US20070237888A1 - Methods to make sidewall light shields for color filter array - Google Patents

Methods to make sidewall light shields for color filter array Download PDF

Info

Publication number
US20070237888A1
US20070237888A1 US11/785,545 US78554507A US2007237888A1 US 20070237888 A1 US20070237888 A1 US 20070237888A1 US 78554507 A US78554507 A US 78554507A US 2007237888 A1 US2007237888 A1 US 2007237888A1
Authority
US
United States
Prior art keywords
color filters
forming
trench
etching
over
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
US11/785,545
Other versions
US7955764B2 (en
Inventor
Saijin Liu
Ulrich C. Boettiger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aptina Imaging Corp
US Bank NA
Original Assignee
Micron Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/399,314 external-priority patent/US20070238035A1/en
Application filed by Micron Technology Inc filed Critical Micron Technology Inc
Priority to US11/785,545 priority Critical patent/US7955764B2/en
Assigned to MICRON TECHNOLOGY, INC. reassignment MICRON TECHNOLOGY, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: LIU, SAIJIN, BOETTIGER, ULRICH C.
Publication of US20070237888A1 publication Critical patent/US20070237888A1/en
Priority to PCT/US2008/059731 priority patent/WO2008130846A2/en
Priority to TW097114385A priority patent/TWI366918B/en
Application granted granted Critical
Publication of US7955764B2 publication Critical patent/US7955764B2/en
Assigned to APTINA IMAGING CORPORATION reassignment APTINA IMAGING CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MICRON TECHNOLOGY, INC.
Assigned to U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT reassignment U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MICRON TECHNOLOGY, INC.
Assigned to MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT reassignment MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT PATENT SECURITY AGREEMENT Assignors: MICRON TECHNOLOGY, INC.
Assigned to U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT reassignment U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT CORRECTIVE ASSIGNMENT TO CORRECT THE REPLACE ERRONEOUSLY FILED PATENT #7358718 WITH THE CORRECT PATENT #7358178 PREVIOUSLY RECORDED ON REEL 038669 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY INTEREST. Assignors: MICRON TECHNOLOGY, INC.
Assigned to MICRON TECHNOLOGY, INC. reassignment MICRON TECHNOLOGY, INC. RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Assigned to MICRON TECHNOLOGY, INC. reassignment MICRON TECHNOLOGY, INC. RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
Expired - Fee Related legal-status Critical Current
Adjusted expiration legal-status Critical

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14683Processes or apparatus peculiar to the manufacture or treatment of these devices or parts thereof
    • H01L27/14685Process for coatings or optical elements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14601Structural or functional details thereof
    • H01L27/1462Coatings
    • H01L27/14621Colour filter arrangements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14601Structural or functional details thereof
    • H01L27/1462Coatings
    • H01L27/14623Optical shielding
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14643Photodiode arrays; MOS imagers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0216Coatings
    • H01L31/02161Coatings for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/02162Coatings for devices characterised by at least one potential jump barrier or surface barrier for filtering or shielding light, e.g. multicolour filters for photodetectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0216Coatings
    • H01L31/02161Coatings for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/02162Coatings for devices characterised by at least one potential jump barrier or surface barrier for filtering or shielding light, e.g. multicolour filters for photodetectors
    • H01L31/02164Coatings for devices characterised by at least one potential jump barrier or surface barrier for filtering or shielding light, e.g. multicolour filters for photodetectors for shielding light, e.g. light blocking layers, cold shields for infrared detectors

