CA2549981A1 - Article having patterned decorative coating - Google Patents

Article having patterned decorative coating Download PDF

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Publication number
CA2549981A1
CA2549981A1 CA002549981A CA2549981A CA2549981A1 CA 2549981 A1 CA2549981 A1 CA 2549981A1 CA 002549981 A CA002549981 A CA 002549981A CA 2549981 A CA2549981 A CA 2549981A CA 2549981 A1 CA2549981 A1 CA 2549981A1
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CA
Canada
Prior art keywords
layer
material comprises
article
carbon
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002549981A
Other languages
French (fr)
Other versions
CA2549981C (en
Inventor
Bryce Anton
Richard P. Welty
Patrick Sullivan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vapor Technologies Inc
Original Assignee
Vapor Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vapor Technologies Inc filed Critical Vapor Technologies Inc
Priority to CA2634297A priority Critical patent/CA2634297C/en
Publication of CA2549981A1 publication Critical patent/CA2549981A1/en
Application granted granted Critical
Publication of CA2549981C publication Critical patent/CA2549981C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/0015—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterized by the colour of the layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0641—Nitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/006—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterized by the colour of the layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/26—Deposition of carbon only
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/56—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/32—Processes for applying liquids or other fluent materials using means for protecting parts of a surface not to be coated, e.g. using stencils, resists
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B05D5/067—Metallic effect
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]

Abstract

An article having a decorative, visibly-patterned, multi-colored surface appearance includes a substrate and a first coating provided by vapor deposition above at least a portion of the substrate, the coating comprising a first material having a first color.
The coating comprises a random arrangement of penetrations through which a portion of an underlying surface is visible, the underlying surface comprising a second material having a second color that differs from the first color. The penetrations form a decorative pattern comprising features distinguishable to an unaided human eye.

Claims (58)

1. An article having a decorative, visibly-patterned, multi-colored surface appearance comprising:
a substrate; and a first coating provided by vapor deposition above at least a portion of the substrate, the coating comprising a first material having a first color;
wherein the coating comprises a random arrangement of penetrations through which a portion of an underlying surface is visible, the underlying surface comprising a second material having a second color that differs from the first color;
wherein the penetrations form a decorative pattern comprising features distinguishable to an unaided human eye.
2. The article of Claim 1, wherein the first coating is deposited by a physical vapor deposition process or a chemical vapor deposition process performed within a vacuum chamber at sub-atmospheric pressure.
3. The article of Claim 2, wherein the physical vapor deposition process or chemical vapor deposition process comprises cathodic arc evaporation.
4. The article of Claim 2, wherein the physical vapor deposition process or chemical vapor deposition process comprises a hot-filament PECVD process.
5. The article of any of the preceding Claims, wherein the first material comprises a metal.
6. The article of Claim 5, wherein the first material further comprises at least one material selected from the group consisting of nitrogen, oxygen, and carbon.
7. The article of Claim 6, wherein the first material comprises at least one material selected from the group consisting of zirconium, scandium, titanium, chromium, hafnium, carbon, and an anodized layer comprising a metal.
8. The article of any of the preceding Claims, further comprising a second coating provided intermediate the first coating and the substrate, the second coating comprising the underlying surface.
9. The article of Claim 8, wherein the second material comprises a metal.
10. The article of Claim 9, wherein the second material further comprises at least one material selected from the group consisting of nitrogen, oxygen, and carbon.
11. The article of Claim 10, wherein the second material comprises at least one material selected from the group consisting of zirconium, titanium, chromium, hafnium, and scandium.
12. The article of Claim 11, wherein the first material comprises at least one of zirconium and scandium.
13. The article of Claim 8, wherein the second material comprises zirconium, oxygen, and carbon and the first material comprises zirconium and nitrogen.
14. The article of Claim 8, wherein the second material comprises diamond-like carbon.
15. A method for producing an article having a decorative coating comprising:
depositing at least a first coating layer onto at least a portion of a surface of a substrate using a physical or chemical vapor deposition method in a vacuum chamber at sub-atmospheric pressure, the first coating layer comprising a first material having a first color; and patterning the first coating layer using a non-uniform patterning process to form a patterned coating layer having penetrations through which a portion of an underlying surface is visible, the underlying surface comprising a second material and having a second color that is visually contrasting to the first color;
wherein the patterned first coating layer comprises a decorative pattern comprising features distinguishable by an unaided human eye.
16. The method of Claim 15, wherein at least one of the first material and the second material comprises diamond-like carbon.
17. The method of Claim 15, wherein the first material comprises a metal.
18. The method of Claim 17, wherein the first material further comprises at least one material selected from the group consisting of nitrogen, oxygen, and carbon.
19. The method of Claim 18, wherein the first coating layer is deposited using one of a cathodic arc evaporation process and a hot-filament PECVD
method.
20. The method of Claim 18, wherein the first material comprises at least one element selected from the group consisting of zirconium, scandium, titanium, chromium, hafnium, and carbon.
21. The method of any of Claims 15-20, wherein the first material comprises an anodized layer comprising a metal.
22. The method of any of Claims 15-21, wherein the patterning process comprises an etching process.
23. The method of any of Claims 15-21, wherein the patterning process comprises a lift-off process.
24. The method of any of Claims 15-21, wherein the patterning process comprises a tumbling or vibratory finishing process.
25. The method of any of Claims 15-21, wherein the patterning process comprises forming a non-continuous masking layer, the masking layer having penetrations through which a portion of the first coating layer is exposed.
26. The method of Claim 25, wherein the patterning process comprises removing portions of the first coating layer under the penetrations in the masking layer.
27. The method of Claim 25, wherein the penetrations in the masking layer are formed by means of a wire or fiber brush.
28. The method of Claim 25, wherein the penetrations in the masking layer are formed by a photolithographic process.
29. The method of Claim 25, wherein the penetrations in the masking layer are formed by non-uniform application of a masking material.
30. The method of Claim 29, wherein the masking material is applied non-uniformly by means of a stamp or stencil.
31. The method of Claim 29, wherein the masking material is applied non-uniformly by means of at least one of a silk-screening process and a spraying process.
32. The method of Claim 25, wherein the penetrations in the masking layer are created by means of a mass finishing operation handling at least ten parts simultaneously.
33. The method of Claim 15, further comprising depositing at least a second coating layer onto the substrate prior to the deposition of the first coating layer, the second coating layer comprising the second material.
34. The method of Claim 33, wherein the second material comprises a metal.
35. The method of Claim 34, wherein the second material further comprises at least one member of the group consisting of nitrogen, oxygen, and carbon.
36. The method of Claim 35, wherein the second material comprises at least one member of the group consisting of zirconium, titanium, chromium, hafnium or scandium.
37. The method of Claim 33, wherein the second material comprises zirconium, oxygen, and carbon, and wherein the first material comprises zirconium and nitrogen.
38. The method of Claim 33, wherein the second material comprises carbon.
39. The method of Claim 38, wherein the first material comprises carbon.
40. The method of Claim 33, wherein the second material comprises an anodized layer comprising a metal.
41. A method for producing an article having a decorative surface comprising:
depositing a first layer of material on a substrate using a vapor deposition method, the first layer of material comprising a first material having a first color;
depositing a second layer of material on the first layer of material using a vapor deposition method, the second layer of material comprising a second material having a second color that differs from the first color; and removing portions of the second layer of material to form apertures extending through the second layer, the apertures arranged in a random configuration;
wherein portions of the first layer are visible through the apertures such that a decorative pattern is formed on the article.
42. The method of Claim 41, wherein the step of removing portions of the second layer of material comprises a masking process.
43. The method of Claim 41, wherein the masking process comprises providing a mask above the second layer of material, the mask comprising at least one of an ink, a photoresist, a paint, a lacquer, a wax, and a metal.
44. The method of Claim 41, wherein the step of removing portions of the second layer of material comprises at least one of an etching process, a lift-off process, and a tumbling or vibratory finishing process.
45. The method of Claim 41, wherein the step of removing portions of the second layer of material comprises forming a non-continuous masking layer, the masking layer having penetrations through which a portion of the first coating layer is exposed.
46. The method of Claim 45, wherein the step of removing portions of the second layer of material comprises removing portions of the second layer of material under the penetrations in the masking layer.
47. The method of Claim 45, wherein the penetrations in the masking layer are formed by non-uniform application of a masking material.
48. The method of Claim 45, wherein the penetrations in the masking layer are created by means of a mass finishing operation handling at least ten parts simultaneously.
49. The method of Claim 41, wherein the first material comprises a metal and at least one material selected from the group consisting of nitrogen, oxygen, and carbon.
50. The method of Claim 49, wherein the first material comprises at least one of zirconium, titanium, chromium, hafnium and scandium.
51. The method of Claim 41, wherein the first coating layer is deposited using at least one of a hot-filament PECVD method and a cathodic arc evaporation process.
52. The method of Claim 41, wherein the first material comprises an anodized layer comprising a metal.
53. The method of Claim 41, wherein the second material comprises a metal and at least one member of the group consisting of nitrogen, oxygen, and carbon.
54. The method of Claim 43, wherein the second material comprises zirconium, titanium, chromium, hafnium or scandium.
55. The method of Claim 41, wherein the second material comprises zirconium, oxygen, and carbon, and wherein the first material comprises zirconium and nitrogen.
56. The method of Claim 41, wherein at least one of the first material and the second material comprises diamond-like carbon.
57. The method of Claim 41, wherein the second material comprises carbon.
58. The method of Claim 56, wherein the first material comprises carbon.
CA2549981A 2005-08-01 2006-06-13 Article having patterned decorative coating Expired - Fee Related CA2549981C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA2634297A CA2634297C (en) 2005-08-01 2006-06-13 Article having patterned decorative coating

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/194,222 US20070026205A1 (en) 2005-08-01 2005-08-01 Article having patterned decorative coating
US11/194,222 2005-08-01

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CA2634297A Division CA2634297C (en) 2005-08-01 2006-06-13 Article having patterned decorative coating

Publications (2)

Publication Number Publication Date
CA2549981A1 true CA2549981A1 (en) 2007-02-01
CA2549981C CA2549981C (en) 2012-07-24

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CA2549981A Expired - Fee Related CA2549981C (en) 2005-08-01 2006-06-13 Article having patterned decorative coating

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Country Status (7)

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US (2) US20070026205A1 (en)
EP (1) EP1749898B1 (en)
CN (1) CN1936068B (en)
CA (2) CA2634297C (en)
ES (1) ES2395733T3 (en)
MX (1) MXPA06008122A (en)
PL (1) PL1749898T3 (en)

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EP1749898A3 (en) 2008-06-25
US8123967B2 (en) 2012-02-28
CA2549981C (en) 2012-07-24
CN1936068B (en) 2011-08-17
PL1749898T3 (en) 2013-02-28
CA2634297C (en) 2013-11-19
US20080264903A1 (en) 2008-10-30
EP1749898A2 (en) 2007-02-07
MXPA06008122A (en) 2007-03-23
EP1749898B1 (en) 2012-09-26
US20070026205A1 (en) 2007-02-01
CN1936068A (en) 2007-03-28
CA2634297A1 (en) 2007-02-01
ES2395733T3 (en) 2013-02-14

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