CN102660197B - Leather brightening agent and leather brightening wet wiper - Google Patents
Leather brightening agent and leather brightening wet wiper Download PDFInfo
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- CN102660197B CN102660197B CN201210117444.4A CN201210117444A CN102660197B CN 102660197 B CN102660197 B CN 102660197B CN 201210117444 A CN201210117444 A CN 201210117444A CN 102660197 B CN102660197 B CN 102660197B
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Abstract
The invention discloses a leather brightening agent. The leather brightening agent comprises the following components in part by weight: 10. 0-30.0 parts of base material, 1.0-5.0parts of emulsifier, 0.5-10 parts of grease, 0.2 to 3.5 parts of auxiliary agent, 52.7-73.5 parts of solvent, 0.1-8.0 parts of crosslinking agent, 0.2-6.0 parts of initiator and 0.2-0.8 parts of other auxiliary materials. The invention also discloses a leather brightening wet wiper with the leather brightening agent. The leather brightening wet wiper comprises a light-tight wiper packaging bag and non-woven fabric which is soaked with an effective dose of the leather brightening agent. The leather brightening agent is better in comprehensive performance, more durable, more resistant to wiping and brighter, can supplement grease to a deep layer of leather to delay aging of the leather, and is bright like a film but has good permeability; and the leather brightening wet wiper is stable and reliable during the storage and carrying, is portable and convenient to use, and can brighten the leather as soon as wiping.
Description
Technical field
The present invention relates to a kind of fur nursing agent, relate in particular to a kind of leather gloss agent.
Background technology
The leather gloss agent of at present widespread use, mainly contains: 1. general grease emulsifying technology, can supplement leather grease, but surface-brightening is poor and not lasting, and wait grease to infiltrate after leather, it is gloomy and lackluster that surface becomes.2. aliphatic polyurethane class, introduces linking agent and carries out polymerization, although leather surface is bright, lacks grease, can not nourish leather, just form a kind of film at leather surface, and this tunic has affected the ventilation property of leather on the contrary, and the original ventilation property of leather is reduced.All kinds of leather polishing technology have advantage in actual applications above, and also defectiveness can not reach perfect combination.
In prior art, in leather gloss agent, add membrane-forming agent (base-material and linking agent) and generally can not add again grease composition, because the proportioning of membrane-forming agent and grease is difficult to control, once deal with the whole structure that will greatly reduce brightening agent improperly, affect the film-formation result of base-material, affect surface brightness, but the present invention is through a large amount of experiment, summary, obtain the proportioning of reasonable uniqueness, grease after emulsification is dispersed in membrane-forming agent, membrane-forming agent in crosslinking curing due to the existence of grease, ventilation property does not decline, and has kept good ventilation property.
The selected base-material of leather gloss agent of the present invention has good film-forming properties, in coordinating with grease and emulsifying agent, do not affect the bright property of film forming, resistance to subduing, the in the situation that of alternating bending, folding line is not stayed in knee, and solvent for use has increased the quick-drying of product, also played auxiliary crosslinked effect simultaneously, when after solvent evaporates, base-material and linking agent, under the effect of initiator, are just cross-linked film forming.
Leather polishing wet tissue of the present invention is selected the carrier of non-woven fabrics as brightening agent, the lighttight wet tissue outer packaging bag of overcoat, in the situation that not seeing light, when solvent for use does not volatilize, can not bring into play effect, working substance can not be attached on non-woven fabrics in a large number, thereby ensures that wet tissue is reliable and stable.In the time that user tears use, after solvent evaporates, base-material and linking agent, under the effect of light trigger, are just cross-linked film forming, wipe bright, easy to use.Leather polishing wet tissue of the present invention is easy to carry, and preserves not the used time reliable and stable, tears use extremely convenient, effective again.
Summary of the invention
Technical problem to be solved by this invention is to provide the better leather gloss agent of a kind of over-all properties, durable more, and more resistance to wiping, brighter; Deep layer is supplemented leather grease, delays leather aging, and bright film forming has again good ventilation property simultaneously.
Meanwhile, the invention provides a kind of leather polishing wet tissue with above-mentioned leather gloss agent, be easy to carry, wipe bright, easy to use.
