CN100519675C - Water soluble pigment ink-jetting printing ink - Google Patents

Water soluble pigment ink-jetting printing ink Download PDF

Info

Publication number
CN100519675C
CN100519675C CN 200410013291 CN200410013291A CN100519675C CN 100519675 C CN100519675 C CN 100519675C CN 200410013291 CN200410013291 CN 200410013291 CN 200410013291 A CN200410013291 A CN 200410013291A CN 100519675 C CN100519675 C CN 100519675C
Authority
CN
China
Prior art keywords
pigment
ink
water
content
contained
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN 200410013291
Other languages
Chinese (zh)
Other versions
CN1583898A (en
Inventor
游在隆
谢琼琳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xie Qionglin
You Zairong
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN 200410013291 priority Critical patent/CN100519675C/en
Publication of CN1583898A publication Critical patent/CN1583898A/en
Application granted granted Critical
Publication of CN100519675C publication Critical patent/CN100519675C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Abstract

This invention has disclosed a kind of water soluble pigment type to gush out and print blackly Colored ink, it is by the pigment, water soluble organic solvent, deionized water, Antiseptic, hand in and unite the acrylic acid resin, the surface-active agent by oneself, moist Wet pharmaceutical, dispersant, it is worth 10 that pH regulates the pharmaceutical. Group's cost inventing The water soluble pigment type textile printing ink shows the following characteristics 1) 25deg.C viscidity of hour is 6Mpa.S, 2) PH is worth 10.0, Between dyne 45 of surface tension/centimeter. Have bright in luster, And the fabric is dealt with before not needing going on, the aftertreatment is very simple Wait for the advantage, namely only need to bake proper hot 190deg.C to the fabric 5 minutes of 210deg.C cylinder press for one minute, but does not need the uapour to steam, Water-washing can get print stamp the finished product.

