US20070039324A1 - Novel fuel production plant and seawater desalination system for use therein - Google Patents

Novel fuel production plant and seawater desalination system for use therein Download PDF

Info

Publication number
US20070039324A1
US20070039324A1 US10/557,797 US55779703A US2007039324A1 US 20070039324 A1 US20070039324 A1 US 20070039324A1 US 55779703 A US55779703 A US 55779703A US 2007039324 A1 US2007039324 A1 US 2007039324A1
Authority
US
United States
Prior art keywords
cooling water
steam
seawater
desalination system
novel fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/557,797
Inventor
Taiji Inui
Tsunehisa Kawaguchi
Hiroshi Yagi
Yasuto Ando
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Assigned to HITACHI, LTD. reassignment HITACHI, LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ANDO, YASUTO, YAGI, HIROSHI, KAWAGUCHI, TSUNEHISA, INUI, TAIJI
Publication of US20070039324A1 publication Critical patent/US20070039324A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/06Flash evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/16Treatment of water, waste water, or sewage by heating by distillation or evaporation using waste heat from other processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/26Multiple-effect evaporating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/06Flash distillation
    • B01D3/065Multiple-effect flash distillation (more than two traps)
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/131Reverse-osmosis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

Definitions

  • GTL Gas-To-Liquid
  • DME dimethylether
  • the fuel synthesizing reaction is itself an exothermic reaction.
  • a large amount of excess heat is inevitable generated, thus resulting in the necessity of installing exhaust heat boilers to generate high- and medium-pressure steam for heat recovery.
  • the generated high- and medium-pressure steam can be utilized by steam turbines for driving compressors, pumps, generators, etc. in the plant.
  • a system using steam turbines requires a large amount of cooling water to condense steam.
  • seawater has been used in many cases primarily for the economical reason.
  • the merit resulting from using seawater as the cooling water is reduced because of regulations, such as charging for use of seawater and a limitation on the temperature difference between seawater and cooling water (i.e., the difference between the temperature of returned seawater and the temperature of supplied seawater), which have been legislated with recent increasing environmental awareness.
  • the limitation on the temperature difference between seawater and cooling water often increases the amount of required cooling water 3-5 times that required in the past. Under such a situation, large-scaled water taking-in equipment has to be installed and the economical merit is lost in most cases.
  • An evaporation method e.g., a multistage flash method or a multiple effect method, which is a potential candidate utilizing excess low-pressure steam, is not taken into consideration because it requires a seawater intake amount 3-4 times that required in a system using the reverse osmosis membrane method for the same amount of produced water even when the intake-discharge temperature difference of seawater is 10° C. that has been allowed in the past, and it requires a larger seawater intake amount when the intake-discharge temperature difference of seawater is limited to be lower than 10° C.
  • An object of the present invention is to provide a novel fuel production plant and a seawater desalination system for use therein in which an evaporation water production system can be applied at a seawater intake amount comparable to that required in a system using the reverse osmosis membrane method, the degree of freedom in selecting the plant installation site is high, salinity of produced water is reduced as compared with that in the case using the reverse osmosis membrane method, and the merit of the evaporation water production system having a low maintenance cost can be enjoyed.
  • the present invention provides a novel fuel production plant for producing synthesized gas from a feedstock and producing novel fuel from the produced synthesized gas, the novel fuel production plant comprising an exhaust heat recovery boiler for generating steam by recovering excess heat generated from the fuel production processes, the novel fuel production plant further comprising an exhaust heat utilizing section including a steam turbine driven with the steam generated from the exhaust heat recovery boiler, an open circulation cooling water supply section for supplying cooling water for a plant, including water for cooling exhaust of the steam turbine, and a seawater desalination system using an evaporation method and supplying desalinated water to replenish the open circulation cooling water, wherein the cooling water supplied from the open circulation cooling water supply section is used in condensing of the desalinated water produced by the seawater desalination system.
  • fresh water can be produced at a seawater intake amount comparable to that required in a system using the reverse osmosis membrane method, and the cooling water can be supplied with a lower remaining salinity in the produced water and a lower maintenance cost than those in the case using the reverse osmosis membrane method.
  • the present invention provides a seawater desalination system for desalinating seawater by using an evaporation method and supplying desalinated water, wherein cooling water supplied from an open circulation cooling water supply section is used in condensing of the desalinated water produced by the seawater desalination system.
  • fresh water can be produced at a seawater intake amount comparable to that required in a system using the reverse osmosis membrane method, and the cooling water can be supplied with a lower remaining salinity in the produced water and a lower maintenance cost than those in the system using the reverse osmosis membrane method.
  • FIG. 1 is a diagram showing the construction of a novel fuel production plant according to one embodiment of the present invention.
  • the novel fuel production plant of this embodiment comprises a novel fuel producing section 100 , an exhaust heat utilizing section 200 , and a cooling water supply section 300 .
  • the novel fuel producing section 100 produces new fuel from a feedstock and generates steam by utilizing exhaust heat.
  • steam turbines are driven using the steam generated by the novel fuel producing section 100 , to thereby drive rotary machines, etc.
  • the cooling water supply section 300 supplies cooling water used in condensers for the steam turbines in the exhaust heat utilizing section 200 .
  • the novel fuel producing section 100 comprises an air compressor 1 , an air separator 2 , an oxygen booster 3 , a reaction/reforming furnace 4 , exhaust heat recovery boilers 5 and 8 , a fuel synthesizing reactor 7 , etc.
  • the feedstock is supplied to the reaction/reforming furnace 4 through a piping 50 .
  • Usable raw materials supplied as the feedstock includes, for example, hydrocarbons such as coal, oil and natural gas, biomass, wasted plastics, etc.
  • natural gas is used as the feedstock.
  • steam, carbon dioxide, etc. may also be supplied in addition to those raw materials.
  • the reaction/reforming furnace 4 is supplied with oxygen through a piping 51 .
  • the oxygen is obtained by compressing air by the air compressor 1 , separating the compressed air by the air separator 2 , and boosting the pressure of the separated oxygen by the oxygen booster 3 .
  • synthesized gas mainly consisted of hydrogen and carbon monoxide is produced from the feedstock gas supplied through the piping 50 and the oxygen supplied through the piping 51 by partial oxidation or auto-thermal reforming, for example.
  • the produced synthesized gas is taken out through a piping 52 .
  • the hot synthesized gas thus produced by the reaction/reforming furnace 4 is supplied to the exhaust heat recovery boiler 5 where steam (high-pressure steam) is generated to lower the temperature of the synthesized gas.
  • the synthesized gas is then supplied to the fuel synthesizing reactor 7 .
