CN1226030C - Oily solid cosmetics - Google Patents
Oily solid cosmetics Download PDFInfo
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- CN1226030C CN1226030C CNB021050309A CN02105030A CN1226030C CN 1226030 C CN1226030 C CN 1226030C CN B021050309 A CNB021050309 A CN B021050309A CN 02105030 A CN02105030 A CN 02105030A CN 1226030 C CN1226030 C CN 1226030C
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- Prior art keywords
- oily solid
- composition
- solid cosmetics
- effect
- cosmetic
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/897—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing halogen, e.g. fluorosilicones
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
Abstract
The oily solid cosmetic includes: (a) a fluorine-modified silicone; (b) an acrylic silicone-based graft copolymer which is obtained by copolymerizing an organopolysiloxane compound having a radical-polymerizing group at one of its polymer chain ends with a radical-polymerizing monomer consisting mainly of a 16-22C alkyl(meth) acrylate; and (c) a volatile silicone. The cosmetic preferably contains the components (a), (b), and (c) in amounts of 1-40 wt.%, 0.5-40 wt.%, and 0.1-40 wt.%, respectively. Provided is an oily solid cosmetic which has good usability and is capable of giving excellent luster after applied to the skin and of excellently keeping an effect of preventing secondary adhesion and a cosmetic effect. The cosmetic is preferably used as a lipstick.
Description
Technical field
The present invention relates to contain fluorine modified polyorganosiloxane, specific acrylic compounds-polysiloxanes quasi-graft copolymer and the oily solid cosmetics of Y 7175, lipstick particularly, more particularly, it is good to relate to a kind of usability, glossiness after smearing is good, and secondary adheres to the also good oily solid cosmetics of persistence that prevents effect and dressing effect.
Background technology
Up to now, the oily solid cosmetics of lipstick, vanishing cream etc. all is the product that constitutes as main component with paraffin, oil preparation, powder, and various qualities all is to come specific implementation by kind that changes these compositions and use level.For these oily solid cosmetics, particularly for the lipstick compositions, exist in be applied on the lip after, this lipstick also can transfection above cup or medicated clothing etc., the problem that promptly so-called secondary adheres to.In addition, even if for the vanishing cream that is used to improve the cosmetic persistence in recent years, the problem that this vanishing cream also exists the secondary to clothes etc. to adhere to.
For this reason, in the oily solid cosmetics of lipstick etc., people have developed many kinds to have good secondary and adheres to effect and the also good technology of its cosmetic persistence of preventing.What specifically can exemplify has, by cooperating polyorganosiloxane resin is dissolved in the material that obtains in the Y 7175, make when lipstick is applied on the lip, treat after the Y 7175 volatile dry, on the surface of lip, form the protecting film technology of one deck polyorganosiloxane resin; By cooperating the fluorinated oil preparation that fluorine is imported to the polysiloxanes that obtains this property of fluorine in the straight catenate polysiloxane chain or PFPE etc., improve the water and oil-resistant of cosmetic film.In addition, these technology are used for vanishing cream similarly.
The problem that the present invention will solve
Yet, for the technology that in lipstick, cooperates polyorganosiloxane resin and Y 7175, be accompanied by the drying of Y 7175, reduce the glossiness of cosmetic film sometimes.In addition, for the technology that in vanishing cream, cooperates polyorganosiloxane resin and Y 7175, because be accompanied by the drying of Y 7175, the cosmetic film can shrink thereupon, the problem that can produce skin-tightening (just so-called take out tight sensation), the flexibility of cosmetic film is reduced.In addition, for cooperating by in straight chain shape polysiloxane chain, importing the fluorine modified polyorganosiloxane that fluorine obtains or the technology of PFPE, the problem that can produce the autgmentability variation of product or tack is reduced.Therefore, it is good that people urgently wish to develop a kind of usability, and the glossiness after smearing is good and secondary adhered to all good oily solid cosmetics of persistence that prevents effect and cosmetic lasting effect.
Technical scheme of the present invention
Present inventors have carried out deep research according to above-mentioned situation, found that the oily solid cosmetics that contains specific fluorine degeneration polysiloxanes, acrylic compounds-polysiloxane series graft copolymer and Y 7175 can address the above problem, wherein, said acrylic compounds-polysiloxane series graft copolymer is that a end by strand has the organopolysiloxane compound of free-radical polymerised group and is that (methyl) alkyl acrylate of 16-22 is that the free radical polymerization monomer of main body carries out copolymerization and obtains with the carbon number.Based on this discovery, finished the present invention.
That is to say that the present invention can provide a kind of oily solid cosmetics, wherein contain composition (a)-composition (c):
(a) the fluorine modified polyorganosiloxane of representing by following general formula (1)
(in the formula, R
1The expression carbon number is the alkyl or phenyl of 1-10, R
2The expression carbon number is the fluoro-alkyl of 1-10, and n represents the integer of 1-6, and m represents the integer of 0-3, (m+n) integer of expression 3-6.)
(b) has the organopolysiloxane compound of free-radical polymerised group by an end of strand and with (methyl) acrylic acid C
16-22Arrcostab is acrylic compounds-polysiloxanes quasi-graft copolymer that the free radical polymerization monomer of main body carries out copolymerization and obtains;
(c) Y 7175.
In addition, the present invention also provides above-mentioned oily solid cosmetics, wherein contains the composition (a) of 1-40 quality %, the composition (b) of 0.5-40 quality % and the composition (c) of 0.1-40 quality %.
In addition, the present invention also provides any above-mentioned oily solid cosmetics, wherein further also contains polyorganosiloxane resin as composition (d).
In addition, the present invention also provides any above-mentioned oily solid cosmetics, and wherein said oily solid cosmetics is a lipstick.
Embodiment of the present invention
Explain the present invention below.
The composition that uses among the present invention (a) is that a kind of playing in oily solid cosmetics of the present invention prevents that secondary from adhering to, keeping the composition of the glossiness effect after smearing, it is by importing the cyclic fluorine modified polyorganosiloxane that fluorine atom obtains in cyclic polysiloxane compound, for example can enumerating the chemical compound by expressions such as following general formulas (1).
(in the formula, R
1The alkyl or phenyl of expression carbon number 1-10, R
2The fluoro-alkyl of expression carbon number 1-10, n represents the integer of 1-6, m represents the integer of 0-3, (m+n) integer of expression 3-6.) as the example more specifically of the fluorine modified polyorganosiloxane of composition (a), can enumerate chemical compound by expressions such as following general formula (2)-(9), for these chemical compounds, can use wherein one or more.
In oily solid cosmetics of the present invention, (said herein " quality % " is meant shared ratio in whole oily solid cosmetics to the preferential 1-40 quality of the content % of composition (a), in addition, " the quality % " that herein uses is with " weight % is corresponding to.In addition, hereinafter it is abbreviated as " % "), be preferably 5-30% especially.As long as use composition (a) by this scope, just can obtain to keep good gloss, have the oily solid cosmetics of good usability again.
The composition of Shi Yonging (b) is that a kind of playing in oily solid cosmetics of the present invention prevents that secondary from adhering to, improving the composition of dressing effect persistence effect in the present invention, and it is that an a kind of end by strand has the organopolysiloxane compound of free-radical polymerised group and with (methyl) acrylic acid C
16-22Arrcostab is acrylic compounds-polysiloxanes quasi-graft copolymer that the free radical polymerization monomer of main body carries out copolymerization and obtains, example as (b) composition, can enumerate the spy and open the copolymer that flat 3-162442 communique, spy are opened record in the flat 4-342513 communique etc., for these copolymers, can use wherein one or more.
Specifically, as the example that has organic poly-polysiloxane compound of free-radical polymerised group at an end of strand, can enumerate chemical compound by following general formula (10) expression.
(in the formula, R
3Expression methyl or hydrogen atom, R
4Difference according to circumstances represents that a kind of carbon number is the divalent saturated hydrocarbon base of 1-10, and this alkyl, has the straight chain shape or the catenate carbochain that are separated by one or two ehter bond, R
5Expression methyl or butyl, d represents the number of 3-300)
On the other hand, said with (methyl) acrylic acid C
16-22Arrcostab is that the free radical polymerization monomer of main body is meant a kind of chemical compound that has a free-radical polymerised unsaturated bond in its molecule, as (methyl) acrylic acid C that is suitable for
16-22The example of Arrcostab can exemplify out acrylic acid palmityl ester, methacrylic acid palmityl ester, stearyl acrylate base ester, methacrylic acid stearyl, acrylic acid iso stearyl ester, methacrylic acid iso stearyl ester, acrylic acid Shan Yu base ester etc.In addition, said among the present invention from (methyl) acrylic acid C
16-22Arrcostab is in the free radical polymerization monomer of main body, except above-mentioned (methyl) acrylic acid C
16-22Outside the Arrcostab, can also use (methyl) acrylic acid C as required
1-15And C
23-30The styrene of Arrcostab, styrene, replacement, vinyl acetate, acrylic acid, methacrylic acid, maleic anhydride, maleate, fumarate, vinyl chloride, vinylidene chloride, ethylene, propylene, butadiene, acrylonitrile, fluoroolefin, N-vinyl pyrrolidone etc.
On an end of strand, have the poly-polysiloxane compound (A) of dimethyl of free-radical polymerised group and based on the copolymerization of the free radical polymerization monomer (B) of (methyl) acrylic acid C16-22 Arrcostab, carry out in the scope of 1/19-2/1 and in the presence of the radical polymerization initiator of routines such as benzoyl peroxide, peroxide lauroyl, azodiisobutyronitrile than ((A)/(B)) according to polymerization.Polymerization can be any polymerization in solution polymerization process, emulsion polymerization method, the outstanding turbid polymerization mass polymerization.As commercially available product, can enumerate KP561, KP562 (all producing) etc. by chemical industrial company of SHIN-ETSU HANTOTAI.
