US20050085562A1 - Ink and method of using the ink - Google Patents

Ink and method of using the ink Download PDF

Info

Publication number
US20050085562A1
US20050085562A1 US10/962,082 US96208204A US2005085562A1 US 20050085562 A1 US20050085562 A1 US 20050085562A1 US 96208204 A US96208204 A US 96208204A US 2005085562 A1 US2005085562 A1 US 2005085562A1
Authority
US
United States
Prior art keywords
ink
weight
drying
water
decelerators
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/962,082
Inventor
Anke Muller
Stefan Engel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JS Staedtler GmbH and Co KG
Original Assignee
JS Staedtler GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JS Staedtler GmbH and Co KG filed Critical JS Staedtler GmbH and Co KG
Assigned to J.S. STAEDTLER GMBH & CO. reassignment J.S. STAEDTLER GMBH & CO. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ENGEL, STEFAN, MULLER, ANKE
Publication of US20050085562A1 publication Critical patent/US20050085562A1/en
Priority to US12/075,577 priority Critical patent/US7612125B2/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0027—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers by lamination or by fusion of the coatings or layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J11/00—Devices or arrangements  of selective printing mechanisms, e.g. ink-jet printers or thermal printers, for supporting or handling copy material in sheet or web form
    • B41J11/0015—Devices or arrangements  of selective printing mechanisms, e.g. ink-jet printers or thermal printers, for supporting or handling copy material in sheet or web form for treating before, during or after printing or for uniform coating or laminating the copy material before or after printing
    • B41J11/002—Curing or drying the ink on the copy materials, e.g. by heating or irradiating
    • B41J11/0022—Curing or drying the ink on the copy materials, e.g. by heating or irradiating using convection means, e.g. by using a fan for blowing or sucking air
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J11/00—Devices or arrangements  of selective printing mechanisms, e.g. ink-jet printers or thermal printers, for supporting or handling copy material in sheet or web form
    • B41J11/0015—Devices or arrangements  of selective printing mechanisms, e.g. ink-jet printers or thermal printers, for supporting or handling copy material in sheet or web form for treating before, during or after printing or for uniform coating or laminating the copy material before or after printing
    • B41J11/002—Curing or drying the ink on the copy materials, e.g. by heating or irradiating
    • B41J11/0024—Curing or drying the ink on the copy materials, e.g. by heating or irradiating using conduction means, e.g. by using a heated platen

