CN103223795A - Printing and imaging method with additive color process - Google Patents
Printing and imaging method with additive color process Download PDFInfo
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- CN103223795A CN103223795A CN2012104085423A CN201210408542A CN103223795A CN 103223795 A CN103223795 A CN 103223795A CN 2012104085423 A CN2012104085423 A CN 2012104085423A CN 201210408542 A CN201210408542 A CN 201210408542A CN 103223795 A CN103223795 A CN 103223795A
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- IZDDOKGHMWMQOO-IBGZPJMESA-N C[C@H](C1)C=CC([I]=C(c2cc(I)ccc2C=[S](c(cc2)ccc2-c2ccccc2)(=O)=O)O2)=C1C2=C Chemical compound C[C@H](C1)C=CC([I]=C(c2cc(I)ccc2C=[S](c(cc2)ccc2-c2ccccc2)(=O)=O)O2)=C1C2=C IZDDOKGHMWMQOO-IBGZPJMESA-N 0.000 description 1
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Abstract
The invention relates to a printing and imaging method with an additive color process, and belongs to the technical field of anti-counterfeit printing. The method comprises the steps that ultraviolet light is used for exciting red, green and blue fluorescent ink jet ink; imaging is performed by an additive color process principle during a printing course; and a color fluorescent image is obtained. The three ultraviolet absorption fluorescent anti-counterfeit ink is invisible, and can present colorful colors after color addition under the illumination of a specific ultraviolet lamp, and various color effects after the addition can be obtained through matching of the red ink, the green ink and the blue ink in different proportions, and through superposition of emission wavelengths within different ranges. A printing pattern obtained by the method is high in ink brightness, bright in color and good in effect.
Description
Technical field
The present invention relates to a kind of additive process printing formation method, utilize the printing jetted ink to carry out additive process and be printed as picture, belong to the anti-counterfeiting printing technology field.
Background technology
Present stage, exist two kinds of formation methods in the colored field: additive process imaging and subtractive process imaging, wherein the additive process imaging applications is at each electronic applications, as LED television set imaging system, computer monitor, mobile phone screen or the like, it is red mainly to be that fluorescent material is launched, green, blue three color light, when different coloured light is radiated at a time-out simultaneously, can produce another new coloured light, and along with the increase of different color contamination resultants, the lightness of mixed light can improve gradually with red (orange), green, blue (purple) three kinds of coloured light are done the mixing of proper proportion respectively, can obtain other different coloured light; The subtractive process principle generally is applied to printing industry, comprises various printers, air brushing machine and large-scale offset printing equipment, image processing software or the like.The additive process and the ratio juris that loses lustre are respectively as depicted in figs. 1 and 2.
Summary of the invention
The invention provides a kind of additive process printing imaging method, by red, green, blue three fluorescence jetted ink, utilize the additive process imaging, air brushing goes out the rich and varied image of color, to reach better antifalse effect and special artistic effect.
The technical scheme that technical solution problem of the present invention is taked:
A kind of additive process printing formation method adopts ultraviolet excitated red, green and blue-fluorescence jetted ink, and the imaging of employing additive process principle obtains color fluorescent image in the process of printing.
Above-mentioned ultraviolet excitated red fluorescence jetted ink is mixed with and is obtained by ultraviolet excitated red fluorescence falsification preventing material (UV absorption red fluorescence anti-fake material), synthetic resin, solvent, auxiliary agent, and it comprises following composition and weight proportion:
Ultraviolet excitated red fluorescence falsification preventing material: 0.1-10 part
Synthetic resin: 5-30 part
Esters solvent: 20-50 part
Ether solvent: 20-40 part
Halogenated alkane solvent: 5-40 part
Surfactant: 0.5-3 part
PH conditioning agent: 0.5-3 part.
Ultraviolet excitated red fluorescence falsification preventing material among the present invention is for exciting the UV absorption material of (absorption) wavelength at 350 ~ 500nm, emission wavelength ranges is the ruddiness of 590 ~ 650nm, the printing ink of this anti-fake material preparation is transparence liquid, after being printed on the stock, visual colourless, present gorgeous redness behind ultra violet lamp, it is disguised strong, can effectively prevent duplicating, counterfeit.
Ultraviolet excitated red fluorescence falsification preventing material can be by europium chloride, phenanthroline, thienyl three fluoro-1,3-diacetyl and acrylic acid synthesize europium coordination monomer (ECM), aggregate into the polymer (rare earth organic complex) that the side face is connected with the coordination of emitting red light europium with methyl methacrylate (MMA) again, excitation wavelength is 350 ~ 500nm, emission wavelength is 602 ~ 630nm, and structural formula is as follows:
Wherein, x represents the unit polymerization degree n
1, y represents COOH-CH-CHCH
3The unit polymerization degree n
2, n
1And n
2Be positive integer, wherein n
1=7-16, n
2=24-47.
Described synthetic resin is one or more the mixture in acrylic resin, epoxy resin, polyurethane resin, vinyl chloride-vinyl acetate resin and the phenolic resins.
Described esters solvent is one or more the mixture in ethyl acetate, methyl formate, butyl ester, 1-Methoxy-2-propyl acetate, methyl acetate, ethyl butyrate, propylene glycol monomethyl ether acetate and the ethyl benzoate.
Described ether solvent is propylene glycol monomethyl ether, ethylene glycol ethyl ether, diethylene glycol butyl ether and 1, the mixture of one or more in the 4-dioxane.
The halogenated alkane solvent is carrene, chloroform, carbon tetrachloride and 1, the mixture of one or more in the 2-dichloroethanes.
Described surfactant is one or more the mixture in organic silicon surfactant and the Organic fluoride surfactant.
Described pH conditioning agent is N, the mixture of one or more in dinethylformamide, triethanolamine and the triethylamine.
The preparation method of described ultraviolet excitated red fluorescence jetted ink comprises the steps:
(1) ultraviolet excitated red fluorescence falsification preventing material and ether solvent, halogenated alkane solvent are mixed according to described proportioning, add thermal agitation, temperature is 30 ~ 55 ℃, obtains the A1 component;
(2) synthetic resin is mixed according to described proportioning with esters solvent, stir, obtain the B1 component;
(3) described A1 component and B1 component are mixed, it is transparent fully to be stirred to solution, adds surfactant, pH conditioning agent then, and mixing and stirring obtains this printing ink again.
The heating mixing time of described A1 component is 20 ~ 40min, and the mixing time of described B1 component is 20 ~ 40min, and described A1 component and B1 component are mixed, and mixing time is 30 ~ 60min; Add surfactant, pH conditioning agent, mixing the time of stirring again is 10 ~ 25min.
The pH of this ultraviolet excitated red fluorescence jetted ink is 7.80-9.69, surface tension is 23.63-30.37mN/m, viscosity is 2.58-4.30mPaS, and the printing ink fluorescence intensity is 532.067-583.552cd, can be printed on the various stocks such as art post paperboard, art paper, offset paper, aluminium-foil paper, photo paper, rice paper, during no ultraviolet source irradiation, for colourless or approaching colourless, under specific ultraviolet source irradiation, present bright-coloured redness, effect is obvious, can well play antifalse effect.
