CN105295310A - Green environment-friendly plasticizer - Google Patents
Green environment-friendly plasticizer Download PDFInfo
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- CN105295310A CN105295310A CN201510771909.1A CN201510771909A CN105295310A CN 105295310 A CN105295310 A CN 105295310A CN 201510771909 A CN201510771909 A CN 201510771909A CN 105295310 A CN105295310 A CN 105295310A
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- softening agent
- environmental type
- fatty acid
- agent according
- biological
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Abstract
The invention discloses a green environment-friendly plasticizer. The green environment-friendly plasticizer is directed at the defects of conventional plasticizers and prepared from the following preparation raw materials: a citrate, a biological plasticizer, a glycerin derivative, o-phthalic anhydride, a fatty acid ester, a catalyst, a stabilizing agent, etc. The green environment-friendly plasticizer has the advantages of reproducibility, stable quality, low cost, no toxicity and harm and high speedup efficiency; a product using the plasticizer is advantageous in the aspects of hardness and tensile strength; and the green environment-friendly plasticizer makes a breakthrough to defects of traditional plasticizers and has a good practical value.
Description
Technical field
The present invention relates to a kind of softening agent, especially relate to a kind of environmental type softening agent.
Background technology
The purposes of softening agent is quite extensive, not only for numerous industries such as rubber, plastics film, plastics, rubber-plastics material, wrapping material, expanding the application of renewal as organic synthesis intermediate and solvent, tensio-active agent, biochemicals etc. simultaneously, relate to the interpenetrative field of multiple intersection, far-reaching influence is produced to the development of all trades and professions.
Just so apply widely, just more and more higher to the requirement of softening agent, under the overall situation of type energy environment protection type society of advocating thriftiness, environmental type softening agent is the necessary choice adapting to a kind of cleaner production that future technical advances trend, economic needs and future market are developed.
Summary of the invention
Goal of the invention: in order to solve in prior art existing problem, the present invention proposes and a kind ofly have recyclability, stay in grade, with low cost, nontoxic environmental type softening agent.
Technical scheme: to achieve these objectives, the present invention takes following technical scheme:
A kind of environmental type softening agent, comprise the raw materials of following component according to weighing scale: citric acid ester type 15-20 part, biological softening agent 10-13 part, glycerol derivative 3-6 part, phthalic anhydride 30-35 part, fatty acid ester 2-6 part, catalyzer 3-8 part, stablizer 4-10 part, wherein stablizer is epoxy compounds, both sodium carbonate mass ratio is the mixture of 3:1.
Further, described citrate is tributyl citrate, tripentyl citrates, citric acid three ester in the ninth of the ten Heavenly Stems, tributyl acetylcitrate, acetyl tributyl citrate three one in ester.
Further, described biological softening agent is one or more in zinc oxide, magnesium oxide, calcium oxide.
Further, described glycerol derivative is biological glycerol or three sodium-acetate glyceryl ester.
Further, described fatty acid ester is sucrose fatty acid polyester.
Further, described catalyzer is titanium dioxide.
Further, described epoxy compounds is the one in epoxy linseed oil, ESO, EPSO.
Beneficial effect: a kind of environmental type softening agent provided by the invention, for the defect that existing softening agent exists, by citric acid ester type, biological softening agent, glycerol derivative, phthalic anhydride, fatty acid ester, catalyzer, the raw materials such as stablizer are formed, environmental type softening agent of the present invention, not only there is recyclability, stay in grade, with low cost, nontoxic, and there is higher speedup efficiency, product after using hardness again, tensile strength all has certain advantage, breach conventional plasticizers and use the upper defect existed, there is very strong practical value.
Embodiment
Embodiment 1:
A kind of environmental type softening agent, comprise the raw materials of following component according to weighing scale: citric acid ester type 15 parts, 10 parts, biological softening agent, glycerol derivative 3 parts, phthalic anhydride 30 parts, fatty acid ester 2 parts, catalyzer 3 parts, stablizer 4 parts, wherein stablizer is epoxy compounds, both sodium carbonate mass ratio is the mixture of 3:1.
Wherein, described citrate is tributyl citrate; Described biological softening agent is zinc oxide, magnesium oxide mass ratio is the mixture of 2:1; Described glycerol derivative is biological glycerol; Described fatty acid ester is sucrose fatty acid polyester; Described catalyzer is titanium dioxide; Described epoxy compounds is epoxy linseed oil.
Embodiment 2:
A kind of environmental type softening agent, comprise the raw materials of following component according to weighing scale: citric acid ester type 20 parts, 13 parts, biological softening agent, glycerol derivative 6 parts, phthalic anhydride 35 parts, fatty acid ester 6 parts, catalyzer 8 parts, stablizer 10 parts, wherein stablizer is epoxy compounds, both sodium carbonate mass ratio is the mixture of 3:1.
Wherein, described citrate is citric acid three ester in the ninth of the ten Heavenly Stems; Described biological softening agent is magnesium oxide, calcium oxide mass ratio is the mixture of 3:2; Described glycerol derivative is three sodium-acetate glyceryl ester; Described fatty acid ester is sucrose fatty acid polyester; Described catalyzer is titanium dioxide; Described epoxy compounds is ESO.