Description

Water miscible pigment jetting printing ink
Technical field:
The invention belongs to a kind of ink and preparation method thereof.
Background technology:
Digital ink-jet printed technology is a kind of brand-new textile printing technology, by the computer control sprayed printed system, dedicated dye or pigment is injected directly on the fabrics such as cotton, fiber crops, silk, chemical fibre, thereby print off various patterns and decorative pattern.Compare with traditional stamp, digital jet printing technology has production efficiency height, quality product height, batch process arbitrarily, save energy, five big characteristics such as pollution not substantially.The ink of digital ink-jet printed usefulness is divided into two kinds of dye-type and pigment styles.Type of dye ink is divided into three kinds of dispersed dye, matching stain, reactive dyestuffs etc.Adopt the digital ink-jet printed of type of dye ink, its fabric must carry out pre-process and post-process, and the product of its stamp exists durable water dungeon degree difference and characteristics such as light fastness is very poor, easy contamination.The report of present domestic existing dye-type digit printing ink.The main drawback of dye-type digit printing ink has: 1, do not possess versatility, different fibers need use different dye inks, need use reactive dye ink as cellulosic fibre, protein fibre need use acid dye ink, trevira uses dispersed dye ink or the like, and the replacing ink needs washing nozzle and pipeline, troublesome poeration.2, the poor stability of ink, conditions such as storage temperature cause the dyestuff crystallization to separate out when changing easily, cause nozzle and line clogging, influence printing quality.3, the light fastness of stamp color is poor.4, in order to prevent dye ink migration or imbibition, promote the reflection or the fixation of dyestuff and fiber, before stamp, need fabric to be carried out pre-treatment with migration inhibitor, catalyzer, need behind the stamp fabric is carried out decatize or aftertreatment so that dyestuff anchors on the fiber, also need to wash and the aftertreatment fiber on remaining dyestuff, make the washing shrinkage of fabric reach requirement.Not only complex process is wasted the water source and the energy, and has environmental pollution to a certain degree.
Existing United States Patent (USP) 5207825 discloses a kind of ink-jet printing composition, and it comprises waterborne liquid low-melting ink vehicle, tinting material and is the polymeric additive of the bisphenol-a derivative of replacement.United States Patent (USP) 5241585 discloses and has a kind ofly comprised low-melting ink vehicle, the tinting material of waterborne liquid and be selected from amine type amine type alcoxylates, the pure monoester type alcoxylates of dehydration sorb (sugar), the ink mixture of the additive of the alkylene oxide adduct of glycerine and their mixture.United States Patent (USP) discloses a kind of ink composite that is applicable to ink jet printing for No. 5316575, and it comprises aqueous resin solution and pigment dyestuff, and wherein said ink composite is essentially no volatile organic compounds.United States Patent (USP) 6113680 discloses pigment-type ink-jet ink, and it contains pigment dyestuff and contains as the polyethylene oxide of hydrophilic segment with as the alkyl of hydrophobic part and the compound and the water of aryl radical forms.
Summary of the invention:
The purpose of this invention is to provide a kind of water-soluble pigment style textile printing ink, this ink can carry out textile printing on the piezo-electric type ink-jet printer, compare with traditional stamp, have bright in luster, and fabric does not need to carry out pre-treatment, aftertreatment is also very simple, only needs that promptly fabric is carried out suitable heat and bakes (180-190 ℃ of bakings 2-5 minutes or 210 ℃ of cylinders were pressed 1 minute) and just can obtain the stamp finished product without decatize, washing.
Water-soluble pigment style textile printing ink of the present invention is made up of pigment, water-miscible organic solvent, deionized water, sanitas, self-crosslinking acrylic resin, tensio-active agent, wetting agent, dispersion agent, PH conditioning agent.
Water-soluble pigment style textile printing ink of the present invention demonstrates following feature: 1, the viscosity 25 ℃ the time is 2-6mPa.S, 2, pH value 7.5-10.0, and between surface tension 25-45 dynes per centimeter.
About the various compositions of composition for ink of the present invention and being described in detail as follows of feature:
1) the said pigment of the present invention is 1, yellow: C.I.Pigment Yellow 109 (PY109 Huang), C.I.PigmentYellow 110 (PY110 Huang), C.I.Pigment Yellow 137 (PY137 Huang), C.I.Pigment Yellow174 (PY174 Huang), 2, red: C.I.Pigment Red 209 (PR209 is red), C.I.Pigment Red 122 (PR122 is red), C.I.Pigment Red 67 (PR 67 is red), 3, blue: (C.I.Pigment Blue15:3 (15:3 phthalocyanine blue), C.I.Pigment Blue 60 (PB60 indigo plant), C.I.Pigment Blue 18 (PB18 indigo plant), 4, black: C.I.Pigment Black7 (7# carbon black), 5, orange: C.I.Pigment Orange 34 (the solid forever orange of 34#), 6, green: C.I.Pigment Green 7 compositions such as (7# phthalein viridescents), its content is 2-6%.
2) water is used as the carrier of aqueous jet composition of the present invention, and in general, in the weight of said composition, the amount of water is between about 55-70%, is preferably between about 45-65%.In order to prevent that nozzle from being stopped up by the dissolved salt in the water, preferably adopts deionized water.
3) water miscible pigment jetting printing ink composition of the present invention comprises as low-melting ink vehicle and gives the fluoropolymer resin of base material to the adhesive effect of colouring matter.Preferentially select self-crosslinking acrylic resin in the present invention for use, this resin can be crosslinked when heating, makes it to solidify, thereby make the stamp product have good water-fast washing and the anti-function of soaping.The resin that is present in the jet ink composition is generally about 3-15% of composition weight, be preferably about 2-5%, too much use resin can increase the viscosity of ink and cause bad printing operation and poor printed patterns quality, very few resin can make the wash durability and the anti-poor performance of soaping of printed matter.
4) water miscible pigment jetting printing ink composition of the present invention comprises one or more dispersion agents, and dispersion agent is mainly used in the ground pigment mill base.Add dispersion agent, can increase the grinding effect of pigment, shorten and grind man-hour, strengthen the depth of shade and the stability thereof of mill base.The consumption of dispersion agent is between the pigment concentration 0.3-2%, and optimum amount is between 0.5-1.5%.Suitable dispersion agent example comprises the Dispers 715W of Di Gao company, SER-AD FX 600 of Sheng Wo company or the like.