Above-mentioned burst of ultraviolel green fluorescence jetted ink is mixed with and is obtained by commercially available burst of ultraviolel green fluorescence anti-fake material (UV absorption green fluorescence anti-fake material), synthetic resin, solvent, auxiliary agent, and it comprises following composition and weight proportion:
Burst of ultraviolel green fluorescence anti-fake material: 0.1 ~ 10 part
Synthetic resin: 5 ~ 30 parts
Esters solvent: 15 ~ 50 parts
Ether solvent: 15 ~ 40 parts
Nitrogenous kind solvent: 10 ~ 30 parts
Sulfur-bearing kind solvent: 10 ~ 30 parts
Surfactant: 0.5 ~ 3 part
PH conditioning agent: 0.5 ~ 3 part.
Burst of ultraviolel green fluorescence anti-fake material among the present invention is for exciting the UV absorption material of (absorption) wavelength at 220 ~ 450nm, emission wavelength ranges is the green glow of 500 ~ 600nm, the printing ink of this anti-fake material preparation is transparence liquid, after being printed on the stock, visual colourless, present gorgeous green behind ultra violet lamp, it is disguised strong, can effectively prevent duplicating, counterfeit.
Burst of ultraviolel green fluorescence anti-fake material chemical name among the present invention: 6-chloro-2-[5-chloro-2-(4-biphenyl sulfonamido)] phenyl-4-benzoxazinone, excitation wavelength is 500-600nm for the 300-400nm emission wavelength, concrete structure is:
Described synthetic resin is one or more the mixture in acrylic resin, epoxy resin, polyurethane resin, vinyl chloride-vinyl acetate resin and the phenolic resins.
Described esters solvent is one or more the mixture in ethyl acetate, methyl formate, butyl ester, 1-Methoxy-2-propyl acetate, methyl acetate, ethyl butyrate, propylene glycol monomethyl ether acetate and the ethyl benzoate.
Described ether solvent is propylene glycol monomethyl ether, ethylene glycol ethyl ether, diethylene glycol butyl ether and 1, the mixture of one or more in the 4-dioxane.
Described nitrogenous kind solvent is N, N-NMF, N, the mixture of one or more in N-methylacetamide, N-N-methyl 2-pyrrolidone N-and the formamide.
Described sulfur-bearing kind solvent is one or both the mixture in dimethyl sulfoxide (DMSO) and the sulfolane.
Described surfactant is one or more the mixture in organic silicon surfactant and the Organic fluoride surfactant.
Described pH conditioning agent is N, the mixture of one or more in dinethylformamide, triethanolamine and the triethylamine.
The preparation method of described burst of ultraviolel green fluorescence jetted ink comprises the steps:
(1) burst of ultraviolel green fluorescence anti-fake material and sulfur-bearing kind solvent, esters solvent are mixed according to described proportioning, add thermal agitation, temperature is 30 ~ 55 ℃, obtains the A2 component;
(2) synthetic resin is mixed according to described proportioning with ether solvent, nitrogenous kind solvent, stir, obtain the B2 component;
(3) described A2 component and B2 component are mixed, it is transparent fully to be stirred to solution, adds surfactant, pH conditioning agent then, and mixing and stirring obtains this printing ink again.
The heating mixing time of described A2 component is 45 ~ 60min, and the mixing time of described B2 component is 20 ~ 40min, and described A2 component and B2 component are mixed, and mixing time is 30 ~ 60min; Add surfactant, pH conditioning agent, mixing the time of stirring again is 10 ~ 25min.
The pH of this burst of ultraviolel green fluorescence jetted ink is 6.82-8.97, surface tension is 22.36-34.66mN/m, viscosity is 2.43-4.57mPaS, and the printing ink fluorescence intensity is 532.538-629.320cd, can be printed on the various stocks such as art post paperboard, art paper, offset paper, aluminium-foil paper, photo paper, rice paper, during no ultraviolet source irradiation, for colourless or approaching colourless, under specific ultraviolet source irradiation, present bright-coloured green, effect is obvious, can well play antifalse effect.
Above-mentioned burst of ultraviolel blue-fluorescence jetted ink is mixed with and is obtained by burst of ultraviolel blue-fluorescence anti-fake material (UV absorption blue-fluorescence anti-fake material), synthetic resin, solvent, auxiliary agent, and it comprises following composition and weight proportion:
Burst of ultraviolel blue-fluorescence anti-fake material: 0.1-10 part
Synthetic resin: 5-25 part
Esters solvent: 30-60 part
Ether solvent: 15-40 part
Alcohols solvent: 10-30 part
Surfactant: 0.5-3 part
PH conditioning agent: 0.5-3 part
Levelling agent: 0.5-3 part.
Burst of ultraviolel blue-fluorescence anti-fake material among the present invention is for exciting the UV absorption material of (absorption) wavelength at 365 ~ 450nm, emission wavelength ranges is the blue light of 400 ~ 500nm, the printing ink of this anti-fake material preparation is transparence liquid, after being printed on the stock, visual colourless, behind ultra violet lamp, present color.It is disguised strong, can effectively prevent duplicating, counterfeit.
Described burst of ultraviolel blue-fluorescence anti-fake material is a kind of heterocycle organic matter, and name is called 2-[5-bromo-(2-tolysulfonyl amino) phenyl]-6-bromo-4-(3H)-quinazolinone, structure is as follows:
Described burst of ultraviolel blue-fluorescence anti-fake material has higher resistance to ag(e)ing, the hyperfluorescence quantum yield.
Described synthetic resin is one or more the mixture in acrylic resin, epoxy resin, polyurethane resin, vinyl chloride-vinyl acetate resin and the phenolic resins.
Described esters solvent is one or more the mixture in ethyl acetate, butyl ester, 1-Methoxy-2-propyl acetate, propyl acetate, propylene glycol monomethyl ether acetate and the butyl acetate.
Described ether solvent is propylene glycol monomethyl ether, ethylene glycol ethyl ether, diethylene glycol butyl ether and 1, the mixture of one or more in the 4-dioxane.
Described alcohols solvent is ethanol, phenmethylol, ethylene glycol, diethylene glycol, the mixture of one or more in isopropyl alcohol, n-butanol and the glycerine.
Described surfactant is one or more the mixture in organic silicon surfactant, the Organic fluoride surfactant.
Described pH conditioning agent is N, the mixture of one or more in N-NMF, triethanolamine and the triethylamine.
Described levelling agent is
The mixture of one or more among Flow ATF-2 and the TEGO Glide 450.
The preparation method of described burst of ultraviolel blue-fluorescence jetted ink comprises the steps:
(1) burst of ultraviolel blue-fluorescence anti-fake material and esters solvent are mixed according to described proportioning, add thermal agitation, temperature is 35 ~ 55 ℃, obtains the A3 component;
(2) synthetic resin is mixed according to described proportioning with ether solvent, stir, obtain the B3 component;
(3) described A3 component and B3 component are mixed, it is transparent fully to be stirred to solution, adds alcohols solvent, surfactant, pH conditioning agent and levelling agent then, and mixing and stirring obtains this printing ink again.