The present invention solves the problems of the technologies described above the technical scheme adopting to be:
A kind of leather gloss agent, the weight part of each component is as follows:
Base-material 10.0 ~ 30.0 weight parts
Emulsifying agent 1.0 ~ 5.0 weight parts
Grease 0.5 ~ 10 weight part
Auxiliary agent 0.2 ~ 3.5 weight part
Solvent 52.7 ~ 73.5 weight parts
Linking agent 0.1 ~ 8.0 weight part
Initiator 0.2 ~ 6.0 weight part
Other auxiliary material 0.2 ~ 0.8 weight part
Described base-material is selected from one or more in aliphatic polyurethane, polyacrylic acid amide, aliphatic urethane acrylate, organosilicon-modified acrylate;
Described emulsifying agent is selected from one or more of cetearyl alcohol alcohol ether-2, cetearyl alcohol alcohol ether-21, PEG-7 hydrogenated castor oil, lauryl alcohol phosphoric acid ester, glyceryl monostearate;
Described grease comprises one or more in carnauba wax, beeswax, lanolin, shea butter, silicone composition;
Described auxiliary agent is higher fatty acid and/or high fatty alcohol, is selected from laurostearic acid and/or lauryl alcohol;
Described solvent is water, and ethanol, Virahol, one or more in ethylene glycol ethyl ether, vinyl acetic monomer, acetone;
Described linking agent is selected from one of isocyanic ester, methyl methacrylate, diallyl phthalate or cyanuric acid tripropylene;
Described initiator is light trigger;
Other described auxiliary material is essence and sanitas.
As one of concrete formula, the weight part of the each component of this brightening agent is as follows:
Aliphatic polyurethane 3.0 weight parts
Organosilicon-modified acrylate 7.0 weight parts
Cetearyl alcohol alcohol ether-2 0.6 weight part
Cetearyl alcohol alcohol ether-21 0.8 weight part
Glyceryl monostearate 0.9 weight part
Carnauba wax 3.0 weight parts
Shea butter 7.0 weight parts
Lauryl alcohol 2.0 weight parts
Virahol 4.0 weight parts
Water 69.5 weight parts
Methyl methacrylate 1.0 weight parts
Light trigger 1.0 weight parts
Other auxiliary material 0.2 weight part.
As two of concrete formula, the weight part of the each component of this brightening agent is as follows:
Polyacrylic acid amide 20.0 weight parts
Cetearyl alcohol alcohol ether-21 2.0 weight part
Glyceryl monostearate 1.5 weight parts
Beeswax 1.0 weight parts
Dimethyl silscone (50cst) 3.0 weight parts
Lauryl alcohol 0.8 weight part
Ethylene glycol ethyl ether 8.0 weight parts
Water 57.5 weight parts
Diallyl phthalate 5.0 weight parts
Light trigger 1.0 weight parts
Other auxiliary material 0.2 weight part.
As three of concrete formula, the weight part of the each component of this brightening agent is as follows:
Aliphatic urethane acrylate 18.0 weight parts
Cetearyl alcohol alcohol ether-2 3.0 weight part
Lauryl alcohol phosphoric acid ester 1.5 weight parts
Glyceryl monostearate 0.5 weight part
Lanolin 8.0 weight parts
Laurostearic acid 2.8 weight parts
Lauryl alcohol 0.6 weight part
Ethanol 8.0 weight parts
Vinyl acetic monomer 2.0 weight parts
Water 52.1 weight parts
Isocyanic ester 3.0 weight parts
Light trigger 0.2 weight part
Other auxiliary material 0.3 weight part.
As four of concrete formula, the weight part of the each component of this brightening agent is as follows:
Polyacrylic acid amide 30.0 weight parts
Cetearyl alcohol alcohol ether-21 0.6 weight part
PEG-7 hydrogenated castor oil 0.4 weight part
Beeswax 0.5 weight part
Dimethyl silscone (50cst) 1.0 weight parts
Laurostearic acid 3.5 weight parts
Acetone 3.0 weight parts
Water 49.7 weight parts
Cyanuric acid tripropylene 8.0 weight parts
Light trigger 3.0 weight parts
Other auxiliary material 0.3 weight part.