  • the synthesized gas is further synthesized into novel fuel under the action of a catalyst.
  • the reaction heat generated at this time is recovered by generating steam (medium-pressure steam) in the exhaust heat recovery boiler 8 .
  • the novel fuel synthesized by the fuel synthesizing reactor 7 , unreacted gases, etc. are sent via a piping 53 to a succeeding liquefying/refining step for liquefaction and refining.
  • the heat of the fuel synthesizing reaction can be recovered from reaction products after exiting the reactor as shown, or can be recovered directly from the interior of the reactor in other cases.
  • the synthesized gas at an outlet of the reaction/reforming furnace 4 has very high temperatures.
  • the fuel synthesizing reaction carried out in the fuel synthesizing reactor 7 of the succeeding stage is an exothermic reaction, and the synthesized gas at an inlet of the fuel synthesizing reactor 7 requires to be cooled down to a temperature suitable for the synthesizing reaction.
  • the exhaust heat recovery boilers 5 , 8 are installed to generate high- and medium-pressure steam for heat recovery.
  • the generated high- and medium-pressure steam is used in the exhaust heat utilizing section 200 by the steam turbines for driving compressors, pumps, generators, etc. in the plant.
  • low-pressure steam is rather excessive because it is used just as a heat source for a reboiler in a part of equipment for liquefying and refining the fuel synthesizing reaction gas, a heat source for degassing feedwater for a boiler, etc.
  • many steam condensing turbines are used from the viewpoint of operating the steam turbines with higher efficiency and keeping steam balance in consideration of the less number of heat sources requiring the low-pressure steam, a larger amount of cooling water is required to condense steam correspondingly.
  • the exhaust heat utilizing section 200 will be described below.
  • the exhaust heat utilizing section 200 comprises a high-pressure steam line, a medium-pressure steam line, and a low-pressure steam line.
  • the high-pressure steam line is constituted by the exhaust heat recovery boiler 5 , a high-pressure boiler 6 , and a high-pressure steam header 54 .
  • High-pressure steam generated by the exhaust heat recovery boiler 5 is used by a steam turbine 9 for driving the feedstock air compressor 1 , a steam turbine 12 for driving the oxygen booster 3 , etc.
  • Exhausts of the driving steam turbines 9 , 12 are cooled in condensers 10 , 13 , etc. by plant circulation cooling water, and are returned to a degasser 25 by condensate transfer pumps 11 , 14 , etc.
  • High-pressure boiler feedwater is withdrawn from the degasser 25 and is boosted up to a predetermined pressure by a high-pressure boiler feedwater pump 27 , followed by being supplied to the exhaust heat recovery boiler 5 and the high-pressure boiler 6 .
  • medium-pressure boiler feedwater is withdrawn from the degasser 25 and is boosted up to a predetermined pressure by a medium-pressure boiler feedwater pump 26 , followed by being supplied to the exhaust heat recovery boiler 8 .
  • the high-pressure steam that is insufficient from the viewpoint of steam balance is supplied to the high-pressure steam header 54 by the high-pressure boiler 6 .
  • the medium-pressure steam line is constituted by the exhaust heat recovery boiler 8 and a medium-pressure steam header 55 .
  • Medium-pressure steam generated by the exhaust heat recovery boiler 8 is used by a pump-driving steam turbine 17 , steam turbines 18 , 21 for driving process gas compressors, etc.
  • the pump-driving steam turbine 17 , the steam turbine 18 for driving the process gas compressor, etc. operate as backpressure turbines and supply the low-pressure steam to a low-pressure steam header 56 .
  • the steam turbine 21 for driving the process gas compressor operates as a condensing turbine. From the viewpoint of steam balance, exhausts of the steam turbine 21 for driving the process gas compressor, etc. are cooled in a condenser 22 , etc. by the plant circulation cooling water, and are returned to the degasser 25 by a condensate transfer pump 23 , etc.
  • a condensing turbine may be used as the steam turbine 18 .
  • a condensing turbine is used as the steam turbine 18 for driving the process gas compressor, the amount of the supplied low-pressure steam becomes insufficient. For that reason, in this embodiment, a backpressure turbine is used to increase the amount of the supplied low-pressure steam.
  • the medium-pressure steam line further includes a gas turbine generator 36 and a gas-turbine exhaust heat boiler 37 .
  • the gas-turbine exhaust heat boiler 37 generates medium-pressure steam and supplies the generated medium-pressure steam to a medium-pressure steam header 55 .
  • the lower-pressure steam line is constituted by a lower-pressure steam header 56 and supplies the lower-pressure steam, which has been received from the pump-driving steam turbine 17 , etc., to a reboiler 47 , the degasser 25 , etc.
  • the lower-pressure steam is also supplied to the brine heater 40 and utilized as a heat source for a seawater desalination system using the evaporation method. In this case, excess steam is set to zero by adjusting a water production rate in the seawater desalination system using the evaporation method.
  • the cooling water supply section 300 will be described below.
  • the cooling water supply section 300 comprises a plant open circulation cooling-water line and a water production line.
  • the plant open circulation cooling-water line is constituted by a cooling tower 34 , a cooling water circulation pump 35 , and a cooling water circulation piping 59 .
  • the cooling water is supplied to the condensers 10 , 13 , 22 , etc. through the cooling water circulation piping 59 .
  • the cooling water having temperature raised with heat exchanges in the condensers 10 , 13 , 22 , etc. is cooled in the cooling tower 34 using the atmosphere, and is circulated within the line after pressure is boosted by the cooling water circulation pump 35 .
  • a part of the cooling water lost by evaporation during the cooling step in the cooling tower 34 using the atmosphere is replenished from the water production line.
  • the water production line employs the multistage flash method as one example of the evaporation method.
  • the water production line is constituted by a heat radiating section 38 of a multistage-flash water production system, a heat recovering section 39 of the multistage-flash water production system, the brine heater 40 , a seawater/brine heat exchanger 41 , a degassing tank 42 , a brine circulation pump 43 , and a vacuum generator 44 .
  • the heat radiating section 38 of the multistage-flash water production system cools and condenses steam evaporated from circulating brine to recover fresh water. Desalted water thus produced is temporarily stored in a desalted water tank 31 and then supplied as makeup water for the plant circulation cooling-water line by a desalted water supply pump 32 .
  • the plant circulation cooling water supplied through a piping 66 is used as a fresh water condensing coolant in the heat radiating section 38 of the multistage-flash water production system.
  • the cooling water exiting the heat radiating section 38 of the multistage-flash water production system is returned to the cooling tower 34 through a piping 63 .
  • the seawater/brine heat exchanger 41 performs heat exchange between seawater supplied through a piping 60 and drain brine discharged through a piping 61 so that the temperature of the discharged brine is lowered and heat is recovered to the supplied seawater.
  • the seawater having passed the seawater/brine heat exchanger 41 is degassed in a degassing tank 42 and then supplied, through a piping 65 , to low-temperature circulating brine that is circulated through a low-temperature circulating brine 64 .
  • the low-temperature circulating brine 64 to which seawater has been newly replenished is boosted in pressure by the brine circulation pump 43 , and is then introduced to the heat recovering section 39 of the multistage-flash water production system.
  • the low-temperature circulating brine 64 serves to not only cool and condense the steam evaporated from high-temperature circulating brine, but also to recover heat for raising the temperature thereof.