The heating mixing time of described A3 component is 20 ~ 40min, and the mixing time of described B3 component is 20 ~ 40min, and described A3 component and B3 component are mixed, and mixing time is 30 ~ 60min; Add surfactant, pH conditioning agent, mixing the time of stirring again is 30 ~ 45min.
This environmental protection burst of ultraviolel blue-fluorescence jetted ink performance: pH is 8 ~ 10.5, surface tension is 26 ~ 35mN/m, viscosity is 2 ~ 10mPaS, the printing ink fluorescence intensity is 510 ~ 800cd, can be printed on the various stocks such as art post paperboard, art paper, offset paper, aluminium-foil paper, photo paper, rice paper, effect is fine, the light resistance height.
All can be converted to the operation of RGB pattern according to the CMYK pattern in desktop printer or large-scale air brushing, air brushing goes out the color after the addition.
Three kinds of UV absorption Antiforge fluorescent inks are invisible printing inks, colorful color after can presenting additive color under the specific ultra violet lamp, cooperation by red, green, blue three color ink different proportions, and the stack of emission wavelength in different range, can access the shades of colour effect after the addition.
It is basic material that the present invention adopts red, green, blue three fluorescence jetted ink, adopts the additive process principle in the process of printing, makes it produce how gorgeous color, has not only enriched false proof market, makes anti-fake product have more artistic effect.
Description of drawings
Fig. 1 is the principle schematic of additive process.
Fig. 2 is the principle schematic of subtractive process.
The specific embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used to the present invention is described and be not used in and limit the scope of the invention.In addition, those skilled in the art are to various changes or modification that the present invention made, and these equivalent form of values fall within the application's scope required for protection equally.Proportioning in the embodiment of the invention is by weight.
Additive process method of the present invention is applied on the fluorescence falsification preventing ink, by desktop printer CMYK pattern is converted to the RGB pattern, changes red, green, blue three chromatic ink amounts then, allocates the different colours of image.
The relativity of additive process and subtractive process
Red, green, blue three fluorescence jetted ink is all according to following method preparation in the embodiment of the invention:
(1) red fluorescence jetted ink: ultraviolet excitated red fluorescence falsification preventing material and ether solvent, halogenated alkane solvent are mixed according to described proportioning, add thermal agitation 20 ~ 40min, temperature is 30 ~ 55 ℃, obtains the A1 component; Synthetic resin is mixed according to described proportioning with esters solvent, stir 20 ~ 40min, evenly, obtain the B1 component; Described A1 component and B1 component are mixed, and it is transparent fully to solution to stir 30 ~ 60min, adds surfactant, pH conditioning agent then, mixes and stirs 10 ~ 25min.
(2) green fluorescence jetted ink: burst of ultraviolel green fluorescence anti-fake material and sulfur-bearing kind solvent, esters solvent are mixed according to described proportioning, add thermal agitation 45 ~ 60min, temperature is 30 ~ 55 ℃, obtains the A2 component; Synthetic resin is mixed according to described proportioning with ether solvent, nitrogenous kind solvent, stir 20 ~ 40min, obtain the B2 component; Described A2 component and B2 component are mixed, and it is transparent fully to solution to stir 30 ~ 60min, adds surfactant, pH conditioning agent then, mixes and stirs 10 ~ 25min.
(3) blue-fluorescence jetted ink: burst of ultraviolel blue-fluorescence anti-fake material and esters solvent are mixed according to described proportioning, add thermal agitation 20 ~ 40min, temperature is 35 ~ 55 ℃, obtains the A3 component; Synthetic resin is mixed according to described proportioning with ether solvent, stir 20 ~ 40min, obtain the B3 component; Described A3 component and B3 component are mixed, and it is transparent fully to solution to stir 30 ~ 60min, adds alcohols solvent, surfactant, pH conditioning agent and levelling agent then, mixes and stirs 30 ~ 45min.
Embodiment 1
Ultraviolet excitated red fluorescence falsification preventing material by 0.5 part, 15.5 the acrylic resin B831(of part is commercially available), 38 parts ethyl acetate (analyzing pure): ethyl benzoate (analyzing pure) is the 5:1(weight ratio) the mixed ester kind solvent, the red fluorescence jetted ink A that 23.5 parts propylene glycol monomethyl ether (analyzing pure), 20 parts carrene (analyzing pure), 2 parts organic silicon surfactant (TEGO), 0.5 part triethylamine (analyzing pure) mix.
Commercially available by 1 part of blue ultraviolet excited fluorescence anti-fake material, 15 parts of acrylic resin AZ5391(), 33.5 parts of ethyl acetate (analyzing pure): butyl ester (analyzing pure) is the 1:3(weight ratio) mixed ester kind solvent, 29.5 parts of ethylene glycol ethyl ethers (analyzing pure): 1,4-dioxane (analyzing pure) is the 2:1(weight ratio) compound ether kind solvent, 16.5 parts of ethanol (analyzing pure), 1.5 parts of organic silicon surfactants (TEGO), 1 part of triethanolamine (analyzing pure), 2 parts of blue-fluorescence jetted ink B that levelling agent TEGO Glide 450 mixes.
By 1.5 parts of green ultraviolet excited fluorescence anti-fake materials, 8.5 parts of epoxy resin (commercially available), 40 parts of methyl acetates (analyzing pure): butyl ester (analyzing pure) is the 1:4(weight ratio) mixed ester kind solvent, 23.5 parts of propylene glycol monomethyl ethers (analyzing pure), 11.5 parts of N, dinethylformamide (analyzing pure), 13 parts of dimethyl sulfoxide (DMSO)s (analyzing pure), 1 part of Organic fluoride surfactant (TEGO), 1.5 parts of N, the green fluorescence jetted ink C that N-NMF (analyzing pure) mixes.
By the white fluorescent China ink that the additive process principle uses 100%A+100%B+100%C to obtain being similar to, behind specific ultra violet lamp, can see the approaching white of color on the stock.
Embodiment 2
Ultraviolet excitated red fluorescence falsification preventing material by 4.5 parts, 19.5 part acrylic resin 5391(commercially available): polyurethane resin (commercially available) is the 3:1(weight ratio) hybrid resin, 31.5 part ethyl acetate (analyzing pure): ethyl benzoate (analyzing pure) is the 5:1(weight ratio) the mixed ester kind solvent, 25.5 part 1,4-dioxane (analyzing pure): the diethylene glycol butyl ether is the 1:5(weight ratio) the compound ether kind solvent, 21 parts chloroform (analyzing pure), 0.5 the organic silicon surfactant (TEGO) of part, the red fluorescence jetted ink A that 1 part triethanolamine (analyzing pure) mixes.
By 5 parts of blue ultraviolet excited fluorescence anti-fake materials, 20 parts of vinyl chloride-vinyl acetate resins (commercially available): acrylic resin 831(is commercially available) be the 3:2(weight ratio) hybrid resin, 37 parts of 1-Methoxy-2-propyl acetates (analyzing pure): butyl ester (analyzing pure) is the 5:4(weight ratio) the mixed ester kind solvent, 24.5 part propylene glycol monomethyl ether (analyzing pure), 15 parts of phenmethylols (analyzing pure): ethylene glycol (analyzing pure) is the 3:5(weight ratio) the mixed alcohols solvent, 1.5 part Organic fluoride surfactant (TEGO), 1 part of triethanolamine (analyzing pure), 0.5 part levelling agent
The blue-fluorescence jetted ink B that mixes.
By 7 parts of green ultraviolet excited fluorescence anti-fake materials, 13 parts of polyurethane resins (commercially available), 33 parts of 1-Methoxy-2-propyl acetates (analyzing pure), 30 parts of diethylene glycol butyl ether: 1, the 4-dioxane is the 3:2(weight ratio) compound ether kind solvent, 10 parts of sulfolane (analyzing pure), 10 parts of N, the green fluorescence jetted ink C that N-dimethylacetylamide (analyzing pure), 1.5 parts of Organic fluoride surfactants (TEGO), 1 part of triethylamine (analyzing pure) mix.
Use 50%A+80%B can obtain purple fluorescence by the additive process principle, 50%A+70%C can obtain green-yellow fluorescence, and 50%B+50%C can obtain cyan, behind specific ultra violet lamp, can see the color on the stock.
Embodiment 3
Ultraviolet excitated red fluorescence falsification preventing material by 9 parts, 20 parts epoxy resin (commercially available) 1,35 parts ethyl acetate (analyzing pure): ethyl benzoate (analyzing pure) is the 5:1(weight ratio) the mixed ester kind solvent, 27 parts ethylene glycol ethyl ether: propylene glycol monomethyl ether is the 3:5(weight ratio) the compound ether kind solvent, 15 parts 1, the red fluorescence jetted ink A that 2-dichloroethanes (analyzing pure), 0.5 part organic silicon surfactant (TEGO), 1 part triethanolamine (analyzing pure) mix.
By 3 parts of blue ultraviolet excited fluorescence anti-fake materials, 19.5 part part epoxy resin (commercially available): acrylic resin AZ5361(is commercially available) be the 1:3(weight ratio) hybrid resin, 35 parts of molten propylene glycol monomethyl ether acetates of ester class (analyzing pure): propyl acetate (analyzing pure) is the 1:1(weight ratio) the compound ether kind solvent, 21.5 part propylene glycol monomethyl ether, 20 parts of ethanol (analyzing pure): isopropyl alcohol (analyzing pure) is the 1:1(weight ratio) the mixed alcohols solvent, 0.5 part Organic fluoride surfactant (TEGO), 1.5 part triethanolamine (analyzing pure), 0.5 part
The blue-fluorescence jetted ink B that Flow ATF-2 mixes.
By 5.5 parts of green ultraviolet excited fluorescence anti-fake materials, 13 parts of polyurethane resins (commercially available), 35.5 parts of 1-Methoxy-2-propyl acetates (analyzing pure), 21 parts of ethylene glycol ethyl ethers (analyzing pure), 10 parts of N, the green fluorescence jetted ink C that dinethylformamide (analyzing pure), 14.5 parts of sulfolane (analyzing pure), 2.5 parts of Organic fluoride surfactants (TEGO), 2 parts of pH conditioning agent triethanolamines (analyzing pure) mix.
Use 50%A+70%B+60%C can obtain the blue alternate iridescent of ash by the additive process principle, behind specific ultra violet lamp, can see the color on the stock.
Embodiment 4
The ultraviolet excitated red fluorescence falsification preventing material (hereinafter to be referred as red fluorescence material) that in 25 parts of propylene glycol monomethyl ethers (analyzing pure), 28 parts carrene (analyzing pure), adds 5.5 parts, the heating magnetic agitation is (25min) evenly, temperature is 55 ℃, forms the A component; Commercially available to 14.5 parts of acrylic resin B831() in add 30 parts of ethyl acetate (analyzing pure): ethyl benzoate (analyzing pure) be the 5:1(weight ratio), magnetic agitation even afterwards (35min), formation B component; A, B component are mixed, and it is transparent fully to solution to stir 30min, adds 1 part of organic silicon surfactant (TEGO), 1 part of triethylamine (analyzing pure) pH conditioning agent, mixes and stirs 25min, obtains red fluorescence jetted ink A.
The ultraviolet excitated red fluorescence falsification preventing material that is adopted is by europium chloride, phenanthroline, thienyl three fluoro-1,3-diacetyl and acrylic acid synthesize europium coordination monomer (ECM), aggregate into the polymer (rare earth organic complex) that the side face is connected with the coordination of emitting red light europium with methyl methacrylate (MMA) again, excitation wavelength is 350 ~ 500nm, emission wavelength is 602 ~ 630nm, and structural formula is:
Wherein, x represents the unit polymerization degree n
1, y represents COOH-CH-CHCH
3The unit polymerization degree n
2, n
1And n
2Be positive integer, wherein n
1=7-16, n
2=24-47.Ultraviolet excitated red fluorescence falsification preventing material in following examples all uses this fluorescent material.
To 34.5 parts of ethyl acetate (analyzing pure): butyl ester (analyzing pure) is the 1:3(weight ratio) the mixed ester kind solvent in add 7 parts burst of ultraviolel blue-fluorescence anti-fake material (hereinafter to be referred as blue fluorescent material), the heating magnetic agitation is (25min) evenly, temperature is 55 ℃, forms the A component; Commercially available to 15 parts of acrylic resin AZ5391() in add 31 parts of ethylene glycol ethyl ethers (analyzing pure): 1,4-dioxane (analyzing pure) is the 2:1(weight ratio) the compound ether kind solvent, magnetic agitation is back (30min) evenly, form the B component, it is transparent fully to solution that A, B component are mixed stirring 30min, adds 16 parts of ethanol (analyzing pure), 1 part of organic silicon surfactant (TEGO), 1 part of pH conditioning agent triethylamine (analyzing pure) and 1 part of levelling agent
Mix and stir 45min, obtain blue-fluorescence jetted ink B.
The blue fluorescent material that is adopted, name is called 2-[5-bromo-(2-tolysulfonyl amino) phenyl]-6-bromo-4-(3H)-quinazolinone, structure is as follows:
The excitation wavelength of this blue fluorescent material is 365nm ~ 450nm, and emission wavelength is 400nm ~ 500nm.In following examples, blue fluorescent material all uses this kind fluorescent material.