Definitions

  • Embodiments described herein relate to methods of forming color filters for use in a solid-state image sensor having a structure that isolates individual features from one another.
  • Solid-state image sensors were developed in the late 1960s and early 1970s primarily for television image acquisition, transmission, and display.
  • An imager absorbs incident radiation of a particular wavelength (such as optical photons, x-rays, or the like) and generates an electrical signal corresponding to the absorbed radiation.
  • semiconductor-based imagers including charge coupled devices (CCDs), photodiode arrays, charge injection devices (CIDs), hybrid focal plane arrays, and complementary metal oxide semiconductor (CMOS) imagers.
  • CCDs charge coupled devices
  • CIDs charge injection devices
  • CMOS complementary metal oxide semiconductor
  • Current applications of solid-state imagers include cameras, scanners, machine vision systems, vehicle navigation systems, star trackers, and motion detector systems, among other uses.
  • imagers typically consist of an array of pixels containing photosensors, where each pixel produces a signal corresponding to the intensity of light impinging on its photosensor when an image is focused on the array. These signals may then be stored, for example, for later display, printing, or analysis or are otherwise used to provide information about the image.
  • the photosensors may be phototransistors, photogates, photodiodes, or other light sensitive devices. The magnitude of the signal produced by each pixel is proportional to the amount of light impinging on the photo sensor.
  • the photosensors To allow the photosensors to capture a color image, the photosensors must be able to separately detect color components for a captured image. For example, in a well known Bayer pattern photosensor array red (R) photons, green (G) photons, and blue (B) photons are captured by different pixel cells of the array. Accordingly, each pixel must be sensitive only to one color or spectral band. For this, a color filter array (CFA) is typically placed in front of the optical path to the photosensors so that each photosensor detects the light of the color of its associated filter. Thus, for an exemplary Bayer pattern photosensor array, each photosensor is covered with either a red, green, or blue filter, according to a specific pattern.
  • RGB red
  • G green
  • B blue
  • CFA color filter array
  • color filter arrays are commonly arranged in a mosaic sequential pattern of red, green, and blue filters known as a Bayer filter pattern.
  • the Bayer filter pattern is quartet-ordered with successive rows that alternate red and green filters, then green and blue filters.
  • each red filter is surrounded by four green and four blue filters, while each blue filter is surrounded by four red and four green filters.
  • each green filter is surrounded by two red, four green, and two blue filters.
  • U.S. Pat. No. 3,971,065 to Bayer describes the Bayer pattern color filter array.
  • Forming a color filter array requires multistep fabrication process that can be complex and difficult to implement to obtain good separation of the color filters. Accordingly, there is a need and desire for improved methods of forming color filter arrays.
  • FIGS. 1A and 1B illustrate partial top-down and cross-sectional views of an imager constructed in accordance with a first structural embodiment discussed herein.
  • FIGS. 2A-5B illustrate partial top-down and cross-sectional views of a first fabrication embodiment for forming the imager illustrated in FIGS. 1A and 1B .
  • FIGS. 6A-7B illustrate partial top-down and cross-sectional views of a second fabrication embodiment for forming the imager illustrated in FIGS. 1A and 1B .
  • FIGS. 8A and 8B illustrate partial top-down and cross-sectional views of an imager constructed in accordance with a second structural embodiment discussed herein.
  • FIGS. 9A-13B illustrate partial top-down and cross-sectional views of a fabrication embodiment for forming the imager illustrated in FIGS. 8A and 8B .
  • FIGS. 14A and 14B illustrate partial top-down and cross-sectional views of an imager constructed in accordance with a third structural embodiment discussed herein.
  • FIG. 15 is a partial top-down block diagram view of an imager device including the imager illustrated in FIGS. 1A and 1B .
  • FIG. 16 illustrates a system having the imager device illustrated in FIG. 15 .
  • substrate used in the following description may include any supporting structure including, but not limited to, a semiconductor substrate that has a substrate surface.
  • a semiconductor substrate should be understood to include silicon, silicon-on-insulator (SOI), silicon-on-sapphire (SOS), doped and undoped semiconductors, epitaxial layers of silicon supported by a base semiconductor foundation, and other semiconductor structures, including those made of semiconductors other than silicon.
  • SOI silicon-on-insulator
  • SOS silicon-on-sapphire
  • doped and undoped semiconductors epitaxial layers of silicon supported by a base semiconductor foundation, and other semiconductor structures, including those made of semiconductors other than silicon.
  • the substrate also need not be semiconductor-based, but may be any support structure suitable for supporting an integrated circuit, including, but not limited to, metals, alloys, glasses, polymers, ceramics, and any other supportive materials as is known in the art.
  • pixel refers to a picture element unit cell containing a photo-conversion device for converting electromagnetic radiation to an electrical signal.
  • a representative three-color Bayer R, G, B pixel array is described herein; however, the embodiments of the invention are not limited to the use of an R, G, B array, and can be used with other color arrays, one example being C, M, Y, K (which represents cyan, magenta, yellow, and black color filters).
  • C, M, Y, K which represents cyan, magenta, yellow, and black color filters.
  • a portion of a representative pixel is illustrated in the figures and description herein, and typically fabrication of other pixel cells in an imager will proceed concurrently and in a similar fashion.
  • Embodiments described herein relate to methods of forming color filters for use in a solid-state image sensor. Although the embodiments of the invention are described in relation to use with a CMOS imager, they are not so limited and have applicability to any solid-state imager.
  • FIGS. 1A and 1B illustrate a partial top-down view and side cross-sectional view (taken along line I-I of FIG. 1A ), respectively, of a portion of a semiconductor-based imager 100 , such as a CMOS imager, constructed in accordance with a first structural embodiment.
  • a semiconductor-based imager 100 such as a CMOS imager
  • the imager 100 includes a plurality of pixel cells including first, second, and third pixel cells 110 b , 110 g , 110 r .
  • the first, second, and third pixel cells 110 b , 110 g , 110 r include a microlens array 102 having microlenses 101 formed over corresponding first, second, and third color filters 103 B, 103 G, 103 R in the color filter array 103 .
  • the color filter array 103 is illustrated as having a Bayer pattern; although, as noted, this is not intended to be limiting.
  • Each of the first, second, and third color filters 103 B, 103 G, 103 R allows a particular wavelength of light to pass through to corresponding first, second, and third photosensors 108 b , 108 g , 108 r formed in a semiconductor substrate 106 ( FIG. 1B ) formed below intervening fabrication layers 104 ( FIG. 1B ) including passivation and metallization layers.
  • the color filter array 103 also includes a light blocking material layer 121 formed between the first, second, and third color filters 103 B, 103 G, 103 R in the color filter array 103 .
  • a light blocking material layer 121 formed between the first, second, and third color filters 103 B, 103 G, 103 R in the color filter array 103 .
  • off-axis light 122 incident upon the imager 100 and intended for capture by the first photosensor 108 b would strike the adjacent photosensor 108 g (as shown by the dashed line) if the material layer 121 were not provided.
  • the off-axis light 122 is prevented from striking the second photosensor 108 g thereby reducing the amount of optical cross talk between photosensors (e.g., first, second, and third photosensors 108 b , 108 g , 108 r ).
  • the material layer 121 thereby acts as a light shield between the photosensors.
  • Asymmetrical pixel cell architecture demands the precise placement of color filters and overlying microlenses to focus light onto the photosensors. Misalignment of the color filter array and overlying microlenses may have detrimental effects caused by an increase in the incidence of cross talk.
  • the illustrated material layer 121 of FIGS. 1A and 1B may also increase the percentage of off-axis light 122 that is captured by the intended first photosensor 108 b by reflecting the off-axis light 122 onto the intended first photosensor 108 b , thereby increasing the quantum efficiency of the pixel cell.
  • FIGS. 2A-5B illustrate a first fabrication embodiment for forming the imager 100 illustrated in FIGS. 1A and 1B .
  • the first color filter 103 B is selectively deposited, patterned, and baked on a planarized upper surface of fabrication layer 104 and over respective first photosensors 108 b of the imager 100 .
  • the first color filter 103 B is formed of any transparent material that allows wavelengths of light (e.g., blue light) to pass through.
  • the first color filter 103 B could be formed of zinc selenide (ZnSe), silicon oxide, silicon nitride, silicon oxynitride, silicon-carbon (SiC) (BLOk), tantalum pentoxide (Ta 2 O 5 ), titanium oxide (TiO 2 ), polymethylmethacrylate, polycarbonate, polyolefin, cellulose acetate butyrate, polystyrene, polyimide, epoxy resin, photosensitive gelatin, acrylate, methacrylate, urethane acrylate, epoxy acrylate, polyester acrylate, or a positive or negative photoresist such as a 3000 series photoresist material (or any other series of photoresist material) produced by FUJIFILM Electronic Materials (FFEM), Japan, including, but not limited to color resists known in the art as SB-3000L, SG-3
  • the first color filter 103 B could also be formed of a material including, but not limited to, glass, for example, zinc selenide (ZnSe), boro-phospho-silicate glass (BPSG), phosphosilicate glass (PSG), borosilicate glass (BSG), silicon oxide, silicon nitride, or silicon oxynitride; an optical thermoplastic material such as tantalum pentoxide (Ta2O5), titanium oxide (TiO2), polymethylmethacrylate, polycarbonate, polyolefin, cellulose acetate butyrate, or polystyrene; a polyimide; a thermoset resin such as an epoxy resin; a photosensitive gelatin; or a radiation curable resin such as acrylate, methacrylate, urethane acrylate, epoxy acrylate, or polyester acrylate.
  • glass for example, zinc selenide (ZnSe), boro-phospho-silicate glass (BPSG), phosphosilicate glass (PSG), boro
  • FIGS. 3A and 3B illustrate partial top-down and side cross-sectional views, respectively, of the second color filter 103 G being selectively deposited, patterned, and baked over respective second photosensors 108 g of the imager 100 .
  • the second color filter 103 G can be formed of any of the materials listed above with respect to the first color filter 103 B.
  • the second color filter 103 G is formed adjacent, but not touching, the first color filter 103 B, thereby defining a trench 120 .
  • the illustrated first and second color filters 103 B, 103 G could each have a width W 1 in the range from about 1000 nm to about 2000 nm, and separated from one another by a distance D 1 in the range from about 50 nm to about 200 nm, although the range is not intended to be limiting.
  • FIGS. 4A and 4B illustrate partial top-down and side cross-sectional views, respectively, of the third color filter 103 R being selectively deposited, patterned, and baked over respective third photosensors 108 r of the imager 100 .
  • the third color filter 103 R can be formed of any of the materials listed above with respect to the first color filter 103 B.
  • the third color filter 103 R is formed adjacent to, but not touching, the second color filter 103 G, thereby defining another trench 120 .
  • the illustrated second and third color filters 103 G, 103 R could each have a width W 1 in the range from about 1000 nm to about 2000 nm, and separated from one another by a distance D 2 in the range from about 50 nm to about 200 nm, although the range is not intended to be limiting.
  • FIGS. 2A-4B illustrate the deposition, patterning, and baking of first, second, and third color filters 103 B, 103 G, 103 R in succession, it is not intended to be limiting. As discussed below with respect to FIGS. 6A-7B , the processing of first, second, and third color filters 103 B, 103 G, 103 R can occur simultaneously. It should also be noted that the order of forming the first second, and third color filters 103 B, 103 G, 103 R is not important; for example, although illustrated as forming the first color filter corresponding to a blue color filter, the first color filter could be any desired color such as green or red, or any other desired color.
  • FIGS. 5A and 5B illustrate partial top-down and side cross-sectional views, respectively, of a material layer 121 formed over the exposed sidewall regions 105 B, 105 G, 105 R ( FIGS. 3A-4B ), and between and over each of the first, second, and third color filters 103 B, 103 G, 103 R in the color filter array 103 .
  • the material layer 121 may be formed of any opaque material, such as, for example, a metal, metal alloy, metal silicides, aluminum, or other opaque material.
  • the material layer 121 may also be formed of a polysilicon material, which is opaque at shorter wavelengths of incoming light.
  • the material layer 121 could be formed of any material having reflective properties, such as, for example, metal compounds such as silver or aluminum.
  • the material layer 121 can be deposited by conventional coating methods, including, but not limited to, spin-coating, spray-coating, and ink jet coating methods.
  • An optional step of planarizing the material layer 121 can be employed for further processing of the imager 100 ( FIGS. 1A and 1B ).
  • the planarization of the material layer could be performed by chemical mechanical polishing (CMP).
  • CMP chemical mechanical polishing
  • Microlenses 101 FIGS. 1A and 1B ) are deposited, patterned, and reflowed to achieve the imager 100 illustrated in FIGS. 1A and 1B .