As five of concrete formula, it is characterized in that: the weight part of the each component of this brightening agent is as follows:
Polyacrylic acid amide 8.0 weight parts
Organosilicon-modified acrylate 6.0 weight parts
Cetearyl alcohol alcohol ether-2 0.8 weight part
Cetearyl alcohol alcohol ether-21 1.2 weight part
Glyceryl monostearate 0.8 weight part
Carnauba wax 7.0 weight parts
Shea butter 3.0 weight parts
Laurostearic acid 2.5 weight parts
Ethylene glycol ethyl ether 8.0 weight parts
Water 62.1 weight parts
Methyl methacrylate 0.1 weight part
Light trigger 0.2 weight part
Other auxiliary material 0.3 weight part.
As six of concrete formula, the weight part of the each component of this brightening agent is as follows:
Aliphatic polyurethane 7.0 weight parts
Organosilicon-modified acrylate 14.0 weight parts
PEG-7 hydrogenated castor oil 5.0 weight parts
Lanolin 0.5 weight part
Laurostearic acid 0.2 weight part
Virahol 5.0 weight parts
Water 53.5 weight parts
Isocyanic ester 8.0 weight parts
Light trigger 6.0 weight parts
Other auxiliary material 0.8 weight part.
The invention provides a kind of leather polishing wet tissue with the leather gloss agent in above-mentioned any one claim, described leather polishing wet tissue comprises lighttight wet tissue outer packaging bag and infiltrates the non-woven fabrics of leather gloss agent described in effective dose simultaneously.
In leather gloss agent of the present invention, by the effect of linking agent, amino in base-material, siloxane bond in air with carbonic acid gas and water generation crosslinked action, and solidified, introduced again the group such as lauryl alcohol, laurostearic acid simultaneously, with can not completely crued amino in air, siloxane bond is combined, and makes it to become stable, and not oxidizable, reach durable wear-resistant.Due to the group such as lauryl alcohol, laurostearic acid with amino crosslinked after, group is elongated, becomes stable, product itself becomes again more resistance to wiping on the contrary, brighter, so leather gloss agent of the present invention exempt to wipe from bright, light is lasting.
After leather gloss agent grease emulsifying of the present invention, molecule is less, and dispersion more even is easier to infiltrate leather deep layer, instead of is attached to leather surface, and grease has increased oilness, has strengthened the flexible resistance of product.So this leather gloss agent can deep layer is supplemented leather grease, delays leather aging, leather polishing after solidifying, wear-resisting resistance to wiping, the softness advantage such as do not harden.
Brief description of the drawings
Fig. 1 is the production scheme of the leather polishing wet tissue of invention.
Embodiment
Below in conjunction with drawings and Examples, the invention will be further described.
A kind of leather gloss agent, is characterized in that the weight part of each component is as follows:
Base-material 10.0 ~ 30.0 weight parts
Emulsifying agent 1.0 ~ 5.0 weight parts
Grease 0.5 ~ 10 weight part
Auxiliary agent 0.2 ~ 3.5 weight part
Solvent 52.7 ~ 73.5 weight parts
Linking agent 0.1 ~ 8.0 weight part
Initiator 0.2 ~ 6.0 weight part
Other auxiliary material 0.2 ~ 0.8 weight part
Described base-material is selected from one or more in aliphatic polyurethane, polyacrylic acid amide, aliphatic urethane acrylate, organosilicon-modified acrylate;
Described emulsifying agent is selected from one or more of cetearyl alcohol alcohol ether-2, cetearyl alcohol alcohol ether-21, PEG-7 hydrogenated castor oil, lauryl alcohol phosphoric acid ester, glyceryl monostearate;
Described grease comprises one or more in carnauba wax, beeswax, lanolin, shea butter, silicone composition;
Described auxiliary agent is selected from laurostearic acid and/or lauryl alcohol;
Described solvent is water, and ethanol, Virahol, one or more in ethylene glycol ethyl ether, vinyl acetic monomer, acetone;
Described linking agent is selected from one of isocyanic ester, methyl methacrylate, diallyl phthalate or cyanuric acid tripropylene;
Described initiator is light trigger;
Other described auxiliary material is essence and sanitas.
Following table is the weight part value of each component in each embodiment:
Embodiment 1
A kind of New-type leather wet tissue brightening agent, the weight part of the each component of this wet tissue brightening agent is as follows:
Aliphatic polyurethane 3.0 weight parts
Organosilicon-modified acrylate 7.0 weight parts
Cetearyl alcohol alcohol ether-2 0.6 weight part
Cetearyl alcohol alcohol ether-21 0.8 weight part
Glyceryl monostearate 0.9 weight part
Carnauba wax 3.0 weight parts
Shea butter 7.0 weight parts
Lauryl alcohol 2.0 weight parts
Virahol 4.0 weight parts
Water 69.5 weight parts
Methyl methacrylate 1.0 weight parts
Light trigger 1.0 weight parts
Other auxiliary material 0.2 weight part
Each composition component is mixed, stir, carry out emulsification, add successively light trigger, linking agent and other auxiliary material, stir.Final is leather wet tissue brightening agent, and this brightening agent and non-woven fabrics are made after leather wet tissue by a certain percentage, packs the sealing of wet tissue outer packaging bag into.Wiping, in leather, is dried rear surface light gently, and tack-free, softness is not hardened.
Embodiment 2
A kind of New-type leather wet tissue brightening agent, the weight part of the each component of this wet tissue brightening agent is as follows:
Polyacrylic acid amide 20.0 weight parts
Cetearyl alcohol alcohol ether-21 2.0 weight part
Glyceryl monostearate 1.5 weight parts
Beeswax 1.0 weight parts
Dimethyl silscone (50cst) 3.0 weight parts
Lauryl alcohol 0.8 weight part
Ethylene glycol ethyl ether 8.0 weight parts
Water 57.5 weight parts
Diallyl phthalate 5.0 weight parts
Light trigger 1.0 weight parts
Other auxiliary material 0.2 weight part
Each composition component is mixed, stir, carry out emulsification, add light trigger, stir.Be leather wet tissue brightening agent, this brightening agent and non-woven fabrics are made after leather wet tissue by a certain percentage, and wiping is in leather gently, and grease infiltrates rapidly leather, and linking agent solidifies through sun exposure at leather surface, solidify rear surface light.
Embodiment 3
A kind of New-type leather wet tissue brightening agent, the weight part of the each component of this wet tissue brightening agent is as follows:
Aliphatic urethane acrylate 18.0 weight parts
Cetearyl alcohol alcohol ether-2 3.0 weight part
Lauryl alcohol phosphoric acid ester 1.5 weight parts
Glyceryl monostearate 0.5 weight part
Lanolin 8.0 weight parts
Laurostearic acid 2.8 weight parts
Lauryl alcohol 0.6 weight part
Ethanol 8.0 weight parts
Vinyl acetic monomer 2.0 weight parts
Water 52.1 weight parts
Isocyanic ester 3.0 weight parts
Light trigger 0.2 weight part
Other auxiliary material 0.3 weight part
Each composition component is mixed, stir, carry out emulsification, add light trigger, stir.Be leather wet tissue brightening agent, this brightening agent and non-woven fabrics are made after leather wet tissue by a certain percentage, and wiping is in leather gently, and grease infiltrates rapidly leather, and linking agent solidifies through sun exposure at leather surface, solidify rear surface light.
Embodiment 4
A kind of New-type leather wet tissue brightening agent, the weight part of the each component of this wet tissue brightening agent is as follows:
Polyacrylic acid amide 30.0 weight parts
Cetearyl alcohol alcohol ether-21 0.6 weight part
PEG-7 hydrogenated castor oil 0.4 weight part
Beeswax 0.5 weight part
Dimethyl silscone (50cst) 1.0 weight parts
Laurostearic acid 3.5 weight parts
Acetone 3.0 weight parts
Water 49.7 weight parts
Cyanuric acid tripropylene 8.0 weight parts
Light trigger 3.0 weight parts
Other auxiliary material 0.3 weight part
Each composition component is mixed, stir, carry out emulsification, add light trigger, stir.Be leather wet tissue brightening agent, this brightening agent and non-woven fabrics are made after leather wet tissue by a certain percentage, and wiping is in leather gently, and grease infiltrates rapidly leather, and linking agent solidifies through sun exposure at leather surface, solidify rear surface light.
Embodiment 5
A kind of New-type leather wet tissue brightening agent, the weight part of the each component of this wet tissue brightening agent is as follows:
Polyacrylic acid amide 8.0 weight parts
Organosilicon-modified acrylate 6.0 weight parts
Cetearyl alcohol alcohol ether-2 0.8 weight part
Cetearyl alcohol alcohol ether-21 1.2 weight part
Glyceryl monostearate 0.8 weight part
Carnauba wax 7.0 weight parts
Shea butter 3.0 weight parts
Laurostearic acid 2.5 weight parts
Ethylene glycol ethyl ether 8.0 weight parts
Water 62.1 weight parts
Methyl methacrylate 0.1 weight part
Light trigger 0.2 weight part
Other auxiliary material 0.3 weight part
Each composition component is mixed, stir, carry out emulsification, add light trigger, stir.Be leather wet tissue brightening agent, this brightening agent and non-woven fabrics are made after leather wet tissue by a certain percentage, on leather, one wipe gently, can deep layer nourish leather, keep again bright property and the ventilation property of leather.
Embodiment 6
A kind of New-type leather wet tissue brightening agent, the weight part of the each component of this wet tissue brightening agent is as follows:
Aliphatic polyurethane 7.0 weight parts
Organosilicon-modified acrylate 14.0 weight parts
PEG-7 hydrogenated castor oil 5.0 weight parts
Lanolin 0.5 weight part
Laurostearic acid 0.2 weight part
Virahol 5.0 weight parts
Water 53.5 weight parts
Isocyanic ester 8.0 weight parts
Light trigger 6.0 weight parts
Other auxiliary material 0.8 weight part
Each composition component is mixed, stir, carry out emulsification, add light trigger, stir.Be leather wet tissue brightening agent, this brightening agent and non-woven fabrics are made after leather wet tissue by a certain percentage, on leather, one wipe gently, can deep layer nourish leather, keep again bright property and the ventilation property of leather.
In above-described embodiment, described base-material can be selected from one or more in aliphatic polyurethane, polyacrylic acid amide, aliphatic urethane acrylate, organosilicon-modified acrylate.
Described emulsifying agent can be selected from one or more of cetearyl alcohol alcohol ether-2, cetearyl alcohol alcohol ether-21, PEG-7 hydrogenated castor oil, lauryl alcohol phosphoric acid ester, glyceryl monostearate.
Described grease can be selected from one or more in carnauba wax, beeswax, lanolin, shea butter, dimethyl silscone (50cst) composition.
Described auxiliary agent is higher fatty acid and high fatty alcohol, can be selected from laurostearic acid and/or lauryl alcohol etc.
Described solvent is water and ethanol, Virahol, one or more of ethylene glycol ethyl ether, vinyl acetic monomer, acetone and other organic solvent.
Described linking agent can be selected from isocyanic ester, methyl methacrylate, diallyl phthalate or cyanuric acid tripropylene.
Described initiator is light trigger;
Other described auxiliary material is essence and sanitas.
Claims (7)
1. a leather gloss agent, is characterized in that: the weight part of the each component of this brightening agent is as follows:
Other described auxiliary material is essence and sanitas.
2. a leather gloss agent, is characterized in that: the weight part of the each component of this brightening agent is as follows:
Other described auxiliary material is essence and sanitas.
3. a leather gloss agent, is characterized in that: the weight part of the each component of this brightening agent is as follows:
Other described auxiliary material is essence and sanitas.
4. a leather gloss agent, is characterized in that: the weight part of the each component of this brightening agent is as follows:
Other described auxiliary material is essence and sanitas.
5. a leather gloss agent, is characterized in that: the weight part of the each component of this brightening agent is as follows:
Other described auxiliary material is essence and sanitas.
6. a leather gloss agent, is characterized in that: the weight part of the each component of this brightening agent is as follows:
Other described auxiliary material is essence and sanitas.
7. cum rights require a leather polishing wet tissue for the leather gloss agent described in any one in 1 to 6, it is characterized in that: described leather polishing wet tissue comprises lighttight wet tissue outer packaging bag and infiltrates the non-woven fabrics of leather gloss agent described in effective dose.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210117444.4A CN102660197B (en) | 2012-04-20 | 2012-04-20 | Leather brightening agent and leather brightening wet wiper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210117444.4A CN102660197B (en) | 2012-04-20 | 2012-04-20 | Leather brightening agent and leather brightening wet wiper |
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| CN102660197A CN102660197A (en) | 2012-09-12 |
| CN102660197B true CN102660197B (en) | 2014-11-05 |
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| CN102660197A (en) | 2012-09-12 |
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