Definitions

  • the present invention relates to an aqueous ink or set of inks for printing uncoated vinyl foils or substrates which are coated with vinyl.
  • the present invention also relates to a method of using the ink.
  • Inks for printing foils are known in principle.
  • solvent printers have the disadvantage that these printers have a large structural size because due to the use of organic solvents, such as butylglycol acetate, suction installations or encapsulations must be provided for protecting the operating personnel.
  • solvent printers are more expensive than printers for aqueous systems because the components used in the systems, such as hoses, must be resistant to organic solvents.
  • special foils can be printed with conventional aqueous inks if the vinyl foils are provided with a coating or a rough surface or are otherwise roughened.
  • the decisive disadvantage is the fact that the foils having special coatings are always extremely expensive.
  • the special coatings have a rough surface and a defined porosity in order to impart a good resistance to scratching to the printed images or lines produced with aqueous inks on such foils.
  • EP 0 974 626 A1 discloses an aqueous pigment ink for printing uncoated vinyl substrates.
  • This ink is composed of an aqueous carrier medium, a drying decelerator, a coloring agent which cannot be dissolved, a dispersing agent and a wetting agent.
  • Such ink has the disadvantage that it does not dry well because of the high proportion of drying decelerator on the basis of glycols.
  • the inks after printing, have the tendency to blur or even smudge.
  • the printed images must be dried after the printing process at high temperatures.
  • it has been found to be disadvantageous that these inks are only resistant to scratching after a complicated drying process at temperatures of about 200° C.
  • printers with heating devices are known in the art.
  • the heating devices are constructed essentially plate-shaped and arranged in such a way that the substrate to be printed upon slides over the surfaces of the plates in order to heat the substrate.
  • the printing process is followed with respect to location and time by another heating zone which dries the printed ink.
  • the disadvantage of printers constructed in this manner is the fact that two heating zones are necessary for safely drying the ink on the substrate.
  • an aqueous ink for printing uncoated or untreated vinyl substrates which does not have the above-discussed disadvantages and which dries quickly after printing and ensures a high resistance to scratching.
  • Another object of the invention is to provide an ink which is waterproof after drying.
  • a pigmented ink for printing on untreated vinyl foils or substrates coated with vinyl by means of piezoelectric printing systems which include at least one heating device, wherein the ink is composed of a liquid carrier substance, water insoluble coloring agents, polymeric binding agents, drying decelerators, as well as additional additives, wherein the liquid carrier substance is composed of water and drying decelerators which are mixable in water.
  • the liquid carrier substance has a content of at least 80% by weight water and the content of drying decelerators is composed of at least butyldiglycol and 1-metaxipropanol-2, and the ink has a pH-value of greater than 8.5.
  • the ink according to the present invention for printing untreated vinyl foils or substrates coated with vinyl by means of ink-jet printing systems is composed of a liquid carrier substance, water insoluble coloring agents, polymeric binding agents as well as other additives, wherein the liquid carrier substance is composed of water and water-mixable decelerators, wherein the liquid carrier substance has a content of at least 75% by weight water, preferably 80% by weight water.
  • An additive of the ink is a pH-regulator or adjusting agent, an amine containing substance, which constitutes a content of between 0.5 and 10% by weight of the ink composition.
  • the binding agent used in the ink for example, an acrylate resin, is present in the basic range in a dissolved form, while the acrylate resin is insoluble in the acid or neutral range.
  • the ink according to the present invention has a pH-value of greater than 7.5, preferably greater than 8.5; this has the result that the binding agent is present in a dissolved form in the ink.
  • the binding agent is hardened. Since the amine, an involatile substance, evaporates after the printing process, this results, because of the increasingly lower proportion of amines, in a pH change toward the acid range, so that the binding agent hardens and produces a dried ink layer which is resistant to scratching on the printing medium.
  • Inks of this type are used in inkjet printing systems, especially when the piezotechnology is used.
  • Each of the inks of examples 1-7 contains water as the primary solvent.
  • the ink contains drying decelerators as the liquid carrier substance. Drying decelerators are, for example, glycols, such as butylglycols or diethyleneglycoles and solvenon.
  • the ink according to the present invention has at least one amine or amine-containing substance for adjusting the pH-value.
  • the ink has a pH-value of greater than 7.5, preferably greater than 8.5.
  • amines examples include ethanol amine, triethanol amine, an ammonia solution, diethanol amine as well as mixtures of these amines.
  • the amines utilized in the ink can be described with a general formula N(R1 R2 R3), wherein the free residues R1, R2 and R3 can independently of each other be a hydrogen group, a methyl group, an ethylene group or an ethanol group (CH2 CH2 OH).
  • Pigments can be used as coloring agents.
  • yellow pigments are pigment yellow 155, 150, 13 and 74.
  • red pigments should be mentioned pigment red 122 or generally pigments having a Chinacridon complex.
  • Blue pigments may be pigment blue 15:3, 15 or a pigment with a phtalocyanine complex.
  • Pigment black 7 or generally soot dispersions are examples for black inks.
  • pigments serving as coloring agents are present in a dry or dispersed form.
  • These dispersions are also called color concentrates and are generally aqueous pigment dispersions whose solid content does generally not exceed 40% by weight.
  • the inks according to the present invention are sold in sets of inks, so that the entire color spectrum can be printed in the case of color printing.
  • a set of inks contains the colors cyan, magenta, yellow, black and/or the light colors of cyan and magenta.
  • Conservation agents may be, for example, triazine or solutions of isothiazolinone derivatives. Examples of some commercially available products are Proxel G, Grotan Bk, Parmetol K 40 or Parmetol A 28.
  • the wetting agents used in the inks according to the present invention are fluorotenside, silicon tensides and/or fatty alcohol polyglycol ethers.
  • An ink of this type is used for printing untreated vinyl foils or substrates coated with vinyl by means of ink-jet systems which have at least one heating device in the form of a heating plate and/or an infrared heater.
  • the heating plate may be arranged directly underneath in front of and/or following the printing head, wherein the heating plate extends over the entire path along which the printing head travels.
  • the heating device may be constructed as an infrared radiator which is arranged above the surface to be printed.