  • FIGS. 6A-7B illustrate a second fabrication embodiment for forming the imager 10 illustrated in FIGS. 1A and 1B .
  • first, second, and third color filter precursors 103 B′, 103 G′, 103 R′ are formed adjacent to, and abutting one another.
  • the first, second, and third color filter precursors 103 B′, 103 G′, 103 R′ are formed of a resist material, such as, for example, SB-3000L, SG-3000L and SR-3000L for blue, green, and red color filters, respectively.
  • first, second, and third color filter precursors 103 B′, 103 G′, 103 R′ having predetermined dimensions, and reduce the volume upon processing.
  • the illustrated first, second, and third color filter precursors 103 B′, 103 G′, 103 R′ are deposited to have a side cross-sectional width W 2 of about 1000 nm, which have reduced volumes upon processing (as illustrated in FIGS. 7A and 7B ).
  • FIGS. 7A and 7B which are partial top-down and side cross-sectional views, respectively, the processing of the first, second, and third color filter precursors 103 B′, 103 G′, 103 R′ ( FIGS. 6A and 6B ) result in first, second, and third color filters 103 B, 103 G, 103 R.
  • Each of the first, second, and third color filters 103 B, 103 G, 103 R has a side cross-sectional width W 3 of about 900 nm (i.e., a reduction of 10% of 1000 nm). Accordingly, the first, second, and third color filters 103 B, 103 G, 103 R are separated from one another by a distance D 3 that is about 100 nm.
  • first, second, and third color filters 103 B, 103 G, 103 R Due to the contraction of the first, second, and third color filters 103 B, 103 G, 103 R, sidewall regions 105 B, 105 G, 105 R are exposed defining trenches 120 between each of the first, second, and third color filters 103 B, 103 G, 103 R.
  • the material layer 121 ( FIGS. 5A and 5B ) is subsequently deposited over each of the sidewall regions 105 B, 105 G, 105 R, within the trenches 120 , and over the first, second, and third color filters 103 B, 103 G, 103 R, as discussed above with respect to FIGS. 5A and 5B .
  • FIGS. 8A and 8B illustrate a partial top-down view and side cross-sectional view (taken along line I-I of FIG. 8A ), respectively, of a portion of a semiconductor-based imager 200 , such as a CMOS imager, constructed in accordance with a second structural embodiment discussed herein.
  • a semiconductor-based imager 200 such as a CMOS imager
  • FIGS. 8A and 8B illustrate the imager 200 that is substantially similar to the imager 100 discussed above with respect to FIGS. 1A-1B .
  • the imager 200 has a material layer 221 formed between first, second, and third pixel cells 210 b , 210 g , 210 r in the pixel cell array 210 , which extends to a portion 104 a below a topmost surface 104 b of the fabrication layer 104 .
  • An optional etch stop layer 126 is formed within the fabrication layer 104 to aid in the processing of the FIG. 8B structure, as discussed below with respect to FIGS. 12A and 12B .
  • FIGS. 9A-12B illustrate an embodiment of fabricating the imager 200 illustrated in FIGS. 8A and 8B .
  • FIGS. 9A and 9B which are partial top-down and side cross-sectional views, respectively, illustrate the first, second, and third color filter precursors 103 B′, 103 G′, 103 R′ deposited adjacent to, and abutting one another.
  • the materials are selected to form the first, second, and third color filters 103 B, 103 G, 103 R ( FIGS. 8A and 8B ) such that there is no contraction.
  • FIGS. 10A and 10B which are partial top-down and side cross-sectional views, respectively, illustrate resist layers 125 deposited and patterned over the first, second, and third color filter precursors 103 B′, 103 G′, 103 R′.
  • the resist layers 125 could be formed of a material that polymerizes upon exposure to polymerizing conditions such as, for example, heat or ultraviolet radiation.
  • the exposed portions 103 B′′, 103 G′′, 103 R′′ of the first, second, and third color filter precursors 103 B′, 103 G′, 103 R′, respectively, between the resist layers 125 are removed by conventional methods, such as, for example, a wet develop in dilute TMAH (tetramethylammonium hydroxide).
  • TMAH tetramethylammonium hydroxide
  • the removal of the portions 103 B′′, 103 G′′, 103 R′′ result in the formation of the first, second, and third color filters 103 B, 103 G, 103 R, and the exposure of sidewall regions ( 105 B, 105 G, 105 R) for each color filter, which define trenches 120 in the FIG. 11B structure.
  • the first and second color filters 103 B, 103 G are etched to have a predetermined distance D 4 between them, and the second and third color filters 103 G, 103 R are etched to have a predetermined distance D 5 between them.
  • the predetermined distances D 4 and D 5 could be substantially the same or different, depending upon the intended application.
  • FIGS. 12A and 12B illustrate partial top-down and side cross-sectional views, respectively, of a further processing step of the structure illustrated in FIGS. 11A and 11B .
  • portions of the fabrication layer 104 below the color filter array 103 are removed by conventional techniques such as, for example, reactive ion etching, such that sidewall regions 107 of the fabrication layer 104 are exposed.
  • the sidewall regions 107 of the fabrication layer 104 are substantially aligned with the sidewall regions 105 B, 105 G, 105 R of the first, second, and third color filters 103 B, 103 G, 103 R.
  • the sidewall regions 107 , 105 B, 105 G, 105 R define trenches 120 between adjacent pixel cells (e.g., first, second, and third pixel cells 210 b , 210 g , 210 r in the pixel cell array 210 of FIGS. 8A and 8B ).
  • the illustrated trenches 120 are defined by a topmost surface of the color filter array 103 and a portion 104 a of the fabrication layer 104 .
  • the etch stop layer 126 is provided within the fabrication layer 104 .
  • the etch stop layer 126 indicates when the removal of the material layers (e.g., color filter materials and fabrication layer 104 ) should be terminated.
  • FIGS. 13A and 13B illustrate the deposition of material layer 111 ( FIGS. 8A and 8B ) between each of the first, second, and third color filters 103 B, 103 G, 103 R to fill the trenches 120 defined by the sidewall regions 107 , 105 B, 105 G, 105 R ( FIG. 12B ).
  • the material layer 111 is deposited in a substantially similar manner as the material layer 121 discussed above with respect to FIGS. 5A and 5B (e.g., spin coating methods).
  • the material layer 111 can be planarized by CMP to expose the topmost surfaces of the color filters.
  • FIGS. 14A and 14B illustrate partial top-down and side cross-sectional views, respectively, of a portion of a semiconductor-based imager 300 , such as a CMOS imager, constructed in accordance with a third structural embodiment discussed herein.
  • a semiconductor-based imager 300 such as a CMOS imager
  • FIG. 14A illustrates a top-down magnified portion of eight pixel cells 210 arranged as four two-way shared pixel cells. Shared pixel cells have recently been introduced, and are further described in U.S. Publication Nos. 2007/0046796, 2007/0045685, and 20060027887, all of which are assigned to Micron Technology, Inc. The disclosures of each of the foregoing are hereby incorporated by reference in their entirety.
  • FIG. 14A illustrates two adjacent pixel cells 210 in one row (e.g., Row A) of the array share common pixel components.
  • Each pixel cell 210 has an individual color filter 230 formed over a photosensor 208 .
  • the photosensors 208 may be any photosensitive structure for converting light radiation into electrons (photo-charges). Due to the proximity of each photosensor 208 sharing common pixel components, a light material layer 321 is deposited to avoid potential cross talk between the adjacent color filters.
  • each pixel cell 210 may have a respective transfer gate 202 as part of a respective transfer transistors for transferring the accumulated photo-charges from the photosensors 208 to a common storage node, shown as floating diffusion region 410 .
  • the transfer gates 202 are angled from the photosensors 208 .
  • the longitudinal extent L′ of the transfer gates 202 is illustrated as being slanted with respect to the length Lp and the width Wp of the associated photosensors 208 .
  • the angular geometry of the transfer gate 202 allows for an efficient layout of the length L′ and width W′ of the transfer gate 102 , which may improve the leakage and lag performance of the pixel cell 210 .
  • the angular layout is also beneficial in maximizing the fill factor of the pixel cell array, by maximizing the area of the photosensor 208 for each pixel cell 210 .
  • the remaining pixel cell read out components shared between the adjacent pixel cells 210 are illustrated as being on a shared trunk 490 , which is located between two column-adjacent pixel cells of a row, and also between pairs of row adjacent pixel cells of a row (e.g., Row B).
  • the shared components on the trunk 490 include a floating diffusion region 410 , which serves as a common storage node for the pixel cells 210 for receiving charges from photosensors 208 by the transfer gates 202 .
  • a reset transistor having a gate 407 is located on a side of the floating diffusion region 410 opposite the photosensors 208 .
  • a source/drain region 406 is located on a second side of the reset transistor gate 407 , which is capable of receiving a supply voltage Vaa-pix.
  • the floating diffusion region 410 is also electrically connected to the gate 409 of a source follower transistor, which has a drain coupled to the supply voltage Vaa-pix.
  • the source follower transistor creates a voltage output signal based on stored charge on the floating diffusion region 410 .
  • a row select transistor having a gate 411 has a source/drain connected to the source of the source follower transistor, for selectively reading out the pixel signal to a column line 420 .
  • the shared pixel cell arrangement illustrated in FIG. 14A is merely exemplary. There are many different arrangements of shared pixel cell circuitry that may employ the light material layer 321 to isolate each pixel cell, thereby reducing optical cross talk.
  • each pixel cell 210 includes a microlens 224 formed over the color filters 230 .
  • Each color filter 230 is isolated by the material layer 321 to prevent cross-talk between adjacent pixel cells 230 .
  • the material layer 321 is formed in a substantially similar fashion as the embodiments discussed above with respect to FIGS. 1A and 1B (for example, the first fabrication embodiment discussed with respect to FIGS. 2A-5B ).
  • the color filters 230 could be formed having various distances (e.g., D 6 and D 7 ) from each other, thereby defining trenches between the color filters.
  • Subsequent processing steps include filling the trenches with material layer 321 , and forming microlenses over respective photosensors 208 in the array. This processing results in material layer 321 having different side cross-sectional widths within the same array (e.g., W 4 and W 5 ) in the same array.
  • the imager 300 illustrated in FIGS. 14A and 14B could have the material layer 321 extend beyond an upper surface of the substrate 106 (as discussed above with respect to FIGS. 8A and 8B ).
  • FIG. 15 illustrates an imaging device 508 incorporating an imager 100 , 200 , 300 (of FIGS. 1A-14B ) constructed in accordance with embodiments discussed above.
  • the pixel cells 110 x (representing any of the first, second, and third pixel cells of FIG. 1A ) of each row in the imager 100 are all turned on at the same time by a row select line, and the pixel cells 110 x of each column are selectively output by respective column select lines.
  • a plurality of row and column lines are provided for the entire array.
  • the row lines are selectively activated in sequence by the row driver 510 in response to row address decoder 520 and the column select lines are selectively activated in sequence for each row activation by the column driver 560 in response to column address decoder 570 .
  • a row and column address is provided for each pixel cells 110 x .
  • the imaging device 508 is operated by the control circuit 550 , which controls address decoders 520 , 570 for selecting the appropriate row and column lines for pixel readout, and row and column driver circuitry 510 , 560 , which apply driving voltage to the drive transistors of the selected row and column lines.
  • the pixel output signals typically include a pixel reset signal Vrst taken off of the floating diffusion region (via the source follower transistor) when it is reset and a pixel image signal Vsig, which is taken off the floating diffusion region (via the source follower transistor) after charges generated by an image are transferred to it.
  • the Vrst and Vsig signals are read by a sample and hold circuit 561 and are subtracted by a differential amplifier 562 , which produces a difference signal (Vrst ⁇ Vsig) for each pixel cells 110 x , which represents the amount of light impinging on the pixel cells 110 x .
  • This signal difference is digitized by an analog-to-digital converter (ADC) 575 .
  • ADC analog-to-digital converter
  • the digitized pixel signals are then fed to an image processor 580 to form a digital image output.
  • the imaging device 508 may be included on a single semiconductor chip (e.g., chip substrate 500 ).
  • FIG. 16 shows a typical system 600 , such as, but not limited to, a camera system.
  • the system 600 is modified to include an imaging device (such as the FIG. 15 imaging device 508 ).
  • the system 600 is an example of a system having digital circuits that could include image sensor devices. Without being limiting, such a system could include a computer system, camera system, scanner, machine vision, vehicle navigation system, video phone, surveillance system, auto focus system, star tracker system, motion detection system, image stabilization system, and other systems employing an imager.
  • System 600 for example, a camera system, includes a lens 680 for focusing an image on imager 100 , and generally comprises a central processing unit (CPU) 610 , such as a microprocessor that controls camera functions and image flow, and communicates with an input/output (I/O) device 640 over a bus 660 .
  • CMOS imager device 508 also communicates with the CPU 610 over the bus 660 .
  • the processor-based system 600 also includes random access memory (RAM) 620 , and can include removable memory 650 , such as flash memory, which also communicate with the CPU 610 over the bus 660 .
  • the imaging device 508 may be combined with the CPU 610 , with or without memory storage on a single integrated circuit or on a different chip than the CPU.
  • CMOS imaging devices e.g., 100 , 200 , 300 of FIGS. 1A-14B
  • CCD charge coupled device

