more heat sources comprise flameless distributed combustors.
727. The method of claim 722, wherein the one or more heat sources comprise natural distributed combustors.
728. The method of claim 722, further comprising controlling the pressure-temperature relationship by controlling a rate of removal of fluid from the formation.
729. The method of claim 722, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
730. The method of claim 722, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10°C/day.
731. The method of claim 722, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
732. The method of claim 722, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
733. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
734. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
735. The method of claim 722, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
736. The method of claim 722, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
737. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
738. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
739. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
740. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
741. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
742. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
743. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
744. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
745. The method of claim 722, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
746. The method of claim 722, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
747. The method of claim 722, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
748. The method of claim 722, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
749. The method of claim 722, further comprising controlling formation conditions to produce a mixture of hydrocarbon fluids and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
750. The method of claim 722, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
751. The method of claim 722, wherein a partial pressure of H2 is measured when the mixture is at a production well.
752. The method of claim 722, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
753. The method of claim 722, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
754. The method of claim 722, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
755. The method of claim 722, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
756. The method of claim 722, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
757. The method of claim 722, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
758. The method of claim 722, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
759. The method of claim 722, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
760. The method of claim 759, wherein at least about 20 heat sources are disposed in the formation for each production well.
761. The method of claim 722, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
762. The method of claim 722, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
763. A method of treating an oil shale formation in situ, comprising:
heating a selected volume (V) of the oil shale formation, wherein formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
764. The method of claim 763, wherein heating a selected volume comprises heating with an electrical heater.
765. The method of claim 763, wherein heating a selected volume comprises heating with a surface burner.
766. The method of claim 763, wherein heating a selected volume comprises heating with a flameless distributed combustor.
767. The method of claim 763, wherein heating a selected volume comprises heating with at least one natural distributed combustor.
768. The method of claim 763, further comprising controlling a pressure and a temperature within at least a majority of the selected volume of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
769. The method of claim 763, further comprising controlling the heating such that an average heating rate of the selected volume is less than about 1 °C per day during pyrolysis.
770. The method of claim 763, wherein a value for C v is determined as an average heat capacity of two or more samples taken from the oil shale formation.
771. The method of claim 763, wherein heating the selected volume comprises transferring heat substantially by conduction.
772. The method of claim 763, wherein heating the selected volume comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
773. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
774. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
775. The method of claim 763, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
776. The method of claim 763, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
777. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
778. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
779. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
780. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
781. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
782. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
783. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
784. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
785. The method of claim 763, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
786. The method of claim 763, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
787. The method of claim 763, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer 788. The method of claim 763, further comprising controlling a pressure within at least a majority of the selected volume of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
789. The method of claim 763, further comprising controlling formation conditions to produce a mixture from the formation comprising condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
790. The method of claim 763, wherein a partial pressure of H2 is measured when the mixture is at a production well.
791. The method of claim 763, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
792. The method of claim 763, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
793. The method of claim 763, further comprising:
providing hydrogen (H2) to the heated volume to hydrogenate hydrocarbons within the volume; and heating a portion of the volume with heat from hydrogenation:
794. The method of claim 763, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
795. The method of claim 763, further comprising increasing a permeability of a majority of the selected volume to greater than about 100 millidarcy.
796. The method of claim 763, further comprising substantially uniformly increasing a permeability of a majority of the selected volume.
797. The method of claim 763, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
798. The method of claim 763, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
799. The method of claim 798, wherein at least about 20 heat sources are disposed in the formation for each production well.
800. The method of claim 763, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
801. The method of claim 763, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
802. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation to raise an average temperature within the selected section to, or above, a temperature that will pyrolyze hydrocarbons within the selected section;
controlling heat output from the one or more heat sources such that an average heating rate of the selected section rises by less than about 3 °C per day when the average temperature of the selected section is at, or above, the temperature that will pyrolyze hydrocarbons within the selected section; and producing a mixture from the formation.
803. The method of claim 802, wherein controlling heat output comprises:
raising the average temperature within the selected section to a first temperature that is at or above a minimum pyrolysis temperature of hydrocarbons within the formation;
limiting energy input into the one or more heat sources to inhibit increase in temperature of the selected section; and increasing energy input into the formation to raise an average temperature of the selected section above the first temperature when production of formation fluid declines below a desired production rate.
804. The method of claim 802, wherein controlling heat output comprises:
raising the average temperature within the selected section to a first temperature that is at or above a minimum pyrolysis temperature of hydrocarbons within the formation;
limiting energy input into the one or more heat sources to inhibit increase in temperature of the selected section; and increasing energy input into the formation to raise an average temperature of the selected section above the first temperature when quality of formation fluid produced from the formation falls below a desired quality.
805. The method of claim 802, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section.
806. The method of claim 802, wherein the one or more heat sources comprise electrical heaters.
807. The method of claim 802, wherein the one or more heat sources comprise surface burners.
808. The method of claim 802, wherein the one or more heat sources comprise flameless distributed combustors.
809. The method of claim 802, wherein the one or more heat sources comprise natural distributed combustors.
810. The method of claim 802, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
811. The method of claim 802, wherein the heat is controlled such that an average heating rate of the selected section is less than about 1.5 °C per day during pyrolysis.
812. The method of claim 802, wherein the heat is controlled such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
813. The method of claim 802, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho. B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density.
814. The method of claim 802, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
815. The method of claim 802, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
816. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
817. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
818. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, wherein the condensable hydrocarbons have an olefin content is less than about 2.5 %
by weight of the condensable hydrocarbons, and wherein the olefin content is greater than about 0.1 % by weight of the condensable hydrocarbons.
819. The method of claim 802, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
820. The method of claim 802, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.10 and wherein the ratio of ethene to ethane is greater than about 0.001.
821. The method of claim 802, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.05 and wherein the ratio of ethene to ethane is greater than about 0.001.
822. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
823. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
824. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
825. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
826. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
827. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
828. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
829. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
830. The method of claim 802, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
831. The method of claim 802, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
832. The method of claim 802, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
833. The method of claim 802, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
834. The method of claim 802, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
835. The method of claim 802, wherein a partial pressure of H2 is measured when the mixture is at a production well.
836. The method of claim 802, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
837. The method of claim 802, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
838. The method of claim 802, further comprising:
providing H2 to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
839. The method of claim 802, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
840. The method of claim 802, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
841. The method of claim 802, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
842. The method of claim 802, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
843. The method of claim 802, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
844. The method of claim 843, wherein at least about 20 heat sources are disposed in the formation for each production well.
845. The method of claim 802, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
846. The method of claim 802, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
847. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation; to heat a selected section of the formation to an average temperature above about 270 °C;
allowing the heat to transfer from the one or more heat sources to the selected section of the formation;
controlling the heat from the one or more heat sources such that an average heating rate of the selected section is less than about 3 °C per day during pyrolysis; and producing a mixture from the formation.
848. The method of claim 847, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
849. The method of claim 847, wherein the one or more heat sources comprise electrical heaters.
850. The method of claim 847, further comprising supplying electricity to the electrical heaters substantially during non-peak hours.
851. The method of claim 847, wherein the one or more heat sources comprise surface burners.
852. The method of claim 847, wherein the one or more heat sources comprise flameless distributed combustors.
853. The method of claim 847, wherein the one or more heat sources comprise natural distributed combustors.
854. The method of claim 847, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
855. The method of claim 847, wherein the heat is further controlled such that an average heating rate of the selected section is less than about 3 °C/day until production of condensable hydrocarbons substantially ceases.
856. The method of claim 847, wherein the heat is further controlled such that an average heating rate of the selected section is less than about 1.5 °C per day during pyrolysis.
857. The method of claim 847, wherein the heat is further controlled such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
858. The method of claim 847, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density.
859. The method of claim 847, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
860. The method of claim 847, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
861. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
862. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
863. The method of claim 847, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
864. The method of claim 847, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
865. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
866. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
867. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
868. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
869. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
870. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
871. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
872. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
873. The method of claim 847, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
874. The method of claim 847, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
875. The method of claim 847, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
876. The method of claim 847, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
877. The method of claim 847, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
878. The method of claim 877, wherein the partial pressure of H2 is measured when the mixture is at a production well.
879. The method of claim 847, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
880. The method of claim 847, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
881. The method of claim 847, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
882. The method of claim 847, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
883. The method of claim 847, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
884. The method of claim 847, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
885. The method of claim 847, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
886. The method of claim 847, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
887. The method of claim 886, wherein at least about 20 heat sources are disposed in the formation for each production well.
888. The method of claim 847, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
889. The method of claim 847, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
890. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
producing a mixture from the formation through at least one production well;
monitoring a temperature at or in the production well; and controlling heat input to raise the monitored temperature at a rate of less than about 3 °C per day.
891. The method of claim 890, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
892. The method of claim 890, wherein the one or more heat sources comprise electrical heaters.
893. The method of claim 890, wherein the one or more heat sources comprise surface burners.
894. The method of claim 890, wherein the one or more heat sources comprise flameless distributed combustors.
895. The method of claim 890, wherein the one or more heat sources comprise natural distributed combustors.
896. The method of claim 890, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
897. The method of claim 890, wherein the heat is controlled such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
898. The method of claim 890, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density.
899. The method of claim 890, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
900. The method of claim 890, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
901. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
902. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
903. The method of claim 890, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
904. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
905. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
906. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
907. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
908. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
909. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
910. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
911. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
912. The method of claim 890, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
913. The method of claim 890, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
914. The method of claim 890, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
915. The method of claim 890, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
916. The method of claim 890, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
917. The method of claim 916, wherein the partial pressure of H2 is measured when the mixture is at a production well.
918. The method of claim 890, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
919. The method of claim 890, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
920. The method of claim 890, further comprising:
providing H2 to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
921. The method of claim 890, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
922. The method of claim 890, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
923. The method of claim 890, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
924. The method of claim 890, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
925. The method of claim 890, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
926. The method of claim 925, wherein at least about 20 heat sources are disposed in the formation for each production well.
927. The method of claim 890, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
928. The method of claim 890, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
929. A method of treating an oil shale formation in situ, comprising:
heating a portion of the formation to a temperature sufficient to support oxidation of hydrocarbons within the portion, wherein the portion is located substantially adjacent to a wellbore;
flowing an oxidant through a conduit positioned within the wellbore to a heat source zone within the portion, wherein the heat source zone supports an oxidation reaction between hydrocarbons and the oxidant;
reacting a portion of the oxidant with hydrocarbons to generate heat; and transferring generated heat substantially by conduction to a pyrolysis zone of the formation to pyrolyze at least a portion of the hydrocarbons within the pyrolysis zone.
930. The method of claim 929, wherein heating the portion of the formation comprises raising a temperature of the portion above about 400 °C.
931. The method of claim 929, wherein the conduit comprises critical flow orifices, the method further comprising flowing the oxidant through the critical flow orifices to the heat source zone.
932. The method of claim 929, further comprising removing reaction products from the heat source zone through the wellbore.
933. The method of claim 929, further comprising removing excess oxidant from the heat source zone to inhibit transport of the oxidant to the pyrolysis zone.
934. The method of claim 929, further comprising transporting the oxidant from the conduit to the heat source zone substantially by diffusion.
935. The method of claim 929, further comprising heating the conduit with reaction products being removed through the wellbore.
936. The method of claim 929, wherein the oxidant comprises hydrogen peroxide.
937. The method of claim 929, wherein the oxidant comprises air.
938. The method of claim 929, wherein the oxidant comprises a fluid substantially free of nitrogen.
939. The method of claim 929, further comprising limiting an amount of oxidant to maintain a temperature of the heat source zone less than about 1200 °C.
940. The method of claim 929, wherein heating the portion of the formation comprises electrically heating the formation.
941. The method of claim 929, wherein heating the portion of the formation comprises heating the portion using exhaust gases from a surface burner.
942. The method of claim 929, wherein heating the portion of the formation comprises heating the portion with a flameless distributed combustor.
943. The method of claim 929, further comprising controlling a pressure and a temperature within at least a majority of the pyrolysis zone, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
944. The method of claim 929, further comprising controlling the heat such that an average heating rate of the pyrolysis zone is less than about 1 °C per day during pyrolysis., 945. The method of claim 929, wherein heating the portion comprises heating the pyrolysis zone such that a thermal conductivity of at least a portion of the pyrolysis zone is greater than about 0.5 W/(m °C).
946. The method of claim 929, further comprising controlling a pressure within at least a majority of the pyrolysis zone of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
947. The method of claim 929, further comprising:
providing hydrogen (H2) to the pyrolysis zone to hydrogenate hydrocarbons within the pyrolysis zone; and heating a portion of the pyrolysis zone with heat from hydrogenation.
948. The method of claim 929, wherein transferring generated heat comprises increasing a permeability of a majority of the pyrolysis zone to greater than about 100 millidarcy.
949. The method of claim 929, wherein transferring generated heat comprises substantially uniformly increasing a permeability of a majority of the pyrolysis zone.
950. The method of claim 929, wherein the heating is controlled to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
951. The method of claim 929, wherein the wellbore is located along strike to reduce pressure differentials along a heated length of the wellbore.
952. The method of claim 929, wherein the wellbore is located along strike to increase uniformity of heating along a heated length of the wellbore.
953. The method of claim 929, wherein the wellbore is located along strike to increase control of heating along a heated length of the wellbore.
954. A method of treating an oil shale formation in situ, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidant;
flowing the oxidant into a conduit, and wherein the conduit is connected such that the oxidant can flow from the conduit to the hydrocarbons;
allowing the oxidant and the hydrocarbons to react to produce heat in a heat source zone;
allowing heat to transfer from the heat source zone to a pyrolysis zone in the formation to pyrolyze at least a portion of the hydrocarbons within the pyrolysis zone; and removing reaction products such that the reaction products are inhibited from flowing from the heat source zone to the pyrolysis zone.
955. The method of claim 954, wherein heating the portion of the formation comprises raising the temperature of the portion above about 400 °C.
956. The method of claim 954, wherein heating the portion of the formation comprises electrically heating the formation.
957. The method of claim 954, wherein heating the portion of the formation comprises heating the portion using exhaust gases from a surface burner.
958. The method of claim 954, wherein the conduit comprises critical flow orifices, the method further comprising flowing the oxidant through the critical flow orifices to the heat source zone.
959. The method of claim 954, wherein the conduit is located within a wellbore, wherein removing reaction products comprises removing reaction products from the heat source zone through the wellbore.
960. The method of claim 954, further comprising removing excess oxidant from the heat source zone to inhibit transport of the oxidant to the pyrolysis zone.
961. The method of claim 954, further comprising transporting the oxidant from the conduit to the heat source zone substantially by diffusion.
962. The method of claim 954, wherein the conduit is located within a wellbore, the method further comprising heating the conduit with reaction products being removed through the wellbore to raise a temperature of the oxidant passing through the conduit.
963. The method of claim 954, wherein the oxidant comprises hydrogen peroxide.
964. The method of claim 954, wherein the oxidant comprises air.
965. The method of claim 954, wherein the oxidant comprises a fluid substantially free of nitrogen.
966. The method of claim 954, further comprising limiting an amount of oxidant to maintain a temperature of the heat source zone less than about 1200 °C.
967. The method of claim 954, further comprising limiting an amount of oxidant to maintain a temperature of the heat source zone at a temperature that inhibits production of oxides of nitrogen.
968. The method of claim 954, wherein heating a portion of the formation to a temperature sufficient to support oxidation of hydrocarbons within the portion further comprises heating with a flameless distributed combustor.
969. The method of claim 954, further comprising controlling a pressure and a temperature within at least a majority of the pyrolysis zone of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
970. The method of claim 954, further comprising controlling the heat such that an average heating rate of the pyrolysis zone is less than about 1 °C per day during pyrolysis.
971. The method of claim 954, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
972. The method of claim 954, wherein allowing heat to transfer comprises heating the pyrolysis zone such that a thermal conductivity of at least a portion of the pyrolysis zone is greater than about 0.5 W/(m °C).
973. The method of claim 954, further comprising controlling a pressure within at least a majority of the pyrolysis zone, wherein the controlled pressure is at least about 2.0 bars absolute.
974. The method of claim 954, further comprising:
providing hydrogen (H2) to the pyrolysis zone to hydrogenate hydrocarbons within the pyrolysis zone; and heating a portion of the pyrolysis zone with heat from hydrogenation.
975. The method of claim 954, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the pyrolysis zone to greater than about 100 millidarcy.
976. The method of claim 954, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the pyrolysis zone.
977. The method of claim 954, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
978. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein the portion is located substantially adjacent to an opening in the formation;
providing the oxidizing fluid to a heat source zone in the formation;
allowing the oxidizing gas to react with at least a portion of the hydrocarbons at the heat source zone to generate heat in the heat source zone; and transferring the generated heat substantially by conduction from the heat source zone to a pyrolysis zone in the formation.
979. The method of claim 978, further comprising transporting the oxidizing fluid through the heat source zone by diffusion.
980. The method of claim 978, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a conduit disposed in the opening.
981. The method of claim 978, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a conduit disposed in the opening such that a rate of oxidation is controlled.
982. The method of claim 978, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit.
983. The method of claim 978, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and transferring substantial heat from the oxidation product in the conduit to the oxidizing fluid in the conduit.
984. The method of claim 978, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
985. The method of claim 978, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
986. The method of claim 978, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the outer conduit.
987. The method of claim 978, wherein the heat source zone extends radially from the opening a width of less than approximately 0.15 m.
988. The method of claim 978, wherein heating the portion comprises applying electrical current to an electric heater disposed within the opening.
989. The method of claim 978, wherein the pyrolysis zone is substantially adjacent to the heat source zone.
990. The method of claim 978, further comprising controlling a pressure and a temperature within at least a majority of the pyrolysis zone of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
991. The method of claim 978, further comprising controlling the heat such that an average heating rate of the pyrolysis zone is less than about 1 °C per day during pyrolysis.
992. The method of claim 978, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
993. The method of claim 978, wherein allowing heat to transfer comprises heating the portion such that a thermal conductivity of at least a portion of the pyrolysis zone is greater than about 0.5 W/(m °C).
994. The method of claim 978, further comprising controlling a pressure within at least a majority of the pyrolysis zone, wherein the controlled pressure is at least about 2.0 bars absolute.
995. The method of claim 978, further comprising:
providing hydrogen (H2) to the pyrolysis zone to hydrogenate hydrocarbons within the pyrolysis zone; and heating a portion of the pyrolysis zone with heat from hydrogenation.
996. The method of claim 978, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the pyrolysis zone to greater than about 100 millidarcy.
997. The method of claim 978, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the pyrolysis zone.
998. The method of claim 978, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
999. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
producing a mixture from the formation; and maintaining an average temperature within the selected section above a minimum pyrolysis temperature and below a vaporization temperature of hydrocarbons having carbon numbers greater than 25 to inhibit production of a substantial amount of hydrocarbons having carbon numbers greater than 25 in the mixture.
1000. The method of claim 999, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1001. The method of claim 999, wherein maintaining the average temperature within the selected section comprises maintaining the temperature within a pyrolysis temperature range.
1002. The method of claim 999, wherein the one or more heat sources comprise electrical heaters.
1003. The method of claim 999, wherein the one or more heat sources comprise surface burners.
1004. The method of claim 999, wherein the one or more heat sources comprise flameless distributed combustors.
1005. The method of claim 999, wherein the one or more heat sources comprise natural distributed combustors.
1006. The method of claim 999, wherein the minimum pyrolysis temperature is greater than about 270 °C.
1007. The method of claim 999, wherein the vaporization temperature is less than approximately 450 °C at atmospheric pressure.
1008. The method of claim 999, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1009. The method of claim 999, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1010. The method of claim 999, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1011. The method of claim 999, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1012. The method of claim 999, wherein providing heat from the one or more heat sources comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
WHAT IS CLAIMED IS:
1. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least one portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
controlling the heat from the one or more heat sources such that an average temperature within at least a majority of the selected section of the formation is less than about 375 °C; and producing a mixture from the formation.
2. The method of claim 1, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
3. The method of claim 1, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
4. The method of claim 1, wherein the one or more heat sources comprise electrical heaters.
5. The method of claim 1, wherein the one or more heat sources comprise surface burners.
6. The method of claim 1, wherein the one or more heat sources comprise flameless distributed combustors.
7. The method of claim 1, wherein the one or more heat sources comprise natural distributed combustors.
8. The method of claim 1, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
9. The method of claim 1, further comprising controlling a pressure within at least a majority of the selected section of the formation with a valve coupled to at least one of the one or more heat sources.
10. The method of claim 1, further comprising controlling a pressure within at least a majority of the selected section of the formation with a valve coupled to a production well located in the formation.
11. The method of claim 1, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
12. The method of claim 1, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
1024. The method of claim 999, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1025. The method of claim 999, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1026. The method of claim 999, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1027. The method of claim 999, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1028. The method of claim 999, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1029. The method of claim 999, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1030. The method of claim 1029, wherein the partial pressure of H2 is measured when the mixture is at a production well.
1031. The method of claim 999, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1032. The method of claim 999, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1033. The method of claim 999, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1034. The method of claim 999, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1035. The method of claim 999, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1036. The method of claim 999, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1037. The method of claim 999, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1038. The method of claim 1037, wherein at least about 20 heat sources are disposed in the formation for each production well.
1039. The method of claim 999, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1040. The method of claim 999, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1041. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
controlling a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than 25; and producing a mixture from the formation.
1042. The method of claim 1041, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1043. The method of claim 1041, wherein the one or more heat sources comprise electrical heaters.
1044. The method of claim 1041, wherein the one or more heat sources comprise surface burners.
1045. The method of claim 1041, wherein the one or more heat sources comprise flameless distributed combustors.
1046. The method of claim 1041, wherein the one or more heat sources comprise natural distributed combustors.
1047. The method of claim 1041, further comprising controlling a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1048. The method of claim 1047, wherein controlling the temperature comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
1049. The method of claim 1041, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1050. The method of claim 1041, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1051. The method of claim 1041, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1052. The method of claim 1041, wherein providing heat from the one or more heat sources comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1053. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1054. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1055. The method of claim 1041, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
1056. The method of claim 1041, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
1057. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1058. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1059. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1060. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1061. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1062. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1063. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1064. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1065. The method of claim 1041, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1066. The method of claim 1041, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1067. The method of claim 1041, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1068. The method of claim 1041, further comprising controlling the pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1069. The method of claim 1041, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1070. The method of claim 1069, wherein the partial pressure of H2 is measured when the mixture is at a production well.
1071. The method of claim 1041, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1072. The method of claim 1041, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1073. The method of claim 1041, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1074. The method of claim 1041, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1075. The method of claim 1041, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1076. The method of claim 1041, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1077. The method of claim 1041, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1078. The method of claim 1077, wherein at least about 20 heat sources are disposed in the formation for each production well.
1079. The method of claim 1041, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1080. The method of claim 1041, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1081. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1082. The method of claim 1081, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1083. The method of claim 1081, wherein the one or more heat sources comprise electrical heaters.
1084. The method of claim 1081, wherein the one or more heat sources comprise surface burners.
1085. The method of claim 1081, wherein the one or more heat sources comprise flameless distributed combustors.
1086. The method of claim 1081, wherein the one or more heat sources comprise natural distributed combustors.
1087. The method of claim 1081, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1088. The method of claim 1081, wherein controlling the temperature comprises maintaining the temperature within the selected section within a pyrolysis temperature range.
1089. The method of claim 1081, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1090. The method of claim 1081, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1091. The method of claim 1081, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1092. The method of claim 1081, wherein providing heat from the one or more heat sources comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1093. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1094. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1095. The method of claim 1081, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
1096. The method of claim 1081, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
1097. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1098. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1099. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1100. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1101. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1102. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1103. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1104. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1105. The method of claim 1081, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1106. The method of claim 1081, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1107. The method of claim 1081, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1108. The method of claim 1081, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1109. The method of claim 1081, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1110. The method of claim 1109, wherein the partial pressure of H2 is measured when the mixture is at a production well.
1111. The method of claim 1081, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1112. The method of claim 1081, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1113. The method of claim 1081, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1114. The method of claim 1081, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1115. The method of claim 1081, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1116. The method of claim 1081, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1117. The method of claim 1081, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1118. The method of claim 1081, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1119. The method of claim 1118, wherein at least about 20 heat sources are disposed in the formation for each production well.
1120. The method of claim 1081, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1121. The method of claim 1081, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1122. A method of treating an oil shale formation in situ, comprising:
heating a section of the formation to a pyrolysis temperature from at least a first heat source, a second heat source and a third heat source, and wherein the first heat source, the second heat source and the third heat source are located along a perimeter of the section;
controlling heat input to the first heat source, the second heat source and the third heat source to limit a heating rate of the section to a rate configured to produce a mixture from the formation with an olefin content of less than about 15% by weight of condensable fluids (on a dry basis) within the produced mixture; and producing the mixture from the formation through a production well.
1123. The method of claim 1122, wherein superposition of heat form the first heat source, second heat source, and third heat source pyrolyzes. a portion of the hydrocarbons within the formation to fluids.
1124. The method of claim 1122, wherein the pyrolysis temperature is between about 270 °C and about 400 °C.
1125. The method of claim 1122, wherein the first heat source is operated for less than about twenty-four hours a day.
1126. The method of claim 1122, wherein the first heat source comprises an electrical heater.
1127. The method of claim 1122, wherein the first heat source comprises a surface burner.
1128. The method of claim 1122, wherein the first heat source comprises a flameless distributed combustor.
1129. The method of claim 1122, wherein the first heat source, second heat source and third heat source are positioned substantially at apexes of an equilateral triangle.
1130. The method of claim 1122, wherein the production well is located substantially at a geometrical center of the first heat source, second heat source, and third heat source.
1131. The method of claim 1122, further comprising a fourth heat source, fifth heat source, and sixth heat source located along the perimeter of the section.
1132. The method of claim 1131, wherein the heat sources are located substantially at apexes of a regular hexagon.
1133. The method of claim 1132, wherein the production well is located substantially at a center of the hexagon.
1134. The method of claim 1122, further comprising controlling a pressure and a temperature within at least a majority of the section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1135. The method of claim 1122, wherein controlling the temperature comprises maintaining the temperature within the selected section within a pyrolysis temperature range.
1136. The method of claim 1122, further comprising controlling the heat such that an average heating rate of the section is less than about 3 °C per day during pyrolysis.
1137. The method of claim 1122, further comprising controlling the heat such that an average heating rate of the section is less than about 1 °C per day during pyrolysis.
1138. The method of claim 1122, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1139. The method of claim 1122, wherein heating the section of the formation comprises transferring heat substantially by conduction.
1140. The method of claim 1122, wherein providing heat from the one or more heat sources comprises heating the section such that a thermal conductivity of at least a portion of the section is greater than about 0.5 W/(m °C).
1141. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1142. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1143. The method of claim 1122, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
1144. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1145. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
411~
1146. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1147. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1148. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1149. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1150. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1151. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1152. The method of claim 1122, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1153. The method of claim 1122, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1154. The method of claim 1122, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1155. The method of claim 1122, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1156. The method of claim 1122, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1157. The method of claim 1156, wherein the partial pressure of H2 is measured when the mixture is at a production well.
1158. The method of claim 1122, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1159. The method of claim 1122, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1160. The method of claim 1122, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1161. The method of claim 1122, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1162. The method of claim 1122, wherein heating the section comprises increasing a permeability of a majority of the section to greater than about 100 millidarcy.
1163. The method of claim 1122, wherein heating the section comprises substantially uniformly increasing a permeability of a majority of the section.
1164. The method of claim 1122, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1165. The method of claim 1122, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1166. The method of claim 1165, wherein at least about 20 heat sources are disposed in the formation for each production well.
1167. The method of claim 1122, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1168. The method of claim 1122, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1169. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1170. The method of claim 1169, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1171. The method of claim 1169, wherein the one or more heat sources comprise electrical heaters.
1172. The method of claim 1169, wherein the one or more heat sources comprise surface burners.
1173. The method of claim 1169, wherein the one or more heat sources comprise flameless distributed combustors.
1174. The method of claim 1169, wherein the one or more heat sources comprise natural distributed combustors.
1175. The method of claim 1169, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1176. The method of claim 1175, wherein controlling the temperature comprises maintaining the temperature within the selected section within a pyrolysis temperature range.
1177. The method of claim 1169, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1178. The method of claim 1169, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1179. The method of claim 1169, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1180. The method of claim 1169, wherein providing heat from the one or more heat sources comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1181. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1182. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1183. The method of claim 1169, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
1184. The method of claim 1169, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
1185. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1186. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1187. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1188. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1189. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1190. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1191. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1192. The method of claim 1169, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1193. The method of claim 1169, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1194. The method of claim 1169, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1195. The method of claim 1169, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1196. The method of claim 1169, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1197. The method of claim 1196, wherein the partial pressure of H2 is measured when the mixture is at a production well.
1198. The method of claim 1169, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1199. The method of claim 1169, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1200. The method of claim 1169, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1201. The method of claim 1169, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1202. The method of claim 1169, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1203. The method of claim 1169, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1204. The method of claim 1169, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1205. The method of claim 1169, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1206. The method of claim 1205, wherein at least about 20 heat sources are disposed in the formation for each production well.
1207. The method of claim 1169, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1208. The method of claim 1169, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1209. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1210. The method of claim 1209, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1211. The method of claim 1209, wherein the one or more heat sources comprise electrical heaters.
1212. The method of claim 1209, wherein the one or more heat sources comprise surface burners.
1213. The method of claim 1209, wherein the one or more heat sources comprise flameless distributed combustors.
1214. The method of claim 1209, wherein the one or more heat sources comprise natural distributed combustors.
1215. The method of claim 1209, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1216. The method of claim 1215, wherein controlling the temperature comprises maintaining the temperature within the selected section within a pyrolysis temperature range.
1217. The method of claim 1209, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1218. The method of claim 1209, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1219. The method of claim 1209, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1220. The method of claim 1209, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1221. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1222. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1% by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1223. The method of claim 1209, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
1224. The method of claim 1209, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
1225. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1226. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1227. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1228. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1229. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1230. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1231. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1232. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1233. The method of claim 1209, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1234. The method of claim 1209, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1235. The method of claim 1209, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1236. The method of claim 1209, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1237. The method of claim 1209, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1238. The method of claim 1237, wherein the partial pressure of H2 is measured when the mixture is at a production well.
1239. The method of claim 1209, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1240. The method of claim 1209, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1241. The method of claim 1209, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1242. The method of claim 1209, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1243. The method of claim 1209, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1244. The method of claim 1209, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1245. The method of claim 1209, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1246. The method of claim 1209, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1247. The method of claim 1246, wherein at least about 20 heat sources are disposed in the formation for each production well.
1248. The method of claim 1209, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1249. The method of claim 1209, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1250. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1251. The method of claim 1250, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1252. The method of claim 1250, wherein the one or more heat sources comprise electrical heaters.
1253. The method of claim 1250, wherein the one or more heat sources comprise surface burners.
1254. The method of claim 1250, wherein the one or more heat sources comprise flameless distributed combustors.
1255. The method of claim 1250, wherein the one or more heat sources comprise natural distributed combustors.
1256. The method of claim 1250, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1257. The method of claim 1256, wherein controlling the temperature comprises maintaining the temperature within the selected section within a pyrolysis temperature range.
1258. The method of claim 1250, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1259. The method of claim 1250, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1260. The method of claim 1250, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1261. The method of claim 1250, wherein providing heat from the one or more heat sources comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1262. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1263. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1264. The method of claim 1250, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
1265. The method of claim 1250, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
1266. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1267. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1268. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1269. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1270. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1271. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1272. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1273. The method of claim 1250, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1274. The method of claim 1250, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1275. The method of claim 1250, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1276. The method of claim 1250, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1277. The method of claim 1250, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1278. The method of claim 1277, wherein the partial pressure of H2 is measured when the mixture is at a production well.
1279. The method of claim 1250, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1280. The method of claim 1250, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1281. The method of claim 1250, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1282. The method of claim 1250, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1283. The method of claim 1250, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1284. The method of claim 1250, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1285. The method of claim 1250, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1286. The method of claim 1250, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1287. The method of claim 1286, wherein at least about 20 heat sources are disposed in the formation for each production well.
1288. The method of claim 1250, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1289. The method of claim 1250, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1290. A method of treating an oil shale formation in situ, comprising:
raising a temperature of a first section of the formation with one or more heat sources to a first pyrolysis temperature;
heating the first section to an upper pyrolysis temperature, wherein heat is supplied to the first section at a rate configured to inhibit olefin production;
producing a first mixture from the formation, wherein the first mixture comprises condensable hydrocarbons and H2;
creating a second mixture from the first mixture, wherein the second mixture comprises a higher concentration of H2 than the first mixture;
raising a temperature of a second section of the formation with one or more heat sources to a second pyrolysis temperature;
providing a portion of the second mixture to the second section;
heating the second section to an upper pyrolysis temperature, wherein heat is supplied to the second section at a rate configured to inhibit olefin production; and producing a third mixture from the second section.
1291. The method of claim 1290, wherein creating the second mixture comprises removing condensable hydrocarbons from the first mixture.
1292. The method of claim 1290, wherein creating the second mixture comprises removing water from the first mixture.
1293. The method of claim 1290, wherein creating the second mixture comprises removing carbon dioxide from the first mixture.
1294. The method of claim 1290, wherein the first pyrolysis temperature is greater than about 270 °C.
1295. The method of claim 1290, wherein the second pyrolysis temperature is greater than about 270 °C.
1296. The method of claim 1290, wherein the upper pyrolysis temperature is about 500 °C.
1297. The method of claim 1290, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the first or second selected section of the formation.
1298. The method of claim 1290, wherein the one or more heat sources comprise electrical heaters.
1299. The method of claim 1290, wherein the one or more heat sources comprise surface burners.
1300. The method of claim 1290, wherein the one or more heat sources comprise flameless distributed combustors.
1301. The method of claim 1290, wherein the one or more heat sources comprise natural distributed combustors.
1302. The method of claim 1290, further comprising controlling a pressure and a temperature within at least a majority of the first section and the second section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1303. The method of claim 1290, further comprising controlling the heat to the first and second sections such that an average heating rate of the first and second sections is less than about 1 °C per day during pyrolysis.
1304. The method of claim 1290, wherein heating the first and the second sections comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1305. The method of claim 1290, wherein heating the first and second sections comprises transferring heat substantially by conduction.
1306. The method of claim 1290, wherein heating the first and second sections comprises heating the first and second sections such that a thermal conductivity of at least a portion of the first and second sections is greater than about 0.5 W/(m °C).
1307. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1308. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein about 0.1% by weight to about 15% by weight of the condensable hydrocarbons are olefins.
1309. The method of claim 1290, wherein the first or third mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1310. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1311. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1312. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1313. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1314. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1315. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1316. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1317. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1318. The method of claim 1290, wherein the first or third mixture comprises a non-condensable component, and wherein the non-condensable component comprises hydrogen, and wherein the hydrogen is greater than about 10%
by volume of the non-condensable component and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1319. The method of claim 1290, wherein the first or third mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1320. The method of claim 1290, wherein the first or third mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1321. The method of claim 1290, further comprising controlling a pressure within at least a majority of the first or second sections of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1322. The method of claim 1290, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2within the mixture is greater than about 0.5 bars.
1323. The method of claim 1322, wherein the partial pressure of H2within a mixture is measured when the mixture is at a production well.
1324. The method of claim 1290, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1325. The method of claim 1290, further comprising:
providing hydrogen (H2) to the first or second section to hydrogenate hydrocarbons within the first or second section; and heating a portion of the first or second section with heat from hydrogenation.
1326. The method of claim 1290, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1327. The method of claim 1290, further comprising increasing a permeability of a majority of the first or second section to greater than about 100 millidarcy.
1328. The method of claim 1290, further comprising substantially uniformly increasing a permeability of a majority of the first or second section.
1329. The method of claim 1290, wherein the heating is controlled to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1330. The method of claim 1290, wherein producing the first or third mixture comprises producing the first or third mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1331. The method of claim 1330, wherein at least about 20 heat sources are disposed in the formation for each production well.
1332. The method of claim 1290, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1333. The method of claim 1290, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1334. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
producing a mixture from the formation; and hydrogenating a portion of the produced mixture with H2 produced from the formation.
1335. The method of claim 1334, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1336. The method of claim 1334, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1337. The method of claim 1334, wherein the one or more heat sources comprise electrical heaters.
1338. The method of claim 1334, wherein the one or more heat sources comprise surface burners.
1339. The method of claim 1334, wherein the one or more heat sources comprise flameless distributed combustors.
1340. The method of claim 1334, wherein the one or more heat sources comprise natural distributed combustors.
1341. The method of claim 1334, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1342. The method of claim 1334, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1°C per day during pyrolysis.
1343. The method of claim 1334, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1344. The method of claim 1334, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1345. The method of claim 1334, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1346. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1347. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1348. The method of claim 1334, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1349. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1350. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1351. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1352. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1353. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1354. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1355. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1356. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1357. The method of claim 1334, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1358. The method of claim 1334, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1359. The method of claim 1334, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1360. The method of claim 1334, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1361. The method of claim 1334, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1362. The method of claim 1334, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1363. The method of claim 1334, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1364. The method of claim 1334, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1365. The method of claim 1334, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1366. The method of claim 1334, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1367. The method of claim 1334, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1368. The method of claim 1334, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1369. The method of claim 1368, wherein at least about 20 heat sources are disposed in the formation for each production well.
1370. The method of claim 1334, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1371. The method of claim 1334, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1372. A method of treating an oil shale formation in situ, comprising:
heating a first section of the formation;
producing H2 from the first section of formation;
heating a second section of the formation; and recirculating a portion of the H2 from the first section into the second section of the formation to provide a reducing environment within the second section of the formation.
1373. The method of claim 1372, wherein heating the first section or heating the second section comprises heating with an electrical heater.
1374. The method of claim 1372, wherein heating the first section or heating the second section comprises heating with a surface burner.
1375. The method of claim 1372, wherein heating the first section or heating the second section comprises heating with a flameless distributed combustor.
1376. The method of claim 1372, wherein heating the first section or heating the second section comprises heating with a natural distributed combustor.
1377. The method of claim 1372, further comprising controlling a pressure and a temperature within at least a majority of the first or second section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1378. The method of claim 1372, further comprising controlling the heat such that an average heating rate of the first or second section is less than about 1 °C per day during pyrolysis.
1379. The method of claim 1372, wherein heating the first section or heating the second section further comprises:
heating a selected volume (~) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (~~), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C~*p~
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1380. The method of claim 13?2, wherein heating the first section or heating the second section comprises transferring heat substantially by conduction.
1381. The method of claim 1372, wherein heating the first section or heating the second section comprises heating the formation such that a thermal conductivity of at least a portion of the first or second section is greater than about 0.5 W/(m °C).
1382. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1383. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1384. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0. 15.
1385. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1386. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1387. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1388. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1389. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1390. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1391. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1392. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1393. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1394. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1395. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1396. The method of claim 1372, further comprising controlling a pressure within at least a majority of the first or second section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1397. The method of claim 1372, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1398. The method of claim 1397, wherein the partial pressure of H2 within a mixture is measured when the mixture is at a production well.
1399. The method of claim 1372, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1400. The method of claim 1372, further comprising:
providing hydrogen (H2) to the second section to hydrogenate hydrocarbons within the section; and heating a portion of the second section with heat from hydrogenation.
1401. The method of claim 1372, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1402. The method of claim 1372, wherein heating the first section or heating the second section comprises increasing a permeability of a majority of the first or second section, respectively, to greater than about 100 millidarcy.
1403. The method of claim 1372, wherein heating the first section or heating the second section comprises substantially uniformly increasing a permeability of a majority of the first or second section, respectively.
1404. The method of claim 1372, further comprising controlling the heating of the first section or controlling the heat of the second section to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1405. The method of claim 1372, further comprising producing a mixture from the formation in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1406. The method of claim 1405, wherein at least about 20 heat sources are disposed in the formation for each production well.
1407. The method of claim 1372, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1408. The method of claim 1372, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1409. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
producing a mixture from the formation; and controlling formation conditions such that the mixture produced from the formation comprises condensable hydrocarbons including H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1410. The method of claim 1409, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1411. The method of claim 1409, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
1412. The method of claim 1409, wherein the one or more heat sources comprise electrical heaters.
1413. The method of claim 1409, wherein the one or more heat sources comprise surface burners.
1414. The method of claim 1409, wherein the one or more heat sources comprise flameless distributed combustors.
1415. The method of claim 1409, wherein the one or more heat sources comprise natural distributed combustors.
1416. The method of claim 1409, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1417. The method of claim 1409, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1418. The method of claim 1409, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1419. The method of claim 1409, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1420. The method of claim 1409, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1421. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1422. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1423. The method of claim 1409, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1424. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1425. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1426. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1427. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1428. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1429. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1430. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1431. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1432. The method of claim 1409, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1433. The method of claim 1409, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1434. The method of claim 1409, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1435. The method of claim 1409, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1436. The method of claim 1409, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1437. The method of claim 1409, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1438. The method of claim 1409, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1439. The method of claim 1409, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1440. The method of claim 1409, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1441. The method of claim 1409, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1442. The method of claim 1409, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1443. The method of claim 1409, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1444. The method of claim 1443, wherein at least about 20 heat sources are disposed in the formation for each production well.
1445. The method of claim 1409, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1446. The method of claim 1409, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1447. The method of claim 1409, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1448. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
maintaining a pressure of the selected section above atmospheric pressure to increase a partial pressure of H2, as compared to the partial pressure of H2 at atmospheric pressure, in at least a majority of the selected section;
and producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1449. The method of claim 1448, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1450. The method of claim 1448, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1451. The method of claim 1448, wherein the one or more heat sources comprise electrical heaters.
1452. The method of claim 1448, wherein the one or more heat sources comprise surface burners.
14$3. The method of claim 1448, wherein the one or more heat sources comprise flameless distributed combustors.
1454. The method of claim 1448, wherein the one or more heat sources comprise natural distributed combustors.
1455. The method of claim 1448, further comprising controlling the pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1456. The method of claim 1448, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1457. The method of claim 1448, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (~) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (~~), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*~*~~*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p~ is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1458. The method of claim 1448, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1459. The method of claim 1448, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1460. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1461. The method of claim 1448, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1462. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1463. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1464. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1465. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1466. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1467. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1468. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1469. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1470. The method of claim 1448, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1471. The method of claim 1448, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1472. The method of claim 1448, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1473. The method of claim 1448, further comprising controlling the pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1474. The method of claim 1448, further comprising increasing the pressure of the selected section, to an upper limit of about 21 bars absolute, to increase an amount of non-condensable hydrocarbons produced from the formation.
1475. The method of claim 1448, further comprising decreasing pressure of the selected section, to a lower limit of about atmospheric pressure, to increase an amount of condensable hydrocarbons produced from the formation.
1476. The method of claim 1448, wherein a partial pressure comprises a partial pressure based on properties measured at a production well.
1477. The method of claim 1448, further comprising altering the pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1478. The method of claim 1448, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1479. The method of claim 1448, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1480. The method of claim 1448, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1481. The method of claim 1448, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1482. The method of claim 1448, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1483. The method of claim 1448, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1484. The method of claim 1448, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1485. The method of claim 1484, wherein at least about 20 heat sources are disposed in the formation for each production well.
1486. The method of claim 1448, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1487. The method of claim 1448, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1488. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
providing H2 to the formation to produce a reducing environment in at least some of the formation;
producing a mixture from the formation.
1489. The method of claim 1488, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1490. The method of claim 1488, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1491. The method of claim 1488, further comprising separating a portion of hydrogen within the mixture and recirculating the portion into the formation.