In oily solid cosmetics of the present invention, the amount of composition (b) is preferably 0.5-40%, is preferably 1-30% especially.Use composition (b) according to this scope, just can obtain secondary and adhere to and prevent that effect is good especially, and the also good oily solid cosmetics of usability.
The composition of Shi Yonging (c) is that a kind of playing in oily solid cosmetics of the present invention improved usability and secondary adheres to the composition that prevents the effect effect in the present invention, as its example, can enumerate low-molecular-weight dimethyl polysiloxane and cyclic polysiloxanes etc.Can enumerate particularly: the methyl polysiloxane of viscosity below 5cps, methyl phenyl silicone, octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane etc., can use in these compositions one or more.
In oily solid cosmetics of the present invention, the content of composition (c) is preferably 1-40%, is preferably 5-30% especially.Use composition (c) according to this scope, just can obtain the good oily solid cosmetics of usability.
In oily solid cosmetics of the present invention, except mentioned component, further contain polyorganosiloxane resin as composition (d) by making it, can improve its secondary better and adhere to and prevent effect.As the polyorganosiloxane resin that is applicable to composition (d), can enumerate: trimethylsiloxy silicic acid, high polymerization degree methyl polysiloxane, high polymerization degree methyl phenyl silicone, cross-linking type methyl polysiloxane, cross-linking type methyl phenyl silicone, the polyether-modified polysiloxanes of cross-linking type, methacrylic acid modified methyl polysiloxanes, polyvinyl pyrrolidone modified methyl polysiloxane etc., can use in these compositions one or more.In these polyorganosiloxane resins; adhere to from secondary and to prevent that effect from considering; good trimethylsiloxy silicic acid, the methacrylic acid modified methyl polysiloxanes of special preferably protecting film formation property, the polyorganosiloxane resin of the methyl polysiloxane of polyvinyl pyrrolidone modified etc.
Fit in oily solid cosmetics of the present invention under the situation of composition (d), the content of composition (d) is preferably 0.5～30%, is preferably 1～20% especially.Use composition (d) according to this scope, just can obtain the good and also good oily solid cosmetics of usability of glossiness after coating.
In oily solid cosmetics of the present invention, except mentioned component, can also fit into firming agent, softening agent, and can cooperate the oil preparation except that composition (a) and composition (c) according to purposes such as hardness or adjustment agent.Specifically, be not limited to animal oil, vegetable oil, synthesize the oils of wet goods as raw material, also be not limited to the character of solid oil, semisolid oil, fluid oil, volatility wet goods, they can be the oil preparationes that is applicable in the conventional cosmetics, for example can enumerate: hydro carbons, oils, wax class, sclerosis oils, ester oil class, fatty acid, higher alcohols, polysiloxanes oils, fluorine-containing be the oil preparation of oils, agnolin derivatives class etc.In oily solid cosmetics of the present invention, the use level of these oil preparationes is approximately 1～80%.In addition, in above-mentioned oil preparation,, consider, preferably cooperate the wax class from the viewpoint of usability and ageing stability as firming agent.In the case, the use level of wax class is approximately 1～30%.
In oily solid cosmetics of the present invention, except mentioned component, can also be as required, in the scope of not damaging effect of the present invention, fit into some powder body, surfactant, UV absorbent, wetting agent, vitamins, beauty treatment composition, antiseptic, water soluble polymer, water, spice etc. aptly.
As the suitable powder that is coupled in the oily solid cosmetics of the present invention, can be that those can give coloring effect, the ultraviolet occlusion effect, powder such as dressing effect, so long as can be as the powder of conventional cosmetic powder use, just there is not particular determination, it is not subjected to spherical, tabular, the shape of needle-like etc., smoke-like, micropartical, the particle diameter of particles such as pigment-level and porous matter, the qualification of performances such as particle structure such as atresia matter can be enumerated: the inorganic powder class particularly, the glossiness powder, the organic dust class, the pigment powdery type, the metal dust class, composite powder class etc.In addition, these powder can make following substances carry out surface treatment, saidly be used to carry out the surface-treated material and have: fluorinated chemical compound, polysiloxanes compounds, metallic soap class, lecithin, hydrogenation lecithin, collagen, hydro carbons, higher fatty acids, higher alcohol, esters, paraffin, wax, surfactant etc., can use in these materials one or more.In oily solid cosmetics of the present invention, the use level of these powder is different with its cooperation purpose, but generally is about 0.1-60%.
In oily solid cosmetics of the present invention, can fit into surfactant according to the purpose of dispersant, wetting agent etc.As the surfactant that uses herein; so long as the surfactant in the common cosmetics gets final product; there is no particular restriction, can enumerate particularly: nonionic surfactant, anionic surfactant, cationic surface active agent, amphoteric surfactant etc.In oily solid cosmetics of the present invention, the use level of surfactant is different with its cooperation purpose, but generally is about 0.01-10%.
Oily solid cosmetics of the present invention can be used for cosmetics such as lipstick, vanishing cream, eye shadow, rouge, but the cosmetics that can bring into play effect of the present invention significantly are lipsticks.In addition, the form of oily solid cosmetics of the present invention has bar-shaped, pie etc.In addition, oily solid cosmetics of the present invention can be with composition (a)-composition (c) and composition (d) and the mixing of other compositions, also can be as required, by heating, be filled in the container etc. and make it be shaped to solid shape and obtain required oily solid cosmetics.
(embodiment)
Enumerate embodiment below the present invention is described further, but the present invention is not subjected to the qualification of these embodiment.
Embodiment 1-11 and comparative example 1-4: lip stick
Has the lip stick of forming shown in table 1 and the table 2 according to following production method manufacturing, then according to the usability of following evaluation methodology to autgmentability etc., glossiness after smearing, secondary adhere to the projects such as persistence that prevent effect, dressing effect to be estimated, and the result is shown in table 1 and the table 2 in the lump with obtaining.
Table 1
(quality %)
| Sequence number | Composition | Embodiment | ||||||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | ||
| 1 | Ethylene-propylene copolymer | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 |
| 2 | Candelilla wax | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 |
| 3 | Three (2 ethyl hexanoic acid) glyceride | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 |
| 4 | Three isostearic acid polyglycerin ester | Residual amount | Residual amount | Residual amount | Residual amount | Residual amount | Residual amount | Residual amount | Residual amount | Residual amount | Residual amount | Residual amount |
| 5 | Fluorine modified polyorganosiloxane (annotating 1) | 0.2 | 1 | 15 | 15 | 15 | 15 | 15 | 15 | 15 | 15 | 15 |
| 6 | Fluorine modified polyorganosiloxane (annotating 2) | -- | -- | -- | 10 | -- | -- | -- | -- | -- | -- | -- |
| 7 | Fluorine modified polyorganosiloxane (annotating 3) | -- | -- | -- | -- | -- | -- | -- | -- | -- | -- | -- |
| 8 | PFPE (annotating 4) | -- | -- | -- | -- | -- | -- | -- | -- | -- | -- | -- |
| 9 | Acrylic compounds-polysiloxanes quasi-graft copolymer (annotating 5) | 20 | 20 | 20 | 20 | 0.5 | 15 | 30 | 20 | 20 | 20 | 20 |
| 10 | Decamethylcyclopentaandoxane | 15 | 15 | 15 | 15 | 15 | 15 | 15 | -- | 25 | 15 | 20 |
| 11 | Polyorganosiloxane resin (annotating 6) | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | -- | 15 |
| 12 | Red No. 202 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |
| 13 | Yellow No. 4 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 |
| 14 | Titanium oxide | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
| 15 | Chamomile extract | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
| 16 | P-methoxycinnamic acid-2-Octyl Nitrite | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |
| 17 | The dl-alpha-tocopherol | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
| 18 | Spice | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
| Evaluation result | ||||||||||||
| Usability | ○ | ◎ | ◎ | ◎ | ○ | ◎ | ◎ | ◎ | ◎ | ◎ | ○ | |
| Glossiness after smearing | ○ | ○ | ◎ | ◎ | ○ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | |
| Secondary adheres to and prevents effect | ○ | ◎ | ◎ | ◎ | ◎ | ○ | ○ | ◎ | ◎ | ○ | ◎ | |
| The persistence of dressing effect | ◎ | ◎ | ◎ | ◎ | ◎ | ○ | ○ | ◎ | ◎ | ○ | ◎ | |
Annotate 1: by the fluorine modified polyorganosiloxane of formula (2) expression
Annotate 2: by the fluorine modified polyorganosiloxane of formula (3) expression
Annotate 3: by the fluorine modified polyorganosiloxane of formula (11) expression
Annotate 4: trade name Off オ Application プ リ Application HC/04 (ア ウ シ モ Application ト corporate system)
Annotate 5: trade name KP-561 (chemical industrial company of SHIN-ETSU HANTOTAI system)
Annotate 6: trade name silicone KF-7312J (chemical industrial company of SHIN-ETSU HANTOTAI system)
Table 2
(quality %)
| NO | Composition | Comparative example | |||
| 1 | 2 | 3 | 4 | ||
| 1 | Ethylene-propylene copolymer | 10 | 10 | 10 | 10 |
| 2 | Candelilla wax | 5 | 5 | 5 | 5 |
| 3 | Three (2 ethyl hexanoic acid) glyceride | 25 | 30 | 10 | 10 |
| 4 | Three isostearic acid polyglycerin ester | Residual amount | Residual amount | Residual amount | Residual amount |
| 5 | Fluorine modified polyorganosiloxane (annotating 1) | -- | 15 | -- | -- |
| 6 | Fluorine modified polyorganosiloxane (annotating 2) | -- | -- | -- | -- |
| 7 | Fluorine modified polyorganosiloxane (annotating 3) | -- | -- | 15 | -- |
| 8 | PFPE (annotating 4) | -- | -- | -- | 15 |
| 9 | Acrylic compounds-polysiloxanes quasi-graft copolymer (annotating 5) | 20 | -- | 20 | 20 |
| 10 | Decamethylcyclopentaandoxane | 15 | 15 | 15 | 15 |
| 11 | Polyorganosiloxane resin (annotating 6) | 7 | 7 | 7 | 7 |
| 12 | Red No. 202 | 1 | 1 | 1 | 1 |
| 13 | Yellow No. 4 | 2.5 | 2.5 | 2.5 | 2.5 |
| 14 | Titanium oxide | 1.5 | 1.5 | 1.5 | 1.5 |
| 15 | Chamomile extract | 0.1 | 0.1 | 0.1 | 0.1 |
| 16 | P-methoxycinnamic acid-2-Octyl Nitrite | 1 | 1 | 1 | 1 |
| 17 | The dl-alpha-tocopherol | 0.1 | 0.1 | 0.1 | 0.1 |
| 18 | Spice | 0.1 | 0.1 | 0.1 | 0.1 |
| Evaluation result | |||||
| Usability | × | △ | △ | × | |
| Glossiness after smearing | ○ | × | × | × | |
| Secondary adheres to and prevents effect | ×× | ○ | × | △ | |
| The persistence of dressing effect | ○ | △ | △ | △ | |
Annotate 1: by the fluorine modified polyorganosiloxane of formula (2) expression
Annotate 2: by the fluorine modified polyorganosiloxane of formula (3) expression
Annotate 3: by the fluorine modified polyorganosiloxane of formula (11) expression
Annotate 4: trade name Off オ Application プ リ Application HC/04 (ア ウ シ モ Application ト corporate system)
Annotate 5: trade name KP-561 (chemical industrial company of SHIN-ETSU HANTOTAI system)
Annotate 6: trade name silicone KF-7312J (chemical industrial company of SHIN-ETSU HANTOTAI system)
(manufacture method)
A: with composition 1-9 mixed dissolution;
B: in A, add composition 10-11, and mix;
C: in B, add composition 12-18, it is uniformly dispersed;
D: with the C dissolving, after removing bubble, it is poured in the container, be cooled to room temperature, obtain lip stick.
Please have historical women 50 people more than 10 years that make up and use the lipstick of the foregoing description and comparative example, then to projects such as " usability ", " glossiness after smearing ", " secondary adhere to prevent effect ", " persistence of dressing effect ", according to the number of feeling good what, judge according to following benchmark.Should illustrate,, estimate according to smearing the state of end after 6 hours for the project of dressing effect persistence.
[judgement] [number of feeling good]
◎: more than 40 people
Zero: 30-39 people
△: 20-29 people
*: 10-19 people
Below * *: 9 people
From the result of table 1 and table 2 as can be seen, compare with the lipstick of comparative example, the performance that glossiness, the secondary of the lipstick of the embodiment of the invention at the usability of autgmentability etc., after smearing adheres to the whole projects that prevent effect, dressing effect is all good.Contrast with embodiments of the invention, to adhere to the performance that prevents aspect effect and the usability at secondary not inferior for the comparative example 1 of gradation composition (a); The glossiness of comparative example 2 after smearing of gradation composition (b) is not inferior; Use straight chain shape fluorine modified polyorganosiloxane or PFPE to replace the comparative example 3 of composition (a) and the performance of comparative example 4 aspect secondary adhesion effect and usability inferior, the neither requirement that can satisfy whole projects of any comparative example.
Embodiment 12: the vanishing cream of pie
(composition) (quality %)
1. candelilla wax 5
2. microwax 10
3. fluorine modified polyorganosiloxane (annotate 7) 2
4. poly-three isostearic acid polyglycerin ester 10
5. decamethyl ring five polysiloxanes 15
6. polyorganosiloxane resin (annotate 6) 3
7.N-lauryl-L-glutamic acid two (cholest Shan Yu
Base octyl group lauryl) ester 2
8. three (octyl group is sad) glyceride surplus
9. acrylic compounds-polysiloxanes quasi-graft copolymer (annotate 28) 10
10. particulate titanium dioxide 1
11. particulate oxide zinc 1
12. titanium oxide 8
13. barium sulfate 2
14. sericite 15
15. red iron oxide 1
16. yellow iron oxide 2
17. black iron oxide 0.5
18. Aloe extract 0.1
19. spice is an amount of
Annotate 7: by the fluorine modified polyorganosiloxane of formula (4) expression
Annotate 8: trade name KP-562 (chemical industrial company of SHIN-ETSU HANTOTAI system)
(manufacture method)
A: with composition 1-9 mixed dissolution;
B: in A, add composition 10-19, homodisperse;
C: with the B dissolving, after removing bubble, be injected in the device shape container, be cooled to room temperature, obtain the vanishing cream of pie.
The performance that glossiness, the secondary of the pie vanishing cream of embodiment 12 in the use of autgmentability etc., after smearing adheres to the whole projects that prevent effect, dressing effect is all good.
Embodiment 13: the eye shadow of pie
(composition) (quality %)
1. microwax 5
2. ceresin 10
3. three isostearic acid polyglycerin ester 4
4. vaseline 5
5. polyorganosiloxane resin (annotate 6) 2.5
6. decamethylcyclopentaandoxane 5
7. fluorine modified siloxane (annotate 1) 5
8. three decane surpluses
9. sad propylene glycol ester 15
10. acrylic compounds-type siloxane graft copolymer (annotate 5) 15
11. spherical nylon powder 5
12. the Pulvis Talci 10 that polysiloxanes is handled
13. red No. 202 0.5
14. blue No. 404 1
15. the titanium oxide 2 that polysiloxanes is handled
16. carboxy vinyl polymer 2
17. collagenic aqueous solution 0.1
18. spice is an amount of
(manufacture method)
A: with composition 1-10 mixed dissolution;
B: in A, add composition 11-18, homodisperse;
C: with the B dissolving, after removing bubble, be injected in the device shape container, be cooled to room temperature, obtain the eye shadow of pie.
The performance that glossiness, the secondary of the pie eye shadow of embodiment 13 at the usability of autgmentability etc., after smearing adheres to the whole projects that prevent effect, dressing effect is all good.
Embodiment 14: the pie rouge
(composition) (quality %)
1. Brazil wax 10
2. the polyethylene-polypropylene copolymer 10
3. the rosin acid tetramethylolmethane 7
4. three isooctyl acid glyceride 5
5. polyorganosiloxane resin (annotate 6) 5
6. two isostearic acid polyglycerin ester 5
7. decamethylcyclopentaandoxane 2.5
8. fluorine modified polyorganosiloxane (annotate 1) 1
9. fluorine modified polyorganosiloxane (annotate 2) 2
10. liquid paraffin surplus
11. acrylic compounds-polysiloxanes quasi-graft copolymer (annotating 8) 10
12. spherical polystyrol powder 4
13. sericite 15
14. Talcum 10
15. organo-clay mineral 0.5
16. red No. 226 1
17. yellow No. 4 aluminum color lakes 2
18. black iron oxide 0.2
19. alkyl-modified carboxy vinyl polymer 0.05
20. the fan selects fragrant extract 0.1
21. spice is an amount of
(manufacture method)
A: with composition 1-11 mixed dissolution;
B: in A, add composition 12-21, homodisperse;
C: with the B dissolving, after removing bubble, be injected in the device shape container, be cooled to room temperature, obtained the rouge of pie.
The performance that glossiness, the secondary of the pie rouge of embodiment 14 at the usability of autgmentability etc., after smearing adheres to the whole projects that prevent effect, dressing effect is all good.
The invention effect
As mentioned above, oily solid cosmetics of the present invention is that a kind of usability is good, and the glossiness after the coating is good, and the secondary also good oily solid cosmetics of continuation that adheres to preventing effectiveness and dressing effect.
Claims (5)
1. oily solid cosmetics, wherein contain composition (a)-composition (c):
(a) the fluorine modified polyorganosiloxane of representing by following general formula (1)
In the formula, R
1The expression carbon number is the alkyl or phenyl of 1-10, R
2The expression carbon number is the fluoro-alkyl of 1-10, and n represents the integer of 1-6, and m represents the integer of 0-3, and m+n represents the integer of 3-6;
(b) have the organopolysiloxane compound of free-radical polymerised group and carry out copolymerization and acrylic acid-polysiloxanes quasi-graft copolymer of obtaining by an end of strand based on the free radical polymerization monomer of acrylic acid C16-22 Arrcostab and/or methacrylic acid C16-22 Arrcostab;
(c) Y 7175.
2. oily solid cosmetics as claimed in claim 1 is characterized in that containing the composition (a) of 1-40 quality %, the composition (b) of 0.5-40 quality % and the composition (c) of 0.1-40 quality %.
3. oily solid cosmetics as claimed in claim 1 or 2 is characterized in that wherein also containing polyorganosiloxane resin as (d) composition.
4. the oily solid cosmetics described in claim 1 or 2 is characterized in that, wherein said oily solid cosmetics is a lipstick.
5. the oily solid cosmetics described in claim 3 is characterized in that, wherein said oily solid cosmetics is a lipstick.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP037898/2001 | 2001-02-15 | ||
| JP2001037898 | 2001-02-15 | ||
| JP012311/2002 | 2002-01-22 | ||
| JP2002012311A JP3864329B2 (en) | 2001-02-15 | 2002-01-22 | Oily solid cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1370514A CN1370514A (en) | 2002-09-25 |
| CN1226030C true CN1226030C (en) | 2005-11-09 |
Family
ID=26609424
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021050309A Expired - Fee Related CN1226030C (en) | 2001-02-15 | 2002-02-11 | Oily solid cosmetics |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP3864329B2 (en) |
| KR (1) | KR100842587B1 (en) |
| CN (1) | CN1226030C (en) |
| HK (1) | HK1047708A1 (en) |
| TW (1) | TWI307280B (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8336071B2 (en) | 1996-12-19 | 2012-12-18 | Gemstar Development Corporation | System and method for modifying advertisement responsive to EPG information |
| US8352978B2 (en) | 1998-05-15 | 2013-01-08 | United Video Properties, Inc. | Systems and methods for advertising television networks, channels, and programs |
| US8359616B2 (en) | 2009-09-30 | 2013-01-22 | United Video Properties, Inc. | Systems and methods for automatically generating advertisements using a media guidance application |
| US8776125B2 (en) | 1996-05-03 | 2014-07-08 | Starsight Telecast Inc. | Method and system for displaying advertisements in an electronic program guide |
| US8832742B2 (en) | 2006-10-06 | 2014-09-09 | United Video Properties, Inc. | Systems and methods for acquiring, categorizing and delivering media in interactive media guidance applications |
| US8863170B2 (en) | 2000-03-31 | 2014-10-14 | United Video Properties, Inc. | System and method for metadata-linked advertisements |
| US8918807B2 (en) | 1997-07-21 | 2014-12-23 | Gemstar Development Corporation | System and method for modifying advertisement responsive to EPG information |
| US8949901B2 (en) | 2011-06-29 | 2015-02-03 | Rovi Guides, Inc. | Methods and systems for customizing viewing environment preferences in a viewing environment control application |
| US9015750B2 (en) | 1998-05-15 | 2015-04-21 | Rovi Guides, Inc. | Interactive television program guide system for determining user values for demographic categories |
| US9075861B2 (en) | 2006-03-06 | 2015-07-07 | Veveo, Inc. | Methods and systems for segmenting relative user preferences into fine-grain and coarse-grain collections |
| US9137491B2 (en) | 2000-02-01 | 2015-09-15 | Rovi Guides, Inc. | Methods and systems for forced advertising |
| US9288521B2 (en) | 2014-05-28 | 2016-03-15 | Rovi Guides, Inc. | Systems and methods for updating media asset data based on pause point in the media asset |
| US9319735B2 (en) | 1995-06-07 | 2016-04-19 | Rovi Guides, Inc. | Electronic television program guide schedule system and method with data feed access |
| US9426509B2 (en) | 1998-08-21 | 2016-08-23 | Rovi Guides, Inc. | Client-server electronic program guide |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007525411A (en) * | 2003-04-14 | 2007-09-06 | ザ プロクター アンド ギャンブル カンパニー | Anhydrous silicone-modified fluorinated polymer for color transfer resistant lip cosmetic composition |
| JP2005306845A (en) * | 2004-03-24 | 2005-11-04 | Kose Corp | Cake powder cosmetic |
| JP4965082B2 (en) * | 2005-03-30 | 2012-07-04 | 株式会社コーセー | Lipstick overcoat |
| WO2016209641A1 (en) * | 2015-06-25 | 2016-12-29 | Elc Management Llc | Transfer resistant cosmetic composition |
| JP6673779B2 (en) * | 2016-08-09 | 2020-03-25 | 株式会社シャネル化粧品技術開発研究所 | External composition and method for producing the same |
| JP7066625B2 (en) * | 2016-11-04 | 2022-05-13 | 株式会社コーセー | Solid powder cosmetics |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10167930A (en) * | 1996-12-09 | 1998-06-23 | Shiseido Co Ltd | Lipstick composition |
| JPH10182396A (en) * | 1996-12-26 | 1998-07-07 | Kose Corp | Cosmetic |
| JP3403352B2 (en) * | 1999-03-31 | 2003-05-06 | 株式会社資生堂 | Lipstick composition |
| JP4142812B2 (en) * | 1999-06-24 | 2008-09-03 | 日本メナード化粧品株式会社 | Cosmetics |
-
2002
- 2002-01-22 JP JP2002012311A patent/JP3864329B2/en not_active Expired - Fee Related
- 2002-02-04 TW TW091101872A patent/TWI307280B/zh not_active IP Right Cessation
- 2002-02-11 CN CNB021050309A patent/CN1226030C/en not_active Expired - Fee Related
- 2002-02-14 KR KR1020020007965A patent/KR100842587B1/en not_active IP Right Cessation
- 2002-12-30 HK HK02109405A patent/HK1047708A1/en not_active IP Right Cessation
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9319735B2 (en) | 1995-06-07 | 2016-04-19 | Rovi Guides, Inc. | Electronic television program guide schedule system and method with data feed access |
| US8776125B2 (en) | 1996-05-03 | 2014-07-08 | Starsight Telecast Inc. | Method and system for displaying advertisements in an electronic program guide |
| US8869204B2 (en) | 1996-05-03 | 2014-10-21 | Starsight Telecast, Inc. | Method and system for displaying advertisements in an electronic program guide |
| US8732757B2 (en) | 1996-12-19 | 2014-05-20 | Gemstar Development Corporation | System and method for targeted advertisement display responsive to user characteristics |
| US8635649B2 (en) | 1996-12-19 | 2014-01-21 | Gemstar Development Corporation | System and method for modifying advertisement responsive to EPG information |
| US8726311B2 (en) | 1996-12-19 | 2014-05-13 | Gemstar Development Corporation | System and method for modifying advertisement responsive to EPG information |
| US8448209B2 (en) | 1996-12-19 | 2013-05-21 | Gemstar Development Corporation | System and method for displaying advertisements responsive to EPG information |
| US8336071B2 (en) | 1996-12-19 | 2012-12-18 | Gemstar Development Corporation | System and method for modifying advertisement responsive to EPG information |
| US9191722B2 (en) | 1997-07-21 | 2015-11-17 | Rovi Guides, Inc. | System and method for modifying advertisement responsive to EPG information |
| US8918807B2 (en) | 1997-07-21 | 2014-12-23 | Gemstar Development Corporation | System and method for modifying advertisement responsive to EPG information |
| US9015749B2 (en) | 1997-07-21 | 2015-04-21 | Rovi Guides, Inc. | System and method for modifying advertisement responsive to EPG information |
| US9015750B2 (en) | 1998-05-15 | 2015-04-21 | Rovi Guides, Inc. | Interactive television program guide system for determining user values for demographic categories |
| US8352978B2 (en) | 1998-05-15 | 2013-01-08 | United Video Properties, Inc. | Systems and methods for advertising television networks, channels, and programs |
| US9426509B2 (en) | 1998-08-21 | 2016-08-23 | Rovi Guides, Inc. | Client-server electronic program guide |
| US9137491B2 (en) | 2000-02-01 | 2015-09-15 | Rovi Guides, Inc. | Methods and systems for forced advertising |
| US8863170B2 (en) | 2000-03-31 | 2014-10-14 | United Video Properties, Inc. | System and method for metadata-linked advertisements |
| US9075861B2 (en) | 2006-03-06 | 2015-07-07 | Veveo, Inc. | Methods and systems for segmenting relative user preferences into fine-grain and coarse-grain collections |
| US9092503B2 (en) | 2006-03-06 | 2015-07-28 | Veveo, Inc. | Methods and systems for selecting and presenting content based on dynamically identifying microgenres associated with the content |
| US9128987B2 (en) | 2006-03-06 | 2015-09-08 | Veveo, Inc. | Methods and systems for selecting and presenting content based on a comparison of preference signatures from multiple users |
| US9215504B2 (en) | 2006-10-06 | 2015-12-15 | Rovi Guides, Inc. | Systems and methods for acquiring, categorizing and delivering media in interactive media guidance applications |
| US8832742B2 (en) | 2006-10-06 | 2014-09-09 | United Video Properties, Inc. | Systems and methods for acquiring, categorizing and delivering media in interactive media guidance applications |
| US8359616B2 (en) | 2009-09-30 | 2013-01-22 | United Video Properties, Inc. | Systems and methods for automatically generating advertisements using a media guidance application |
| US8949901B2 (en) | 2011-06-29 | 2015-02-03 | Rovi Guides, Inc. | Methods and systems for customizing viewing environment preferences in a viewing environment control application |
| US9288521B2 (en) | 2014-05-28 | 2016-03-15 | Rovi Guides, Inc. | Systems and methods for updating media asset data based on pause point in the media asset |
Also Published As
| Publication number | Publication date |
|---|---|
| HK1047708A1 (en) | 2003-03-07 |
| KR100842587B1 (en) | 2008-07-01 |
| JP3864329B2 (en) | 2006-12-27 |
| KR20020067653A (en) | 2002-08-23 |
| TWI307280B (en) | 2009-03-11 |
| CN1370514A (en) | 2002-09-25 |
| JP2002316912A (en) | 2002-10-31 |
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