Abstract

A pigmented ink for printing on untreated vinyl foils or substrates coated with vinyl by means of piezoelectric printing systems which include at least one heating device, wherein the ink is composed of a liquid carrier substance, water insoluble coloring agents, polymeric binding agents, drying decelerators, as well as additional additives, wherein the liquid carrier substance is composed of water and drying decelerators which are mixable in water. The liquid carrier substance has a content of at least 80% by weight water and the content of drying decelerators is composed of at least butyldiglycol and 1-metaxipropanol-2, and the ink has a pH-value of greater than 8.5.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention
  • The present invention relates to an aqueous ink or set of inks for printing uncoated vinyl foils or substrates which are coated with vinyl. The present invention also relates to a method of using the ink.
  • 2. Description of the Related Art
  • Inks for printing foils are known in principle.
  • When printing vinyl foils, it is necessary to distinguish between the coatings of coated and uncoated foils.
  • For printing uncoated foils, special inks on a non-aqueous basis are known, wherein these inks are also referred to as so-called solvent inks.
  • These inks have the disadvantage that they have a strong and unpleasant odor, are damaging to health and are flammable. This is also partially true for so-called ECO-solvent inks or light-solvent inks. Another disadvantage is to be seen in the fact that solvent inks can only be used in so-called solvent printers which are very expensive. There is no doubt that the above-described solvent inks dissolve the substrate and partially or fully roughen the substrate, so that the dried printed line has a good resistance to stretching.
  • The use of solvent printers has the disadvantage that these printers have a large structural size because due to the use of organic solvents, such as butylglycol acetate, suction installations or encapsulations must be provided for protecting the operating personnel. In addition, solvent printers are more expensive than printers for aqueous systems because the components used in the systems, such as hoses, must be resistant to organic solvents.
  • In addition, special foils can be printed with conventional aqueous inks if the vinyl foils are provided with a coating or a rough surface or are otherwise roughened.
  • However, the decisive disadvantage is the fact that the foils having special coatings are always extremely expensive. The special coatings have a rough surface and a defined porosity in order to impart a good resistance to scratching to the printed images or lines produced with aqueous inks on such foils.
  • In addition, EP 0 974 626 A1 discloses an aqueous pigment ink for printing uncoated vinyl substrates. This ink is composed of an aqueous carrier medium, a drying decelerator, a coloring agent which cannot be dissolved, a dispersing agent and a wetting agent. Such ink has the disadvantage that it does not dry well because of the high proportion of drying decelerator on the basis of glycols. In addition, after printing, the inks have the tendency to blur or even smudge. The printed images must be dried after the printing process at high temperatures. Moreover, it has been found to be disadvantageous that these inks are only resistant to scratching after a complicated drying process at temperatures of about 200° C.
  • For drying the printed images produced in the above-described manner, printers with heating devices are known in the art. The heating devices are constructed essentially plate-shaped and arranged in such a way that the substrate to be printed upon slides over the surfaces of the plates in order to heat the substrate. The printing process is followed with respect to location and time by another heating zone which dries the printed ink. The disadvantage of printers constructed in this manner is the fact that two heating zones are necessary for safely drying the ink on the substrate.
    • SUMMARY OF THE INVENTION
  • Therefore, it is the primary object of the present invention to provide an aqueous ink for printing uncoated or untreated vinyl substrates which does not have the above-discussed disadvantages and which dries quickly after printing and ensures a high resistance to scratching. Another object of the invention is to provide an ink which is waterproof after drying.
  • In accordance with the present invention these objects are met by a pigmented ink for printing on untreated vinyl foils or substrates coated with vinyl by means of piezoelectric printing systems which include at least one heating device, wherein the ink is composed of a liquid carrier substance, water insoluble coloring agents, polymeric binding agents, drying decelerators, as well as additional additives, wherein the liquid carrier substance is composed of water and drying decelerators which are mixable in water. The liquid carrier substance has a content of at least 80% by weight water and the content of drying decelerators is composed of at least butyldiglycol and 1-metaxipropanol-2, and the ink has a pH-value of greater than 8.5.
    • DETAILED DESCRIPTION OF THE INVENTION
  • The ink according to the present invention for printing untreated vinyl foils or substrates coated with vinyl by means of ink-jet printing systems is composed of a liquid carrier substance, water insoluble coloring agents, polymeric binding agents as well as other additives, wherein the liquid carrier substance is composed of water and water-mixable decelerators, wherein the liquid carrier substance has a content of at least 75% by weight water, preferably 80% by weight water.
  • An additive of the ink is a pH-regulator or adjusting agent, an amine containing substance, which constitutes a content of between 0.5 and 10% by weight of the ink composition.
  • The binding agent used in the ink, for example, an acrylate resin, is present in the basic range in a dissolved form, while the acrylate resin is insoluble in the acid or neutral range.