1492. The method of claim 1488, wherein the one or more heat sources comprise electrical heaters.
1493. The method of claim 1488, wherein the one or more heat sources comprise surface burners.
1494. The method of claim 1488, wherein the one or more heat sources comprise flameless distributed combustors.
1495. The method of claim 1488, wherein the one or more heat sources comprise natural distributed combustors.
1496. The method of claim 1488, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1497. The method of claim 1488, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1498. The method of claim 1488, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1499. The method of claim 1488, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1500. The method of claim 1488, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1501. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1502. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1503. The method of claim 1488, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1504. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1505. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1506. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1507. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1508. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1509. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1510. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1511. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1512. The method of claim 1488, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1513. The method of claim 1488, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1514. The method of claim 1488, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1515. The method of claim 1488, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1516. The method of claim 1488, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1517. The method of claim 1488, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1518. The method of claim 1488, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1519. The method of claim 1488, wherein providing hydrogen (H2) to the formation further comprises:
hydrogenating hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1520. The method of claim 1488, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1521. The method of claim 1488, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1522. The method of claim 1488, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1523. The method of claim 1488, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1524. The method of claim 1488, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1525. The method of claim 1524, wherein at least about 20 heat sources are disposed in the formation for each production well.
1526. The method of claim 1488, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1527. The method of claim 1488, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1528. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
providing H2 to the selected section to hydrogenate hydrocarbons within the selected section and to heat a portion of the section with heat from the hydrogenation; and controlling heating of the selected section by controlling amounts of H2 provided to the selected section.
1529. The method of claim 1528, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1530. The method of claim 1528, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1531. The method of claim 1528, wherein the one or more heat sources comprise electrical heaters.
1532. The method of claim 1528, wherein the one or more heat sources comprise surface burners.
1533. The method of claim 1528, wherein the one or more heat sources comprise flameless distributed combustors.
1534. The method of claim 1528, wherein the one or more heat sources comprise natural distributed combustors.
1535. The method of claim 1528, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1536. The method of claim 1528, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1537. The method of claim 1528, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p8 is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1538. The method of claim 1528, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1539. The method of claim 1528, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1540. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1541. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1542. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1543. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1544. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1545. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1546. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1547. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1548. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1549. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1550. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1551. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1552. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1553. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1554. The method of claim 1528, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1555. The method of claim 1528, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1556. The method of claim 1555, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1557. The method of claim 1528, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1558. The method of claim 1528, further comprising controlling formation conditions by recirculating a portion of hydrogen from a produced mixture into the formation.
1559. The method of claim 1528, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1560. The method of claim 1528, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1561. The method of claim 1528, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1562. The method of claim 1528, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1563. The method of claim 1562, wherein at least about 20 heat sources are disposed in the formation for each production well.
1564. The method of claim 1528, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1565. The method of claim 1528, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1566. An in situ method for producing H2 from an oil shale formation, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation, wherein a H2 partial pressure within the mixture is greater than about 0.5 bars.
1567. The method of claim 1566, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1568. The method of claim 1566, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1569. The method of claim 1566, wherein the one or more heat sources comprise electrical heaters.
1570. The method of claim 1566, wherein the one or more heat sources comprise surface burners.
1571. The method of claim 1566, wherein the one or more heat sources comprise flameless distributed combustors.
1572. The method of claim 1566, wherein the one or more heat sources comprise natural distributed combustors.
1573. The method of claim 1566, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1574. The method of claim 1566, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1575. The method of claim 1566, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1576. The method of claim 1566, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1577. The method of claim 1566, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1578. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1579. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1580. The method of claim 1566, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1581. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1582. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1583. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1584. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1585. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1586. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1587. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1588. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1589. The method of claim 1566, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1590. The method of claim 1566, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1591. The method of claim 1566, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1592. The method of claim 1566, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1593. The method of claim 1566, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1594. The method of claim 1566, further comprising recirculating a portion of the hydrogen within the mixture into the formation.
1595. The method of claim 1566, further comprising condensing a hydrocarbon component from the produced mixture and hydrogenating the condensed hydrocarbons with a portion of the hydrogen.
1596. The method of claim 1566, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1597. The method of claim 1566, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1598. The method of claim 1566, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1599. The method of claim 1566, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1600. The method of claim 1566, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1601. The method of claim 1600, wherein at least about 20 heat sources are disposed in the formation for each production well.
1602. The method of claim 1566, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1603. The method of claim 1566, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1604. The method of claim 1566, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1605. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section has been selected for heating using an atomic hydrogen weight percentage of at least a portion of hydrocarbons in the selected section, and wherein at least the portion of the hydrocarbons in the selected section comprises an atomic hydrogen weight percentage, when measured on a dry, ash-free basis, of greater than about 4.0 %; and producing a mixture from the formation.
1606. The method of claim 1605, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1607. The method of claim 1605, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1608. The method of claim 1605, wherein the one or more heat sources comprise electrical heaters.
1609. The method of claim 1605, wherein the one or more heat sources comprise surface burners.
1610. The method of claim 1605, wherein the one or more heat sources comprise flameless distributed combustors.
1611. The method of claim 1605, wherein the one or more heat sources comprise natural distributed combustors.
1612. The method of claim 1605, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1613. The method of claim 1605, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1614. The method of claim 1605, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1615. The method of claim 1605, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1616. The method of claim 1605, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1617. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1618. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1619. The method of claim 1605, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1620. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1621. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1622. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1623. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1624. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1625. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1626. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1627. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1628. The method of claim 1605, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1629. The method of claim 1605, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1630. The method of claim 1605, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1631. The method of claim 1605, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1632. The method of claim 1605, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1633. The method of claim 1632, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1634. The method of claim 1605, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1635. The method of claim 1605, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1636. The method of claim 1605, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1637. The method of claim 1605, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1638. The method of claim 1605, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1639. The method of claim 1605, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1640. The method of claim 1605, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1641. The method of claim 1605, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1642. The method of claim 1641, wherein at least about 20 heat sources are disposed in the formation for each production well.
1643. The method of claim 1605, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1644. The method of claim 1605, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1645. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein at least some hydrocarbons within the selected section have an initial atomic hydrogen weight percentage of greater than about 4.0 %; and producing a mixture from the formation.
1646. The method of claim 1645, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1647. The method of claim 1645, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1648. The method of claim 1645, wherein the one or more heat sources comprise electrical heaters.
1649. The method of claim 1645, wherein the one or more heat sources comprise surface burners, 1650. The method of claim 1645, wherein the one or more heat sources comprise flameless distributed combustors.
1651. The method of claim 1645, wherein the one or more heat sources comprise natural distributed combustors.
1652. The method of claim 1645, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1653. The method of claim 1645, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1654. The method of claim 1645, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (Cv), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*Cv*Pb wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1655. The method of claim 1645, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1656. The method of claim 1645, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1657. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1658. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1659. The method of claim 1645, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1660. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1661. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1662. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1663. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1664. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1665. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1666. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1667. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloallcanes.
1668. The method of claim 1645, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1669. The method of claim 1645, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1670. The method of claim 1645, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1671. The method of claim 1645, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1672. The method of claim 1645, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1673. The method of claim 1672, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1674. The method of claim 1645, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1675. The method of claim 1645, further comprising controlling formation conditions by recirculating a. portion of hydrogen from the mixture into the formation.
1676. The method of claim 1645, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1677. The method of claim 1645, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1678. The method of claim 1645, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1679. The method of claim 1645, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1680. The method of claim 1645, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1681. The method of claim 1645, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1682. The method of claim 1681, wherein at least about 20 heat sources are disposed in the formation for each production well.
1683. The method of claim 1645, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1684. The method of claim 1645, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1685. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section has been selected for heating using vitrinite reflectance of at least some hydrocarbons in the selected section, and wherein at least a portion of the hydrocarbons in the selected section comprises a vitrinite reflectance of greater than about 0.3 %;
wherein at least a portion of the hydrocarbons in the selected section comprises a vitrinite reflectance of less than about 4.5 %; and producing a mixture from the formation.
1686. The method of claim 1685, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1687. The method of claim 1685, further comprising maintaining a temperature within the selected section within a pyrolysis temperature.
1688. The method of claim 1685, wherein the vitrinite reflectance of at least the portion of hydrocarbons within the selected section is between about 0.47 % and about 1.5 % such that a majority of the produced mixture comprises condensable hydrocarbons.
1689. The method of claim 1685, wherein the vitrinite reflectance of at least the portion of hydrocarbons within the selected section is between about 1.4 % and about 4.2 % such that a majority of the produced mixture comprises non-condensable hydrocarbons.
1690. The method of claim 1685, wherein the one or more heat sources comprise electrical heaters.
1691. The method of claim 1685, wherein the one or more heat sources comprise surface burners.
1692. The method of claim 1685, wherein the one or more heat sources comprise flameless distributed combustors.
1693. The method of claim 1685, wherein the one or more heat sources comprise natural distributed combustors.
1694. The method of claim 1685, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1695. The method of claim 1685, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1696. The method of claim 1685, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (Cv), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*Cv*pB
wherein Pwr is the heating energy/day,h is an average heating rate of the formation, pb is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1697. The method of claim 1685, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
, 1698. The method of claim 1685, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1699. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1700. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1701. The method of claim 1685, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1702. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1703. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1704. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
' 1705. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1706. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1707. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1708. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1709. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1710. The method of claim 1685, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1711. The method of claim 1685, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1712. The method of claim 1685, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1713. The method of claim 1685, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1714. The method of claim 1685, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1715. The method of claim 1714, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1716. The method of claim 1685, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1717. The method of claim 1685, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1718. The method of claim 1685, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1719. The method of claim 1685, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1720. The method of claim 1685, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1721. The method of claim 1685, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1722. The method of claim 1685, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1723. The method of claim 1685, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1724. The method of claim 1723, wherein at least about 20 heat sources are disposed in the formation for each production well.
1725. The method of claim 1685, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1726. The method of claim 1685, further comprising providing heat from three or more heat sources to at least a portion of the fonnation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1727. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section has been selected for heating using a total organic matter weight percentage of at least a portion of the selected section, and wherein at least the portion of the selected section comprises a total organic matter weight percentage, of at least about 5.0 %; and producing a mixture from the formation.
1728. The method of claim 1727, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1729. The method of claim 1727, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1730. The method of claim 1727, wherein the one or more heat sources comprise electrical heaters.
1731. The method of claim 1727, wherein the one or more heat sources comprise surface burners.
1732. The method of claim 1727, wherein the one or more heat sources comprise flameless distributed combustors.
1733. The method of claim 1727, wherein the one or more heat sources comprise natural distributed combustors.
1734. The method of claim 1727, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1735. . The method of claim 1727, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1736. The method of claim 1727, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1737. The method of claim 1727, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1738. The method of claim 1727, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1739. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1740. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1741. The method of claim 1727, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1742. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1743. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1744. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1745. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1746. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1747. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises mufti-ring aromatics with more than two rings.
1748. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1749. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1750. The method of claim 1727, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1751. The method of claim 1727, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1752. The method of claim 1727, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1753. The method of claim 1727, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1754. The method of claim 1727, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1755. The method of claim 1754, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1756. The method of claim 1727, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1757. The method of claim 1727, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1758. The method of claim 1727, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1759. The method of claim 1727, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1760. The method of claim 1727, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1761. The method of claim 1727, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1762. The method of claim 1727, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1763. The method of claim 1727, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1764. The method of claim 1763, wherein at least about 20 heat sources are disposed in the formation for each production well.
1765. The method of claim 1727, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1766. The method of claim 1727, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1767. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein at least some hydrocarbons within the selected section have an initial total organic matter weight percentage of at least about 5.0%; and producing a mixture from the formation.
1768. The method of claim 1767, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1769. The method of claim 1767, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1770. The method of claim 1767, wherein the one or more heat sources comprise electrical heaters.
1771. The method of claim 1767, wherein the one or more heat sources comprise surface burners.
1772. The method of claim 1767, wherein the one or more heat sources comprise flameless distributed combustors.
1773. The method of claim 1767, wherein the one or more heat sources comprise natural distributed combustors.
1774. The method of claim 1767, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1775. The method of claim 1767, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1776. The method of claim 1767, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volmne of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p$ is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1777. The method of claim 1767, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1778. The method of claim 1767, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1779. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1780. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1781. The method of claim 1767, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1782. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1783. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1784. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1785. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1786. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1787. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1788. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1789. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1790. The method of claim 1767, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1791. The method of claim 1767, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1792. The method of claim 1767, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1793. The method of claim 1767, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1794. The method of claim 1767, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1795. The method of claim 1794, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1796. The method of claim 1767, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1797. The method of claim 1767, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1798. The method of claim 1767, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1799. The method of claim 1767, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1800. The method of claim 1767, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1801. The method of claim 1767, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1802. The method of claim 1767, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1803. The method of claim 1767, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1804. The method of claim 1803, wherein at least about 20 heat sources are disposed in the formation for each production well.
1805. The method of claim 1767, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1806. The method of claim 1767, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1807. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section has been selected for heating using an atomic oxygen weight percentage of at least a portion of hydrocarbons in the selected section, and wherein at least a portion of the hydrocarbons in the selected section comprises an atomic oxygen weight percentage of less than about 15% when measured on a dry, ash free basis; and producing a mixture from the formation.
1808. The method of claim 1807, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1809. The method of claim 1807, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1810. The method of claim 1807, wherein the one or more heat sources comprise electrical heaters.
1811. The method of claim 1807, wherein the one or more heat sources comprise surface burners.
1812. The method of claim 1807, wherein the one or more heat sources comprise flameless distributed combustors.
1813. The method of claim 1807, wherein the one or more heat sources comprise natural distributed combustors.
1814. The method of claim 1807, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1815. The method of claim 1807, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1816. The method of claim 1807, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1817. The method of claim 1807, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1818. The method of claim 1807, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1819. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1820. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1821. The method of claim 1807, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1822. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1823. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1824. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1825. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1826. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1827. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1828. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1829. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1830. The method of claim 1807, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1831. The method of claim 1807, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1832. The method of claim 1807, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1833. The method of claim 1807, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1834. The method of claim 1807, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1835. The method of claim 1834, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1836. The method of claim 1807, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1837. The method of claim 1807, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1838. The method of claim 1807, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1839. The method of claim 1807, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1840. The method of claim 1807, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1841. The method of claim 1807, wherein allowing the heat to transfer further comprises substantially uniformly increasing a permeability of a majority of the selected section.
1842. The method of claim 1807, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1843. The method of claim 1807, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1844. The method of claim 1843, wherein at least about 20 heat sources are disposed in the formation for each production well.
1845. The method of claim 1807, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1846. The method of claim 1807, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1847. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to a selected section of the formation;
allowing the heat to transfer from the one or more heat sources to the selected section of the formation to pyrolyze hydrocarbon within the selected section;
wherein at least some hydrocarbons within the selected section have an initial atomic oxygen weight percentage of less than about 15 %; and producing a mixture from the formation.
1848. The method of claim 1847, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1849. The method of claim 1847, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range 1850. The method of claim 1847, wherein the one or more heat sources comprise electrical heaters.
1851. The method of claim 1847, wherein the one or more heat sources comprise surface burners.
1852. The method of claim 1847, wherein the one or more heat sources comprise flameless distributed combustors.
1853. The method of claim 1847, wherein the one or more heat sources comprise natural distributed combustors.
1854. The method of claim 1847, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1855. The method of claim 1847, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1856. The method of claim 1847, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, la is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1857. The method of claim 1847, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1858. The method of claim 1847, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1859. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1860. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1861. The method of claim 1847, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1862. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1863. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1864. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1865. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1866. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1867. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1868. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1869. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1870. The method of claim 1847, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1871. The method of claim 1847, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1872. The method of claim 1847, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1873. The method of claim 1847, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1874. The method of claim 1847, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of Hz within the mixture is greater than about 0.5 bars.
1875. The method of claim 1874, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1876. The method of claim 1847, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1877. The method of claim 1847, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1878. The method of claim 1847, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1879. The method of claim 1847, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1880. The method of claim 1847, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1881. The method of claim 1847, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1882. The method of claim 1847, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1883. The method of claim 1847, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1884. The method of claim 1883, wherein at least about 20 heat sources are disposed in the formation for each production well.
1885. The method of claim 1847, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1886. The method of claim 1847, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1887. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section has been selected for heating using an atomic hydrogen to carbon ratio of at least a portion of hydrocarbons in the selected section, wherein at least a portion of the hydrocarbons in the selected section comprises an atomic hydrogen to carbon ratio greater than about 0.70, and wherein the atomic hydrogen to carbon ratio is less than about 1.65; and producing a mixture from the formation.
1888. The method of claim 1887, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1889. The method of claim 1887, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1890. The method of claim 1887, wherein the one or more heat sources comprise electrical heaters.
1891. The method of claim 1887, wherein the one or more heat sources comprise surface burners.
1892. The method of claim 1887, wherein the one or more heat sources comprise flameless distributed combustors.
1893. The method of claim 1887, wherein the one or more heat sources comprise natural distributed combustors.
1894. The method of claim 1887, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1895. The method of claim 1887, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1896. The method of claim 1887, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulls density, and wherein the heating rate is less than about 10 °C/day.
1897. The method of claim 1887, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1898. The method of claim 1887, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1899. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1900. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1901. The method of claim 1887, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1902. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1903. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1904. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1905. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1906. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1907. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1908. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1909. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1910. The method of claim 1887, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1911. The method of claim 1887, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1912. The method of claim 1887, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1913. The method of claim 1887, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1914. The method of claim 1887, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1915. The method of claim 1914, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1916. The method of claim 1887, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1917. The method of claim 1887, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1918. The method of claim 1887, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1919. The method of claim 1887, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1920. The method of claim 1887, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1921. The method of claim 1887, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1922. The method of claim 1887, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1923. The method of claim 1887, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1924. The method of claim 1923, wherein at least about 20 heat sources are disposed in the formation for each production well.
1925. The method of claim 1887, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1926. The method of claim 1887, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1927. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to a selected section of the formation;
allowing the heat to transfer from the one or more heat sources to the selected section of the formation to pyrolyze hydrocarbons within the selected section;
wherein at least some hydrocarbons within the selected section have an initial atomic hydrogen to carbon ratio greater than about 0.70;
wherein the initial atomic hydrogen to carbon ratio is less than about 1.65;
and producing a mixture from the formation.
1928. The method of claim 1927, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1929. The method of claim 1927, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1930. The method of claim 1927, wherein the one or more heat sources comprise electrical heaters.
1931. The method of claim 1927, wherein the one or more heat sources comprise surface burners.
1932. The method of claim 1927, wherein the one or more heat sources comprise flameless distributed combustors.
1933. The method of claim 1927, wherein the one or more heat sources comprise natural distributed combustors.
1934. The method of claim 1927, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1935. The method of claim 1927, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1936. The method of claim 1927, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulls density, and wherein the heating rate is less than about 10 °C/day.
1937. The method of claim 1927, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1938. The method of claim 1927, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1939. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1940. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1941. The method of claim 1927, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1942. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1943. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1944. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1945. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1946. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1947. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1948. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1949. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1950. The method of claim 1927, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1951. The method of claim 1927, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1952. The method of claim 1927, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1953. The method of claim 1927, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1954. The method of claim 1927, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1955. The method of claim 1954, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1956. The method of claim 1927, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1957. The method of claim 1927, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1958. The method of claim 1927, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1959. The method of claim 1927, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1960. The method of claim 1927, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1961. The method of claim 1927, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1962. The method of claim 1927, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1963. The method of claim 1927, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1964. The method of claim 1963, wherein at least about 20 heat sources are disposed in the formation for each production well.
1965. The method of claim 1927, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1966. The method of claim 1927, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1967. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section has been selected for heating using an atomic oxygen to carbon ratio of at least a portion of hydrocarbons in the selected section, wherein at least a portion of the hydrocarbons in the selected section comprises an atomic oxygen to carbon ratio greater than about 0.025, and wherein the atomic oxygen to carbon ratio of at least a portion of the hydrocarbons in the selected section is less than about 0.15; and producing a mixture from the formation.
1968. The method of claim 1967, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1969. The method of claim 1967, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1970. The method of claim 1967, wherein the one or more heat sources comprise electrical heaters.
1971. The method of claim 1967, wherein the one or more heat sources comprise surface burners.
1972. The method of claim 1967, wherein the one or more heat sources comprise flameless distributed combustors.
1973. The method of claim 1967, wherein the one or more heat sources comprise natural distributed combustors.
1974. The method of claim 1967, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1975. The method of claim 1967, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1976. The method of claim 1967, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10°C/day.
1977. The method of claim 1967, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1978. The method of claim 1967, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m°C).
1979. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1980. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1981. The method of claim 1967, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1982. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1983. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1984. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1985. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1986. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1987. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises mufti-ring aromatics with more than two rings.
1988. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1989. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1990. The method of claim 1967, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1991. The method of claim 1967, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1992. The method of claim 1967, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1993. The method of claim 1967, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1994. The method of claim 1967, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1995. The method of claim 1994, wherein the partial pressure of HZ within the mixture is measured when the mixture is at a production well.
1996. The method of claim 1967, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1997. The method of claim 1967, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1998. The method of claim 1967, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1999. The method of claim 1967, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2000. The method of claim 1967, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2001. The method of claim 1967, wherein allowing the heat to transfer further comprises substantially uniformly increasing a permeability of a majority of the selected section.
2002. The method of claim 1967, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2003. The method of claim 1967, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2004. The method of claim 2003, wherein at least about 20 heat sources are disposed in the formation for each production well.
2005. The method of claim 1967, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2006. The method of claim 1967, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2007. A method of treating an oil shale formation in situ, comprising providing heat from one or more heat sources to a selected section of the formation;
allowing the heat to transfer from the one or more heat sources to the selected section of the formation to pyrolyze hydrocarbons within the selected section;
wherein at least some hydrocarbons within the selected section have an initial atomic oxygen to carbon ratio greater than about 0.025;
wherein the initial atomic oxygen to carbon ratio is less than about 0.15; and producing a mixture from the formation.
2008. The method of claim 2007, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2009. The method of claim 2007, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2010. The method of claim 2007, wherein the one or more heat sources comprise electrical heaters.
2011. The method of claim 2007, wherein the one or more heat sources comprise surface burners.
2012. The method of claim 2007, wherein the one or more heat sources comprise flameless distributed combustors.
2013. The method of claim 2007, wherein the one or more heat sources comprise natural distributed combustors.
2014. The method of claim 2007, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2015. The method of claim 2007, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1°C per day during pyrolysis.
2016. The method of claim 2007, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p$ is formation bulls density, and wherein the heating rate is less than about 10°C/day.
2017. The method of claim 2007, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2018. The method of claim 2007, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2019. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2020. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2021. The method of claim 2007, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2022. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2023. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2024. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2025. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2026. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2027. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2028. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2029. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2030. The method of claim 2007, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2031. The method of claim 2007, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2032. The method of claim 2007, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2033. The method of claim 2007, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2034. The method of claim 2007, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2035. The method of claim 2034, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2036. The method of claim 2007, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2037. The method of claim 2007, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
203 8. The method of claim 2007, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2039. The method of claim 2007, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2040. The method of claim 2007, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2041. The method of claim 2007, wherein allowing the heat to transfer further comprises substantially uniformly increasing a permeability of a majority of the selected section.
2042. The method of claim 2007, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2043. The method of claim 2007, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2044. The method of claim 2043, wherein at least about 20 heat sources are disposed in the formation for each production well.
2045. The method of claim 2007, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2046. The method of claim 2007, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2047. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section has been selected for heating using a moisture content in the selected section, and wherein at least a portion of the selected section comprises a moisture content of less than about 15 % by weight; and producing a mixture from the formation.
2048. The method of claim 2047, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2049. The method of claim 2047, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2050. The method of claim 2047, wherein the one or more heat sources comprise electrical heaters.
2051. The method of claim 2047, wherein the one or more heat sources comprise surface burners.
2052. The method of claim 2047, wherein the one or more heat sources comprise flameless distributed combustors.
2053. The method of claim 2047, wherein the one or more heat sources comprise natural distributed combustors.
2054. The method of claim 2047, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2055. The method of claim 2047, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2056. The method of claim 2047, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2057. The method of claim 2047, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2058. The method of claim 2047, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2059. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2060. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2061. The method of claim 2047, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2062. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2063. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2064. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2065. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2066. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2067. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2068. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2069. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2070. The method of claim 2047, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2071. The method of claim 2047, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2072. The method of claim 2047, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2073. The method of claim 2047, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2074. The method of claim 2047, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2075. The method of claim 2074, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2076. The method of claim 2047, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2077. The method of claim 2047, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2078. The method of claim 2047, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2079. The method of claim 2047, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2080. The method of claim 2047, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2081. The method of claim 2047, wherein allowing the heat to transfer further comprises substantially uniformly increasing a permeability of a majority of the selected section.
2082. The method of claim 2047, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2083. The method of claim 2047, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2084. The method of claim 2083, wherein at least about 20 heat sources are disposed in the formation for each production well.
2085. The method of claim 2047, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2086. The method of claim 2047, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2087. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to a selected section of the formation;
allowing the heat to transfer from the one or more heat sources to the selected section of the formation;
wherein at least a portion of the selected section has an initial moisture content of less than about 15 % by weight; and producing a mixture from the formation.
2088. The method of claim 2087, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2089. The method of claim 2087, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2090. The method of claim 2087, wherein the one or more heat sources comprise electrical heaters.
2091. The method of claim 2087, wherein the one or more heat sources comprise surface burners.
2092. The method of claim 2087, wherein the one or more heat sources comprise flameless distributed combustors.
2093. The method of claim 2087, wherein the one or more heat sources comprise natural distributed combustors.
2094. The method of claim 2087, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2095. The method of claim 2087, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2096. The method of claim 2087, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2097. The method of claim 2087, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2098. The method of claim 2087, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2099. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2100. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2101. The method of claim 2087, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2102. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2103. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2104. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2105. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2106. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2107. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2108. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2109. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2110. The method of claim 2087, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2111. The method of claim 2087, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2112. The method of claim 2087, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2113. The method of claim 2087, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2114. The method of claim 2087, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2115. The method of claim 2114, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2116. The method of claim 2087, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2117. The method of claim 2087, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2118. The method of claim 2087, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2119. The method of claim 2087, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2120. The method of claim 2087, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2121. The method of claim 2087, wherein allowing the heat to transfer further comprises substantially uniformly increasing a permeability of a majority of the selected section.
2122. The method of claim 2087, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2123. The method of claim 2087, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2124. The method of claim 2124, wherein at least about 20 heat sources are disposed in the formation for each production well.
2125. The method of claim 2087, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2126. The method of claim 2087, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2127. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section is heated in a reducing environment during at least a portion of the time that the selected section is being heated; and producing a mixture from the formation.
2128. The method of claim 2127, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2129. The method of claim 2127, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2130. The method of claim 2127, wherein the one or more heat sources comprise electrical heaters.
2131. The method of claim 2127, wherein the one or more heat sources comprise surface burners.
2132. The method of claim 2127, wherein the one or more heat sources comprise flameless distributed combustors.
2133. The method of claim 2127, wherein the one or more heat sources comprise natural distributed combustors.
2134. The method of claim 2127, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2135. The method of claim 2127, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2136. The method of claim 2127, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C"*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2137. The method of claim 2127, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2138. The method of claim 2127, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2139. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2140. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2141. The method of claim 2127, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2142. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2143. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2144. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2145. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2146. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2147. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2148. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2149. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2150. The method of claim 2127, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2151. The method of claim 2127, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2152. The method of claim 2127, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2153. The method of claim 2127, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2154. The method of claim 2127, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2155. The method of claim 2154, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2156. The method of claim 2127, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2157. The method of claim 2127, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2158. The method of claim 2127, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2159. The method of claim 2127, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2160. The method of claim 2127, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2161. The method of claim 2127, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2162. The method of claim 2127, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2163. The method of claim 2127, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2164. The method of claim 2163, wherein at least about 20 heat sources are disposed in the formation for each production well.
2165. The method of claim 2127, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2166. The method of claim 2127, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2167. A method of treating an oil shale formation in situ, comprising:
heating a first section of the formation to produce a mixture from the formation;
heating a second section of the formation; and recirculating a portion of the produced mixture from the first section into the second section of the formation to provide a reducing environment within the second section of the formation.
2168. The method of claim 2167, further comprising maintaining a temperature within the first section or the second section within a pyrolysis temperature range.
2169. The method of claim 2167, wherein heating the first or the second section comprises heating with an electrical heater.
2170. The method of claim 2167, wherein heating the first or the second section comprises heating with a surface burner.
2171. The method of claim 2167, wherein heating the first or the second section comprises heating with a flameless distributed combustor.
2172. The method of claim 2167, wherein heating the first or the second section comprises heating with a natural distributed combustor.
2173. The method of claim 2167, further comprising controlling a pressure and a temperature within at least a majority of the first or second section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2174. The method of claim 2167, further comprising controlling the heat such that an average heating rate of the first or the second section is less than about 1 °C per day during pyrolysis.
2175. The method of claim 2167, wherein heating the first or the second section comprises:
heating a selected volume (V) of the oil shale formation from one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h *Y*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulls density, and wherein the heating rate is less than about 10 °C/day.
2176. The method of claim 2167, wherein heating the first or the second section comprises transferring heat substantially by conduction.
2177. The method of claim 2167, wherein heating the first or the second section comprises heating the first or the second section such that a thermal conductivity of at least a portion of the first or the second section is greater than about 0.5 W/(m °C).
2178. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2179. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2180. The method of claim 2167, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2181. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2182. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2183. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2184. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2185. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2186. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2187. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2188. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2189. The method of claim 2167, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2190. The method of claim 2167, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2191. The method of claim 2167, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2192. The method of claim 2167, further comprising controlling a pressure within at least a majority of the first or second section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2193. The method of claim 2167, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2194. The method of claim 2193, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2195. The method of claim 2167, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2196. The method of claim 2167, further comprising:
providing hydrogen (H2) to the first or second section to hydrogenate hydrocarbons within the first or second section; and heating a portion of the first or second section with heat from hydrogenation.
2197. The method of claim 2167, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2198. The method of claim 2167, wherein heating the first or the second section comprises increasing a permeability of a majority of the first or the second section to greater than about 100 millidarcy.
2199. The method of claim 2167, wherein heating the first or the second section comprises substantially uniformly increasing a permeability of a majority of the first or the second section.
2200. The method of claim 2167, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2201. The method of claim 2167, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2202. The method of claim 2201, wherein at least about 20 heat sources are disposed in the formation for each production well.
2203. The method of claim 2167, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2204. The method of claim 2167, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2205. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation; and allowing the heat to transfer from the one or more heat sources to a selected section of the formation such that a permeability of at least a portion of the selected section increases to greater than about 100 millidarcy.
2206. The method of claim 2205, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2207. The method of claim 2205, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2208. The method of claim 2205, wherein the one or more heat sources comprise electrical heaters.
2209. The method of claim 2205, wherein the one or more heat sources comprise surface burners.
2210. The method of claim 2205, wherein the one or more heat sources comprise flameless distributed combustors.
2211. The method of claim 2205, wherein the one or more heat sources comprise natural distributed combustors.
2212. The method of claim 2205, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2213. The method of claim 2205, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2214. The method of claim 2205, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2215. The method of claim 2205, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2216. The method of claim 2205, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2217. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2218. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2219. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2220. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2221. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2222. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2223. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2224. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2225. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2226. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2227. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2228. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2229. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2230. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2231. The method of claim 2205, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2232. The method of claim 2205, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2233. The method of claim 2232, further comprising producing a mixture from the formation, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2234. The method of claim 2205, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2235. The method of claim 2205, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2236. The method of claim 2205, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2237. The method of claim 2205, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2238. The method of claim 2205, further comprising increasing a permeability of a majority of the selected section to greater than about 5 Darcy.
2239. The method of claim 2205, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2240. The method of claim 2205, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2241. The method of claim 2205, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2242. The method of claim 2241, wherein at least about 20 heat sources are disposed in the formation for each production well.
2243. The method of claim 2205, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2244. The method of claim 2205, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2245. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation; and allowing the heat to transfer from the one or more heat sources to a selected section of the formation such that a permeability of a majority of at least a portion of the selected section increases substantially uniformly.
2246. The method of claim 2245, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2247. The method of claim 2245, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2248. The method of claim 2245, wherein the one or more heat sources comprise electrical heaters.
2249. The method of claim 2245, wherein the one or more heat sources comprise surface burners.
2250. The method of claim 2245, wherein the one or more heat sources comprise flameless distributed combustors.
2251. The method of claim 2245, wherein the one or more heat sources comprise natural distributed combustors.
2252. The method of claim 2245, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2253. The method of claim 2245, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2254. The method of claim 2245, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2255. The method of claim 2245, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2256. The method of claim 2245, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2257. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2258. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2259. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2260. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2261. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2262. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2263. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2264. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2265. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2266. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2267. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2268. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2269. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2270. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2271. The method of claim 2245, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2272. The method of claim 2245, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2273. The method of claim 2245, further comprising producing a mixture from the formation, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2274. The method of claim 2245, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2275. The method of claim 2245, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2276. The method of claim 2245, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2277. The method of claim 2245, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2278. The method of claim 2245, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2279. The method of claim 2245, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2280. The method of claim 2245, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2281. The method of claim 2280, wherein at least about 20 heat sources are disposed in the formation for each production well.
2282. The method of claim 2245, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2283. The method of claim 2245, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2284. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation; and allowing the heat to transfer from the one or more heat sources to a selected section of the formation such that a porosity of a majority of at least a portion of the selected section increases substantially uniformly.
2285. The method of claim 2284, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2286. The method of claim 2284, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2287. The method of claim 2284, wherein the one or more heat sources comprise electrical heaters.
2288. The method of claim 2284, wherein the one or more heat sources comprise surface burners.
2289. The method of claim 2284, wherein the one or more heat sources comprise flameless distributed combustors.
2290. The method of claim 2284, wherein the one or more heat sources comprise natural distributed combustors.
2291. The method of claim 2284, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2292. The method of claim 2284, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2293. The method of claim 2284, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulls density, and wherein the heating rate is less than about 10 °C/day.
2294. The method of claim 2284, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2295. The method of claim 2284, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2296. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2297. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2298. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2299. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2300. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2301. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2302. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2303. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2304. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2305. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2306. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2307. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2308. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2309. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2310. The method of claim 2284, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2311. The method of claim 2284, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2312. The method of claim 2284, further comprising producing a mixture from the formation, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2313. The method of claim 2284, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2314. The method of claim 2284, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2315. The method of claim 2284, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2316. The method of claim 2284, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2317. The method of claim 2284, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2318. The method of claim 2284, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2319. The method of claim 2284, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2320. The method of claim 2284, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2321. The method of claim 2320, wherein at least about 20 heat sources are disposed in the formation for each production well.
2322. The method of claim 2284, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2323. The method of claim 2284, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2324. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and controlling the heat to yield at least about 15 % by weight of a total organic carbon content of at least some of the oil shale formation into condensable hydrocarbons.
2325. The method of claim 2324, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2326. The method of claim 2324, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2327. The method of claim 2324, wherein the one or more heat sources comprise electrical heaters.
2328. The method of claim 2324, wherein the one or more heat sources comprise surface burners.
2329. The method of claim 2324, wherein the one or more heat sources comprise flameless distributed combustors.
2330. The method of claim 2324, wherein the one or more heat sources comprise natural distributed combustors.
2331. The method of claim 2324, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2332. The method of claim 2324, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2333. The method of claim 2324, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2334. The method of claim 2324, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2335. The method of claim 2324, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2336. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2337. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2338. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2339. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2340. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2341. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2342. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2343. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2344. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2345. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2346. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2347. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2348. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2349. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2350. The method of claim 2324, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2351. The method of claim 2324, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2352. The method of claim 2324, further comprising producing a mixture from the formation, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2353. The method of claim 2324, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2354. The method of claim 2324, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2355. The method of claim 2324, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2356. The method of claim 2324, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2357. The method of claim 2324, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2358. The method of claim 2324, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2359. The method of claim 2324, wherein the heating is controlled to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2360. The method of claim 2324, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2361. The method of claim 2360, wherein at least about 20 heat sources are disposed in the formation for each production well.
2362. The method of claim 2324, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2363. The method of claim 2324, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2364. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2365. The method of claim 2364, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2366. The method of claim 2364, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2367. The method of claim 2364, wherein the one or more heat sources comprise electrical heaters.
2368. The method of claim 2364, wherein the one or more heat sources comprise surface burners.
2369. The method of claim 2364, wherein the one or more heat sources comprise flameless distributed combustors.
2370. The method of claim 2364, wherein the one or more heat sources comprise natural distributed combustors.
2371. The method of claim 2364, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2372. The method of claim 2364, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2373. The method of claim 2364, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2374. The method of claim 2364, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2375. The method of claim 2364, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2376. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2377. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2378. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2379. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2380. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2381. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2382. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2383. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2384. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2385. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2386. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2387. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2388. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2389. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2390. The method of claim 2364, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2391. The method of claim 2364, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2392. The method of claim 2364, further comprising producing a mixture from the formation, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2393. The method of claim 2364, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2394. The method of claim 2364, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2395. The method of claim 2364, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2396. The method of claim 2364, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2397. The method of claim 2364, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2398. The method of claim 2364, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2399. The method of claim 2364, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2400. The method of claim 2399, wherein at least about 20 heat sources are disposed in the formation for each production well.
2401. The method of claim 2364, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2402. The method of claim 2364, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2403. A method of treating an oil shale formation in situ, comprising:
heating a first section of the formation to pyrolyze at least some hydrocarbons in the first section and produce a first mixture from the formation;
heating a second section of the formation to pyrolyze at least some hydrocarbons in the second section and produce a second mixture from the formation; and leaving an unpyrolyzed section between the first section and the second section to inhibit subsidence of the formation.
2404. The method of claim 2403, further comprising maintaining a temperature within the first section or the second section within a pyrolysis temperature range.
2405. The method of claim 2403, wherein heating the first section or heating the second section comprises heating with an electrical heater.
2406. The method of claim 2403, wherein heating the first section or heating the second section comprises heating with a surface burner.
2407. The method of claim 2403, wherein heating the first section or heating the second section comprises heating with a flameless distributed combustor.
2408. The method of claim 2403, wherein heating the first section or heating the second section comprises heating with a natural distributed combustor.
2409. The method of claim 2403, further comprising controlling a pressure and a temperature within at least a majority of the first or second section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2410. The method of claim 2403, further comprising controlling the heat such that an average heating rate of the first or second section is less than about 1 °C per day during pyrolysis.
2411. The method of claim 2403, wherein heating the first section or heating the second section comprises:
heating a selected volume (V) of the oil shale formation from one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2412. The method of claim 2403, wherein heating the first section or heating the second section comprises transferring heat substantially by conduction.
2413. The method of claim 2403, wherein heating the first section or heating the second section comprises heating the formation such that a thermal conductivity of at least a portion of the first or second section, respectively, is greater than about 0.5 W/(m °C).
2414. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2415. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2416. The method of claim 2403, wherein the first or second mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2417. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2418. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2419. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2420. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2421. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2422. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2423. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2424. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2425. The method of claim 2403, wherein the first or second mixture comprises a non-condensable component, and wherein the non-condensable component comprises hydrogen, and wherein the hydrogen is greater than about % by volume of the non-condensable component and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2426. The method of claim 2403, wherein the first or second mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the first or second mixture is ammonia.
2427. The method of claim 2403, wherein the first or second mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2428. The method of claim 2403, further comprising controlling a pressure within at least a majority of the first or second section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2429. The method of claim 2403, further comprising controlling formation conditions to produce the first or second mixture, wherein a partial pressure of H2 within the first or second mixture is greater than about 0.5 bars.
2430. The method of claim 2403, wherein a partial pressure of H2 within the first or second mixture is measured when the first or second mixture is at a production well.
2431. The method of claim 2403, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2432. The method of claim 2403, further comprising controlling formation conditions by recirculating a portion of hydrogen from the first or second mixture into the formation.
2433. The method of claim 2403, further comprising:
providing hydrogen (H2) to the first or second section to hydrogenate hydrocarbons within the first or second section, respectively; and heating a portion of the first or second section, respectively, with heat from hydrogenation.
2434. The method of claim 2403, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2435. The method of claim 2403, wherein heating the first section or heating the second section comprises increasing a permeability of a majority of the first or second section, respectively, to greater than about 100 millidarcy.
2436. The method of claim 2403, wherein heating the first section or heating the second section comprises substantially uniformly increasing a permeability of a majority of the first or second section, respectively.
2437. The method of claim 2403, further comprising controlling heating of the first or second section to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay, from the first or second section, respectively.
2438. The method of claim 2403, wherein producing the first or second mixture comprises producing the first or second mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2439. The method of claim 2438, wherein at least about 20 heat sources are disposed in the formation for each production well.
2440. The method of claim 2403, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2441. The method of claim 2403, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2442. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation through one or more production wells, wherein the heating is controlled such that the mixture can be produced from the formation as a vapor, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2443. The method of claim 2442, wherein at least about 20 heat sources are disposed in the formation for each production well.
2444. The method of claim 2442, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2445. The method of claim 2442, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2446. The method of claim 2442, wherein the one or more heat sources comprise electrical heaters.
2447. The method of claim 2442, wherein the one or more heat sources comprise surface burners.
2448. The method of claim 2442, wherein the one or more heat sources comprise flameless distributed combustors.
2449. The method of claim 2442, wherein the one or more heat sources comprise natural distributed combustors.
2450. The method of claim 2442, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2451. The method of claim 2442, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2452. The method of claim 2442, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C"*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulls density, and wherein the heating rate is less than about 10 °C/day.
2453. The method of claim 2442, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
244. The method of claim 2442, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2455. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2456. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1% by weight to about 15% by weight of the condensable hydrocarbons are olefins.
2457. The method of claim 2442, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2458. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2459. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2460. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2461. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2462. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2463. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2464. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2465. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2466. The method of claim 2442, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2467. The method of claim 2442, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2468. The method of claim 2442, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2469. The method of claim 2442, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2470. The method of claim 2442, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2471. The method of claim 2470, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2472. The method of claim 2442, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2473. The method of claim 2442, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2474. The method of claim 2442, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2475. The method of claim 2442, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2476. The method of claim 2442, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2477. The method of claim 2442, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2478. The method of claim 2442, wherein the heating is controlled to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2479. The method of claim 2442, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2480. The method of claim 2442, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2481. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation, wherein the one or more heat sources are disposed within one or more first wells;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation through one or more second wells, wherein one or more of the first or second wells are initially used for a first purpose and are then used for one or more other purposes.
2482. The method of claim 2481, wherein the first purpose comprises removing water from the formation, and wherein the second purpose comprises providing heat to the formation.
2483. The method of claim 2481, wherein the first purpose comprises removing water from the formation, and wherein the second purpose comprises producing the mixture.
2484. The method of claim 2481, wherein the first purpose comprises heating, and wherein the second purpose comprises removing water from the formation.
2485. The method of claim 2481, wherein the first purpose comprises producing the mixture, and wherein the second purpose comprises removing water from the formation.
2486. The method of claim 2481, wherein the one or more heat sources comprise electrical heaters.
2487. The method of claim 2481, wherein the one or more heat sources comprise surface burners.
2488. The method of claim 2481, wherein the one or more heat sources comprise flameless distributed combustors.
2489. The method of claim 2481, wherein the one or more heat sources comprise natural distributed combustors.
2490. The method of claim 2481, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2491. The method of claim 2481, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1.0°C per day during pyrolysis.
2492. The method of claim 2481, wherein providing heat from the one or more heat sources to at least the portion of the formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2493. The method of claim 2481, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2494. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2495. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1% by weight to about 15% by weight of the condensable hydrocarbons are olefins.