Embodiment 3:
A kind of environmental type softening agent, comprise the raw materials of following component according to weighing scale: citric acid ester type 18 parts, 12 parts, biological softening agent, glycerol derivative 5 parts, phthalic anhydride 33 parts, fatty acid ester 4 parts, catalyzer 5 parts, stablizer 7 parts, wherein stablizer is epoxy compounds, both sodium carbonate mass ratio is the mixture of 3:1.
Wherein, described citrate is tributyl acetylcitrate; Described biological softening agent is zinc oxide, calcium oxide mass ratio is the mixture of 2:1; Described glycerol derivative is biological glycerol; Described fatty acid ester is sucrose fatty acid polyester; Described catalyzer is titanium dioxide; Described epoxy compounds is EPSO.
The preparation method of the traditionally softening agent of the composition according to above-described embodiment 1-3 is prepared into softening agent, and apply it in rubber, plastics film, plastics, rubber-plastics material, wrapping material and go, various finished product all meets national standard and hygienic standard through inspection.
Use a kind of environmental type softening agent of above-described embodiment 1-3, comparatively conventional plasticizers, not only there is recyclability, stay in grade, with low cost, nontoxic, and there is higher speedup efficiency, product after using again hardness, tensile strength all has certain advantage, breaches conventional plasticizers and uses the upper defect existed, have very strong practical value, adapt to the demand of a kind of cleaner production that future technical advances trend, economic needs and future market are developed, replicability is strong.
It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also make some improvement, these improvement also should be considered as protection scope of the present invention.
Claims (7)
1. an environmental type softening agent, it is characterized in that the raw materials comprising following component according to weighing scale: citric acid ester type 15-20 part, biological softening agent 10-13 part, glycerol derivative 3-6 part, phthalic anhydride 30-35 part, fatty acid ester 2-6 part, catalyzer 3-8 part, stablizer 4-10 part, wherein stablizer is epoxy compounds, both sodium carbonate mass ratio is the mixture of 3:1.
2. environmental type softening agent according to claim 1, is characterized in that: described citrate is tributyl citrate, tripentyl citrates, citric acid three ester in the ninth of the ten Heavenly Stems, tributyl acetylcitrate, acetyl tributyl citrate three one in ester.
3. environmental type softening agent according to claim 1, is characterized in that: described biological softening agent is one or more in zinc oxide, magnesium oxide, calcium oxide.
4. environmental type softening agent according to claim 1, is characterized in that: described glycerol derivative is biological glycerol or three sodium-acetate glyceryl ester.
5. environmental type softening agent according to claim 1, is characterized in that: described fatty acid ester is sucrose fatty acid polyester.
6. environmental type softening agent according to claim 1, is characterized in that: described catalyzer is titanium dioxide.
7. environmental type softening agent according to claim 1, is characterized in that: described epoxy compounds is the one in epoxy linseed oil, ESO, EPSO.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510771909.1A CN105295310A (en) | 2015-11-11 | 2015-11-11 | Green environment-friendly plasticizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510771909.1A CN105295310A (en) | 2015-11-11 | 2015-11-11 | Green environment-friendly plasticizer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105295310A true CN105295310A (en) | 2016-02-03 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510771909.1A Pending CN105295310A (en) | 2015-11-11 | 2015-11-11 | Green environment-friendly plasticizer |
Country Status (1)
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| CN (1) | CN105295310A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634673A (en) * | 2016-09-09 | 2017-05-10 | 聊城市瑞邦塑料助剂有限公司 | Environment-friendly plasticizer and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005048989A1 (en) * | 2003-11-14 | 2005-06-02 | Alza Corporation | Excipients in drug delivery vehicles |
| US20080026959A1 (en) * | 2006-07-25 | 2008-01-31 | Halliburton Energy Services, Inc. | Degradable particulates and associated methods |
| CN101367731A (en) * | 2008-07-29 | 2009-02-18 | 中国林业科学研究院林产化学工业研究所 | C22 triacid triester elasticizer and method of preparing the same |
| CN103788532A (en) * | 2013-09-28 | 2014-05-14 | 青岛三立新源电器有限公司 | Environment-friendly plasticizer composition |
-
2015
- 2015-11-11 CN CN201510771909.1A patent/CN105295310A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005048989A1 (en) * | 2003-11-14 | 2005-06-02 | Alza Corporation | Excipients in drug delivery vehicles |
| US20080026959A1 (en) * | 2006-07-25 | 2008-01-31 | Halliburton Energy Services, Inc. | Degradable particulates and associated methods |
| CN101367731A (en) * | 2008-07-29 | 2009-02-18 | 中国林业科学研究院林产化学工业研究所 | C22 triacid triester elasticizer and method of preparing the same |
| CN103788532A (en) * | 2013-09-28 | 2014-05-14 | 青岛三立新源电器有限公司 | Environment-friendly plasticizer composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634673A (en) * | 2016-09-09 | 2017-05-10 | 聊城市瑞邦塑料助剂有限公司 | Environment-friendly plasticizer and preparation method and application thereof |
| CN106634673B (en) * | 2016-09-09 | 2019-08-13 | 聊城市瑞邦塑料助剂有限公司 | A kind of environment-friendlyplasticizer plasticizer and the preparation method and application thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160203 |