5) water miscible pigment jetting printing ink composition of the present invention can comprise solubleness or the dispersiveness of one or more organic solvent with increase resin or colorant.Water-miscible organic solvent content is 3-10%.Have now found that, preferably use the mixture of two kinds of solvents, although other solvent also can be used, preferred first kind of solvent is N-Methyl pyrrolidone or 2-Pyrrolidone.This solvent is to be enough to dissolve or the amount of dispersion resin or colouring matter exists.The preferred amounts of this solvent is in the scope of 3-6% weight in the present invention.Preferred second kind of solvent is pure ethers, comprise: ethylene glycol monomethyl ether, ethylene glycol ethyl ether, ethylene glycol is ether, diethylene glycol dimethyl ether, Diethylene Glycol butyl ether, propylene glycol monomethyl ether, dipropylene glycol methyl ether, tripropylene glycol methyl ether, tripropylene glycol ether, triethylene glycol methyl ether etc., the total amount of the alcohol ether component of using in the composition for ink of the present invention is considered by the viscosity of combination and is changed in wide scope, excessive glycol ether should be avoided, the thickness because composition may become too and can not pass through nozzle, and can cause problem of environmental pollution.Most preferred scope is between 2-8%.
6) water miscible pigment jetting printing ink composition of the present invention comprises that one or more wetting agent is parched at the nozzle place to prevent ink.Can use any suitable wetting agent.The example of the wetting agent that is suitable for comprises aliphatic polyol for example glycol, triol, and other polyol.The example of suitable polyvalent alcohol comprises propylene glycol, butyleneglycol, glycerine, glycol ether, dipropylene glycol, Triethylene glycol, tripropylene glycol, polyoxyethylene glycol etc.The amount of employed wetting agent component depends on used polyvalent alcohol molecular weight to a certain extent, and wetting action reduces with the increase of molecular weight usually, and most preferred weight is between 5-15%.Most preferred scope is 10-15%.
7) composition for ink of the present invention comprises one or more tensio-active agents, it is believed that tensio-active agent can provide more than a kind of benefit.So tensio-active agent is considered in the preparation of ink-jet printing composition and can prevents the foaming of ink between the usage period.Think that also tensio-active agent provides the short ink setting time by the surface tension that reduces ink composite.Any suitable tensio-active agent all can be used.The example of suitable tensio-active agent comprises siloxanes and acetylenic diols, as DC-150, SURFYNOL104 (disappearing worried 104), SURFYNOL SE (worried SE disappears), SURFYNOL440 (disappearing worried 440) etc.Tensio-active agent is present in the composition for ink of the present invention in the foaming of usage period and the amount that shortens time of drying can prevent ink effectively, and its contained tensio-active agent is siloxanes and acetylenic diols, and its content is 0.2-1.0%.Be preferably between about 0.2-0.8%.Preferably avoid excessive use tensio-active agent, because excessive use tensio-active agent may exert an adverse impact to printing quality.
8) its contained sanitas LEX that is ROHM AND HAAS, the TROYSAN174 of Te Luoyi company, TROYSAN186 etc., its content is 0.1-0.6%.
9) its contained PH conditioning agent is oxyammonia, thanomin, trolamine etc., adds the PH conditioning agent and can guarantee solubility and the dispersibility of fluoropolymer resin in aqueous carrier.For this reason, wish the pH value of ink is remained on the scope of 7.5-10, the consumption of PH conditioning agent is between the 0.1-1.0%, is preferably between the 0.2-0.8%.
This ink of the present invention can carry out textile printing on the piezo-electric type ink-jet printer, compare with traditional stamp, have bright in luster, and fabric does not need to carry out pre-treatment, advantages such as aftertreatment is also very simple only need that promptly fabric is carried out suitable heat and bake (180-190 ℃ of bakings 2-5 minutes or 210 ℃ of cylinders were pressed 1 minute) and just can obtain the stamp finished product without decatize, washing.Water-soluble pigment style textile printing ink of the present invention demonstrates following feature: 1, the viscosity 25 ℃ the time is 2-6mPa.S, 2, pH value 7.5-10.0, and between surface tension 25-45 dynes per centimeter.
Embodiment:
Describe the present invention below in conjunction with embodiment:
Embodiment:
The preparation of A, aqueous pigment dispersions:
1, prescription: following is weight (part)
Red Yellow Blue Black Orange Green
Pigment 250 260 250 250 250 250
Sodium-chlor 900 900 900 900 900 900
Polyoxyethylene glycol (grind resin) 160 150 150 160
Disper715W (Di Gao chemical company) dispersion agent 10 15 10 15 15 12
Acrylic resin (grind resin) 100
Glycol ether (wetting agent) 160
2, technology:
By above-mentioned prescription all materials are put in the kneader, mediated 3-5 hours, then, mixture is poured in the container that hot water is housed, about about 1 hour of 80 ℃ of following high-speed stirring, form pulpous state, filter slurry and water and clean 5 times repeatedly, obtain solids content and be 50% aqueous pigment dispersions to remove sodium-chlor.
The preparation of B, ink-jet printed concentrated solution:
1, prescription:
Raw material weight (part)
The pigment dispersion of above-mentioned steps (mill base) 52
Dispersion agent Disper715W (Di Gao chemical company) 0.5
Emulsion acrylic resin 10
Ethylene glycol 37
Disodium edta 0.06
Sanitas 0.44
2, technology:
Above-mentioned material was put into the sand mill dispersion grinding 4 hours, to prepare ink-jet printed concentrated solution.
The preparation of C, water-soluble ink-jet printing ink:
1, prescription:
Raw material weight (part)
The ink-jet printed concentrated solution 30 of above-mentioned steps
Glycerol 9
Sanitas 0.4
Disodium edta 0.05
Diethylene glycol monobutyl ether 3.2
N-Methyl pyrrolidone 4
The water soluble surfactant active 0.8
Self-crosslinking acrylic resin 5
PH conditioning agent 0.55
Water 47
2, technology
Above-mentioned material is added homogenizer successively stirred 3-5 hours, then,, and then, promptly get ink-jet printing ink with the membrane filtration of 0.8um with this ink 1.0um membrane filtration.