2496. The method of claim 2481, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2497. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2498. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2499. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2500. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2501. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2502. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2503. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2504. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2505. The method of claim 2481, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2506. The method of claim 2481, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2507. The method of claim 2481, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2508. The method of claim 2481, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2509. The method of claim 2481, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2510. The method of claim 2509, wherein the partial pressure of H2 is measured when the mixture is at a production well.
2511. The method of claim 2481, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2512. The method of claim 2481, further comprising controlling formation conditions, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
2513. The method of claim 2481, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2514. The method of claim 2481, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2515. The method of claim 2481, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2516. The method of claim 2481, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2517. The method of claim 2481, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2518. The method of claim 2481, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2519. The method of claim 2518, wherein at least about 20 heat sources are disposed in the formation for each production well.
2520. The method of claim 2481, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2521. The method of claim 2481, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2522. A method for forming heater wells in an oil shale formation, comprising:
forming a first wellbore in the formation;
forming a second wellbore in the formation using magnetic tracking such that the second wellbore is arranged substantially parallel to the first wellbore; and providing at least one heat source within the first wellbore and at least one heat source within the second wellbore such that the heat sources can provide heat to at least a portion of the formation.
2523. The method of claim 2522, wherein superposition of heat from the at least one heat source within the first wellbore and the at least one heat source within the second wellbore pyrolyzes at least some hydrocarbons within a selected section of the formation.
2524. The method of claim 2522, further comprising maintaining a temperature within a selected section within a pyrolysis temperature range.
2525. The method of claim 2522, wherein the heat sources comprise electrical heaters.
2526. The method of claim 2522, wherein the heat sources comprise surface burners.
2527. The method of claim 2522, wherein the heat sources comprise flameless distributed combustors.
2528. The method of claim 2522, wherein the heat sources comprise natural distributed combustors.
2529. The method of claim 2522, further comprising controlling a pressure and a temperature within at least a majority of a selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2530. The method of claim 2522, further comprising controlling the heat from the heat sources such that heat transferred from the heat sources to at least the portion of the hydrocarbons is less than about 1 °C per day during pyrolysis.
2531. The method of claim 2522, further comprising:
heating a selected volume (V) of the oil shale formation from the heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2532. The method of claim 2522, further comprising allowing the heat to transfer from the heat sources to at least the portion of the formation substantially by conduction.
2533. The method of claim 2522, further comprising providing heat from the heat sources to at least the portion of the formation such that a thermal conductivity of at least the portion of the formation is greater than about 0.5 W/(m °C).
2534. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2535. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2536. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2537. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2538. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2539. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2540. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2541. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2542. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2543. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2544. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2545. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2546. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2547. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2548. The method of claim 2522, further comprising controlling a pressure within at least a majority of a selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2549. The method of claim 2522, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2550. The method of claim 2522, further comprising producing a mixture from the formation, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2551. The method of claim 2522, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2552. The method of claim 2522, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2553. The method of claim 2522, further comprising:
providing hydrogen (H2) to the portion to hydrogenate hydrocarbons within the formation; and heating a portion of the formation with heat from hydrogenation.
2554. The method of claim 2522, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2555. The method of claim 2522, further comprising allowing heat to transfer from the heat sources to a selected section of the formation to pyrolyze at least some hydrocarbons within the selected section such that a permeability of a majority of a selected section of the formation increases to greater than about 100 millidarcy.
2556. The method of claim 2522, further comprising allowing heat to transfer from the heat sources to a selected section of the formation to pyrolyze at least some hydrocarbons within the selected section such that a permeability of a majority of the selected section increases substantially uniformly.
2557. The method of claim 2522, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2558. The method of claim 2522, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2559. The method of claim 2558, wherein at least about 20 heat sources are disposed in the formation for each production well.
2560. The method of claim 2522, further comprising forming a production well in the formation using magnetic tracking such that the production well is substantially parallel to the first wellbore and coupling a wellhead to the third wellbore.
2561. The method of claim 2522, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2562. The method of claim 2522, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2563. A method for installing a heater well into an oil shale formation, comprising:
forming a bore in the ground using a steerable motor and an accelerometer; and providing a heat source within the bore such that the heat source can transfer heat to at least a portion of the formation.
2564. The method of claim 2563, further comprising installing at least two heater wells, and wherein superposition of heat from at least the two heater wells pyrolyzes at least some hydrocarbons within a selected section of the formation.
2565. The method of claim 2563, further comprising maintaining a temperature within a selected section within a pyrolysis temperature range.
2566. The method of claim 2563, wherein the heat source comprises an electrical heater.
2567. The method of claim 2563, wherein the heat source comprises a surface burner.
2568. The method of claim 2563, wherein the heat source comprises a flameless distributed combustor.
2569. The method of claim 2563, wherein the heat source comprises a natural distributed combustor.
2570. The method of claim 2563, further comprising controlling a pressure and a temperature within at least a majority of a selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2571. The method of claim 2563, further comprising controlling the heat from the heat source such that heat transferred from the heat source to at least the portion of the formation is less than about 1 °C per day during pyrolysis.
2572. The method of claim 2563, further comprising:
heating a selected volume (V) of the oil shale formation from the heat source, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2573. The method of claim 2563, further comprising allowing the heat to transfer from the heat source to at least the portion of the formation substantially by conduction.
2574. The method of claim 2563, further comprising providing heat from the heat source to at least the portion of the formation such that a thermal conductivity of at least the portion of the formation is greater than about 0.5 W/(m °C).
2575. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2576. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2577. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2578. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2579. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2580. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2581. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2582. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2583. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2584. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2585. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2586. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2587. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2588. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2589. The method of claim 2563, further comprising controlling a pressure within at least a majority of a selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2590. The method of claim 2563, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2591. The method of claim 2563, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2592. The method of claim 2563, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2593. The method of claim 2563, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2594. The method of claim 2563, further comprising:
providing hydrogen (H2) to the at least the heated portion to hydrogenate hydrocarbons within the formation; and heating a portion of the formation with heat from hydrogenation.
2595. The method of claim 2563, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2596. The method of claim 2563, further comprising allowing heat to transfer from the heat source to a selected section of the formation to pyrolyze at least some hydrocarbons within the selected section such that a permeability of a majority of a selected section of the formation increases to greater than about 100 millidarcy.
2597. The method of claim 2563, further comprising allowing heat to transfer from the heat source to a selected section of the formation to pyrolyze at least some hydrocarbons within the selected section such that a permeability of a majority of the selected section increases substantially uniformly.
2598. The method of claim 2563, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2599. The method of claim 2563, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2600. The method of claim 2599, wherein at least about 20 heat sources are disposed in the formation for each production well.
2601. The method of claim 2563, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2602. The method of claim 2563, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2603. A method for installing of wells in an oil shale formation, comprising:
forming a wellbore in the formation by geosteered drilling; and providing a heat source within the wellbore such that the heat source can transfer heat to at least a portion of the formation.
2604. The method of claim 2603, further comprising maintaining a temperature within a selected section within a pyrolysis temperature range.
2605. The method of claim 2603, wherein the heat source comprises an electrical heater.
2606. The method of claim 2603, wherein the heat source comprises a surface burner.
2607. The method of claim 2603, wherein the heat source comprises a flameless distributed combustor.
2608. The method of claim 2603, wherein the heat source comprises a natural distributed combustor.
2609. The method of claim 2603, further comprising controlling a pressure and a temperature within at least a majority of a selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2610. The method of claim 2603, further comprising controlling the heat from the heat source such that heat transferred from the heat source to at least the portion of the formation is less than about 1 °C per day during pyrolysis.
2611. The method of claim 2603, further comprising:
heating a selected volume (V) of the oil shale formation from the heat source, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2612. The method of claim 2603, further comprising allowing the heat to transfer from the heat source to at least the portion of the formation substantially by conduction.
2613. The method of claim 2603, further comprising providing heat from the heat source to at least the portion of the formation such that a thermal conductivity of at least the portion of the formation is greater than about 0.5 W/(m °C).
2614. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2615. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2616. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2617. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2618. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2619. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2620. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2621. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2622. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2623. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2624. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2625. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2626. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2627. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2628. The method of claim 2603, further comprising controlling a pressure within at least a majority of a selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2629. The method of claim 2603, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2630. The method of claim 2629, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2631. The method of claim 2603, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2632. The method of claim 2603, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2633. The method of claim 2603, further comprising:
providing hydrogen (H2) to at least the heated portion to hydrogenate hydrocarbons within the formation;
and heating a portion of the formation with heat from hydrogenation.
2634. The method of claim 2603, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2635. The method of claim 2603, further comprising allowing heat to transfer from the heat source to a selected section of the formation to pyrolyze at least some hydrocarbons within the selected section such that a permeability of a majority of a selected section of the formation increases to greater than about 100 millidarcy.
2636. The method of claim 2603, further comprising allowing heat to transfer from the heat source to a selected section of the formation to pyrolyze at least some hydrocarbons within the selected section such that a permeability of a majority of the selected section increases substantially uniformly.
2637. The method of claim 2603, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2638. The method of claim 2603, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2639. The method of claim 2638, wherein at least about 20 heat sources are disposed in the formation for each production well.
2640. The method of claim 2603, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2641. The method of claim 2603, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2642. A method of treating an oil shale formation in situ, comprising:
heating a selected section of the formation with a heating element placed within a wellbore, wherein at least one end of the heating element is free to move axially within the wellbore to allow for thermal expansion of the heating element.
2643. The method of claim 2642, further comprising at least two heating elements within at least two wellbores, and wherein superposition of heat from at least the two heating elements pyrolyzes at least some hydrocarbons within a selected section of the formation.
2644. The method of claim 2642, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2645. The method of claim 2642, wherein the heating element comprises a pipe-in-pipe heater.
2646. The method of claim 2642, wherein the heating element comprises a flameless distributed combustor.
2647. The method of claim 2642, wherein the heating element comprises a mineral insulated cable coupled to a support, and wherein the support is free to move within the wellbore.
2648. The method of claim 2642, wherein the heating element comprises a mineral insulated cable suspended from a wellhead.
2649. The method of claim 2642, further comprising controlling a pressure and a temperature within at least a majority of a heated section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2650. The method of claim 2642, further comprising controlling the heat such that an average heating rate of the heated section is less than about 1 °C per day during pyrolysis.
2651. The method of claim 2642, wherein heating the section of the formation further comprises:
heating a selected volume (V) of the oil shale formation from the heating element, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2652. The method of claim 2642, wherein heating the section of the formation comprises transferring heat substantially by conduction.
2653. The method of claim 2642, further comprising heating the selected section of the formation such that a thermal conductivity of the selected section is greater than about 0.5 W/(m °C).
2654. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2655. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2656. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2657. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2658. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2659. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2660. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2661. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2662. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2663. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2664. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2665. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2666. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2667. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2668. The method of claim 2642, further comprising controlling a pressure within the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2669. The method of claim 2642, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2670. The method of claim 2669, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2671. The method of claim 2642, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2672. The method of claim 2642, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2673. The method of claim 2642, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the heated section; and heating a portion of the section with heat from hydrogenation.
2674. The method of claim 2642, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2675. The method of claim 2642, wherein heating comprises increasing a permeability of a majority of the heated section to greater than about 100 millidarcy.
2676. The method of claim 2642, wherein heating comprises substantially uniformly increasing a permeability of a majority of the heated section.
2677. The method of claim 2642, wherein the heating is controlled to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2678. The method of claim 2642, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2679. The method of claim 2678, wherein at least about 20 heat sources are disposed in the formation for each production well.
2680. The method of claim 2642, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2681. The method of claim 2642, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2682. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation through a production well, wherein the production well is located such that a majority of the mixture produced from the formation comprises non-condensable hydrocarbons and a non-condensable component comprising hydrogen.
2683. The method of claim 2682, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2684. The method of claim 2682, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2685. The method of claim 2682, wherein the production well is less than approximately 6 m from a heat source of the one or more heat sources.
2686. The method of claim 2682, wherein the production well is less than approximately 3 m from a heat source of the one or more heat sources.
2687. The method of claim 2682, wherein the production well is less than approximately 1.5 m from a heat source of the one or more heat sources.
2688. The method of claim 2682, wherein an additional heat source is positioned within a wellbore of the production well.
2689. The method of claim 2682, wherein the one or more heat sources comprise electrical heaters.
2690. The method of claim 2682, wherein the one or more heat sources comprise surface burners.
2691. The method of claim 2682, wherein the one or more heat sources comprise flameless distributed combustors.
2692. The method of claim 2682, wherein the one or more heat sources comprise natural distributed combustors.
2693. The method of claim 2682, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2694. The method of claim 2682, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2695. The method of claim 2682, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulls density, and wherein the heating rate is less than about 10 °C/day.
2696. The method of claim 2682, wherein allowing the heat to transfer from the one or more heat sources to the selected section comprises transferring heat substantially by conduction.
2697. The method of claim 2682, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2698. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2699. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2700. The method of claim 2682, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2701. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2702. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2703. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2704. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2705. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2706. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2707. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2708. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2709. The method of claim 2682, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2710. The method of claim 2682, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2711. The method of claim 2682, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2712. The method of claim 2682, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2713. The method of claim 2682, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2714. The method of claim 2713, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2715. The method of claim 2682, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2716. The method of claim 2682, further comprising controlling formation conditions by recirculating a portion of the hydrogen from the mixture into the formation.
2717. The method of claim 2682, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2718. The method of claim 2682, further comprising:
producing condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2719. The method of claim 2682, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2720. The method of claim 2682, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2721. The method of claim 2682, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2722. The method of claim 2682, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2723. The method of claim 2722, wherein at least about 20 heat sources are disposed in the formation for each production well.
2724. The method of claim 2682, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2725. The method of claim 2682, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2726. A method of treating an oil shale formation in situ, comprising:
providing heat to at least a portion of the formation from one or more first heat sources placed within a pattern in the formation;
allowing the heat to transfer from the one or more first heat sources to a first section of the formation;
heating a second section of the formation with at least one second heat source, wherein the second section is located within the first section, and wherein at least the one second heat source is configured to raise an average temperature of a portion of the second section to a higher temperature than an average temperature of the first section; and producing a mixture from the formation through a production well positioned within the second section, wherein a majority of the produced mixture comprises non-condensable hydrocarbons and a non-condensable component comprising H2 components.
2727. The method of claim 2726, wherein the one or more first heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the first section of the formation.
2728. The method of claim 2726, further comprising maintaining a temperature within the first section within a pyrolysis temperature range.
2729. The method of claim 2726, wherein at least the one heat source comprises a heater element positioned within the production well.
2730. The method of claim 2726, wherein at least the one second heat source comprises an electrical heater.
2731. The method of claim 2726, wherein at least the one second heat source comprises a surface burner.
2732. The method of claim 2726, wherein at least the one second heat source comprises a flameless distributed combustor.
2733. The method of claim 2726, wherein at least the one second heat source comprises a natural distributed combustor.
2734. The method of claim 2726, further comprising controlling a pressure and a temperature within at least a majority of the first or the second section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2735. The method of claim 2726, further comprising controlling the heat such that an average heating rate of the first section is less than about 1 °C per day during pyrolysis.
2736. The method of claim 2726, wherein providing heat to the formation further comprises:
heating a selected volume (V) of the oil shale formation from the one or more first heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C"*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2737. The method of claim 2726, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2738. The method of claim 2726, wherein providing heat from the one or more first heat sources comprises heating the first section such that a thermal conductivity of at least a portion of the first section is greater than about 0.5 W/(m °C).
2739. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2740. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2741. The method of claim 2726, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2742. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2743. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2744. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2745. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2746. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2747. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises mufti-ring aromatics with more than two rings.
2748. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2749. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2750. The method of claim 2726, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2751. The method of claim 2726, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2752. The method of claim 2726, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2753. The method of claim 2726, further comprising controlling a pressure within at least a majority of the first or the second section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2754. The method of claim 2726, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2755. The method of claim 2754, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2756. The method of claim 2726, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2757. The method of claim 2726, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2758. The method of claim 2726, further comprising:
providing hydrogen (H2) to the first or second section to hydrogenate hydrocarbons within the first or second section, respectively; and heating a portion of the first or second section, respectively, with heat from hydrogenation.
2759. The method of claim 2726, further comprising:
producing condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2760. The method of claim 2726, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the first or second section to greater than about 100 millidarcy.
2761. The method of claim 2726, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the first or second section.
2762. The method of claim 2726, wherein heating the first or the second section is controlled to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2763. The method of claim 2726, wherein at least about 7 heat sources are disposed in the formation for each production well.
2764. The method of claim 2763, wherein at least about 20 heat sources are disposed in the formation for each production well.
2765. The method of claim 2726, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2766. The method of claim 2726, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2767. A method of treating an oil shale formation in situ, comprising:
providing heat into the formation from a plurality of heat sources placed in a pattern within the formation, wherein a spacing between heat sources is greater than about 6 m;
allowing the heat to transfer from the plurality of heat sources to a selected section of the formation; and producing a mixture from the formation from a plurality of production wells, wherein the plurality of production wells are positioned within the pattern, and wherein a spacing between production wells is greater than about 12 m.
2768. The method of claim 2767, wherein superposition of heat from the plurality of heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2769. The method of claim 2767, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2770. The method of claim 2767, wherein the plurality of heat sources comprises electrical heaters.
2771. The method of claim 2767, wherein the plurality of heat sources comprises surface burners.
2772. The method of claim 2767, wherein the plurality of heat sources comprises flameless distributed combustors.
2773. The method of claim 2767, wherein the plurality of heat sources comprises natural distributed combustors.
2774. The method of claim 2767, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2775. The method of claim 2767, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2776. The method of claim 2767, wherein providing heat from the plurality of heat sources comprises:
heating a selected volume (V) of the oil shale formation from the plurality of heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, ~is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2777. The method of claim 2767, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2778. The method of claim 2767, wherein providing heat comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2779. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2780. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2781. The method of claim 2767, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2782. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2783. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2784. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2785. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2786. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2787. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2788. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2789. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2790. The method of claim 2767, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2791. The method of claim 2767, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2792. The method of claim 2767, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2793. The method of claim 2767, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2794. The method of claim 2767, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2795. The method of claim 2794, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2796. The method of claim 2767, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2797. The method of claim 2767, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2798. The method of claim 2767, further comprising:
providing hydrogen (H2) to the selected section to hydrogenate hydrocarbons within the selected section;
and heating a portion of the selected section with heat from hydrogenation.
2799. The method of claim 2767, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2800. The method of claim 2767, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2801. The method of claim 2767, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2802. The method of claim 2767, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2803. The method of claim 2767, wherein at least about 7 heat sources are disposed in the formation for each production well.
2804. The method of claim 2803, wherein at least about 20 heat sources are disposed in the formation for each production well.
2805. The method of claim 2767, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2806. The method of claim 2767, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2807. A system configured to heat an oil shale formation, comprising:
a heater disposed in an opening in the formation, wherein the heater is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2808. The system of claim 2807, wherein the oxidizing fluid is configured to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
2809. The system of claim 2807, wherein the conduit comprises orifices, and wherein the orifices are configured to provide the oxidizing fluid into the opening.
2810. The system of claim 2807, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configured to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
2811. The system of claim 2807, wherein the conduit is further configured to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
2812. The system of claim 2807, wherein the conduit is further configured to remove an oxidation product.
2813. The system of claim 2807, wherein the conduit is further configured to remove an oxidation product such that the oxidation product transfers substantial heat to the oxidizing fluid.
2814. The system of claim 2807, wherein the conduit is further configured to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2815. The system of claim 2807, wherein the conduit is further configured to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
2816. The system of claim 2807, wherein the conduit is further configured to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2817. The system of claim 2807, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2818. The system of claim 2807, further comprising a center conduit disposed within the conduit, wherein the center conduit is configured to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configured to remove an oxidation product during use.
2819. The system of claim 2807, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2820. The system of claim 2807, further comprising a conductor disposed in a second conduit, wherein the second conduit is disposed within the opening, and wherein the conductor is configured to heat at least a portion of the formation during application of an electrical current to the conductor.
2821. The system of claim 2807, further comprising an insulated conductor disposed within the opening, wherein the insulated conductor is configured to heat at least a portion of the formation during application of an electrical current to the insulated conductor.
2822. The system of claim 2807, further comprising at least one elongated member disposed within the opening, wherein the at least the one elongated member is configured to heat at least a portion of the formation during application of an electrical current to the at least the one elongated member.
2823. The system of claim 2807, further comprising a heat exchanger disposed external to the formation, wherein the heat exchanger is configured to heat the oxidizing fluid, wherein the conduit is further configured to provide the heated oxidizing fluid into the opening during use, and wherein the heated oxidizing fluid is configured to heat at least a portion of the formation during use.
2824. The system of claim 2807, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2825. The system of claim 2807, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2826. The system of claim 2807, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2827. The system of claim 2807, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2828. The system of claim 2807, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configured to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
2829. The system of claim 2807, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
2830. The system of claim 2807, wherein the system is further configured such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
2831. A system configurable to heat an oil shale formation, comprising:
a heater configurable to be disposed in an opening in the formation, wherein the heater is further configurable to provide heat to at least a portion of the formation during use;
a conduit configurable to be disposed in the opening, wherein the conduit is configurable to provide an oxidizing fluid from an oxidizing fluid source to a reaction zone in the formation during use, and wherein the system is configurable to allow the oxidizing fluid to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone; and wherein the system is further configurable to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2832. The system of claim 2831, wherein the oxidizing fluid is configurable to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
2833. The system of claim 2831, wherein the conduit comprises orifices, and wherein the orifices are configurable to provide the oxidizing fluid into the opening.
2834. The system of claim 2831, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configurable to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
2835. The system of claim 2831, wherein the conduit is further configurable to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
2836. The system of claim 2831, wherein the conduit is further configurable to remove an oxidation product.
2837. The system of claim 2831, wherein the conduit is further configurable to remove an oxidation product, such that the oxidation product transfers heat to the oxidizing fluid.
2838. The system of claim 2831, wherein the conduit is further configurable to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2839. The system of claim 2831, wherein the conduit is further configurable to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
2840. The system of claim 2831, wherein the conduit is further configurable to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2841. The system of claim 2831, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2842. The system of claim 2831, further comprising a center conduit disposed within the conduit, wherein the center conduit is configurable to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configurable to remove an oxidation product during use.
2843. The system of claim 2831, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2844. The system of claim 2831, further comprising a conductor disposed in a second conduit, wherein the second conduit is disposed within the opening, and wherein the conductor is configurable to heat at least a portion of the formation during application of an electrical current to the conductor.
2845. The system of claim 2831, further comprising an insulated conductor disposed within the opening, wherein the insulated conductor is configurable to heat at least a portion of the formation during application of an electrical current to the insulated conductor.
2846. The system of claim 2831, further comprising at least one elongated member disposed within the opening, wherein the at least the one elongated member is configurable to heat at least a portion of the formation during application of an electrical current to the at least the one elongated member.
2847. The system of claim 2831, further comprising a heat exchanger disposed external to the formation, wherein the heat exchanger is configurable to heat the oxidizing fluid, wherein the conduit is further configurable to provide the heated oxidizing fluid into the opening during use, and wherein the heated oxidizing fluid is configurable to heat at least a portion of the formation during use.
2848. The system of claim 2831, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2849. The system of claim 2831, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2850. The system of claim 2831, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2851. The system of claim 2831, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2852. The system of claim 2831, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configurable to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
2853. The system of claim 2831, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
2854. The system of claim 2831, wherein the system is further configurable such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
2855. The system of claim 2831, wherein the system is configured to heat an oil shale formation, and wherein the system comprises:
a heater disposed in an opening in the formation, wherein the heater is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2856. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing fluid to react with at least a portion of the hydrocarbons at the reaction zone to generate heat at the reaction zone; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
2857. The method of claim 2856, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
2858. The method of claim 2856, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a conduit disposed in the opening.
2859. The method of claim 2856, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a conduit disposed in the opening such that a rate of oxidation is controlled.
2860. The method of claim 2856, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially constant over time within the reaction zone.
2861. The method of claim 2856, wherein a conduit is disposed in the opening, the method further comprising cooling the conduit with the oxidizing fluid to reduce heating of the conduit by oxidation.
2862. The method of claim 2856, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit.
2863. The method of claim 2856, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and transferring heat from the oxidation product in the conduit to oxidizing fluid in the conduit.
2864. The method of claim 2856, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2865. The method of claim 2856, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
2866. The method of claim 2856, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
2867. The method of claim 2856, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
2868. The method of claim 2856, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the outer conduit.
2869. The method of claim 2856, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2870. The method of claim 2856, wherein heating the portion comprises applying electrical current to a conductor disposed in a conduit, wherein the conduit is disposed within the opening.
2871. The method of claim 2856, wherein heating the portion comprises applying electrical current to an insulated conductor disposed within the opening.
2872. The method of claim 2856, wherein heating the portion comprises applying electrical current to at least one elongated member disposed within the opening.
2873. The method of claim 2856, wherein heating the portion comprises heating the oxidizing fluid in a heat exchanger disposed external to the formation such that providing the oxidizing fluid into the opening comprises transferring heat from the heated oxidizing fluid to the portion.
2874. The method of claim 2856, further comprising removing water from the formation prior to heating the portion.
2875. The method of claim 2856, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
2876. The method of claim 2856, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2877. The method of claim 2856, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2878. The method of claim 2856, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2879. The method of claim 2856, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2880. The method of claim 2856, wherein the pyrolysis zone is substantially adjacent to the reaction zone.
2881. A system configured to heat an oil shale formation, comprising:
a heater disposed in an opening in the formation, wherein the heater is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone, and wherein the conduit is further configured to remove an oxidation product from the formation during use; and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2882. The system of claim 2881, wherein the oxidizing fluid is configured to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
2883. The system of claim 2881, wherein the conduit comprises orifices, and wherein the orifices are configured to provide the oxidizing fluid into the opening.
2884. The system of claim 2881, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configured to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
2885. The system of claim 2881, wherein the conduit is further configured to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
2886. The system of claim 2881, wherein the conduit is further configured such that the oxidation product transfers heat to the oxidizing fluid.
2887. The system of claim 2881, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2888. The system of claim 2881, wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
2889. The system of claim 2881, wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2890. The system of claim 2881, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2891. The system of claim 2881, further comprising a center conduit disposed within the conduit, wherein the center conduit is configured to provide the oxidizing fluid into the opening during use.
2892. The system of claim 2881, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2893. The system of claim 2881, further comprising a conductor disposed in a second conduit, wherein the second conduit is disposed within the opening, and wherein the conductor is configured to heat at least a portion of the formation during application of an electrical current to the conductor.
2894. The system of claim 2881, further comprising an insulated conductor disposed within the opening, wherein the insulated conductor is configured to heat at least a portion of the formation during application of an electrical current to the insulated conductor.
2895. The system of claim 2881, further comprising at least one elongated member disposed within the opening, wherein the at least the one elongated member is configured to heat at least a portion of the formation during application of an electrical current to the at least the one elongated member.
2896. The system of claim 2881, further comprising a heat exchanger disposed external to the formation, wherein the heat exchanger is configured to heat the oxidizing fluid, wherein the conduit is further configured to provide the heated oxidizing fluid into the opening during use, and wherein the heated oxidizing fluid is configured to heat at least a portion of the formation during use.
2897. The system of claim 2881, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2898. The system of claim 2881, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2899. The system of claim 2881, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2900. The system of claim 2881, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2901. The system of claim 2881, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configured to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
2902. The system of claim 2881, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
2903. The system of claim 2881, wherein the system is further configured such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
2904. A system configurable to heat an oil shale formation, comprising:
a heater configurable to be disposed in an opening in the formation, wherein the heater is further configurable to provide heat to at least a portion of the formation during use;
a conduit configurable to be disposed in the opening, wherein the conduit is further configurable to provide an oxidizing fluid from an oxidizing fluid source to a reaction zone in the formation during use, wherein the system is configurable to allow the oxidizing fluid to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone, and wherein the conduit is further configurable to remove an oxidation product from the formation during use; and wherein the system is further configurable to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone during use.
2905. The system of claim 2904, wherein the oxidizing fluid is configurable to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
2906. The system of claim 2904, wherein the conduit comprises orifices, and wherein the orifices are configurable to provide the oxidizing fluid into the opening.
2907. The system of claim 2904, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configurable to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
2908. The system of claim 2904, wherein the conduit is further configurable to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
2909. The system of claim 2904, wherein the conduit is further configurable such that the oxidation product transfers heat to the oxidizing fluid.
2910. The system of claim 2904, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2911. The system of claim 2904, wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
2912. The system of claim 2904, wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2913. The system of claim 2904, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2914. The system of claim 2904, further comprising a center conduit disposed within the conduit, wherein the center conduit is configurable to provide the oxidizing fluid into the opening during use.
2915. The system of claim 2904, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2916. The system of claim 2904, further comprising a conductor disposed in a second conduit, wherein the second conduit is disposed within the opening, and wherein the conductor is configurable to heat at least a portion of the formation during application of an electrical current to the conductor.
2917. The system of claim 2904, further comprising an insulated conductor disposed within the opening, wherein the insulated conductor is configurable to heat at least a portion of the formation during application of an electrical current to the insulated conductor.
2918. The system of claim 2904, further comprising at least one elongated member disposed within the opening, wherein the at least the one elongated member is configurable to heat at least a portion of the formation during application of an electrical current to the at least the one elongated member.
2919. The system of claim 2904, further comprising a heat exchanger disposed external to the formation, wherein the heat exchanger is configurable to heat the oxidizing fluid, wherein the conduit is further configurable to provide the heated oxidizing fluid into the opening during use, and wherein the heated oxidizing fluid is configurable to heat at least a portion of the formation during use.
2920. The system of claim 2904, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2921. The system of claim 2904, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2922. The system of claim 2904, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2923. The system of claim 2904, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2924. The system of claim 2904, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configurable to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
2925. The system of claim 2904, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
2926. The system of claim 2904, wherein the system is further configurable such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
2927. The system of claim 2904, wherein the system is configured to heat an oil shale formation, and wherein the system comprises:
a heater disposed in an opening in the formation, wherein the heater is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone, and wherein the conduit is further configured to remove an oxidation product from the formation during use; and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2928. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein the portion is located substantially adjacent to an opening in the formation;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing gas to react with at least a portion of the hydrocarbons at the reaction zone to generate heat in the reaction zone;
removing at least a portion of an oxidation product through the opening; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
2929. The method of claim 2928, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
2930. The method of claim 2928, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a conduit disposed in the opening.
2931. The method of claim 2928, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a conduit disposed in the opening such that a rate of oxidation is controlled.
2932. The method of claim 2928, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially maintained within the reaction zone.
2933. The method of claim 2928, wherein a conduit is disposed in the opening, the method further comprising cooling the conduit with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
2934. The method of claim 2928, wherein a conduit is disposed within the opening, and wherein removing at least the portion of the oxidation product through the opening comprises removing at least the portion of the oxidation product through the conduit.
2935. The method of claim 2928, wherein a conduit is disposed within the opening, and wherein removing at least the portion of the oxidation product through the opening comprises removing at least the portion of the oxidation product through the conduit, the method further comprising transferring substantial heat from the oxidation product in the conduit to the oxidizing fluid in the conduit.
2936. The method of claim 2928, wherein a conduit is disposed within the opening, wherein removing at least the portion of the oxidation product through the opening comprises removing at least the portion of the oxidation product through the conduit, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2937. The method of claim 2928, wherein a conduit is disposed within the opening, and wherein removing at least the portion of the oxidation product through the opening comprises removing at least the portion of the oxidation product through the conduit, the method further comprising controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
2938. The method of claim 2928, wherein a conduit is disposed within the opening, and wherein removing at least the portion of the oxidation product through the opening comprises removing at least the portion of the oxidation product through the conduit, the method further comprising substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
2939. The method of claim 2928, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
2940. The method of claim 2928, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing at least a portion of the oxidation product through the outer conduit.
2941. The method of claim 2928, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2942. The method of claim 2928, wherein heating the portion comprises applying electrical current to a conductor disposed in a conduit, wherein the conduit is disposed within the opening.
2943. The method of claim 2928, wherein heating the portion comprises applying electrical current to an insulated conductor disposed within the opening.
2944. The method of claim 2928, wherein heating the portion comprises applying electrical current to at least one elongated member disposed within the opening.
2945. The method of claim 2928, wherein heating the portion comprises heating the oxidizing fluid in a heat exchanger disposed external to the formation such that providing the oxidizing fluid into the opening comprises transferring heat from the heated oxidizing fluid to the portion.
2946. The method of claim 2928, further comprising removing water from the formation prior to heating the portion.
2947. The method of claim 2928, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
2948. The method of claim 2928, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2949. The method of claim 2928, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2950. The method of claim 2928, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2951. The method of claim 2928, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2952. The method of claim 2928, wherein the pyrolysis zone is substantially adjacent to the reaction.
2953. A system configured to heat an oil shale formation, comprising:
an electric heater disposed in an opening in the formation, wherein the electric heater is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2954. The system of claim 2953, wherein the oxidizing fluid is configured to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
2955. The system of claim 2953, wherein the conduit comprises orifices, and wherein the orifices are configured to provide the oxidizing fluid into the opening.
2956. The system of claim 2953, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configured to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
2957. The system of claim 2953, wherein the conduit is further configured to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
2958. The system of claim 2953, wherein the conduit is further configured to remove an oxidation product.
2959. The system of claim 2953, wherein the conduit is further configured to remove an oxidation product, such that the oxidation product transfers heat to the oxidizing fluid.
2960. The system of claim 2953, wherein the conduit is further configured to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2961. The system of claim 2953, wherein the conduit is further configured to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
2962. The system of claim 2953, wherein the conduit is further configured to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2963. The system of claim 2953, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2964. The system of claim 2953, further comprising a center conduit disposed within the conduit, wherein the center conduit is configured to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configured to remove an oxidation product during use.
2965. The system of claim 2953, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2966. The system of claim 2953, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2967. The system of claim 2953, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2968. The system of claim 2953, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2969. The system of claim 2953, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2970. The system of claim 2953, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configured to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
2971. The system of claim 2953, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
2972. The system of claim 2953, wherein the system is further configured such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
2973. A system configurable to heat an oil shale formation, comprising:
an electric heater configurable to be disposed in an opening in the formation, wherein the electric heater is further configurable to provide heat to at least a portion of the formation during use, and wherein at least the portion is located substantially adjacent to the opening;
a conduit configurable to be disposed in the opening, wherein the conduit is further configurable to provide an oxidizing fluid from an oxidizing fluid source to a reaction zone in the formation during use, and wherein the system is configurable to allow the oxidizing fluid to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone; and wherein the system is further configurable to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2974. The system of claim 2973, wherein the oxidizing fluid is configurable to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
2975. The system of claim 2973, wherein the conduit comprises orifices, and wherein the orifices are configurable to provide the oxidizing fluid into the opening.
2976. The system of claim 2973, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configurable to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
2977. The system of claim 2973, wherein the conduit is further configurable to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
2978. The system of claim 2973, wherein the conduit is further configurable to remove an oxidation product.
2979. The system of claim 2973, wherein the conduit is further configurable to remove an oxidation product such that the oxidation product transfers heat to the oxidizing fluid.
2980. The system of claim 2973, wherein the conduit is further configurable to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2981. The system of claim 2973, wherein the conduit is further configurable to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
2982. The system of claim 2973, wherein the conduit is further configurable to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2983. The system of claim 2973, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2984. The system of claim 2973, further comprising a center conduit disposed within the conduit, wherein the center conduit is configurable to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configurable to remove an oxidation product during use.
2985. The system of claim 2973, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2986. The system of claim 2973, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2987. The system of claim 2973, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2988. The system of claim 2973, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2989. The system of claim 2973, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2990. The system of claim 2973, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configurable to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
2991. The system of claim 2973, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
2992. The system of claim 2973, wherein the system is further configurable such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
2993. The system of claim 2973, wherein the system is configured to heat an oil shale formation, and wherein the system comprises:
an electric heater disposed in an opening in the formation, wherein the electric heater is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2994. A system configured to heat an oil shale formation, comprising:
a conductor disposed in a first conduit, wherein the first conduit is disposed in an opening in the formation, and wherein the conductor is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a second conduit disposed in the opening, wherein the second conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone; and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2995. The system of claim 2994, wherein the oxidizing fluid is configured to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
2996. The system of claim 2994, wherein the second conduit comprises orifices, and wherein the orifices are configured to provide the oxidizing fluid into the opening.
2997. The system of claim 2994, wherein the second conduit comprises critical flow orifices, and wherein the critical flow orifices are configured to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
2998. The system of claim 2994, wherein the second conduit is further configured to be cooled with the oxidizing fluid to reduce heating of the second conduit by oxidation.
2999. The system of claim 2994, wherein the second conduit is further configured to remove an oxidation product.
3000. The system of claim 2994, wherein the second conduit is further configured to remove an oxidation product such that the oxidation product transfers heat to the oxidizing fluid.
3001. The system of claim 2994, wherein the second conduit is further configured to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the second conduit.
3002. The system of claim 2994, wherein the second conduit is further configured to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the second conduit and a pressure of the oxidation product in the second conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3003. The system of claim 2994, wherein the second conduit is further configured to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3004. The system of claim 2994, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3005. The system of claim 2994, further comprising a center conduit disposed within the second conduit, wherein the center conduit is configured to provide the oxidizing fluid into the opening during use, and wherein the second conduit is further configured to remove an oxidation product during use.
3006. The system of claim 2994, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3007. The system of claim 2994, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3008. The system of claim 2994, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3009. The system of claim 2994, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3010. The system of claim 2994, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3011. The system of claim 2994, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configured to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3012. The system of claim 2994, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3013. The system of claim 2994, wherein the system is further configured such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
3014. A system configurable to heat an oil shale formation, comprising:
a conductor configurable to be disposed in a first conduit, wherein the first conduit is configurable to be disposed in an opening in the formation, and wherein the conductor is further configurable to provide heat to at least a portion of the formation during use;
a second conduit configurable to be disposed in the opening, wherein the second conduit is further configurable to provide an oxidizing fluid from an oxidizing fluid source to a reaction zone in the formation during use, and wherein the system is configurable to allow the oxidizing fluid to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone; and wherein the system is further configurable to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3015. The system of claim 3014, wherein the oxidizing fluid is configurable to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
3016. The system of claim 3014, wherein the second conduit comprises orifices, and wherein the orifices are configurable to provide the oxidizing fluid into the opening.
3017. The system of claim 3014, wherein the second conduit comprises critical flow orifices, and wherein the critical flow orifices are configurable to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
3018. The system of claim 3014, wherein the second conduit is further configurable to be cooled with the oxidizing fluid to reduce heating of the second conduit by oxidation.
3019. The system of claim 3014, wherein the second conduit is further configurable to remove an oxidation product.
3020. The system of claim 3014, wherein the second conduit is further configurable to remove an oxidation product such that the oxidation product transfers heat to the oxidizing fluid.
3021. The system of claim 3014, wherein the second conduit is further configurable to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the second conduit.
3022. The system of claim 3014, wherein the second conduit is further configurable to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the second conduit and a pressure of the oxidation product in the second conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3023. The system of claim 3014, wherein the second conduit is further configurable to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3024. The system of claim 3014, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3025. The system of claim 3014, further comprising a center conduit disposed within the second conduit, wherein the center conduit is configurable to provide the oxidizing fluid into the opening during use, and wherein the second conduit is further configurable to remove an oxidation product during use.
3026. The system of claim 3014, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3027. The system of claim 3014, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3028. The system of claim 3014, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3029. The system of claim 3014, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3030. The system of claim 3014, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3031. The system of claim 3014, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configurable to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3032. The system of claim 3014, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3033. The system of claim 3014, wherein the system is further configurable such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
3034. The system of claim 3014, wherein the system is configured to heat an oil shale formation, and wherein the system comprises:
a conductor disposed in a first conduit, wherein the first conduit is disposed in an opening in the formation, and wherein the conductor is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a second conduit disposed in the opening, wherein the second conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone; and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3035. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein heating comprises applying an electrical current to a conductor disposed in a first conduit to provide heat to the portion, and wherein the first conduit is disposed within the opening;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing fluid to react with at least a portion of the hydrocarbons at the reaction zone to generate heat at the reaction zone; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
3036. The method of claim 3035, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
3037. The method of claim 3035, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a second conduit disposed in the opening.
3038. The method of claim 3035, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a second conduit disposed in the opening such that a rate of oxidation is controlled.
3039. The method of claim 3035, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially constant over time within the reaction zone.
3040. The method of claim 3035, wherein a second conduit is disposed in the opening, the method further comprising cooling the second conduit with the oxidizing fluid to reduce heating of the second conduit by oxidation.
3041. The method of claim 3035, wherein a second conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the second conduit.
3042. The method of claim 3035, wherein a second conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the second conduit and transferring heat from the oxidation product in the conduit to the oxidizing fluid in the second conduit.
3043. The method of claim 3035, wherein a second conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the second conduit, wherein a flow rate of the oxidizing fluid in the second conduit is approximately equal to a flow rate of the oxidation product in the second conduit.
3044. The method of claim 3035, wherein a second conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the second conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the second conduit to reduce contamination of the oxidation product by the oxidizing fluid.
3045. The method of claim 3035, wherein a second conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
3046. The method of claim 3035, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
3047. The method of claim 3035, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the outer conduit.
3048. The method of claim 3035, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3049. The method of claim 3035, further comprising removing water from the formation prior to heating the portion.
3050. The method of claim 3035, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
3051. The method of claim 3035, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3052. The method of claim 3035, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3053. The method of claim 3035, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3054. The method of claim 3035, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3055. A system configured to heat an oil shale formation, comprising:
an insulated conductor disposed in an opening in the formation, wherein the insulated conductor is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3056. The system of claim 3055, wherein the oxidizing fluid is configured to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
3057. The system of claim 3055, wherein the conduit comprises orifices, and wherein the orifices are configured to provide the oxidizing fluid into the opening.
3058. The system of claim 3055, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configured to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
3059. The system of claim 3055, wherein the conduit is configured to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
3060. The system of claim 3055, wherein the conduit is further configured to remove an oxidation product.
3061. The system of claim 3055, wherein the conduit is further configured to remove an oxidation product, and wherein the conduit is further configured such that the oxidation product transfers substantial heat to the oxidizing fluid.
3062. The system of claim 3055, wherein the conduit is further configured to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3063. The system of claim 3055, wherein the conduit is further configured to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the second conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3064. The system of claim 3055, wherein the conduit is further configured to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3065. The system of claim 3055, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3066. The system of claim 3055, further comprising a center conduit disposed within the conduit, wherein the center conduit is configured to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configured to remove an oxidation product during use.
3067. The system of claim 3055, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3068. The system of claim 3055, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3069. The system of claim 3055, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3070. The system of claim 3055, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3071. The system of claim 3055, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3072. The system of claim 3055, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configured to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3073. The system of claim 3055, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3074. The system of claim 3055, wherein the system is further configured such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
3075. A system configurable to heat an oil shale formation, comprising:
an insulated conductor configurable to be disposed in an opening in the formation, wherein the insulated conductor is further configurable to provide heat to at least a portion of the formation during use;
a conduit configurable to be disposed in the opening, wherein the conduit is further configurable to provide an oxidizing fluid from an oxidizing fluid source to a reaction zone in the formation during use, and wherein the system is configurable to allow the oxidizing fluid to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone; and wherein the system is further configurable to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3076. The system of claim 3075, wherein the oxidizing fluid is configurable to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
3077. The system of claim 3075, wherein the conduit comprises orifices, and wherein the orifices are configurable to provide the oxidizing fluid into the opening.
3078. The system of claim 3075, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configurable to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
3079. The system of claim 3075, wherein the conduit is further configurable to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
3080. The system of claim 3075, wherein the conduit is further configurable to remove an oxidation product.
3081. The system of claim 3075, wherein the conduit is further configurable to remove an oxidation product, such that the oxidation product transfers heat to the oxidizing fluid.
3082. The system of claim 3075, wherein the conduit is further configurable to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3083. The system of claim 3075, wherein the conduit is further configurable to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3084. The system of claim 3075, wherein the conduit is further configurable to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3085. The system of claim 3075, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3086. The system of claim 3075, further comprising a center conduit disposed within the conduit, wherein the center conduit is configurable to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configurable to remove an oxidation product during use.
3087. The system of claim 3075, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3088. The system of claim 3075, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3089. The system of claim 3075, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3090. The system of claim 3075, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3091. The system of claim 3075, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3092. The system of claim 3075, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configurable to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3093. The system of claim 3075, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3094. The system of claim 3075, wherein the system is further configurable such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
3095. The system of claim 3075, wherein the system is configured to heat an oil shale formation, and wherein the system comprises:
an insulated conductor disposed in an opening in the formation, wherein the insulated conductor is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3096. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein heating comprises applying an electrical current to an insulated conductor to provide heat to the portion, and wherein the insulated conductor is disposed within the opening;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing fluid to react with at least a portion of the hydrocarbons at the reaction zone to generate heat at the reaction zone; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
3097. The method of claim 3096, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
3098. The method of claim 3096, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a conduit disposed in the opening.
3099. The method of claim 3096, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a conduit disposed in the opening such that a rate of oxidation is controlled.
3100. The method of claim 3096, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially constant over time within the reaction zone.
3101. The method of claim 3096, wherein a conduit is disposed in the opening, the method further comprising cooling the conduit with the oxidizing fluid to reduce heating of the conduit by oxidation.
3102. The method of claim 3096, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from he formation through the conduit.
3103. The method of claim 3096, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and transferring heat from the oxidation product in the conduit to the oxidizing fluid in the conduit.
3104. The method of claim 3096, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3105. The method of claim 3096, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
3106. The method of claim 3096, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
3107. The method of claim 3096, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
3108. The method of claim 3096, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the outer conduit.
3109. The method of claim 3096, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3110. The method of claim 3096, further comprising removing water from the formation prior to heating the portion.
3111. The method of claim 3096, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
3112. The method of claim 3096, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3113. The method of claim 3096, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3114. The method of claim 3096, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3115. The method of claim 3096, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3116. The method of claim 3096, wherein the pyrolysis zone is substantially adjacent to the reaction zone.
3117. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein the portion is located substantially adjacent to an opening in the formation, wherein heating comprises applying an electrical current to an insulated conductor to provide heat to the portion, wherein the insulated conductor is coupled to a conduit, wherein the conduit comprises critical flow orifices, and wherein the conduit is disposed within the opening;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing fluid to react with at least a portion of the hydrocarbons at the reaction zone to generate heat at the reaction zone; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
3118. The method of clean 3117, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
3119. The method of claim 3117, further comprising controlling a flow of the oxidizing fluid with the critical flow orifices such that a rate of oxidation is controlled.
3120. The method of claim 3117, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially constant over time within the reaction zone.
3121. The method of claim 3117, further comprising cooling the conduit with the oxidizing fluid to reduce heating of the conduit by oxidation.
3122. The method of claim 3117, further comprising removing an oxidation product from the formation through the conduit.
3123. The method of claim 3117, further comprising removing an oxidation product from the formation through the conduit and transferring heat from the oxidation product in the conduit to the oxidizing fluid in the conduit.
3124. The method of claim 3117, further comprising removing an oxidation product from the formation through the conduit, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3125. The method of claim 3117, further comprising removing an oxidation product from the formation through the conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
3126. The method of claim 3117, further comprising removing an oxidation product from the formation through the conduit and substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
3127. The method of claim 3117, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
3128. The method of claim 3117, wherein a center conduit is disposed within the conduit, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the conduit.
3129. The method of claim 3117, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3130. The method of claim 3117, further comprising removing water from the formation prior to heating the portion.
3131. The method of claim 3117, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
3132. The method of claim 3117, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3133. The method of claim 3117, farther comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3134. The method of claim 3117, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3135. The method of claim 3117, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3136. The method of claim 3117, wherein the pyrolysis zone is substantially adjacent to the reaction zone.
3137. A system configured to heat an oil shale formation, comprising:
at least one elongated member disposed in an opening in the formation, wherein at least the one elongated member is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3138. The system of claim 3137, wherein the oxidizing fluid is configured to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
3139. The system of claim 3137, wherein the conduit comprises orifices, and wherein the orifices are configured to provide the oxidizing fluid into the opening.
3140. The system of claim 3137, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configured to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
3141. The system of claim 3137, wherein the conduit is further configured to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
3142. The system of claim 3137, wherein the conduit is further configured to remove an oxidation product.
3143. The system of claim 3137, wherein the conduit is further configured to remove an oxidation product such that the oxidation product transfers heat to the oxidizing fluid.
3144. The system of claim 3137, wherein the conduit is further configured to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3145. The system of claim 3137, wherein the conduit is further configured to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3146. The system of claim 3137, wherein the conduit is further configured to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3147. The system of claim 3137, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3148. The system of claim 3137, further comprising a center conduit disposed within the conduit, wherein the center conduit is configured to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configured to remove an oxidation product during use.
3149. The system of claim 3137, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3150. The system of claim 3137, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3151. The system of claim 3137, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3152. The system of claim 3137, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3153. The system of claim 3137, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3154. The system of claim 3137, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configured to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3155. The system of claim 3137, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3156. The system of claim 3137, wherein the system is further configured such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
3157. A system configurable to heat an oil shale formation, comprising:
at least one elongated member configurable to be disposed in an opening in the formation, wherein at least the one elongated member is further configurable to provide heat to at least a portion of the formation during use;
a conduit configurable to be disposed in the opening, wherein the conduit is further configurable to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the system is configurable to allow the oxidizing fluid to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone; and wherein the system is further configurable to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3158. The system of claim 3157, wherein the oxidizing fluid is configurable to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
3159. The system of claim 3157, wherein the conduit comprises orifices, and wherein the orifices are configurable to provide the oxidizing fluid into the opening.
3160. The system of claim 3157, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configurable to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
3161. The system of claim 3157, wherein the conduit is further configurable to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
3162. The system of claim 3157, wherein the conduit is further configurable to remove an oxidation product.
3163. The system of claim 3157, wherein the conduit is further configurable to remove an oxidation product such that the oxidation product transfers heat to the oxidizing fluid.
3164. The system of claim 3157, wherein the conduit is further configurable to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3165. The system of claim 3157, wherein the conduit is further configurable to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3166. The system of claim 3157, wherein the conduit is further configurable to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3167. The system of claim 3157, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3168. The system of claim 3157, further comprising a center conduit disposed within the conduit, wherein the center conduit is configurable to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configurable to remove an oxidation product during use.
3169. The system of claim 3157, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3170. The system of claim 3157, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3171. The system of claim 3157, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3172. The system of claim 3157, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3173. The system of claim 3157, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3174. The system of claim 3157, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configurable to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3175. The system of claim 3157, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3176. The system of claim 3157, wherein the system is further configurable such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
3177. The system of claim 3157, wherein the system is configured to heat an oil shale formation, and wherein the system comprises:
at least one elongated member disposed in an opening in the formation, wherein at least the one elongated member is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3178. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein heating comprises applying an electrical current to at least one elongated member to provide heat to the portion, and wherein at least the one elongated member is disposed within the opening;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing fluid to react with at least a portion of the hydrocarbons at the reaction zone to generate heat at the reaction zone; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
3179. The method of claim 3178, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
3180. The method of claim 3178, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a conduit disposed in the opening.
3181. The method of claim 3178, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a conduit disposed in the opening such that a rate of oxidation is controlled.
3182. The method of claim 3178, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially constant over time within the reaction zone.
3183. The method of claim 3178, wherein a conduit is disposed in the opening, the method further comprising cooling the conduit with the oxidizing fluid to reduce heating of the conduit by oxidation.
3184. The method of claim 3178, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit.
3185. The method of claim 3178, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and transferring heat from the oxidation product in the conduit to the oxidizing fluid in the conduit.
3186. The method of claim 3178, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3187. The method of claim 3178, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
3188. The method of claim 3178, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
3189. The method of claim 3178, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
3190. The method of claim 3178, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the outer conduit.
3191. The method of claim 3178, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3192. The method of claim 3178, further comprising removing water from the formation prior to heating the portion.
3193. The method of claim 3178, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
3194. The method of claim 3178, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3195. The method of claim 3178, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3196. The method of claim 3178, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3197. The method of claim 3178, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3198. The method of claim 3178, wherein the pyrolysis zone is substantially adjacent to the reaction zone.
3199. A system configured to heat an oil shale formation, comprising:
a heat exchanger disposed external to the formation, wherein the heat exchanger is configured to heat an oxidizing fluid during use;
a conduit disposed in the opening, wherein the conduit is configured to provide the heated oxidizing fluid from the heat exchanger to at least a portion of the formation during use, wherein the system is configured to allow heat to transfer from the heated oxidizing fluid to at least the portion of the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at a reaction zone in the formation during use such that heat is generated at the reaction zone; and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3200. The system of claim 3199, wherein the oxidizing fluid is configured to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
3201. The system of claim 3199, wherein the conduit comprises orifices, and wherein the orifices are configured to provide the oxidizing fluid into the opening.
3202. The system of claim 3199, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configured to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
3203. The system of claim 3199, wherein the conduit is further configured to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
3204. The system of claim 3199, wherein the conduit is further configured to remove an oxidation product.
3205. The system of claim 3199, wherein the conduit is further configured to remove an oxidation product, such that the oxidation product transfers heat to the oxidizing fluid.
3206. The system of claim 3199, wherein the conduit is further configured to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3207. The system of claim 3199, wherein the conduit is further configured to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3208. The system of claim 3199, wherein the conduit is further configured to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3209. The system of claim 3199, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3210. The system of claim 3199, further comprising a center conduit disposed within the conduit, wherein the center conduit is configured to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configured to remove an oxidation product during use.
3211. The system of claim 3199, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3212. The system of claim 3199, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3213. The system of claim 3199, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3214. The system of claim 3199, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3215. The system of claim 3199, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3216. The system of claim 3199, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configured to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3217. The system of claim 3199, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3218. A system configurable to heat an oil shale formation, comprising:
a heat exchanger configurable to be disposed external to the formation, wherein the heat exchanger is further configurable to heat an oxidizing fluid during use;
a conduit configurable to be disposed in the opening, wherein the conduit is further configurable to provide the heated oxidizing fluid from the heat exchanger to at least a portion of the formation during use, wherein the system is configurable to allow heat to transfer from the heated oxidizing fluid to at least the portion of the formation during use, and wherein the system is further configurable to allow the oxidizing fluid to oxidize at least some hydrocarbons at a reaction zone in the formation during use such that heat is generated at the reaction zone;
and wherein the system is further configurable to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3219. The system of claim 3218, wherein the oxidizing fluid is configurable to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
3220. The system of claim 3218, wherein the conduit comprises orifices, and wherein the orifices are configurable to provide the oxidizing fluid into the opening.
3221. The system of claim 3218, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configurable to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
3222. The system of claim 3218, wherein the conduit is further configurable to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
3223. The system of claim 3218, wherein the conduit is further configurable to remove an oxidation product.
3224. The system of claim 3218, wherein the conduit is further configurable to remove an oxidation product such that the oxidation product transfers heat to the oxidizing fluid.
3225. The system of claim 3218, wherein the conduit is further configurable to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3226. The system of claim 3218, wherein the conduit is further configurable to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3227. The system of claim 3218, wherein the conduit is further configurable to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3228. The system of claim 3218, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3229. The system of claim 3218, further comprising a center conduit disposed within the conduit, wherein the center conduit is configurable to provide the oxidizing fluid into the opening during use, and wherein the second conduit is further configurable to remove an oxidation product during use.
3230. The system of claim 3218, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3231. The system of claim 3218, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3232. The system of claim 3218, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3233. The system of claim 3218, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3234. The system of claim 3218, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3235. The system of claim 3218, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configurable to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3236. The system of claim 3218, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3237. The system of claim 3218, wherein the system is configured to heat an oil shale formation, and wherein the system comprises:
a heat exchanger disposed external to the formation, wherein the heat exchanger is configured to heat an oxidizing fluid during use;
a conduit disposed in the opening, wherein the conduit is configured to provide the heated oxidizing fluid from the heat exchanger to at least a portion of the formation during use, wherein the system is configured to allow heat to transfer from the heated oxidizing fluid to at least the portion of the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at a reaction zone in the formation during use such that heat is generated at the reaction zone; and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3238. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein heating comprises:
heating the oxidizing fluid with a heat exchanger, wherein the heat exchanger is disposed external to the formation;
providing the heated oxidizing fluid from the heat exchanger to the portion of the formation;
allowing heat to transfer from the heated oxidizing fluid to the portion of the formation;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing fluid to react with at least a portion of the hydrocarbons at the reaction zone to generate heat at the reaction zone; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
3239. The method of claim 3238, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
3240. The method of claim 3238, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a conduit disposed in the opening.
3241. The method of claim 3238, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a conduit disposed in the opening such that a rate of oxidation is controlled.
3242. The method of claim 3238, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially constant over time within the reaction zone.
3243. The method of claim 3238, wherein a conduit is disposed in the opening, the method further comprising cooling the conduit with the oxidizing fluid to reduce heating of the conduit by oxidation.
3244. The method of claim 3238, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit.
3245. The method of claim 3238, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and transferring heat from the oxidation product in the conduit to the oxidizing fluid in the conduit.
3246. The method of claim 3238, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3247. The method of claim 3238, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
3248. The method of claim 3238, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
3249. The method of claim 3238, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
3250. The method of claim 3238, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the outer conduit.
3251. The method of claim 3238, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3252. The method of claim 3238, further comprising removing water from the formation prior to heating the portion.
3253. The method of claim 3238, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
3254. The method of claim 3238, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3255. The method of claim 3238, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3256. The method of claim 3238, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3257. The method of claim 3238, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3258. The method of claim 3238, wherein the pyrolysis zone is substantially adjacent to the reaction zone.
3259. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein heating comprises:
oxidizing a fuel gas in a heater, wherein the heater is disposed external to the formation;
providing the oxidized fuel gas from the heater to the portion of the formation;
allowing heat to transfer from the oxidized fuel gas to the portion of the formation;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing fluid to react with at least a portion of the hydrocarbons at the reaction zone to generate heat at the reaction zone; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
3260. The method of claim 3259, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
3261. The method of claim 3259, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a conduit disposed in the opening.
3262. The method of claim 3259, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a conduit disposed in the opening such that a rate of oxidation is controlled.
3263. The method of claim 3259, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially constant over time within the reaction zone.
3264. The method of claim 3259, wherein a conduit is disposed in the opening, the method further comprising cooling the conduit with the oxidizing fluid to reduce heating of the conduit by oxidation.
3265. The method of claim 3259, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit.
3266. The method of claim 3259, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and transferring heat from the oxidation product in the conduit to the oxidizing fluid in the conduit.
3267. The method of claim 3259, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3268. The method of claim 3259, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
3269. The method of claim 3259, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
3270. The method of claim 3259, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
3271. The method of claim 3259, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the outer conduit.
3272. The method of claim 3259, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3273. The method of claim 3259, further comprising removing water from the formation prior to heating the portion.
3274. The method of claim 3259, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
3275. The method of claim 3259, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3276. The method of claim 3259, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3277. The method of claim 3259, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3278. The method of claim 3259, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3279. The method of claim 3259, wherein the pyrolysis zone is substantially adjacent to the reaction zone.
3280. A system configured to heat an oil shale formation, comprising:
an insulated conductor disposed within an open wellbore in the formation, wherein the insulated conductor is configured to provide radiant heat to at least a portion of the formation during use; and wherein the system is configured to allow heat to transfer from the insulated conductor to a selected section of the formation during use.
3281. The system of claim 3280, wherein the insulated conductor is further configured to generate heat during application of an electrical current to the insulated conductor during use.
3282. The system of claim 3280, further comprising a support member, wherein the support member is configured to support the insulated conductor.
3283. The system of claim 3280, further comprising a support member and a centralizes, wherein the support member is configured to support the insulated conductor, and wherein the centralizes is configured to maintain a location of the insulated conductor on the support member.
3284. The system of claim 3280, wherein the open wellbore comprises a diameter of at least approximately 5 cm.
3285. The system of claim 3280, further comprising a lead-in conductor coupled to the insulated conductor, wherein the lead-in conductor comprises a low resistance conductor configured to generate substantially no heat.
3286. The system of claim 3280, further comprising a lead-in conductor coupled to the insulated conductor, wherein the lead-in conductor comprises a rubber insulated conductor.
3287. The system of claim 3280, further comprising a lead-in conductor coupled to the insulated conductor, wherein the lead-in conductor comprises a copper wire.
3288. The system of claim 3280, further comprising a lead-in conductor coupled to the insulated conductor with a cold pin transition conductor.
3289. The system of claim 3280, further comprising a lead-in conductor coupled to the insulated conductor with a cold pin transition conductor, wherein the cold pin transition conductor comprises a substantially low resistance insulated conductor.
3290. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, and wherein the electrically insulating material is disposed in a sheath.
3291. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, and wherein the conductor comprises a copper-nickel alloy.
3292. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, wherein the conductor comprises a copper-nickel alloy, and wherein the copper-nickel alloy comprises approximately 7 % nickel by weight to approximately 12 % nickel by weight.
3293. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, wherein the conductor comprises a copper-nickel alloy, and wherein the copper-nickel alloy comprises approximately 2 % nickel by weight to approximately 6 %
nickel by weight.
3294. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, and wherein the electrically insulating material comprises a thermally conductive material.
3295. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, and wherein the electrically insulating material comprises magnesium oxide.
3296. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, wherein the electrically insulating material comprises magnesium oxide, and wherein the magnesium oxide comprises a thickness of at least approximately 1 mm.
3297. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, and wherein the electrically insulating material comprises aluminum oxide and magnesium oxide.
3298. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, wherein the electrically insulating material comprises magnesium oxide, wherein the magnesium oxide comprises grain particles, and wherein the grain particles are configured to occupy porous spaces within the magnesium oxide.
3299. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, and wherein the electrically insulating material is disposed in a sheath, and wherein the sheath comprises a corrosion-resistant material.
3300. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, and wherein the electrically insulating material is disposed in a sheath, and wherein the sheath comprises stainless steel.
3301. The system of claim 3280, further comprising two additional insulated conductors, wherein the insulated conductor and the two additional insulated conductors are configured in a 3-phase Y configuration.
3302. The system of claim 3280, further comprising an additional insulated conductor, wherein the insulated conductor and the additional insulated conductor are coupled to a support member, and wherein the insulated conductor and the additional insulated conductor are configured in a series electrical configuration.
3303. The system of claim 3280, further comprising an additional insulated conductor, wherein the insulated conductor and the additional insulated conductor are coupled to a support member, and wherein the insulated conductor and the additional insulated conductor are configured in a parallel electrical configuration.
3304. The system of claim 3280, wherein the insulated conductor is configured to generate radiant heat of approximately 500 W/m to approximately 1150 W/m during use.
3305. The system of claim 3280, further comprising a support member configured to support the insulated conductor, wherein the support member comprises orifices configured to provide fluid flow through the support member into the open wellbore during use.
3306. The system of claim 3280, further comprising a support member configured to support the insulated conductor, wherein the support member comprises critical flow orifices configured to provide a substantially constant amount of fluid flow through the support member into the open wellbore during use.
3307. The system of claim 3280, further comprising a tube coupled to the insulated conductor, wherein the tube is configured to provide a flow of fluid into the open wellbore during use.
3308. The system of claim 3280, further comprising a tube coupled to the insulated conductor, wherein the tube comprises critical flow orifices configured to provide a substantially constant amount of fluid flow through the support member into the open wellbore during use.
3309. The system of claim 3280, further comprising an overburden casing coupled to the open wellbore, wherein the overburden casing is disposed in an overburden of the formation.
3310. The system of claim 3280, further comprising an overburden casing coupled to the open wellbore, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
1. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least one portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
controlling the heat from the one or more heat sources such that an average temperature within at least a majority of the selected section of the formation is less than about 375 °C; and producing a mixture from the formation.
2. The method of claim 1, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
3. The method of claim 1, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
4. The method of claim 1, wherein the one or more heat sources comprise electrical heaters.
5. The method of claim 1, wherein the one or more heat sources comprise surface burners.
6. The method of claim 1, wherein the one or more heat sources comprise flameless distributed combustors.
7. The method of claim 1, wherein the one or more heat sources comprise natural distributed combustors.
8. The method of claim 1, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
9. The method of claim 1, further comprising controlling a pressure within at least a majority of the selected section of the formation with a valve coupled to at least one of the one or more heat sources.
10. The method of claim 1, further comprising controlling a pressure within at least a majority of the selected section of the formation with a valve coupled to a production well located in the formation.
11. The method of claim 1, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
12. The method of claim 1, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity(C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
13. The method of claim 1, wherein allowing the heat to transfer from the one or more heat sources to the selected section comprises transferring heat substantially by conduction.
14. The method of claim 1, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
15. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons having an API
gravity of at least about 25°.
16. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
17. The method of claim 1, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
18. The method of claim 1, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
19. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
20. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
21. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
22. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
23. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
24. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
25. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
26. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein about % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
27. The method of claim 1, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, and wherein greater than about 10 % by volume of the non-condensable component comprises hydrogen and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
28. The method of claim 1, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
29. The method of claim 1, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
30. The method of claim 1, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
31. The method of claim 1, further comprising controlling formation conditions such that the produced mixture comprises a partial pressure of H2 within the mixture greater than about 0.5 bars.
32. The method of claim 31, wherein the partial pressure of H2 is measured when the mixture is at a production well.
33. The method of claim 1, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
34. The method of claim 1, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
35. The method of claim 1, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
36. The method of claim 1, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
37. The method of claim 1, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
38. The method of claim 1, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
39. The method of claim 1, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
40. The method of claim 1, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
41. The method of claim 40, wherein at least about 20 heat sources are disposed in the formation for each production well.
42. The method of claim 1, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
43. The method of claim 1, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
44. The method of claim 1, further comprising separating the produced mixture into a gas stream and a liquid stream.
45. The method of claim 1, further comprising separating the produced mixture into a gas stream and a liquid stream and separating the liquid stream into an aqueous stream and a non-aqueous stream.
46. The method of claim 1, wherein the produced mixture comprises H2S, the method further comprising separating a portion of the H2S from non-condensable hydrocarbons.
47. The method of claim 1, wherein the produced mixture comprises CO2, the method further comprising separating a portion of the CO2 from non-condensable hydrocarbons.
48. The method of claim 1, wherein the mixture is produced from a production well, wherein the heating is controlled such that the mixture can be produced from the formation as a vapor.
49. The method of claim 1, wherein the mixture is produced from a production well, the method further comprising heating a wellbore of the production well to inhibit condensation of the mixture within the wellbore.
50. The method of claim 1, wherein the mixture is produced from a production well, wherein a wellbore of the production well comprises a heater element configured to heat the formation adjacent to the wellbore, and further comprising heating the formation with the heater element to produce the mixture, wherein the mixture comprises a large non-condensable hydrocarbon gas component and H2.
51. The method of claim 1, wherein the minimum pyrolysis temperature is about 270 °C.
52. The method of claim 1, further comprising maintaining the pressure within the formation above about 2.0 bars absolute to inhibit production of fluids having carbon numbers above 25.
53. The method of claim 1, further comprising controlling pressure within the formation in a range from about atmospheric pressure to about 100 bars, as measured at a wellhead of a production well, to control an amount of condensable hydrocarbons within the produced mixture, wherein the pressure is reduced to increase production of condensable hydrocarbons, and wherein the pressure is increased to increase production of non-condensable hydrocarbons.
54. The method of claim 1, further comprising controlling pressure within the formation in a range from about atmospheric pressure to about 100 bars, as measured at a wellhead of a production well, to control an API gravity of condensable hydrocarbons within the produced mixture, wherein the pressure is reduced to decrease the API
gravity, and wherein the pressure is increased to reduce the API gravity.
55. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from at least the portion to a selected section of the formation substantially by conduction of heat;
pyrolyzing at least some hydrocarbons within the selected section of the formation; and producing a mixture from the formation.
56. The method of claim 55, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
57. The method of claim 55, wherein the one or more heat sources comprise electrical heaters.
58. The method of claim 55, wherein the one or more heat sources comprise surface burners.
59. The method of claim 55, wherein the one or more heat sources comprise flameless distributed combustors.
60. The method of claim 55, wherein the one or more heat sources comprise natural distributed combustors.
61. The method of claim 55, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
62. The method of claim 55, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1.0 ° C per day during pyrolysis.
63. The method of claim 55, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
64. The method of claim 55, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
65. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons having an API
gravity of at least about 25°.
66. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
67. The method of claim 55, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
68. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
69. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
70. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
71. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
72. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
73. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises mufti-ring aromatics with more than two rings.
74. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
75. The method of claim 55, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
76. The method of claim 55, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
77. The method of claim 55, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
78. The method of claim 55, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
79. The method of claim 55, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
80. The method of claim 55, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
81. The method of claim 80, wherein the partial pressure of H2 is measured when the mixture is at a production well.
82. The method of claim 55, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
83. The method of claim 55, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
84. The method of claim 55, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
85. The method of claim 55, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
86. The method of claim 55, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
87. The method of claim 55, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
88. The method of claim 55, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
89. The method of claim 55, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
90. The method of claim 89, wherein at least about 20 heat sources are disposed in the formation for each production well.
91. The method of claim 55, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
92. The method of claim 55, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
93. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
controlling the heat from the one or more heat sources such that an average temperature within at least a majority of the selected section of the formation is less than about 370 °C such that production of a substantial amount of hydrocarbons having carbon numbers greater than 25 is inhibited;
controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least 2.0 bars; and producing a mixture from the formation, wherein about 0.1 % by weight of the produced mixture to about 15 % by weight of the produced mixture are olefins, and wherein an average carbon number of the produced mixture is greater than 1 and less than about 25.
94. The method of claim 93, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
95. The method of claim 93, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
96. The method of claim 93, wherein the one or more heat sources comprise electrical heaters.
97. The method of claim 93, wherein the one or more heat sources comprise surface burners.
98. The method of claim 93, wherein the one or more heat sources comprise flameless distributed combustors.
99. The method of claim 93, wherein the one or more heat sources comprise natural distributed combustors.
100. The method of claim 93, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
101. The method of claim 93, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
102. The method of claim 93, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
103. The method of claim 93, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
104. The method of claim 93, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
105. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
106. The method of claim 93, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
107. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
108. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
109. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
110. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
111. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
112. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
113. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
114. The method of claim 93, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
115. The method of claim 93, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
116. The method of claim 93, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
117. The method of claim 93, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
118. The method of claim 93, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
119. The method of claim 118, wherein the partial pressure of H2 is measured when the mixture is at a production well.
120. The method of claim 93, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
121. The method of claim 93, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
122. The method of claim 93, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
123. The method of claim 93, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
124. The method of claim 93, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
125. The method of claim 93, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
126. The method of claim 93, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
127. The method of claim 126, wherein at least about 20 heat sources are disposed in the formation for each production well.
128. The method of claim 93, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
129. The method of claim 93, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
130. The method of claim 93, further comprising separating the produced mixture into a gas stream and a liquid stream.
131. The method of claim 93, further comprising separating the produced mixture into a gas stream and a liquid stream and separating the liquid stream into an aqueous stream and a non-aqueous stream.
132. The method of claim 93, wherein the produced mixture comprises H2S, the method further comprising separating a portion of the H2S from non-condensable hydrocarbons.
133. The method of claim 93, wherein the produced mixture comprises CO2, the method further comprising separating a portion of the CO2 from non-condensable hydrocarbons.
134. The method of claim 93, wherein the mixture is produced from a production well, wherein the heating is controlled such that the mixture can be produced from the formation as a vapor.
135. The method of claim 93, wherein the mixture is produced from a production well, the method further comprising heating a wellbore of the production well to inhibit condensation of the mixture within the wellbore.
136. The method of claim 93, wherein the mixture is produced from a production well, wherein a wellbore of the production well comprises a heater element configured to heat the formation adjacent to the wellbore, and further comprising heating the formation with the heater element to produce the mixture, wherein the produced mixture comprise a large non-condensable hydrocarbon gas component and H2.
137. The method of claim 93, wherein the minimum pyrolysis temperature is about 270 °C.
138. The method of claim 93, further comprising maintaining the pressure within the formation above about 2.0 bars absolute to inhibit production of fluids having carbon numbers above 25.
139. The method of claim 93, further comprising controlling pressure within the formation in a range from about atmospheric pressure to about 100 bars absolute, as measured at a wellhead of a production well, to control an amount of condensable fluids within the produced mixture, wherein the pressure is reduced to increase production of condensable fluids, and wherein the pressure is increased to increase production of non-condensable fluids.
140. The method of claim 93, further comprising controlling pressure within the formation in a range from about atmospheric pressure to about 100 bars absolute, as measured at a wellhead of a production well, to control an API gravity of condensable fluids within the produced mixture, wherein the pressure is reduced to decrease the API
gravity, and wherein the pressure is increased to reduce the API gravity.
141. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute; and producing a mixture from the formation.
142. The method of claim 141, wherein controlling the pressure comprises controlling the pressure with a valve coupled to at least one of the one or more heat sources.
143. The method of claim 141, wherein controlling the pressure comprises controlling the pressure with a valve coupled to a production well located in the formation.
144. The method of claim 141, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
145. The method of claim 141, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
146. The method of claim 141, wherein the one or more heat sources comprise electrical heaters.
147. The method of claim 141, wherein the one or more heat sources comprise surface burners.
148. The method of claim 141, wherein the one or more heat sources comprise flameless distributed combustors.
149. The method of claim 141, wherein the one or more heat sources comprise natural distributed combustors.
150. The method of claim 141, further comprising controlling a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
151. The method of claim 141, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
152. The method of claim 141, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the.equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
153. The method of claim 141, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
154. The method of claim 141, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
155. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
156. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
157. The method of claim 141, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
158. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
159. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
160. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
161. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
162. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
163. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
164. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
165. The method of claim 141, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
166. The method of claim 141, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
167. The method of claim 141, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
168. The method of claim 141, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
169. The method of claim 141, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
170. The method of claim 169, wherein the partial pressure of H2 is measured when the mixture is at a production well.
171. The method of claim 141, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
172. The method of claim 141, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
173. The method of claim 141, further comprising:
providing hydrogen (Hz) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
174. The method of claim 141, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
175. The method of claim 141, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
176. The method of claim 141, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
177. The method of claim 141, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
178. The method of claim 141, wherein producing the mixture from the formation comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
179. The method of claim 178, wherein at least about 20 heat sources are disposed in the formation for each production well.
180. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute;
controlling the heat from the one or more heat sources such that an average temperature within at least a majority of the selected section of the formation is less than about 375°C; and producing a mixture from the formation.
181. The method of claim 180, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
182. The method of claim 180, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
183. The method of claim 180, wherein the one or more heat sources comprise electrical heaters.
184. The method of claim 180, wherein the one or more heat sources comprise surface burners.
185. The method of claim 180, wherein the one or more heat sources comprise flameless distributed combustors.
186. The method of claim 180, wherein the one or more heat sources comprise natural distributed combustors.
187. The method of claim 180, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
188. The method of claim 180, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1°C per day during pyrolysis.
189. The method of claim 180, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10°C/day.
190. The method of claim 180, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
191. The method of claim 180, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m°C).
192. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
193. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
194. The method of claim 180, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
195. The method of claim 180, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
196. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
197. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
198. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
199. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
200. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
201. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises mufti-ring aromatics with more than two rings.
202. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
203. The method of claim 180, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
204. The method of claim 180, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
205. The method of claim 180, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
206. The method of claim 180, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
207. The method of claim 180, wherein controlling the heat further comprises controlling the heat such that coke production is inhibited.
208. The method of claim 180, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of HZ within the mixture is greater than about 0.5 bars.
209. The method of claim 208, wherein the partial pressure of HZ is measured when the mixture is at a production well.
210. The method of claim 180, further comprising altering the pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
211. The method of claim 180, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
212. The method of claim 180, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
213. The method of claim 180, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
214. The method of claim 180, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
215. The method of claim 180, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
216. The method of claim 180, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
217. The method of claim 180, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
218. The method of claim 217, wherein at least about 20 heat sources are disposed in the formation for each production well.
219. The method of claim 180, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
220. The method of claim 180, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
221. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
producing a mixture from the formation, wherein at least a portion of the mixture is produced during the pyrolysis and the mixture moves through the formation in a vapor phase; and maintaining a pressure within at least a majority of the selected section above about 2.0 bars absolute.
222. The method of claim 221, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at (east the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
223. The method of claim 221, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
224. The method of claim 221, wherein the one or more heat sources comprise electrical heaters.
225. The method of claim 221, wherein the one or more heat sources comprise surface burners.
226. The method of claim 221, wherein the one or more heat sources comprise flameless distributed combustors.
227. The method of claim 221, wherein the one or more heat sources comprise natural distributed combustors.
228. The method of claim 221, further comprising controlling the pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
229. The method of claim 221, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1°C per day during pyrolysis.
230. The method of claim 221, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) ofthe oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
231. The method of claim 221, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
232. The method of claim 221, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m°C).
233. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
234. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
235. The method of claim 221, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
236. The method of claim 221, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
237. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
238. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
239. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
240. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
241. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
242. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
243. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
244. The method of claim 221, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
245. The method of claim 221, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
246. The method of claim 221, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
247. The method of claim 221, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
248. The method of claim 221, wherein the pressure is measured at a wellhead of a production well.
249. The method of claim 221, wherein the pressure is measured at a location within a wellbore of the production well.
250. The method of claim 221, wherein the pressure is maintained below about 100 bars absolute.
251. The method of claim 221, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
252. The method of claim 251, wherein the partial pressure of H2 is measured when the mixture is at a production well.
253. The method of claim 221, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
254. The method of claim 221, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
255. The method of claim 221, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
256. The method of claim 221, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
257. The method of claim 221, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
258. The method of claim 221, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
259. The method of claim 221, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
260. The method of claim 221, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
261. The method of claim 260, wherein at least about 20 heat sources are disposed in the formation for each production well.
262. The method of claim 221, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
263. The method of claim 221, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
264. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
maintaining a pressure within at least a majority of the selected section of the formation above 2.0 bars absolute; and producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity higher than an API gravity of condensable hydrocarbons in a mixture producible from the formation at the same temperature and at atmospheric pressure.
265. The method of claim 264, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
266. The method of claim 264, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
267. The method of claim 264, wherein the one or more heat sources comprise electrical heaters.
268. The method of claim 264, wherein the one or more heat sources comprise surface burners.
269. The method of claim 264, wherein the one or more heat sources comprise flameless distributed combustors.
270. The method of claim 264, wherein the one or more heat sources comprise natural distributed combustors.
271. The method of claim 264, further comprising controlling the pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
272. The method of claim 264, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1°C per day during pyrolysis.
273. The method of claim 264, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (Cv), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*Cv*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10°C/day.
274. The method of claim 264, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
275. The method of claim 264, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m°C).
276. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
277. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
278. The method of claim 264, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
279. The method of claim 264, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
280. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
281. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
282. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
283. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
284. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
285. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
286. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
287. The method of claim 264, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
288. The method of claim 264, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
289. The method of claim 264, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
290. The method of claim 264, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
291. The method of claim 264, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
292. The method of claim 264, wherein a partial pressure of H2 is measured when the mixture is at a production well.
293. The method of claim 264, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
294. The method of claim 264, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
295. The method of claim 264, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
296. The method of claim 264, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
297. The method of claim 264, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
298. The method of claim 264, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
299. The method of claim 264, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
300. The method of claim 264, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
301. The method of claim 300, wherein at least about 20 heat sources are disposed in the formation for each production well.
302. The method of claim 264, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
303. The method of claim 264, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
304. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
maintaining a pressure within at least a majority of the selected section of the formation to above 2.0 bars absolute; and producing a fluid from the formation, wherein condensable hydrocarbons within the fluid comprise an atomic hydrogen to atomic carbon ratio of greater than about 1.75.
305. The method of claim 304, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
306. The method of claim 304, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
307. The method of claim 304, wherein the one or more heat sources comprise electrical heaters.
308. The method of claim 304, wherein the one or more heat sources comprise surface burners.
309. The method of claim 304, wherein the one or more heat sources comprise flameless distributed combustors.
310. The method of claim 304, wherein the one or more heat sources comprise natural distributed combustors.
311. The method of claim 304, further comprising controlling the pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
312. The method of claim 304, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1°C per day during pyrolysis.
313. The method of claim 304, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (Cv), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*Cv*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10°C/day.
314. The method of claim 304, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
315. The method of claim 304, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m°C).
316. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
317. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
318. The method of claim 304, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
319. The method of claim 304, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
320. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
321. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
322. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
323. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
324. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
325. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
326. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
327. The method of claim 304, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
328. The method of claim 304, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
329. The method of claim 304, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
330. The method of claim 304, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
331. The method of claim 304, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
332. The method of claim 304, wherein a partial pressure of H2 is measured when the mixture is at a production well.
333. The method of claim 304, further comprising altering the pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
334. The method of claim 304, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
335. The method of claim 304, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
336. The method of claim 304, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
337. The method of claim 304, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
338. The method of claim 304, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
339. The method of claim 304, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
340. The method of claim 304, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
341. The method of claim 340, wherein at least about 20 heat sources are disposed in the formation for each production well.
342. The method of claim 304, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
343. The method of claim 304, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
344. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
maintaining a pressure within at least a majority of the selected section of the formation to above 2.0 bars absolute; and producing a mixture from the formation, wherein the produced mixture comprises a higher amount of non-condensable components as compared to non-condensable components producible from the formation under the same temperature conditions and at atmospheric pressure.
345. The method of claim 344, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
346. The method of claim 344, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
347. The method of claim 344, wherein the one or more heat sources comprise electrical heaters.
348. The method of claim 344, wherein the one or more heat sources comprise surface burners.
349. The method of claim 344, wherein the one or more heat sources comprise flameless distributed combustors.
350. The method of claim 344, wherein the one or more heat sources comprise natural distributed combustors.
351. The method of claim 344, further comprising controlling the pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
352. The method of claim 344, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1°C per day during pyrolysis.
353. The method of claim 344, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
354. The method of claim 344, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
355. The method of claim 344, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
356. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
357. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
358. The method of claim 344, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
359. The method of claim 344, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
360. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
361. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
362. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
363. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
364. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
365. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
366. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
367. The method of claim 344, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
368. The method of claim 344, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
369. The method of claim 344, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
370. The method of claim 344, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
371. The method of claim 344, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
372. The method of claim 344, wherein a partial pressure of H2 is measured when the mixture is at a production well.
373. The method of claim 344, further comprising altering the pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
374. The method of claim 344, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
375. The method of claim 344, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
376. The method of claim 344, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
377. The method of claim 344, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
378. The method of claim 344, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
379. The method of claim 344, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
380. The method of claim 379, wherein at least about 20 heat sources are disposed in the formation for each production well.
381. The method of claim 344, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
382. The method of claim 344, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
383. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation such that superimposed heat from the one or more heat sources pyrolyzes at least about 20 % by weight of hydrocarbons within the selected section of the formation; and producing a mixture from the formation.
384. The method of claim 383, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
385. The method of claim 383, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
386. The method of claim 383, wherein the one or more heat sources comprise electrical heaters.
387. The method of claim 383, wherein the one or more heat sources comprise surface burners.
388. The method of claim 383, wherein the one or more heat sources comprise flameless distributed combustors.
389. The method of claim 383, wherein the one or more heat sources comprise natural distributed combustors.
390. The method of claim 383, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
391. The method of claim 383, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
392. The method of claim 383, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
393. The method of claim 383, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
394. The method of claim 383, wherein providing heat from the one or more heat sources comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
395. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
396. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
397. The method of claim 383, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
398. The method of claim 383, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
399. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
400. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
401. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
402. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
403. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
404. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
405. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
406. The method of claim 383, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
407. The method of claim 383, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
408. The method of claim 383, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
409. The method of claim 383, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
410. The method of claim 383, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
411. The method of claim 383, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
412. The method of claim 383, wherein a partial pressure of H2 is measured when the mixture is at a production well.
413. The method of claim 383, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
414. The method of claim 383, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
415. The method of claim 383, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
416. The method of claim 383, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
417. The method of claim 383, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
418. The method of claim 383, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
419. The method of claim 383, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
420. The method of claim 383, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
421. The method of claim 420, wherein at least about 20 heat sources are disposed in the formation for each production well.
422. The method of claim 383, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
423. The method of claim 383, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
424. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation such that superimposed heat from the one or more heat sources pyrolyzes at least about 20 % of hydrocarbons within the selected section of the formation; and producing a mixture from the formation, wherein the mixture comprises a condensable component having an API gravity of at least about 25°.
425. The method of claim 424, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
426. The method of claim 424, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
427. The method of claim 424, wherein the one or more heat sources comprise electrical heaters.
428. The method of claim 424, wherein the one or more heat sources comprise surface burners.
429. The method of claim 424, wherein the one or more heat sources comprise flameless distributed combustors.
430. The method of claim 424, wherein the one or more heat sources comprise natural distributed combustors.
431. The method of claim 424, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
432. The method of claim 424, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
433. The method of claim 424, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
434. The method of claim 424, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
435. The method of claim 424, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
436. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
437. The method of claim 424, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
438. The method of claim 424, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
439. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
440. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
441. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
442. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
443. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
444. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
445. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
446. The method of claim 424, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
447. The method of claim 424, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
448. The method of claim 424, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
449. The method of claim 424, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
450. The method of claim 424, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
451. The method of claim 424, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
452. The method of claim 424, wherein a partial pressure of H2 is measured when the mixture is at a production well.
453. The method of claim 424, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
454. The method of claim 424, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
455. The method of claim 424, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
456. The method of claim 424, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
457. The method of claim 424, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
458. The method of claim 424, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
459. The method of claim 424, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
460. The method of claim 424, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
461. The method of claim 460, wherein at least about 20 heat sources are disposed in the formation for each production well.
462. The method of claim 424, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
463. The method of claim 424, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
464. A method of treating a layer of an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the layer, wherein the one or more heat sources are positioned proximate an edge of the layer;
allowing the heat to transfer from the one or more heat sources to a selected section of the layer such that superimposed heat from the one or more heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation; and producing a mixture from the formation.
465. The method of claim 464, wherein the one or more heat sources are laterally spaced from a center of the layer.
466. The method of claim 464, wherein the one or more heat sources are positioned in a staggered line.
467. The method of claim 464, wherein the one or more heat sources positioned proximate the edge of the layer can increase an amount of hydrocarbons produced per unit of energy input to the one or more heat sources.
468. The method of claim 464, wherein the one or more heat sources positioned proximate the edge of the layer can increase the volume of formation undergoing pyrolysis per unit of energy input to the one or more heat sources.
469. The method of claim 464, wherein the one or more heat sources comprise electrical heaters.
470. The method of claim 464, wherein the one or more heat sources comprise surface burners.
471. The method of claim 464, wherein the one or more heat sources comprise flameless distributed combustors.
472. The method of claim 464, wherein the one or more heat sources comprise natural distributed combustors.
473. The method of claim 464, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
474. The method of claim 464, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1.0°C per day during pyrolysis.
475. The method of claim 464, wherein providing heat from the one or more heat sources to at least the portion of the layer comprises:
heating a selected volume (.NU.) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C .NU.), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*.NU.*C .NU.*.rho. .beta.
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho. .beta. is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
476. The method of claim 464, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
477. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
478. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
479. The method of claim 464, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
480. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
481. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
482. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
483. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
484. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
485. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
486. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
487. The method of claim 464, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
488. The method of claim 464, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
489. The method of claim 464, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
490. The method of claim 464, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
491. The method of claim 464, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
492. The method of claim 464, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
493. The method of claim 492, wherein the partial pressure of H2 is measured when the mixture is at a production well.
494. The method of claim 464, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
495. The method of claim 464, further comprising controlling formation conditions, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
496. The method of claim 464, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
497. The method of claim 464, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
498. The method of claim 464, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
499. The method of claim 464, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
500. The method of claim 464, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
501. The method of claim 464, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
502. The method of claim 501, wherein at least about 20 heat sources are disposed in the formation for each production well.
503. The method of claim 464, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
504. The method of claim 464, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
505. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure; and producing a mixture from the formation.
506. The method of claim 505, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
507. The method of claim 505, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
508. The method of claim 505, wherein the one or more heat sources comprise electrical heaters.
509. The method of claim 505, wherein the one or more heat sources comprise surface burners.
510. The method of claim 505, wherein the one or more heat sources comprise flameless distributed combustors.
511. The method of claim 505, wherein the one or more heat sources comprise natural distributed combustors.
512. The method of claim 505, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
513. The method of claim 505, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (.NU.) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C .NU.), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C .NU. *.rho. .beta.
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p .beta. is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
514. The method of claim 505, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
515. The method of claim 505, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
516. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
517. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
518. The method of claim 505, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
519. The method of claim 505, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
520. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
521. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
522. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
523. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
524. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
525. The method of Maim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
526. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
527. The method of claim 505, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
528. The method of claim 505, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
529. The method of claim 505, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
530. The method of claim 505, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
531. The method of claim 505, wherein the controlled pressure is at least about 2.0 bars absolute.
532. The method of claim 505, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
533. The method of claim 505, wherein a partial pressure of H2 is measured when the mixture is at a production well.
534. The method of claim 505, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
535. The method of claim 505, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
536. The method of claim 505, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
537. The method of claim 505, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
538. The method of claim 505, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
539. The method of claim 505, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
540. The method of claim 505, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
541. The method of claim 505, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
542. The method of claim 541, wherein at least about 20 heat sources are disposed in the formation for each production well.
543. The method of claim 505, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
544. The method of claim 505, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
545. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation to raise an average temperature within the selected section to, or above, a temperature that will pyrolyze hydrocarbons within the selected section;
producing a mixture from the formation; and controlling API gravity of the produced mixture to be greater than about 25 degrees API by controlling average pressure and average temperature in the selected section such that the average pressure in the selected section is greater than the pressure (p) set forth in the following equation for an assessed average temperature (T) in the selected section:
p = e [-44000/T + 67]
where p is measured in psia and T is measured in ~ Kelvin.
546. The method of claim 545, wherein the API gravity of the produced mixture is controlled to be greater than about 30 degrees API, and wherein the equation is:
p = e[-31000/T + 51]
547. The method of claim 545, wherein the API gravity of the produced mixture is controlled to be greater than about 35 degrees API, and wherein the equation is:
p = e [-22000/T + 38]
548. The method of claim 545, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
549. The method of claim 545, wherein controlling the average temperature comprises maintaining a temperature in the selected section within a pyrolysis temperature range.
550. The method of claim 545, wherein the one or more heat sources comprise electrical heaters.
551. The method of claim 545, wherein the one or more heat sources comprise surface burners.
552. The method of claim 545, wherein the one or more heat sources comprise flameless distributed combustors.
553. The method of claim 545, wherein the one or more heat sources comprise natural distributed combustors.
554. The method of claim 545, further comprising controlling a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
555. The method of claim 545, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
556. The method of claim 545, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
557. The method of claim 545, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
558. The method of claim 545, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
559. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
560. The method of claim 545, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
561. The method of claim 545, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
562. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
563. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
564. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
565. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
566. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
567. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
568. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
569. The method of claim 545, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
570. The method of claim 545, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
571. The method of claim 545, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
572. The method of claim 545, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
573. The method of claim 545, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
574. The method of claim 545, wherein a partial pressure of H2 is measured when the mixture is at a production well.
575. The method of claim 545, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
576. The method of claim 545, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
577. The method of claim 545, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
578. The method of claim 545, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
579. The method of claim 545, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
580. The method of claim 545, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
581. The method of claim 545, wherein the heat is controlled to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
582. The method of claim 545, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
583. The method of claim 582, wherein at least about 20 heat sources are disposed in the formation for each production well.
584. The method of claim 545, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
585. The method of claim 545, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
586. A method of treating an oil shale formation in situ, comprising:
providing heat to at least a portion of an oil shale formation such that a temperature (T) in a substantial part of the heated portion exceeds 270 °C and hydrocarbons are pyrolyzed within the heated portion of the formation;
controlling a pressure (p) within at least a substantial part of the heated portion of the formation;
wherein p bar > e [(-A/T)+B-2.6744];
wherein p is the pressure in bars absolute and T is the temperature in degrees K, and A and B are parameters that are larger than 10 and are selected in relation to the characteristics and composition of the oil shale formation and on the required olefin content and carbon number of the pyrolyzed hydrocarbon fluids; and producing pyrolyzed hydrocarbon fluids from the heated portion of the formation.
587. The method of claim 586, wherein A is greater than 14000 and B is greater than about 25 and a majority of the produced pyrolyzed hydrocarbon fluids have an average carbon number lower than 25 and comprise less than about 10 % by weight of olefins.
588. The method of claim 586, wherein T is less than about 390 °C, p is greater than about 1.4 bars, A is greater than about 44000, and b is greater than about 67, and a majority of the produced pyrolyzed hydrocarbon fluids have an average carbon number less than 25 and comprise less than 10 % by weight of olefins.
589. The method of claim 586, wherein T is less than about 390 °C, p is greater than about 2 bars, A is less than about 57000, and b is less than about 83, and a majority of the produced pyrolyzed hydrocarbon fluids have an average carbon number lower than about 21.
590. The method of claim 586, further comprising controlling the heat such that an average heating rate of the heated portion is less than about 3°C per day during pyrolysis.
591. The method of claim 586, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
592. The method of claim 586, wherein heat is transferred substantially by conduction from the one or more heat sources to the heated portion of the formation.
593. The method of claim 586, wherein heat is transferred substantially by conduction from the one or more heat sources to the heated portion of the formation such that the thermal conductivity of at least part of the heated portion is substantially uniformly modified to a value greater than about 0.6 W/m °C and the permeability of said part increases substantially uniformly to a value greater than 1 Darcy.
594. The method of claim 586, further comprising controlling formation conditions to produce a mixture of hydrocarbon fluids and H2, wherein a partial pressure of H2 within the mixture flowing through the formation is greater than 0.5 bars.
595. The method of claim 594, further comprising, hydrogenating a portion of the produced pyrolyzed hydrocarbon fluids with at least a portion of the produced hydrogen and heating the fluids with heat from hydrogenation.
596. The method of claim 586, wherein the substantially gaseous pyrolyzed hydrocarbon fluids are produced from a production well, the method further comprising heating a wellbore of the production well to inhibit condensation of the hydrocarbon fluids within the wellbore.
597. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation to raise an average temperature within the selected section to, or above, a temperature that will pyrolyze hydrocarbons within the selected section;
producing a mixture from the formation; and controlling a weight percentage of olefins of the produced mixture to be less than about 20 % by weight by controlling average pressure and average temperature in the selected section such that the average pressure in the selected section is greater than the pressure (p) set forth in the following equation for an assessed average temperature (T) in the selected section:
p = e [-57000/T + 83]
where p is measured in psia and T is measured in ° Kelvin.
598. The method of claim 597, wherein the weight percentage of olefins of the produced mixture is controlled to be less than about 10 % by weight, and wherein the equation is:
p = e [-16000/T + 28].
599. The method of claim 597, wherein the weight percentage of olefins of the produced mixture is controlled to be less than about 5 % by weight, and wherein the equation is:
p = e [-12000/T + 22].
600. The method of claim 597, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
601. The method of claim 597, wherein the one or more heat sources comprise electrical heaters.
602. The method of claim 597, wherein the one or more heat sources comprise surface burners.
603. The method of claim 597, wherein the one or more heat sources comprise flameless distributed combustors.
604. The method of claim 597, wherein the one or more heat sources comprise natural distributed combustors.
605. The method of claim 597, further comprising controlling a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
606. The method of claim 605, wherein controlling an average temperature comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
607. The method of claim 597, further comprising controlling the heat such that an average heating rate of the selected section is less than about 3.0 °C per day during pyrolysis.
608. The method of claim 597, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
609. The method of claim 597, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
610. The method of claim 597, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
611. The method of claim 597, wherein providing heat from the one or more heat sources comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
612. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
613. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
614. The method of claim 597, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
615. The method of claim 597, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
616. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
617. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
618. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
619. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
620. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
621. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
622. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
623. The method of claim 597, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
624. The method of claim 597, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
625. The method of claim 597, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
626. The method of claim 597, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
627. The method of claim 597, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
628. The method of claim 597, wherein a partial pressure of H2 is measured when the mixture is at a production well.
629. The method of claim 597, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
630. The method of claim 597, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
631. The method of claim 597, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
632. The method of claim 597, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
633. The method of claim 597, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
634. The method of claim 597, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
635. The method of claim 597, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
636. The method of claim 597, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
637. The method of claim 636, wherein at least about 20 heat sources are disposed in the formation for each production well.
638. The method of claim 597, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
639. The method of claim 597, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
640. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation to raise an average temperature within the selected section to, or above, a temperature that will pyrolyze hydrocarbons within the selected section;
producing a mixture from the formation; and controlling hydrocarbons having carbon numbers greater than 25 of the produced mixture to be less than about 25 % by weight by controlling average pressure and average temperature in the selected section such that the average pressure in the selected section is greater than the pressure (p) set forth in the following equation for an assessed average temperature (T) in the selected section:
p = e [-14000/T + 25]
where p is measured in psia and T is measured in ° Kelvin.
641. The method of claim 640, wherein the hydrocarbons having carbon numbers greater than 25 of the produced mixture is controlled to be less than about 20 % by weight, and wherein the equation is:
p = e [-16000/T + 28].
642. The method of claim 640, wherein the hydrocarbons having carbon numbers greater than 25 of the produced mixture is controlled to be less than about 15 % by weight, and wherein the equation is:
p = e[-18000/T + 32].
643. The method of claim 640, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
644. The method of claim 640, wherein the one or more heat sources comprise electrical heaters.
645. The method of claim 640, wherein the one or more heat sources comprise surface burners.
646. The method of claim 640, wherein the one or more heat sources comprise flameless distributed combustors.
647. The method of claim 640, wherein the one or more heat sources comprise natural distributed combustors.
648. The method of claim 640, further comprising controlling a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
649. The method of claim 648, wherein controlling the temperature comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
650. The method of claim 640, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
651. The method of claim 640, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v,*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
652. The method of claim 640, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
653. The method of claim 640, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
654. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
655. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
656. The method of claim 640, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
657. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
658. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
659. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
660. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
661. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
662. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
663. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
664. The method of claim 640, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
665. The method of claim 640, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
666. The method of claim 640, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
667. The method of claim 640, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
668. The method of claim 640, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
669. The method of claim 640, wherein a partial pressure of H2 is measured when the mixture is at a production well.
670. The method of claim 640, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
671. The method of claim 640, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
672. The method of claim 640, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
673. The method of claim 640, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
674. The method of claim 640, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
675. The method of claim 640, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
676. The method of claim 640, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
677. The method of claim 676, wherein at least about 20 heat sources are disposed in the formation for each production well.
678. The method of claim 640, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
679. The method of claim 640, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
680. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation to raise an average temperature within the selected section to, or above, a temperature that will pyrolyze hydrocarbons within the selected section;
producing a mixture from the formation; and controlling an atomic hydrogen to carbon ratio of the produced mixture to be greater than about 1.7 by controlling average pressure and average temperature in the selected section such that the average pressure in the selected section is greater than the pressure (p) set forth in the following equation for an assessed average temperature (T) in the selected section:
p = e[-38000/T + 61]
where p is measured in psia and T is measured in ° Kelvin.
681. The method. of claim 680, wherein the atomic hydrogen to carbon ratio of the produced mixture is controlled to be greater than about 1.8, and wherein the equation is:
p = e[-13000/T + 24].
682. The method of claim 680, wherein the atomic hydrogen to carbon ratio of the produced mixture is controlled to be greater than about 1.9, and wherein the equation is:
p = e[-8000/T + 18]
683. The method of claim 680, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
684. The method of claim 680, wherein the one or more heat sources comprise electrical heaters.
685. The method of claim 680, wherein the one or more heat sources comprise surface burners.
686. The method of claim 680, wherein the one or more heat sources comprise flameless distributed combustors.
687. The method of claim 680, wherein the one or more heat sources comprise natural distributed combustors.
688. The method of claim 680, further comprising controlling a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
689. The method of claim 688, wherein controlling the temperature comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
690. The method of claim 680, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
691. The method of claim 680, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
692. The method of claim 680, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
693. The method of claim 680, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
694. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
695. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
696. The method of claim 680, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
697. The method of claim 680, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
698. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
699. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
700. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
701. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
702. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
703. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises mufti-ring aromatics with more than two rings.
704. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
705. The method of claim 680, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
706. The method of claim 680, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
707. The method of claim 680, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
708. The method of claim 680, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
709. The method of claim 680, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
710. The method of claim 680, wherein a partial pressure of H2 is measured when the mixture is at a production well.
711. The method of claim 680, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
712. The method of claim 680, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
713. The method of claim 680, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
714. The method of claim 680, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
715. The method of claim 680, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
716. The method of claim 680, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
717. The method of claim 680, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
718. The method of claim 680, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
719. The method of claim 718, wherein at least about 20 heat sources are disposed in the formation for each production well.
720. The method of claim 680, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
721. The method of claim 680, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
722. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least one portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
controlling a pressure-temperature relationship within at least the selected section of the formation by selected energy input into the one or more heat sources and by pressure release from the selected section through wellbores of the one or more heat sources; and producing a mixture from the formation.
723. The method of claim 722, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
724. The method of claim 722, wherein the one or more heat sources comprise at least two heat sources.
725. The method of claim 722, wherein the one or more heat sources comprise surface burners.
726. The method of claim 722, wherein the one or more heat sources comprise flameless distributed combustors.
727. The method of claim 722, wherein the one or more heat sources comprise natural distributed combustors.
728. The method of claim 722, further comprising controlling the pressure-temperature relationship by controlling a rate of removal of fluid from the formation.
729. The method of claim 722, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
730. The method of claim 722, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10°C/day.
731. The method of claim 722, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
732. The method of claim 722, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
733. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
734. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
735. The method of claim 722, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
736. The method of claim 722, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
737. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
738. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
739. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
740. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
741. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
742. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
743. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
744. The method of claim 722, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
745. The method of claim 722, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
746. The method of claim 722, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
747. The method of claim 722, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
748. The method of claim 722, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
749. The method of claim 722, further comprising controlling formation conditions to produce a mixture of hydrocarbon fluids and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
750. The method of claim 722, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
751. The method of claim 722, wherein a partial pressure of H2 is measured when the mixture is at a production well.
752. The method of claim 722, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
753. The method of claim 722, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
754. The method of claim 722, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
755. The method of claim 722, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
756. The method of claim 722, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
757. The method of claim 722, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
758. The method of claim 722, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
759. The method of claim 722, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
760. The method of claim 759, wherein at least about 20 heat sources are disposed in the formation for each production well.
761. The method of claim 722, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
762. The method of claim 722, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
763. A method of treating an oil shale formation in situ, comprising:
heating a selected volume (V) of the oil shale formation, wherein formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
764. The method of claim 763, wherein heating a selected volume comprises heating with an electrical heater.
765. The method of claim 763, wherein heating a selected volume comprises heating with a surface burner.
766. The method of claim 763, wherein heating a selected volume comprises heating with a flameless distributed combustor.
767. The method of claim 763, wherein heating a selected volume comprises heating with at least one natural distributed combustor.
768. The method of claim 763, further comprising controlling a pressure and a temperature within at least a majority of the selected volume of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
769. The method of claim 763, further comprising controlling the heating such that an average heating rate of the selected volume is less than about 1 °C per day during pyrolysis.
770. The method of claim 763, wherein a value for C v is determined as an average heat capacity of two or more samples taken from the oil shale formation.
771. The method of claim 763, wherein heating the selected volume comprises transferring heat substantially by conduction.
772. The method of claim 763, wherein heating the selected volume comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
773. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
774. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
775. The method of claim 763, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
776. The method of claim 763, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
777. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
778. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
779. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
780. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
781. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
782. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
783. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
784. The method of claim 763, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
785. The method of claim 763, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
786. The method of claim 763, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
787. The method of claim 763, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer 788. The method of claim 763, further comprising controlling a pressure within at least a majority of the selected volume of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
789. The method of claim 763, further comprising controlling formation conditions to produce a mixture from the formation comprising condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
790. The method of claim 763, wherein a partial pressure of H2 is measured when the mixture is at a production well.
791. The method of claim 763, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
792. The method of claim 763, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
793. The method of claim 763, further comprising:
providing hydrogen (H2) to the heated volume to hydrogenate hydrocarbons within the volume; and heating a portion of the volume with heat from hydrogenation:
794. The method of claim 763, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
795. The method of claim 763, further comprising increasing a permeability of a majority of the selected volume to greater than about 100 millidarcy.
796. The method of claim 763, further comprising substantially uniformly increasing a permeability of a majority of the selected volume.
797. The method of claim 763, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
798. The method of claim 763, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
799. The method of claim 798, wherein at least about 20 heat sources are disposed in the formation for each production well.
800. The method of claim 763, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
801. The method of claim 763, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
802. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation to raise an average temperature within the selected section to, or above, a temperature that will pyrolyze hydrocarbons within the selected section;
controlling heat output from the one or more heat sources such that an average heating rate of the selected section rises by less than about 3 °C per day when the average temperature of the selected section is at, or above, the temperature that will pyrolyze hydrocarbons within the selected section; and producing a mixture from the formation.
803. The method of claim 802, wherein controlling heat output comprises:
raising the average temperature within the selected section to a first temperature that is at or above a minimum pyrolysis temperature of hydrocarbons within the formation;
limiting energy input into the one or more heat sources to inhibit increase in temperature of the selected section; and increasing energy input into the formation to raise an average temperature of the selected section above the first temperature when production of formation fluid declines below a desired production rate.
804. The method of claim 802, wherein controlling heat output comprises:
raising the average temperature within the selected section to a first temperature that is at or above a minimum pyrolysis temperature of hydrocarbons within the formation;
limiting energy input into the one or more heat sources to inhibit increase in temperature of the selected section; and increasing energy input into the formation to raise an average temperature of the selected section above the first temperature when quality of formation fluid produced from the formation falls below a desired quality.
805. The method of claim 802, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section.
806. The method of claim 802, wherein the one or more heat sources comprise electrical heaters.
807. The method of claim 802, wherein the one or more heat sources comprise surface burners.
808. The method of claim 802, wherein the one or more heat sources comprise flameless distributed combustors.
809. The method of claim 802, wherein the one or more heat sources comprise natural distributed combustors.
810. The method of claim 802, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
811. The method of claim 802, wherein the heat is controlled such that an average heating rate of the selected section is less than about 1.5 °C per day during pyrolysis.
812. The method of claim 802, wherein the heat is controlled such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
813. The method of claim 802, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho. B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density.
814. The method of claim 802, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
815. The method of claim 802, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
816. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
817. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
818. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, wherein the condensable hydrocarbons have an olefin content is less than about 2.5 %
by weight of the condensable hydrocarbons, and wherein the olefin content is greater than about 0.1 % by weight of the condensable hydrocarbons.
819. The method of claim 802, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
820. The method of claim 802, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.10 and wherein the ratio of ethene to ethane is greater than about 0.001.
821. The method of claim 802, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.05 and wherein the ratio of ethene to ethane is greater than about 0.001.
822. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
823. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
824. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
825. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
826. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
827. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
828. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
829. The method of claim 802, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
830. The method of claim 802, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
831. The method of claim 802, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
832. The method of claim 802, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
833. The method of claim 802, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
834. The method of claim 802, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
835. The method of claim 802, wherein a partial pressure of H2 is measured when the mixture is at a production well.
836. The method of claim 802, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
837. The method of claim 802, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
838. The method of claim 802, further comprising:
providing H2 to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
839. The method of claim 802, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
840. The method of claim 802, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
841. The method of claim 802, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
842. The method of claim 802, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
843. The method of claim 802, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
844. The method of claim 843, wherein at least about 20 heat sources are disposed in the formation for each production well.
845. The method of claim 802, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
846. The method of claim 802, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
847. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation; to heat a selected section of the formation to an average temperature above about 270 °C;
allowing the heat to transfer from the one or more heat sources to the selected section of the formation;
controlling the heat from the one or more heat sources such that an average heating rate of the selected section is less than about 3 °C per day during pyrolysis; and producing a mixture from the formation.
848. The method of claim 847, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
849. The method of claim 847, wherein the one or more heat sources comprise electrical heaters.
850. The method of claim 847, further comprising supplying electricity to the electrical heaters substantially during non-peak hours.
851. The method of claim 847, wherein the one or more heat sources comprise surface burners.
852. The method of claim 847, wherein the one or more heat sources comprise flameless distributed combustors.
853. The method of claim 847, wherein the one or more heat sources comprise natural distributed combustors.
854. The method of claim 847, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
855. The method of claim 847, wherein the heat is further controlled such that an average heating rate of the selected section is less than about 3 °C/day until production of condensable hydrocarbons substantially ceases.
856. The method of claim 847, wherein the heat is further controlled such that an average heating rate of the selected section is less than about 1.5 °C per day during pyrolysis.
857. The method of claim 847, wherein the heat is further controlled such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
858. The method of claim 847, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density.
859. The method of claim 847, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
860. The method of claim 847, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
861. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
862. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
863. The method of claim 847, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
864. The method of claim 847, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
865. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
866. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
867. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
868. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
869. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
870. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
871. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
872. The method of claim 847, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
873. The method of claim 847, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
874. The method of claim 847, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
875. The method of claim 847, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
876. The method of claim 847, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
877. The method of claim 847, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
878. The method of claim 877, wherein the partial pressure of H2 is measured when the mixture is at a production well.
879. The method of claim 847, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
880. The method of claim 847, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
881. The method of claim 847, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
882. The method of claim 847, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
883. The method of claim 847, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
884. The method of claim 847, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
885. The method of claim 847, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
886. The method of claim 847, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
887. The method of claim 886, wherein at least about 20 heat sources are disposed in the formation for each production well.
888. The method of claim 847, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
889. The method of claim 847, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
890. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
producing a mixture from the formation through at least one production well;
monitoring a temperature at or in the production well; and controlling heat input to raise the monitored temperature at a rate of less than about 3 °C per day.
891. The method of claim 890, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
892. The method of claim 890, wherein the one or more heat sources comprise electrical heaters.
893. The method of claim 890, wherein the one or more heat sources comprise surface burners.
894. The method of claim 890, wherein the one or more heat sources comprise flameless distributed combustors.
895. The method of claim 890, wherein the one or more heat sources comprise natural distributed combustors.
896. The method of claim 890, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
897. The method of claim 890, wherein the heat is controlled such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
898. The method of claim 890, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density.
899. The method of claim 890, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
900. The method of claim 890, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
901. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
902. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
903. The method of claim 890, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
904. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
905. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
906. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
907. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
908. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
909. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
910. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
911. The method of claim 890, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
912. The method of claim 890, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
913. The method of claim 890, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
914. The method of claim 890, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
915. The method of claim 890, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
916. The method of claim 890, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
917. The method of claim 916, wherein the partial pressure of H2 is measured when the mixture is at a production well.
918. The method of claim 890, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
919. The method of claim 890, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
920. The method of claim 890, further comprising:
providing H2 to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
921. The method of claim 890, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
922. The method of claim 890, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
923. The method of claim 890, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
924. The method of claim 890, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
925. The method of claim 890, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
926. The method of claim 925, wherein at least about 20 heat sources are disposed in the formation for each production well.
927. The method of claim 890, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
928. The method of claim 890, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
929. A method of treating an oil shale formation in situ, comprising:
heating a portion of the formation to a temperature sufficient to support oxidation of hydrocarbons within the portion, wherein the portion is located substantially adjacent to a wellbore;
flowing an oxidant through a conduit positioned within the wellbore to a heat source zone within the portion, wherein the heat source zone supports an oxidation reaction between hydrocarbons and the oxidant;
reacting a portion of the oxidant with hydrocarbons to generate heat; and transferring generated heat substantially by conduction to a pyrolysis zone of the formation to pyrolyze at least a portion of the hydrocarbons within the pyrolysis zone.
930. The method of claim 929, wherein heating the portion of the formation comprises raising a temperature of the portion above about 400 °C.
931. The method of claim 929, wherein the conduit comprises critical flow orifices, the method further comprising flowing the oxidant through the critical flow orifices to the heat source zone.
932. The method of claim 929, further comprising removing reaction products from the heat source zone through the wellbore.
933. The method of claim 929, further comprising removing excess oxidant from the heat source zone to inhibit transport of the oxidant to the pyrolysis zone.
934. The method of claim 929, further comprising transporting the oxidant from the conduit to the heat source zone substantially by diffusion.
935. The method of claim 929, further comprising heating the conduit with reaction products being removed through the wellbore.
936. The method of claim 929, wherein the oxidant comprises hydrogen peroxide.
937. The method of claim 929, wherein the oxidant comprises air.
938. The method of claim 929, wherein the oxidant comprises a fluid substantially free of nitrogen.
939. The method of claim 929, further comprising limiting an amount of oxidant to maintain a temperature of the heat source zone less than about 1200 °C.
940. The method of claim 929, wherein heating the portion of the formation comprises electrically heating the formation.
941. The method of claim 929, wherein heating the portion of the formation comprises heating the portion using exhaust gases from a surface burner.
942. The method of claim 929, wherein heating the portion of the formation comprises heating the portion with a flameless distributed combustor.
943. The method of claim 929, further comprising controlling a pressure and a temperature within at least a majority of the pyrolysis zone, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
944. The method of claim 929, further comprising controlling the heat such that an average heating rate of the pyrolysis zone is less than about 1 °C per day during pyrolysis., 945. The method of claim 929, wherein heating the portion comprises heating the pyrolysis zone such that a thermal conductivity of at least a portion of the pyrolysis zone is greater than about 0.5 W/(m °C).
946. The method of claim 929, further comprising controlling a pressure within at least a majority of the pyrolysis zone of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
947. The method of claim 929, further comprising:
providing hydrogen (H2) to the pyrolysis zone to hydrogenate hydrocarbons within the pyrolysis zone; and heating a portion of the pyrolysis zone with heat from hydrogenation.
948. The method of claim 929, wherein transferring generated heat comprises increasing a permeability of a majority of the pyrolysis zone to greater than about 100 millidarcy.
949. The method of claim 929, wherein transferring generated heat comprises substantially uniformly increasing a permeability of a majority of the pyrolysis zone.
950. The method of claim 929, wherein the heating is controlled to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
951. The method of claim 929, wherein the wellbore is located along strike to reduce pressure differentials along a heated length of the wellbore.
952. The method of claim 929, wherein the wellbore is located along strike to increase uniformity of heating along a heated length of the wellbore.
953. The method of claim 929, wherein the wellbore is located along strike to increase control of heating along a heated length of the wellbore.
954. A method of treating an oil shale formation in situ, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidant;
flowing the oxidant into a conduit, and wherein the conduit is connected such that the oxidant can flow from the conduit to the hydrocarbons;
allowing the oxidant and the hydrocarbons to react to produce heat in a heat source zone;
allowing heat to transfer from the heat source zone to a pyrolysis zone in the formation to pyrolyze at least a portion of the hydrocarbons within the pyrolysis zone; and removing reaction products such that the reaction products are inhibited from flowing from the heat source zone to the pyrolysis zone.
955. The method of claim 954, wherein heating the portion of the formation comprises raising the temperature of the portion above about 400 °C.
956. The method of claim 954, wherein heating the portion of the formation comprises electrically heating the formation.
957. The method of claim 954, wherein heating the portion of the formation comprises heating the portion using exhaust gases from a surface burner.
958. The method of claim 954, wherein the conduit comprises critical flow orifices, the method further comprising flowing the oxidant through the critical flow orifices to the heat source zone.
959. The method of claim 954, wherein the conduit is located within a wellbore, wherein removing reaction products comprises removing reaction products from the heat source zone through the wellbore.
960. The method of claim 954, further comprising removing excess oxidant from the heat source zone to inhibit transport of the oxidant to the pyrolysis zone.
961. The method of claim 954, further comprising transporting the oxidant from the conduit to the heat source zone substantially by diffusion.
962. The method of claim 954, wherein the conduit is located within a wellbore, the method further comprising heating the conduit with reaction products being removed through the wellbore to raise a temperature of the oxidant passing through the conduit.
963. The method of claim 954, wherein the oxidant comprises hydrogen peroxide.
964. The method of claim 954, wherein the oxidant comprises air.
965. The method of claim 954, wherein the oxidant comprises a fluid substantially free of nitrogen.
966. The method of claim 954, further comprising limiting an amount of oxidant to maintain a temperature of the heat source zone less than about 1200 °C.
967. The method of claim 954, further comprising limiting an amount of oxidant to maintain a temperature of the heat source zone at a temperature that inhibits production of oxides of nitrogen.
968. The method of claim 954, wherein heating a portion of the formation to a temperature sufficient to support oxidation of hydrocarbons within the portion further comprises heating with a flameless distributed combustor.
969. The method of claim 954, further comprising controlling a pressure and a temperature within at least a majority of the pyrolysis zone of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
970. The method of claim 954, further comprising controlling the heat such that an average heating rate of the pyrolysis zone is less than about 1 °C per day during pyrolysis.
971. The method of claim 954, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
972. The method of claim 954, wherein allowing heat to transfer comprises heating the pyrolysis zone such that a thermal conductivity of at least a portion of the pyrolysis zone is greater than about 0.5 W/(m °C).
973. The method of claim 954, further comprising controlling a pressure within at least a majority of the pyrolysis zone, wherein the controlled pressure is at least about 2.0 bars absolute.
974. The method of claim 954, further comprising:
providing hydrogen (H2) to the pyrolysis zone to hydrogenate hydrocarbons within the pyrolysis zone; and heating a portion of the pyrolysis zone with heat from hydrogenation.
975. The method of claim 954, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the pyrolysis zone to greater than about 100 millidarcy.
976. The method of claim 954, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the pyrolysis zone.
977. The method of claim 954, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
978. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein the portion is located substantially adjacent to an opening in the formation;
providing the oxidizing fluid to a heat source zone in the formation;
allowing the oxidizing gas to react with at least a portion of the hydrocarbons at the heat source zone to generate heat in the heat source zone; and transferring the generated heat substantially by conduction from the heat source zone to a pyrolysis zone in the formation.
979. The method of claim 978, further comprising transporting the oxidizing fluid through the heat source zone by diffusion.
980. The method of claim 978, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a conduit disposed in the opening.
981. The method of claim 978, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a conduit disposed in the opening such that a rate of oxidation is controlled.
982. The method of claim 978, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit.
983. The method of claim 978, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and transferring substantial heat from the oxidation product in the conduit to the oxidizing fluid in the conduit.
984. The method of claim 978, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
985. The method of claim 978, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
986. The method of claim 978, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the outer conduit.
987. The method of claim 978, wherein the heat source zone extends radially from the opening a width of less than approximately 0.15 m.
988. The method of claim 978, wherein heating the portion comprises applying electrical current to an electric heater disposed within the opening.
989. The method of claim 978, wherein the pyrolysis zone is substantially adjacent to the heat source zone.
990. The method of claim 978, further comprising controlling a pressure and a temperature within at least a majority of the pyrolysis zone of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
991. The method of claim 978, further comprising controlling the heat such that an average heating rate of the pyrolysis zone is less than about 1 °C per day during pyrolysis.
992. The method of claim 978, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
993. The method of claim 978, wherein allowing heat to transfer comprises heating the portion such that a thermal conductivity of at least a portion of the pyrolysis zone is greater than about 0.5 W/(m °C).
994. The method of claim 978, further comprising controlling a pressure within at least a majority of the pyrolysis zone, wherein the controlled pressure is at least about 2.0 bars absolute.
995. The method of claim 978, further comprising:
providing hydrogen (H2) to the pyrolysis zone to hydrogenate hydrocarbons within the pyrolysis zone; and heating a portion of the pyrolysis zone with heat from hydrogenation.
996. The method of claim 978, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the pyrolysis zone to greater than about 100 millidarcy.
997. The method of claim 978, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the pyrolysis zone.
998. The method of claim 978, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
999. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
producing a mixture from the formation; and maintaining an average temperature within the selected section above a minimum pyrolysis temperature and below a vaporization temperature of hydrocarbons having carbon numbers greater than 25 to inhibit production of a substantial amount of hydrocarbons having carbon numbers greater than 25 in the mixture.
1000. The method of claim 999, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1001. The method of claim 999, wherein maintaining the average temperature within the selected section comprises maintaining the temperature within a pyrolysis temperature range.
1002. The method of claim 999, wherein the one or more heat sources comprise electrical heaters.
1003. The method of claim 999, wherein the one or more heat sources comprise surface burners.
1004. The method of claim 999, wherein the one or more heat sources comprise flameless distributed combustors.
1005. The method of claim 999, wherein the one or more heat sources comprise natural distributed combustors.
1006. The method of claim 999, wherein the minimum pyrolysis temperature is greater than about 270 °C.
1007. The method of claim 999, wherein the vaporization temperature is less than approximately 450 °C at atmospheric pressure.
1008. The method of claim 999, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1009. The method of claim 999, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1010. The method of claim 999, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1011. The method of claim 999, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1012. The method of claim 999, wherein providing heat from the one or more heat sources comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
WHAT IS CLAIMED IS:
1. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least one portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
controlling the heat from the one or more heat sources such that an average temperature within at least a majority of the selected section of the formation is less than about 375 °C; and producing a mixture from the formation.
2. The method of claim 1, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
3. The method of claim 1, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
4. The method of claim 1, wherein the one or more heat sources comprise electrical heaters.
5. The method of claim 1, wherein the one or more heat sources comprise surface burners.
6. The method of claim 1, wherein the one or more heat sources comprise flameless distributed combustors.
7. The method of claim 1, wherein the one or more heat sources comprise natural distributed combustors.
8. The method of claim 1, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
9. The method of claim 1, further comprising controlling a pressure within at least a majority of the selected section of the formation with a valve coupled to at least one of the one or more heat sources.
10. The method of claim 1, further comprising controlling a pressure within at least a majority of the selected section of the formation with a valve coupled to a production well located in the formation.
11. The method of claim 1, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
12. The method of claim 1, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
1024. The method of claim 999, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1025. The method of claim 999, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1026. The method of claim 999, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1027. The method of claim 999, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1028. The method of claim 999, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1029. The method of claim 999, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1030. The method of claim 1029, wherein the partial pressure of H2 is measured when the mixture is at a production well.
1031. The method of claim 999, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1032. The method of claim 999, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1033. The method of claim 999, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1034. The method of claim 999, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1035. The method of claim 999, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1036. The method of claim 999, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1037. The method of claim 999, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1038. The method of claim 1037, wherein at least about 20 heat sources are disposed in the formation for each production well.
1039. The method of claim 999, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1040. The method of claim 999, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1041. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
controlling a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than 25; and producing a mixture from the formation.
1042. The method of claim 1041, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1043. The method of claim 1041, wherein the one or more heat sources comprise electrical heaters.
1044. The method of claim 1041, wherein the one or more heat sources comprise surface burners.
1045. The method of claim 1041, wherein the one or more heat sources comprise flameless distributed combustors.
1046. The method of claim 1041, wherein the one or more heat sources comprise natural distributed combustors.
1047. The method of claim 1041, further comprising controlling a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1048. The method of claim 1047, wherein controlling the temperature comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
1049. The method of claim 1041, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1050. The method of claim 1041, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1051. The method of claim 1041, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1052. The method of claim 1041, wherein providing heat from the one or more heat sources comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1053. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1054. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1055. The method of claim 1041, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
1056. The method of claim 1041, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
1057. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1058. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1059. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1060. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1061. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1062. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1063. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1064. The method of claim 1041, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1065. The method of claim 1041, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1066. The method of claim 1041, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1067. The method of claim 1041, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1068. The method of claim 1041, further comprising controlling the pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1069. The method of claim 1041, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1070. The method of claim 1069, wherein the partial pressure of H2 is measured when the mixture is at a production well.
1071. The method of claim 1041, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1072. The method of claim 1041, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1073. The method of claim 1041, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1074. The method of claim 1041, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1075. The method of claim 1041, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1076. The method of claim 1041, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1077. The method of claim 1041, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1078. The method of claim 1077, wherein at least about 20 heat sources are disposed in the formation for each production well.
1079. The method of claim 1041, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1080. The method of claim 1041, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1081. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1082. The method of claim 1081, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1083. The method of claim 1081, wherein the one or more heat sources comprise electrical heaters.
1084. The method of claim 1081, wherein the one or more heat sources comprise surface burners.
1085. The method of claim 1081, wherein the one or more heat sources comprise flameless distributed combustors.
1086. The method of claim 1081, wherein the one or more heat sources comprise natural distributed combustors.
1087. The method of claim 1081, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1088. The method of claim 1081, wherein controlling the temperature comprises maintaining the temperature within the selected section within a pyrolysis temperature range.
1089. The method of claim 1081, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1090. The method of claim 1081, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1091. The method of claim 1081, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1092. The method of claim 1081, wherein providing heat from the one or more heat sources comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1093. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1094. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1095. The method of claim 1081, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
1096. The method of claim 1081, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
1097. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1098. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1099. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1100. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1101. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1102. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1103. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1104. The method of claim 1081, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1105. The method of claim 1081, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1106. The method of claim 1081, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1107. The method of claim 1081, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1108. The method of claim 1081, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1109. The method of claim 1081, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1110. The method of claim 1109, wherein the partial pressure of H2 is measured when the mixture is at a production well.
1111. The method of claim 1081, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1112. The method of claim 1081, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1113. The method of claim 1081, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1114. The method of claim 1081, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1115. The method of claim 1081, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1116. The method of claim 1081, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1117. The method of claim 1081, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1118. The method of claim 1081, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1119. The method of claim 1118, wherein at least about 20 heat sources are disposed in the formation for each production well.
1120. The method of claim 1081, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1121. The method of claim 1081, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1122. A method of treating an oil shale formation in situ, comprising:
heating a section of the formation to a pyrolysis temperature from at least a first heat source, a second heat source and a third heat source, and wherein the first heat source, the second heat source and the third heat source are located along a perimeter of the section;
controlling heat input to the first heat source, the second heat source and the third heat source to limit a heating rate of the section to a rate configured to produce a mixture from the formation with an olefin content of less than about 15% by weight of condensable fluids (on a dry basis) within the produced mixture; and producing the mixture from the formation through a production well.
1123. The method of claim 1122, wherein superposition of heat form the first heat source, second heat source, and third heat source pyrolyzes. a portion of the hydrocarbons within the formation to fluids.
1124. The method of claim 1122, wherein the pyrolysis temperature is between about 270 °C and about 400 °C.
1125. The method of claim 1122, wherein the first heat source is operated for less than about twenty-four hours a day.
1126. The method of claim 1122, wherein the first heat source comprises an electrical heater.
1127. The method of claim 1122, wherein the first heat source comprises a surface burner.
1128. The method of claim 1122, wherein the first heat source comprises a flameless distributed combustor.
1129. The method of claim 1122, wherein the first heat source, second heat source and third heat source are positioned substantially at apexes of an equilateral triangle.
1130. The method of claim 1122, wherein the production well is located substantially at a geometrical center of the first heat source, second heat source, and third heat source.
1131. The method of claim 1122, further comprising a fourth heat source, fifth heat source, and sixth heat source located along the perimeter of the section.
1132. The method of claim 1131, wherein the heat sources are located substantially at apexes of a regular hexagon.
1133. The method of claim 1132, wherein the production well is located substantially at a center of the hexagon.
1134. The method of claim 1122, further comprising controlling a pressure and a temperature within at least a majority of the section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1135. The method of claim 1122, wherein controlling the temperature comprises maintaining the temperature within the selected section within a pyrolysis temperature range.
1136. The method of claim 1122, further comprising controlling the heat such that an average heating rate of the section is less than about 3 °C per day during pyrolysis.
1137. The method of claim 1122, further comprising controlling the heat such that an average heating rate of the section is less than about 1 °C per day during pyrolysis.
1138. The method of claim 1122, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1139. The method of claim 1122, wherein heating the section of the formation comprises transferring heat substantially by conduction.
1140. The method of claim 1122, wherein providing heat from the one or more heat sources comprises heating the section such that a thermal conductivity of at least a portion of the section is greater than about 0.5 W/(m °C).
1141. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1142. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1143. The method of claim 1122, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
1144. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1145. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
411~
1146. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1147. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1148. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1149. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1150. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1151. The method of claim 1122, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1152. The method of claim 1122, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1153. The method of claim 1122, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1154. The method of claim 1122, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1155. The method of claim 1122, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1156. The method of claim 1122, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1157. The method of claim 1156, wherein the partial pressure of H2 is measured when the mixture is at a production well.
1158. The method of claim 1122, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1159. The method of claim 1122, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1160. The method of claim 1122, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1161. The method of claim 1122, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1162. The method of claim 1122, wherein heating the section comprises increasing a permeability of a majority of the section to greater than about 100 millidarcy.
1163. The method of claim 1122, wherein heating the section comprises substantially uniformly increasing a permeability of a majority of the section.
1164. The method of claim 1122, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1165. The method of claim 1122, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1166. The method of claim 1165, wherein at least about 20 heat sources are disposed in the formation for each production well.
1167. The method of claim 1122, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1168. The method of claim 1122, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1169. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1170. The method of claim 1169, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1171. The method of claim 1169, wherein the one or more heat sources comprise electrical heaters.
1172. The method of claim 1169, wherein the one or more heat sources comprise surface burners.
1173. The method of claim 1169, wherein the one or more heat sources comprise flameless distributed combustors.
1174. The method of claim 1169, wherein the one or more heat sources comprise natural distributed combustors.
1175. The method of claim 1169, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1176. The method of claim 1175, wherein controlling the temperature comprises maintaining the temperature within the selected section within a pyrolysis temperature range.
1177. The method of claim 1169, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1178. The method of claim 1169, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1179. The method of claim 1169, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1180. The method of claim 1169, wherein providing heat from the one or more heat sources comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1181. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1182. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1183. The method of claim 1169, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
1184. The method of claim 1169, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
1185. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1186. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1187. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1188. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1189. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1190. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1191. The method of claim 1169, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1192. The method of claim 1169, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1193. The method of claim 1169, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1194. The method of claim 1169, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1195. The method of claim 1169, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1196. The method of claim 1169, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1197. The method of claim 1196, wherein the partial pressure of H2 is measured when the mixture is at a production well.
1198. The method of claim 1169, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1199. The method of claim 1169, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1200. The method of claim 1169, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1201. The method of claim 1169, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1202. The method of claim 1169, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1203. The method of claim 1169, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1204. The method of claim 1169, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1205. The method of claim 1169, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1206. The method of claim 1205, wherein at least about 20 heat sources are disposed in the formation for each production well.
1207. The method of claim 1169, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1208. The method of claim 1169, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1209. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1210. The method of claim 1209, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1211. The method of claim 1209, wherein the one or more heat sources comprise electrical heaters.
1212. The method of claim 1209, wherein the one or more heat sources comprise surface burners.
1213. The method of claim 1209, wherein the one or more heat sources comprise flameless distributed combustors.
1214. The method of claim 1209, wherein the one or more heat sources comprise natural distributed combustors.
1215. The method of claim 1209, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1216. The method of claim 1215, wherein controlling the temperature comprises maintaining the temperature within the selected section within a pyrolysis temperature range.
1217. The method of claim 1209, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1218. The method of claim 1209, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1219. The method of claim 1209, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1220. The method of claim 1209, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1221. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1222. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1% by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1223. The method of claim 1209, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
1224. The method of claim 1209, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
1225. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1226. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1227. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1228. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1229. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1230. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1231. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1232. The method of claim 1209, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1233. The method of claim 1209, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1234. The method of claim 1209, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1235. The method of claim 1209, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1236. The method of claim 1209, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1237. The method of claim 1209, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1238. The method of claim 1237, wherein the partial pressure of H2 is measured when the mixture is at a production well.
1239. The method of claim 1209, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1240. The method of claim 1209, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1241. The method of claim 1209, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1242. The method of claim 1209, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1243. The method of claim 1209, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1244. The method of claim 1209, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1245. The method of claim 1209, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1246. The method of claim 1209, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1247. The method of claim 1246, wherein at least about 20 heat sources are disposed in the formation for each production well.
1248. The method of claim 1209, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1249. The method of claim 1209, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1250. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1251. The method of claim 1250, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1252. The method of claim 1250, wherein the one or more heat sources comprise electrical heaters.
1253. The method of claim 1250, wherein the one or more heat sources comprise surface burners.
1254. The method of claim 1250, wherein the one or more heat sources comprise flameless distributed combustors.
1255. The method of claim 1250, wherein the one or more heat sources comprise natural distributed combustors.
1256. The method of claim 1250, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1257. The method of claim 1256, wherein controlling the temperature comprises maintaining the temperature within the selected section within a pyrolysis temperature range.
1258. The method of claim 1250, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1259. The method of claim 1250, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1260. The method of claim 1250, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1261. The method of claim 1250, wherein providing heat from the one or more heat sources comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1262. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1263. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1264. The method of claim 1250, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the non-condensable hydrocarbons are olefins.
1265. The method of claim 1250, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001.
1266. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1267. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1268. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1269. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1270. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1271. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1272. The method of claim 1250, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1273. The method of claim 1250, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1274. The method of claim 1250, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1275. The method of claim 1250, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1276. The method of claim 1250, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1277. The method of claim 1250, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1278. The method of claim 1277, wherein the partial pressure of H2 is measured when the mixture is at a production well.
1279. The method of claim 1250, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1280. The method of claim 1250, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1281. The method of claim 1250, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1282. The method of claim 1250, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1283. The method of claim 1250, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1284. The method of claim 1250, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1285. The method of claim 1250, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1286. The method of claim 1250, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1287. The method of claim 1286, wherein at least about 20 heat sources are disposed in the formation for each production well.
1288. The method of claim 1250, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1289. The method of claim 1250, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1290. A method of treating an oil shale formation in situ, comprising:
raising a temperature of a first section of the formation with one or more heat sources to a first pyrolysis temperature;
heating the first section to an upper pyrolysis temperature, wherein heat is supplied to the first section at a rate configured to inhibit olefin production;
producing a first mixture from the formation, wherein the first mixture comprises condensable hydrocarbons and H2;
creating a second mixture from the first mixture, wherein the second mixture comprises a higher concentration of H2 than the first mixture;
raising a temperature of a second section of the formation with one or more heat sources to a second pyrolysis temperature;
providing a portion of the second mixture to the second section;
heating the second section to an upper pyrolysis temperature, wherein heat is supplied to the second section at a rate configured to inhibit olefin production; and producing a third mixture from the second section.
1291. The method of claim 1290, wherein creating the second mixture comprises removing condensable hydrocarbons from the first mixture.
1292. The method of claim 1290, wherein creating the second mixture comprises removing water from the first mixture.
1293. The method of claim 1290, wherein creating the second mixture comprises removing carbon dioxide from the first mixture.
1294. The method of claim 1290, wherein the first pyrolysis temperature is greater than about 270 °C.
1295. The method of claim 1290, wherein the second pyrolysis temperature is greater than about 270 °C.
1296. The method of claim 1290, wherein the upper pyrolysis temperature is about 500 °C.
1297. The method of claim 1290, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the first or second selected section of the formation.
1298. The method of claim 1290, wherein the one or more heat sources comprise electrical heaters.
1299. The method of claim 1290, wherein the one or more heat sources comprise surface burners.
1300. The method of claim 1290, wherein the one or more heat sources comprise flameless distributed combustors.
1301. The method of claim 1290, wherein the one or more heat sources comprise natural distributed combustors.
1302. The method of claim 1290, further comprising controlling a pressure and a temperature within at least a majority of the first section and the second section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1303. The method of claim 1290, further comprising controlling the heat to the first and second sections such that an average heating rate of the first and second sections is less than about 1 °C per day during pyrolysis.
1304. The method of claim 1290, wherein heating the first and the second sections comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1305. The method of claim 1290, wherein heating the first and second sections comprises transferring heat substantially by conduction.
1306. The method of claim 1290, wherein heating the first and second sections comprises heating the first and second sections such that a thermal conductivity of at least a portion of the first and second sections is greater than about 0.5 W/(m °C).
1307. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1308. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein about 0.1% by weight to about 15% by weight of the condensable hydrocarbons are olefins.
1309. The method of claim 1290, wherein the first or third mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1310. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1311. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1312. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1313. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1314. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1315. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1316. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1317. The method of claim 1290, wherein the first or third mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1318. The method of claim 1290, wherein the first or third mixture comprises a non-condensable component, and wherein the non-condensable component comprises hydrogen, and wherein the hydrogen is greater than about 10%
by volume of the non-condensable component and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1319. The method of claim 1290, wherein the first or third mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1320. The method of claim 1290, wherein the first or third mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1321. The method of claim 1290, further comprising controlling a pressure within at least a majority of the first or second sections of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1322. The method of claim 1290, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2within the mixture is greater than about 0.5 bars.
1323. The method of claim 1322, wherein the partial pressure of H2within a mixture is measured when the mixture is at a production well.
1324. The method of claim 1290, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1325. The method of claim 1290, further comprising:
providing hydrogen (H2) to the first or second section to hydrogenate hydrocarbons within the first or second section; and heating a portion of the first or second section with heat from hydrogenation.
1326. The method of claim 1290, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1327. The method of claim 1290, further comprising increasing a permeability of a majority of the first or second section to greater than about 100 millidarcy.
1328. The method of claim 1290, further comprising substantially uniformly increasing a permeability of a majority of the first or second section.
1329. The method of claim 1290, wherein the heating is controlled to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1330. The method of claim 1290, wherein producing the first or third mixture comprises producing the first or third mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1331. The method of claim 1330, wherein at least about 20 heat sources are disposed in the formation for each production well.
1332. The method of claim 1290, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1333. The method of claim 1290, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1334. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
producing a mixture from the formation; and hydrogenating a portion of the produced mixture with H2 produced from the formation.
1335. The method of claim 1334, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1336. The method of claim 1334, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1337. The method of claim 1334, wherein the one or more heat sources comprise electrical heaters.
1338. The method of claim 1334, wherein the one or more heat sources comprise surface burners.
1339. The method of claim 1334, wherein the one or more heat sources comprise flameless distributed combustors.
1340. The method of claim 1334, wherein the one or more heat sources comprise natural distributed combustors.
1341. The method of claim 1334, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1342. The method of claim 1334, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1°C per day during pyrolysis.
1343. The method of claim 1334, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1344. The method of claim 1334, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1345. The method of claim 1334, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1346. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1347. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1348. The method of claim 1334, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1349. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1350. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1351. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1352. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1353. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1354. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1355. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1356. The method of claim 1334, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1357. The method of claim 1334, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1358. The method of claim 1334, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1359. The method of claim 1334, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1360. The method of claim 1334, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1361. The method of claim 1334, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1362. The method of claim 1334, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1363. The method of claim 1334, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1364. The method of claim 1334, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1365. The method of claim 1334, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1366. The method of claim 1334, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1367. The method of claim 1334, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1368. The method of claim 1334, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1369. The method of claim 1368, wherein at least about 20 heat sources are disposed in the formation for each production well.
1370. The method of claim 1334, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1371. The method of claim 1334, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1372. A method of treating an oil shale formation in situ, comprising:
heating a first section of the formation;
producing H2 from the first section of formation;
heating a second section of the formation; and recirculating a portion of the H2 from the first section into the second section of the formation to provide a reducing environment within the second section of the formation.
1373. The method of claim 1372, wherein heating the first section or heating the second section comprises heating with an electrical heater.
1374. The method of claim 1372, wherein heating the first section or heating the second section comprises heating with a surface burner.
1375. The method of claim 1372, wherein heating the first section or heating the second section comprises heating with a flameless distributed combustor.
1376. The method of claim 1372, wherein heating the first section or heating the second section comprises heating with a natural distributed combustor.
1377. The method of claim 1372, further comprising controlling a pressure and a temperature within at least a majority of the first or second section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1378. The method of claim 1372, further comprising controlling the heat such that an average heating rate of the first or second section is less than about 1 °C per day during pyrolysis.
1379. The method of claim 1372, wherein heating the first section or heating the second section further comprises:
heating a selected volume (~) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (~~), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C~*p~
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1380. The method of claim 13?2, wherein heating the first section or heating the second section comprises transferring heat substantially by conduction.
1381. The method of claim 1372, wherein heating the first section or heating the second section comprises heating the formation such that a thermal conductivity of at least a portion of the first or second section is greater than about 0.5 W/(m °C).
1382. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1383. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1384. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0. 15.
1385. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1386. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1387. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1388. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1389. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1390. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1391. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1392. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1393. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1394. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1395. The method of claim 1372, further comprising producing a mixture from the second section, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1396. The method of claim 1372, further comprising controlling a pressure within at least a majority of the first or second section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1397. The method of claim 1372, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1398. The method of claim 1397, wherein the partial pressure of H2 within a mixture is measured when the mixture is at a production well.
1399. The method of claim 1372, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1400. The method of claim 1372, further comprising:
providing hydrogen (H2) to the second section to hydrogenate hydrocarbons within the section; and heating a portion of the second section with heat from hydrogenation.
1401. The method of claim 1372, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1402. The method of claim 1372, wherein heating the first section or heating the second section comprises increasing a permeability of a majority of the first or second section, respectively, to greater than about 100 millidarcy.
1403. The method of claim 1372, wherein heating the first section or heating the second section comprises substantially uniformly increasing a permeability of a majority of the first or second section, respectively.
1404. The method of claim 1372, further comprising controlling the heating of the first section or controlling the heat of the second section to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1405. The method of claim 1372, further comprising producing a mixture from the formation in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1406. The method of claim 1405, wherein at least about 20 heat sources are disposed in the formation for each production well.
1407. The method of claim 1372, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1408. The method of claim 1372, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1409. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
producing a mixture from the formation; and controlling formation conditions such that the mixture produced from the formation comprises condensable hydrocarbons including H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1410. The method of claim 1409, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1411. The method of claim 1409, wherein controlling formation conditions comprises maintaining a temperature within the selected section within a pyrolysis temperature range.
1412. The method of claim 1409, wherein the one or more heat sources comprise electrical heaters.
1413. The method of claim 1409, wherein the one or more heat sources comprise surface burners.
1414. The method of claim 1409, wherein the one or more heat sources comprise flameless distributed combustors.
1415. The method of claim 1409, wherein the one or more heat sources comprise natural distributed combustors.
1416. The method of claim 1409, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1417. The method of claim 1409, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1418. The method of claim 1409, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1419. The method of claim 1409, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1420. The method of claim 1409, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1421. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1422. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1423. The method of claim 1409, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1424. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1425. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1426. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1427. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1428. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1429. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1430. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1431. The method of claim 1409, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1432. The method of claim 1409, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1433. The method of claim 1409, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1434. The method of claim 1409, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1435. The method of claim 1409, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1436. The method of claim 1409, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1437. The method of claim 1409, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
1438. The method of claim 1409, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1439. The method of claim 1409, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1440. The method of claim 1409, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1441. The method of claim 1409, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1442. The method of claim 1409, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1443. The method of claim 1409, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1444. The method of claim 1443, wherein at least about 20 heat sources are disposed in the formation for each production well.
1445. The method of claim 1409, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1446. The method of claim 1409, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1447. The method of claim 1409, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1448. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
maintaining a pressure of the selected section above atmospheric pressure to increase a partial pressure of H2, as compared to the partial pressure of H2 at atmospheric pressure, in at least a majority of the selected section;
and producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1449. The method of claim 1448, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1450. The method of claim 1448, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1451. The method of claim 1448, wherein the one or more heat sources comprise electrical heaters.
1452. The method of claim 1448, wherein the one or more heat sources comprise surface burners.
14$3. The method of claim 1448, wherein the one or more heat sources comprise flameless distributed combustors.
1454. The method of claim 1448, wherein the one or more heat sources comprise natural distributed combustors.
1455. The method of claim 1448, further comprising controlling the pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1456. The method of claim 1448, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1457. The method of claim 1448, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (~) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (~~), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*~*~~*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p~ is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1458. The method of claim 1448, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1459. The method of claim 1448, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1460. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1461. The method of claim 1448, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1462. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1463. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1464. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1465. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1466. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1467. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1468. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1469. The method of claim 1448, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1470. The method of claim 1448, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1471. The method of claim 1448, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1472. The method of claim 1448, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1473. The method of claim 1448, further comprising controlling the pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1474. The method of claim 1448, further comprising increasing the pressure of the selected section, to an upper limit of about 21 bars absolute, to increase an amount of non-condensable hydrocarbons produced from the formation.
1475. The method of claim 1448, further comprising decreasing pressure of the selected section, to a lower limit of about atmospheric pressure, to increase an amount of condensable hydrocarbons produced from the formation.
1476. The method of claim 1448, wherein a partial pressure comprises a partial pressure based on properties measured at a production well.
1477. The method of claim 1448, further comprising altering the pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1478. The method of claim 1448, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1479. The method of claim 1448, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1480. The method of claim 1448, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1481. The method of claim 1448, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1482. The method of claim 1448, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1483. The method of claim 1448, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1484. The method of claim 1448, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1485. The method of claim 1484, wherein at least about 20 heat sources are disposed in the formation for each production well.
1486. The method of claim 1448, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1487. The method of claim 1448, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1488. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
providing H2 to the formation to produce a reducing environment in at least some of the formation;
producing a mixture from the formation.
1489. The method of claim 1488, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1490. The method of claim 1488, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1491. The method of claim 1488, further comprising separating a portion of hydrogen within the mixture and recirculating the portion into the formation.
1492. The method of claim 1488, wherein the one or more heat sources comprise electrical heaters.
1493. The method of claim 1488, wherein the one or more heat sources comprise surface burners.
1494. The method of claim 1488, wherein the one or more heat sources comprise flameless distributed combustors.
1495. The method of claim 1488, wherein the one or more heat sources comprise natural distributed combustors.
1496. The method of claim 1488, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1497. The method of claim 1488, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1498. The method of claim 1488, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1499. The method of claim 1488, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1500. The method of claim 1488, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1501. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1502. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1503. The method of claim 1488, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1504. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1505. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1506. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1507. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1508. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1509. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1510. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1511. The method of claim 1488, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1512. The method of claim 1488, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1513. The method of claim 1488, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1514. The method of claim 1488, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1515. The method of claim 1488, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1516. The method of claim 1488, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1517. The method of claim 1488, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1518. The method of claim 1488, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1519. The method of claim 1488, wherein providing hydrogen (H2) to the formation further comprises:
hydrogenating hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1520. The method of claim 1488, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1521. The method of claim 1488, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1522. The method of claim 1488, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1523. The method of claim 1488, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1524. The method of claim 1488, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1525. The method of claim 1524, wherein at least about 20 heat sources are disposed in the formation for each production well.
1526. The method of claim 1488, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1527. The method of claim 1488, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1528. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
providing H2 to the selected section to hydrogenate hydrocarbons within the selected section and to heat a portion of the section with heat from the hydrogenation; and controlling heating of the selected section by controlling amounts of H2 provided to the selected section.
1529. The method of claim 1528, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1530. The method of claim 1528, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1531. The method of claim 1528, wherein the one or more heat sources comprise electrical heaters.
1532. The method of claim 1528, wherein the one or more heat sources comprise surface burners.
1533. The method of claim 1528, wherein the one or more heat sources comprise flameless distributed combustors.
1534. The method of claim 1528, wherein the one or more heat sources comprise natural distributed combustors.
1535. The method of claim 1528, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1536. The method of claim 1528, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1537. The method of claim 1528, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p8 is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1538. The method of claim 1528, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1539. The method of claim 1528, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1540. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1541. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1542. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1543. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1544. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1545. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1546. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1547. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1548. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1549. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1550. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1551. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1552. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1553. The method of claim 1528, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1554. The method of claim 1528, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1555. The method of claim 1528, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1556. The method of claim 1555, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1557. The method of claim 1528, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1558. The method of claim 1528, further comprising controlling formation conditions by recirculating a portion of hydrogen from a produced mixture into the formation.
1559. The method of claim 1528, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1560. The method of claim 1528, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1561. The method of claim 1528, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1562. The method of claim 1528, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1563. The method of claim 1562, wherein at least about 20 heat sources are disposed in the formation for each production well.
1564. The method of claim 1528, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1565. The method of claim 1528, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1566. An in situ method for producing H2 from an oil shale formation, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation, wherein a H2 partial pressure within the mixture is greater than about 0.5 bars.
1567. The method of claim 1566, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1568. The method of claim 1566, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1569. The method of claim 1566, wherein the one or more heat sources comprise electrical heaters.
1570. The method of claim 1566, wherein the one or more heat sources comprise surface burners.
1571. The method of claim 1566, wherein the one or more heat sources comprise flameless distributed combustors.
1572. The method of claim 1566, wherein the one or more heat sources comprise natural distributed combustors.
1573. The method of claim 1566, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1574. The method of claim 1566, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1575. The method of claim 1566, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1576. The method of claim 1566, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1577. The method of claim 1566, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1578. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1579. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1580. The method of claim 1566, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1581. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1582. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1583. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1584. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1585. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1586. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1587. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1588. The method of claim 1566, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1589. The method of claim 1566, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1590. The method of claim 1566, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1591. The method of claim 1566, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1592. The method of claim 1566, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1593. The method of claim 1566, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1594. The method of claim 1566, further comprising recirculating a portion of the hydrogen within the mixture into the formation.
1595. The method of claim 1566, further comprising condensing a hydrocarbon component from the produced mixture and hydrogenating the condensed hydrocarbons with a portion of the hydrogen.
1596. The method of claim 1566, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1597. The method of claim 1566, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1598. The method of claim 1566, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1599. The method of claim 1566, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1600. The method of claim 1566, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1601. The method of claim 1600, wherein at least about 20 heat sources are disposed in the formation for each production well.
1602. The method of claim 1566, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1603. The method of claim 1566, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1604. The method of claim 1566, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1605. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section has been selected for heating using an atomic hydrogen weight percentage of at least a portion of hydrocarbons in the selected section, and wherein at least the portion of the hydrocarbons in the selected section comprises an atomic hydrogen weight percentage, when measured on a dry, ash-free basis, of greater than about 4.0 %; and producing a mixture from the formation.
1606. The method of claim 1605, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1607. The method of claim 1605, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1608. The method of claim 1605, wherein the one or more heat sources comprise electrical heaters.
1609. The method of claim 1605, wherein the one or more heat sources comprise surface burners.
1610. The method of claim 1605, wherein the one or more heat sources comprise flameless distributed combustors.
1611. The method of claim 1605, wherein the one or more heat sources comprise natural distributed combustors.
1612. The method of claim 1605, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1613. The method of claim 1605, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1614. The method of claim 1605, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1615. The method of claim 1605, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1616. The method of claim 1605, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1617. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1618. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1619. The method of claim 1605, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1620. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1621. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1622. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1623. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1624. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1625. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1626. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1627. The method of claim 1605, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1628. The method of claim 1605, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1629. The method of claim 1605, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1630. The method of claim 1605, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1631. The method of claim 1605, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1632. The method of claim 1605, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1633. The method of claim 1632, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1634. The method of claim 1605, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1635. The method of claim 1605, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1636. The method of claim 1605, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1637. The method of claim 1605, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1638. The method of claim 1605, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1639. The method of claim 1605, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1640. The method of claim 1605, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1641. The method of claim 1605, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1642. The method of claim 1641, wherein at least about 20 heat sources are disposed in the formation for each production well.
1643. The method of claim 1605, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1644. The method of claim 1605, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1645. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein at least some hydrocarbons within the selected section have an initial atomic hydrogen weight percentage of greater than about 4.0 %; and producing a mixture from the formation.
1646. The method of claim 1645, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1647. The method of claim 1645, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1648. The method of claim 1645, wherein the one or more heat sources comprise electrical heaters.
1649. The method of claim 1645, wherein the one or more heat sources comprise surface burners, 1650. The method of claim 1645, wherein the one or more heat sources comprise flameless distributed combustors.
1651. The method of claim 1645, wherein the one or more heat sources comprise natural distributed combustors.
1652. The method of claim 1645, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1653. The method of claim 1645, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1654. The method of claim 1645, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (Cv), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*Cv*Pb wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1655. The method of claim 1645, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1656. The method of claim 1645, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1657. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1658. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1659. The method of claim 1645, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1660. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1661. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1662. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1663. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1664. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1665. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1666. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1667. The method of claim 1645, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloallcanes.
1668. The method of claim 1645, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1669. The method of claim 1645, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1670. The method of claim 1645, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1671. The method of claim 1645, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1672. The method of claim 1645, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1673. The method of claim 1672, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1674. The method of claim 1645, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1675. The method of claim 1645, further comprising controlling formation conditions by recirculating a. portion of hydrogen from the mixture into the formation.
1676. The method of claim 1645, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1677. The method of claim 1645, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1678. The method of claim 1645, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1679. The method of claim 1645, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1680. The method of claim 1645, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1681. The method of claim 1645, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1682. The method of claim 1681, wherein at least about 20 heat sources are disposed in the formation for each production well.
1683. The method of claim 1645, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1684. The method of claim 1645, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1685. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section has been selected for heating using vitrinite reflectance of at least some hydrocarbons in the selected section, and wherein at least a portion of the hydrocarbons in the selected section comprises a vitrinite reflectance of greater than about 0.3 %;
wherein at least a portion of the hydrocarbons in the selected section comprises a vitrinite reflectance of less than about 4.5 %; and producing a mixture from the formation.
1686. The method of claim 1685, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1687. The method of claim 1685, further comprising maintaining a temperature within the selected section within a pyrolysis temperature.
1688. The method of claim 1685, wherein the vitrinite reflectance of at least the portion of hydrocarbons within the selected section is between about 0.47 % and about 1.5 % such that a majority of the produced mixture comprises condensable hydrocarbons.
1689. The method of claim 1685, wherein the vitrinite reflectance of at least the portion of hydrocarbons within the selected section is between about 1.4 % and about 4.2 % such that a majority of the produced mixture comprises non-condensable hydrocarbons.
1690. The method of claim 1685, wherein the one or more heat sources comprise electrical heaters.
1691. The method of claim 1685, wherein the one or more heat sources comprise surface burners.
1692. The method of claim 1685, wherein the one or more heat sources comprise flameless distributed combustors.
1693. The method of claim 1685, wherein the one or more heat sources comprise natural distributed combustors.
1694. The method of claim 1685, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1695. The method of claim 1685, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1696. The method of claim 1685, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (Cv), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*Cv*pB
wherein Pwr is the heating energy/day,h is an average heating rate of the formation, pb is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1697. The method of claim 1685, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
, 1698. The method of claim 1685, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1699. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1700. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1701. The method of claim 1685, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1702. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1703. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1704. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
' 1705. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1706. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1707. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1708. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1709. The method of claim 1685, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1710. The method of claim 1685, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1711. The method of claim 1685, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1712. The method of claim 1685, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1713. The method of claim 1685, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1714. The method of claim 1685, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1715. The method of claim 1714, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1716. The method of claim 1685, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1717. The method of claim 1685, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1718. The method of claim 1685, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1719. The method of claim 1685, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1720. The method of claim 1685, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1721. The method of claim 1685, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1722. The method of claim 1685, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1723. The method of claim 1685, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1724. The method of claim 1723, wherein at least about 20 heat sources are disposed in the formation for each production well.
1725. The method of claim 1685, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1726. The method of claim 1685, further comprising providing heat from three or more heat sources to at least a portion of the fonnation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1727. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section has been selected for heating using a total organic matter weight percentage of at least a portion of the selected section, and wherein at least the portion of the selected section comprises a total organic matter weight percentage, of at least about 5.0 %; and producing a mixture from the formation.
1728. The method of claim 1727, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1729. The method of claim 1727, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1730. The method of claim 1727, wherein the one or more heat sources comprise electrical heaters.
1731. The method of claim 1727, wherein the one or more heat sources comprise surface burners.
1732. The method of claim 1727, wherein the one or more heat sources comprise flameless distributed combustors.
1733. The method of claim 1727, wherein the one or more heat sources comprise natural distributed combustors.
1734. The method of claim 1727, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1735. . The method of claim 1727, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1736. The method of claim 1727, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1737. The method of claim 1727, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1738. The method of claim 1727, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1739. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1740. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1741. The method of claim 1727, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1742. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1743. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1744. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1745. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1746. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1747. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises mufti-ring aromatics with more than two rings.
1748. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1749. The method of claim 1727, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1750. The method of claim 1727, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1751. The method of claim 1727, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1752. The method of claim 1727, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1753. The method of claim 1727, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1754. The method of claim 1727, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1755. The method of claim 1754, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1756. The method of claim 1727, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1757. The method of claim 1727, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1758. The method of claim 1727, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1759. The method of claim 1727, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1760. The method of claim 1727, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1761. The method of claim 1727, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1762. The method of claim 1727, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1763. The method of claim 1727, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1764. The method of claim 1763, wherein at least about 20 heat sources are disposed in the formation for each production well.
1765. The method of claim 1727, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1766. The method of claim 1727, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1767. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein at least some hydrocarbons within the selected section have an initial total organic matter weight percentage of at least about 5.0%; and producing a mixture from the formation.
1768. The method of claim 1767, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1769. The method of claim 1767, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1770. The method of claim 1767, wherein the one or more heat sources comprise electrical heaters.
1771. The method of claim 1767, wherein the one or more heat sources comprise surface burners.
1772. The method of claim 1767, wherein the one or more heat sources comprise flameless distributed combustors.
1773. The method of claim 1767, wherein the one or more heat sources comprise natural distributed combustors.
1774. The method of claim 1767, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1775. The method of claim 1767, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1776. The method of claim 1767, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volmne of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p$ is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1777. The method of claim 1767, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1778. The method of claim 1767, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1779. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1780. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1781. The method of claim 1767, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1782. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1783. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1784. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1785. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1786. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1787. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1788. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1789. The method of claim 1767, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1790. The method of claim 1767, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1791. The method of claim 1767, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1792. The method of claim 1767, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1793. The method of claim 1767, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1794. The method of claim 1767, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1795. The method of claim 1794, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1796. The method of claim 1767, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1797. The method of claim 1767, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1798. The method of claim 1767, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1799. The method of claim 1767, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1800. The method of claim 1767, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1801. The method of claim 1767, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1802. The method of claim 1767, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1803. The method of claim 1767, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1804. The method of claim 1803, wherein at least about 20 heat sources are disposed in the formation for each production well.
1805. The method of claim 1767, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1806. The method of claim 1767, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1807. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section has been selected for heating using an atomic oxygen weight percentage of at least a portion of hydrocarbons in the selected section, and wherein at least a portion of the hydrocarbons in the selected section comprises an atomic oxygen weight percentage of less than about 15% when measured on a dry, ash free basis; and producing a mixture from the formation.
1808. The method of claim 1807, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1809. The method of claim 1807, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1810. The method of claim 1807, wherein the one or more heat sources comprise electrical heaters.
1811. The method of claim 1807, wherein the one or more heat sources comprise surface burners.
1812. The method of claim 1807, wherein the one or more heat sources comprise flameless distributed combustors.
1813. The method of claim 1807, wherein the one or more heat sources comprise natural distributed combustors.
1814. The method of claim 1807, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1815. The method of claim 1807, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1816. The method of claim 1807, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1817. The method of claim 1807, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1818. The method of claim 1807, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1819. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1820. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1821. The method of claim 1807, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1822. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1823. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1824. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1825. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1826. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1827. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1828. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1829. The method of claim 1807, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1830. The method of claim 1807, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1831. The method of claim 1807, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1832. The method of claim 1807, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1833. The method of claim 1807, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1834. The method of claim 1807, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1835. The method of claim 1834, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1836. The method of claim 1807, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1837. The method of claim 1807, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1838. The method of claim 1807, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1839. The method of claim 1807, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1840. The method of claim 1807, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1841. The method of claim 1807, wherein allowing the heat to transfer further comprises substantially uniformly increasing a permeability of a majority of the selected section.
1842. The method of claim 1807, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1843. The method of claim 1807, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1844. The method of claim 1843, wherein at least about 20 heat sources are disposed in the formation for each production well.
1845. The method of claim 1807, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1846. The method of claim 1807, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1847. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to a selected section of the formation;
allowing the heat to transfer from the one or more heat sources to the selected section of the formation to pyrolyze hydrocarbon within the selected section;
wherein at least some hydrocarbons within the selected section have an initial atomic oxygen weight percentage of less than about 15 %; and producing a mixture from the formation.
1848. The method of claim 1847, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1849. The method of claim 1847, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range 1850. The method of claim 1847, wherein the one or more heat sources comprise electrical heaters.
1851. The method of claim 1847, wherein the one or more heat sources comprise surface burners.
1852. The method of claim 1847, wherein the one or more heat sources comprise flameless distributed combustors.
1853. The method of claim 1847, wherein the one or more heat sources comprise natural distributed combustors.
1854. The method of claim 1847, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1855. The method of claim 1847, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1856. The method of claim 1847, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, la is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
1857. The method of claim 1847, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1858. The method of claim 1847, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1859. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1860. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1861. The method of claim 1847, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1862. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1863. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1864. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1865. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1866. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1867. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1868. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1869. The method of claim 1847, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1870. The method of claim 1847, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1871. The method of claim 1847, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1872. The method of claim 1847, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1873. The method of claim 1847, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1874. The method of claim 1847, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of Hz within the mixture is greater than about 0.5 bars.
1875. The method of claim 1874, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1876. The method of claim 1847, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1877. The method of claim 1847, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1878. The method of claim 1847, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1879. The method of claim 1847, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1880. The method of claim 1847, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1881. The method of claim 1847, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1882. The method of claim 1847, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1883. The method of claim 1847, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1884. The method of claim 1883, wherein at least about 20 heat sources are disposed in the formation for each production well.
1885. The method of claim 1847, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1886. The method of claim 1847, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1887. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section has been selected for heating using an atomic hydrogen to carbon ratio of at least a portion of hydrocarbons in the selected section, wherein at least a portion of the hydrocarbons in the selected section comprises an atomic hydrogen to carbon ratio greater than about 0.70, and wherein the atomic hydrogen to carbon ratio is less than about 1.65; and producing a mixture from the formation.
1888. The method of claim 1887, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1889. The method of claim 1887, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1890. The method of claim 1887, wherein the one or more heat sources comprise electrical heaters.
1891. The method of claim 1887, wherein the one or more heat sources comprise surface burners.
1892. The method of claim 1887, wherein the one or more heat sources comprise flameless distributed combustors.
1893. The method of claim 1887, wherein the one or more heat sources comprise natural distributed combustors.
1894. The method of claim 1887, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1895. The method of claim 1887, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1896. The method of claim 1887, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulls density, and wherein the heating rate is less than about 10 °C/day.
1897. The method of claim 1887, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1898. The method of claim 1887, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1899. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1900. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1901. The method of claim 1887, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1902. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1903. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1904. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1905. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1906. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1907. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1908. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1909. The method of claim 1887, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1910. The method of claim 1887, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1911. The method of claim 1887, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1912. The method of claim 1887, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1913. The method of claim 1887, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1914. The method of claim 1887, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1915. The method of claim 1914, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1916. The method of claim 1887, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1917. The method of claim 1887, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1918. The method of claim 1887, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1919. The method of claim 1887, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1920. The method of claim 1887, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1921. The method of claim 1887, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1922. The method of claim 1887, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1923. The method of claim 1887, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1924. The method of claim 1923, wherein at least about 20 heat sources are disposed in the formation for each production well.
1925. The method of claim 1887, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1926. The method of claim 1887, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1927. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to a selected section of the formation;
allowing the heat to transfer from the one or more heat sources to the selected section of the formation to pyrolyze hydrocarbons within the selected section;
wherein at least some hydrocarbons within the selected section have an initial atomic hydrogen to carbon ratio greater than about 0.70;
wherein the initial atomic hydrogen to carbon ratio is less than about 1.65;
and producing a mixture from the formation.
1928. The method of claim 1927, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1929. The method of claim 1927, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1930. The method of claim 1927, wherein the one or more heat sources comprise electrical heaters.
1931. The method of claim 1927, wherein the one or more heat sources comprise surface burners.
1932. The method of claim 1927, wherein the one or more heat sources comprise flameless distributed combustors.
1933. The method of claim 1927, wherein the one or more heat sources comprise natural distributed combustors.
1934. The method of claim 1927, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1935. The method of claim 1927, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1936. The method of claim 1927, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulls density, and wherein the heating rate is less than about 10 °C/day.
1937. The method of claim 1927, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1938. The method of claim 1927, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
1939. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1940. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1941. The method of claim 1927, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1942. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1943. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1944. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1945. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1946. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1947. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
1948. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1949. The method of claim 1927, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1950. The method of claim 1927, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1951. The method of claim 1927, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1952. The method of claim 1927, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1953. The method of claim 1927, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1954. The method of claim 1927, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1955. The method of claim 1954, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
1956. The method of claim 1927, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1957. The method of claim 1927, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1958. The method of claim 1927, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1959. The method of claim 1927, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
1960. The method of claim 1927, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
1961. The method of claim 1927, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
1962. The method of claim 1927, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
1963. The method of claim 1927, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
1964. The method of claim 1963, wherein at least about 20 heat sources are disposed in the formation for each production well.
1965. The method of claim 1927, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
1966. The method of claim 1927, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
1967. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section has been selected for heating using an atomic oxygen to carbon ratio of at least a portion of hydrocarbons in the selected section, wherein at least a portion of the hydrocarbons in the selected section comprises an atomic oxygen to carbon ratio greater than about 0.025, and wherein the atomic oxygen to carbon ratio of at least a portion of the hydrocarbons in the selected section is less than about 0.15; and producing a mixture from the formation.
1968. The method of claim 1967, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
1969. The method of claim 1967, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
1970. The method of claim 1967, wherein the one or more heat sources comprise electrical heaters.
1971. The method of claim 1967, wherein the one or more heat sources comprise surface burners.
1972. The method of claim 1967, wherein the one or more heat sources comprise flameless distributed combustors.
1973. The method of claim 1967, wherein the one or more heat sources comprise natural distributed combustors.
1974. The method of claim 1967, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
1975. The method of claim 1967, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
1976. The method of claim 1967, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10°C/day.
1977. The method of claim 1967, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
1978. The method of claim 1967, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m°C).
1979. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
1980. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
1981. The method of claim 1967, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
1982. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
1983. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
1984. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
1985. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
1986. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
1987. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises mufti-ring aromatics with more than two rings.
1988. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
1989. The method of claim 1967, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
1990. The method of claim 1967, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
1991. The method of claim 1967, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
1992. The method of claim 1967, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
1993. The method of claim 1967, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
1994. The method of claim 1967, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
1995. The method of claim 1994, wherein the partial pressure of HZ within the mixture is measured when the mixture is at a production well.
1996. The method of claim 1967, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
1997. The method of claim 1967, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
1998. The method of claim 1967, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
1999. The method of claim 1967, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2000. The method of claim 1967, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2001. The method of claim 1967, wherein allowing the heat to transfer further comprises substantially uniformly increasing a permeability of a majority of the selected section.
2002. The method of claim 1967, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2003. The method of claim 1967, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2004. The method of claim 2003, wherein at least about 20 heat sources are disposed in the formation for each production well.
2005. The method of claim 1967, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2006. The method of claim 1967, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2007. A method of treating an oil shale formation in situ, comprising providing heat from one or more heat sources to a selected section of the formation;
allowing the heat to transfer from the one or more heat sources to the selected section of the formation to pyrolyze hydrocarbons within the selected section;
wherein at least some hydrocarbons within the selected section have an initial atomic oxygen to carbon ratio greater than about 0.025;
wherein the initial atomic oxygen to carbon ratio is less than about 0.15; and producing a mixture from the formation.
2008. The method of claim 2007, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2009. The method of claim 2007, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2010. The method of claim 2007, wherein the one or more heat sources comprise electrical heaters.
2011. The method of claim 2007, wherein the one or more heat sources comprise surface burners.
2012. The method of claim 2007, wherein the one or more heat sources comprise flameless distributed combustors.
2013. The method of claim 2007, wherein the one or more heat sources comprise natural distributed combustors.
2014. The method of claim 2007, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2015. The method of claim 2007, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1°C per day during pyrolysis.
2016. The method of claim 2007, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p$ is formation bulls density, and wherein the heating rate is less than about 10°C/day.
2017. The method of claim 2007, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2018. The method of claim 2007, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2019. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2020. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2021. The method of claim 2007, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2022. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2023. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2024. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2025. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2026. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2027. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2028. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2029. The method of claim 2007, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2030. The method of claim 2007, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2031. The method of claim 2007, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2032. The method of claim 2007, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2033. The method of claim 2007, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2034. The method of claim 2007, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2035. The method of claim 2034, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2036. The method of claim 2007, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2037. The method of claim 2007, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
203 8. The method of claim 2007, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2039. The method of claim 2007, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2040. The method of claim 2007, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2041. The method of claim 2007, wherein allowing the heat to transfer further comprises substantially uniformly increasing a permeability of a majority of the selected section.
2042. The method of claim 2007, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2043. The method of claim 2007, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2044. The method of claim 2043, wherein at least about 20 heat sources are disposed in the formation for each production well.
2045. The method of claim 2007, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2046. The method of claim 2007, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2047. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section has been selected for heating using a moisture content in the selected section, and wherein at least a portion of the selected section comprises a moisture content of less than about 15 % by weight; and producing a mixture from the formation.
2048. The method of claim 2047, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2049. The method of claim 2047, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2050. The method of claim 2047, wherein the one or more heat sources comprise electrical heaters.
2051. The method of claim 2047, wherein the one or more heat sources comprise surface burners.
2052. The method of claim 2047, wherein the one or more heat sources comprise flameless distributed combustors.
2053. The method of claim 2047, wherein the one or more heat sources comprise natural distributed combustors.
2054. The method of claim 2047, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2055. The method of claim 2047, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2056. The method of claim 2047, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2057. The method of claim 2047, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2058. The method of claim 2047, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2059. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2060. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2061. The method of claim 2047, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2062. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2063. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2064. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2065. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2066. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2067. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2068. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2069. The method of claim 2047, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2070. The method of claim 2047, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2071. The method of claim 2047, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2072. The method of claim 2047, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2073. The method of claim 2047, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2074. The method of claim 2047, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2075. The method of claim 2074, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2076. The method of claim 2047, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2077. The method of claim 2047, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2078. The method of claim 2047, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2079. The method of claim 2047, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2080. The method of claim 2047, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2081. The method of claim 2047, wherein allowing the heat to transfer further comprises substantially uniformly increasing a permeability of a majority of the selected section.
2082. The method of claim 2047, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2083. The method of claim 2047, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2084. The method of claim 2083, wherein at least about 20 heat sources are disposed in the formation for each production well.
2085. The method of claim 2047, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2086. The method of claim 2047, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2087. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to a selected section of the formation;
allowing the heat to transfer from the one or more heat sources to the selected section of the formation;
wherein at least a portion of the selected section has an initial moisture content of less than about 15 % by weight; and producing a mixture from the formation.
2088. The method of claim 2087, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2089. The method of claim 2087, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2090. The method of claim 2087, wherein the one or more heat sources comprise electrical heaters.
2091. The method of claim 2087, wherein the one or more heat sources comprise surface burners.
2092. The method of claim 2087, wherein the one or more heat sources comprise flameless distributed combustors.
2093. The method of claim 2087, wherein the one or more heat sources comprise natural distributed combustors.
2094. The method of claim 2087, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2095. The method of claim 2087, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2096. The method of claim 2087, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2097. The method of claim 2087, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2098. The method of claim 2087, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2099. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2100. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2101. The method of claim 2087, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2102. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2103. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2104. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2105. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2106. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2107. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2108. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2109. The method of claim 2087, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2110. The method of claim 2087, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2111. The method of claim 2087, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2112. The method of claim 2087, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2113. The method of claim 2087, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2114. The method of claim 2087, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2115. The method of claim 2114, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2116. The method of claim 2087, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2117. The method of claim 2087, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2118. The method of claim 2087, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2119. The method of claim 2087, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2120. The method of claim 2087, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2121. The method of claim 2087, wherein allowing the heat to transfer further comprises substantially uniformly increasing a permeability of a majority of the selected section.
2122. The method of claim 2087, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2123. The method of claim 2087, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2124. The method of claim 2124, wherein at least about 20 heat sources are disposed in the formation for each production well.
2125. The method of claim 2087, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2126. The method of claim 2087, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2127. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation;
wherein the selected section is heated in a reducing environment during at least a portion of the time that the selected section is being heated; and producing a mixture from the formation.
2128. The method of claim 2127, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2129. The method of claim 2127, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2130. The method of claim 2127, wherein the one or more heat sources comprise electrical heaters.
2131. The method of claim 2127, wherein the one or more heat sources comprise surface burners.
2132. The method of claim 2127, wherein the one or more heat sources comprise flameless distributed combustors.
2133. The method of claim 2127, wherein the one or more heat sources comprise natural distributed combustors.
2134. The method of claim 2127, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2135. The method of claim 2127, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2136. The method of claim 2127, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C"*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2137. The method of claim 2127, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2138. The method of claim 2127, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2139. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2140. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2141. The method of claim 2127, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2142. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2143. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2144. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2145. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2146. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2147. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2148. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2149. The method of claim 2127, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2150. The method of claim 2127, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2151. The method of claim 2127, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2152. The method of claim 2127, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2153. The method of claim 2127, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2154. The method of claim 2127, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2155. The method of claim 2154, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2156. The method of claim 2127, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2157. The method of claim 2127, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2158. The method of claim 2127, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2159. The method of claim 2127, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2160. The method of claim 2127, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2161. The method of claim 2127, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2162. The method of claim 2127, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2163. The method of claim 2127, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2164. The method of claim 2163, wherein at least about 20 heat sources are disposed in the formation for each production well.
2165. The method of claim 2127, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2166. The method of claim 2127, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2167. A method of treating an oil shale formation in situ, comprising:
heating a first section of the formation to produce a mixture from the formation;
heating a second section of the formation; and recirculating a portion of the produced mixture from the first section into the second section of the formation to provide a reducing environment within the second section of the formation.
2168. The method of claim 2167, further comprising maintaining a temperature within the first section or the second section within a pyrolysis temperature range.
2169. The method of claim 2167, wherein heating the first or the second section comprises heating with an electrical heater.
2170. The method of claim 2167, wherein heating the first or the second section comprises heating with a surface burner.
2171. The method of claim 2167, wherein heating the first or the second section comprises heating with a flameless distributed combustor.
2172. The method of claim 2167, wherein heating the first or the second section comprises heating with a natural distributed combustor.
2173. The method of claim 2167, further comprising controlling a pressure and a temperature within at least a majority of the first or second section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2174. The method of claim 2167, further comprising controlling the heat such that an average heating rate of the first or the second section is less than about 1 °C per day during pyrolysis.
2175. The method of claim 2167, wherein heating the first or the second section comprises:
heating a selected volume (V) of the oil shale formation from one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h *Y*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulls density, and wherein the heating rate is less than about 10 °C/day.
2176. The method of claim 2167, wherein heating the first or the second section comprises transferring heat substantially by conduction.
2177. The method of claim 2167, wherein heating the first or the second section comprises heating the first or the second section such that a thermal conductivity of at least a portion of the first or the second section is greater than about 0.5 W/(m °C).
2178. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2179. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2180. The method of claim 2167, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2181. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2182. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2183. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2184. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2185. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2186. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2187. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2188. The method of claim 2167, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2189. The method of claim 2167, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2190. The method of claim 2167, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2191. The method of claim 2167, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2192. The method of claim 2167, further comprising controlling a pressure within at least a majority of the first or second section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2193. The method of claim 2167, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2194. The method of claim 2193, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2195. The method of claim 2167, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2196. The method of claim 2167, further comprising:
providing hydrogen (H2) to the first or second section to hydrogenate hydrocarbons within the first or second section; and heating a portion of the first or second section with heat from hydrogenation.
2197. The method of claim 2167, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2198. The method of claim 2167, wherein heating the first or the second section comprises increasing a permeability of a majority of the first or the second section to greater than about 100 millidarcy.
2199. The method of claim 2167, wherein heating the first or the second section comprises substantially uniformly increasing a permeability of a majority of the first or the second section.
2200. The method of claim 2167, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2201. The method of claim 2167, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2202. The method of claim 2201, wherein at least about 20 heat sources are disposed in the formation for each production well.
2203. The method of claim 2167, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2204. The method of claim 2167, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2205. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation; and allowing the heat to transfer from the one or more heat sources to a selected section of the formation such that a permeability of at least a portion of the selected section increases to greater than about 100 millidarcy.
2206. The method of claim 2205, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2207. The method of claim 2205, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2208. The method of claim 2205, wherein the one or more heat sources comprise electrical heaters.
2209. The method of claim 2205, wherein the one or more heat sources comprise surface burners.
2210. The method of claim 2205, wherein the one or more heat sources comprise flameless distributed combustors.
2211. The method of claim 2205, wherein the one or more heat sources comprise natural distributed combustors.
2212. The method of claim 2205, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2213. The method of claim 2205, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2214. The method of claim 2205, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2215. The method of claim 2205, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2216. The method of claim 2205, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2217. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2218. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2219. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2220. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2221. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2222. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2223. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2224. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2225. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2226. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2227. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2228. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2229. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2230. The method of claim 2205, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2231. The method of claim 2205, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2232. The method of claim 2205, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2233. The method of claim 2232, further comprising producing a mixture from the formation, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2234. The method of claim 2205, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2235. The method of claim 2205, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2236. The method of claim 2205, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2237. The method of claim 2205, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2238. The method of claim 2205, further comprising increasing a permeability of a majority of the selected section to greater than about 5 Darcy.
2239. The method of claim 2205, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2240. The method of claim 2205, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2241. The method of claim 2205, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2242. The method of claim 2241, wherein at least about 20 heat sources are disposed in the formation for each production well.
2243. The method of claim 2205, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2244. The method of claim 2205, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2245. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation; and allowing the heat to transfer from the one or more heat sources to a selected section of the formation such that a permeability of a majority of at least a portion of the selected section increases substantially uniformly.
2246. The method of claim 2245, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2247. The method of claim 2245, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2248. The method of claim 2245, wherein the one or more heat sources comprise electrical heaters.
2249. The method of claim 2245, wherein the one or more heat sources comprise surface burners.
2250. The method of claim 2245, wherein the one or more heat sources comprise flameless distributed combustors.
2251. The method of claim 2245, wherein the one or more heat sources comprise natural distributed combustors.
2252. The method of claim 2245, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2253. The method of claim 2245, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2254. The method of claim 2245, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2255. The method of claim 2245, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2256. The method of claim 2245, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2257. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2258. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2259. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2260. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2261. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2262. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2263. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2264. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2265. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2266. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2267. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2268. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2269. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2270. The method of claim 2245, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2271. The method of claim 2245, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2272. The method of claim 2245, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2273. The method of claim 2245, further comprising producing a mixture from the formation, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2274. The method of claim 2245, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2275. The method of claim 2245, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2276. The method of claim 2245, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2277. The method of claim 2245, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2278. The method of claim 2245, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2279. The method of claim 2245, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2280. The method of claim 2245, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2281. The method of claim 2280, wherein at least about 20 heat sources are disposed in the formation for each production well.
2282. The method of claim 2245, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2283. The method of claim 2245, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2284. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation; and allowing the heat to transfer from the one or more heat sources to a selected section of the formation such that a porosity of a majority of at least a portion of the selected section increases substantially uniformly.
2285. The method of claim 2284, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2286. The method of claim 2284, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2287. The method of claim 2284, wherein the one or more heat sources comprise electrical heaters.
2288. The method of claim 2284, wherein the one or more heat sources comprise surface burners.
2289. The method of claim 2284, wherein the one or more heat sources comprise flameless distributed combustors.
2290. The method of claim 2284, wherein the one or more heat sources comprise natural distributed combustors.
2291. The method of claim 2284, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2292. The method of claim 2284, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2293. The method of claim 2284, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulls density, and wherein the heating rate is less than about 10 °C/day.
2294. The method of claim 2284, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2295. The method of claim 2284, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2296. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2297. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2298. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2299. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2300. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2301. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2302. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2303. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2304. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2305. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2306. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2307. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2308. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2309. The method of claim 2284, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2310. The method of claim 2284, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2311. The method of claim 2284, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2312. The method of claim 2284, further comprising producing a mixture from the formation, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2313. The method of claim 2284, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2314. The method of claim 2284, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2315. The method of claim 2284, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2316. The method of claim 2284, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2317. The method of claim 2284, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2318. The method of claim 2284, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2319. The method of claim 2284, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2320. The method of claim 2284, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2321. The method of claim 2320, wherein at least about 20 heat sources are disposed in the formation for each production well.
2322. The method of claim 2284, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2323. The method of claim 2284, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2324. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and controlling the heat to yield at least about 15 % by weight of a total organic carbon content of at least some of the oil shale formation into condensable hydrocarbons.
2325. The method of claim 2324, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2326. The method of claim 2324, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2327. The method of claim 2324, wherein the one or more heat sources comprise electrical heaters.
2328. The method of claim 2324, wherein the one or more heat sources comprise surface burners.
2329. The method of claim 2324, wherein the one or more heat sources comprise flameless distributed combustors.
2330. The method of claim 2324, wherein the one or more heat sources comprise natural distributed combustors.
2331. The method of claim 2324, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2332. The method of claim 2324, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2333. The method of claim 2324, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2334. The method of claim 2324, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2335. The method of claim 2324, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2336. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2337. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2338. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2339. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2340. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2341. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2342. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2343. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2344. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2345. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2346. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2347. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2348. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2349. The method of claim 2324, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2350. The method of claim 2324, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2351. The method of claim 2324, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2352. The method of claim 2324, further comprising producing a mixture from the formation, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2353. The method of claim 2324, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2354. The method of claim 2324, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2355. The method of claim 2324, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2356. The method of claim 2324, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2357. The method of claim 2324, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2358. The method of claim 2324, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2359. The method of claim 2324, wherein the heating is controlled to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2360. The method of claim 2324, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2361. The method of claim 2360, wherein at least about 20 heat sources are disposed in the formation for each production well.
2362. The method of claim 2324, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2363. The method of claim 2324, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2364. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2365. The method of claim 2364, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2366. The method of claim 2364, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2367. The method of claim 2364, wherein the one or more heat sources comprise electrical heaters.
2368. The method of claim 2364, wherein the one or more heat sources comprise surface burners.
2369. The method of claim 2364, wherein the one or more heat sources comprise flameless distributed combustors.
2370. The method of claim 2364, wherein the one or more heat sources comprise natural distributed combustors.
2371. The method of claim 2364, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2372. The method of claim 2364, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2373. The method of claim 2364, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2374. The method of claim 2364, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2375. The method of claim 2364, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2376. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2377. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2378. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2379. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2380. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2381. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2382. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2383. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2384. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2385. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2386. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2387. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2388. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2389. The method of claim 2364, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2390. The method of claim 2364, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2391. The method of claim 2364, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2392. The method of claim 2364, further comprising producing a mixture from the formation, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2393. The method of claim 2364, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2394. The method of claim 2364, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2395. The method of claim 2364, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2396. The method of claim 2364, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2397. The method of claim 2364, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2398. The method of claim 2364, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2399. The method of claim 2364, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2400. The method of claim 2399, wherein at least about 20 heat sources are disposed in the formation for each production well.
2401. The method of claim 2364, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2402. The method of claim 2364, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2403. A method of treating an oil shale formation in situ, comprising:
heating a first section of the formation to pyrolyze at least some hydrocarbons in the first section and produce a first mixture from the formation;
heating a second section of the formation to pyrolyze at least some hydrocarbons in the second section and produce a second mixture from the formation; and leaving an unpyrolyzed section between the first section and the second section to inhibit subsidence of the formation.
2404. The method of claim 2403, further comprising maintaining a temperature within the first section or the second section within a pyrolysis temperature range.
2405. The method of claim 2403, wherein heating the first section or heating the second section comprises heating with an electrical heater.
2406. The method of claim 2403, wherein heating the first section or heating the second section comprises heating with a surface burner.
2407. The method of claim 2403, wherein heating the first section or heating the second section comprises heating with a flameless distributed combustor.
2408. The method of claim 2403, wherein heating the first section or heating the second section comprises heating with a natural distributed combustor.
2409. The method of claim 2403, further comprising controlling a pressure and a temperature within at least a majority of the first or second section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2410. The method of claim 2403, further comprising controlling the heat such that an average heating rate of the first or second section is less than about 1 °C per day during pyrolysis.
2411. The method of claim 2403, wherein heating the first section or heating the second section comprises:
heating a selected volume (V) of the oil shale formation from one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.RHO.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .RHO.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2412. The method of claim 2403, wherein heating the first section or heating the second section comprises transferring heat substantially by conduction.
2413. The method of claim 2403, wherein heating the first section or heating the second section comprises heating the formation such that a thermal conductivity of at least a portion of the first or second section, respectively, is greater than about 0.5 W/(m °C).
2414. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2415. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2416. The method of claim 2403, wherein the first or second mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2417. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2418. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2419. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2420. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2421. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2422. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2423. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2424. The method of claim 2403, wherein the first or second mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2425. The method of claim 2403, wherein the first or second mixture comprises a non-condensable component, and wherein the non-condensable component comprises hydrogen, and wherein the hydrogen is greater than about % by volume of the non-condensable component and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2426. The method of claim 2403, wherein the first or second mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the first or second mixture is ammonia.
2427. The method of claim 2403, wherein the first or second mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2428. The method of claim 2403, further comprising controlling a pressure within at least a majority of the first or second section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2429. The method of claim 2403, further comprising controlling formation conditions to produce the first or second mixture, wherein a partial pressure of H2 within the first or second mixture is greater than about 0.5 bars.
2430. The method of claim 2403, wherein a partial pressure of H2 within the first or second mixture is measured when the first or second mixture is at a production well.
2431. The method of claim 2403, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2432. The method of claim 2403, further comprising controlling formation conditions by recirculating a portion of hydrogen from the first or second mixture into the formation.
2433. The method of claim 2403, further comprising:
providing hydrogen (H2) to the first or second section to hydrogenate hydrocarbons within the first or second section, respectively; and heating a portion of the first or second section, respectively, with heat from hydrogenation.
2434. The method of claim 2403, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2435. The method of claim 2403, wherein heating the first section or heating the second section comprises increasing a permeability of a majority of the first or second section, respectively, to greater than about 100 millidarcy.
2436. The method of claim 2403, wherein heating the first section or heating the second section comprises substantially uniformly increasing a permeability of a majority of the first or second section, respectively.
2437. The method of claim 2403, further comprising controlling heating of the first or second section to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay, from the first or second section, respectively.
2438. The method of claim 2403, wherein producing the first or second mixture comprises producing the first or second mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2439. The method of claim 2438, wherein at least about 20 heat sources are disposed in the formation for each production well.
2440. The method of claim 2403, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2441. The method of claim 2403, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2442. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation through one or more production wells, wherein the heating is controlled such that the mixture can be produced from the formation as a vapor, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2443. The method of claim 2442, wherein at least about 20 heat sources are disposed in the formation for each production well.
2444. The method of claim 2442, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2445. The method of claim 2442, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2446. The method of claim 2442, wherein the one or more heat sources comprise electrical heaters.
2447. The method of claim 2442, wherein the one or more heat sources comprise surface burners.
2448. The method of claim 2442, wherein the one or more heat sources comprise flameless distributed combustors.
2449. The method of claim 2442, wherein the one or more heat sources comprise natural distributed combustors.
2450. The method of claim 2442, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2451. The method of claim 2442, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2452. The method of claim 2442, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C"*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulls density, and wherein the heating rate is less than about 10 °C/day.
2453. The method of claim 2442, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
244. The method of claim 2442, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2455. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2456. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1% by weight to about 15% by weight of the condensable hydrocarbons are olefins.
2457. The method of claim 2442, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2458. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2459. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2460. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2461. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2462. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2463. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2464. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2465. The method of claim 2442, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2466. The method of claim 2442, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2467. The method of claim 2442, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2468. The method of claim 2442, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2469. The method of claim 2442, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2470. The method of claim 2442, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2471. The method of claim 2470, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2472. The method of claim 2442, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2473. The method of claim 2442, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2474. The method of claim 2442, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2475. The method of claim 2442, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2476. The method of claim 2442, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2477. The method of claim 2442, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2478. The method of claim 2442, wherein the heating is controlled to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2479. The method of claim 2442, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2480. The method of claim 2442, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2481. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation, wherein the one or more heat sources are disposed within one or more first wells;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation through one or more second wells, wherein one or more of the first or second wells are initially used for a first purpose and are then used for one or more other purposes.
2482. The method of claim 2481, wherein the first purpose comprises removing water from the formation, and wherein the second purpose comprises providing heat to the formation.
2483. The method of claim 2481, wherein the first purpose comprises removing water from the formation, and wherein the second purpose comprises producing the mixture.
2484. The method of claim 2481, wherein the first purpose comprises heating, and wherein the second purpose comprises removing water from the formation.
2485. The method of claim 2481, wherein the first purpose comprises producing the mixture, and wherein the second purpose comprises removing water from the formation.
2486. The method of claim 2481, wherein the one or more heat sources comprise electrical heaters.
2487. The method of claim 2481, wherein the one or more heat sources comprise surface burners.
2488. The method of claim 2481, wherein the one or more heat sources comprise flameless distributed combustors.
2489. The method of claim 2481, wherein the one or more heat sources comprise natural distributed combustors.
2490. The method of claim 2481, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2491. The method of claim 2481, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1.0°C per day during pyrolysis.
2492. The method of claim 2481, wherein providing heat from the one or more heat sources to at least the portion of the formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2493. The method of claim 2481, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2494. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2495. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1% by weight to about 15% by weight of the condensable hydrocarbons are olefins.
2496. The method of claim 2481, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2497. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2498. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2499. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2500. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2501. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2502. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2503. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2504. The method of claim 2481, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2505. The method of claim 2481, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2506. The method of claim 2481, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2507. The method of claim 2481, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2508. The method of claim 2481, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2509. The method of claim 2481, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H2, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2510. The method of claim 2509, wherein the partial pressure of H2 is measured when the mixture is at a production well.
2511. The method of claim 2481, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2512. The method of claim 2481, further comprising controlling formation conditions, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation.
2513. The method of claim 2481, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2514. The method of claim 2481, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2515. The method of claim 2481, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2516. The method of claim 2481, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2517. The method of claim 2481, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2518. The method of claim 2481, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2519. The method of claim 2518, wherein at least about 20 heat sources are disposed in the formation for each production well.
2520. The method of claim 2481, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2521. The method of claim 2481, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2522. A method for forming heater wells in an oil shale formation, comprising:
forming a first wellbore in the formation;
forming a second wellbore in the formation using magnetic tracking such that the second wellbore is arranged substantially parallel to the first wellbore; and providing at least one heat source within the first wellbore and at least one heat source within the second wellbore such that the heat sources can provide heat to at least a portion of the formation.
2523. The method of claim 2522, wherein superposition of heat from the at least one heat source within the first wellbore and the at least one heat source within the second wellbore pyrolyzes at least some hydrocarbons within a selected section of the formation.
2524. The method of claim 2522, further comprising maintaining a temperature within a selected section within a pyrolysis temperature range.
2525. The method of claim 2522, wherein the heat sources comprise electrical heaters.
2526. The method of claim 2522, wherein the heat sources comprise surface burners.
2527. The method of claim 2522, wherein the heat sources comprise flameless distributed combustors.
2528. The method of claim 2522, wherein the heat sources comprise natural distributed combustors.
2529. The method of claim 2522, further comprising controlling a pressure and a temperature within at least a majority of a selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2530. The method of claim 2522, further comprising controlling the heat from the heat sources such that heat transferred from the heat sources to at least the portion of the hydrocarbons is less than about 1 °C per day during pyrolysis.
2531. The method of claim 2522, further comprising:
heating a selected volume (V) of the oil shale formation from the heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2532. The method of claim 2522, further comprising allowing the heat to transfer from the heat sources to at least the portion of the formation substantially by conduction.
2533. The method of claim 2522, further comprising providing heat from the heat sources to at least the portion of the formation such that a thermal conductivity of at least the portion of the formation is greater than about 0.5 W/(m °C).
2534. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2535. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2536. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2537. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2538. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2539. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2540. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2541. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2542. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2543. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2544. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2545. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2546. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2547. The method of claim 2522, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2548. The method of claim 2522, further comprising controlling a pressure within at least a majority of a selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2549. The method of claim 2522, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2550. The method of claim 2522, further comprising producing a mixture from the formation, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2551. The method of claim 2522, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2552. The method of claim 2522, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2553. The method of claim 2522, further comprising:
providing hydrogen (H2) to the portion to hydrogenate hydrocarbons within the formation; and heating a portion of the formation with heat from hydrogenation.
2554. The method of claim 2522, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2555. The method of claim 2522, further comprising allowing heat to transfer from the heat sources to a selected section of the formation to pyrolyze at least some hydrocarbons within the selected section such that a permeability of a majority of a selected section of the formation increases to greater than about 100 millidarcy.
2556. The method of claim 2522, further comprising allowing heat to transfer from the heat sources to a selected section of the formation to pyrolyze at least some hydrocarbons within the selected section such that a permeability of a majority of the selected section increases substantially uniformly.
2557. The method of claim 2522, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2558. The method of claim 2522, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2559. The method of claim 2558, wherein at least about 20 heat sources are disposed in the formation for each production well.
2560. The method of claim 2522, further comprising forming a production well in the formation using magnetic tracking such that the production well is substantially parallel to the first wellbore and coupling a wellhead to the third wellbore.
2561. The method of claim 2522, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2562. The method of claim 2522, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2563. A method for installing a heater well into an oil shale formation, comprising:
forming a bore in the ground using a steerable motor and an accelerometer; and providing a heat source within the bore such that the heat source can transfer heat to at least a portion of the formation.
2564. The method of claim 2563, further comprising installing at least two heater wells, and wherein superposition of heat from at least the two heater wells pyrolyzes at least some hydrocarbons within a selected section of the formation.
2565. The method of claim 2563, further comprising maintaining a temperature within a selected section within a pyrolysis temperature range.
2566. The method of claim 2563, wherein the heat source comprises an electrical heater.
2567. The method of claim 2563, wherein the heat source comprises a surface burner.
2568. The method of claim 2563, wherein the heat source comprises a flameless distributed combustor.
2569. The method of claim 2563, wherein the heat source comprises a natural distributed combustor.
2570. The method of claim 2563, further comprising controlling a pressure and a temperature within at least a majority of a selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2571. The method of claim 2563, further comprising controlling the heat from the heat source such that heat transferred from the heat source to at least the portion of the formation is less than about 1 °C per day during pyrolysis.
2572. The method of claim 2563, further comprising:
heating a selected volume (V) of the oil shale formation from the heat source, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2573. The method of claim 2563, further comprising allowing the heat to transfer from the heat source to at least the portion of the formation substantially by conduction.
2574. The method of claim 2563, further comprising providing heat from the heat source to at least the portion of the formation such that a thermal conductivity of at least the portion of the formation is greater than about 0.5 W/(m °C).
2575. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2576. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2577. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2578. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2579. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2580. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2581. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2582. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2583. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2584. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2585. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2586. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2587. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2588. The method of claim 2563, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2589. The method of claim 2563, further comprising controlling a pressure within at least a majority of a selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2590. The method of claim 2563, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2591. The method of claim 2563, wherein a partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2592. The method of claim 2563, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2593. The method of claim 2563, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2594. The method of claim 2563, further comprising:
providing hydrogen (H2) to the at least the heated portion to hydrogenate hydrocarbons within the formation; and heating a portion of the formation with heat from hydrogenation.
2595. The method of claim 2563, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2596. The method of claim 2563, further comprising allowing heat to transfer from the heat source to a selected section of the formation to pyrolyze at least some hydrocarbons within the selected section such that a permeability of a majority of a selected section of the formation increases to greater than about 100 millidarcy.
2597. The method of claim 2563, further comprising allowing heat to transfer from the heat source to a selected section of the formation to pyrolyze at least some hydrocarbons within the selected section such that a permeability of a majority of the selected section increases substantially uniformly.
2598. The method of claim 2563, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2599. The method of claim 2563, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2600. The method of claim 2599, wherein at least about 20 heat sources are disposed in the formation for each production well.
2601. The method of claim 2563, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2602. The method of claim 2563, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2603. A method for installing of wells in an oil shale formation, comprising:
forming a wellbore in the formation by geosteered drilling; and providing a heat source within the wellbore such that the heat source can transfer heat to at least a portion of the formation.
2604. The method of claim 2603, further comprising maintaining a temperature within a selected section within a pyrolysis temperature range.
2605. The method of claim 2603, wherein the heat source comprises an electrical heater.
2606. The method of claim 2603, wherein the heat source comprises a surface burner.
2607. The method of claim 2603, wherein the heat source comprises a flameless distributed combustor.
2608. The method of claim 2603, wherein the heat source comprises a natural distributed combustor.
2609. The method of claim 2603, further comprising controlling a pressure and a temperature within at least a majority of a selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2610. The method of claim 2603, further comprising controlling the heat from the heat source such that heat transferred from the heat source to at least the portion of the formation is less than about 1 °C per day during pyrolysis.
2611. The method of claim 2603, further comprising:
heating a selected volume (V) of the oil shale formation from the heat source, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2612. The method of claim 2603, further comprising allowing the heat to transfer from the heat source to at least the portion of the formation substantially by conduction.
2613. The method of claim 2603, further comprising providing heat from the heat source to at least the portion of the formation such that a thermal conductivity of at least the portion of the formation is greater than about 0.5 W/(m °C).
2614. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2615. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2616. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2617. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2618. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2619. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2620. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2621. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2622. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2623. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2624. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2625. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2626. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2627. The method of claim 2603, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2628. The method of claim 2603, further comprising controlling a pressure within at least a majority of a selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2629. The method of claim 2603, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2630. The method of claim 2629, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2631. The method of claim 2603, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2632. The method of claim 2603, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2633. The method of claim 2603, further comprising:
providing hydrogen (H2) to at least the heated portion to hydrogenate hydrocarbons within the formation;
and heating a portion of the formation with heat from hydrogenation.
2634. The method of claim 2603, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2635. The method of claim 2603, further comprising allowing heat to transfer from the heat source to a selected section of the formation to pyrolyze at least some hydrocarbons within the selected section such that a permeability of a majority of a selected section of the formation increases to greater than about 100 millidarcy.
2636. The method of claim 2603, further comprising allowing heat to transfer from the heat source to a selected section of the formation to pyrolyze at least some hydrocarbons within the selected section such that a permeability of a majority of the selected section increases substantially uniformly.
2637. The method of claim 2603, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2638. The method of claim 2603, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2639. The method of claim 2638, wherein at least about 20 heat sources are disposed in the formation for each production well.
2640. The method of claim 2603, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2641. The method of claim 2603, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2642. A method of treating an oil shale formation in situ, comprising:
heating a selected section of the formation with a heating element placed within a wellbore, wherein at least one end of the heating element is free to move axially within the wellbore to allow for thermal expansion of the heating element.
2643. The method of claim 2642, further comprising at least two heating elements within at least two wellbores, and wherein superposition of heat from at least the two heating elements pyrolyzes at least some hydrocarbons within a selected section of the formation.
2644. The method of claim 2642, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2645. The method of claim 2642, wherein the heating element comprises a pipe-in-pipe heater.
2646. The method of claim 2642, wherein the heating element comprises a flameless distributed combustor.
2647. The method of claim 2642, wherein the heating element comprises a mineral insulated cable coupled to a support, and wherein the support is free to move within the wellbore.
2648. The method of claim 2642, wherein the heating element comprises a mineral insulated cable suspended from a wellhead.
2649. The method of claim 2642, further comprising controlling a pressure and a temperature within at least a majority of a heated section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2650. The method of claim 2642, further comprising controlling the heat such that an average heating rate of the heated section is less than about 1 °C per day during pyrolysis.
2651. The method of claim 2642, wherein heating the section of the formation further comprises:
heating a selected volume (V) of the oil shale formation from the heating element, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*pB
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, pB is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2652. The method of claim 2642, wherein heating the section of the formation comprises transferring heat substantially by conduction.
2653. The method of claim 2642, further comprising heating the selected section of the formation such that a thermal conductivity of the selected section is greater than about 0.5 W/(m °C).
2654. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2655. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 %
by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2656. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2657. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2658. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2659. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2660. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2661. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2662. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2663. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2664. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2665. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2666. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2667. The method of claim 2642, further comprising producing a mixture from the formation, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2668. The method of claim 2642, further comprising controlling a pressure within the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2669. The method of claim 2642, further comprising controlling formation conditions to produce a mixture from the formation, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2670. The method of claim 2669, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2671. The method of claim 2642, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2672. The method of claim 2642, further comprising producing a mixture from the formation and controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2673. The method of claim 2642, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the heated section; and heating a portion of the section with heat from hydrogenation.
2674. The method of claim 2642, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2675. The method of claim 2642, wherein heating comprises increasing a permeability of a majority of the heated section to greater than about 100 millidarcy.
2676. The method of claim 2642, wherein heating comprises substantially uniformly increasing a permeability of a majority of the heated section.
2677. The method of claim 2642, wherein the heating is controlled to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2678. The method of claim 2642, further comprising producing a mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2679. The method of claim 2678, wherein at least about 20 heat sources are disposed in the formation for each production well.
2680. The method of claim 2642, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2681. The method of claim 2642, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2682. A method of treating an oil shale formation in situ, comprising:
providing heat from one or more heat sources to at least a portion of the formation;
allowing the heat to transfer from the one or more heat sources to a selected section of the formation; and producing a mixture from the formation through a production well, wherein the production well is located such that a majority of the mixture produced from the formation comprises non-condensable hydrocarbons and a non-condensable component comprising hydrogen.
2683. The method of claim 2682, wherein the one or more heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2684. The method of claim 2682, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2685. The method of claim 2682, wherein the production well is less than approximately 6 m from a heat source of the one or more heat sources.
2686. The method of claim 2682, wherein the production well is less than approximately 3 m from a heat source of the one or more heat sources.
2687. The method of claim 2682, wherein the production well is less than approximately 1.5 m from a heat source of the one or more heat sources.
2688. The method of claim 2682, wherein an additional heat source is positioned within a wellbore of the production well.
2689. The method of claim 2682, wherein the one or more heat sources comprise electrical heaters.
2690. The method of claim 2682, wherein the one or more heat sources comprise surface burners.
2691. The method of claim 2682, wherein the one or more heat sources comprise flameless distributed combustors.
2692. The method of claim 2682, wherein the one or more heat sources comprise natural distributed combustors.
2693. The method of claim 2682, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2694. The method of claim 2682, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2695. The method of claim 2682, wherein providing heat from the one or more heat sources to at least the portion of formation comprises:
heating a selected volume (V) of the oil shale formation from the one or more heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulls density, and wherein the heating rate is less than about 10 °C/day.
2696. The method of claim 2682, wherein allowing the heat to transfer from the one or more heat sources to the selected section comprises transferring heat substantially by conduction.
2697. The method of claim 2682, wherein providing heat from the one or more heat sources comprises heating the selected section such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2698. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2699. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2700. The method of claim 2682, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2701. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2702. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2703. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2704. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2705. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2706. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2707. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2708. The method of claim 2682, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2709. The method of claim 2682, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2710. The method of claim 2682, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2711. The method of claim 2682, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2712. The method of claim 2682, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2713. The method of claim 2682, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2714. The method of claim 2713, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2715. The method of claim 2682, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2716. The method of claim 2682, further comprising controlling formation conditions by recirculating a portion of the hydrogen from the mixture into the formation.
2717. The method of claim 2682, further comprising:
providing hydrogen (H2) to the heated section to hydrogenate hydrocarbons within the section; and heating a portion of the section with heat from hydrogenation.
2718. The method of claim 2682, further comprising:
producing condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2719. The method of claim 2682, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2720. The method of claim 2682, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2721. The method of claim 2682, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2722. The method of claim 2682, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heat sources are disposed in the formation for each production well.
2723. The method of claim 2722, wherein at least about 20 heat sources are disposed in the formation for each production well.
2724. The method of claim 2682, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2725. The method of claim 2682, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2726. A method of treating an oil shale formation in situ, comprising:
providing heat to at least a portion of the formation from one or more first heat sources placed within a pattern in the formation;
allowing the heat to transfer from the one or more first heat sources to a first section of the formation;
heating a second section of the formation with at least one second heat source, wherein the second section is located within the first section, and wherein at least the one second heat source is configured to raise an average temperature of a portion of the second section to a higher temperature than an average temperature of the first section; and producing a mixture from the formation through a production well positioned within the second section, wherein a majority of the produced mixture comprises non-condensable hydrocarbons and a non-condensable component comprising H2 components.
2727. The method of claim 2726, wherein the one or more first heat sources comprise at least two heat sources, and wherein superposition of heat from at least the two heat sources pyrolyzes at least some hydrocarbons within the first section of the formation.
2728. The method of claim 2726, further comprising maintaining a temperature within the first section within a pyrolysis temperature range.
2729. The method of claim 2726, wherein at least the one heat source comprises a heater element positioned within the production well.
2730. The method of claim 2726, wherein at least the one second heat source comprises an electrical heater.
2731. The method of claim 2726, wherein at least the one second heat source comprises a surface burner.
2732. The method of claim 2726, wherein at least the one second heat source comprises a flameless distributed combustor.
2733. The method of claim 2726, wherein at least the one second heat source comprises a natural distributed combustor.
2734. The method of claim 2726, further comprising controlling a pressure and a temperature within at least a majority of the first or the second section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2735. The method of claim 2726, further comprising controlling the heat such that an average heating rate of the first section is less than about 1 °C per day during pyrolysis.
2736. The method of claim 2726, wherein providing heat to the formation further comprises:
heating a selected volume (V) of the oil shale formation from the one or more first heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C"*p B
wherein Pwr is the heating energy/day, h is an average heating rate of the formation, p B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2737. The method of claim 2726, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2738. The method of claim 2726, wherein providing heat from the one or more first heat sources comprises heating the first section such that a thermal conductivity of at least a portion of the first section is greater than about 0.5 W/(m °C).
2739. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2740. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2741. The method of claim 2726, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2742. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2743. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2744. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2745. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2746. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2747. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises mufti-ring aromatics with more than two rings.
2748. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2749. The method of claim 2726, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2750. The method of claim 2726, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2751. The method of claim 2726, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2752. The method of claim 2726, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2753. The method of claim 2726, further comprising controlling a pressure within at least a majority of the first or the second section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2754. The method of claim 2726, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2755. The method of claim 2754, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2756. The method of claim 2726, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2757. The method of claim 2726, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2758. The method of claim 2726, further comprising:
providing hydrogen (H2) to the first or second section to hydrogenate hydrocarbons within the first or second section, respectively; and heating a portion of the first or second section, respectively, with heat from hydrogenation.
2759. The method of claim 2726, further comprising:
producing condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2760. The method of claim 2726, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the first or second section to greater than about 100 millidarcy.
2761. The method of claim 2726, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the first or second section.
2762. The method of claim 2726, wherein heating the first or the second section is controlled to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2763. The method of claim 2726, wherein at least about 7 heat sources are disposed in the formation for each production well.
2764. The method of claim 2763, wherein at least about 20 heat sources are disposed in the formation for each production well.
2765. The method of claim 2726, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2766. The method of claim 2726, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2767. A method of treating an oil shale formation in situ, comprising:
providing heat into the formation from a plurality of heat sources placed in a pattern within the formation, wherein a spacing between heat sources is greater than about 6 m;
allowing the heat to transfer from the plurality of heat sources to a selected section of the formation; and producing a mixture from the formation from a plurality of production wells, wherein the plurality of production wells are positioned within the pattern, and wherein a spacing between production wells is greater than about 12 m.
2768. The method of claim 2767, wherein superposition of heat from the plurality of heat sources pyrolyzes at least some hydrocarbons within the selected section of the formation.
2769. The method of claim 2767, further comprising maintaining a temperature within the selected section within a pyrolysis temperature range.
2770. The method of claim 2767, wherein the plurality of heat sources comprises electrical heaters.
2771. The method of claim 2767, wherein the plurality of heat sources comprises surface burners.
2772. The method of claim 2767, wherein the plurality of heat sources comprises flameless distributed combustors.
2773. The method of claim 2767, wherein the plurality of heat sources comprises natural distributed combustors.
2774. The method of claim 2767, further comprising controlling a pressure and a temperature within at least a majority of the selected section of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure.
2775. The method of claim 2767, further comprising controlling the heat such that an average heating rate of the selected section is less than about 1 °C per day during pyrolysis.
2776. The method of claim 2767, wherein providing heat from the plurality of heat sources comprises:
heating a selected volume (V) of the oil shale formation from the plurality of heat sources, wherein the formation has an average heat capacity (C v), and wherein the heating pyrolyzes at least some hydrocarbons within the selected volume of the formation; and wherein heating energy/day provided to the volume is equal to or less than Pwr, wherein Pwr is calculated by the equation:
Pwr = h*V*C v*.rho.B
wherein Pwr is the heating energy/day, ~is an average heating rate of the formation, .rho.B is formation bulk density, and wherein the heating rate is less than about 10 °C/day.
2777. The method of claim 2767, wherein allowing the heat to transfer comprises transferring heat substantially by conduction.
2778. The method of claim 2767, wherein providing heat comprises heating the selected formation such that a thermal conductivity of at least a portion of the selected section is greater than about 0.5 W/(m °C).
2779. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°.
2780. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1 % by weight to about 15 % by weight of the condensable hydrocarbons are olefins.
2781. The method of claim 2767, wherein the produced mixture comprises non-condensable hydrocarbons, and wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons ranges from about 0.001 to about 0.15.
2782. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen.
2783. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen.
2784. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1 % by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur.
2785. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols.
2786. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20 % by weight of the condensable hydrocarbons are aromatic compounds.
2787. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5 % by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings.
2788. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3 % by weight of the condensable hydrocarbons are asphaltenes.
2789. The method of claim 2767, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5 % by weight to about 30 % by weight of the condensable hydrocarbons are cycloalkanes.
2790. The method of claim 2767, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises hydrogen, wherein the hydrogen is greater than about 10 % by volume of the non-condensable component, and wherein the hydrogen is less than about 80 % by volume of the non-condensable component.
2791. The method of claim 2767, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05 % by weight of the produced mixture is ammonia.
2792. The method of claim 2767, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer.
2793. The method of claim 2767, further comprising controlling a pressure within at least a majority of the selected section of the formation, wherein the controlled pressure is at least about 2.0 bars absolute.
2794. The method of claim 2767, further comprising controlling formation conditions to produce the mixture, wherein a partial pressure of H2 within the mixture is greater than about 0.5 bars.
2795. The method of claim 2794, wherein the partial pressure of H2 within the mixture is measured when the mixture is at a production well.
2796. The method of claim 2767, further comprising altering a pressure within the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25.
2797. The method of claim 2767, further comprising controlling formation conditions by recirculating a portion of hydrogen from the mixture into the formation.
2798. The method of claim 2767, further comprising:
providing hydrogen (H2) to the selected section to hydrogenate hydrocarbons within the selected section;
and heating a portion of the selected section with heat from hydrogenation.
2799. The method of claim 2767, further comprising:
producing hydrogen and condensable hydrocarbons from the formation; and hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen.
2800. The method of claim 2767, wherein allowing the heat to transfer comprises increasing a permeability of a majority of the selected section to greater than about 100 millidarcy.
2801. The method of claim 2767, wherein allowing the heat to transfer comprises substantially uniformly increasing a permeability of a majority of the selected section.
2802. The method of claim 2767, further comprising controlling the heat to yield greater than about 60 % by weight of condensable hydrocarbons, as measured by Fischer Assay.
2803. The method of claim 2767, wherein at least about 7 heat sources are disposed in the formation for each production well.
2804. The method of claim 2803, wherein at least about 20 heat sources are disposed in the formation for each production well.
2805. The method of claim 2767, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, and wherein the unit of heat sources comprises a triangular pattern.
2806. The method of claim 2767, further comprising providing heat from three or more heat sources to at least a portion of the formation, wherein three or more of the heat sources are located in the formation in a unit of heat sources, wherein the unit of heat sources comprises a triangular pattern, and wherein a plurality of the units are repeated over an area of the formation to form a repetitive pattern of units.
2807. A system configured to heat an oil shale formation, comprising:
a heater disposed in an opening in the formation, wherein the heater is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2808. The system of claim 2807, wherein the oxidizing fluid is configured to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
2809. The system of claim 2807, wherein the conduit comprises orifices, and wherein the orifices are configured to provide the oxidizing fluid into the opening.
2810. The system of claim 2807, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configured to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
2811. The system of claim 2807, wherein the conduit is further configured to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
2812. The system of claim 2807, wherein the conduit is further configured to remove an oxidation product.
2813. The system of claim 2807, wherein the conduit is further configured to remove an oxidation product such that the oxidation product transfers substantial heat to the oxidizing fluid.
2814. The system of claim 2807, wherein the conduit is further configured to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2815. The system of claim 2807, wherein the conduit is further configured to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
2816. The system of claim 2807, wherein the conduit is further configured to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2817. The system of claim 2807, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2818. The system of claim 2807, further comprising a center conduit disposed within the conduit, wherein the center conduit is configured to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configured to remove an oxidation product during use.
2819. The system of claim 2807, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2820. The system of claim 2807, further comprising a conductor disposed in a second conduit, wherein the second conduit is disposed within the opening, and wherein the conductor is configured to heat at least a portion of the formation during application of an electrical current to the conductor.
2821. The system of claim 2807, further comprising an insulated conductor disposed within the opening, wherein the insulated conductor is configured to heat at least a portion of the formation during application of an electrical current to the insulated conductor.
2822. The system of claim 2807, further comprising at least one elongated member disposed within the opening, wherein the at least the one elongated member is configured to heat at least a portion of the formation during application of an electrical current to the at least the one elongated member.
2823. The system of claim 2807, further comprising a heat exchanger disposed external to the formation, wherein the heat exchanger is configured to heat the oxidizing fluid, wherein the conduit is further configured to provide the heated oxidizing fluid into the opening during use, and wherein the heated oxidizing fluid is configured to heat at least a portion of the formation during use.
2824. The system of claim 2807, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2825. The system of claim 2807, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2826. The system of claim 2807, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2827. The system of claim 2807, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2828. The system of claim 2807, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configured to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
2829. The system of claim 2807, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
2830. The system of claim 2807, wherein the system is further configured such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
2831. A system configurable to heat an oil shale formation, comprising:
a heater configurable to be disposed in an opening in the formation, wherein the heater is further configurable to provide heat to at least a portion of the formation during use;
a conduit configurable to be disposed in the opening, wherein the conduit is configurable to provide an oxidizing fluid from an oxidizing fluid source to a reaction zone in the formation during use, and wherein the system is configurable to allow the oxidizing fluid to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone; and wherein the system is further configurable to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2832. The system of claim 2831, wherein the oxidizing fluid is configurable to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
2833. The system of claim 2831, wherein the conduit comprises orifices, and wherein the orifices are configurable to provide the oxidizing fluid into the opening.
2834. The system of claim 2831, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configurable to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
2835. The system of claim 2831, wherein the conduit is further configurable to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
2836. The system of claim 2831, wherein the conduit is further configurable to remove an oxidation product.
2837. The system of claim 2831, wherein the conduit is further configurable to remove an oxidation product, such that the oxidation product transfers heat to the oxidizing fluid.
2838. The system of claim 2831, wherein the conduit is further configurable to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2839. The system of claim 2831, wherein the conduit is further configurable to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
2840. The system of claim 2831, wherein the conduit is further configurable to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2841. The system of claim 2831, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2842. The system of claim 2831, further comprising a center conduit disposed within the conduit, wherein the center conduit is configurable to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configurable to remove an oxidation product during use.
2843. The system of claim 2831, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2844. The system of claim 2831, further comprising a conductor disposed in a second conduit, wherein the second conduit is disposed within the opening, and wherein the conductor is configurable to heat at least a portion of the formation during application of an electrical current to the conductor.
2845. The system of claim 2831, further comprising an insulated conductor disposed within the opening, wherein the insulated conductor is configurable to heat at least a portion of the formation during application of an electrical current to the insulated conductor.
2846. The system of claim 2831, further comprising at least one elongated member disposed within the opening, wherein the at least the one elongated member is configurable to heat at least a portion of the formation during application of an electrical current to the at least the one elongated member.
2847. The system of claim 2831, further comprising a heat exchanger disposed external to the formation, wherein the heat exchanger is configurable to heat the oxidizing fluid, wherein the conduit is further configurable to provide the heated oxidizing fluid into the opening during use, and wherein the heated oxidizing fluid is configurable to heat at least a portion of the formation during use.
2848. The system of claim 2831, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2849. The system of claim 2831, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2850. The system of claim 2831, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2851. The system of claim 2831, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2852. The system of claim 2831, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configurable to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
2853. The system of claim 2831, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
2854. The system of claim 2831, wherein the system is further configurable such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
2855. The system of claim 2831, wherein the system is configured to heat an oil shale formation, and wherein the system comprises:
a heater disposed in an opening in the formation, wherein the heater is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2856. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing fluid to react with at least a portion of the hydrocarbons at the reaction zone to generate heat at the reaction zone; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
2857. The method of claim 2856, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
2858. The method of claim 2856, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a conduit disposed in the opening.
2859. The method of claim 2856, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a conduit disposed in the opening such that a rate of oxidation is controlled.
2860. The method of claim 2856, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially constant over time within the reaction zone.
2861. The method of claim 2856, wherein a conduit is disposed in the opening, the method further comprising cooling the conduit with the oxidizing fluid to reduce heating of the conduit by oxidation.
2862. The method of claim 2856, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit.
2863. The method of claim 2856, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and transferring heat from the oxidation product in the conduit to oxidizing fluid in the conduit.
2864. The method of claim 2856, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2865. The method of claim 2856, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
2866. The method of claim 2856, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
2867. The method of claim 2856, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
2868. The method of claim 2856, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the outer conduit.
2869. The method of claim 2856, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2870. The method of claim 2856, wherein heating the portion comprises applying electrical current to a conductor disposed in a conduit, wherein the conduit is disposed within the opening.
2871. The method of claim 2856, wherein heating the portion comprises applying electrical current to an insulated conductor disposed within the opening.
2872. The method of claim 2856, wherein heating the portion comprises applying electrical current to at least one elongated member disposed within the opening.
2873. The method of claim 2856, wherein heating the portion comprises heating the oxidizing fluid in a heat exchanger disposed external to the formation such that providing the oxidizing fluid into the opening comprises transferring heat from the heated oxidizing fluid to the portion.
2874. The method of claim 2856, further comprising removing water from the formation prior to heating the portion.
2875. The method of claim 2856, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
2876. The method of claim 2856, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2877. The method of claim 2856, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2878. The method of claim 2856, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2879. The method of claim 2856, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2880. The method of claim 2856, wherein the pyrolysis zone is substantially adjacent to the reaction zone.
2881. A system configured to heat an oil shale formation, comprising:
a heater disposed in an opening in the formation, wherein the heater is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone, and wherein the conduit is further configured to remove an oxidation product from the formation during use; and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2882. The system of claim 2881, wherein the oxidizing fluid is configured to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
2883. The system of claim 2881, wherein the conduit comprises orifices, and wherein the orifices are configured to provide the oxidizing fluid into the opening.
2884. The system of claim 2881, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configured to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
2885. The system of claim 2881, wherein the conduit is further configured to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
2886. The system of claim 2881, wherein the conduit is further configured such that the oxidation product transfers heat to the oxidizing fluid.
2887. The system of claim 2881, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2888. The system of claim 2881, wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
2889. The system of claim 2881, wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2890. The system of claim 2881, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2891. The system of claim 2881, further comprising a center conduit disposed within the conduit, wherein the center conduit is configured to provide the oxidizing fluid into the opening during use.
2892. The system of claim 2881, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2893. The system of claim 2881, further comprising a conductor disposed in a second conduit, wherein the second conduit is disposed within the opening, and wherein the conductor is configured to heat at least a portion of the formation during application of an electrical current to the conductor.
2894. The system of claim 2881, further comprising an insulated conductor disposed within the opening, wherein the insulated conductor is configured to heat at least a portion of the formation during application of an electrical current to the insulated conductor.
2895. The system of claim 2881, further comprising at least one elongated member disposed within the opening, wherein the at least the one elongated member is configured to heat at least a portion of the formation during application of an electrical current to the at least the one elongated member.
2896. The system of claim 2881, further comprising a heat exchanger disposed external to the formation, wherein the heat exchanger is configured to heat the oxidizing fluid, wherein the conduit is further configured to provide the heated oxidizing fluid into the opening during use, and wherein the heated oxidizing fluid is configured to heat at least a portion of the formation during use.
2897. The system of claim 2881, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2898. The system of claim 2881, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2899. The system of claim 2881, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2900. The system of claim 2881, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2901. The system of claim 2881, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configured to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
2902. The system of claim 2881, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
2903. The system of claim 2881, wherein the system is further configured such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
2904. A system configurable to heat an oil shale formation, comprising:
a heater configurable to be disposed in an opening in the formation, wherein the heater is further configurable to provide heat to at least a portion of the formation during use;
a conduit configurable to be disposed in the opening, wherein the conduit is further configurable to provide an oxidizing fluid from an oxidizing fluid source to a reaction zone in the formation during use, wherein the system is configurable to allow the oxidizing fluid to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone, and wherein the conduit is further configurable to remove an oxidation product from the formation during use; and wherein the system is further configurable to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone during use.
2905. The system of claim 2904, wherein the oxidizing fluid is configurable to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
2906. The system of claim 2904, wherein the conduit comprises orifices, and wherein the orifices are configurable to provide the oxidizing fluid into the opening.
2907. The system of claim 2904, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configurable to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
2908. The system of claim 2904, wherein the conduit is further configurable to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
2909. The system of claim 2904, wherein the conduit is further configurable such that the oxidation product transfers heat to the oxidizing fluid.
2910. The system of claim 2904, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2911. The system of claim 2904, wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
2912. The system of claim 2904, wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2913. The system of claim 2904, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2914. The system of claim 2904, further comprising a center conduit disposed within the conduit, wherein the center conduit is configurable to provide the oxidizing fluid into the opening during use.
2915. The system of claim 2904, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2916. The system of claim 2904, further comprising a conductor disposed in a second conduit, wherein the second conduit is disposed within the opening, and wherein the conductor is configurable to heat at least a portion of the formation during application of an electrical current to the conductor.
2917. The system of claim 2904, further comprising an insulated conductor disposed within the opening, wherein the insulated conductor is configurable to heat at least a portion of the formation during application of an electrical current to the insulated conductor.
2918. The system of claim 2904, further comprising at least one elongated member disposed within the opening, wherein the at least the one elongated member is configurable to heat at least a portion of the formation during application of an electrical current to the at least the one elongated member.
2919. The system of claim 2904, further comprising a heat exchanger disposed external to the formation, wherein the heat exchanger is configurable to heat the oxidizing fluid, wherein the conduit is further configurable to provide the heated oxidizing fluid into the opening during use, and wherein the heated oxidizing fluid is configurable to heat at least a portion of the formation during use.
2920. The system of claim 2904, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2921. The system of claim 2904, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2922. The system of claim 2904, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2923. The system of claim 2904, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2924. The system of claim 2904, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configurable to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
2925. The system of claim 2904, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
2926. The system of claim 2904, wherein the system is further configurable such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
2927. The system of claim 2904, wherein the system is configured to heat an oil shale formation, and wherein the system comprises:
a heater disposed in an opening in the formation, wherein the heater is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone, and wherein the conduit is further configured to remove an oxidation product from the formation during use; and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2928. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein the portion is located substantially adjacent to an opening in the formation;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing gas to react with at least a portion of the hydrocarbons at the reaction zone to generate heat in the reaction zone;
removing at least a portion of an oxidation product through the opening; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
2929. The method of claim 2928, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
2930. The method of claim 2928, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a conduit disposed in the opening.
2931. The method of claim 2928, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a conduit disposed in the opening such that a rate of oxidation is controlled.
2932. The method of claim 2928, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially maintained within the reaction zone.
2933. The method of claim 2928, wherein a conduit is disposed in the opening, the method further comprising cooling the conduit with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
2934. The method of claim 2928, wherein a conduit is disposed within the opening, and wherein removing at least the portion of the oxidation product through the opening comprises removing at least the portion of the oxidation product through the conduit.
2935. The method of claim 2928, wherein a conduit is disposed within the opening, and wherein removing at least the portion of the oxidation product through the opening comprises removing at least the portion of the oxidation product through the conduit, the method further comprising transferring substantial heat from the oxidation product in the conduit to the oxidizing fluid in the conduit.
2936. The method of claim 2928, wherein a conduit is disposed within the opening, wherein removing at least the portion of the oxidation product through the opening comprises removing at least the portion of the oxidation product through the conduit, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2937. The method of claim 2928, wherein a conduit is disposed within the opening, and wherein removing at least the portion of the oxidation product through the opening comprises removing at least the portion of the oxidation product through the conduit, the method further comprising controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
2938. The method of claim 2928, wherein a conduit is disposed within the opening, and wherein removing at least the portion of the oxidation product through the opening comprises removing at least the portion of the oxidation product through the conduit, the method further comprising substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
2939. The method of claim 2928, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
2940. The method of claim 2928, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing at least a portion of the oxidation product through the outer conduit.
2941. The method of claim 2928, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2942. The method of claim 2928, wherein heating the portion comprises applying electrical current to a conductor disposed in a conduit, wherein the conduit is disposed within the opening.
2943. The method of claim 2928, wherein heating the portion comprises applying electrical current to an insulated conductor disposed within the opening.
2944. The method of claim 2928, wherein heating the portion comprises applying electrical current to at least one elongated member disposed within the opening.
2945. The method of claim 2928, wherein heating the portion comprises heating the oxidizing fluid in a heat exchanger disposed external to the formation such that providing the oxidizing fluid into the opening comprises transferring heat from the heated oxidizing fluid to the portion.
2946. The method of claim 2928, further comprising removing water from the formation prior to heating the portion.
2947. The method of claim 2928, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
2948. The method of claim 2928, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2949. The method of claim 2928, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2950. The method of claim 2928, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2951. The method of claim 2928, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2952. The method of claim 2928, wherein the pyrolysis zone is substantially adjacent to the reaction.
2953. A system configured to heat an oil shale formation, comprising:
an electric heater disposed in an opening in the formation, wherein the electric heater is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2954. The system of claim 2953, wherein the oxidizing fluid is configured to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
2955. The system of claim 2953, wherein the conduit comprises orifices, and wherein the orifices are configured to provide the oxidizing fluid into the opening.
2956. The system of claim 2953, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configured to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
2957. The system of claim 2953, wherein the conduit is further configured to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
2958. The system of claim 2953, wherein the conduit is further configured to remove an oxidation product.
2959. The system of claim 2953, wherein the conduit is further configured to remove an oxidation product, such that the oxidation product transfers heat to the oxidizing fluid.
2960. The system of claim 2953, wherein the conduit is further configured to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2961. The system of claim 2953, wherein the conduit is further configured to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
2962. The system of claim 2953, wherein the conduit is further configured to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2963. The system of claim 2953, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2964. The system of claim 2953, further comprising a center conduit disposed within the conduit, wherein the center conduit is configured to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configured to remove an oxidation product during use.
2965. The system of claim 2953, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2966. The system of claim 2953, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2967. The system of claim 2953, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2968. The system of claim 2953, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2969. The system of claim 2953, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2970. The system of claim 2953, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configured to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
2971. The system of claim 2953, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
2972. The system of claim 2953, wherein the system is further configured such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
2973. A system configurable to heat an oil shale formation, comprising:
an electric heater configurable to be disposed in an opening in the formation, wherein the electric heater is further configurable to provide heat to at least a portion of the formation during use, and wherein at least the portion is located substantially adjacent to the opening;
a conduit configurable to be disposed in the opening, wherein the conduit is further configurable to provide an oxidizing fluid from an oxidizing fluid source to a reaction zone in the formation during use, and wherein the system is configurable to allow the oxidizing fluid to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone; and wherein the system is further configurable to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2974. The system of claim 2973, wherein the oxidizing fluid is configurable to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
2975. The system of claim 2973, wherein the conduit comprises orifices, and wherein the orifices are configurable to provide the oxidizing fluid into the opening.
2976. The system of claim 2973, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configurable to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
2977. The system of claim 2973, wherein the conduit is further configurable to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
2978. The system of claim 2973, wherein the conduit is further configurable to remove an oxidation product.
2979. The system of claim 2973, wherein the conduit is further configurable to remove an oxidation product such that the oxidation product transfers heat to the oxidizing fluid.
2980. The system of claim 2973, wherein the conduit is further configurable to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
2981. The system of claim 2973, wherein the conduit is further configurable to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
2982. The system of claim 2973, wherein the conduit is further configurable to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2983. The system of claim 2973, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
2984. The system of claim 2973, further comprising a center conduit disposed within the conduit, wherein the center conduit is configurable to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configurable to remove an oxidation product during use.
2985. The system of claim 2973, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
2986. The system of claim 2973, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
2987. The system of claim 2973, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
2988. The system of claim 2973, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
2989. The system of claim 2973, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
2990. The system of claim 2973, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configurable to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
2991. The system of claim 2973, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
2992. The system of claim 2973, wherein the system is further configurable such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
2993. The system of claim 2973, wherein the system is configured to heat an oil shale formation, and wherein the system comprises:
an electric heater disposed in an opening in the formation, wherein the electric heater is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2994. A system configured to heat an oil shale formation, comprising:
a conductor disposed in a first conduit, wherein the first conduit is disposed in an opening in the formation, and wherein the conductor is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a second conduit disposed in the opening, wherein the second conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone; and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
2995. The system of claim 2994, wherein the oxidizing fluid is configured to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
2996. The system of claim 2994, wherein the second conduit comprises orifices, and wherein the orifices are configured to provide the oxidizing fluid into the opening.
2997. The system of claim 2994, wherein the second conduit comprises critical flow orifices, and wherein the critical flow orifices are configured to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
2998. The system of claim 2994, wherein the second conduit is further configured to be cooled with the oxidizing fluid to reduce heating of the second conduit by oxidation.
2999. The system of claim 2994, wherein the second conduit is further configured to remove an oxidation product.
3000. The system of claim 2994, wherein the second conduit is further configured to remove an oxidation product such that the oxidation product transfers heat to the oxidizing fluid.
3001. The system of claim 2994, wherein the second conduit is further configured to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the second conduit.
3002. The system of claim 2994, wherein the second conduit is further configured to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the second conduit and a pressure of the oxidation product in the second conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3003. The system of claim 2994, wherein the second conduit is further configured to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3004. The system of claim 2994, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3005. The system of claim 2994, further comprising a center conduit disposed within the second conduit, wherein the center conduit is configured to provide the oxidizing fluid into the opening during use, and wherein the second conduit is further configured to remove an oxidation product during use.
3006. The system of claim 2994, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3007. The system of claim 2994, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3008. The system of claim 2994, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3009. The system of claim 2994, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3010. The system of claim 2994, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3011. The system of claim 2994, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configured to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3012. The system of claim 2994, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3013. The system of claim 2994, wherein the system is further configured such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
3014. A system configurable to heat an oil shale formation, comprising:
a conductor configurable to be disposed in a first conduit, wherein the first conduit is configurable to be disposed in an opening in the formation, and wherein the conductor is further configurable to provide heat to at least a portion of the formation during use;
a second conduit configurable to be disposed in the opening, wherein the second conduit is further configurable to provide an oxidizing fluid from an oxidizing fluid source to a reaction zone in the formation during use, and wherein the system is configurable to allow the oxidizing fluid to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone; and wherein the system is further configurable to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3015. The system of claim 3014, wherein the oxidizing fluid is configurable to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
3016. The system of claim 3014, wherein the second conduit comprises orifices, and wherein the orifices are configurable to provide the oxidizing fluid into the opening.
3017. The system of claim 3014, wherein the second conduit comprises critical flow orifices, and wherein the critical flow orifices are configurable to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
3018. The system of claim 3014, wherein the second conduit is further configurable to be cooled with the oxidizing fluid to reduce heating of the second conduit by oxidation.
3019. The system of claim 3014, wherein the second conduit is further configurable to remove an oxidation product.
3020. The system of claim 3014, wherein the second conduit is further configurable to remove an oxidation product such that the oxidation product transfers heat to the oxidizing fluid.
3021. The system of claim 3014, wherein the second conduit is further configurable to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the second conduit.
3022. The system of claim 3014, wherein the second conduit is further configurable to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the second conduit and a pressure of the oxidation product in the second conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3023. The system of claim 3014, wherein the second conduit is further configurable to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3024. The system of claim 3014, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3025. The system of claim 3014, further comprising a center conduit disposed within the second conduit, wherein the center conduit is configurable to provide the oxidizing fluid into the opening during use, and wherein the second conduit is further configurable to remove an oxidation product during use.
3026. The system of claim 3014, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3027. The system of claim 3014, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3028. The system of claim 3014, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3029. The system of claim 3014, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3030. The system of claim 3014, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3031. The system of claim 3014, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configurable to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3032. The system of claim 3014, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3033. The system of claim 3014, wherein the system is further configurable such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
3034. The system of claim 3014, wherein the system is configured to heat an oil shale formation, and wherein the system comprises:
a conductor disposed in a first conduit, wherein the first conduit is disposed in an opening in the formation, and wherein the conductor is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a second conduit disposed in the opening, wherein the second conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone; and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3035. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein heating comprises applying an electrical current to a conductor disposed in a first conduit to provide heat to the portion, and wherein the first conduit is disposed within the opening;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing fluid to react with at least a portion of the hydrocarbons at the reaction zone to generate heat at the reaction zone; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
3036. The method of claim 3035, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
3037. The method of claim 3035, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a second conduit disposed in the opening.
3038. The method of claim 3035, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a second conduit disposed in the opening such that a rate of oxidation is controlled.
3039. The method of claim 3035, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially constant over time within the reaction zone.
3040. The method of claim 3035, wherein a second conduit is disposed in the opening, the method further comprising cooling the second conduit with the oxidizing fluid to reduce heating of the second conduit by oxidation.
3041. The method of claim 3035, wherein a second conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the second conduit.
3042. The method of claim 3035, wherein a second conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the second conduit and transferring heat from the oxidation product in the conduit to the oxidizing fluid in the second conduit.
3043. The method of claim 3035, wherein a second conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the second conduit, wherein a flow rate of the oxidizing fluid in the second conduit is approximately equal to a flow rate of the oxidation product in the second conduit.
3044. The method of claim 3035, wherein a second conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the second conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the second conduit to reduce contamination of the oxidation product by the oxidizing fluid.
3045. The method of claim 3035, wherein a second conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
3046. The method of claim 3035, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
3047. The method of claim 3035, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the outer conduit.
3048. The method of claim 3035, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3049. The method of claim 3035, further comprising removing water from the formation prior to heating the portion.
3050. The method of claim 3035, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
3051. The method of claim 3035, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3052. The method of claim 3035, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3053. The method of claim 3035, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3054. The method of claim 3035, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3055. A system configured to heat an oil shale formation, comprising:
an insulated conductor disposed in an opening in the formation, wherein the insulated conductor is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3056. The system of claim 3055, wherein the oxidizing fluid is configured to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
3057. The system of claim 3055, wherein the conduit comprises orifices, and wherein the orifices are configured to provide the oxidizing fluid into the opening.
3058. The system of claim 3055, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configured to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
3059. The system of claim 3055, wherein the conduit is configured to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
3060. The system of claim 3055, wherein the conduit is further configured to remove an oxidation product.
3061. The system of claim 3055, wherein the conduit is further configured to remove an oxidation product, and wherein the conduit is further configured such that the oxidation product transfers substantial heat to the oxidizing fluid.
3062. The system of claim 3055, wherein the conduit is further configured to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3063. The system of claim 3055, wherein the conduit is further configured to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the second conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3064. The system of claim 3055, wherein the conduit is further configured to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3065. The system of claim 3055, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3066. The system of claim 3055, further comprising a center conduit disposed within the conduit, wherein the center conduit is configured to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configured to remove an oxidation product during use.
3067. The system of claim 3055, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3068. The system of claim 3055, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3069. The system of claim 3055, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3070. The system of claim 3055, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3071. The system of claim 3055, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3072. The system of claim 3055, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configured to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3073. The system of claim 3055, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3074. The system of claim 3055, wherein the system is further configured such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
3075. A system configurable to heat an oil shale formation, comprising:
an insulated conductor configurable to be disposed in an opening in the formation, wherein the insulated conductor is further configurable to provide heat to at least a portion of the formation during use;
a conduit configurable to be disposed in the opening, wherein the conduit is further configurable to provide an oxidizing fluid from an oxidizing fluid source to a reaction zone in the formation during use, and wherein the system is configurable to allow the oxidizing fluid to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone; and wherein the system is further configurable to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3076. The system of claim 3075, wherein the oxidizing fluid is configurable to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
3077. The system of claim 3075, wherein the conduit comprises orifices, and wherein the orifices are configurable to provide the oxidizing fluid into the opening.
3078. The system of claim 3075, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configurable to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
3079. The system of claim 3075, wherein the conduit is further configurable to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
3080. The system of claim 3075, wherein the conduit is further configurable to remove an oxidation product.
3081. The system of claim 3075, wherein the conduit is further configurable to remove an oxidation product, such that the oxidation product transfers heat to the oxidizing fluid.
3082. The system of claim 3075, wherein the conduit is further configurable to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3083. The system of claim 3075, wherein the conduit is further configurable to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3084. The system of claim 3075, wherein the conduit is further configurable to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3085. The system of claim 3075, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3086. The system of claim 3075, further comprising a center conduit disposed within the conduit, wherein the center conduit is configurable to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configurable to remove an oxidation product during use.
3087. The system of claim 3075, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3088. The system of claim 3075, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3089. The system of claim 3075, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3090. The system of claim 3075, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3091. The system of claim 3075, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3092. The system of claim 3075, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configurable to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3093. The system of claim 3075, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3094. The system of claim 3075, wherein the system is further configurable such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
3095. The system of claim 3075, wherein the system is configured to heat an oil shale formation, and wherein the system comprises:
an insulated conductor disposed in an opening in the formation, wherein the insulated conductor is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3096. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein heating comprises applying an electrical current to an insulated conductor to provide heat to the portion, and wherein the insulated conductor is disposed within the opening;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing fluid to react with at least a portion of the hydrocarbons at the reaction zone to generate heat at the reaction zone; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
3097. The method of claim 3096, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
3098. The method of claim 3096, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a conduit disposed in the opening.
3099. The method of claim 3096, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a conduit disposed in the opening such that a rate of oxidation is controlled.
3100. The method of claim 3096, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially constant over time within the reaction zone.
3101. The method of claim 3096, wherein a conduit is disposed in the opening, the method further comprising cooling the conduit with the oxidizing fluid to reduce heating of the conduit by oxidation.
3102. The method of claim 3096, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from he formation through the conduit.
3103. The method of claim 3096, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and transferring heat from the oxidation product in the conduit to the oxidizing fluid in the conduit.
3104. The method of claim 3096, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3105. The method of claim 3096, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
3106. The method of claim 3096, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
3107. The method of claim 3096, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
3108. The method of claim 3096, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the outer conduit.
3109. The method of claim 3096, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3110. The method of claim 3096, further comprising removing water from the formation prior to heating the portion.
3111. The method of claim 3096, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
3112. The method of claim 3096, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3113. The method of claim 3096, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3114. The method of claim 3096, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3115. The method of claim 3096, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3116. The method of claim 3096, wherein the pyrolysis zone is substantially adjacent to the reaction zone.
3117. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein the portion is located substantially adjacent to an opening in the formation, wherein heating comprises applying an electrical current to an insulated conductor to provide heat to the portion, wherein the insulated conductor is coupled to a conduit, wherein the conduit comprises critical flow orifices, and wherein the conduit is disposed within the opening;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing fluid to react with at least a portion of the hydrocarbons at the reaction zone to generate heat at the reaction zone; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
3118. The method of clean 3117, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
3119. The method of claim 3117, further comprising controlling a flow of the oxidizing fluid with the critical flow orifices such that a rate of oxidation is controlled.
3120. The method of claim 3117, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially constant over time within the reaction zone.
3121. The method of claim 3117, further comprising cooling the conduit with the oxidizing fluid to reduce heating of the conduit by oxidation.
3122. The method of claim 3117, further comprising removing an oxidation product from the formation through the conduit.
3123. The method of claim 3117, further comprising removing an oxidation product from the formation through the conduit and transferring heat from the oxidation product in the conduit to the oxidizing fluid in the conduit.
3124. The method of claim 3117, further comprising removing an oxidation product from the formation through the conduit, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3125. The method of claim 3117, further comprising removing an oxidation product from the formation through the conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
3126. The method of claim 3117, further comprising removing an oxidation product from the formation through the conduit and substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
3127. The method of claim 3117, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
3128. The method of claim 3117, wherein a center conduit is disposed within the conduit, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the conduit.
3129. The method of claim 3117, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3130. The method of claim 3117, further comprising removing water from the formation prior to heating the portion.
3131. The method of claim 3117, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
3132. The method of claim 3117, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3133. The method of claim 3117, farther comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3134. The method of claim 3117, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3135. The method of claim 3117, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3136. The method of claim 3117, wherein the pyrolysis zone is substantially adjacent to the reaction zone.
3137. A system configured to heat an oil shale formation, comprising:
at least one elongated member disposed in an opening in the formation, wherein at least the one elongated member is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3138. The system of claim 3137, wherein the oxidizing fluid is configured to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
3139. The system of claim 3137, wherein the conduit comprises orifices, and wherein the orifices are configured to provide the oxidizing fluid into the opening.
3140. The system of claim 3137, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configured to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
3141. The system of claim 3137, wherein the conduit is further configured to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
3142. The system of claim 3137, wherein the conduit is further configured to remove an oxidation product.
3143. The system of claim 3137, wherein the conduit is further configured to remove an oxidation product such that the oxidation product transfers heat to the oxidizing fluid.
3144. The system of claim 3137, wherein the conduit is further configured to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3145. The system of claim 3137, wherein the conduit is further configured to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3146. The system of claim 3137, wherein the conduit is further configured to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3147. The system of claim 3137, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3148. The system of claim 3137, further comprising a center conduit disposed within the conduit, wherein the center conduit is configured to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configured to remove an oxidation product during use.
3149. The system of claim 3137, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3150. The system of claim 3137, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3151. The system of claim 3137, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3152. The system of claim 3137, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3153. The system of claim 3137, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3154. The system of claim 3137, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configured to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3155. The system of claim 3137, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3156. The system of claim 3137, wherein the system is further configured such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
3157. A system configurable to heat an oil shale formation, comprising:
at least one elongated member configurable to be disposed in an opening in the formation, wherein at least the one elongated member is further configurable to provide heat to at least a portion of the formation during use;
a conduit configurable to be disposed in the opening, wherein the conduit is further configurable to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the system is configurable to allow the oxidizing fluid to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone; and wherein the system is further configurable to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3158. The system of claim 3157, wherein the oxidizing fluid is configurable to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
3159. The system of claim 3157, wherein the conduit comprises orifices, and wherein the orifices are configurable to provide the oxidizing fluid into the opening.
3160. The system of claim 3157, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configurable to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
3161. The system of claim 3157, wherein the conduit is further configurable to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
3162. The system of claim 3157, wherein the conduit is further configurable to remove an oxidation product.
3163. The system of claim 3157, wherein the conduit is further configurable to remove an oxidation product such that the oxidation product transfers heat to the oxidizing fluid.
3164. The system of claim 3157, wherein the conduit is further configurable to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3165. The system of claim 3157, wherein the conduit is further configurable to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3166. The system of claim 3157, wherein the conduit is further configurable to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3167. The system of claim 3157, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3168. The system of claim 3157, further comprising a center conduit disposed within the conduit, wherein the center conduit is configurable to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configurable to remove an oxidation product during use.
3169. The system of claim 3157, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3170. The system of claim 3157, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3171. The system of claim 3157, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3172. The system of claim 3157, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3173. The system of claim 3157, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3174. The system of claim 3157, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configurable to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3175. The system of claim 3157, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3176. The system of claim 3157, wherein the system is further configurable such that transferred heat can pyrolyze at least some hydrocarbons in the pyrolysis zone.
3177. The system of claim 3157, wherein the system is configured to heat an oil shale formation, and wherein the system comprises:
at least one elongated member disposed in an opening in the formation, wherein at least the one elongated member is configured to provide heat to at least a portion of the formation during use;
an oxidizing fluid source;
a conduit disposed in the opening, wherein the conduit is configured to provide an oxidizing fluid from the oxidizing fluid source to a reaction zone in the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at the reaction zone during use such that heat is generated at the reaction zone;
and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3178. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein heating comprises applying an electrical current to at least one elongated member to provide heat to the portion, and wherein at least the one elongated member is disposed within the opening;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing fluid to react with at least a portion of the hydrocarbons at the reaction zone to generate heat at the reaction zone; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
3179. The method of claim 3178, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
3180. The method of claim 3178, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a conduit disposed in the opening.
3181. The method of claim 3178, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a conduit disposed in the opening such that a rate of oxidation is controlled.
3182. The method of claim 3178, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially constant over time within the reaction zone.
3183. The method of claim 3178, wherein a conduit is disposed in the opening, the method further comprising cooling the conduit with the oxidizing fluid to reduce heating of the conduit by oxidation.
3184. The method of claim 3178, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit.
3185. The method of claim 3178, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and transferring heat from the oxidation product in the conduit to the oxidizing fluid in the conduit.
3186. The method of claim 3178, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3187. The method of claim 3178, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
3188. The method of claim 3178, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
3189. The method of claim 3178, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
3190. The method of claim 3178, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the outer conduit.
3191. The method of claim 3178, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3192. The method of claim 3178, further comprising removing water from the formation prior to heating the portion.
3193. The method of claim 3178, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
3194. The method of claim 3178, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3195. The method of claim 3178, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3196. The method of claim 3178, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3197. The method of claim 3178, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3198. The method of claim 3178, wherein the pyrolysis zone is substantially adjacent to the reaction zone.
3199. A system configured to heat an oil shale formation, comprising:
a heat exchanger disposed external to the formation, wherein the heat exchanger is configured to heat an oxidizing fluid during use;
a conduit disposed in the opening, wherein the conduit is configured to provide the heated oxidizing fluid from the heat exchanger to at least a portion of the formation during use, wherein the system is configured to allow heat to transfer from the heated oxidizing fluid to at least the portion of the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at a reaction zone in the formation during use such that heat is generated at the reaction zone; and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3200. The system of claim 3199, wherein the oxidizing fluid is configured to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
3201. The system of claim 3199, wherein the conduit comprises orifices, and wherein the orifices are configured to provide the oxidizing fluid into the opening.
3202. The system of claim 3199, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configured to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
3203. The system of claim 3199, wherein the conduit is further configured to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
3204. The system of claim 3199, wherein the conduit is further configured to remove an oxidation product.
3205. The system of claim 3199, wherein the conduit is further configured to remove an oxidation product, such that the oxidation product transfers heat to the oxidizing fluid.
3206. The system of claim 3199, wherein the conduit is further configured to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3207. The system of claim 3199, wherein the conduit is further configured to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3208. The system of claim 3199, wherein the conduit is further configured to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3209. The system of claim 3199, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3210. The system of claim 3199, further comprising a center conduit disposed within the conduit, wherein the center conduit is configured to provide the oxidizing fluid into the opening during use, and wherein the conduit is further configured to remove an oxidation product during use.
3211. The system of claim 3199, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3212. The system of claim 3199, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3213. The system of claim 3199, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3214. The system of claim 3199, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3215. The system of claim 3199, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3216. The system of claim 3199, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configured to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3217. The system of claim 3199, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3218. A system configurable to heat an oil shale formation, comprising:
a heat exchanger configurable to be disposed external to the formation, wherein the heat exchanger is further configurable to heat an oxidizing fluid during use;
a conduit configurable to be disposed in the opening, wherein the conduit is further configurable to provide the heated oxidizing fluid from the heat exchanger to at least a portion of the formation during use, wherein the system is configurable to allow heat to transfer from the heated oxidizing fluid to at least the portion of the formation during use, and wherein the system is further configurable to allow the oxidizing fluid to oxidize at least some hydrocarbons at a reaction zone in the formation during use such that heat is generated at the reaction zone;
and wherein the system is further configurable to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3219. The system of claim 3218, wherein the oxidizing fluid is configurable to generate heat in the reaction zone such that the oxidizing fluid is transported through the reaction zone substantially by diffusion.
3220. The system of claim 3218, wherein the conduit comprises orifices, and wherein the orifices are configurable to provide the oxidizing fluid into the opening.
3221. The system of claim 3218, wherein the conduit comprises critical flow orifices, and wherein the critical flow orifices are configurable to control a flow of the oxidizing fluid such that a rate of oxidation in the formation is controlled.
3222. The system of claim 3218, wherein the conduit is further configurable to be cooled with the oxidizing fluid such that the conduit is not substantially heated by oxidation.
3223. The system of claim 3218, wherein the conduit is further configurable to remove an oxidation product.
3224. The system of claim 3218, wherein the conduit is further configurable to remove an oxidation product such that the oxidation product transfers heat to the oxidizing fluid.
3225. The system of claim 3218, wherein the conduit is further configurable to remove an oxidation product, and wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3226. The system of claim 3218, wherein the conduit is further configurable to remove an oxidation product, and wherein a pressure of the oxidizing fluid in the conduit and a pressure of the oxidation product in the conduit are controlled to reduce contamination of the oxidation product by the oxidizing fluid.
3227. The system of claim 3218, wherein the conduit is further configurable to remove an oxidation product, and wherein the oxidation product is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3228. The system of claim 3218, wherein the oxidizing fluid is substantially inhibited from flowing into portions of the formation beyond the reaction zone.
3229. The system of claim 3218, further comprising a center conduit disposed within the conduit, wherein the center conduit is configurable to provide the oxidizing fluid into the opening during use, and wherein the second conduit is further configurable to remove an oxidation product during use.
3230. The system of claim 3218, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3231. The system of claim 3218, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3232. The system of claim 3218, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3233. The system of claim 3218, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3234. The system of claim 3218, further comprising an overburden casing coupled to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3235. The system of claim 3218, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material is configurable to substantially inhibit a flow of fluid between the opening and the overburden casing during use.
3236. The system of claim 3218, further comprising an overburden casing coupled to the opening, wherein the overburden casing is disposed in an overburden of the formation, wherein a packing material is disposed at a junction of the overburden casing and the opening, and wherein the packing material comprises cement.
3237. The system of claim 3218, wherein the system is configured to heat an oil shale formation, and wherein the system comprises:
a heat exchanger disposed external to the formation, wherein the heat exchanger is configured to heat an oxidizing fluid during use;
a conduit disposed in the opening, wherein the conduit is configured to provide the heated oxidizing fluid from the heat exchanger to at least a portion of the formation during use, wherein the system is configured to allow heat to transfer from the heated oxidizing fluid to at least the portion of the formation during use, and wherein the oxidizing fluid is selected to oxidize at least some hydrocarbons at a reaction zone in the formation during use such that heat is generated at the reaction zone; and wherein the system is configured to allow heat to transfer substantially by conduction from the reaction zone to a pyrolysis zone of the formation during use.
3238. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein heating comprises:
heating the oxidizing fluid with a heat exchanger, wherein the heat exchanger is disposed external to the formation;
providing the heated oxidizing fluid from the heat exchanger to the portion of the formation;
allowing heat to transfer from the heated oxidizing fluid to the portion of the formation;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing fluid to react with at least a portion of the hydrocarbons at the reaction zone to generate heat at the reaction zone; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
3239. The method of claim 3238, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
3240. The method of claim 3238, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a conduit disposed in the opening.
3241. The method of claim 3238, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a conduit disposed in the opening such that a rate of oxidation is controlled.
3242. The method of claim 3238, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially constant over time within the reaction zone.
3243. The method of claim 3238, wherein a conduit is disposed in the opening, the method further comprising cooling the conduit with the oxidizing fluid to reduce heating of the conduit by oxidation.
3244. The method of claim 3238, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit.
3245. The method of claim 3238, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and transferring heat from the oxidation product in the conduit to the oxidizing fluid in the conduit.
3246. The method of claim 3238, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3247. The method of claim 3238, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
3248. The method of claim 3238, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
3249. The method of claim 3238, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
3250. The method of claim 3238, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the outer conduit.
3251. The method of claim 3238, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3252. The method of claim 3238, further comprising removing water from the formation prior to heating the portion.
3253. The method of claim 3238, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
3254. The method of claim 3238, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3255. The method of claim 3238, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3256. The method of claim 3238, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3257. The method of claim 3238, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3258. The method of claim 3238, wherein the pyrolysis zone is substantially adjacent to the reaction zone.
3259. An in situ method for heating an oil shale formation, comprising:
heating a portion of the formation to a temperature sufficient to support reaction of hydrocarbons within the portion of the formation with an oxidizing fluid, wherein heating comprises:
oxidizing a fuel gas in a heater, wherein the heater is disposed external to the formation;
providing the oxidized fuel gas from the heater to the portion of the formation;
allowing heat to transfer from the oxidized fuel gas to the portion of the formation;
providing the oxidizing fluid to a reaction zone in the formation;
allowing the oxidizing fluid to react with at least a portion of the hydrocarbons at the reaction zone to generate heat at the reaction zone; and transferring the generated heat substantially by conduction from the reaction zone to a pyrolysis zone in the formation.
3260. The method of claim 3259, further comprising transporting the oxidizing fluid through the reaction zone by diffusion.
3261. The method of claim 3259, further comprising directing at least a portion of the oxidizing fluid into the opening through orifices of a conduit disposed in the opening.
3262. The method of claim 3259, further comprising controlling a flow of the oxidizing fluid with critical flow orifices of a conduit disposed in the opening such that a rate of oxidation is controlled.
3263. The method of claim 3259, further comprising increasing a flow of the oxidizing fluid in the opening to accommodate an increase in a volume of the reaction zone such that a rate of oxidation is substantially constant over time within the reaction zone.
3264. The method of claim 3259, wherein a conduit is disposed in the opening, the method further comprising cooling the conduit with the oxidizing fluid to reduce heating of the conduit by oxidation.
3265. The method of claim 3259, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit.
3266. The method of claim 3259, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and transferring heat from the oxidation product in the conduit to the oxidizing fluid in the conduit.
3267. The method of claim 3259, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit, wherein a flow rate of the oxidizing fluid in the conduit is approximately equal to a flow rate of the oxidation product in the conduit.
3268. The method of claim 3259, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and controlling a pressure between the oxidizing fluid and the oxidation product in the conduit to reduce contamination of the oxidation product by the oxidizing fluid.
3269. The method of claim 3259, wherein a conduit is disposed within the opening, the method further comprising removing an oxidation product from the formation through the conduit and substantially inhibiting the oxidation product from flowing into portions of the formation beyond the reaction zone.
3270. The method of claim 3259, further comprising substantially inhibiting the oxidizing fluid from flowing into portions of the formation beyond the reaction zone.
3271. The method of claim 3259, wherein a center conduit is disposed within an outer conduit, and wherein the outer conduit is disposed within the opening, the method further comprising providing the oxidizing fluid into the opening through the center conduit and removing an oxidation product through the outer conduit.
3272. The method of claim 3259, wherein the portion of the formation extends radially from the opening a width of less than approximately 0.2 m.
3273. The method of claim 3259, further comprising removing water from the formation prior to heating the portion.
3274. The method of claim 3259, further comprising controlling the temperature of the formation to substantially inhibit production of oxides of nitrogen during oxidation.
3275. The method of claim 3259, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation.
3276. The method of claim 3259, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
3277. The method of claim 3259, further comprising coupling an overburden casing to the opening, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing is further disposed in cement.
3278. The method of claim 3259, further comprising coupling an overburden casing to the opening, wherein a packing material is disposed at a junction of the overburden casing and the opening.
3279. The method of claim 3259, wherein the pyrolysis zone is substantially adjacent to the reaction zone.
3280. A system configured to heat an oil shale formation, comprising:
an insulated conductor disposed within an open wellbore in the formation, wherein the insulated conductor is configured to provide radiant heat to at least a portion of the formation during use; and wherein the system is configured to allow heat to transfer from the insulated conductor to a selected section of the formation during use.
3281. The system of claim 3280, wherein the insulated conductor is further configured to generate heat during application of an electrical current to the insulated conductor during use.
3282. The system of claim 3280, further comprising a support member, wherein the support member is configured to support the insulated conductor.
3283. The system of claim 3280, further comprising a support member and a centralizes, wherein the support member is configured to support the insulated conductor, and wherein the centralizes is configured to maintain a location of the insulated conductor on the support member.
3284. The system of claim 3280, wherein the open wellbore comprises a diameter of at least approximately 5 cm.
3285. The system of claim 3280, further comprising a lead-in conductor coupled to the insulated conductor, wherein the lead-in conductor comprises a low resistance conductor configured to generate substantially no heat.
3286. The system of claim 3280, further comprising a lead-in conductor coupled to the insulated conductor, wherein the lead-in conductor comprises a rubber insulated conductor.
3287. The system of claim 3280, further comprising a lead-in conductor coupled to the insulated conductor, wherein the lead-in conductor comprises a copper wire.
3288. The system of claim 3280, further comprising a lead-in conductor coupled to the insulated conductor with a cold pin transition conductor.
3289. The system of claim 3280, further comprising a lead-in conductor coupled to the insulated conductor with a cold pin transition conductor, wherein the cold pin transition conductor comprises a substantially low resistance insulated conductor.
3290. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, and wherein the electrically insulating material is disposed in a sheath.
3291. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, and wherein the conductor comprises a copper-nickel alloy.
3292. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, wherein the conductor comprises a copper-nickel alloy, and wherein the copper-nickel alloy comprises approximately 7 % nickel by weight to approximately 12 % nickel by weight.
3293. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, wherein the conductor comprises a copper-nickel alloy, and wherein the copper-nickel alloy comprises approximately 2 % nickel by weight to approximately 6 %
nickel by weight.
3294. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, and wherein the electrically insulating material comprises a thermally conductive material.
3295. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, and wherein the electrically insulating material comprises magnesium oxide.
3296. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, wherein the electrically insulating material comprises magnesium oxide, and wherein the magnesium oxide comprises a thickness of at least approximately 1 mm.
3297. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, and wherein the electrically insulating material comprises aluminum oxide and magnesium oxide.
3298. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, wherein the electrically insulating material comprises magnesium oxide, wherein the magnesium oxide comprises grain particles, and wherein the grain particles are configured to occupy porous spaces within the magnesium oxide.
3299. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, and wherein the electrically insulating material is disposed in a sheath, and wherein the sheath comprises a corrosion-resistant material.
3300. The system of claim 3280, wherein the insulated conductor comprises a conductor disposed in an electrically insulating material, and wherein the electrically insulating material is disposed in a sheath, and wherein the sheath comprises stainless steel.
3301. The system of claim 3280, further comprising two additional insulated conductors, wherein the insulated conductor and the two additional insulated conductors are configured in a 3-phase Y configuration.
3302. The system of claim 3280, further comprising an additional insulated conductor, wherein the insulated conductor and the additional insulated conductor are coupled to a support member, and wherein the insulated conductor and the additional insulated conductor are configured in a series electrical configuration.
3303. The system of claim 3280, further comprising an additional insulated conductor, wherein the insulated conductor and the additional insulated conductor are coupled to a support member, and wherein the insulated conductor and the additional insulated conductor are configured in a parallel electrical configuration.
3304. The system of claim 3280, wherein the insulated conductor is configured to generate radiant heat of approximately 500 W/m to approximately 1150 W/m during use.
3305. The system of claim 3280, further comprising a support member configured to support the insulated conductor, wherein the support member comprises orifices configured to provide fluid flow through the support member into the open wellbore during use.
3306. The system of claim 3280, further comprising a support member configured to support the insulated conductor, wherein the support member comprises critical flow orifices configured to provide a substantially constant amount of fluid flow through the support member into the open wellbore during use.
3307. The system of claim 3280, further comprising a tube coupled to the insulated conductor, wherein the tube is configured to provide a flow of fluid into the open wellbore during use.
3308. The system of claim 3280, further comprising a tube coupled to the insulated conductor, wherein the tube comprises critical flow orifices configured to provide a substantially constant amount of fluid flow through the support member into the open wellbore during use.
3309. The system of claim 3280, further comprising an overburden casing coupled to the open wellbore, wherein the overburden casing is disposed in an overburden of the formation.
3310. The system of claim 3280, further comprising an overburden casing coupled to the open wellbore, wherein the overburden casing is disposed in an overburden of the formation, and wherein the overburden casing comprises steel.
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