  • At the time of printing, the ink according to the present invention has a pH-value of greater than 7.5, preferably greater than 8.5; this has the result that the binding agent is present in a dissolved form in the ink. By effecting a desired change of the pH-value from the basic range in the direction toward the acid range, wherein the change is controlled in a targeted manner through the quantity of the pH-adjusting agent, the binding agent is hardened. Since the amine, an involatile substance, evaporates after the printing process, this results, because of the increasingly lower proportion of amines, in a pH change toward the acid range, so that the binding agent hardens and produces a dried ink layer which is resistant to scratching on the printing medium.
  • Inks of this type are used in inkjet printing systems, especially when the piezotechnology is used.
  • The invention will now be described in more detail using the following ink examples:
    • EXAMPLE 1 Framework Example
  •   20 to 90% by weight water as solvent
      5 to 40% by weight drying decelerator
     0.5 to 20% by weight binding agent
      1 to 50% by weight coloring agent
     0.5 to 10% by weight pH regulator
    0.01 to 1% by weight conservation agent
    0.05 to 2% by weight wetting agent
      0 to 5% by weight additional additives
    • EXAMPLE 2 Black
  • 51.9 by weight % water as solvent
    12.0 by weight % drying decelerator
     5.0 by weight % binding agent
    25.0 by weight % pigment black
     5.0 by weight % pH regulator
     0.1 by weight % conservation agent
     1.0 by weight % wetting agent
    • EXAMPLE 3 Magenta
  • 60.5 by weight % water as solvent
    13.0 by weight % drying decelerator
     7.4 by weight % binding agent
    16.0 by weight % pigment red 122
     2.0 by weight % pH regulator
     0.1 by weight % conservation agent
     1.0 by weight % wetting agent
    • EXAMPLE 3 Magenta Light
  • 73.6 by weight % deionized water
    13.0 by weight % butyldiglycol + Solvenon
     5.0 by weight % binding agent
     5.3 by weight % Chinacridon complex
     2.0 by weight % ammonia solution
     0.1 by weight % Grotan Bk
     1.0 by weight % silicon tenside
    • EXAMPLE 5 Cyan
  • 64.9 by weight % deionized water
    13.0 by weight % butyldiglycol + Solvenon
     5.0 by weight % binding agent
    11.0 by weight % pigment blue 15
     5.0 by weight % dimethylethanolamine
     0.1 by weight % Proxel G
     1.0 by weight % fatty alcohol polyglycol ether
    • EXAMPLE 6 Cyan Light
  • 72.3 by weight % deionized water
    13.0 by weight % butyldiglycol + Solvenon
     5.0 by weight % binding agent
     3.6 by weight % Phlalocyanine Complex
     5.0 by weight % dimethylethanol amine
     0.1 by weight % Grotan Bk
     1.0 by weight % silicone tenside
    • EXAMPLE 7 Yellow
  • 53.4 by weight % deionized water
    13.0 by weight % butyldiglycol + Solvenon
     5.0 by weight % binding agent
    22.5 by weight % pigment yellow 155
     5.0 by weight % dimethylethanol amine
     0.1 by weight % Grotan Bk
     1.0 by weight % fatty alcohol polyglycol ether
  • Each of the inks of examples 1-7 contains water as the primary solvent. The ink contains drying decelerators as the liquid carrier substance. Drying decelerators are, for example, glycols, such as butylglycols or diethyleneglycoles and solvenon.
  • The ink according to the present invention has at least one amine or amine-containing substance for adjusting the pH-value. Through the basic amines or basic amine-containing substances, the ink produced with these compounds becomes basic, so that additionally the wear at the printing head is minimized, and the durability of the ink supply systems is extended. The ink has a pH-value of greater than 7.5, preferably greater than 8.5.
  • Examples of the amines are ethanol amine, triethanol amine, an ammonia solution, diethanol amine as well as mixtures of these amines.
  • The amines utilized in the ink can be described with a general formula N(R1 R2 R3), wherein the free residues R1, R2 and R3 can independently of each other be a hydrogen group, a methyl group, an ethylene group or an ethanol group (CH2 CH2 OH).
  • Pigments can be used as coloring agents. Examples of yellow pigments are pigment yellow 155, 150, 13 and 74. As representatives of red pigments should be mentioned pigment red 122 or generally pigments having a Chinacridon complex. Blue pigments may be pigment blue 15:3, 15 or a pigment with a phtalocyanine complex. Pigment black 7 or generally soot dispersions are examples for black inks.
  • It is insignificant in this connection whether the pigments serving as coloring agents are present in a dry or dispersed form. These dispersions are also called color concentrates and are generally aqueous pigment dispersions whose solid content does generally not exceed 40% by weight.
  • As a rule, the inks according to the present invention are sold in sets of inks, so that the entire color spectrum can be printed in the case of color printing. Such a set of inks contains the colors cyan, magenta, yellow, black and/or the light colors of cyan and magenta.
  • Conservation agents may be, for example, triazine or solutions of isothiazolinone derivatives. Examples of some commercially available products are Proxel G, Grotan Bk, Parmetol K 40 or Parmetol A 28.
  • The wetting agents used in the inks according to the present invention are fluorotenside, silicon tensides and/or fatty alcohol polyglycol ethers.
  • An ink of this type is used for printing untreated vinyl foils or substrates coated with vinyl by means of ink-jet systems which have at least one heating device in the form of a heating plate and/or an infrared heater.
  • The heating plate may be arranged directly underneath in front of and/or following the printing head, wherein the heating plate extends over the entire path along which the printing head travels. As an alternative or additionally the heating device may be constructed as an infrared radiator which is arranged above the surface to be printed.
  • While specific embodiments of the invention have been shown and described in detail to illustrate the inventive principles, it will be understood that the invention may be embodied otherwise without departing from such principles.

Claims (8)

1. A pigmented ink for printing on untreated vinyl foils or substrates coated with vinyl using piezoelectric printing systems including at least one heating device, the ink comprising
a liquid carrier substance,
water insoluble coloring agents,
polymeric binding agents,
drying decelerators,
additional additives, wherein
the liquid carrier substance is comprised of water and water mixable drying decelerators, wherein
the liquid carrier substance has a content of at least 80% by weight water, wherein
the content of drying decelerators is comprised of at least butyldiglycol and 1-methoxipropanol-2, and wherein
the ink has a pH-value of greater than 8.5.
2. The ink according to claim 1, wherein the pH-regulator is an amine or amine-containing substance, and wherein the amine or the amine-containing substance is basic.
3. The ink according to claim 1, wherein the amine is a dimethylethanol amine, a triethanol amine, an ammonia solution, or a mixture of these substances.
4. The ink according to claim 1, wherein the binding agent is present in the liquid ink in a dissolved form.
5. The ink according to claim 1, wherein the ink comprises
  20 to 90% by weight water as solvent   5 to 40% by weight drying decelerator  0.5 to 20% by weight binding agent   1 to 50% by weight coloring agent  0.5 to 10% by weight pH regulator 0.01 to 1% by weight conservation agent 0.05 to 2% by weight wetting agent   0 to 5% by weight additional additives
6. A method of using an ink or an ink set in an ink-jet printing system which comprises
a liquid carrier substance,
water insoluble coloring agents,
polymeric binding agents,
drying decelerators,
additional additives, wherein the liquid carrier substance is comprised of water and water mixable drying decelerators, wherein
the liquid carrier substance has a content of at least 80% by weight water, wherein the content of drying decelerators is comprised of at least butyldiglycol and 1-methoxipropanol-2, and wherein the ink has a pH-value of greater than 8.5.
7. The method according to claim 6, wherein the heating plate is arranged directly below and in front of and/or following a printing head of the printing system, wherein the heating plate is arranged so as to extend over an entire path traveled by the printing head.
8. The method according to claim 6, wherein the heating device is an infrared radiator arranged above a surface to be printed.
US10/962,082 2003-10-09 2004-10-08 Ink and method of using the ink Abandoned US20050085562A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US12/075,577 US7612125B2 (en) 2003-10-09 2008-03-11 Ink and method of using the ink

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10347034A DE10347034B4 (en) 2003-10-09 2003-10-09 Using an ink
DE10347034.4 2003-10-09

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/075,577 Division US7612125B2 (en) 2003-10-09 2008-03-11 Ink and method of using the ink

Publications (1)

Publication Number Publication Date
US20050085562A1 true US20050085562A1 (en) 2005-04-21

Family

ID=34306345

Family Applications (2)

Application Number Title Priority Date Filing Date
US10/962,082 Abandoned US20050085562A1 (en) 2003-10-09 2004-10-08 Ink and method of using the ink
US12/075,577 Expired - Fee Related US7612125B2 (en) 2003-10-09 2008-03-11 Ink and method of using the ink

Family Applications After (1)

Application Number Title Priority Date Filing Date
US12/075,577 Expired - Fee Related US7612125B2 (en) 2003-10-09 2008-03-11 Ink and method of using the ink

Country Status (7)

Country Link
US (2) US20050085562A1 (en)
EP (1) EP1522561B1 (en)
JP (1) JP4278594B2 (en)
CN (1) CN100363442C (en)
AT (1) ATE432324T1 (en)
DE (2) DE10347034B4 (en)
ES (1) ES2326417T3 (en)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1862513B1 (en) * 2006-06-01 2010-07-21 Basler lacke ag Ink for printing substrates with a non-porous surface
EP2113540B1 (en) 2007-02-23 2013-04-24 Konica Minolta Holdings, Inc. Water-based ink jet ink and recording method
EP2128207B1 (en) 2007-02-26 2012-12-05 Konica Minolta Holdings, Inc. Water-based ink-jet recording ink
JP5444591B2 (en) 2007-04-11 2014-03-19 コニカミノルタ株式会社 Water-based heat fixing type ink and heat fixing type ink jet recording method
EP2199089A1 (en) 2008-12-16 2010-06-23 Basler lacke ag Ink jet printer
WO2010122994A1 (en) 2009-04-23 2010-10-28 コニカミノルタＩｊ株式会社 Water-based inkjet ink, method for producing an inkjet printed product using the same, and method for producing water-based inkjet ink
DE102009032615A1 (en) * 2009-07-10 2011-01-20 J. S. Staedtler Gmbh & Co. Kg Ink for writing, drawing and / or painting equipment and their use
US10632740B2 (en) 2010-04-23 2020-04-28 Landa Corporation Ltd. Digital printing process
BR112014021758B1 (en) 2012-03-05 2021-06-08 Landa Corporation Ltd. paint film structures
US9498946B2 (en) 2012-03-05 2016-11-22 Landa Corporation Ltd. Apparatus and method for control or monitoring of a printing system
EP2822778B1 (en) 2012-03-05 2019-05-08 Landa Corporation Ltd. Digital printing process
WO2013132345A1 (en) 2012-03-05 2013-09-12 Landa Corporation Ltd. Ink film constructions
US10434761B2 (en) 2012-03-05 2019-10-08 Landa Corporation Ltd. Digital printing process
US10642198B2 (en) 2012-03-05 2020-05-05 Landa Corporation Ltd. Intermediate transfer members for use with indirect printing systems and protonatable intermediate transfer members for use with indirect printing systems
US9902147B2 (en) 2012-03-05 2018-02-27 Landa Corporation Ltd. Digital printing system
US9643403B2 (en) 2012-03-05 2017-05-09 Landa Corporation Ltd. Printing system
WO2013132339A1 (en) 2012-03-05 2013-09-12 Landa Corporation Ltd. Treatment of release layer
WO2015036960A1 (en) 2013-09-11 2015-03-19 Landa Corporation Ltd. Release layer treatment formulations
US10190012B2 (en) 2012-03-05 2019-01-29 Landa Corporation Ltd. Treatment of release layer and inkjet ink formulations
JP6393190B2 (en) 2012-03-15 2018-09-19 ランダ コーポレイション リミテッド Endless flexible belt for printing system
GB201401173D0 (en) 2013-09-11 2014-03-12 Landa Corp Ltd Ink formulations and film constructions thereof
GB2536489B (en) 2015-03-20 2018-08-29 Landa Corporation Ltd Indirect printing system
GB2537813A (en) 2015-04-14 2016-11-02 Landa Corp Ltd Apparatus for threading an intermediate transfer member of a printing system
GB201609463D0 (en) 2016-05-30 2016-07-13 Landa Labs 2012 Ltd Method of manufacturing a multi-layer article
US10933661B2 (en) 2016-05-30 2021-03-02 Landa Corporation Ltd. Digital printing process
CN110959028B (en) * 2017-08-02 2022-09-09 花王株式会社 Aqueous pigment dispersions
WO2019026805A1 (en) * 2017-08-02 2019-02-07 花王株式会社 Polymer emulsion
CN111212736B (en) 2017-10-19 2021-11-23 兰达公司 Endless flexible belt for a printing system
JP7225230B2 (en) 2017-11-19 2023-02-20 ランダ コーポレイション リミテッド digital printing system
US11511536B2 (en) 2017-11-27 2022-11-29 Landa Corporation Ltd. Calibration of runout error in a digital printing system
US11707943B2 (en) 2017-12-06 2023-07-25 Landa Corporation Ltd. Method and apparatus for digital printing
US11679615B2 (en) 2017-12-07 2023-06-20 Landa Corporation Ltd. Digital printing process and method
EP3814144A4 (en) 2018-06-26 2022-03-16 Landa Corporation Ltd. An intermediate transfer member for a digital printing system
US10994528B1 (en) 2018-08-02 2021-05-04 Landa Corporation Ltd. Digital printing system with flexible intermediate transfer member
WO2020075012A1 (en) 2018-10-08 2020-04-16 Landa Corporation Ltd. Friction reduction means for printing systems and method
CN113272144B (en) 2018-12-24 2023-04-04 兰达公司 Digital printing system and method
JP2023505035A (en) 2019-11-25 2023-02-08 ランダ コーポレイション リミテッド Ink drying in digital printing using infrared radiation absorbed by particles embedded inside the ITM
US11321028B2 (en) 2019-12-11 2022-05-03 Landa Corporation Ltd. Correcting registration errors in digital printing

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5106417A (en) * 1989-10-26 1992-04-21 Ciba-Geigy Corporation Aqueous printing ink compositions for ink jet printing
US5156675A (en) * 1991-05-16 1992-10-20 Xerox Corporation Ink for ink jet printing
US5316575A (en) * 1992-10-08 1994-05-31 Videojet Systems, International, Inc. Pigmented, low volatile organic compound, ink jet composition and method
US5512089A (en) * 1994-08-23 1996-04-30 Scitex Digital Printing, Inc. Process of making aqueous pigmented ink-jet ink with improved machine runnability
US5640187A (en) * 1992-09-10 1997-06-17 Canon Kabushiki Kaisha Ink jet recording method and ink jet recording apparatus therefor
US5889083A (en) * 1996-09-06 1999-03-30 Videojet Systems International, Inc. Aqueous jet ink compositions
US5969005A (en) * 1996-07-08 1999-10-19 Fuji Xerox Co., Ltd Ink for ink jet recording and ink jet recording method
US7137694B2 (en) * 2003-09-29 2006-11-21 Hewlett-Packard Development Company, L.P. Ink drying system for printer

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5221334A (en) * 1990-04-11 1993-06-22 E. I. Du Pont De Nemours And Company Aqueous pigmented inks for ink jet printers
US5085698A (en) * 1990-04-11 1992-02-04 E. I. Du Pont De Nemours And Company Aqueous pigmented inks for ink jet printers
US6087416A (en) * 1998-07-22 2000-07-11 E.I. Du Pont De Nemours And Company Aqueous pigmented ink jet inks for printing on vinyls
EP0997301A3 (en) * 1998-10-30 2000-07-12 Xerox Corporation Infrared foil heater for drying ink jet images on a recording medium
DE10055744A1 (en) * 2000-11-10 2002-05-23 Advanced Photonics Tech Ag Small drying unit for coatings on substrates, such as ink on paper in home or office, comprises near infrared source with cooled reflector and safety casing
US20030055135A1 (en) * 2001-09-17 2003-03-20 Westvaco Corporation Pigmented ink jet inks

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5106417A (en) * 1989-10-26 1992-04-21 Ciba-Geigy Corporation Aqueous printing ink compositions for ink jet printing
US5156675A (en) * 1991-05-16 1992-10-20 Xerox Corporation Ink for ink jet printing
US5640187A (en) * 1992-09-10 1997-06-17 Canon Kabushiki Kaisha Ink jet recording method and ink jet recording apparatus therefor
US5316575A (en) * 1992-10-08 1994-05-31 Videojet Systems, International, Inc. Pigmented, low volatile organic compound, ink jet composition and method
US5512089A (en) * 1994-08-23 1996-04-30 Scitex Digital Printing, Inc. Process of making aqueous pigmented ink-jet ink with improved machine runnability
US5969005A (en) * 1996-07-08 1999-10-19 Fuji Xerox Co., Ltd Ink for ink jet recording and ink jet recording method
US5889083A (en) * 1996-09-06 1999-03-30 Videojet Systems International, Inc. Aqueous jet ink compositions
US7137694B2 (en) * 2003-09-29 2006-11-21 Hewlett-Packard Development Company, L.P. Ink drying system for printer

Also Published As

Publication number Publication date
US20080161457A1 (en) 2008-07-03
CN1618897A (en) 2005-05-25
CN100363442C (en) 2008-01-23
ATE432324T1 (en) 2009-06-15
DE502004009520D1 (en) 2009-07-09
JP4278594B2 (en) 2009-06-17
US7612125B2 (en) 2009-11-03
DE10347034A1 (en) 2005-05-19
JP2005113147A (en) 2005-04-28
EP1522561B1 (en) 2009-05-27
DE10347034B4 (en) 2006-11-09
EP1522561A1 (en) 2005-04-13
ES2326417T3 (en) 2009-10-09

Similar Documents

Publication Publication Date Title
US7612125B2 (en) Ink and method of using the ink
KR101747006B1 (en) Fixer fluids
JP5277549B2 (en) Water-based inkjet ink
CN104159983B (en) Ink composite
CN101412865B (en) Inkjet recording aqueous ink
CN102781677B (en) Inkjet treatment liquid, inkjet recording apparatus, inkjet recording method and image formation
EP0583168B1 (en) Method and device for ink jet recording
EP1577354B1 (en) Ink-jet imaging on offset media
JP4843805B2 (en) Ink jet ink and printing method using the same
US8865793B2 (en) Water-based ink-jet recording ink
EP1951826B1 (en) Use of marking fluids for vinyl substrates
EP2285920B1 (en) Ink-jet overcoat composition and related systems and methods
JP2014019811A (en) Ink set and printing method using the same
JP2004195451A (en) Image recording element on which image is formed with transparent overcoat
US11034851B2 (en) Ink sets
WO2013095332A1 (en) Pretreatment fluids with ammonium metal chelate cross-linker for printing media
JP2009263557A (en) Water-based inkjet ink
WO2018105416A1 (en) Recording-liquid set, ink-jet recording method, and ink/recording medium set
JP2005521575A (en) Compositions and methods
JP7206853B2 (en) Ink, printing method and inkjet printing apparatus
JP3734164B2 (en) Undercoat agent for preventing bleeding
KR20170125330A (en) Aqueous inkjet ink composition for printing on non-absorbent base material
JP2023039058A (en) Pre-coating liquid, ink set, printing method and inkjet printing apparatus
JP2023144702A (en) Aqueous inkjet ink for printing, and method for manufacturing printed matter
KR20040081593A (en) Ink composition for ink jet printer

Legal Events

Date Code Title Description
AS Assignment

Owner name: J.S. STAEDTLER GMBH & CO., GERMANY

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:MULLER, ANKE;ENGEL, STEFAN;REEL/FRAME:015891/0432

Effective date: 20041006

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION