CN102514276A - Carbon-based abrasion-proof material and preparation method thereof - Google Patents
Carbon-based abrasion-proof material and preparation method thereof Download PDFInfo
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- CN102514276A CN102514276A CN201110360841XA CN201110360841A CN102514276A CN 102514276 A CN102514276 A CN 102514276A CN 201110360841X A CN201110360841X A CN 201110360841XA CN 201110360841 A CN201110360841 A CN 201110360841A CN 102514276 A CN102514276 A CN 102514276A
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Abstract
The invention relates to a carbon-based abrasion-proof material. The carbon-based abrasion-proof material consists of an abrasion-proof layer and a supporting layer, wherein the abrasion-proof layer comprises the following components in percentage by weight: 10 to 25 percent of carbon fiber, 5 to 10 percent of acrylonitrile pulp, 15 to 20 percent of cotton velvet pulp, 18 to 25 percent of nano phenolic resin, 3 to 8 percent of graphite, 3 to 8 percent of iron oxide red, 1 to 5 percent of aluminum oxide, 5 to 15 percent of calcium carbonate, 3 to 6 percent of carboxylated acrylonitrile butadiene rubber latex, 1 to 2 percent of aluminum sulfate, 0.7 to 1.4 percent of sodium hydroxide and 0.01 to 0.03 percent of polyacrylamide; and the supporting layer comprises the following components in percentage by weight: 20 to 30 percent of cotton velvet pulp, 25 to 40 percent of glass fiber, 0 to 30 percent of calcium carbonate, 1 to 2 percent of aluminum sulfate, 0.01 to 0.03 percent of polyacrylamide, 15 to 25 percent of nano phenolic resin and 0 to 30 percent of textile industry scrap. The preparation method comprises the following steps of: (1) uniformly mixing the components of the abrasion-proof layer and the supporting layer respectively, adding water with a mass 1 to 5 times that of a mixture of the abrasion-proof layer and the supporting layer respectively, and forming abrasion-proof layer mixed liquor and supporting layer mixed liquor; (2) simultaneously casting the abrasion-proof layer mixed liquor and the supporting layer mixed liquor into a screen mesh through different pipelines, and overlapping the mixed liquors; (3) making the screen mesh in a vibration state, and making the abrasion-proof layer and the supporting layer firmly connected through roller extruding; and (4) removing residual water by extruding and drying. The carbon-based abrasion-proof material has low cost, high abrasion resistance and high weather resistance.
Description
Technical field
The present invention relates to the auto-parts technical field, especially relate to a kind of high-abrasive material that is used for auto parts and components.
Background technology
The manufacturing of traditional wet type abrasives is to process through the batch mixes of paper oar abrasives.This paper substrate abrasives of processing with the traditional handicraft means is demonstrating some significant disadvantages under the service condition of top load: demonstrate relatively poor temperature tolerance when (1) paper base material has higher coefficient of friction; (2) the paper substrate abrasives has better oil compatible than copper base abrasives, but this compatibility is still disliked deficiency in actual use; (3) heat conductivity of paper base material is relatively poor, under the big situation of load, is prone to produce on the surface hot spot of part.
Summary of the invention
To the problems referred to above that prior art exists, the applicant provides a kind of carbon back high-abrasive material and preparation method thereof.Cost of the present invention is low, and wearability and temperature tolerance are excellent.
Technical scheme of the present invention is following:
A kind of carbon back high-abrasive material; Be made up of wearing layer and supporting layer, the component of said wearing layer and the mass percent of each component are: carbon fiber 10 ~ 25%, acrylonitrile pulp 5 ~ 10%, velveteen pulp 15 ~ 20%, nanometer phenolic resins 18 ~ 25%, graphite 3 ~ 8%, iron oxide red 3 ~ 8%, aluminium oxide 1 ~ 5%, calcium carbonate 5 ~ 15%, carboxylic acrylonitrile butadiene rubber latex 3 ~ 6%, aluminum sulfate 1 ~ 2%, NaOH 0.7 ~ 1.4%, polyacrylamide 0.01 ~ 0.03%;
The component of said supporting layer and the mass percent of each component are: velveteen pulp 20 ~ 30%, glass fibre 25 ~ 40%, calcium carbonate 0 ~ 30%, aluminum sulfate 1 ~ 2%, polyacrylamide 0.01 ~ 0.03%, nanometer phenolic resins 15 ~ 25%, textile industry leftover pieces 0 ~ 30%.
A kind of preparation method of carbon back high-abrasive material, concrete steps are following:
(1) said wearing layer and supporting layer are mixed by its set of dispense ratio respectively, and add the water of quality respectively, form wearing layer mixed liquor and supporting layer mixed liquor for 1 ~ 5 times in its mixture;
(2) wearing layer mixed liquor and supporting layer mixed liquor get up to the silk screen laminated through different pipelines while curtain coatings, and wherein wearing layer is on the upper strata, and supporting layer is in lower floor;
(3) silk screen is in vibrational state, makes the fiber in the wearing layer pass supporting layer, and through the roller extruding wearing layer firmly is connected with supporting layer;
(4) wearing layer is connected back formation carbon back high-abrasive material of the present invention with supporting layer, and wherein residual moisture is sloughed through extruding and oven dry.
Beneficial technical effects of the present invention is:
One deck carbon fiber is as thin as a wafer arranged on the surface of abrasives of the present invention, and closeness is 20 ~ 30g/m
2, be evenly distributed, have excellent abrasive and temperature tolerance.Not only rely on resin-bondedly between carbon fiber layer and the base material, and have fiber intert to connect, with the base material strong bonded.Thermal conductivity that carbon fiber is good and temperature tolerance can well be protected the material of basic unit.Because of the requirement of its friction characteristics is reduced, price is also comparatively cheap, and the price of the price of whole wearing piece and traditional paper substrate wearing piece is close, and can be used to be attached at the friction lining on the automobile synchronizer tooth ring.
The specific embodiment
Embodiment 1
The preparation method of this carbon back high-abrasive material is:
(1) with the component of wearing layer: carbon fiber 18%, acrylonitrile pulp 8%, velveteen pulp 19%, nanometer phenolic resins 22%, graphite 6%, iron oxide red 6%, aluminium oxide 3%, calcium carbonate 10%, carboxylic acrylonitrile butadiene rubber latex 5%, aluminum sulfate 1.98%, NaOH 1%, polyacrylamide 0.02% mix; Add the water of 3 times of mixture qualities, be made into the wearing layer mixed liquor;
Component with supporting layer: velveteen pulp 24%, glass fibre 30%, calcium carbonate 14%, aluminum sulfate 1.98%, polyacrylamide 0.02%, nanometer phenolic resins 18%, cotton thread weaving leftover pieces 12% mix; Add the water of 3 times of mixture qualities, be made into the wearing layer mixed liquor;
(2) wearing layer mixed liquor and supporting layer mixed liquor pass through two different pipelines up and down, and curtain coating is got up to the silk screen laminated simultaneously, and wherein wearing layer is on the upper strata, and supporting layer is in lower floor;
(3) silk screen is in vibrational state, makes the fiber in the wearing layer pass supporting layer, and through the extruding of suspension roller wearing layer firmly is connected with supporting layer;
(4) wearing layer is connected back formation carbon back high-abrasive material of the present invention with supporting layer, and wherein residual moisture is sloughed through extruding roller and drying unit.
Carry out the carbon friction material of the present invention's preparation and the performance test of common paper substrate and copper base friction material at HF-35WT Wet-type friction material testing stand.The coefficient of friction of carbon back wearing piece (0.12) is between the coefficient of friction of paper substrate (0.15) and copper base (0.1) wearing piece.Paper base material is at 0.85J/mm
2The time produce hot spot, and carbon-based material can reach 1.15J/mm
2The carbon back wearing piece has close quiet, dyanainic friction coefficient, so it can provide the level and smooth gearshift the same with the paper substrate wearing piece; Simultaneously it does not have the paper substrate wearing piece such easy to wear and in the inconstant shortcoming of whole life cycle internal friction coefficient again, thereby makes the maintenance times that reduces speed changer become possibility.
Claims (2)
1. a carbon back high-abrasive material is made up of wearing layer and supporting layer, it is characterized in that:
The component of said wearing layer and the mass percent of each component are: carbon fiber 10 ~ 25%, acrylonitrile pulp 5 ~ 10%, velveteen pulp 15 ~ 20%, nanometer phenolic resins 18 ~ 25%, graphite 3 ~ 8%, iron oxide red 3 ~ 8%, aluminium oxide 1 ~ 5%, calcium carbonate 5 ~ 15%, carboxylic acrylonitrile butadiene rubber latex 3 ~ 6%, aluminum sulfate 1 ~ 2%, NaOH 0.7 ~ 1.4%, polyacrylamide 0.01 ~ 0.03%;
The component of said supporting layer and the mass percent of each component are: velveteen pulp 20 ~ 30%, glass fibre 25 ~ 40%, calcium carbonate 0 ~ 30%, aluminum sulfate 1 ~ 2%, polyacrylamide 0.01 ~ 0.03%, nanometer phenolic resins 15 ~ 25%, textile industry leftover pieces 0 ~ 30%.
2. the preparation method of a carbon back high-abrasive material is characterized in that concrete steps are following:
(1) said wearing layer and supporting layer are mixed by its set of dispense ratio respectively, and add the water of quality respectively, form wearing layer mixed liquor and supporting layer mixed liquor for 1 ~ 5 times in its mixture;
(2) wearing layer mixed liquor and supporting layer mixed liquor get up to the silk screen laminated through different pipelines while curtain coatings, and wherein wearing layer is on the upper strata, and supporting layer is in lower floor;
(3) silk screen is in vibrational state, makes the fiber in the wearing layer pass supporting layer, and through the roller extruding wearing layer firmly is connected with supporting layer;
(4) wearing layer is connected back formation carbon back high-abrasive material of the present invention with supporting layer, and wherein residual moisture is sloughed through extruding and oven dry.
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CN201110360841XA CN102514276A (en) | 2011-11-15 | 2011-11-15 | Carbon-based abrasion-proof material and preparation method thereof |
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CN201110360841XA CN102514276A (en) | 2011-11-15 | 2011-11-15 | Carbon-based abrasion-proof material and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102808878A (en) * | 2012-09-05 | 2012-12-05 | 杭州吉成汽车零部件有限公司 | Carbon-based friction material for drum brake of light passenger vehicle and preparation method of carbon-based friction material |
CN105505099A (en) * | 2015-12-28 | 2016-04-20 | 常熟市金亿复合材料有限公司 | Abrasion-resistant hollow glass plate |
Citations (5)
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US4256801A (en) * | 1979-12-14 | 1981-03-17 | Raybestos-Manhattan, Incorporated | Carbon fiber/flame-resistant organic fiber sheet as a friction material |
US6130177A (en) * | 1997-10-16 | 2000-10-10 | Nsk-Warner Kabushiki Kaisha | Wet friction material |
US6182804B1 (en) * | 1997-01-16 | 2001-02-06 | Borgwarner, Inc. | High performance two-ply friction material |
CN1446875A (en) * | 2003-01-28 | 2003-10-08 | 西北工业大学 | Paper based friction material with carbon fibers enhanced and its preparation method |
CN1632034A (en) * | 2004-11-11 | 2005-06-29 | 西安交通大学 | Doublelayer paper base friction material and friction plate making method |
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2011
- 2011-11-15 CN CN201110360841XA patent/CN102514276A/en active Pending
Patent Citations (5)
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US4256801A (en) * | 1979-12-14 | 1981-03-17 | Raybestos-Manhattan, Incorporated | Carbon fiber/flame-resistant organic fiber sheet as a friction material |
US6182804B1 (en) * | 1997-01-16 | 2001-02-06 | Borgwarner, Inc. | High performance two-ply friction material |
US6130177A (en) * | 1997-10-16 | 2000-10-10 | Nsk-Warner Kabushiki Kaisha | Wet friction material |
CN1446875A (en) * | 2003-01-28 | 2003-10-08 | 西北工业大学 | Paper based friction material with carbon fibers enhanced and its preparation method |
CN1632034A (en) * | 2004-11-11 | 2005-06-29 | 西安交通大学 | Doublelayer paper base friction material and friction plate making method |
Non-Patent Citations (2)
Title |
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任钢、邓海金、李明: "汽车用纸基摩擦材料国外研究进展", 《汽车技术》 * |
杨瑞丽、付业伟、李贺军: "碳质双层纸基摩擦材料的制备与性能表征", 《陕西师范大学学报(自然科学版)》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102808878A (en) * | 2012-09-05 | 2012-12-05 | 杭州吉成汽车零部件有限公司 | Carbon-based friction material for drum brake of light passenger vehicle and preparation method of carbon-based friction material |
CN102808878B (en) * | 2012-09-05 | 2014-10-29 | 杭州吉成汽车零部件有限公司 | Carbon-based friction material for drum brake of light passenger vehicle and preparation method of carbon-based friction material |
CN105505099A (en) * | 2015-12-28 | 2016-04-20 | 常熟市金亿复合材料有限公司 | Abrasion-resistant hollow glass plate |
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Application publication date: 20120627 |