Abstract

Methods of forming color filters having a light blocking material therebetween. A color filter is formed such that a trench is defined between a color filter and an adjacent color filter. The trench may be formed by exposing the color filter to polymerizing conditions such as, for example, ultraviolet radiation and heat. The trench may also be formed by etching between adjacent color filters. A material is formed within the trench.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • This application is a continuation-in-part of application Ser. No. 11/399,314, filed Apr. 7, 2006, which is hereby incorporated by reference.
  • FIELD OF THE INVENTION
  • Embodiments described herein relate to methods of forming color filters for use in a solid-state image sensor having a structure that isolates individual features from one another.
  • BACKGROUND OF THE INVENTION
  • Solid-state image sensors were developed in the late 1960s and early 1970s primarily for television image acquisition, transmission, and display. An imager absorbs incident radiation of a particular wavelength (such as optical photons, x-rays, or the like) and generates an electrical signal corresponding to the absorbed radiation. There are a number of different types of semiconductor-based imagers, including charge coupled devices (CCDs), photodiode arrays, charge injection devices (CIDs), hybrid focal plane arrays, and complementary metal oxide semiconductor (CMOS) imagers. Current applications of solid-state imagers include cameras, scanners, machine vision systems, vehicle navigation systems, star trackers, and motion detector systems, among other uses.
  • These imagers typically consist of an array of pixels containing photosensors, where each pixel produces a signal corresponding to the intensity of light impinging on its photosensor when an image is focused on the array. These signals may then be stored, for example, for later display, printing, or analysis or are otherwise used to provide information about the image. The photosensors may be phototransistors, photogates, photodiodes, or other light sensitive devices. The magnitude of the signal produced by each pixel is proportional to the amount of light impinging on the photo sensor.
  • To allow the photosensors to capture a color image, the photosensors must be able to separately detect color components for a captured image. For example, in a well known Bayer pattern photosensor array red (R) photons, green (G) photons, and blue (B) photons are captured by different pixel cells of the array. Accordingly, each pixel must be sensitive only to one color or spectral band. For this, a color filter array (CFA) is typically placed in front of the optical path to the photosensors so that each photosensor detects the light of the color of its associated filter. Thus, for an exemplary Bayer pattern photosensor array, each photosensor is covered with either a red, green, or blue filter, according to a specific pattern.
  • As noted, color filter arrays are commonly arranged in a mosaic sequential pattern of red, green, and blue filters known as a Bayer filter pattern. The Bayer filter pattern is quartet-ordered with successive rows that alternate red and green filters, then green and blue filters. Thus, each red filter is surrounded by four green and four blue filters, while each blue filter is surrounded by four red and four green filters. In contrast, each green filter is surrounded by two red, four green, and two blue filters. U.S. Pat. No. 3,971,065 to Bayer describes the Bayer pattern color filter array.
  • Forming a color filter array requires multistep fabrication process that can be complex and difficult to implement to obtain good separation of the color filters. Accordingly, there is a need and desire for improved methods of forming color filter arrays.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIGS. 1A and 1B illustrate partial top-down and cross-sectional views of an imager constructed in accordance with a first structural embodiment discussed herein.
  • FIGS. 2A-5B illustrate partial top-down and cross-sectional views of a first fabrication embodiment for forming the imager illustrated in FIGS. 1A and 1B.
  • FIGS. 6A-7B illustrate partial top-down and cross-sectional views of a second fabrication embodiment for forming the imager illustrated in FIGS. 1A and 1B.
  • FIGS. 8A and 8B illustrate partial top-down and cross-sectional views of an imager constructed in accordance with a second structural embodiment discussed herein.
  • FIGS. 9A-13B illustrate partial top-down and cross-sectional views of a fabrication embodiment for forming the imager illustrated in FIGS. 8A and 8B.
  • FIGS. 14A and 14B illustrate partial top-down and cross-sectional views of an imager constructed in accordance with a third structural embodiment discussed herein.
  • FIG. 15 is a partial top-down block diagram view of an imager device including the imager illustrated in FIGS. 1A and 1B.
  • FIG. 16 illustrates a system having the imager device illustrated in FIG. 15.
  • DETAILED DESCRIPTION OF THE INVENTION
  • In the following detailed description, reference is made to various specific embodiments. These embodiments are described with sufficient detail to enable those skilled in the art to practice the invention, and it is to be understood that other embodiments may be employed, and that structural and electrical changes may be made.
  • The term “substrate” used in the following description may include any supporting structure including, but not limited to, a semiconductor substrate that has a substrate surface. A semiconductor substrate should be understood to include silicon, silicon-on-insulator (SOI), silicon-on-sapphire (SOS), doped and undoped semiconductors, epitaxial layers of silicon supported by a base semiconductor foundation, and other semiconductor structures, including those made of semiconductors other than silicon. When reference is made to a semiconductor substrate or wafer in the following description, previous process steps may have been utilized to form regions or junctions in or over the base semiconductor or foundation. The substrate also need not be semiconductor-based, but may be any support structure suitable for supporting an integrated circuit, including, but not limited to, metals, alloys, glasses, polymers, ceramics, and any other supportive materials as is known in the art.
  • The term “pixel” or “pixel cell” refers to a picture element unit cell containing a photo-conversion device for converting electromagnetic radiation to an electrical signal. For purposes of illustration, a representative three-color Bayer R, G, B pixel array is described herein; however, the embodiments of the invention are not limited to the use of an R, G, B array, and can be used with other color arrays, one example being C, M, Y, K (which represents cyan, magenta, yellow, and black color filters). Also, for purposes of illustration, a portion of a representative pixel is illustrated in the figures and description herein, and typically fabrication of other pixel cells in an imager will proceed concurrently and in a similar fashion.
  • Embodiments described herein relate to methods of forming color filters for use in a solid-state image sensor. Although the embodiments of the invention are described in relation to use with a CMOS imager, they are not so limited and have applicability to any solid-state imager.
  • Referring now to the drawings, where like elements are designated by like numerals, FIGS. 1A and 1B illustrate a partial top-down view and side cross-sectional view (taken along line I-I of FIG. 1A), respectively, of a portion of a semiconductor-based imager 100, such as a CMOS imager, constructed in accordance with a first structural embodiment.
  • As illustrated in FIG. 1A, the imager 100 includes a plurality of pixel cells including first, second, and third pixel cells 110 b, 110 g, 110 r. The first, second, and third pixel cells 110 b, 110 g, 110 r include a microlens array 102 having microlenses 101 formed over corresponding first, second, and third color filters 103B, 103G, 103R in the color filter array 103. The color filter array 103 is illustrated as having a Bayer pattern; although, as noted, this is not intended to be limiting. Each of the first, second, and third color filters 103B, 103G, 103R allows a particular wavelength of light to pass through to corresponding first, second, and third photosensors 108 b, 108 g, 108 r formed in a semiconductor substrate 106 (FIG. 1B) formed below intervening fabrication layers 104 (FIG. 1B) including passivation and metallization layers.
  • The color filter array 103 also includes a light blocking material layer 121 formed between the first, second, and third color filters 103B, 103G, 103R in the color filter array 103. As illustrated in FIG. 1B, off-axis light 122 incident upon the imager 100 and intended for capture by the first photosensor 108 b would strike the adjacent photosensor 108 g (as shown by the dashed line) if the material layer 121 were not provided. By providing the material layer 121 between the first and second color filters 103B, 103G, however, the off-axis light 122 is prevented from striking the second photosensor 108 g thereby reducing the amount of optical cross talk between photosensors (e.g., first, second, and third photosensors 108 b, 108 g, 108 r). The material layer 121 thereby acts as a light shield between the photosensors.
  • The problem of optical cross talk is exacerbated by asymmetrical pixel cell architectures that have recently been proposed to increase photosensor array density. Asymmetrical pixel cell architecture demands the precise placement of color filters and overlying microlenses to focus light onto the photosensors. Misalignment of the color filter array and overlying microlenses may have detrimental effects caused by an increase in the incidence of cross talk.
  • In addition to decreasing the incidence of cross talk, the illustrated material layer 121 of FIGS. 1A and 1B may also increase the percentage of off-axis light 122 that is captured by the intended first photosensor 108 b by reflecting the off-axis light 122 onto the intended first photosensor 108 b, thereby increasing the quantum efficiency of the pixel cell.
  • FIGS. 2A-5B illustrate a first fabrication embodiment for forming the imager 100 illustrated in FIGS. 1A and 1B. As illustrated in FIGS. 2A and 2B, which are partial top-down and side cross-sectional views, respectively, the first color filter 103B is selectively deposited, patterned, and baked on a planarized upper surface of fabrication layer 104 and over respective first photosensors 108 b of the imager 100.
  • The first color filter 103B is formed of any transparent material that allows wavelengths of light (e.g., blue light) to pass through. For example, the first color filter 103B could be formed of zinc selenide (ZnSe), silicon oxide, silicon nitride, silicon oxynitride, silicon-carbon (SiC) (BLOk), tantalum pentoxide (Ta2O5), titanium oxide (TiO2), polymethylmethacrylate, polycarbonate, polyolefin, cellulose acetate butyrate, polystyrene, polyimide, epoxy resin, photosensitive gelatin, acrylate, methacrylate, urethane acrylate, epoxy acrylate, polyester acrylate, or a positive or negative photoresist such as a 3000 series photoresist material (or any other series of photoresist material) produced by FUJIFILM Electronic Materials (FFEM), Japan, including, but not limited to color resists known in the art as SB-3000L, SG-3000L and SR-3000L for blue, green, and red color filters, respectively. The first color filter 103B could also be formed of a material including, but not limited to, glass, for example, zinc selenide (ZnSe), boro-phospho-silicate glass (BPSG), phosphosilicate glass (PSG), borosilicate glass (BSG), silicon oxide, silicon nitride, or silicon oxynitride; an optical thermoplastic material such as tantalum pentoxide (Ta2O5), titanium oxide (TiO2), polymethylmethacrylate, polycarbonate, polyolefin, cellulose acetate butyrate, or polystyrene; a polyimide; a thermoset resin such as an epoxy resin; a photosensitive gelatin; or a radiation curable resin such as acrylate, methacrylate, urethane acrylate, epoxy acrylate, or polyester acrylate. The preceding materials are only illustrative examples.
  • FIGS. 3A and 3B illustrate partial top-down and side cross-sectional views, respectively, of the second color filter 103G being selectively deposited, patterned, and baked over respective second photosensors 108 g of the imager 100. The second color filter 103G can be formed of any of the materials listed above with respect to the first color filter 103B.
  • The second color filter 103G is formed adjacent, but not touching, the first color filter 103B, thereby defining a trench 120. The illustrated first and second color filters 103B, 103G could each have a width W1 in the range from about 1000 nm to about 2000 nm, and separated from one another by a distance D1 in the range from about 50 nm to about 200 nm, although the range is not intended to be limiting. By forming the first and second color filters 103B, 103G apart from one another, sidewall regions 105B, 105G of the first and second color filters 103B, 103G, respectively, are exposed for further processing, as discussed below with respect to FIGS. 5A and 5B.
  • FIGS. 4A and 4B illustrate partial top-down and side cross-sectional views, respectively, of the third color filter 103R being selectively deposited, patterned, and baked over respective third photosensors 108 r of the imager 100. The third color filter 103R can be formed of any of the materials listed above with respect to the first color filter 103B.
  • The third color filter 103R is formed adjacent to, but not touching, the second color filter 103G, thereby defining another trench 120. The illustrated second and third color filters 103G, 103R could each have a width W1 in the range from about 1000 nm to about 2000 nm, and separated from one another by a distance D2 in the range from about 50 nm to about 200 nm, although the range is not intended to be limiting. By forming the second and third color filters 103G, 103R apart from one another, sidewall regions 105G, 105R of each second and third color filters 103G, 103R, respectively, are exposed.
  • Although FIGS. 2A-4B illustrate the deposition, patterning, and baking of first, second, and third color filters 103B, 103G, 103R in succession, it is not intended to be limiting. As discussed below with respect to FIGS. 6A-7B, the processing of first, second, and third color filters 103B, 103G, 103R can occur simultaneously. It should also be noted that the order of forming the first second, and third color filters 103B, 103G, 103R is not important; for example, although illustrated as forming the first color filter corresponding to a blue color filter, the first color filter could be any desired color such as green or red, or any other desired color.
  • FIGS. 5A and 5B illustrate partial top-down and side cross-sectional views, respectively, of a material layer 121 formed over the exposed sidewall regions 105B, 105G, 105R (FIGS. 3A-4B), and between and over each of the first, second, and third color filters 103B, 103G, 103R in the color filter array 103. The material layer 121 may be formed of any opaque material, such as, for example, a metal, metal alloy, metal silicides, aluminum, or other opaque material. The material layer 121 may also be formed of a polysilicon material, which is opaque at shorter wavelengths of incoming light. Alternatively, the material layer 121 could be formed of any material having reflective properties, such as, for example, metal compounds such as silver or aluminum. The material layer 121 can be deposited by conventional coating methods, including, but not limited to, spin-coating, spray-coating, and ink jet coating methods.
  • An optional step of planarizing the material layer 121 can be employed for further processing of the imager 100 (FIGS. 1A and 1B). The planarization of the material layer could be performed by chemical mechanical polishing (CMP). Microlenses 101 (FIGS. 1A and 1B) are deposited, patterned, and reflowed to achieve the imager 100 illustrated in FIGS. 1A and 1B.
  • FIGS. 6A-7B illustrate a second fabrication embodiment for forming the imager 10 illustrated in FIGS. 1A and 1B. As illustrated in FIGS. 6A and 6B, which are partial top-down and side cross-sectional views, respectively, first, second, and third color filter precursors 103B′, 103G′, 103R′ are formed adjacent to, and abutting one another. The first, second, and third color filter precursors 103B′, 103G′, 103R′ are formed of a resist material, such as, for example, SB-3000L, SG-3000L and SR-3000L for blue, green, and red color filters, respectively. These materials typically contract by about 10% upon processing, for example, by being subjected to polymerizing conditions such as heat or ultraviolet radiation. Accordingly, it is possible to deposit first, second, and third color filter precursors 103B′, 103G′, 103R′ having predetermined dimensions, and reduce the volume upon processing. For example, the illustrated first, second, and third color filter precursors 103B′, 103G′, 103R′ are deposited to have a side cross-sectional width W2 of about 1000 nm, which have reduced volumes upon processing (as illustrated in FIGS. 7A and 7B).
  • As illustrated in FIGS. 7A and 7B, which are partial top-down and side cross-sectional views, respectively, the processing of the first, second, and third color filter precursors 103B′, 103G′, 103R′ (FIGS. 6A and 6B) result in first, second, and third color filters 103B, 103G, 103R. Each of the first, second, and third color filters 103B, 103G, 103R has a side cross-sectional width W3 of about 900 nm (i.e., a reduction of 10% of 1000 nm). Accordingly, the first, second, and third color filters 103B, 103G, 103R are separated from one another by a distance D3 that is about 100 nm. Due to the contraction of the first, second, and third color filters 103B, 103G, 103R, sidewall regions 105B, 105G, 105R are exposed defining trenches 120 between each of the first, second, and third color filters 103B, 103G, 103R. The material layer 121 (FIGS. 5A and 5B) is subsequently deposited over each of the sidewall regions 105B, 105G, 105R, within the trenches 120, and over the first, second, and third color filters 103B, 103G, 103R, as discussed above with respect to FIGS. 5A and 5B.
  • FIGS. 8A and 8B illustrate a partial top-down view and side cross-sectional view (taken along line I-I of FIG. 8A), respectively, of a portion of a semiconductor-based imager 200, such as a CMOS imager, constructed in accordance with a second structural embodiment discussed herein.
  • FIGS. 8A and 8B illustrate the imager 200 that is substantially similar to the imager 100 discussed above with respect to FIGS. 1A-1B. The imager 200, however, has a material layer 221 formed between first, second, and third pixel cells 210 b, 210 g, 210 r in the pixel cell array 210, which extends to a portion 104 a below a topmost surface 104 b of the fabrication layer 104. An optional etch stop layer 126 is formed within the fabrication layer 104 to aid in the processing of the FIG. 8B structure, as discussed below with respect to FIGS. 12A and 12B.
  • FIGS. 9A-12B illustrate an embodiment of fabricating the imager 200 illustrated in FIGS. 8A and 8B. FIGS. 9A and 9B, which are partial top-down and side cross-sectional views, respectively, illustrate the first, second, and third color filter precursors 103B′, 103G′, 103R′ deposited adjacent to, and abutting one another. In the illustrated embodiment, the materials are selected to form the first, second, and third color filters 103B, 103G, 103R (FIGS. 8A and 8B) such that there is no contraction.
  • FIGS. 10A and 10B, which are partial top-down and side cross-sectional views, respectively, illustrate resist layers 125 deposited and patterned over the first, second, and third color filter precursors 103B′, 103G′, 103R′. The resist layers 125 could be formed of a material that polymerizes upon exposure to polymerizing conditions such as, for example, heat or ultraviolet radiation.
  • The exposed portions 103B″, 103G″, 103R″ of the first, second, and third color filter precursors 103B′, 103G′, 103R′, respectively, between the resist layers 125 are removed by conventional methods, such as, for example, a wet develop in dilute TMAH (tetramethylammonium hydroxide). As illustrated in FIGS. 11A and 11B, the removal of the portions 103B″, 103G″, 103R″ result in the formation of the first, second, and third color filters 103B, 103G, 103R, and the exposure of sidewall regions (105B, 105G, 105R) for each color filter, which define trenches 120 in the FIG. 11B structure. The first and second color filters 103B, 103G are etched to have a predetermined distance D4 between them, and the second and third color filters 103G, 103R are etched to have a predetermined distance D5 between them. The predetermined distances D4 and D5 could be substantially the same or different, depending upon the intended application.
  • FIGS. 12A and 12B illustrate partial top-down and side cross-sectional views, respectively, of a further processing step of the structure illustrated in FIGS. 11A and 11B. Specifically, portions of the fabrication layer 104 below the color filter array 103 are removed by conventional techniques such as, for example, reactive ion etching, such that sidewall regions 107 of the fabrication layer 104 are exposed.
  • As a result of the processing, the sidewall regions 107 of the fabrication layer 104 are substantially aligned with the sidewall regions 105B, 105G, 105R of the first, second, and third color filters 103B, 103G, 103R. Together, the sidewall regions 107, 105B, 105G, 105R define trenches 120 between adjacent pixel cells (e.g., first, second, and third pixel cells 210 b, 210 g, 210 r in the pixel cell array 210 of FIGS. 8A and 8B). The illustrated trenches 120 are defined by a topmost surface of the color filter array 103 and a portion 104 a of the fabrication layer 104.
  • In the illustrated embodiment, the etch stop layer 126 is provided within the fabrication layer 104. The etch stop layer 126 indicates when the removal of the material layers (e.g., color filter materials and fabrication layer 104) should be terminated. FIGS. 13A and 13B illustrate the deposition of material layer 111 (FIGS. 8A and 8B) between each of the first, second, and third color filters 103B, 103G, 103R to fill the trenches 120 defined by the sidewall regions 107, 105B, 105G, 105R (FIG. 12B). The material layer 111 is deposited in a substantially similar manner as the material layer 121 discussed above with respect to FIGS. 5A and 5B (e.g., spin coating methods). As discussed above with respect to FIGS. 5A and 5B, the material layer 111 can be planarized by CMP to expose the topmost surfaces of the color filters.
  • FIGS. 14A and 14B illustrate partial top-down and side cross-sectional views, respectively, of a portion of a semiconductor-based imager 300, such as a CMOS imager, constructed in accordance with a third structural embodiment discussed herein.
  • FIG. 14A illustrates a top-down magnified portion of eight pixel cells 210 arranged as four two-way shared pixel cells. Shared pixel cells have recently been introduced, and are further described in U.S. Publication Nos. 2007/0046796, 2007/0045685, and 20060027887, all of which are assigned to Micron Technology, Inc. The disclosures of each of the foregoing are hereby incorporated by reference in their entirety.
  • FIG. 14A illustrates two adjacent pixel cells 210 in one row (e.g., Row A) of the array share common pixel components. Each pixel cell 210 has an individual color filter 230 formed over a photosensor 208. The photosensors 208 may be any photosensitive structure for converting light radiation into electrons (photo-charges). Due to the proximity of each photosensor 208 sharing common pixel components, a light material layer 321 is deposited to avoid potential cross talk between the adjacent color filters.
  • For a CMOS imager, each pixel cell 210 may have a respective transfer gate 202 as part of a respective transfer transistors for transferring the accumulated photo-charges from the photosensors 208 to a common storage node, shown as floating diffusion region 410. The transfer gates 202 are angled from the photosensors 208. For example, the longitudinal extent L′ of the transfer gates 202 is illustrated as being slanted with respect to the length Lp and the width Wp of the associated photosensors 208. The angular geometry of the transfer gate 202 allows for an efficient layout of the length L′ and width W′ of the transfer gate 102, which may improve the leakage and lag performance of the pixel cell 210. In addition, the angular layout is also beneficial in maximizing the fill factor of the pixel cell array, by maximizing the area of the photosensor 208 for each pixel cell 210.
  • The remaining pixel cell read out components shared between the adjacent pixel cells 210 are illustrated as being on a shared trunk 490, which is located between two column-adjacent pixel cells of a row, and also between pairs of row adjacent pixel cells of a row (e.g., Row B). The shared components on the trunk 490 include a floating diffusion region 410, which serves as a common storage node for the pixel cells 210 for receiving charges from photosensors 208 by the transfer gates 202. A reset transistor having a gate 407 is located on a side of the floating diffusion region 410 opposite the photosensors 208. A source/drain region 406 is located on a second side of the reset transistor gate 407, which is capable of receiving a supply voltage Vaa-pix. The floating diffusion region 410 is also electrically connected to the gate 409 of a source follower transistor, which has a drain coupled to the supply voltage Vaa-pix. The source follower transistor creates a voltage output signal based on stored charge on the floating diffusion region 410. A row select transistor having a gate 411 has a source/drain connected to the source of the source follower transistor, for selectively reading out the pixel signal to a column line 420. The shared pixel cell arrangement illustrated in FIG. 14A is merely exemplary. There are many different arrangements of shared pixel cell circuitry that may employ the light material layer 321 to isolate each pixel cell, thereby reducing optical cross talk.
  • As illustrated in FIG. 14B, each pixel cell 210 includes a microlens 224 formed over the color filters 230. Each color filter 230 is isolated by the material layer 321 to prevent cross-talk between adjacent pixel cells 230. The material layer 321 is formed in a substantially similar fashion as the embodiments discussed above with respect to FIGS. 1A and 1B (for example, the first fabrication embodiment discussed with respect to FIGS. 2A-5B). For example, the color filters 230 could be formed having various distances (e.g., D6 and D7) from each other, thereby defining trenches between the color filters. Subsequent processing steps include filling the trenches with material layer 321, and forming microlenses over respective photosensors 208 in the array. This processing results in material layer 321 having different side cross-sectional widths within the same array (e.g., W4 and W5) in the same array.
  • It should be noted that the imager 300 illustrated in FIGS. 14A and 14B could have the material layer 321 extend beyond an upper surface of the substrate 106 (as discussed above with respect to FIGS. 8A and 8B).
  • FIG. 15 illustrates an imaging device 508 incorporating an imager 100, 200, 300 (of FIGS. 1A-14B) constructed in accordance with embodiments discussed above.
  • In operation of the FIG. 15 imaging device 508, the pixel cells 110 x (representing any of the first, second, and third pixel cells of FIG. 1A) of each row in the imager 100 are all turned on at the same time by a row select line, and the pixel cells 110 x of each column are selectively output by respective column select lines. A plurality of row and column lines are provided for the entire array. The row lines are selectively activated in sequence by the row driver 510 in response to row address decoder 520 and the column select lines are selectively activated in sequence for each row activation by the column driver 560 in response to column address decoder 570. Thus, a row and column address is provided for each pixel cells 110 x. The imaging device 508 is operated by the control circuit 550, which controls address decoders 520, 570 for selecting the appropriate row and column lines for pixel readout, and row and column driver circuitry 510, 560, which apply driving voltage to the drive transistors of the selected row and column lines.
  • The pixel output signals typically include a pixel reset signal Vrst taken off of the floating diffusion region (via the source follower transistor) when it is reset and a pixel image signal Vsig, which is taken off the floating diffusion region (via the source follower transistor) after charges generated by an image are transferred to it. The Vrst and Vsig signals are read by a sample and hold circuit 561 and are subtracted by a differential amplifier 562, which produces a difference signal (Vrst−Vsig) for each pixel cells 110 x, which represents the amount of light impinging on the pixel cells 110 x. This signal difference is digitized by an analog-to-digital converter (ADC) 575. The digitized pixel signals are then fed to an image processor 580 to form a digital image output. In addition, as depicted in FIG. 15, the imaging device 508 may be included on a single semiconductor chip (e.g., chip substrate 500).
  • It should be noted that additional features of the circuitry of the FIG. 15 imaging device 508 are described in U.S. Pat. Nos. 6,140,630; 6,376,868; 6,310,366; 6,326,652; 6,204,524; 6,333,205; and 6,852,591, all of which are assigned to Micron Technology, Inc. The disclosures of each of the foregoing are hereby incorporated by reference in their entirety.
  • FIG. 16 shows a typical system 600, such as, but not limited to, a camera system. The system 600 is modified to include an imaging device (such as the FIG. 15 imaging device 508). The system 600 is an example of a system having digital circuits that could include image sensor devices. Without being limiting, such a system could include a computer system, camera system, scanner, machine vision, vehicle navigation system, video phone, surveillance system, auto focus system, star tracker system, motion detection system, image stabilization system, and other systems employing an imager.
  • System 600, for example, a camera system, includes a lens 680 for focusing an image on imager 100, and generally comprises a central processing unit (CPU) 610, such as a microprocessor that controls camera functions and image flow, and communicates with an input/output (I/O) device 640 over a bus 660. CMOS imager device 508 also communicates with the CPU 610 over the bus 660. The processor-based system 600 also includes random access memory (RAM) 620, and can include removable memory 650, such as flash memory, which also communicate with the CPU 610 over the bus 660. The imaging device 508 may be combined with the CPU 610, with or without memory storage on a single integrated circuit or on a different chip than the CPU.
  • It should again be noted that although the embodiments have been described with specific references to CMOS imaging devices (e.g., 100, 200, 300 of FIGS. 1A-14B), they have broader applicability and may be used in any imaging apparatus. For example, embodiments may be used in conjunction with charge coupled device (CCD) imagers. The above description and drawings illustrate embodiments which achieve the objects, features, and advantages described. Although certain advantages and embodiments have been described above, those skilled in the art will recognize that substitutions, additions, deletions, modifications and/or other changes may be made.

Claims (30)

1. A method of forming an imager, comprising:
forming a plurality of color filters over respective photosensors formed in a substrate such that a trench is located between at least two adjacent color filters; and
forming a material within the trench to optically isolate the adjacent color filters.
2. The method of claim 1, wherein the at least two adjacent color filters are formed apart from one another to define the trench.
3. The method of claim 1, wherein the at least two adjacent color filters are capable of contraction upon polymerization, and the step of forming a plurality of color filters comprises contracting the color filters to form the trench between two adjacent color filters.
4. The method of claim 1, wherein the trench is formed by the act of etching between two adjacent color filters.
5. The method of claim 4, further comprising:
forming the plurality of color filters such that they abut one another; and
etching between adjacent color filters to form the trench.
6. The method of claim 1, further comprising forming and patterning a mask over respective adjacent color filters such that at least a portion of the surfaces of the color filters are exposed.
7. The method of claim 6, wherein the trench is formed by etching the exposed surface and the material forming the color filters below the exposed surface.
8. The method of claim 7, wherein the etching extends to a fabrication layer formed over the photosensors.
9. The method of claim 7, wherein the etching extends beyond and into a fabrication layer formed over the photosensors.
10. The method of claim 9, further comprising forming an etch stop layer in the fabrication layer, and terminating the etching step upon reaching the etch stop layer.
11. The method of claim 1, wherein the color filters are patterned, deposited, and baked in succession.
12. The method of claim 1, wherein the color filters are patterned and deposited in succession, and subsequently baked simultaneously.
13. The method of claim 1, wherein the material is formed by deposition.
14. The method of claim 13, wherein the deposition step is performed by a method selected from the group consisting of spin-coating, spray-coating, and ink jet coating.
15. The method of claim 14, wherein the deposition step is performed by spin-coating material within and over the trench.
16. The method of claim 1, wherein the material is formed of an opaque material.
17. The method of claim 16, wherein the opaque material is formed of a material selected from the group consisting of metal, metal alloy, metal silicides, and aluminum.
18. A method of forming an integrated circuit, comprising:
forming a plurality of pixel cells by:
forming a plurality of photosensors arranged into a plurality of rows and columns in association with a substrate;
forming a respective color filter above each photosensor, at least two of said color filters separated from each other by a distance in the range of about 50 nm to about 200 nm; and
filling a space defined by the separation with a light blocking material, the step of filling the space performed by the act of spin-coating a light blocking material layer over the color filters.
19. The method of claim 18, wherein forming respective color filters further comprises etching the color filters to form the space between each color filter.
20. The method of claim 18, wherein forming the color filters at a distance from one another further comprises forming at least two adjacent and abutting color filters, and contracting the color filters to form the space.
21. The method of claim 20, wherein contracting the color filters is performed by exposing the color filters to polymerizing conditions.
22. The method of claim 21, wherein the act of exposing the color filters to polymerizing conditions comprises exposure to ultraviolet radiation.
23. The method of claim 21, wherein the act of exposing the color filters to polymerizing conditions comprises exposure to heat.
24. The method of claim 18, further comprising etching a fabrication layer formed over the semiconductor substrate to extend the space to a portion within the fabrication layer.
25. A method of forming an imager device, comprising:
providing an integrated circuit capable of capturing images, and having a plurality of pixel cells, the pixel cells formed by:
forming a plurality of photosensors arranged into a plurality of rows and columns in a substrate;
forming color filters over the photosensors, at least two of said color filters separated from each other by a predetermined distance such that respective sidewall regions of the color filters are exposed;
forming a light shield over the sidewall regions of the color filters, the light shield formed by spin-coating an aluminum material layer over the color filters;
planarizing the light shields to expose a topmost surface of the color filters; and
providing read out circuitry for the pixel cell array.
26. The method of claim 25, wherein the sidewall regions of the color filters are exposed by the act of etching the color filters.
27. The method of claim 25, wherein the sidewall regions of the color filters are exposed by the act of exposing the color filters to polymerizing conditions.
28. The method of claim 27 wherein the act of exposing the color filters to polymerizing conditions comprises exposure to ultraviolet radiation.
29. The method of claim 27, wherein the act of exposing the color filters to polymerizing conditions comprises exposure to heat.
30. The method of claim 25, wherein the predetermined distance is in the range of about 50 nm to about 200 nm.
US11/785,545 2006-04-07 2007-04-18 Methods to make sidewall light shields for color filter array Expired - Fee Related US7955764B2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US11/785,545 US7955764B2 (en) 2006-04-07 2007-04-18 Methods to make sidewall light shields for color filter array
PCT/US2008/059731 WO2008130846A2 (en) 2007-04-18 2008-04-09 Methods to make sidewall light shields for color filter array
TW097114385A TWI366918B (en) 2007-04-18 2008-04-18 Methods to make sidewall light shields for color filter array

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/399,314 US20070238035A1 (en) 2006-04-07 2006-04-07 Method and apparatus defining a color filter array for an image sensor
US11/785,545 US7955764B2 (en) 2006-04-07 2007-04-18 Methods to make sidewall light shields for color filter array

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US11/399,314 Continuation-In-Part US20070238035A1 (en) 2006-04-07 2006-04-07 Method and apparatus defining a color filter array for an image sensor

Publications (2)

Publication Number Publication Date
US20070237888A1 true US20070237888A1 (en) 2007-10-11
US7955764B2 US7955764B2 (en) 2011-06-07

Family

ID=39789490

Family Applications (1)

Application Number Title Priority Date Filing Date
US11/785,545 Expired - Fee Related US7955764B2 (en) 2006-04-07 2007-04-18 Methods to make sidewall light shields for color filter array

Country Status (3)

Country Link
US (1) US7955764B2 (en)
TW (1) TWI366918B (en)
WO (1) WO2008130846A2 (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090008731A1 (en) * 2007-07-05 2009-01-08 Hong Lae Kim Image Sensor and Method for Manufacturing the Same
US20090032823A1 (en) * 2007-08-01 2009-02-05 Ki-Ju Im Photo sensor and light emitting display having the same
US20100103288A1 (en) * 2008-10-28 2010-04-29 Samsung Electronics Co., Ltd. Image sensor
US20110037854A1 (en) * 2007-06-28 2011-02-17 Sony Corporation Solid-state imaging device and camera module
US20120050600A1 (en) * 2010-08-30 2012-03-01 Jung-Chak Ahn Unit pixel array and image sensor having the same
FR2966979A1 (en) * 2010-10-28 2012-05-04 St Microelectronics Grenoble 2 OPTICAL DEVICE, METHOD FOR MANUFACTURING SAME, AND ELECTRONIC HOUSING INCLUDING THE OPTICAL DEVICE
US20120273906A1 (en) * 2011-04-28 2012-11-01 Jeffrey Mackey Dielectric barriers for pixel arrays
US20130269765A1 (en) * 2012-04-13 2013-10-17 Electronics And Telecommunications Research Institute Bidirectional color embodiment thin film silicon solar cell
CN104282699A (en) * 2013-07-08 2015-01-14 台湾积体电路制造股份有限公司 Apparatus and method for fabricating a light guiding grid
US20150323381A1 (en) * 2014-05-08 2015-11-12 Infineon Technologies Dresden Gmbh Arrangement and method for determining the spatial direction of radiation incidence
US9497366B1 (en) 2015-05-27 2016-11-15 Semiconductor Components Industries, Llc Imaging systems with integrated light shield structures
US20170170220A1 (en) * 2015-12-14 2017-06-15 Samsung Electronics Co., Ltd. Image sensor having hybrid color filter
US20180286904A1 (en) * 2017-03-28 2018-10-04 Canon Kabushiki Kaisha Device, electronic apparatus, and transport apparatus
US20190206917A1 (en) * 2016-09-02 2019-07-04 Sony Semiconductor Solutions Corporation Solid-state imaging apparatus, method for manufacturing the same, and electronic device
US11641002B2 (en) 2018-05-18 2023-05-02 Stmicroelectronics (Grenoble 2) Sas Optical transmission/reception circuit

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004091763A2 (en) 2003-04-10 2004-10-28 President And Fellows Of Harvard College Formation and control of fluidic species
KR20070029618A (en) 2003-08-27 2007-03-14 더 프레지던트 앤드 펠로우즈 오브 하바드 칼리지 Electronic control of fluidic species
US8384818B2 (en) * 2008-06-18 2013-02-26 Panasonic Corporation Solid-state imaging device including arrays of optical elements and photosensitive cells
US10510787B2 (en) 2017-10-19 2019-12-17 Semiconductor Components Industries, Llc Structures and methods of creating clear pixels
US11646337B2 (en) 2020-07-09 2023-05-09 Semiconductor Components Industries, Llc Methods for using a gas permeable layer to form air gaps in an image sensor

Citations (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3971065A (en) * 1975-03-05 1976-07-20 Eastman Kodak Company Color imaging array
US6140630A (en) * 1998-10-14 2000-10-31 Micron Technology, Inc. Vcc pump for CMOS imagers
US6204524B1 (en) * 1999-07-14 2001-03-20 Micron Technology, Inc. CMOS imager with storage capacitor
US6310366B1 (en) * 1999-06-16 2001-10-30 Micron Technology, Inc. Retrograde well structure for a CMOS imager
US6326652B1 (en) * 1999-06-18 2001-12-04 Micron Technology, Inc., CMOS imager with a self-aligned buried contact
US6333205B1 (en) * 1999-08-16 2001-12-25 Micron Technology, Inc. CMOS imager with selectively silicided gates
US6376868B1 (en) * 1999-06-15 2002-04-23 Micron Technology, Inc. Multi-layered gate for a CMOS imager
US20030063204A1 (en) * 2001-08-31 2003-04-03 Canon Kabushiki Kaisha Image pickup apparatus
US6724425B1 (en) * 1999-07-14 2004-04-20 Hyundai Electronics Industries Co., Ltd. Solid state image sensor and method for fabricating the same
US20060027887A1 (en) * 2003-10-09 2006-02-09 Micron Technology, Inc. Gapless microlens array and method of fabrication
US20060081898A1 (en) * 2004-10-15 2006-04-20 Taiwan Semiconductor Manufacturing Co., Ltd. Enhanced color image sensor device and method of making the same
US20060158547A1 (en) * 2005-01-18 2006-07-20 Matsushita Electric Industrial Co., Ltd. Solid state imaging device and fabrication method thereof, and camera incorporating the solid state imaging device
US20060169878A1 (en) * 2005-01-17 2006-08-03 Masahiro Kasano Solid-state imaging device and manufacturing method for the same
US20070007443A1 (en) * 2005-07-06 2007-01-11 Matsushita Electric Industrial Co., Ltd. Solid-state imaging device and method for manufacturing the same
US20070040102A1 (en) * 2005-08-22 2007-02-22 Micron Technology, Inc. Method and apparatus providing an optical guide for an imager pixel having a ring of air-filled spaced slots around a photosensor
US20070046796A1 (en) * 2005-08-30 2007-03-01 Micron Technology, Inc. Method and apparatus providing a two-way shared storage gate on a four-way shared pixel
US20070045685A1 (en) * 2005-08-24 2007-03-01 Micron Technology, Inc. Method and apparatus providing integrated color pixel with buried sub-wavelength gratings in solid state imagers
US20070096232A1 (en) * 2005-09-28 2007-05-03 Joon Hwang CMOS image sensor and method for manufacturing the same
US20070188635A1 (en) * 2006-02-15 2007-08-16 Takumi Yamaguchi Solid-state imaging device and camera
US20070206241A1 (en) * 2006-03-06 2007-09-06 Micron Technology, Inc. Fused multi-array color image sensor
US20080049126A1 (en) * 2006-08-28 2008-02-28 Micron Technology, Inc. Color filter array and method of fabrication and use

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60178404A (en) 1984-02-27 1985-09-12 Canon Inc Color separating filter

Patent Citations (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3971065A (en) * 1975-03-05 1976-07-20 Eastman Kodak Company Color imaging array
US6140630A (en) * 1998-10-14 2000-10-31 Micron Technology, Inc. Vcc pump for CMOS imagers
US6376868B1 (en) * 1999-06-15 2002-04-23 Micron Technology, Inc. Multi-layered gate for a CMOS imager
US6310366B1 (en) * 1999-06-16 2001-10-30 Micron Technology, Inc. Retrograde well structure for a CMOS imager
US6326652B1 (en) * 1999-06-18 2001-12-04 Micron Technology, Inc., CMOS imager with a self-aligned buried contact
US6204524B1 (en) * 1999-07-14 2001-03-20 Micron Technology, Inc. CMOS imager with storage capacitor
US6724425B1 (en) * 1999-07-14 2004-04-20 Hyundai Electronics Industries Co., Ltd. Solid state image sensor and method for fabricating the same
US6852591B2 (en) * 1999-07-14 2005-02-08 Micron Technology, Inc. Method of forming CMOS imager with storage capacitor
US6333205B1 (en) * 1999-08-16 2001-12-25 Micron Technology, Inc. CMOS imager with selectively silicided gates
US20030063204A1 (en) * 2001-08-31 2003-04-03 Canon Kabushiki Kaisha Image pickup apparatus
US20060027887A1 (en) * 2003-10-09 2006-02-09 Micron Technology, Inc. Gapless microlens array and method of fabrication
US20060081898A1 (en) * 2004-10-15 2006-04-20 Taiwan Semiconductor Manufacturing Co., Ltd. Enhanced color image sensor device and method of making the same
US20060169878A1 (en) * 2005-01-17 2006-08-03 Masahiro Kasano Solid-state imaging device and manufacturing method for the same
US20060158547A1 (en) * 2005-01-18 2006-07-20 Matsushita Electric Industrial Co., Ltd. Solid state imaging device and fabrication method thereof, and camera incorporating the solid state imaging device
US20070007443A1 (en) * 2005-07-06 2007-01-11 Matsushita Electric Industrial Co., Ltd. Solid-state imaging device and method for manufacturing the same
US20070040102A1 (en) * 2005-08-22 2007-02-22 Micron Technology, Inc. Method and apparatus providing an optical guide for an imager pixel having a ring of air-filled spaced slots around a photosensor
US20070045685A1 (en) * 2005-08-24 2007-03-01 Micron Technology, Inc. Method and apparatus providing integrated color pixel with buried sub-wavelength gratings in solid state imagers
US20070046796A1 (en) * 2005-08-30 2007-03-01 Micron Technology, Inc. Method and apparatus providing a two-way shared storage gate on a four-way shared pixel
US20070096232A1 (en) * 2005-09-28 2007-05-03 Joon Hwang CMOS image sensor and method for manufacturing the same
US20070188635A1 (en) * 2006-02-15 2007-08-16 Takumi Yamaguchi Solid-state imaging device and camera
US20070206241A1 (en) * 2006-03-06 2007-09-06 Micron Technology, Inc. Fused multi-array color image sensor
US20080049126A1 (en) * 2006-08-28 2008-02-28 Micron Technology, Inc. Color filter array and method of fabrication and use

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8648943B2 (en) * 2007-06-28 2014-02-11 Sony Corporation Solid-state imaging device and camera module
US9640578B2 (en) 2007-06-28 2017-05-02 Sony Corporation Solid-state imaging device and camera module
US20110037854A1 (en) * 2007-06-28 2011-02-17 Sony Corporation Solid-state imaging device and camera module
US20090008731A1 (en) * 2007-07-05 2009-01-08 Hong Lae Kim Image Sensor and Method for Manufacturing the Same
US7977681B2 (en) * 2007-08-01 2011-07-12 Samsung Mobile Display Co., Ltd. Photo sensor and light emitting display having the same
US20090032823A1 (en) * 2007-08-01 2009-02-05 Ki-Ju Im Photo sensor and light emitting display having the same
US20100103288A1 (en) * 2008-10-28 2010-04-29 Samsung Electronics Co., Ltd. Image sensor
US20120050600A1 (en) * 2010-08-30 2012-03-01 Jung-Chak Ahn Unit pixel array and image sensor having the same
US8970768B2 (en) * 2010-08-30 2015-03-03 Samsung Electronics Co., Ltd. Unit pixel array and image sensor having the same
FR2966979A1 (en) * 2010-10-28 2012-05-04 St Microelectronics Grenoble 2 OPTICAL DEVICE, METHOD FOR MANUFACTURING SAME, AND ELECTRONIC HOUSING INCLUDING THE OPTICAL DEVICE
CN102455472A (en) * 2010-10-28 2012-05-16 意法半导体(格勒诺布尔2)公司 Optical device, method for manufacturing same and electronic packaging including said optical device
EP2448001A3 (en) * 2010-10-28 2013-12-25 STMicroelectronics (Grenoble 2) SAS Optical device, method for manufacturing same and electronic packaging including said optical device
US20120273906A1 (en) * 2011-04-28 2012-11-01 Jeffrey Mackey Dielectric barriers for pixel arrays
TWI548072B (en) * 2011-04-28 2016-09-01 普廷數碼影像控股公司 Dielectric barriers for pixel arrays
US9093579B2 (en) * 2011-04-28 2015-07-28 Semiconductor Components Industries, Llc Dielectric barriers for pixel arrays
US20130269765A1 (en) * 2012-04-13 2013-10-17 Electronics And Telecommunications Research Institute Bidirectional color embodiment thin film silicon solar cell
CN104282699A (en) * 2013-07-08 2015-01-14 台湾积体电路制造股份有限公司 Apparatus and method for fabricating a light guiding grid
US9559238B2 (en) * 2014-05-08 2017-01-31 Infineon Technologies Dresden Gmbh Arrangement and method for determining the spatial direction of radiation incidence
US20150323381A1 (en) * 2014-05-08 2015-11-12 Infineon Technologies Dresden Gmbh Arrangement and method for determining the spatial direction of radiation incidence
US9497366B1 (en) 2015-05-27 2016-11-15 Semiconductor Components Industries, Llc Imaging systems with integrated light shield structures
US20170170220A1 (en) * 2015-12-14 2017-06-15 Samsung Electronics Co., Ltd. Image sensor having hybrid color filter
US20190206917A1 (en) * 2016-09-02 2019-07-04 Sony Semiconductor Solutions Corporation Solid-state imaging apparatus, method for manufacturing the same, and electronic device
US11069730B2 (en) * 2016-09-02 2021-07-20 Sony Semiconductor Solutions Corporation Solid-state imaging apparatus, method for manufacturing the same, and electronic device
US20180286904A1 (en) * 2017-03-28 2018-10-04 Canon Kabushiki Kaisha Device, electronic apparatus, and transport apparatus
US10263023B2 (en) * 2017-03-28 2019-04-16 Canon Kabushiki Kaisha Device, electronic apparatus, and transport apparatus
US11641002B2 (en) 2018-05-18 2023-05-02 Stmicroelectronics (Grenoble 2) Sas Optical transmission/reception circuit

Also Published As

Publication number Publication date
WO2008130846A2 (en) 2008-10-30
US7955764B2 (en) 2011-06-07
WO2008130846A9 (en) 2010-01-14
TWI366918B (en) 2012-06-21
WO2008130846A3 (en) 2008-12-11
TW200903816A (en) 2009-01-16

Similar Documents

Publication Publication Date Title
US7955764B2 (en) Methods to make sidewall light shields for color filter array
US11404463B2 (en) Color filter array, imagers and systems having same, and methods of fabrication and use thereof
CN106068563B (en) Solid-state imaging device, method of manufacturing solid-state imaging device, and electronic apparatus
US9799698B2 (en) Solid-state imaging device having improved light-collection, method of manufacturing the same, and electronic apparatus
US7560295B2 (en) Methods for creating gapless inner microlenses, arrays of microlenses, and imagers having same
US7799491B2 (en) Color filter array and imaging device containing such color filter array and method of fabrication
US7428103B2 (en) Gapless microlens array and method of fabrication
US20070238035A1 (en) Method and apparatus defining a color filter array for an image sensor
US7335963B2 (en) Light block for pixel arrays
US7724439B2 (en) Lens, a lens array and imaging device and system having a lens, and method of forming the same
US7879638B2 (en) Backside illuminated imager and method of fabricating the same
US8389921B2 (en) Image sensor having array of pixels and metal reflectors with widths scaled based on distance from center of the array
US20090090850A1 (en) Deep Recess Color Filter Array and Process of Forming the Same
US8077230B2 (en) Methods and apparatus for reducing color material related defects in imagers
US20080204580A1 (en) Method, apparatus and system providing imaging device with color filter array
US20060261385A1 (en) Phase shift transparent structures for imaging devices
US20240072081A1 (en) Image sensor

Legal Events

Date Code Title Description
AS Assignment

Owner name: MICRON TECHNOLOGY, INC., IDAHO

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:LIU, SAIJIN;BOETTIGER, ULRICH C.;REEL/FRAME:019275/0900;SIGNING DATES FROM 20070416 TO 20070417

Owner name: MICRON TECHNOLOGY, INC., IDAHO

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:LIU, SAIJIN;BOETTIGER, ULRICH C.;SIGNING DATES FROM 20070416 TO 20070417;REEL/FRAME:019275/0900

FEPP Fee payment procedure

Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

STCF Information on status: patent grant

Free format text: PATENTED CASE

FPAY Fee payment

Year of fee payment: 4

AS Assignment

Owner name: APTINA IMAGING CORPORATION, CAYMAN ISLANDS

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:MICRON TECHNOLOGY, INC.;REEL/FRAME:036972/0924

Effective date: 20081003

AS Assignment

Owner name: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT, CALIFORNIA

Free format text: SECURITY INTEREST;ASSIGNOR:MICRON TECHNOLOGY, INC.;REEL/FRAME:038669/0001

Effective date: 20160426

Owner name: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGEN

Free format text: SECURITY INTEREST;ASSIGNOR:MICRON TECHNOLOGY, INC.;REEL/FRAME:038669/0001

Effective date: 20160426

AS Assignment

Owner name: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT, MARYLAND

Free format text: PATENT SECURITY AGREEMENT;ASSIGNOR:MICRON TECHNOLOGY, INC.;REEL/FRAME:038954/0001

Effective date: 20160426

Owner name: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL

Free format text: PATENT SECURITY AGREEMENT;ASSIGNOR:MICRON TECHNOLOGY, INC.;REEL/FRAME:038954/0001

Effective date: 20160426

AS Assignment

Owner name: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT, CALIFORNIA

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE REPLACE ERRONEOUSLY FILED PATENT #7358718 WITH THE CORRECT PATENT #7358178 PREVIOUSLY RECORDED ON REEL 038669 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY INTEREST;ASSIGNOR:MICRON TECHNOLOGY, INC.;REEL/FRAME:043079/0001

Effective date: 20160426

Owner name: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGEN

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE REPLACE ERRONEOUSLY FILED PATENT #7358718 WITH THE CORRECT PATENT #7358178 PREVIOUSLY RECORDED ON REEL 038669 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY INTEREST;ASSIGNOR:MICRON TECHNOLOGY, INC.;REEL/FRAME:043079/0001

Effective date: 20160426

AS Assignment

Owner name: MICRON TECHNOLOGY, INC., IDAHO

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT;REEL/FRAME:047243/0001

Effective date: 20180629

MAFP Maintenance fee payment

Free format text: PAYMENT OF MAINTENANCE FEE, 8TH YEAR, LARGE ENTITY (ORIGINAL EVENT CODE: M1552); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

Year of fee payment: 8

AS Assignment

Owner name: MICRON TECHNOLOGY, INC., IDAHO

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT;REEL/FRAME:050937/0001

Effective date: 20190731

FEPP Fee payment procedure

Free format text: MAINTENANCE FEE REMINDER MAILED (ORIGINAL EVENT CODE: REM.); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

LAPS Lapse for failure to pay maintenance fees

Free format text: PATENT EXPIRED FOR FAILURE TO PAY MAINTENANCE FEES (ORIGINAL EVENT CODE: EXP.); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

STCH Information on status: patent discontinuation

Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362

FP Lapsed due to failure to pay maintenance fee

Effective date: 20230607