Claims (2)

1, a kind of water miscible pigment jetting printing ink is characterized in that it is made up of pigment, water-miscible organic solvent, deionized water, sanitas, self-crosslinking acrylic resin, tensio-active agent, wetting agent, dispersion agent, pH regulator agent;
1) said pigment is 1. yellow: C.I.Pigment Yellow 109, C.I.Pigment Yellow 110, C.I.Pigment Yellow 137, C.I.Pigment Yellow 174,2. red: C.I.Pigment Red 209, C.I.Pigment Red 122, C.I.Pigment Red 67,3. blue: C.I.Pigment Blue 15:3, C.I.PigmentBlue 60, C.I.Pigment Blue 18,4. black: C.I.Pigment Black 7,5. orange: C.I.PigmentOrange 34,6. green: C.I.Pigment Green 7 forms, and its content is 2-6%;
2) said water-miscible organic solvent is: N-Methyl pyrrolidone, and 2-Pyrrolidone, gylcol ether, Diethylene Glycol ethers, triethylene glycol ethers, its content are 3-10%;
3) resin is ACRYLIC EMULSION, the styrene/acrylic copolymer emulsion of self-crosslinking, and content is 3-15%;
4) contained lubricant is propylene glycol, glycerol, Diethylene Glycol, triethylene glycol, TEG, polyoxyethylene glycol, and its content is 10-15%;
5) its contained sanitas LEX that is ROHM AND HAAS, the TROYSAN174 of Te Luoyi company, TORYSAN186, its content are 0.1-0.6%;
6) its contained tensio-active agent is siloxanes and acetylenic diols, and its content is 0.2-1.0%;
7) its contained pH regulator agent oxyammonia, thanomin, trolamine, its content is 0.1-1.0%;
8) its contained dispersion agent Dispers 175W that is Di Gao company, the SER-AD FX 600 of Sheng Wo company, consumption are between the pigment concentration 0.3-2%;
6) its contained deionized water, content is 55-70%.
2, water miscible pigment jetting printing ink according to claim 1 is characterized in that surface tension 25-45 dynes per centimeter, and viscosity is that 2-6mPas/25 ℃, pH are 7.5-10.
CN 200410013291 2004-06-09 2004-06-09 Water soluble pigment ink-jetting printing ink Active CN100519675C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200410013291 CN100519675C (en) 2004-06-09 2004-06-09 Water soluble pigment ink-jetting printing ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200410013291 CN100519675C (en) 2004-06-09 2004-06-09 Water soluble pigment ink-jetting printing ink

Publications (2)

Publication Number Publication Date
CN1583898A CN1583898A (en) 2005-02-23
CN100519675C true CN100519675C (en) 2009-07-29

Family

ID=34600419

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200410013291 Active CN100519675C (en) 2004-06-09 2004-06-09 Water soluble pigment ink-jetting printing ink

Country Status (1)

Country Link
CN (1) CN100519675C (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006249203A (en) * 2005-03-09 2006-09-21 Brother Ind Ltd Inkjet recording ink
CN1995232A (en) * 2005-12-31 2007-07-11 深圳市海川实业股份有限公司 10YR 8.5/2 dye composition and object color lump prepared from the composition
CN101081952B (en) * 2007-07-12 2011-04-20 石深泉 Environment-friendly type on-press-coating ink-jet CTP offset master, pigment ink and preparation method thereof
CN101457041B (en) * 2007-12-10 2011-05-04 珠海纳思达企业管理有限公司 High optical density and low permeability black pigment ink composition and method of making the same
CN101899237B (en) * 2010-06-25 2013-04-24 上海英威喷墨科技有限公司 Latex-type waterborne pigment oil ink for inkjet printing of non-absorbed substrate as well as preparation method and applications thereof
CN102108641B (en) * 2011-01-12 2012-09-05 郑州鸿盛数码科技股份有限公司 Digital printing active dye jet ink
CN102838899A (en) * 2012-09-11 2012-12-26 东莞市锐达涂料有限公司 Water-soluble environmental-protection composite printing ink and preparation method thereof
CN102976791B (en) * 2012-11-02 2014-09-17 广东道氏技术股份有限公司 Shrink-proof glazing agent and its application
CN105949411B (en) * 2016-05-13 2018-08-17 佛山科学技术学院 For ink-jet printed block type pigment dispersion color fixing agent and preparation method and application
CN106223022A (en) * 2016-07-27 2016-12-14 董荣琴 A kind of fabric water solublity inorganic agent and preparation method thereof
CN106318030A (en) * 2016-08-16 2017-01-11 湖南新力华纳米科技有限公司 Environmentally-friendly pigment black ink color paste used for automatic digital laser printing and preparation method thereof
JP6812909B2 (en) * 2017-06-15 2021-01-13 京セラドキュメントソリューションズ株式会社 Transfer printing method and manufacturing method of printed matter
CN108587321A (en) * 2018-03-30 2018-09-28 深圳市墨库图文技术有限公司 The digital ink-jet printed white of one kind and colour-wash ink and preparation method thereof
JP7154956B2 (en) * 2018-11-02 2022-10-18 株式会社Screenホールディングス Inkjet overcoat composition and printed matter
CN109913040A (en) * 2019-04-01 2019-06-21 中山布瑞特环保油墨有限公司 A kind of aqueous chalk and preparation method thereof
CN110028841A (en) * 2019-05-18 2019-07-19 北京联创佳艺影像新材料技术有限公司 A kind of ink improving digital printing clear-cut margin degree
CN113026384B (en) * 2021-03-18 2023-01-03 常州喜莱维纺织科技有限公司 Fabric micro-printing method

Also Published As

Publication number Publication date
CN1583898A (en) 2005-02-23

Similar Documents

Publication Publication Date Title
CN100519675C (en) Water soluble pigment ink-jetting printing ink
CN104245861B (en) Ink-jet sublimable dye ink and colouring method
TWI484001B (en) An ink group for ink jet printing and printing, and a method for dyeing the fibers using the ink set
CN101309975B (en) Disperse dye, disperse dye composition, ink for ink-jet printing, and staining method and stained material using the dye, composition or ink
CN100560859C (en) Natural fabric and polyamide fibre wet method transfer printing method
JP3141792B2 (en) Inkjet recording liquid
CN101531848B (en) An environment-friendly digital ink-jet direct printing textile ink and method for preparing same
CN107904984A (en) A kind of water nano digit printing direct-injection ink, production technology and Method of printing
CN100532475C (en) Digital-printing ink-jet ink made of nano pigment and its making process
CN1831055B (en) Ink for ink-jet recording
CN105369652B (en) A kind of ink and preparation method thereof
CN101245204A (en) Thermal sublimation digit printing ink-jet writing ink and preparation method
CN102443314A (en) Cold dyeing digital direct injection printing ink and its application technology
JP5613170B2 (en) Mixture of disperse dyes
CN103572615A (en) Fluorescent disperse dye ink for inkjet printing and preparation method of fluorescent disperse dye ink
AU2002349526B2 (en) Ink for inkjet recording
CN101981132A (en) Azopyridone disperse dyes, their preparation and use
CN103228740A (en) Disperse dye and method for dyeing hydrophobic fiber material using same
CN107254785B (en) Application of high-temperature direct-injection dispersion ink
CN107904987B (en) Water-based active direct-injection printing ink suitable for Beijing porcelain sprayer and preparation method thereof
CN107312387A (en) A kind of high temperature direct-injection dispersible ink and preparation method thereof
CN101072835A (en) Azo compounds
JP2008266466A (en) Inkjet ink and method for dyeing composite fiber product therewith
CN103717685A (en) Gray ink composition for ink jet printing and method for printing fibers using same
JP2004529222A (en) dispersion

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C56 Change in the name or address of the patentee

Owner name: YOU ZAIRONG

Free format text: FORMER NAME: YOU ZAILONG

CP01 Change in the name or title of a patent holder

Address after: 4, C1, Finance Plaza, Xindu street, 43, Fujian, Fuzhou Province: 350001

Co-patentee after: Xie Qionglin

Patentee after: You Zairong

Address before: 4, C1, Finance Plaza, Xindu street, 43, Fujian, Fuzhou Province: 350001

Co-patentee before: Xie Qionglin

Patentee before: You Zailong

EE01 Entry into force of recordation of patent licensing contract

Assignee: Fuzhou Di jet Digital Technology Co.,Ltd.

Assignor: You Zairong|Xie Qionglin

Contract fulfillment period: 2009.11.18 to 2024.6.8

Contract record no.: 2009350000262

Denomination of invention: Water soluble pigment ink-jetting printing ink

Granted publication date: 20090729

License type: Exclusive license

Record date: 20091211

LIC Patent licence contract for exploitation submitted for record

Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.11.18 TO 2024.6.8; CHANGE OF CONTRACT

Name of requester: FUZHOU DIJIETE DIGITAL SCIENCE AND TECHNOLOGY CO.,

Effective date: 20091211

DD01 Delivery of document by public notice
DD01 Delivery of document by public notice

Addressee: Gao Jian

Document name: payment instructions