To 13.5 parts of dimethyl sulfoxide (DMSO)s (analyzing pure), 31.5 parts of methyl acetates (analyzing pure): butyl ester (analyzing pure) is the 1:4(weight ratio) the mixed ester kind solvent in add 2 parts burst of ultraviolel green fluorescence anti-fake material (hereinafter to be referred as green fluorescent material), the heating magnetic agitation is even, temperature is 30 ℃, stir 45min, form the A component; In 15.5 parts of epoxy resin (commercially available), add 11 parts of N, N-NMF (analyzing pure), 26.5 parts of propylene glycol monomethyl ethers (analyzing pure) ether solvent, wherein synthetic resin is, after magnetic agitation is even, form the B component, it is transparent fully to solution that A, B component are mixed stirring 30min, adds 1 part of Organic fluoride surfactant (TEGO), 0.5 part of pH conditioning agent triethanolamine (analyzing pure).Mix and stir 20min, obtain green fluorescence jetted ink C.
Green fluorescent material chemical name: 6-chloro-2-[5-chloro-2-(4-biphenyl sulfonamido)] phenyl-4-benzoxazinone, absorbing wavelength is 300 ~ 400nm, and emission wavelength is 500 ~ 600nm, and concrete structure is:
In following examples, green fluorescent material all uses this kind fluorescent material.
Use 50%A+80%B can obtain purple fluorescence by the additive process principle, 50%A+70%C can obtain green-yellow fluorescence, and 50%B+50%C can obtain cyan, behind specific ultra violet lamp, can see the color on the stock.
Embodiment 5
To 32 part 1,4-dioxane (analyzing pure): the diethylene glycol butyl ether is the 1:5(weight ratio) the halogenated alkane mixed solvent, 21.5 the red fluorescence material that adds 1.5 parts in the chloroform (analyzing pure) of part, heating magnetic agitation (30min) is even, temperature is 40 ℃, form the A component, commercially available to 16.5 parts of acrylic resin 5391(): polyurethane resin (commercially available) is the 3:1(weight ratio) in add 28 parts of ethyl acetate (analyzing pure): ethyl benzoate (analyzing pure) is the 5:1(weight ratio), after magnetic agitation (35min) is even, form the B component, A, it is transparent fully to solution that the B component is mixed stirring 30min, add 1.5 parts of organic silicon surfactants (TEGO), 0.5 part pH conditioning agent triethanolamine (analyzing pure), mix and stir 10min, obtain red fluorescence jetted ink A.
To 45 parts of 1-Methoxy-2-propyl acetates (analyzing pure): butyl ester (analyzing pure) is the 5:4(weight ratio) the mixed ester kind solvent in add 4 parts blue fluorescent material, 30min is even for the heating magnetic agitation, temperature is 45 ℃, forms the A component; To 10 parts of vinyl chloride-vinyl acetate resins (commercially available): acrylic resin 831(is commercially available) be the 3:2(weight ratio) hybrid resin in add 25 parts of propylene glycol monomethyl ethers, after magnetic agitation 35min is even, form the B component, it is transparent fully to solution that A, B component are mixed stirring 50min, add 15 parts of ethanol (analyzing pure), 0.5 part of organic silicon surfactant (TEGO), 1 part of pH conditioning agent triethanolamine (analyzing pure) and 2 parts of levelling agent TEGO Glide450, mix and stir 30min, obtain blue-fluorescence jetted ink B.
To 10 parts of sulfolane (analyzing pure): dimethyl sulfoxide (DMSO) (analyzing pure) is the 1:1(weight ratio) mixing sulfur-bearing kind solvent, 20 parts of 1-Methoxy-2-propyl acetates (analyzing pure): ethyl benzoate (analyzing pure) is the 3:1(weight ratio) the mixed ester kind solvent in, the green fluorescent material that adds 0.5 part, the heating magnetic agitation is (60min) evenly, temperature is 45 ℃, forms the A component; In 30 parts of polyurethane resins (commercially available), add 15 parts of formamides (analyzing pure) and 40 parts of ethylene glycol ethyl ethers (analyzing pure), after magnetic agitation 40min is even, form the B component, it is transparent fully to solution that A, B component are mixed stirring 30min, adds 3 parts of Organic fluoride surfactants (TEGO), 3 parts of pH conditioning agent triethylamines (analyzing pure).Mix and stir 25min, obtain green fluorescence jetted ink C.
Use 50%A+70%B+60%C can obtain the blue alternate iridescent of ash by the additive process principle, behind specific ultra violet lamp, can see the color on the stock.
Embodiment 6
To 26.5 parts of ethylene glycol ethyl ethers: propylene glycol monomethyl ether is the 3:5(weight ratio) the ethers mixed solvent, 28 parts 1, the red fluorescence material that adds 8.5 parts in the 2-dichloroethanes (analyzing pure), heating magnetic agitation (35min) is even, temperature is 30 ℃, form the A component, add 26.5 parts of ethyl acetate (analyzing pure) in 13.5 parts of epoxy resin (commercially available): ethyl benzoate (analyzing pure) is the 5:1(weight ratio), after magnetic agitation (35min) is even, form the B component, A, it is transparent fully to solution that the B component is mixed stirring 45min, add 2 parts of organic silicon surfactants (TEGO), 2 parts of pH conditioning agent triethanolamines (analyzing pure), mix and stir 15min, obtain red fluorescence jetted ink A.
To 30 parts of ethyl acetate: propylene glycol monomethyl ether acetate is the 2:1(weight ratio) the mixed ester kind solvent in, add 3.5 parts blue fluorescent material, 40min is even for the heating magnetic agitation, temperature is 40 ℃, forms the A component; In 20 parts of epoxy resin (commercially available), add 15 parts of propylene glycol monomethyl ether diethylene glycol butyl ether, after magnetic agitation 20min is even, form the B component, it is transparent fully to solution that A, B component are mixed stirring 60min, adds 10 parts of ethanol (analyzing pure), 0.5 part of Organic fluoride surfactant (TEGO), 0.5 part of pH conditioning agent triethanolamine (analyzing pure) and 0.5 part of levelling agent
Flow ATF-2 mixes and stirs 30min, obtains blue-fluorescence jetted ink B.
To 30 parts of dimethyl sulfoxide (DMSO)s (analyzing pure), 50 parts of methyl formates (analyzing pure): 1-Methoxy-2-propyl acetate (analyzing pure) is the 4:1(weight ratio) in add 2.5 parts green fluorescent material, the heating magnetic agitation is (45min) evenly, temperature is 55 ℃, forms the A component; Add 30 parts of N-methyl pyrrolidones (analyzing pure) in 5 parts of vinyl chloride-vinyl acetate resins (commercially available): N-N dimethylacetylamide (analyzing pure) is the 1:2(weight ratio) the nitrogenous kind solvent of mixing and 15 part 1,4 dioxane (analyzing pure), after magnetic agitation 20min is even, form the B component, it is transparent fully to solution that A, B component are mixed stirring 30min, adds 0.5 part of organic silicon surfactant (TEGO), 0.5 part of pH conditioning agent triethylamine (analyzing pure).Mix and stir 10min, obtain green fluorescence jetted ink C.
Use 50%A+70%B+60%C can obtain the blue alternate iridescent of ash by the additive process principle, behind specific ultra violet lamp, can see the color on the stock.
Embodiment 7
To 29 parts of ethylene glycol ethyl ethers: propylene glycol monomethyl ether is the 3:5(weight ratio) the ethers mixed solvent, 25.5 1 of part, the red fluorescence material that adds 1.5 parts in the 2-dichloroethanes (analyzing pure), the heating magnetic agitation is (40min) evenly, temperature is 45 ℃, form the A component, add 26.5 parts of ethyl acetate (analyzing pure) in 15.5 parts of vinyl chloride-vinyl acetate resins (commercially available): ethyl benzoate (analyzing pure) is the 5:1(weight ratio), after magnetic agitation (35min) is even, form the B component, A, it is transparent fully to solution that the B component is mixed stirring 50min, add 0.5 part of organic silicon surfactant (TEGO), 1 part of pH conditioning agent N, dinethylformamide (analyzing pure), mix and stir 20min, obtain red fluorescence jetted ink A.
To 37.5 parts of 1-Methoxy-2-propyl acetates (analyzing pure): butyl ester (analyzing pure) is the 5:4(weight ratio) the mixed ester kind solvent in add 3 parts blue fluorescent material, 35min is even for the heating magnetic agitation, temperature is 35 ℃, forms the A component; To 12 parts of vinyl chloride-vinyl acetate resins (commercially available): acrylic resin 831(is commercially available) be the 3:2(weight ratio) hybrid resin in add 27 parts of propylene glycol monomethyl ethers (analyzing pure), after magnetic agitation 35min is even, form the B component, it is transparent fully to solution that A, B component are mixed stirring 45min, add 18 parts of phenmethylols (analyzing pure): ethylene glycol (analyzing pure) is the 3:5(weight ratio), 2 parts of Organic fluoride surfactants (TEGO), 1.5 parts of pH conditioning agent N, dinethylformamide (analyzing pure) and 1 part of levelling agent
Stir 40min for mixing, obtain blue-fluorescence jetted ink B.
The green fluorescent material that in 17.5 parts of sulfolane (analyzing pure), 34.5 parts of 1-Methoxy-2-propyl acetates (analyzing pure), adds 0.5 part, the heating magnetic agitation is even, and temperature is 55 ℃, stirs 50min, forms the A component; In 15.5 parts of polyurethane resins (commercially available), add 13.5 parts of N, N-dimethylacetylamide (analyzing pure), 17 parts of ethylene glycol ethyl ethers (analyzing pure), after magnetic agitation 30min is even, form the B component, it is transparent fully to solution that A, B component are mixed stirring 40min, adds 1 part of organic silicon surfactant (TEGO), 1 part of pH conditioning agent triethylamine (analyzing pure).Mix and stir 25min, obtain green fluorescence jetted ink C.
By the white fluorescent China ink that the additive process principle uses 100%A+100%B+100%C to obtain being similar to, behind specific ultra violet lamp, can see the approaching white of color on the stock.
Embodiment 8
To 40 parts of ethylene glycol ethyl ethers, the red fluorescence material that adds 0.1 part in 5 parts the carbon tetrachloride (analyzing pure), the heating magnetic agitation is (20min) evenly, temperature is 45 ℃, form the A component, in 30 parts of phenolic resins (commercially available), add 50 parts of methyl formates (analyzing pure), after magnetic agitation (40min) is even, form the B component, A, it is transparent fully to solution that the B component is mixed stirring 40min, add 3 parts of organic silicon surfactants (TEGO), 1 part of pH conditioning agent N, dinethylformamide (analyzing pure) mixes and stirs 15min, obtains red fluorescence jetted ink A.
The blue fluorescent material that in 60 parts of 1-Methoxy-2-propyl acetates (analyzing pure), adds 0.1 part, 40min is even for the heating magnetic agitation, and temperature is 35 ℃, forms the A component; In 25 parts of vinyl chloride-vinyl acetate resins (commercially available), add 4027 parts of propylene glycol monomethyl ethers (analyzing pure), after magnetic agitation 40min is even, form the B component, it is transparent fully to solution that A, B component are mixed stirring 60min, add 30 parts of phenmethylols (analyzing pure), 3 parts of Organic fluoride surfactants (TEGO), 3 parts of pH conditioning agent N, dinethylformamide (analyzing pure) and 3 parts of levelling agents
Stir 45min for mixing, obtain blue-fluorescence jetted ink B.
To 27.5 parts of sulfolane (analyzing pure): dimethyl sulfoxide (DMSO) (analyzing pure) is the 3:2(weight ratio) mixing sulfur-bearing kind solvent, 23.5 parts of methyl acetates (analyzing pure): butyl ester (analyzing pure) is the 2:1(weight ratio) the mixed ester kind solvent in add 10 parts green fluorescent material, the heating magnetic agitation is (45min) evenly, temperature is 45 ℃, forms the A component; To 25 parts of epoxy resin (commercially available): vinyl chloride-vinyl acetate resin (commercially available) is the 3:2(weight ratio) hybrid resin in add 21 parts of diethylene glycol butyl ether (analyzing pure), 13 parts of propylene glycol monomethyl ethers (analyzing pure), after magnetic agitation 35min is even, form the B component, it is transparent fully to solution that A, B component are mixed stirring 50min, add 1.5 parts of organic silicon surfactants (TEGO), 0.5 part of pH conditioning agent N, N-NMF (analyzing pure).Mix and stir 20min, obtain green fluorescence jetted ink C.
Use 50%A+80%B can obtain purple fluorescence by the additive process principle, 50%A+70%C can obtain green-yellow fluorescence, and 50%B+50%C can obtain cyan, behind specific ultra violet lamp, can see the color on the stock.
Embodiment 9
To 20 parts of diethylene glycol butyl ether, the red fluorescence material that adds 10 parts in 40 parts the chloroform (analyzing pure), the heating magnetic agitation is (40min) evenly, temperature is 45 ℃, form the A component, add 20 parts of methyl acetates (analyzing pure) in 5 parts of epoxy resin (commercially available): butyl ester (analyzing pure) is the 1:4(weight ratio) the mixed ester kind solvent, after magnetic agitation (20min) is even, form the B component, A, it is transparent fully to solution that the B component is mixed stirring 30min, add 2 parts of Organic fluoride surfactants (TEGO), 3 parts of pH conditioning agent triethylamines (analyzing pure), mix and stir 25min, obtain red fluorescence jetted ink A.
To 55 parts of propylene glycol monomethyl ether acetates (analyzing pure): propyl acetate (analyzing pure) is the 1:1(weight ratio) the mixed ester kind solvent in, add 10 parts blue fluorescent material, 40min is even for the heating magnetic agitation, temperature is 40 ℃, forms the A component; To 20 parts of epoxy resin (commercially available): acrylic resin AZ5361(is commercially available) be the 1:3(weight ratio) hybrid resin in add 10 parts of propylene glycol monomethyl ethers, after magnetic agitation 30min is even, form the B component, A, B component mix that to stir 50min transparent fully to solution, and adds 10.5 parts of ethanol (analyzing pure): isopropyl alcohol (analyzing pure) is the 1:1(weight ratio) mixed alcohols solvent, 0.5 part of Organic fluoride surfactant (TEGO), 0.5 part of pH conditioning agent triethanolamine (analyzing pure) and 0.5 part of levelling agent
Flow ATF-2 mixes and stirs 35min, obtains blue-fluorescence jetted ink B.
The green fluorescent material that in 20 parts of sulfolane (analyzing pure), 15 parts of 1-Methoxy-2-propyl acetates (analyzing pure), adds 0.1 part, the heating magnetic agitation is even, and temperature is 45 ℃, stirs 60min, forms the A component; In 19.5 parts of polyurethane resins (commercially available), add 21.5 parts of ethylene glycol ethyl ethers (analyzing pure), 19 parts of diethylene glycol butyl ether: 1, the 4-dioxane is the 3:2(weight ratio) the compound ether kind solvent, after magnetic agitation 30min is even, form the B component, it is transparent fully to solution that A, B component are mixed stirring 60min, add 2 parts of Organic fluoride surfactants (TEGO), 1 part of pH conditioning agent N, dinethylformamide (analyzing pure).Mix and stir 10min, obtain green fluorescence jetted ink C.
By the white fluorescent China ink that the additive process principle uses 100%A+100%B+100%C to obtain being similar to, behind specific ultra violet lamp, can see the approaching white of color on the stock.
Three kinds of UV absorption Antiforge fluorescent inks are invisible printing inks, colorful color after can presenting additive color under the specific ultra violet lamp, cooperation by red, green, blue three color ink different proportions, and the stack of emission wavelength in different range, can access the shades of colour effect after the addition.
Red, blue, green three kinds of UV absorption fluorescence jetted inks of the present invention and import (according to sign indicating number bodyguard 5553) UV absorption fluorescence jetted ink are printed simultaneously, the present invention that contrast obtains and the print pattern of import fluorescence jetted ink, can see printing ink brightness height of the present invention, bright-colored, effective, and the brightness of Japanese red fluorescence jetted ink red ink is low, and color is not bright-coloured.
In other embodiments of the invention, each component of printing ink can adopt the concrete component of enumerating, be different from the embodiment of the invention in summary of the invention, carry out different collocation and combination, all can obtain the performance and the effect of printing ink of the present invention.Printing ink of the present invention can be printed on the various stocks such as art post paperboard, art paper, offset paper, aluminium-foil paper, photo paper, rice paper, during no ultraviolet source irradiation, for colourless or approaching colourless, under specific ultraviolet source irradiation, present bright-coloured redness, effect is obvious, can well play antifalse effect.
Claims (10)
1. additive process printing formation method is characterized in that: adopts ultraviolet excitated red, green and blue-fluorescence jetted ink, the imaging of employing additive process principle obtains color fluorescent image in the process of printing.
2. additive process printing formation method according to claim 1, it is characterized in that: described ultraviolet excitated red fluorescence jetted ink comprises following composition and weight proportion:
Ultraviolet excitated red fluorescence falsification preventing material: 0.1 ~ 10 part
Synthetic resin: 5 ~ 30 parts
Esters solvent: 20 ~ 50 parts
Ether solvent: 20 ~ 40 parts
Halogenated alkane solvent: 5 ~ 40 parts
Surfactant: 0.5 ~ 3 part
PH conditioning agent: 0.5 ~ 3 part.
3. additive process printing formation method according to claim 2, it is characterized in that: the excitation wavelength of described ultraviolet excitated red fluorescence falsification preventing material is 350 ~ 500nm, emission wavelength is 590 ~ 650nm.
4. additive process printing formation method according to claim 2, it is characterized in that: described synthetic resin is one or more in acrylic resin, epoxy resin, polyurethane resin, vinyl chloride-vinyl acetate resin and the phenolic resins; Described esters solvent is one or more in ethyl acetate, methyl formate, butyl ester, 1-Methoxy-2-propyl acetate, methyl acetate, ethyl butyrate, propylene glycol monomethyl ether acetate and the ethyl benzoate; Described ether solvent is propylene glycol monomethyl ether, ethylene glycol ethyl ether, diethylene glycol butyl ether and 1, one or more in the 4-dioxane; Described halogenated alkane solvent is carrene, chloroform, carbon tetrachloride and 1, one or more in the 2-dichloroethanes; Described surfactant is one or more in organic silicon surfactant and the Organic fluoride surfactant; Described pH conditioning agent is N, one or more in N-NMF, triethanolamine and the triethylamine.
5. additive process printing formation method according to claim 1, it is characterized in that: described burst of ultraviolel green fluorescence jetted ink comprises following composition and weight proportion:
Burst of ultraviolel green fluorescence anti-fake material: 0.1 ~ 10 part
Synthetic resin: 5 ~ 30 parts
Esters solvent: 15 ~ 50 parts
Ether solvent: 15 ~ 40 parts
Nitrogenous kind solvent: 10 ~ 30 parts
Sulfur-bearing kind solvent: 10 ~ 30 parts
Surfactant: 0.5 ~ 3 part
PH conditioning agent: 0.5 ~ 3 part.
6. additive process printing formation method according to claim 5, it is characterized in that: the excitation wavelength of described burst of ultraviolel green fluorescence anti-fake material is 220 ~ 450nm, emission wavelength is 500 ~ 600nm.
7. additive process printing formation method according to claim 5, it is characterized in that: described synthetic resin is one or more in acrylic resin, epoxy resin, polyurethane resin, vinyl chloride-vinyl acetate resin and the phenolic resins; Described esters solvent is one or more in ethyl acetate, methyl formate, butyl ester, 1-Methoxy-2-propyl acetate, methyl acetate, ethyl butyrate, propylene glycol monomethyl ether acetate and the ethyl benzoate; Described ether solvent is propylene glycol monomethyl ether, ethylene glycol ethyl ether, diethylene glycol butyl ether and 1, one or more in the 4-dioxane; Described nitrogenous kind solvent is N, N-NMF, N, one or more in N-dimethylacetylamide, N-N-methyl 2-pyrrolidone N-and the formamide; Described sulfur-bearing kind solvent is one or both in dimethyl sulfoxide (DMSO) and the sulfolane; Described surfactant is one or more in organic silicon surfactant and the Organic fluoride surfactant; Described pH conditioning agent is N, one or more in dinethylformamide, triethanolamine and the triethylamine.
8. additive process printing formation method according to claim 1, it is characterized in that: described burst of ultraviolel blue-fluorescence jetted ink comprises following composition and weight proportion:
Burst of ultraviolel blue-fluorescence anti-fake material: 0.1-10 part
Synthetic resin: 5-25 part
Esters solvent: 30-60 part
Ether solvent: 15-40 part
Alcohols solvent: 10-30 part
Surfactant: 0.5-3 part
PH conditioning agent: 0.5-3 part
Levelling agent: 0.5-3 part.
9. additive process printing formation method according to claim 7, it is characterized in that: the excitation wavelength of described burst of ultraviolel blue-fluorescence anti-fake material is 365-450nm, emission wavelength ranges is 400 ~ 500nm; Described synthetic resin is one or more in acrylic resin, epoxy resin, polyurethane resin, vinyl chloride-vinyl acetate resin and the phenolic resins; Described esters solvent is one or more in ethyl acetate, butyl ester, 1-Methoxy-2-propyl acetate, propyl acetate, propylene glycol monomethyl ether acetate and the butyl acetate; Described ether solvent is propylene glycol monomethyl ether, ethylene glycol ethyl ether, diethylene glycol butyl ether and 1, one or more in the 4-dioxane; Described alcohols solvent is ethanol, phenmethylol, ethylene glycol, diethylene glycol, one or more in isopropyl alcohol, n-butanol and the glycerine; Described surfactant is one or more in organic silicon surfactant, the Organic fluoride surfactant; Described pH conditioning agent is N, one or more in dinethylformamide, triethanolamine and the triethylamine; Described levelling agent is one or more among BYKETOL-SPECIAL, BYKETOL-OK, TEGO Flow ATF-2 and the TEGO Glide 450.
10. each described additive process is printed formation method among the claim 1-9, it is characterized in that: adopt the operation of RGB pattern on desktop printer or large-scale air brushing instrument, air brushing goes out the image after the addition.
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104691127A (en) * | 2015-02-10 | 2015-06-10 | 首都师范大学 | Method for implementing lifelong anti-counterfeiting of commodities |
| CN106189491A (en) * | 2016-07-12 | 2016-12-07 | 桐城市凌志彩印包装有限责任公司 | A kind of antifalse ink |
| CN108604133A (en) * | 2016-02-09 | 2018-09-28 | 曼彻斯特大学 | The improvement that image is formed |
| CN109385142A (en) * | 2018-09-29 | 2019-02-26 | 广东轻工职业技术学院 | A kind of fluorescent ink and preparation method thereof and discrimination method |
| CN110079160A (en) * | 2019-05-29 | 2019-08-02 | 苏州大学 | It is a kind of based on ternary the fluorescence falsification preventing ink of energy transfer, preparation method and applications three times |
| CN111002733A (en) * | 2019-12-23 | 2020-04-14 | 北京印刷学院 | Method for reducing color difference of printing color of ultraviolet fluorescent ink |
| CN111391539A (en) * | 2020-04-10 | 2020-07-10 | 公安部第一研究所 | Card containing multicolor fluorescent pattern and manufacturing method thereof |
| CN111683818A (en) * | 2019-01-11 | 2020-09-18 | 中钞光华印制有限公司 | Manufacturing method of multicolor fluorescent product, multicolor fluorescent product and fluorescent handicraft |
| CN112063235A (en) * | 2020-06-09 | 2020-12-11 | 广州市恒远彩印有限公司 | RGB invisible fluorescent ink and preparation method thereof |
| CN115027161A (en) * | 2022-07-27 | 2022-09-09 | 河南省邮电科技有限公司 | Multicolor overprinting color printing method under fluorescent lamp |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5837042A (en) * | 1996-06-10 | 1998-11-17 | Videojet Systems International, Inc. | Invisible fluorescent jet ink |
| CN1230973A (en) * | 1996-07-26 | 1999-10-06 | 录象射流系统国际有限公司 | Jet ink composition |
| US6022908A (en) * | 1998-04-22 | 2000-02-08 | Hewlett-Packard Company | Printing liquids for improved print quality |
-
2012
- 2012-10-24 CN CN201210408542.3A patent/CN103223795B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5837042A (en) * | 1996-06-10 | 1998-11-17 | Videojet Systems International, Inc. | Invisible fluorescent jet ink |
| CN1230973A (en) * | 1996-07-26 | 1999-10-06 | 录象射流系统国际有限公司 | Jet ink composition |
| US6022908A (en) * | 1998-04-22 | 2000-02-08 | Hewlett-Packard Company | Printing liquids for improved print quality |
Non-Patent Citations (2)
| Title |
|---|
| 梁丽娟等: "蓝色荧光喷墨油墨的配方设计", 《中国印刷与包装研究》, vol. 2, no. 1, 30 November 2010 (2010-11-30), pages 381 - 382 * |
| 裴桂范: "丝网印刷油墨第一部分──组份与配色", 《丝网印刷》, no. 02, 25 April 1994 (1994-04-25), pages 37 - 40 * |
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| US11100619B2 (en) | 2016-02-09 | 2021-08-24 | The University Of Manchester | Image formation |
| CN108604133A (en) * | 2016-02-09 | 2018-09-28 | 曼彻斯特大学 | The improvement that image is formed |
| CN106189491A (en) * | 2016-07-12 | 2016-12-07 | 桐城市凌志彩印包装有限责任公司 | A kind of antifalse ink |
| CN109385142A (en) * | 2018-09-29 | 2019-02-26 | 广东轻工职业技术学院 | A kind of fluorescent ink and preparation method thereof and discrimination method |
| CN109385142B (en) * | 2018-09-29 | 2021-12-14 | 广东轻工职业技术学院 | Fluorescent ink and preparation method and identification method thereof |
| CN111683818B (en) * | 2019-01-11 | 2022-03-18 | 中钞光华印制有限公司 | Manufacturing method of multicolor fluorescent product, multicolor fluorescent product and fluorescent handicraft |
| CN111683818A (en) * | 2019-01-11 | 2020-09-18 | 中钞光华印制有限公司 | Manufacturing method of multicolor fluorescent product, multicolor fluorescent product and fluorescent handicraft |
| CN110079160A (en) * | 2019-05-29 | 2019-08-02 | 苏州大学 | It is a kind of based on ternary the fluorescence falsification preventing ink of energy transfer, preparation method and applications three times |
| CN110079160B (en) * | 2019-05-29 | 2022-09-09 | 苏州大学 | Fluorescent anti-counterfeiting ink based on ternary triple energy transfer, and preparation method and application thereof |
| CN111002733B (en) * | 2019-12-23 | 2021-11-05 | 北京印刷学院 | Method for reducing color difference of printing color of ultraviolet fluorescent ink |
| CN111002733A (en) * | 2019-12-23 | 2020-04-14 | 北京印刷学院 | Method for reducing color difference of printing color of ultraviolet fluorescent ink |
| CN111391539A (en) * | 2020-04-10 | 2020-07-10 | 公安部第一研究所 | Card containing multicolor fluorescent pattern and manufacturing method thereof |
| CN112063235A (en) * | 2020-06-09 | 2020-12-11 | 广州市恒远彩印有限公司 | RGB invisible fluorescent ink and preparation method thereof |
| CN115027161A (en) * | 2022-07-27 | 2022-09-09 | 河南省邮电科技有限公司 | Multicolor overprinting color printing method under fluorescent lamp |
| CN115027161B (en) * | 2022-07-27 | 2024-04-05 | 河南省邮电科技有限公司 | Color printing method for multicolor overprinting under fluorescent lamp |
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