  • the brine having temperature further raised by the brine heater 40 using the low-pressure steam becomes high-temperature circulating brine 67 that is successively introduced for flashing to respective steps (stages) of both the heat recovering section 39 and the heat radiating section 38 of the multistage-flash water production system, which have been held in lower-pressure states by the vacuum generator 44 using the medium-pressure steam.
  • the high-temperature circulating brine 67 is gradually condensed and cooled while being flashed in the respective stages.
  • the evaporation method used in the water production line is not limited to the above-described multistage flash method, and the multiple effect method may be used instead. Further, both the multistage flash method and the multiple effect method may be used in a combined manner.
  • a first feature of the above-described novel fuel production plant of this embodiment resides in that the plant circulation cooling water supplied through the piping 66 is used as the fresh water condensing coolant in the heat radiating section 38 of the multistage-flash water production system.
  • the plant circulation cooling water supplied through the piping 66 is used as the fresh water condensing coolant in the heat radiating section 38 of the multistage-flash water production system.
  • the known seawater desalination system using the reverse osmosis membrane method has to take in seawater at a rate of 1500 t/hour, i.e., about twice the rate of the required fresh water, on condition that the known system is one having the highest fresh water recovery rate.
  • the seawater intake amount required in the known seawater desalination system using the evaporation method is 6000 t/hour.
  • 4500 t/hour is the amount of seawater used as the fresh water condensing coolant in the heat radiating section 38 of the multistage-flash water production system
  • 1500 t/hour is the amount of seawater required for the water production.
  • the seawater intake amount is not affected by the limitation on the temperature difference between the seawater and the cooling water and remains at 1500 t/hour.
  • a temperature difference ⁇ T 2 between the cooling water flowing through the piping 66 and the cooling water returned from the piping 63 is set to 10° C.
  • the seawater intake amount can be reduced to a level comparable to that required in the known seawater desalination system using the reverse osmosis membrane method. Also, according to this embodiment, there is no need of considering corrosion resistance to salt contained in the seawater with respect to piping materials for the heat radiating section 38 of the multistage-flash water production system, and hence a relatively inexpensive material can also be used.
  • a second feature of the present invention resides in that the evaporation method, e.g., the multistage flash method or the multiple effect method, is applied to the water production line for desalinating seawater.
  • the evaporation method e.g., the multistage flash method or the multiple effect method
  • replacement of an expensive membrane is no longer required and the maintenance cost of the water production system is reduced.
  • the evaporation method can produce fresh water with a lower remaining salinity than the reverse osmosis membrane method. As a result, the maintenance cost of the cooling water line is also reduced.
  • a third feature of this embodiment resides in that a backpressure turbine is used as the steam turbine 18 for driving the process gas compressor to compensate for the amount of the low-pressure steam consumed by the brine heater 40 .
  • the amount of the supplied lower-pressure steam can be increased.
  • the use of a backpressure turbine eliminates the need of an additional condenser for use with a condensing turbine, the amount of the circulated cooling water is reduced correspondingly. Even though the amount Q 2 of the cooling water circulated through the heat radiating section 38 of the multistage-flash water production system is increased by 4500 t/hour as described above, the amount of the circulated cooling water can be reduced by about 1500 t/hour as a result of not using the additional condenser.
  • a fourth feature of this embodiment resides in that the gas turbine generator 36 is installed as a power supply source for the plant and the gas-turbine exhaust heat boiler 37 is installed to generate the medium-pressure steam.
  • a steam turbine can be installed at a position indicated by a symbol X in the drawing similarly to the steam turbine 12 .
  • that steam turbine has to be constituted in similar arrangement of the driving steam turbine 21 , the condenser 13 and the condensate transfer pump 14 , and hence an additional condenser is required. Since the use of the gas turbine eliminates the need of an additional condenser, the amount of the circulated cooling water is reduced correspondingly.
  • the amount Q 2 of the cooling water circulated through the heat radiating section 38 of the multistage-flash water production system is increased by, e.g., 4500 t/hour as described above, the amount of the circulated cooling water can be reduced by about 3100 t/hour as a result of not using the additional condenser.
  • the amount of the circulated cooling water can be reduced by the amount of the cooling water used by the two condensers, i.e., 4600 t/hour, and therefore the amount of the circulated cooling water can be reduced by 100 t/hour as a whole.
  • the novel fuel production plant of this embodiment can be started up on a stand-alone basis, thus resulting in higher operability of the plant. Also, since the use of the evaporation method in the water production system eliminates the need of a high-pressure seawater pump consuming a large quantity of power, which has been required in the reverse osmosis membrane system, the output power of the generator can be reduced by about 15%. Additionally, since a gas turbine is used as a generator driver, the amount of the required high-pressure steam can be reduced correspondingly and so can be the capacity in operation of the high-pressure boiler.
  • a fifth feature of this embodiment resides in that the lower-pressure steam generated in the exhaust heat utilizing section 200 is supplied to and utilized by the brine heater 40 of the multistage-flash water production system.
  • the excess steam can be consumed by changing a water production rate of the water production system, or it can be eliminated by optimizing the steam balance.
  • the water production rate if the lower-pressure steam is excessive and the water production rate can be adjusted to a lower value, it is also possible to reduce the number of stages and the number of evaporators in the water production system, thereby cutting the equipment cost.
  • a sixth feature of this embodiment resides in that the seawater/brine heat exchanger 41 is installed to perform heat exchange between the brine discharged from the evaporation water production system and the seawater supplied to it. With the sixth feature, heat can be recovered and the temperature of the discharged brine can be kept not higher than a predetermined value when the intake-discharge temperature difference of seawater is specified as a result of control for environmental protection.
  • the seawater desalination system is intended to desalinate seawater by using the evaporation method and to supply the desalinated water for replenishment of the cooling water, and it is featured in that the cooling water supplied from the open circulation cooling water supply section is used in condensing of the desalinated water produced by the seawater desalination system.
  • the seawater desalination system can be employed not only to supply the cooling water in the novel fuel production plant, but also as a fresh water supply source in an oil refinery, a chemical plant, a steam-turbine power generation plant, etc.
  • a water production system using the evaporation method can be employed with a seawater intake amount comparable to that required in a system using the reverse osmosis membrane method, and the merit of the evaporation water production system having a lower maintenance cost than the reverse osmosis membrane method can be enjoyed.

Abstract

A novel fuel producing section produces synthesized gas from a feedstock and synthesizes novel fuel from the synthesized gas thus produced, and has exhaust heat recovery boilers for generating steam by recovering excess heat generated from the synthesizing processes. An exhaust heat utilizing section includes steam turbines driven with the steam generated from the exhaust heat recovery boilers. An open circulation cooling water supply section supplies cooling water for a plant, including water for cooling exhausts of the steam turbines, and includes a seawater desalination system for desalinating seawater by the evaporation method and supplying desalinated water to replenish the cooling water. The cooling water supplied from the open circulation cooling water supply section is used in condensing of the desalinated water produced by the seawater desalination system.

Description

    TECHNICAL FIELD
  • The present invention relates to a novel fuel production plant for producing novel fuel, and to a seawater desalination system for use in the plant.
  • BACKGROUND ART
  • Recently, attention has been focused on plants for producing novel fuel, such as Gas-To-Liquid (GTL) and dimethylether (DME). As a novel fuel production plant, one known example for producing dimethylether by using natural gas as a feedstock is disclosed in, e.g., JP,A 10-195008.
  • DISCLOSURE OF THE INVENTION
  • In plants for producing novel fuel, such as GTL and DME, (hereinafter referred to as “novel fuel production plants” or simply as “plants”), for example, a partial oxidation method or an auto-thermal reforming method using hydrocarbons, etc. as a feedstock is employed to produce synthesized gas necessary for synthesizing fuel. In those synthesized gas producing methods, the temperature of the synthesized gas at an outlet of a reaction/reforming furnace is very high (1200-1500° C.). On the other hand, from the viewpoint of synthesizing fuel in a succeeding stage, the synthesized gas has to be cooled down to synthesizing reaction temperatures (200-300° C.) at an inlet of a fuel synthesizing reactor. Also, the fuel synthesizing reaction is itself an exothermic reaction. In the novel fuel production plant, therefore, a large amount of excess heat is inevitable generated, thus resulting in the necessity of installing exhaust heat boilers to generate high- and medium-pressure steam for heat recovery. The generated high- and medium-pressure steam can be utilized by steam turbines for driving compressors, pumps, generators, etc. in the plant.
  • A system using steam turbines requires a large amount of cooling water to condense steam. Hitherto, in facilities requiring a large amount of cooling water, seawater has been used in many cases primarily for the economical reason. However, the merit resulting from using seawater as the cooling water is reduced because of regulations, such as charging for use of seawater and a limitation on the temperature difference between seawater and cooling water (i.e., the difference between the temperature of returned seawater and the temperature of supplied seawater), which have been legislated with recent increasing environmental awareness. The limitation on the temperature difference between seawater and cooling water often increases the amount of required cooling water 3-5 times that required in the past. Under such a situation, large-scaled water taking-in equipment has to be installed and the economical merit is lost in most cases. For that reason, it is tried to employ, as a cooling water system for a plant, an open circulation cooling water system provided with a cooling tower, and to minimize the amount of used seawater by compensating for only losses, which are caused due to evaporation, scattering and forced blow from the cooling tower, with desalination of seawater.
  • In such a try, for the desalination of seawater, a reverse osmosis membrane method is primarily studied because this method requires a less seawater intake amount in spite of accompanying the problems that the remaining salinity is high, a plant cannot be practically installed in some cases depending on properties of seawater, and a membrane occupying about ⅓ of the overall plant cost has to be frequently replaced, thus resulting in a higher maintenance cost. An evaporation method, e.g., a multistage flash method or a multiple effect method, which is a potential candidate utilizing excess low-pressure steam, is not taken into consideration because it requires a seawater intake amount 3-4 times that required in a system using the reverse osmosis membrane method for the same amount of produced water even when the intake-discharge temperature difference of seawater is 10° C. that has been allowed in the past, and it requires a larger seawater intake amount when the intake-discharge temperature difference of seawater is limited to be lower than 10° C.
  • An object of the present invention is to provide a novel fuel production plant and a seawater desalination system for use therein in which an evaporation water production system can be applied at a seawater intake amount comparable to that required in a system using the reverse osmosis membrane method, the degree of freedom in selecting the plant installation site is high, salinity of produced water is reduced as compared with that in the case using the reverse osmosis membrane method, and the merit of the evaporation water production system having a low maintenance cost can be enjoyed.
  • To achieve the above object, the present invention provides a novel fuel production plant for producing synthesized gas from a feedstock and producing novel fuel from the produced synthesized gas, the novel fuel production plant comprising an exhaust heat recovery boiler for generating steam by recovering excess heat generated from the fuel production processes, the novel fuel production plant further comprising an exhaust heat utilizing section including a steam turbine driven with the steam generated from the exhaust heat recovery boiler, an open circulation cooling water supply section for supplying cooling water for a plant, including water for cooling exhaust of the steam turbine, and a seawater desalination system using an evaporation method and supplying desalinated water to replenish the open circulation cooling water, wherein the cooling water supplied from the open circulation cooling water supply section is used in condensing of the desalinated water produced by the seawater desalination system.
  • With that arrangement, fresh water can be produced at a seawater intake amount comparable to that required in a system using the reverse osmosis membrane method, and the cooling water can be supplied with a lower remaining salinity in the produced water and a lower maintenance cost than those in the case using the reverse osmosis membrane method.
  • Also, to achieve the above object, the present invention provides a seawater desalination system for desalinating seawater by using an evaporation method and supplying desalinated water, wherein cooling water supplied from an open circulation cooling water supply section is used in condensing of the desalinated water produced by the seawater desalination system.
  • With that arrangement, fresh water can be produced at a seawater intake amount comparable to that required in a system using the reverse osmosis membrane method, and the cooling water can be supplied with a lower remaining salinity in the produced water and a lower maintenance cost than those in the system using the reverse osmosis membrane method.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a diagram showing the construction of a novel fuel production plant according to one embodiment of the present invention.
  • BEST MODE FOR CARRYING OUT THE INVENTION
  • The construction of a novel fuel production plant according to one embodiment of the present invention will be described below with reference to FIG. 1.
  • FIG. 1 is a diagram showing the construction of the novel fuel production plant according to one embodiment of the present invention.
  • The novel fuel production plant of this embodiment comprises a novel fuel producing section 100, an exhaust heat utilizing section 200, and a cooling water supply section 300. The novel fuel producing section 100 produces new fuel from a feedstock and generates steam by utilizing exhaust heat. In the exhaust heat utilizing section 200, steam turbines are driven using the steam generated by the novel fuel producing section 100, to thereby drive rotary machines, etc. The cooling water supply section 300 supplies cooling water used in condensers for the steam turbines in the exhaust heat utilizing section 200.
  • The novel fuel producing section 100 comprises an air compressor 1, an air separator 2, an oxygen booster 3, a reaction/reforming furnace 4, exhaust heat recovery boilers 5 and 8, a fuel synthesizing reactor 7, etc.
  • The feedstock is supplied to the reaction/reforming furnace 4 through a piping 50. Usable raw materials supplied as the feedstock includes, for example, hydrocarbons such as coal, oil and natural gas, biomass, wasted plastics, etc. In this embodiment, natural gas is used as the feedstock. Though not shown, steam, carbon dioxide, etc. may also be supplied in addition to those raw materials. Further, the reaction/reforming furnace 4 is supplied with oxygen through a piping 51. The oxygen is obtained by compressing air by the air compressor 1, separating the compressed air by the air separator 2, and boosting the pressure of the separated oxygen by the oxygen booster 3. In the reaction/reforming furnace 4, synthesized gas mainly consisted of hydrogen and carbon monoxide is produced from the feedstock gas supplied through the piping 50 and the oxygen supplied through the piping 51 by partial oxidation or auto-thermal reforming, for example. The produced synthesized gas is taken out through a piping 52.
  • The hot synthesized gas thus produced by the reaction/reforming furnace 4 is supplied to the exhaust heat recovery boiler 5 where steam (high-pressure steam) is generated to lower the temperature of the synthesized gas. The synthesized gas is then supplied to the fuel synthesizing reactor 7. In the fuel synthesizing reactor 7, the synthesized gas is further synthesized into novel fuel under the action of a catalyst. The reaction heat generated at this time is recovered by generating steam (medium-pressure steam) in the exhaust heat recovery boiler 8. The novel fuel synthesized by the fuel synthesizing reactor 7, unreacted gases, etc. are sent via a piping 53 to a succeeding liquefying/refining step for liquefaction and refining. The heat of the fuel synthesizing reaction can be recovered from reaction products after exiting the reactor as shown, or can be recovered directly from the interior of the reactor in other cases.
  • With the above-mentioned synthesized gas production method, the synthesized gas at an outlet of the reaction/reforming furnace 4 has very high temperatures. On the other hand, the fuel synthesizing reaction carried out in the fuel synthesizing reactor 7 of the succeeding stage is an exothermic reaction, and the synthesized gas at an inlet of the fuel synthesizing reactor 7 requires to be cooled down to a temperature suitable for the synthesizing reaction. In the novel fuel production plant, since a large amount of excess heat is generated with that necessity of cooling the synthesized gas, the exhaust heat recovery boilers 5, 8 are installed to generate high- and medium-pressure steam for heat recovery.
  • The generated high- and medium-pressure steam is used in the exhaust heat utilizing section 200 by the steam turbines for driving compressors, pumps, generators, etc. in the plant. However, low-pressure steam is rather excessive because it is used just as a heat source for a reboiler in a part of equipment for liquefying and refining the fuel synthesizing reaction gas, a heat source for degassing feedwater for a boiler, etc. Also, if many steam condensing turbines are used from the viewpoint of operating the steam turbines with higher efficiency and keeping steam balance in consideration of the less number of heat sources requiring the low-pressure steam, a larger amount of cooling water is required to condense steam correspondingly.
  • The exhaust heat utilizing section 200 will be described below. The exhaust heat utilizing section 200 comprises a high-pressure steam line, a medium-pressure steam line, and a low-pressure steam line.
  • The high-pressure steam line is constituted by the exhaust heat recovery boiler 5, a high-pressure boiler 6, and a high-pressure steam header 54. High-pressure steam generated by the exhaust heat recovery boiler 5 is used by a steam turbine 9 for driving the feedstock air compressor 1, a steam turbine 12 for driving the oxygen booster 3, etc. Exhausts of the driving steam turbines 9, 12 are cooled in condensers 10, 13, etc. by plant circulation cooling water, and are returned to a degasser 25 by condensate transfer pumps 11, 14, etc. High-pressure boiler feedwater is withdrawn from the degasser 25 and is boosted up to a predetermined pressure by a high-pressure boiler feedwater pump 27, followed by being supplied to the exhaust heat recovery boiler 5 and the high-pressure boiler 6. Also, medium-pressure boiler feedwater is withdrawn from the degasser 25 and is boosted up to a predetermined pressure by a medium-pressure boiler feedwater pump 26, followed by being supplied to the exhaust heat recovery boiler 8. Additionally, the high-pressure steam that is insufficient from the viewpoint of steam balance is supplied to the high-pressure steam header 54 by the high-pressure boiler 6.
  • The medium-pressure steam line is constituted by the exhaust heat recovery boiler 8 and a medium-pressure steam header 55. Medium-pressure steam generated by the exhaust heat recovery boiler 8 is used by a pump-driving steam turbine 17, steam turbines 18, 21 for driving process gas compressors, etc. From the viewpoint of steam balance, the pump-driving steam turbine 17, the steam turbine 18 for driving the process gas compressor, etc. operate as backpressure turbines and supply the low-pressure steam to a low-pressure steam header 56. The steam turbine 21 for driving the process gas compressor operates as a condensing turbine. From the viewpoint of steam balance, exhausts of the steam turbine 21 for driving the process gas compressor, etc. are cooled in a condenser 22, etc. by the plant circulation cooling water, and are returned to the degasser 25 by a condensate transfer pump 23, etc.
  • Here, a condensing turbine may be used as the steam turbine 18. Taking into account the amount of the low-pressure steam used by a brine heater 40, however, of a condensing turbine is used as the steam turbine 18 for driving the process gas compressor, the amount of the supplied low-pressure steam becomes insufficient. For that reason, in this embodiment, a backpressure turbine is used to increase the amount of the supplied low-pressure steam.
  • The medium-pressure steam line further includes a gas turbine generator 36 and a gas-turbine exhaust heat boiler 37. The gas-turbine exhaust heat boiler 37 generates medium-pressure steam and supplies the generated medium-pressure steam to a medium-pressure steam header 55.
  • The lower-pressure steam line is constituted by a lower-pressure steam header 56 and supplies the lower-pressure steam, which has been received from the pump-driving steam turbine 17, etc., to a reboiler 47, the degasser 25, etc. The lower-pressure steam is also supplied to the brine heater 40 and utilized as a heat source for a seawater desalination system using the evaporation method. In this case, excess steam is set to zero by adjusting a water production rate in the seawater desalination system using the evaporation method.
  • The cooling water supply section 300 will be described below. The cooling water supply section 300 comprises a plant open circulation cooling-water line and a water production line.
  • The plant open circulation cooling-water line is constituted by a cooling tower 34, a cooling water circulation pump 35, and a cooling water circulation piping 59. The cooling water is supplied to the condensers 10, 13, 22, etc. through the cooling water circulation piping 59. The cooling water having temperature raised with heat exchanges in the condensers 10, 13, 22, etc. is cooled in the cooling tower 34 using the atmosphere, and is circulated within the line after pressure is boosted by the cooling water circulation pump 35. A part of the cooling water lost by evaporation during the cooling step in the cooling tower 34 using the atmosphere is replenished from the water production line.
  • The water production line employs the multistage flash method as one example of the evaporation method. The water production line is constituted by a heat radiating section 38 of a multistage-flash water production system, a heat recovering section 39 of the multistage-flash water production system, the brine heater 40, a seawater/brine heat exchanger 41, a degassing tank 42, a brine circulation pump 43, and a vacuum generator 44.
  • The heat radiating section 38 of the multistage-flash water production system cools and condenses steam evaporated from circulating brine to recover fresh water. Desalted water thus produced is temporarily stored in a desalted water tank 31 and then supplied as makeup water for the plant circulation cooling-water line by a desalted water supply pump 32. The plant circulation cooling water supplied through a piping 66 is used as a fresh water condensing coolant in the heat radiating section 38 of the multistage-flash water production system. The cooling water exiting the heat radiating section 38 of the multistage-flash water production system is returned to the cooling tower 34 through a piping 63.
  • The seawater/brine heat exchanger 41 performs heat exchange between seawater supplied through a piping 60 and drain brine discharged through a piping 61 so that the temperature of the discharged brine is lowered and heat is recovered to the supplied seawater. The seawater having passed the seawater/brine heat exchanger 41 is degassed in a degassing tank 42 and then supplied, through a piping 65, to low-temperature circulating brine that is circulated through a low-temperature circulating brine 64.
  • The low-temperature circulating brine 64 to which seawater has been newly replenished is boosted in pressure by the brine circulation pump 43, and is then introduced to the heat recovering section 39 of the multistage-flash water production system. Here, the low-temperature circulating brine 64 serves to not only cool and condense the steam evaporated from high-temperature circulating brine, but also to recover heat for raising the temperature thereof.
  • The brine having temperature further raised by the brine heater 40 using the low-pressure steam becomes high-temperature circulating brine 67 that is successively introduced for flashing to respective steps (stages) of both the heat recovering section 39 and the heat radiating section 38 of the multistage-flash water production system, which have been held in lower-pressure states by the vacuum generator 44 using the medium-pressure steam. The high-temperature circulating brine 67 is gradually condensed and cooled while being flashed in the respective stages. Then, a part of the high-temperature circulating brine is blown off externally of the line from the heat radiating section 38 of the multistage-flash water production system through the piping 61, and the remaining high-temperature circulating brine is recirculated as the low-temperature circulating brine 64.
  • Note that the evaporation method used in the water production line is not limited to the above-described multistage flash method, and the multiple effect method may be used instead. Further, both the multistage flash method and the multiple effect method may be used in a combined manner.
  • A first feature of the above-described novel fuel production plant of this embodiment resides in that the plant circulation cooling water supplied through the piping 66 is used as the fresh water condensing coolant in the heat radiating section 38 of the multistage-flash water production system. For example, when fresh water is produced at a rate of 750 t/hour in the water production line, the known seawater desalination system using the reverse osmosis membrane method has to take in seawater at a rate of 1500 t/hour, i.e., about twice the rate of the required fresh water, on condition that the known system is one having the highest fresh water recovery rate. On the other hand, if it is assumed that the evaporation method requires a seawater intake amount four times that required by the reverse osmosis membrane method when the temperature difference between the seawater and the cooling water is 10° C., the seawater intake amount required in the known seawater desalination system using the evaporation method is 6000 t/hour. Of 6000 t/hour, 4500 t/hour is the amount of seawater used as the fresh water condensing coolant in the heat radiating section 38 of the multistage-flash water production system, and 1500 t/hour is the amount of seawater required for the water production. In this case, by using the plant circulation cooling water supplied through the piping 66 as the fresh water condensing coolant in the heat radiating section 38 of the multistage-flash water production system, an amount Q1 of seawater to be taken in through the piping 60 is given as 1500 t/hour that is equal to the amount required in the known seawater desalination system using the reverse osmosis membrane method. If the temperature difference between the seawater and the cooling water is limited to 2° C., i.e., to a most tightly controlled level in recent years, the known seawater desalination system using the evaporation method requires a very large seawater intake amount of 24000 t/hour (=4500×10/2+1500). However, when the plant circulation cooling water supplied through the piping 66 is used as the fresh water condensing coolant in the heat radiating section 38 of the multistage-flash water production system, the seawater intake amount is not affected by the limitation on the temperature difference between the seawater and the cooling water and remains at 1500 t/hour. Though depending on the cooling capability of the cooling tower 34, it is general that a temperature difference ΔT2 between the cooling water flowing through the piping 66 and the cooling water returned from the piping 63 is set to 10° C. In this case, because the cooling efficiency is increased 5 times as the temperature difference increases 5 times, an amount Q2 of the cooling water supplied to the heat radiating section 38 of the multistage-flash water production system through the piping 66 is given as 4500 t/hour {=(24000−1500) t/hour×⅕}. Since an amount Q3 of the cooling water supplied to the exhaust heat utilizing section 200 from the cooling tower 34 through the piping 59 is, e.g., about 33600 t/hour, the amount Q2 of the cooling water supplied from the piping 66 to the heat radiating section 38 of the multistage-flash water production system through the piping 66 is about 13% of the above-mentioned cooling water amount Q3.
  • Thus, according to this embodiment, by using the plant circulation cooling water supplied through the piping 66 as the fresh water condensing coolant in the heat radiating section 38 of the multistage-flash water production system, the seawater intake amount can be reduced to a level comparable to that required in the known seawater desalination system using the reverse osmosis membrane method. Also, according to this embodiment, there is no need of considering corrosion resistance to salt contained in the seawater with respect to piping materials for the heat radiating section 38 of the multistage-flash water production system, and hence a relatively inexpensive material can also be used.
  • A second feature of the present invention resides in that the evaporation method, e.g., the multistage flash method or the multiple effect method, is applied to the water production line for desalinating seawater. With the second feature, replacement of an expensive membrane is no longer required and the maintenance cost of the water production system is reduced. Further, comparing the reverse osmosis membrane method and the evaporation method, it is general that the evaporation method can produce fresh water with a lower remaining salinity than the reverse osmosis membrane method. As a result, the maintenance cost of the cooling water line is also reduced.
  • A third feature of this embodiment resides in that a backpressure turbine is used as the steam turbine 18 for driving the process gas compressor to compensate for the amount of the low-pressure steam consumed by the brine heater 40. With the third feature, the amount of the supplied lower-pressure steam can be increased. Also, since the use of a backpressure turbine eliminates the need of an additional condenser for use with a condensing turbine, the amount of the circulated cooling water is reduced correspondingly. Even though the amount Q2 of the cooling water circulated through the heat radiating section 38 of the multistage-flash water production system is increased by 4500 t/hour as described above, the amount of the circulated cooling water can be reduced by about 1500 t/hour as a result of not using the additional condenser.
  • A fourth feature of this embodiment resides in that the gas turbine generator 36 is installed as a power supply source for the plant and the gas-turbine exhaust heat boiler 37 is installed to generate the medium-pressure steam. As the power supply source for the plant, a steam turbine can be installed at a position indicated by a symbol X in the drawing similarly to the steam turbine 12. In the case using a steam turbine as the power supply source for the plant, however, that steam turbine has to be constituted in similar arrangement of the driving steam turbine 21, the condenser 13 and the condensate transfer pump 14, and hence an additional condenser is required. Since the use of the gas turbine eliminates the need of an additional condenser, the amount of the circulated cooling water is reduced correspondingly. Even though the amount Q2 of the cooling water circulated through the heat radiating section 38 of the multistage-flash water production system is increased by, e.g., 4500 t/hour as described above, the amount of the circulated cooling water can be reduced by about 3100 t/hour as a result of not using the additional condenser.
  • Consequently, by using a backpressure turbine as the steam turbine 18, using the gas turbine generator 36 in place of the steam turbine generator, and installing the gas turbine exhaust heat boiler 37, the amount of the circulated cooling water can be reduced by the amount of the cooling water used by the two condensers, i.e., 4600 t/hour (=1500 t/hour+3100 t/hour). With this embodiment, as described above, in spite of the amount Q2 of the cooling water supplied through the piping 66 being increased by 4500 t/hour when the plant circulation cooling water supplied through the piping 66 is used as the fresh water condensing coolant in the heat radiating section 38 of the multistage-flash water production system, the amount of the circulated cooling water can be reduced by the amount of the cooling water used by the two condensers, i.e., 4600 t/hour, and therefore the amount of the circulated cooling water can be reduced by 100 t/hour as a whole. Although those numerical values are shown merely by way of example, it is concluded that, even with the amount of the cooling water increased by using the plant circulation cooling water supplied through the piping 66 as the fresh water condensing coolant in the heat radiating section 38 of the multistage-flash water production system, the total amount of the circulated cooling water can be reduced to a level comparable to or smaller than that in the system using the reverse osmosis membrane method by modifying the other arrangement.
  • Further, by using the gas turbine generator as the power supply source for the plant, the novel fuel production plant of this embodiment can be started up on a stand-alone basis, thus resulting in higher operability of the plant. Also, since the use of the evaporation method in the water production system eliminates the need of a high-pressure seawater pump consuming a large quantity of power, which has been required in the reverse osmosis membrane system, the output power of the generator can be reduced by about 15%. Additionally, since a gas turbine is used as a generator driver, the amount of the required high-pressure steam can be reduced correspondingly and so can be the capacity in operation of the high-pressure boiler.
  • A fifth feature of this embodiment resides in that the lower-pressure steam generated in the exhaust heat utilizing section 200 is supplied to and utilized by the brine heater 40 of the multistage-flash water production system. Here, if the lower-pressure steam is excessive, the excess steam can be consumed by changing a water production rate of the water production system, or it can be eliminated by optimizing the steam balance. In the case adjusting the water production rate, if the lower-pressure steam is excessive and the water production rate can be adjusted to a lower value, it is also possible to reduce the number of stages and the number of evaporators in the water production system, thereby cutting the equipment cost.
  • A sixth feature of this embodiment resides in that the seawater/brine heat exchanger 41 is installed to perform heat exchange between the brine discharged from the evaporation water production system and the seawater supplied to it. With the sixth feature, heat can be recovered and the temperature of the discharged brine can be kept not higher than a predetermined value when the intake-discharge temperature difference of seawater is specified as a result of control for environmental protection.
  • Thus, it is possible to optimize the steam balance of the plant, to eliminate the excess steam in the plant, and to increase the overall thermal efficiency of the plant by changing a part of steam turbine driven machines to a gas turbine driven machine, changing a part of condensing turbines to a backpressure turbine, recovering heat from the discharged brine, and adjusting the water production rate of the evaporation water production system.
  • The seawater desalination system according to this embodiment is intended to desalinate seawater by using the evaporation method and to supply the desalinated water for replenishment of the cooling water, and it is featured in that the cooling water supplied from the open circulation cooling water supply section is used in condensing of the desalinated water produced by the seawater desalination system. The seawater desalination system can be employed not only to supply the cooling water in the novel fuel production plant, but also as a fresh water supply source in an oil refinery, a chemical plant, a steam-turbine power generation plant, etc.
  • INDUSTRIAL APPLICABILITY
  • According to the present invention, in a novel fuel production plant and a seawater desalination system for use therein which are installed in a district undergoing restriction in use of seawater, a water production system using the evaporation method can be employed with a seawater intake amount comparable to that required in a system using the reverse osmosis membrane method, and the merit of the evaporation water production system having a lower maintenance cost than the reverse osmosis membrane method can be enjoyed.

Claims (7)

1. A novel fuel production plant for producing synthesized gas from a feedstock and producing novel fuel from the produced synthesized gas, said novel fuel production plant comprising an exhaust heat recovery boiler for generating steam by recovering excess heat generated from the fuel production processes, said novel fuel production plant further comprising:
an exhaust heat utilizing section including a steam turbine driven with the steam generated from said exhaust heat recovery boiler,
an open circulation cooling water supply section for supplying cooling water for a plant, including water for cooling exhaust of said steam turbine, and a seawater desalination system using an evaporation method with steam utilized as a heat source and supplying desalinated water to replenish the open circulation cooling water,
wherein the cooling water supplied from said open circulation cooling water supply section is used in condensing of the desalinated water produced by said seawater desalination system.
2. The novel fuel production plant according to claim 1, wherein the evaporation method used in said seawater desalination system is a multistage flash method, a multiple effect method, or a combination of both the methods.
3. The novel fuel production plant according to claim 1, wherein a gas turbine is used to drive a machine to be driven.
4. The novel fuel production plant according to claim 3, further comprising a gas turbine exhaust heat boiler for generating steam with exhaust heat of said gas turbine,
wherein the steam generated by said gas turbine exhaust heat boiler is supplied to said exhaust heat utilizing section.
5. The novel fuel production plant according to claim 1, further comprising a heat exchanger for performing heat exchange between brine discharged from said seawater desalination system and seawater as feed material supplied to said seawater desalination system.
6. The novel fuel production plant according to claim 1, wherein a water production rate of said seawater desalination system is modified such that excess steam generated in said plant is consumed as a heat source for said seawater desalination system.
7. A seawater desalination system for desalinating seawater by using an evaporation method with steam utilized as a heat source and supplying desalinated water,
wherein cooling water supplied from an open circulation cooling water supply section is used in condensing of the desalinated water produced by said seawater desalination system.
US10/557,797 2003-06-09 2003-06-09 Novel fuel production plant and seawater desalination system for use therein Abandoned US20070039324A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2003/007263 WO2004108860A1 (en) 2003-06-09 2003-06-09 Novel fuel production plant and seawater desalination system for use therein

Publications (1)

Publication Number Publication Date
US20070039324A1 true US20070039324A1 (en) 2007-02-22

Family

ID=33495949

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/557,797 Abandoned US20070039324A1 (en) 2003-06-09 2003-06-09 Novel fuel production plant and seawater desalination system for use therein

Country Status (5)

Country Link
US (1) US20070039324A1 (en)
EP (1) EP1645613A1 (en)
JP (1) JPWO2004108860A1 (en)
AU (1) AU2003242051A1 (en)
WO (1) WO2004108860A1 (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060201024A1 (en) * 2004-07-19 2006-09-14 Earthrenew, Inc. Process and system for drying and heat treating materials
US20060254080A1 (en) * 2004-07-19 2006-11-16 Earthrenew, Inc. Process and apparatus for manufacture of fertilizer products from manure and sewage
US20070163316A1 (en) * 2006-01-18 2007-07-19 Earthrenew Organics Ltd. High organic matter products and related systems for restoring organic matter and nutrients in soil
US20100139116A1 (en) * 2006-01-18 2010-06-10 Earthrenew, Inc. Systems for prevention of hap emissions and for efficient drying/dehydration processes
US7975398B2 (en) 2004-07-19 2011-07-12 Earthrenew, Inc. Process and system for drying and heat treating materials
US20110214308A1 (en) * 2004-07-19 2011-09-08 Earthrenew, Inc. Control system for gas turbine in material treatment unit
AT510279B1 (en) * 2011-02-22 2012-03-15 Klaus Dipl Ing Engelhart METHOD FOR CONVERTING ENERGY
US20140284199A1 (en) * 2012-05-18 2014-09-25 Air Products And Chemicals, Inc. Water Purification Using Energy from a Steam-Hydrocarbon Reforming Process
CN109162776A (en) * 2017-10-30 2019-01-08 中机国能电力工程有限公司 A kind of supply of steam power plant's black starting-up power supply and heat recovery association system and application method
CN112794283A (en) * 2020-12-31 2021-05-14 河南中氢动力研究院有限公司 Seawater hydrogen production and desalination integrated equipment

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1701006B1 (en) * 2005-02-22 2016-10-05 Kabushiki Kaisha Toshiba Electric power-generating and desalination combined plant and operation method of the same
WO2007114279A1 (en) * 2006-03-30 2007-10-11 Nippon Steel Engineering Co., Ltd. Liquid fuel synthesis system
RU2008140161A (en) * 2006-03-30 2010-05-10 Ниппон Стил Инджиниринг Ко., Лтд. (Jp) LIQUID FUEL SYNTHESIS SYSTEM
KR100774546B1 (en) * 2006-11-13 2007-11-08 두산중공업 주식회사 Seawater desalinating apparatus using blowdown of heat recovery steam generator
CN103739030A (en) * 2013-12-30 2014-04-23 众和海水淡化工程有限公司 Waste heat utilizing seawater desalination system
CN104357079B (en) * 2014-11-30 2016-04-06 东北电力大学 A kind of retrieving arrangement responding to adsorption desorption oil shale distillation gas lightweight oil
CN105174344B (en) * 2015-09-15 2017-10-31 广州中国科学院先进技术研究所 A kind of marine seawater desalination system reclaimed based on diesel residual heat
JP7353163B2 (en) * 2019-12-25 2023-09-29 三菱重工業株式会社 Ammonia derivative manufacturing plant and ammonia derivative manufacturing method

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3448013A (en) * 1966-08-10 1969-06-03 Westinghouse Electric Corp Distillate cooling means for flash evaporators
US4009575A (en) * 1975-05-12 1977-03-01 said Thomas L. Hartman, Jr. Multi-use absorption/regeneration power cycle
US4123324A (en) * 1976-02-02 1978-10-31 Hitachi, Ltd. Apparatus for decontaminating a radioactively contaminated coolant
US4512387A (en) * 1982-05-28 1985-04-23 Rodriguez Larry A Power transformer waste heat recovery system
US4813237A (en) * 1988-08-19 1989-03-21 Energiagazdalkodasi Intezet Apparatus for making up feed water for a power station
US5156706A (en) * 1982-09-07 1992-10-20 Sephton Hugo H Evaporation of liquids with dispersant added
US5582691A (en) * 1993-12-14 1996-12-10 Flynn; Robert J. Ocean thermal energy conversion (OTEC) system
US20020046561A1 (en) * 1998-09-10 2002-04-25 Ormat Industries Ltd. Retrofit equipment for reducing the consumption of fossil fuel by a power plant using solar insolation
US20040128976A1 (en) * 2002-10-23 2004-07-08 Eberhard Gralla Gas and steam power plant for water desalination
US6804962B1 (en) * 1999-12-23 2004-10-19 Melvin L. Prueitt Solar energy desalination system

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5297051A (en) * 1976-02-09 1977-08-15 Hitachi Ltd Steam power and manufacturing palnt for fresh water
JP2669545B2 (en) * 1988-10-14 1997-10-29 株式会社日立製作所 Exhaust heat recovery boiler system and its operation method
JPH10195008A (en) * 1996-12-30 1998-07-28 Nkk Corp Apparatus for production of dimethyl ether
JPH10288473A (en) * 1997-04-16 1998-10-27 Mitsubishi Heavy Ind Ltd Circulating water pipe device of cooling tower
JP3358523B2 (en) * 1998-01-23 2002-12-24 栗田工業株式会社 Water treatment chemical concentration calculation method and automatic management method
JPH11216459A (en) * 1998-01-29 1999-08-10 Nishishiba Electric Co Ltd Seawater desalting device

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3448013A (en) * 1966-08-10 1969-06-03 Westinghouse Electric Corp Distillate cooling means for flash evaporators
US4009575A (en) * 1975-05-12 1977-03-01 said Thomas L. Hartman, Jr. Multi-use absorption/regeneration power cycle
US4123324A (en) * 1976-02-02 1978-10-31 Hitachi, Ltd. Apparatus for decontaminating a radioactively contaminated coolant
US4512387A (en) * 1982-05-28 1985-04-23 Rodriguez Larry A Power transformer waste heat recovery system
US5156706A (en) * 1982-09-07 1992-10-20 Sephton Hugo H Evaporation of liquids with dispersant added
US4813237A (en) * 1988-08-19 1989-03-21 Energiagazdalkodasi Intezet Apparatus for making up feed water for a power station
US5582691A (en) * 1993-12-14 1996-12-10 Flynn; Robert J. Ocean thermal energy conversion (OTEC) system
US20020046561A1 (en) * 1998-09-10 2002-04-25 Ormat Industries Ltd. Retrofit equipment for reducing the consumption of fossil fuel by a power plant using solar insolation
US6804962B1 (en) * 1999-12-23 2004-10-19 Melvin L. Prueitt Solar energy desalination system
US20040128976A1 (en) * 2002-10-23 2004-07-08 Eberhard Gralla Gas and steam power plant for water desalination

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110214308A1 (en) * 2004-07-19 2011-09-08 Earthrenew, Inc. Control system for gas turbine in material treatment unit
US20060254080A1 (en) * 2004-07-19 2006-11-16 Earthrenew, Inc. Process and apparatus for manufacture of fertilizer products from manure and sewage
US10094616B2 (en) 2004-07-19 2018-10-09 2292055 Ontario Inc. Process and system for drying and heat treating materials
US20080104858A1 (en) * 2004-07-19 2008-05-08 Earthrenew, Inc. Process and system for drying and heat treating materials
US20060201024A1 (en) * 2004-07-19 2006-09-14 Earthrenew, Inc. Process and system for drying and heat treating materials
US7866060B2 (en) * 2004-07-19 2011-01-11 Earthrenew, Inc. Process and system for drying and heat treating materials
US7882646B2 (en) 2004-07-19 2011-02-08 Earthrenew, Inc. Process and system for drying and heat treating materials
US8407911B2 (en) 2004-07-19 2013-04-02 Earthrenew, Inc. Process and system for drying and heat treating materials
US7975398B2 (en) 2004-07-19 2011-07-12 Earthrenew, Inc. Process and system for drying and heat treating materials
US20110212239A1 (en) * 2004-07-19 2011-09-01 Earthrenew, Inc. Process and system for drying and heat treating materials
US20100139116A1 (en) * 2006-01-18 2010-06-10 Earthrenew, Inc. Systems for prevention of hap emissions and for efficient drying/dehydration processes
US8156662B2 (en) 2006-01-18 2012-04-17 Earthrenew, Inc. Systems for prevention of HAP emissions and for efficient drying/dehydration processes
US20110160058A1 (en) * 2006-01-18 2011-06-30 Earthrenew, Inc. High organic matter products and related systems for restoring organic matter and nutrients in soil
US20070163316A1 (en) * 2006-01-18 2007-07-19 Earthrenew Organics Ltd. High organic matter products and related systems for restoring organic matter and nutrients in soil
AT510279B1 (en) * 2011-02-22 2012-03-15 Klaus Dipl Ing Engelhart METHOD FOR CONVERTING ENERGY
US20140284199A1 (en) * 2012-05-18 2014-09-25 Air Products And Chemicals, Inc. Water Purification Using Energy from a Steam-Hydrocarbon Reforming Process
CN109162776A (en) * 2017-10-30 2019-01-08 中机国能电力工程有限公司 A kind of supply of steam power plant's black starting-up power supply and heat recovery association system and application method
CN112794283A (en) * 2020-12-31 2021-05-14 河南中氢动力研究院有限公司 Seawater hydrogen production and desalination integrated equipment

Also Published As

Publication number Publication date
AU2003242051A8 (en) 2005-01-04
AU2003242051A1 (en) 2005-01-04
EP1645613A8 (en) 2006-07-12
JPWO2004108860A1 (en) 2006-07-20
EP1645613A1 (en) 2006-04-12
WO2004108860A1 (en) 2004-12-16

Similar Documents

Publication Publication Date Title
US20070039324A1 (en) Novel fuel production plant and seawater desalination system for use therein
US20220119328A1 (en) Use of renewable energy in methanol synthesis
JP4762555B2 (en) Power generation desalination method
RU2085754C1 (en) Method of and gas turbine plant for continuous conversion of energy
EP1921281B1 (en) Seawater desalinating apparatus using blowdown water of heat recovery steam generator
EP3849939B1 (en) Process for the synthesis of ammonia
JP5331890B2 (en) Cogeneration plant and biomass reforming combined power plant
US5842345A (en) Heat recovery and power generation from industrial process streams
Liu et al. A comprehensive study of a novel multigeneration system using a combined power plant based on geothermal energy and oxyfuel combustion
RU2665794C1 (en) Method and plant for mechanical and thermal energy generation
EP3730473A1 (en) Use of renewable energy in methanol synthesis
EP3844371B1 (en) System for generating energy in a working fluid from hydrogen and oxygen and method of operating this system
US8186177B2 (en) Systems for reducing cooling water and power consumption in gasification systems and methods of assembling such systems
Szacsvay et al. Distillation desalination systems powered by waste heat from combined cycle power generation units
RU2774008C1 (en) Installation for generating thermal and mechanical energy and method for its regulation
Hamed et al. Prospects of improving energy consumption of the multi-stage flash distillation process
US20230167748A1 (en) Method and apparatus for co-generating electricity in a process plant integrated with a thermal power generator using feedwater
RU2806868C1 (en) Energy complex for generating thermal and electrical energy and its method of operation (variant)
RU2675841C1 (en) Installation for urea synthesis
RU2233986C1 (en) Method of distribution of steam between steam turbines operating at counterpressure in production of ammonia
EP2975014A1 (en) Methanol plant and gasoline synthesis plant
Hornburg et al. Dual purpose power/water plants utilizing both distillation and reverse osmosis
JP2005248826A (en) Power generation/distillation compound plant and method for operating same
KR102230950B1 (en) Steam suplly system and method for steam supplying
KR20240042681A (en) Methods and systems for producing hydrogen

Legal Events

Date Code Title Description
AS Assignment

Owner name: HITACHI, LTD., JAPAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:INUI, TAIJI;KAWAGUCHI, TSUNEHISA;YAGI, HIROSHI;AND OTHERS;REEL/FRAME:018147/0905;SIGNING DATES FROM 20050926 TO 20051026

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION