US20030079526A1 - Method and apparatus for detecting holes in plastic containers - Google Patents

Method and apparatus for detecting holes in plastic containers Download PDF

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Publication number
US20030079526A1
US20030079526A1 US10/004,362 US436201A US2003079526A1 US 20030079526 A1 US20030079526 A1 US 20030079526A1 US 436201 A US436201 A US 436201A US 2003079526 A1 US2003079526 A1 US 2003079526A1
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Prior art keywords
container
hole
pressure fluid
sound
production
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US10/004,362
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US6553809B1 (en
Inventor
Donald Hayward
David Bogstad
Donald Miller
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Plastic Technologies Inc
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Plastic Technologies Inc
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Assigned to PLASTIC TECHNOLOGIES, INC. reassignment PLASTIC TECHNOLOGIES, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BOGSTAD, DAVID A., HAYWARD, DONALD W., MILLER, DONALD WAYNE
Priority to US10/004,362 priority Critical patent/US6553809B1/en
Priority to PCT/US2002/034933 priority patent/WO2003038392A1/en
Priority to BR0213764-0A priority patent/BR0213764A/en
Priority to NZ532669A priority patent/NZ532669A/en
Priority to AU2002348331A priority patent/AU2002348331B2/en
Priority to CA002466089A priority patent/CA2466089C/en
Priority to MXPA04004097A priority patent/MXPA04004097A/en
Priority to US10/493,730 priority patent/US7040167B2/en
Priority to EP02782254A priority patent/EP1451549A4/en
Assigned to PLASTIC TECHNOLOGIES, INC. reassignment PLASTIC TECHNOLOGIES, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BOGSTAD, DAVID A., HAYWARD, DONALD W., MILLER, DONALD WAYNE
Publication of US6553809B1 publication Critical patent/US6553809B1/en
Application granted granted Critical
Publication of US20030079526A1 publication Critical patent/US20030079526A1/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N29/00Investigating or analysing materials by the use of ultrasonic, sonic or infrasonic waves; Visualisation of the interior of objects by transmitting ultrasonic or sonic waves through the object
    • G01N29/22Details, e.g. general constructional or apparatus details
    • G01N29/227Details, e.g. general constructional or apparatus details related to high pressure, tension or stress conditions
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N29/00Investigating or analysing materials by the use of ultrasonic, sonic or infrasonic waves; Visualisation of the interior of objects by transmitting ultrasonic or sonic waves through the object
    • G01N29/04Analysing solids
    • G01N29/045Analysing solids by imparting shocks to the workpiece and detecting the vibrations or the acoustic waves caused by the shocks
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N29/00Investigating or analysing materials by the use of ultrasonic, sonic or infrasonic waves; Visualisation of the interior of objects by transmitting ultrasonic or sonic waves through the object
    • G01N29/14Investigating or analysing materials by the use of ultrasonic, sonic or infrasonic waves; Visualisation of the interior of objects by transmitting ultrasonic or sonic waves through the object using acoustic emission techniques
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2291/00Indexing codes associated with group G01N29/00
    • G01N2291/01Indexing codes associated with the measuring variable
    • G01N2291/014Resonance or resonant frequency
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2291/00Indexing codes associated with group G01N29/00
    • G01N2291/01Indexing codes associated with the measuring variable
    • G01N2291/015Attenuation, scattering
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2291/00Indexing codes associated with group G01N29/00
    • G01N2291/02Indexing codes associated with the analysed material
    • G01N2291/023Solids
    • G01N2291/0235Plastics; polymers; soft materials, e.g. rubber
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2291/00Indexing codes associated with group G01N29/00
    • G01N2291/10Number of transducers
    • G01N2291/101Number of transducers one transducer
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2291/00Indexing codes associated with group G01N29/00
    • G01N2291/26Scanned objects
    • G01N2291/269Various geometry objects
    • G01N2291/2695Bottles, containers

Definitions

  • the invention relates to a method and apparatus for monitoring the production of plastic blow molded containers. More particularly, the invention contemplates the sensing of defects caused by the formation of holes in the walls of plastic blow molded containers by monitoring the sound adjacent predetermined location along the production line of plastic blow molded containers.
  • the leak testing of tanks, pressure vessels, and containers is an important manufacturing consideration in many different industries.
  • the gas-tight or liquid tight integrity of these components is usually determined by some form of a pressure-decay test.
  • the unit under test is injected with air to some specified overpressure, and the pressure is monitored for a specified period of time. If the pressure does not decay below a specified value at the end of the designated time period, the component under test is considered to be leak-free.
  • Another technique involves drawing a vacuum on the component being tested and then completely surrounding it with helium gas.
  • a detector inside the vacuum system notifies the operator if helium is present in the air being pumped from the component.
  • Still another method involves the pressurization/immersion technique which consists of pressurizing the component, totally immersing the component in water or some other clear liquid, and observing the point of bubble emergence.
  • Yet another method utilizes a collimated beam of light which is scanned across the component under test.
  • the test component has been pressurized with a tracer gas that strongly absorbs the light.
  • the light energy absorbed by the gas produces an acoustic emission which is detected by a microphone.
  • the resulting signal may be processed either as an alarm or it may be processed in coordination with the beam scanning mechanism to indicate exactly where the leak is located.
  • Another method involves apparatus adopted to detect the sound issued outwardly by the individual blow-molding dies during the blow-molding process wherein the sound is converted to an electrical signal and is compared with a reference signal or level and the faulty burst container is rejected.
  • Another object of the invention is to produce a method and apparatus that will detect the presence of a hole in a container being formed by a blow molding process.
  • Another object of the invention is to produce a method and apparatus for detecting a hole in the wall of a plastic container and producing a signal in response thereto.
  • FIG. 1 is an enlarged view of the sensing tube placed in proximity to the plastic containers being formed to convey an acoustical signal created by the flow of pressure fluid through a hole in the container being formed during a blow molding operation;
  • FIG. 2 is a block diagram of a system for sensing a hole in a plastic blow molded container during the production thereof.
  • the typical blow molding machines include an annular rotatably mounted platform capable of serially receiving hollow plastic preforms or parisons.
  • the preforms are carried in molds having an inner cavity in the desired configuration or shape of the finished container to be formed.
  • the preforms are heated to a predetermined temperature, which prepares the plastic material to be readily blow molded.
  • high pressure fluid such as compressed air, is sequentially introduced into the hollow interior of the preforms.
  • the preforms are thereby caused to expand and assume the shape of the associated mold.
  • the containers are caused to be inspected for defects. In the event a defective container is detected, means are provided for rejecting the container prior to filling or storage.
  • the completed plastic containers are then transferred, from the annular rotating platform to a conveyor which transports the containers to a filling station. Finally, the filled containers are suitably removed from the conveyor to be stored for later delivery or are immediately loaded on appropriate vehicles for delivery to the ultimate customer. Obviously, unfilled containers may also be off-loaded in a similar fashion.
  • the drawings disclose an apparatus generally indicated by reference numeral 10 positioned in proximity of the annular rotating platform 12 of a blow-molding machine of the type manufactured by Sidel, a corporation of France.
  • the rotating platform 12 contains an annular array of mold cavities 14 into which heated plastic preforms 16 are indexed to a source 18 of pressure fluid which in most instances is compressed air.
  • the pressure fluid is introduced into the hollow interior of the heated preform 16 causing the preform to expand and assume the shape of the interior of the mold cavity 14 as a completed container 20 .
  • a hole 22 is caused to be formed in the wall of the container 20 , the pressure fluid from the source 18 escaping through the hole 22 will create an acoustic signal.
  • a sound detector 24 is positioned adjacent the periphery of the rotating platform 12 .
  • the input of the sound detector 24 is coupled to a sound columnator 26 .
  • the sound columnator 26 is formed of a hollow plastic tube having the distal end thereof pointed in the direction of the container 20 .
  • the sound detector 24 suitable for the purposes of the invention is commercially available and identified as Radio Shack Sound Level Meter Model 33-2050 having an output of from 0 to 1 volt D.C.
  • the output of the sound detector 24 is coupled to the input of an amplifier and discriminator 30 which may be set to produce an output signal based upon the amplitude of the voltage signal produced by the sound level meter 26 which may be fed to a logic circuit 40 consisting of timing and/or counting and control logic.
  • the logic circuit 40 may be coupled to an air blow-off station 50 which is disposed downstream of the acoustic sensor and is effective to remove any defective container sensed by the logic circuit 40 .
  • the air blow-off station 50 includes solenoid operated valves controlling the flow of pressure fluid, such as compressed air for example, to forcefully eject a defective container.
  • the sound columnator 26 tends to both focus the transmission of sound energy caused by the pressure fluid flowing through the hole 22 in the container 20 , but also tends to intensify the sound energy as it passes from the hole 22 to the sound detector 24 .
  • the apparatus illustrated in FIG. 1 is placed adjacent the blow molding machine so that the open end of columnator 26 of the sound detector 24 faces the cavity 14 wherein the pressure fluid is injected into the heated preform 16 to cause the preform to expand to form a completed container 20 .
  • the escaping pressure fluid flowing there through would create an acoustic signal which would be sensed by the columnator 26 and thence the sound detector 24 .
  • the sound detector 24 would produce an electric signal in response to the acoustic signal and the electric signal would be sent to the amplifier and discriminator circuit 30 .
  • the signal received from the sound detector 24 is amplified and the amplified signal is sent to the logic circuit 40 .
  • the logic circuit 40 is operative to coordinate and keep tract of the subsequent path of the container facing a hole in the wall thereof and will send an appropriately timed signal to the air blow-off station 50 .
  • the station 50 contains solenoid-operated valves controlling the flow of pressurized air capable of completing the rejection operation. The pressurized air will then be appropriate to remove the container housing the hole from the production line.

Abstract

The invention relates to a method and apparatus for monitoring the production of blow molded plastic containers. It has been discovered that by sonically monitoring the production of a plastic blow molded container, the occurrence of a hole in the wall of the container being formed by a blow molding operation will produce a detectable noise signal. The noise signal is caused by the flow of pressure fluid through the hole. The flow of pressure fluid is caused by the pressure differentiating between the inside and the outside of the container being produced. The noise signal is of an amplitude and frequency readily recognizable from the ambient background noise.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention [0001]
  • The invention relates to a method and apparatus for monitoring the production of plastic blow molded containers. More particularly, the invention contemplates the sensing of defects caused by the formation of holes in the walls of plastic blow molded containers by monitoring the sound adjacent predetermined location along the production line of plastic blow molded containers. [0002]
  • 2. Description of the Prior Art [0003]
  • The leak testing of tanks, pressure vessels, and containers is an important manufacturing consideration in many different industries. In some instances, the gas-tight or liquid tight integrity of these components is usually determined by some form of a pressure-decay test. With this technique, the unit under test is injected with air to some specified overpressure, and the pressure is monitored for a specified period of time. If the pressure does not decay below a specified value at the end of the designated time period, the component under test is considered to be leak-free. [0004]
  • Another technique involves drawing a vacuum on the component being tested and then completely surrounding it with helium gas. A detector inside the vacuum system notifies the operator if helium is present in the air being pumped from the component. [0005]
  • Still another method involves the pressurization/immersion technique which consists of pressurizing the component, totally immersing the component in water or some other clear liquid, and observing the point of bubble emergence. [0006]
  • Yet another method utilizes a collimated beam of light which is scanned across the component under test. The test component has been pressurized with a tracer gas that strongly absorbs the light. When the light passes through the gas emerging from the source of the leak, the light energy absorbed by the gas produces an acoustic emission which is detected by a microphone. The resulting signal may be processed either as an alarm or it may be processed in coordination with the beam scanning mechanism to indicate exactly where the leak is located. [0007]
  • Another method involves apparatus adopted to detect the sound issued outwardly by the individual blow-molding dies during the blow-molding process wherein the sound is converted to an electrical signal and is compared with a reference signal or level and the faulty burst container is rejected. [0008]
  • SUMMARY OF THE INVENTION
  • Amongst the objectives of the present invention is to produce a method and apparatus for monitoring the production of blow molded plastic containers to detect the presence of a hole in the container during production of the containers. [0009]
  • Another object of the invention is to produce a method and apparatus that will detect the presence of a hole in a container being formed by a blow molding process. [0010]
  • Another object of the invention is to produce a method and apparatus for detecting a hole in the wall of a plastic container and producing a signal in response thereto. [0011]
  • The above as well as other objects of the invention may typically be achieved by a method and apparatus for monitoring the production of blow molded plastic containers comprising the steps of introducing pressure fluid to the interior of a plastic container being formed by a blow molding process; [0012]
  • acoustically sensing the sound of pressure fluid travelling through a hole in the plastic container being formed; [0013]
  • producing a control signal in response to the sound produced by the pressure fluid travelling through the hole in the plastic container; and [0014]
  • sensing the amplitude of the control signal to operatively identify the container with the hole. [0015]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • Other objects and advantages of the invention will become readily apparent to those skilled in the art from reading the following detailed description of a preferred embodiment of the invention when considered in the light of the accompanying drawings in which: [0016]
  • FIG. 1 is an enlarged view of the sensing tube placed in proximity to the plastic containers being formed to convey an acoustical signal created by the flow of pressure fluid through a hole in the container being formed during a blow molding operation; and [0017]
  • FIG. 2 is a block diagram of a system for sensing a hole in a plastic blow molded container during the production thereof.[0018]
  • DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
  • Referring to the drawings, there is illustrated a system incorporating the features of the invention, and more particularly disclosing a station along the production line of a typical blow molding machine. [0019]
  • The typical blow molding machines include an annular rotatably mounted platform capable of serially receiving hollow plastic preforms or parisons. The preforms are carried in molds having an inner cavity in the desired configuration or shape of the finished container to be formed. The preforms are heated to a predetermined temperature, which prepares the plastic material to be readily blow molded. Upon reaching the desired temperature, high pressure fluid, such as compressed air, is sequentially introduced into the hollow interior of the preforms. The preforms are thereby caused to expand and assume the shape of the associated mold. The containers are caused to be inspected for defects. In the event a defective container is detected, means are provided for rejecting the container prior to filling or storage. [0020]
  • The completed plastic containers are then transferred, from the annular rotating platform to a conveyor which transports the containers to a filling station. Finally, the filled containers are suitably removed from the conveyor to be stored for later delivery or are immediately loaded on appropriate vehicles for delivery to the ultimate customer. Obviously, unfilled containers may also be off-loaded in a similar fashion. [0021]
  • There are certain instances in which, due to a myriad of reasons, the completed containers have undetected faults such as, for example, minute holes or apertures in the walls of the containers. When these faulty containers are subsequently filled with a fluid such as a carbonated beverage, disastrous results occur. Accordingly, it has become extremely important to develop a method and apparatus for the detection of these difficult to detect faults in plastic containers. [0022]
  • The drawings disclose an apparatus generally indicated by [0023] reference numeral 10 positioned in proximity of the annular rotating platform 12 of a blow-molding machine of the type manufactured by Sidel, a corporation of France. The rotating platform 12 contains an annular array of mold cavities 14 into which heated plastic preforms 16 are indexed to a source 18 of pressure fluid which in most instances is compressed air. The pressure fluid is introduced into the hollow interior of the heated preform 16 causing the preform to expand and assume the shape of the interior of the mold cavity 14 as a completed container 20. In the event a hole 22 is caused to be formed in the wall of the container 20, the pressure fluid from the source 18 escaping through the hole 22 will create an acoustic signal.
  • A [0024] sound detector 24 is positioned adjacent the periphery of the rotating platform 12. The input of the sound detector 24 is coupled to a sound columnator 26. The sound columnator 26 is formed of a hollow plastic tube having the distal end thereof pointed in the direction of the container 20. The sound detector 24 suitable for the purposes of the invention is commercially available and identified as Radio Shack Sound Level Meter Model 33-2050 having an output of from 0 to 1 volt D.C.
  • As illustrated in FIG. 2, the output of the [0025] sound detector 24 is coupled to the input of an amplifier and discriminator 30 which may be set to produce an output signal based upon the amplitude of the voltage signal produced by the sound level meter 26 which may be fed to a logic circuit 40 consisting of timing and/or counting and control logic.
  • The [0026] logic circuit 40 may be coupled to an air blow-off station 50 which is disposed downstream of the acoustic sensor and is effective to remove any defective container sensed by the logic circuit 40. Typically, the air blow-off station 50 includes solenoid operated valves controlling the flow of pressure fluid, such as compressed air for example, to forcefully eject a defective container.
  • It has been surprisingly discovered that the [0027] sound columnator 26 tends to both focus the transmission of sound energy caused by the pressure fluid flowing through the hole 22 in the container 20, but also tends to intensify the sound energy as it passes from the hole 22 to the sound detector 24.
  • Further, it has been found that satisfactory results are achieved by utilizing a plastic tube twelve inches in length and forming of a rigid polyvinyl chloride (PVC) having a nominal I.D. of 1.0 inch, and an O.D. of 1.3 inches. [0028]
  • In operation, the apparatus illustrated in FIG. 1 is placed adjacent the blow molding machine so that the open end of [0029] columnator 26 of the sound detector 24 faces the cavity 14 wherein the pressure fluid is injected into the heated preform 16 to cause the preform to expand to form a completed container 20.
  • Should the [0030] container 20 contain a fault such as a hole 22, or a defect in the finish 23 of the container 20, the escaping pressure fluid flowing there through would create an acoustic signal which would be sensed by the columnator 26 and thence the sound detector 24. The sound detector 24 would produce an electric signal in response to the acoustic signal and the electric signal would be sent to the amplifier and discriminator circuit 30.
  • The signal received from the [0031] sound detector 24 is amplified and the amplified signal is sent to the logic circuit 40. The logic circuit 40 is operative to coordinate and keep tract of the subsequent path of the container facing a hole in the wall thereof and will send an appropriately timed signal to the air blow-off station 50. The station 50 contains solenoid-operated valves controlling the flow of pressurized air capable of completing the rejection operation. The pressurized air will then be appropriate to remove the container housing the hole from the production line.
  • In accordance with the provisions of the patent statutes, the present invention has been described in what is considered to represent its preferred embodiment. However, it should be understood that the invention can be practiced otherwise than as specifically illustrated and described without departing from it's spirit or scope. [0032]

Claims (10)

What is claimed is:
1. A method for monitoring the production of blow molded plastic containers for detecting a hole in the container comprising the steps of:
introducing pressure fluid to the interior of blow molded plastic containers during the production of the containers;
acoustically sensing the sound of pressure fluid travelling through a hole in the container; and
producing a control signal in response to the sound produced by the pressure fluid travelling through the hole in the plastic container.
2. The method defined in claim 1 wherein the step of producing a control signal includes amplifying the control signal.
3. The method defined in claim 2 further including the step of rejecting the container having a hole therein.
4. The method defined in claim 3 wherein said step of rejecting the container includes directing pressure fluid to reject the container having a hole therein.
5. Apparatus for monitoring the production of blow molded plastic containers for detecting a hole in the container comprising:
a conduit for introducing pressure fluid to the interior of blow molded plastic containers during the production of the containers;
a sensor for sensing the sound of pressure fluid travelling through a hole in the container and for producing a control signal in response to the sound; and
a container rejecter for receiving the control signal produced by said sensor for rejecting the container having the hole therein.
6. Apparatus as defined in claim 5 wherein said sensor includes a columnator for transmitting the sound produced by the pressure fluid travelling through the hole.
7. Apparatus as defined in claim 6 wherein said columnator is an elongate hollow cylinder.
8. Apparatus as defined in claim 7 wherein said cylinder is formed of a plastic material.
9. Apparatus as defined in claim 8 wherein said plastic material is polyvinyl chloride.
10. A method for monitoring the production of blow molded plastic containers for detecting a hole in the container comprising the steps of:
introducing pressure fluid to the interior of blow molded plastic containers during the production of the containers;
acoustically sensing the sound of pressure fluid travelling through an incomplete finish of the container; and
producing a control signal in response to the sound produced by the pressure fluid travelling through the incomplete finish of the container.
US10/004,362 2001-11-01 2001-11-01 Method and apparatus for detecting holes in plastic containers Expired - Fee Related US6553809B1 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
US10/004,362 US6553809B1 (en) 2001-11-01 2001-11-01 Method and apparatus for detecting holes in plastic containers
MXPA04004097A MXPA04004097A (en) 2001-11-01 2002-10-31 Method and appparatus for detecting holes in plastic containers.
EP02782254A EP1451549A4 (en) 2001-11-01 2002-10-31 Method and appparatus for detecting holes in plastic containers
NZ532669A NZ532669A (en) 2001-11-01 2002-10-31 Method and apparatus for detecting holes in plastic containers
AU2002348331A AU2002348331B2 (en) 2001-11-01 2002-10-31 Method and apparatus for detecting holes in plastic containers
CA002466089A CA2466089C (en) 2001-11-01 2002-10-31 Method and appparatus for detecting holes in plastic containers
PCT/US2002/034933 WO2003038392A1 (en) 2001-11-01 2002-10-31 Method and apparatus for detecting holes in plastic containers
US10/493,730 US7040167B2 (en) 2001-11-01 2002-10-31 Method and apparatus for detecting holes in plastic containers
BR0213764-0A BR0213764A (en) 2001-11-01 2002-10-31 Method for monitoring the production of blow molded plastic container to detect a defect in any of the containers, and apparatus for monitoring the production of blow molded plastic container formed by introducing a pressure fluid into an interior of a preform in a mold cavity

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/004,362 US6553809B1 (en) 2001-11-01 2001-11-01 Method and apparatus for detecting holes in plastic containers

Related Child Applications (1)

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US10/493,730 Continuation US7040167B2 (en) 2001-11-01 2002-10-31 Method and apparatus for detecting holes in plastic containers

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US6553809B1 US6553809B1 (en) 2003-04-29
US20030079526A1 true US20030079526A1 (en) 2003-05-01

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US10/493,730 Expired - Fee Related US7040167B2 (en) 2001-11-01 2002-10-31 Method and apparatus for detecting holes in plastic containers

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EP (1) EP1451549A4 (en)
AU (1) AU2002348331B2 (en)
BR (1) BR0213764A (en)
CA (1) CA2466089C (en)
MX (1) MXPA04004097A (en)
NZ (1) NZ532669A (en)
WO (1) WO2003038392A1 (en)

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US9074286B2 (en) 2003-10-20 2015-07-07 Novellus Systems, Inc. Wet etching methods for copper removal and planarization in semiconductor processing
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IT201600079175A1 (en) * 2016-07-28 2018-01-28 Fillshape Srl Envelope verification device and procedure for filling lines.
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CA2466089A1 (en) 2003-05-08
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CA2466089C (en) 2009-02-17
WO2003038392A8 (en) 2004-10-07
EP1451549A1 (en) 2004-09-01
US20050181087A1 (en) 2005-08-18
NZ532669A (en) 2005-10-28
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AU2002348331B2 (en) 2006-10-05
US6553809B1 (en) 2003-04-29

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