US20070292568A1 - Dynamic modified atmosphere package system - Google Patents
Dynamic modified atmosphere package system Download PDFInfo
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- US20070292568A1 US20070292568A1 US11/453,712 US45371206A US2007292568A1 US 20070292568 A1 US20070292568 A1 US 20070292568A1 US 45371206 A US45371206 A US 45371206A US 2007292568 A1 US2007292568 A1 US 2007292568A1
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- Prior art keywords
- interior space
- liquid
- package
- gas
- separating member
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/18—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
- B65D81/20—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas
- B65D81/2069—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas in a special atmosphere
- B65D81/2076—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas in a special atmosphere in an at least partially rigid container
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D17/00—Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions
- B65D17/28—Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions at lines or points of weakness
- B65D17/401—Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions at lines or points of weakness characterised by having the line of weakness provided in an end wall
- B65D17/4011—Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions at lines or points of weakness characterised by having the line of weakness provided in an end wall for opening completely by means of a tearing tab
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
Definitions
- the present invention relates to a dynamic modified atmosphere package system. More particularly, the present invention relates to a dynamic modified atmosphere package system for providing a pressurized gaseous environment for a quantity of product.
- Modified atmosphere packaging generally refers to the practice of modifying the composition of the internal atmosphere or headspace of a package in order to improve the shelf-life of the product.
- the product is typically a food product but may also include pharmaceuticals or other types of products.
- the modification usually involves attempts to lower the amount of oxygen in order to slow down the growth of aerobic organisms and the speed of oxidation reactions.
- the removed oxygen is typically replaced with nitrogen, commonly known as an inert gas, or carbon dioxide, which can lower the pH or inhibit the growth of bacteria.
- modified atmosphere packaging is generally considered a technique used for prolonging the shelf-life of fresh or minimally processed foods.
- the air surrounding the food in the package is changed to another composition using, for example, a gas-flush process.
- the initial fresh state of the food may be prolonged by slowing the natural deterioration of the food product.
- Respiring foods such as fruits and vegetables continue to take in oxygen and give off carbon dioxide as they continue to respire and ripen after harvest.
- Refrigeration and controlled atmosphere storage methods may be used to retard the ripening process. Reducing temperature slows the produce metabolism, including the rate of respiration. Under controlled atmosphere storage, respiration and ripening may be reduced further by lowering the oxygen content of the air, which normally consists of approximately 21% oxygen, 78% nitrogen, and 1% other elements.
- Low permeable/high barrier packaging films are typically used for non-respiring foods such as meat, fish, and cheese.
- permeable or semi-permeable packaging films are typically used for respiring foods such as fruits and vegetables.
- Such packaging films are typically engineered with enough permeability to allow carbon dioxide concentrations to build within the package, thereby slowing the respiration rate of the produce, and oxygen levels to remain low (1%-5%) to prevent anaerobic fermentation. If the permeability of the film, for oxygen and carbon dioxide, is adapted to the particular respiration rate of the product, an equilibrium modified atmosphere may be established in the package.
- Such equilibrium modified atmosphere packaging may be used to increase the shelf-life of fresh-cut produce by reducing respiration and ethylene production rates, delaying senescence, and inhibiting the growth of spoilage organisms.
- modified atmosphere packaging techniques necessarily rely on various permeable or semi-permeable films, or barrier films, and are incapable of retaining a positive pressure atmosphere within the package.
- Currently available modified atmosphere packaging techniques and packaging systems are not suitable for products requiring a positive pressure atmosphere within the package or for products that might benefit by having a positive pressure atmosphere within the package.
- a package capable of retaining a positive pressure atmosphere within the package is a tennis ball can (or tennis ball tube).
- the air pressure inside a tennis ball is typically 12 psi (pounds per square inch) greater than the ambient air pressure at sea level. Over time, air escapes from the inside of the ball causing a decrease in the amount of air pushing on the inside of the ball and, consequently, decreasing the bounce characteristics of the ball.
- the ball is packaged in a positive pressure tube, with the tube pressurized to around 12 psi, which is enough to prevent air from escaping from the inside of the ball.
- a tennis ball can or similar package may be capable of retaining a positive pressure, such a package does not include capabilities for dynamically modifying the elements comprising the atmosphere within the package.
- a dynamic modified atmosphere package system that provides a pressurized gaseous environment would be useful, for example, for the carbonated fruits or vegetables products described in U.S. Pat. No. 5,968,573, U.S. patent application Ser. No. 10/857,043, U.S. Provisional Application Ser. No. 60/699,450, and U.S. patent application Ser. No. 10/304,197, all commonly owned or licensed by The Fizzy Fruit Company and herein incorporated by reference.
- the described carbonated fruits or vegetables products generally include fruits or vegetables that have absorbed enough carbon dioxide so that the fruits or vegetables have acquired an effervescent or “fizzy” quality. The absorbed carbon dioxide tends to remain absorbed within the tissue of the fruits or vegetables for a longer period of time when the carbonated fruits or vegetables are maintained in a pressurized carbon dioxide rich atmosphere.
- a dynamic modified atmosphere package system that addresses the above and other shortcomings.
- a dynamic modified atmosphere package system is needed that is capable of providing a pressurized gaseous modified atmosphere for a quantity of product such as, for example, fresh-cut fruits or vegetables.
- a dynamic modified atmosphere package system is described herein that overcomes the shortcomings of prior art modified atmosphere package systems by providing a dynamic modified atmosphere package comprising, in one embodiment, a sealable container having a first interior space for holding a quantity of product and a second interior space separated from the first interior space, the sealable container configured so that a liquid is able to pass from the first interior space into the second interior space, the liquid becoming substantially trapped within the second interior space, and the sealable container configured so that a gas is able to vent from the second interior space into the first interior space.
- the package is capable of providing a pressurized gaseous modified atmosphere for a quantity of product such as, for example, fresh-cut fruits or vegetables.
- the package is capable of providing a pressurized carbon dioxide rich atmosphere for carbonating or maintaining the carbonation of a quantity of fruits or vegetables.
- an optimum amount of oxygen is provided to avoid harmful anaerobic conditions.
- sodium bicarbonate and citric acid placed in the second interior space of the package is mixed with water to produce carbon dioxide, and sodium percarbonate placed in the second interior space is mixed with water to generate oxygen.
- the package includes a pull-tab type lid with additional features to slow the release of pressure when the pull-tab lid is opened to access the first interior space and the quantity of product therein.
- the package may comprise a clear plastic cup having a separating member that may be inserted into the cup after gas generating tablets have been placed in the bottom of the cup.
- a quantity of product is placed within the interior space above the insert, water is added, and a metallic pull-tab lid is sealed over the opening of the cup.
- a pressurized atmosphere rich in carbon dioxide is generated, and enough carbon dioxide is absorbed by the tissue of fruits or vegetables within the sealed package so that the fruits or vegetables acquire an effervescent or “fizzy” quality.
- a quantity of fruits or vegetables is placed within the sealed package, the package is sealed, and, at a time thereafter, mechanical mixing means are used for initiating carbonation of the fruits or vegetables.
- the mechanical mixing means may involve rupturing membranes filled with the reactants for generating carbon dioxide and oxygen, thereby initiating the carbonation of the fruits or vegetables.
- the sealed package may include a separating member having at least one gas vent hole for allowing the generated carbon dioxide and oxygen to surround the fruits or vegetables, the separating member configured without a liquid passage hole and with the gas vent hole sized to prevent the passage of liquid through the separating member.
- FIG. 1 is a perspective view of a dynamic modified atmosphere package system according to one embodiment.
- FIG. 2 is a cross-sectional view of a dynamic modified atmosphere package system according to one embodiment.
- FIG. 3 is an exploded view of selected components of a dynamic modified atmosphere package system according to one embodiment.
- FIG. 4 is a bottom view of a pull-tab type lid according to one embodiment.
- FIG. 5 is a cross-sectional view of a pull-tab type lid according to one embodiment.
- FIG. 6 is a cross-sectional view of a pull-tab type lid with double cut protection, according to one embodiment.
- a suitable package incorporates an internal release of carbon dioxide from within the package by using a source of carbon dioxide that can produce a volume of carbon dioxide inside the package that, upon sealing the package, would pressurize the package with enough carbon dioxide for carbonating fruits or vegetables within the package to achieve a sufficient carbonation level within the tissue or fleshy parts of the fruits or vegetables.
- a sealed package having therein between thirty and forty pounds per square inch of pressurized carbon dioxide is enough pressurized carbon dioxide to adequately carbonate a portion of fresh-cut grapes.
- the present inventors experimented with, in one embodiment, using a pellet of dry ice for generating pressurized carbon dioxide within a package. However, it was determined that while such a pellet does comprise a suitable gas generating substance, and is, therefore, to be included as an acceptable gas generating substance in at least one embodiment, the handling of dry ice is not easily accommodated in typical fruit (or food) processing environments.
- the present inventors subsequently found that a dry powder mixture of sodium bicarbonate and citric acid (or other appropriate carboxylic base and acid) which when activated by water or a water-based solution would generate the requisite volume of carbon dioxide to pressurize the package.
- sodium percarbonate or a food grade hydrogen peroxide or a combination of the two or another substance may be used to generate oxygen within the package so that the modified atmosphere includes enough oxygen to avoid the growth of anaerobic bacteria.
- oxygen is consumed and carbon dioxide is produced.
- the present inventors found that, unlike any other modified atmosphere or pressurized package system or method, by generating within the sealed package pressurized carbon dioxide as well as enough oxygen to prevent anaerobic conditions, the atmosphere within the sealed package may be dynamically modified to achieve a desired gaseous composition, even as the fruits or vegetables (or other products) continue to ripen, respire, or otherwise affect the composition of the atmosphere within the sealed package.
- a gas generating substance may be included so that the resulting modified atmosphere includes or maintains a level of approximately two to three percent oxygen.
- gas generating substances and suitably corresponding liquids may be used with a suitably designed package system for carbonating products (such as fruits or vegetables) within a package and for prolonging the shelf-life of such products.
- products such as fruits or vegetables
- sodium bicarbonate and citric acid may be activated with water to generate carbon dioxide in a separated space within the package, and the separated space may be configured to prevent unreacted reactants and residual solution formed in the reaction from coming into contact with and possibly tainting the flavor of fruits or vegetables in the package. It was found that such contact may cause an unpleasant or salty taste in, for example, a “fizzy” fruit product.
- Such improvements include, but are not limited to, using transparent material for display of the product contained in the sealed container, fabricating the sealable container using semi-rigid material and with ribs and other features to improve pressure retention characteristics, sizing and positioning gas vent holes to allow gas flow and prevent liquid flow, sizing and positioning any liquid passage hole to allow for a desired gas generating reaction rate yet prevent liquid from fouling or tainting the product, including mechanical means for initiating carbonation of the product after sealing the package, designing a pull-tab type lid for the package that incorporates opening features for slowing the release of pressure when opening the pressurized package, and other aspects described or depicted in the drawings.
- FIG. 1 is a perspective view of a dynamic modified atmosphere package system 100 according to one embodiment.
- the dynamic modified atmosphere package system 100 includes a sealable container 105 capable of retaining a positive pressure, a quantity of product 110 within a first interior space 115 within the sealable container 105 , a separating member 120 within the sealable container 105 separating the first interior space 115 from a second interior space 125 within the sealable container 105 , a gas generating substance 130 , 135 within the second interior space 125 within the sealable container 105 , and a predetermined quantity of a liquid 140 capable of reacting with the gas generating substance 130 , 135 within the second interior space 125 to generate a pressurized carbon dioxide rich atmosphere within the first and second interior spaces 115 and 125 , the pressurized carbon dioxide rich atmosphere also including enough oxygen to avoid anaerobic conditions associated with the quantity of product 110 .
- the sealable container 105 may include a pull-tab type lid 145 sealing
- the sealable container 105 may be made from any of a wide variety of materials and may be formed into any of a wide variety of shapes.
- the sealable container 105 may be formed from a transparent material such as a transparent plastic and may be formed into the shape of a cup 150 .
- the cup 150 may be substantially cubic with a square or rectangular base instead of the substantially cylindrical shape shown, and the cup 150 may be made of an opaque or colored material.
- the sealable container 105 is capable of retaining a positive internal pressure of at least thirty pounds per square inch (psi).
- the sealable container 105 may be designed to retain an internal pressure of between thirty and forty pounds per square inch.
- a rigid or semi-rigid material may be used.
- the sealable container 105 may comprise a cup 150 made of polyethylene terephthalate (PET) or a similarly formable semi-rigid material and a metallic pull-tab type lid 145 sealed about the opening of the cup 150 .
- PET polyethylene terephthalate
- the pull-tab type lid 145 may be an aluminum pull-tab type lid, or the lid 145 may be made of another material or combination of materials such as laminated or composite materials.
- the sealable container 105 includes a pull-tab type lid 145 that may be opened to expose the quantity of product 110 within the first interior space 115 of the sealable container 105 by pulling a pull-tab 155 outward, away from the lid 145 and cup 150 , similar to fruit or pudding cups using similar pull-tab type lids.
- the pull-tab type lid 145 opens to expose a four ounce or eight ounce volume within the first interior space 115 , suitable for holding a quantity of product 110 .
- the product is typically a food product but may include pharmaceuticals or other types of products.
- the quantity of product 110 may include, for example, a portion of fruits or vegetables, where reference to “a portion of fruits or vegetables” is used herein to refer to a portion of any one or any combination of the following: a single type of fruit, a mixture of different types of fruit, a single type of vegetable, a mixture of different types of vegetable, or a mixture of one or more types of fruit and one or more types of vegetable.
- the fruits or vegetables may comprise fresh-cut whole grapes, de-stemmed grapes mixed with strawberries, a particular type of fruit mixed with a particular type of vegetable, or any other combination of fruits or vegetables.
- the fruits or vegetables may comprise fresh-cut or minimally processed fruits or vegetables but may also include fruits or vegetables that have been processed.
- the fruits or vegetables may comprise fruits or vegetables that have been carbonated before placement into the first interior space 115 of the sealable container 105 .
- the separating member 120 separates the first interior space 115 from the second interior space 125 and includes at least one gas venting hole configured so that gas generated by the gas generating substance 130 , 135 is able to vent from the second interior space 125 into the first interior space 115 .
- the separating member 120 includes at least one liquid passage hole configured so that the liquid 140 is able to pass from the first interior space 115 into the second interior space 125 , thereafter becoming substantially trapped within said second interior space 125 .
- the separating member may be configured to substantially prevent the liquid 140 from passing from the second interior space 125 into the first interior space 115 even as the sealable container 105 is tipped on its side or inverted.
- the venting hole allows liquid to flow freely from the first interior space 115 into the second interior space 125 by letting gas trapped in the second interior space 125 into the first interior space 115 . Without the gas venting hole, according to one embodiment, the liquid may stop flowing into the second interior space 125 .
- the separating member 120 may be integral to either the material comprising the first interior space 115 or the material comprising the second interior space 125 or both, or the separating member 120 may comprise an insert that fits into the bottom of the cup 150 , thereby separating the first interior space 115 (as a larger upper space within the cup 150 ) and the second interior space 125 (as a smaller lower space at the bottom of the cup 150 ).
- a liquid 140 such as water may be introduced into the first interior space 115 before or after the quantity of product 110 and before or after sealably closing the sealable container 105 .
- the water initially collects at the surfaces of the separating member in communication with the first interior space. Then, after passing through a liquid passage hole in the separating member, the water collects in the bottom area of the sealable container 105 . As the water collects in the bottom area, or second interior space 125 , the water mixes with gas generating substance 130 , 135 , which may comprise sodium bicarbonate and citric acid, respectively, causing a generation of carbon dioxide gas.
- the generated carbon dioxide gas is allowed to vent into the first interior space 115 through at least one gas venting hole in the separating member 120 and also through the liquid passage hole as well, filling the first and second interior spaces with pressurized carbon dioxide.
- the pressurized carbon dioxide is then available for carbonation of fruits or vegetables within the first interior space 115 .
- the quantity of product 110 comprises a portion of fruits or vegetables with at least some of the fruits or vegetables capable of absorbing at least some of the carbon dioxide for acquiring an effervescent quality. As more carbon dioxide is absorbed into the tissue or fleshy part of the fruits or vegetables, the fruits or vegetables become more effervescent or “fizzy.”
- the gas generating substance 130 , 135 may generate both carbon dioxide to create a pressurized carbon dioxide rich atmosphere within the sealable container 105 and just enough (perhaps between 1% to 5%) oxygen to avoid anaerobic conditions.
- the gas generating substance 130 , 135 may comprise sodium bicarbonate and citric acid for generating carbon dioxide when mixed with water and sodium percarbonate for generating oxygen when mixed with water.
- gas generating tablets may be positioned within the second interior space 125 for generation of carbon dioxide and oxygen when mixed with (or activated by) a liquid 140 .
- the tablets may comprise active ingredients compressed to a density at least partially dependent upon a desired gas generation rate when the tablets are mixed with a predetermined amount of the liquid 140 .
- the active ingredients for generating oxygen may be compressed within the respective tablet to a greater density to control the reaction rate and generation of oxygen.
- the active ingredients for generating carbon dioxide may be compressed within the respective tablet to adjust the generation rate of carbon dioxide.
- the desired gas generation rates for carbon dioxide and oxygen may, therefore, be adjusted based upon, in part, the particular respiration rates of the fruits or vegetables or various other parameters, such as, for example, the time between the insertion of the liquid 140 and sealing the pull-tab type lid 145 to the cup 150 .
- FIG. 2 is a cross-sectional view of a dynamic modified atmosphere package system 200 according to one embodiment.
- the system 200 may comprise a cup 205 and a pull-tab type lid 210 , which together comprise a sealable container capable of retaining a positive pressure inside and holding a quantity of product 215 within a first interior space 220 .
- Other types of lids may be used for sealing the sealable container, and, as mentioned, the container need not take the shape of a cup.
- a cup shape is useful for holding a quantity of product 215 , such as, for example, a portion of fruits or vegetables (depicted in FIG. 2 as de-stemmed grapes), within a first interior space 220 .
- a separating member 225 may be inserted into the bottom portion of the cup 205 for separating the first interior space 220 from a second interior space 230 .
- the separating member 225 provides space for reacting a carboxylic base with an acid to form carbon dioxide and other reactants to produce an amount of oxygen, both in gaseous form to dynamically modify the atmosphere within the container for carbonating a quantity of product 215 and maintaining optimum oxygen levels at least partially in response to respiration or other changes in the quantity of product 215 affecting the composition of the atmosphere within the sealable container, according to one embodiment.
- the dynamic modified atmosphere package system 200 may be used to dynamically modify the atmosphere for products such as pharmaceuticals and use other reactants for producing different compositions of atmosphere within the sealable package and for dynamically modifying the composition of such atmosphere at least partially in response to changes in the pharmaceutical or other product within the first interior space 220 .
- a pull-tab type lid 210 may be sealed upon suitably mating rim surfaces of the cup 205 using a can seaming machine. Such a machine may seal a lid 210 over a cup 205 by folding the lid material over the cup material. Commercially available can seaming (or can sealing) machines may be used. However, modifications may be needed so that the resulting sealed container is capable of retaining a positive pressure gaseous atmosphere. In one embodiment, the sealed container is capable of retaining at least thirty pounds per square inch of internal pressure.
- the cup 205 , the lid 210 , and the seal between the lid 210 and the cup 205 are capable of retaining between thirty and fifty pounds per square inch of internal gaseous pressure.
- the cup 205 may incorporate structural features such as a rib 235 about the circumference of the cup 205 near its rim surfaces.
- the rib 235 feature provides additional strength and rigidity.
- material thickness of the cup 205 may be increased to improve pressure retention capabilities.
- the cup 205 comprises a PET plastic material with a thickness of approximately 0.6 millimeters. It was found that a material thickness of 0.3 millimeters may be too thin without additional structural changes, such as additional rib features.
- cup 2 includes substantially flat sides below the rib 235 and extending away from the lid 210 toward the bottom 240 of the cup 205 .
- substantially flat sides allow for improved readability of shrink type labels or printing processes which may be used for product labeling.
- the sides of cup 205 are shown tapering down from a larger diameter rib 235 area to smaller diameters toward the bottom 240 .
- Other configurations are possible.
- the cup 205 may include straight sides.
- a tapered shape allows for nesting multiple empty cups together for improved shipping densities and lowered overall material costs.
- a lower portion 245 of the cup 205 may have a slightly smaller diameter so that the separating member 225 may be easily and freely inserted into the cup 205 .
- the smaller diameter of the lower portion 245 provides an interference fit between the inside surfaces of the lower portion 245 of the cup and the outward (or peripheral) surfaces of the separating member 225 .
- the interference fit in one embodiment, is tight enough that the separating member 225 remains positioned within the lower portion 245 of the cup 205 and separates the first interior space 220 from the second interior space 230 .
- the interference fit is tight enough to prevent liquid trapped within the second interior space 230 from passing into the first interior space 220 if, for example, the cup 205 is tipped from an upright orientation or inverted.
- the inside surfaces of the lower portion 245 of the cup and the outward surfaces of the separating member 225 need not be straight (as shown) but may incorporate complementary or cooperatively mating ribs or bends so that the separating member 225 remains in its position in the lower portion 245 of the cup.
- One method for dynamically modifying an atmosphere within a package includes providing a sealable container, such as the cup 205 and lid 210 , that is capable of retaining a positive pressure and has a first interior space 220 and a second interior space 230 .
- a gas generating substance such as tabets 250 , 255 , may be placed into the second interior space 230 of the sealable container.
- a separating member 225 may be inserted into the sealable container to separate the first interior space 220 from the second interior space 230 .
- a quantity of product 215 such as grapes, for example, may be introduced into the first interior space 220 .
- a predetermined quantity of a liquid 260 may be introduced into the first interior space 220 where the liquid 260 is capable of reacting with the gas generating substance to generate a pressurized carbon dioxide rich atmosphere within the first interior space 220 .
- the liquid 260 in one embodiment, is also capable of reacting with the gas generating substance to generate enough oxygen to avoid anaerobic conditions associated with the quantity of product 215 .
- the opening to the first interior space 220 may be sealed using a pull-tab type lid 210 as shown in FIG. 2 .
- the above method steps may be performed in the sequence described or in different orders.
- the liquid 260 may be introduced into the first interior space 220 before the quantity of product 215 or even before the separating member 225 is placed into the lower portion 245 of the cup 205 .
- Various other embodiments may require differently ordered steps.
- the gas generating substance may be placed within the lower portion 245 before the lower portion 245 is sealably attached to the rest of the cup 205 (perhaps using a thermal welding or other process).
- the liquid 260 passes downward within the first interior space 220 and through a liquid passage hole 265 in the separating member 225 , collecting as shown in FIG. 2 in the bottom 240 of the cup 205 .
- the bottom 240 may comprise an annular trough within which the gas generating substance such as tablets 250 , 255 may come to rest.
- the annular trough may serve to concentrate the liquid 260 or allow for the use of a lower predetermined amount of liquid 260 for sufficient reaction with the gas generating substance.
- tablet 250 comprises sodium bicarbonate or a mixture of sodium bicarbonate and sodium percarbonate or some other carboxylic base
- tablet 255 comprises citric acid or some other appropriate acid for generating carbon dioxide and oxygen when mixed with water or an appropriate liquid solution.
- the oxygen generating substance may comprise a separate tablet or an oxygen generating substance mixed into or incorporated into a tablet comprising sodium bicarbonate.
- tablet 250 may comprise an oxygen generating substance such as sodium percarbonate
- tablet 255 may comprise a carbon dioxide generating substance such as sodium bicarbonate
- a third tablet (not shown) may comprise citric acid.
- At least one ridge or upward protrusion is formed upon the separating member 225 .
- a gas venting hole positioned on such a ridge allows for gas generated within the second interior space 230 to vent into the first interior space 220 without becoming blocked by the liquid 260 .
- ridges 270 may be formed on the separating member 225 , and gas venting holes 275 , 280 may be positioned on the ridges 270 , as shown.
- the gas venting holes 275 , 280 are positioned enough above the level of the liquid passage hole 265 so that at least one of the gas venting holes remains unblocked should the cup 205 be tipped to one side or the other or if the liquid 260 accumulates at the liquid passage hole 265 at a rate faster than the liquid 260 is able to pass through the hole 265 . If for example, the liquid 260 is introduced into the first interior space 220 using automated food packaging and processing equipment, the liquid 260 may be introduced very rapidly or at a rate that exceeds the flow rate through the liquid passage hole 265 .
- the ridges 270 permit at least one gas vent 275 , 280 to remain unblocked so that gas generated within the second interior space 230 is able to vent into the first interior space 220 .
- the gas vent 275 is positioned opposite the gas vent 280 so that if the cup 205 is tipped causing the liquid 260 to block the gas vent 275 (before the liquid 260 is able to pass downward though the liquid passage hole 265 ) then the oppositely positioned gas venting hole 280 will remain unblocked. Additional, perhaps smaller, venting holes may be used to improve efficiency.
- the liquid passage hole 265 is substantially centered, as shown in FIG. 2 , and positioned within a depression 285 protruding into the second interior space 230 .
- the depression 285 may help prevent the liquid passage hole 265 from becoming blocked by part of the quantity of product 215 and may include grooves or uneven surfaces (not shown) to further reduce the possibility of product 215 blocking the liquid passage hole 265 .
- the depression 285 may be positioned to be far enough above a raised bottom portion 290 of the bottom 240 of the cup 205 protruding upward toward the depression 285 so that gas generating tablets 250 , 255 do not become wedged between the lower surface of the depression 285 and the upper surface of the raised bottom portion 290 .
- the liquid passage hole 265 has a diameter large enough for the liquid 260 to pass substantially freely from said first interior space 220 into the second interior space 230 without becoming blocked due to adhesive forces between molecules of the liquid 260 and surfaces of the liquid passage hole 265 .
- the liquid passage hole 265 is sized with a diameter between two millimeters and six millimeters inclusively. It was found, in one embodiment, that a separating member 225 formed of PET material having at least one liquid passage hole with a diameter between two millimeters and six millimeters, inclusively, allows for liquid (such as water) to pass substantially freely through the separating member 225 .
- any liquid 260 will flow downward away from the liquid passage hole 265 and into the spaces formed by the ridges 270 , and because the gas venting holes 275 , 280 are sized with a diameter too small for the liquid 260 to pass, the liquid 260 is substantially trapped within the second interior space 230 .
- the gas venting holes 275 , 280 are each sized with a diameter between 0.25 millimeter and one millimeter inclusively.
- a separating member 225 formed of PET material having at least one gas venting hole with a diameter between 0.25 millimeter and one millimeter, inclusively allows for gaseaous carbon dioxide and oxygen to pass substantially freely through the separating member 225 while preventing the liquid 260 from passing through the separating member 225 . It was further found, in one embodiment, that having two such gas venting holes, each positioned apart from the other, provides sufficient gaseous permeability of the separating member 225 even in the event one of the two vents might become blocked.
- a quantity of product (such as fruits or vegetables) may be sealed within a package such as a sealable container comprising a cup 205 and a pull-tab type lid 210 as shown in FIG. 2 .
- mechanical mixing means may be used for initiating carbonation of the fruits or vegetables.
- the mechanical mixing means may involve rupturing membranes filled with the reactants needed for generating carbon dioxide and oxygen.
- the liquid 260 may be surrounded by a membrane and positioned within the second interior space 230 . A vigorous shake or tap of the package causes the membrane to rupture, thereby allowing the liquid 260 to mix with the gas generating substance.
- the liquid 260 may be initially contained within a membrane having a similar cross-section as the gas generating substance 250 shown in FIG. 2 . Therefore, in one embodiment, the liquid 260 may be contained in a liquid containing membrane 250 , which, when ruptured, allows the liquid 260 to fill the bottom 240 and mix with a gas generating substance 255 , thereby initiating the generation of carbon dioxide and oxygen gas and subsequent carbonation of the fruits or vegetables within the first interior space 220 .
- a convexity or button 295 may comprise a deformable structure capable of deflecting upward and into the second interior space 230 enough for causing a liquid containing membrane 250 (or a gas generating substance filled membrane) to rupture, thereby allowing the appropriate reactants to mix to initiate the generation of carbon dioxide and oxygen and subsequent carbonation of the fruits or vegetables within the package.
- the exterior convexity or button 295 comprises a deformable structure that may be deflected inward using a finger or thumb.
- the deformable structure deflects upward into the second interior space 230 but does not deflect back into its original position even as pressure builds within the first and second interior spaces.
- the deformable structure deflects upward into the second interior space 230 for initiating a modification of the atmosphere within the package and then relaxes back into its former position as pressure builds within the package.
- the separating member need not include a liquid passage hole 265 since the liquid 260 may be introduced into the bottom 240 of the cup 205 (or second interior space 230 ) before insertion of the separating member.
- the separating member for such systems may have at least one gas vent hole for allowing the generated gas to vent into the first interior space 220 .
- FIG. 3 is an exploded view of selected components of a dynamic modified atmosphere package system according to one embodiment.
- the structural components of a package suitable for dynamically modifying the atmosphere within the package include a pull-tab type lid 300 , an insert or separating member 305 , and a cup 310 .
- the pull-tab type lid 300 may comprise any of a wide variety of commercially produced pull-tab type tops that may be sealed to a cup such as the cup 310 shown.
- the pull-tab type lid 300 comprises a lid modified to retain a higher than typical internal pressure and to allow for a slowed release of internal pressure when the pull-tab 315 is pulled away from the lid 300 to open the top for access to the contents within the cup 310 .
- the lid 300 is made of aluminum.
- the lid 300 may be made of other materials such as plastics, laminate (or composite) materials, or any material or combination of materials that may be formed into a lid capable of retaining an internal pressure of at least thirty pounds per square inch.
- the lid 300 is capable of retaining an internal pressure of between thirty and fifty pounds per square inch internal gaseous pressure.
- the lid 300 includes modifications for slowing a release of pressure from within the sealed and pressurized package.
- the modifications for slowing the release of pressure may include a pressure release score line capable of puncturing a portion of the lid 300 when the pull-tab 315 is initially pulled in an outward direction away from the lid 300 and the interior space within the cup 310 .
- the pressure release score line may include a rivet score line 320 (running through or on both sides of a rivet 325 formed upon the lid 300 ) or a score line beneath pull-tab 315 (not shown) or a combination of score line features that provide a puncturing of the lid 300 to release pressure from within the sealed package prior to the pull-tab tip 330 puncturing an opening score line 335 for removal of the pull-tab 315 and lid material 340 circumscribed by the opening score line 335 about a periphery of the lid 300 .
- the lid 300 includes modifications for reducing sharpness of the edge exposed after removal of the pull-tab 315 and lid material 340 circumscribed by the opening score line 335 about a periphery of the lid 300 .
- the lid 300 may also incorporate “double protection” features so that both the inside edge at the opening score line 335 exposed after removal of the lid material 340 and the edge of the removed lid material 340 have reduced sharpness.
- the insert or separating member 305 for a package suitable for dynamically modifying the atmosphere within the package includes at least one liquid passage hole 345 configured so that a liquid is able to pass from a first interior space on one side 360 of the separating member 305 through the liquid passage hole 345 into a second interior space on the other side (opposite side 360 ) of the separating member 305 and at least one gas venting hole 350 configured so that a gas is able to vent from the second interior space into the first interior space, with the liquid that passed through the liquid passage hole 345 into the second interior space becoming substantially trapped within said second interior space.
- the separating member 305 may further include a ridge portion 355 having a gas venting hole 350 thereon so that a predetermined quantity of a liquid may be contained within the first interior space on one side 360 of the separating member 305 without blocking at least one gas venting hole thereby permitting gas to vent from the second interior space on the other side (opposite side 360 ) into the first interior space even if liquid accumulates within the first interior space at the liquid passage hole 345 at a liquid accumulation rate that exceeds a liquid passage rate through the liquid passage hole 345 .
- approximately eight milliliters of a liquid such as water may be contained within the first interior space on one side 360 of the separating member 305 without blocking at least one gas venting hole. That is, in one embodiment, for a package having a first interior space of approximately four ounces, the ridge portion 355 having a gas venting hole 350 thereon protrudes above the lower surfaces (and depression regions which funnel into the liquid passage hole 345 ) enough so that approximately eight milliliters of a liquid such as water may be contained without blocking the gas venting hole 350 .
- the liquid passage hole 345 has a diameter large enough for a liquid to pass substantially freely from the first interior space on one side 360 of the separating member 305 through the liquid passage hole 345 into the second interior space on the other side of the separating member 305 without becoming blocked due to adhesive forces (surface tension) between molecules of the liquid and surfaces of the liquid passage hole 345 .
- the liquid passage hole diameter may be between two milimeters and six milimeters inclusively, depending upon the type of material used and thickness of the separating member 305 proximate to the liquid passage hole 345 . It was found that a liquid passage hole diameter of about two millimeters provides sufficient liquid flow through the separating member 305 , according to one embodiment. If thinner material is used for the separating member 305 , for example, then a small diameter liquid passage hole 345 may be used.
- the gas venting hole 350 has a diameter large enough for gas to vent substantially freely through the gas venting hole 350 from the second interior space (opposite side 360 ) into the first interior space on side 360 and small enough to substantially block passage of a liquid through the gas venting hole 360 from the second interior space into the first interior space.
- the gas venting hole diameter may be between 0.25 millimeter and one millimeter inclusively. It was found that a gas venting hole diameter of about 0.25 millimeter provides sufficient gas flow through the separating member 305 , according to one embodiment.
- one gas venting hole 350 is positioned near a first edge area 365 of the separating member 305 and another gas venting hole 370 is positioned near a second edge area 375 of the separating member 305 , with the first edge area 365 and said second edge area 375 being substantially opposite from one another.
- the liquid passage hole 345 is substantially centrally positioned between the first edge area 365 and the second edge area 375 , with the first edge area 365 and the second edge area 375 being substantially opposite from one another.
- At least a portion of the separating member 305 in communication with the first interior space, for example, side 360 includes a formed depression 380 protruding into the second interior space (opposite side 360 ) and having the liquid passage hole 345 positioned therein.
- the formed depression region 380 may also include at least one groove 385 protruding into the second interior space (opposite side 360 ) and oriented to channel liquid to the liquid passage hole 345 .
- each groove 385 may be V-shaped or U-shaped to improve the channeling of liquid to the liquid passage hole 345 .
- the depression 380 with grooves 385 leading to the liquid passage hole 345 may be cooperatively sized and oriented so that the chosen quantity of product packaged within the first interior space is less likely to block the liquid passage hole 345 .
- the depression 380 and grooves 385 may be sized so as to reduce the likelihood that one of a quantity of grapes might block the liquid passage hole 345 .
- the depression 380 may be somewhat shorter than the longest dimension of a typical grape, and each of the V-shaped grooves 385 may be sized small enough so that the smallest radius on a typical grape is still larger than the radius needed to block one of the V-shaped gooves 385 .
- the grooves 385 may be formed with any shape, depth, length, and so forth.
- the gooves 385 are designed based at least partially upon the shape of the product to be enclosed within the package and a likelihood that some portion of the product may block the passage of liquid through the separating member or the venting of gas through the separating member.
- Additional depression areas and additional liquid passage holes may be incorporated into the separating member 305 .
- only a single liquid passage hole 345 is needed for sufficient liquid flow through the separating member 305 , and having only one such liquid passage hole 345 minimizes the likelihood that liquid may flow back from the second interior space into the first interior space and potentially tainting the product.
- the separating member 305 may comprise an insert that fits into a bottom portion of a cup 310 .
- the separating member 305 may be formed or molded of PET material with a material thickness similar to the material thickness of the cup 310 .
- the separating member may comprise a thinner (or thicker) material than the cup 310 .
- the material thickness of the separating member 305 or for that matter, the material thickness of the cup 310 , may vary throughout the component. For instance, the edge areas 365 , 375 may be formed to include somewhat thicker material so that the separating member 305 fits more tightly into the bottom of the cup 310 .
- the cup rim 390 may be formed to include somewhat thicker material than other areas of the cup 310 so that the rim 390 provides additional rigidity for improved sealing characteristics when the outward rim 395 of the pull-tab type lid 300 is sealably folded over the rim 390 of the cup 310 , according to one embodiment.
- the material thicknesses of the separating member 305 and the cup 310 are substantially similar with the cross-sectional material thicknesses for the separating member 225 and the cup 205 depicted in FIG. 2 .
- the material thicknesses of the separating member 305 and the cup 310 are substantially uniform throughout each of the respective components.
- the material thicknesses of the package components may vary throughout and incorporate molded features such as ribs to achieve desired rigidity and strength characteristics.
- FIG. 4 is a bottom view of a pull-tab type lid 400 according to one embodiment.
- the lid 400 incorporates modifications for slowing a release of pressure from within a pressurized package sealably closed with the lid 400 .
- the modifications for slowing the release of pressure may include a pressure release score line capable of puncturing a portion of the lid 400 when the pull-tab 405 (shown in dashed lines) is initially pulled in an outward direction away from the lid 400 .
- the pressure release score line may include a rivet score line 410 that runs through or on both sides of a rivet 415 formed upon the lid 400 or a neighboring score line 420 that runs near the rivet 415 or a combination of score line features that provide a puncturing of the lid 400 to release pressure from within the sealed package prior to the pull-tab tip 425 (positioned on the other side or top side of lid 400 ) puncturing an opening score line 430 for removal of the pull-tab 405 and lid material 435 circumscribed by the opening score line 430 about a periphery of the lid 400 just inside a rim 440 of the lid 400 .
- one or both of the rivet score line 410 and the neighboring score line 420 provide a first stage pressure release mechanism for the lid 400 .
- the lid 400 includes at least one score line feature, such as, for example, rivet score line 410 , for slowing a release of pressurized gas when the lid 400 is opened.
- the score line feature may comprise at least one pressure release score line designed to puncture through a portion of the lid 400 when the pull-tab 405 on the lid 400 is pulled in an outward direction away from the lid 400 .
- the score line feature may provide a two-stage opening mechanism for slowing the release of pressurized gas from the pressurized sealed package.
- the first stage opening mechanism may comprise a pressure release score line, such as one or both or the rivet score line 410 and the neighboring score line 420 , capable of puncturing a portion of the lid 400 when the pull-tab 405 is initially pulled in an outward direction away from the lid 400 .
- the second stage opening mechanism may comprise an opening score line 430 about a periphery of the lid 400 that breaks away for removal of the pull-tab 405 and lid material 435 circumscribed by the opening score line 430 .
- FIG. 5 is a cross-sectional view of the pull-tab type lid 300 at the cut line shown in FIG. 3 , according to one embodiment.
- the outward rim 395 of the pull-tab lid 300 is shown in an unfolded, unsealed position (to be consistent with FIG. 3 ).
- the cup rim 390 may fit within the area 505 under the outward rim 395 .
- the outward rim 395 may be sealed to the cup rim 390 using a can seaming (or sealing) machine, which folds the outward rim 395 and cup rim 390 down to create a sealed edge as shown in FIG. 2 .
- the rivet 325 is shown as a formed protrusion or bubble in the lid material 340 which is then headed down around the pull-tab 315 material, thereby fastening the pull-tab 315 to the lid material 340 .
- the pull-tab tip 330 is shown in an unopened, as sealed, position. In one embodiment, when the pull-tab end 510 is lifted outward, away from the lid material 340 , the rivet score line 320 (hidden) and neighboring score line 420 deflect and the pull-tab tip 330 plunges into a trough 515 having the opening score line 335 therein.
- the lid material 340 is punctured along one or both of the rivet and neighboring score lines, providing a slowed release of pressure, according to one embodiment.
- the pull-tab tip 330 punctures the opening score line 335 .
- the pull-tab 315 may be pulled away from the rest of the lid 300 for removing both the pull-tab 315 and the lid material 340 .
- the score lines may be made on one or both surfaces of the lid material 340 .
- the rivet score line 320 depicted in FIG. 3 may have a cross-section similar to the neighboring score line 420 shown in FIG. 5 , having both a top score 520 and a bottom score 525 , or the rivet score line 320 may have only one of a top score or a bottom score.
- the neighboring score line 420 may include only one of a top score 520 or a bottom score 525 .
- the opening score line 335 may likewise include both a top score 530 and a bottom score 535 , as shown, or just a top score 530 or just a bottom score 535 .
- the rivet score line 320 includes both top and bottom scores
- the neighboring score line 420 includes both top 520 and bottom 525 scores (as shown)
- the opening score line 335 includes only a top score 530 .
- the lid 300 includes a reduced profile 540 opening score line 410 about a periphery of the lid 300 that breaks away for removal of the pull-tab 315 and lid material 340 circumscribed by the opening score line 335 .
- the reduced profile 540 opening score line 335 reduces the sharpness of the edge along the opening score line 335 left after removal of the pull-tab 315 and lid material 340 .
- the reduced profile 540 in one embodiment, comprises a compressed S-shaped profile 545 as shown in FIG. 5 .
- Typical pull-tab type lids do not incorporate a similarly compressed S-shaped profile 545 , instead having a deeper or larger profile 540 between a portion of the lid material 340 having the opening score line 335 thereon and a point 550 where the lid bends upward toward the outward rim 395 .
- FIG. 6 is a cross-sectional view of a pull-tab type lid 600 , according to one embodiment.
- FIG. 6 is a cross-sectional view of a pull-tab type lid as in FIG. 5 but with a pull-tab type lid 600 that incorporates a “double protection” design for reducing sharpness of both the open container edge 605 along the opening score line 610 and the lid material edge 615 on the removed lid material 620 .
- the double protection design includes an open container edge S-shaped fold 625 , whereby the open container edge 605 comprises a fold of lid material covering the opening score line 610 that serves to reduce the effective sharpness of the inside edge of the opened container, and a removed lid material edge S-shaped fold 630 , whereby the outward lid material edge 615 comprises a fold of lid material covering the opening score line 610 that serves to reduce the effective sharpness of the outward edge of the removed lid material 620 .
- a double protection pull-tab type lid 600 is used to minimize open container edge sharpness, referred to as “can end safety” or cut protection. Other pull-tab type designs may be used.
Abstract
Description
- The present invention relates to a dynamic modified atmosphere package system. More particularly, the present invention relates to a dynamic modified atmosphere package system for providing a pressurized gaseous environment for a quantity of product.
- Modified atmosphere packaging generally refers to the practice of modifying the composition of the internal atmosphere or headspace of a package in order to improve the shelf-life of the product. The product is typically a food product but may also include pharmaceuticals or other types of products. The modification usually involves attempts to lower the amount of oxygen in order to slow down the growth of aerobic organisms and the speed of oxidation reactions. The removed oxygen is typically replaced with nitrogen, commonly known as an inert gas, or carbon dioxide, which can lower the pH or inhibit the growth of bacteria.
- In the context of food products, modified atmosphere packaging is generally considered a technique used for prolonging the shelf-life of fresh or minimally processed foods. In this preservation technique, the air surrounding the food in the package is changed to another composition using, for example, a gas-flush process. The initial fresh state of the food may be prolonged by slowing the natural deterioration of the food product. Respiring foods such as fruits and vegetables continue to take in oxygen and give off carbon dioxide as they continue to respire and ripen after harvest. Refrigeration and controlled atmosphere storage methods may be used to retard the ripening process. Reducing temperature slows the produce metabolism, including the rate of respiration. Under controlled atmosphere storage, respiration and ripening may be reduced further by lowering the oxygen content of the air, which normally consists of approximately 21% oxygen, 78% nitrogen, and 1% other elements.
- Low permeable/high barrier packaging films are typically used for non-respiring foods such as meat, fish, and cheese. By contrast, permeable or semi-permeable packaging films are typically used for respiring foods such as fruits and vegetables. Such packaging films are typically engineered with enough permeability to allow carbon dioxide concentrations to build within the package, thereby slowing the respiration rate of the produce, and oxygen levels to remain low (1%-5%) to prevent anaerobic fermentation. If the permeability of the film, for oxygen and carbon dioxide, is adapted to the particular respiration rate of the product, an equilibrium modified atmosphere may be established in the package. Such equilibrium modified atmosphere packaging may be used to increase the shelf-life of fresh-cut produce by reducing respiration and ethylene production rates, delaying senescence, and inhibiting the growth of spoilage organisms.
- However, these modified atmosphere packaging techniques necessarily rely on various permeable or semi-permeable films, or barrier films, and are incapable of retaining a positive pressure atmosphere within the package. Currently available modified atmosphere packaging techniques and packaging systems are not suitable for products requiring a positive pressure atmosphere within the package or for products that might benefit by having a positive pressure atmosphere within the package.
- One example of a package capable of retaining a positive pressure atmosphere within the package is a tennis ball can (or tennis ball tube). The air pressure inside a tennis ball is typically 12 psi (pounds per square inch) greater than the ambient air pressure at sea level. Over time, air escapes from the inside of the ball causing a decrease in the amount of air pushing on the inside of the ball and, consequently, decreasing the bounce characteristics of the ball. To prevent the ball from becoming “flat,” the ball is packaged in a positive pressure tube, with the tube pressurized to around 12 psi, which is enough to prevent air from escaping from the inside of the ball. Although a tennis ball can or similar package may be capable of retaining a positive pressure, such a package does not include capabilities for dynamically modifying the elements comprising the atmosphere within the package.
- A dynamic modified atmosphere package system that provides a pressurized gaseous environment would be useful, for example, for the carbonated fruits or vegetables products described in U.S. Pat. No. 5,968,573, U.S. patent application Ser. No. 10/857,043, U.S. Provisional Application Ser. No. 60/699,450, and U.S. patent application Ser. No. 10/304,197, all commonly owned or licensed by The Fizzy Fruit Company and herein incorporated by reference. The described carbonated fruits or vegetables products generally include fruits or vegetables that have absorbed enough carbon dioxide so that the fruits or vegetables have acquired an effervescent or “fizzy” quality. The absorbed carbon dioxide tends to remain absorbed within the tissue of the fruits or vegetables for a longer period of time when the carbonated fruits or vegetables are maintained in a pressurized carbon dioxide rich atmosphere.
- What is needed, therefore, is a dynamic modified atmosphere package system that addresses the above and other shortcomings. A dynamic modified atmosphere package system is needed that is capable of providing a pressurized gaseous modified atmosphere for a quantity of product such as, for example, fresh-cut fruits or vegetables.
- A dynamic modified atmosphere package system is described herein that overcomes the shortcomings of prior art modified atmosphere package systems by providing a dynamic modified atmosphere package comprising, in one embodiment, a sealable container having a first interior space for holding a quantity of product and a second interior space separated from the first interior space, the sealable container configured so that a liquid is able to pass from the first interior space into the second interior space, the liquid becoming substantially trapped within the second interior space, and the sealable container configured so that a gas is able to vent from the second interior space into the first interior space.
- In one embodiment, the package is capable of providing a pressurized gaseous modified atmosphere for a quantity of product such as, for example, fresh-cut fruits or vegetables. In one embodiment, the package is capable of providing a pressurized carbon dioxide rich atmosphere for carbonating or maintaining the carbonation of a quantity of fruits or vegetables.
- In one embodiment, an optimum amount of oxygen is provided to avoid harmful anaerobic conditions. In one embodiment, sodium bicarbonate and citric acid placed in the second interior space of the package is mixed with water to produce carbon dioxide, and sodium percarbonate placed in the second interior space is mixed with water to generate oxygen.
- In one embodiment, the package includes a pull-tab type lid with additional features to slow the release of pressure when the pull-tab lid is opened to access the first interior space and the quantity of product therein.
- In one embodiment, the package may comprise a clear plastic cup having a separating member that may be inserted into the cup after gas generating tablets have been placed in the bottom of the cup. In one embodiment, a quantity of product is placed within the interior space above the insert, water is added, and a metallic pull-tab lid is sealed over the opening of the cup. In one embodiment, a pressurized atmosphere rich in carbon dioxide is generated, and enough carbon dioxide is absorbed by the tissue of fruits or vegetables within the sealed package so that the fruits or vegetables acquire an effervescent or “fizzy” quality.
- In various embodiments, a quantity of fruits or vegetables is placed within the sealed package, the package is sealed, and, at a time thereafter, mechanical mixing means are used for initiating carbonation of the fruits or vegetables. The mechanical mixing means may involve rupturing membranes filled with the reactants for generating carbon dioxide and oxygen, thereby initiating the carbonation of the fruits or vegetables. The sealed package may include a separating member having at least one gas vent hole for allowing the generated carbon dioxide and oxygen to surround the fruits or vegetables, the separating member configured without a liquid passage hole and with the gas vent hole sized to prevent the passage of liquid through the separating member.
- The foregoing and other objectives, features, and advantages of the invention will be more readily understood upon consideration of the following detailed description of the invention taken in conjunction with the accompanying drawings.
- For a more complete understanding of the present invention, the drawings herein illustrate examples of the invention. The drawings, however, do not limit the scope of the invention. Similar references in the drawings indicate similar elements.
-
FIG. 1 is a perspective view of a dynamic modified atmosphere package system according to one embodiment. -
FIG. 2 is a cross-sectional view of a dynamic modified atmosphere package system according to one embodiment. -
FIG. 3 is an exploded view of selected components of a dynamic modified atmosphere package system according to one embodiment. -
FIG. 4 is a bottom view of a pull-tab type lid according to one embodiment. -
FIG. 5 is a cross-sectional view of a pull-tab type lid according to one embodiment. -
FIG. 6 is a cross-sectional view of a pull-tab type lid with double cut protection, according to one embodiment. - In the following detailed description, numerous specific details are set forth in order to provide a thorough understanding of the present invention. However, those skilled in the art will understand that the present invention may be practiced without these specific details, that the present invention is not limited to the depicted embodiments, and that the present invention may be practiced in a variety of alternative embodiments. In other instances, well known methods, procedures, components, and systems have not been described in detail.
- Various operations will be described as multiple discrete steps performed in turn in a manner that is helpful for understanding the present invention. However, the order of description should not be construed as to imply that these operations are necessarily performed in the order they are presented, nor even order dependent. Lastly, repeated usage of the phrase “in one embodiment” does not necessarily refer to the same embodiment, although it may.
- As an overview, the present inventors set out to develop the concept of packaging carbonated (or “fizzy”) fruits or vegetables (or other products) in a modified atmosphere of pressurized carbon dioxide. One embodiment of a suitable package incorporates an internal release of carbon dioxide from within the package by using a source of carbon dioxide that can produce a volume of carbon dioxide inside the package that, upon sealing the package, would pressurize the package with enough carbon dioxide for carbonating fruits or vegetables within the package to achieve a sufficient carbonation level within the tissue or fleshy parts of the fruits or vegetables. In one embodiment, it was found that a sealed package having therein between thirty and forty pounds per square inch of pressurized carbon dioxide is enough pressurized carbon dioxide to adequately carbonate a portion of fresh-cut grapes.
- The present inventors experimented with, in one embodiment, using a pellet of dry ice for generating pressurized carbon dioxide within a package. However, it was determined that while such a pellet does comprise a suitable gas generating substance, and is, therefore, to be included as an acceptable gas generating substance in at least one embodiment, the handling of dry ice is not easily accommodated in typical fruit (or food) processing environments. The present inventors subsequently found that a dry powder mixture of sodium bicarbonate and citric acid (or other appropriate carboxylic base and acid) which when activated by water or a water-based solution would generate the requisite volume of carbon dioxide to pressurize the package.
- It was further determined that sodium percarbonate or a food grade hydrogen peroxide or a combination of the two or another substance may be used to generate oxygen within the package so that the modified atmosphere includes enough oxygen to avoid the growth of anaerobic bacteria. As the fruits or vegetables continue to respire and ripen within the package, oxygen is consumed and carbon dioxide is produced. The present inventors found that, unlike any other modified atmosphere or pressurized package system or method, by generating within the sealed package pressurized carbon dioxide as well as enough oxygen to prevent anaerobic conditions, the atmosphere within the sealed package may be dynamically modified to achieve a desired gaseous composition, even as the fruits or vegetables (or other products) continue to ripen, respire, or otherwise affect the composition of the atmosphere within the sealed package. In one embodiment, a gas generating substance may be included so that the resulting modified atmosphere includes or maintains a level of approximately two to three percent oxygen.
- The present inventors further determined that other combinations of gas generating substances and suitably corresponding liquids (or “reactants”) may be used with a suitably designed package system for carbonating products (such as fruits or vegetables) within a package and for prolonging the shelf-life of such products. In one embodiment, sodium bicarbonate and citric acid may be activated with water to generate carbon dioxide in a separated space within the package, and the separated space may be configured to prevent unreacted reactants and residual solution formed in the reaction from coming into contact with and possibly tainting the flavor of fruits or vegetables in the package. It was found that such contact may cause an unpleasant or salty taste in, for example, a “fizzy” fruit product.
- Additional improvements are included, as will be discussed below for various embodiments, to provide suitable strength and commercially viable characteristics for a dynamic modified atmosphere package system. Such improvements include, but are not limited to, using transparent material for display of the product contained in the sealed container, fabricating the sealable container using semi-rigid material and with ribs and other features to improve pressure retention characteristics, sizing and positioning gas vent holes to allow gas flow and prevent liquid flow, sizing and positioning any liquid passage hole to allow for a desired gas generating reaction rate yet prevent liquid from fouling or tainting the product, including mechanical means for initiating carbonation of the product after sealing the package, designing a pull-tab type lid for the package that incorporates opening features for slowing the release of pressure when opening the pressurized package, and other aspects described or depicted in the drawings.
- Turning now to the drawings,
FIG. 1 is a perspective view of a dynamic modifiedatmosphere package system 100 according to one embodiment. The dynamic modifiedatmosphere package system 100, as shown, includes asealable container 105 capable of retaining a positive pressure, a quantity ofproduct 110 within a firstinterior space 115 within thesealable container 105, a separatingmember 120 within thesealable container 105 separating the firstinterior space 115 from a secondinterior space 125 within thesealable container 105, agas generating substance interior space 125 within thesealable container 105, and a predetermined quantity of a liquid 140 capable of reacting with thegas generating substance interior space 125 to generate a pressurized carbon dioxide rich atmosphere within the first and secondinterior spaces product 110. Also as shown, thesealable container 105 may include a pull-tab type lid 145 sealing an opening to the firstinterior space 115. - The
sealable container 105 may be made from any of a wide variety of materials and may be formed into any of a wide variety of shapes. For example, as shown inFIG. 1 , thesealable container 105 may be formed from a transparent material such as a transparent plastic and may be formed into the shape of acup 150. As will be appreciated, other shapes and materials may be used. For instance, thecup 150 may be substantially cubic with a square or rectangular base instead of the substantially cylindrical shape shown, and thecup 150 may be made of an opaque or colored material. - In one embodiment the
sealable container 105 is capable of retaining a positive internal pressure of at least thirty pounds per square inch (psi). Thesealable container 105 may be designed to retain an internal pressure of between thirty and forty pounds per square inch. To accommodate this positive pressure, a rigid or semi-rigid material may be used. For example, thesealable container 105 may comprise acup 150 made of polyethylene terephthalate (PET) or a similarly formable semi-rigid material and a metallic pull-tab type lid 145 sealed about the opening of thecup 150. The pull-tab type lid 145 may be an aluminum pull-tab type lid, or thelid 145 may be made of another material or combination of materials such as laminated or composite materials. In one embodiment, thesealable container 105 includes a pull-tab type lid 145 that may be opened to expose the quantity ofproduct 110 within the firstinterior space 115 of thesealable container 105 by pulling a pull-tab 155 outward, away from thelid 145 andcup 150, similar to fruit or pudding cups using similar pull-tab type lids. - In one embodiment, the pull-
tab type lid 145 opens to expose a four ounce or eight ounce volume within the firstinterior space 115, suitable for holding a quantity ofproduct 110. The product is typically a food product but may include pharmaceuticals or other types of products. The quantity ofproduct 110 may include, for example, a portion of fruits or vegetables, where reference to “a portion of fruits or vegetables” is used herein to refer to a portion of any one or any combination of the following: a single type of fruit, a mixture of different types of fruit, a single type of vegetable, a mixture of different types of vegetable, or a mixture of one or more types of fruit and one or more types of vegetable. For example, the fruits or vegetables may comprise fresh-cut whole grapes, de-stemmed grapes mixed with strawberries, a particular type of fruit mixed with a particular type of vegetable, or any other combination of fruits or vegetables. The fruits or vegetables may comprise fresh-cut or minimally processed fruits or vegetables but may also include fruits or vegetables that have been processed. The fruits or vegetables may comprise fruits or vegetables that have been carbonated before placement into the firstinterior space 115 of thesealable container 105. - In one embodiment, the separating
member 120 separates the firstinterior space 115 from the secondinterior space 125 and includes at least one gas venting hole configured so that gas generated by thegas generating substance interior space 125 into the firstinterior space 115. In one embodiment, the separatingmember 120 includes at least one liquid passage hole configured so that the liquid 140 is able to pass from the firstinterior space 115 into the secondinterior space 125, thereafter becoming substantially trapped within said secondinterior space 125. The separating member may be configured to substantially prevent the liquid 140 from passing from the secondinterior space 125 into the firstinterior space 115 even as thesealable container 105 is tipped on its side or inverted. - In one embodiment, the venting hole allows liquid to flow freely from the first
interior space 115 into the secondinterior space 125 by letting gas trapped in the secondinterior space 125 into the firstinterior space 115. Without the gas venting hole, according to one embodiment, the liquid may stop flowing into the secondinterior space 125. - The separating
member 120 may be integral to either the material comprising the firstinterior space 115 or the material comprising the secondinterior space 125 or both, or the separatingmember 120 may comprise an insert that fits into the bottom of thecup 150, thereby separating the first interior space 115 (as a larger upper space within the cup 150) and the second interior space 125 (as a smaller lower space at the bottom of the cup 150). - As will be discussed in more detail below, according to one embodiment, a liquid 140 such as water may be introduced into the first
interior space 115 before or after the quantity ofproduct 110 and before or after sealably closing thesealable container 105. When thesealable container 105 is maintained in a substantially upright orientation, as shown inFIG. 1 , the water initially collects at the surfaces of the separating member in communication with the first interior space. Then, after passing through a liquid passage hole in the separating member, the water collects in the bottom area of thesealable container 105. As the water collects in the bottom area, or secondinterior space 125, the water mixes withgas generating substance interior space 115 through at least one gas venting hole in the separatingmember 120 and also through the liquid passage hole as well, filling the first and second interior spaces with pressurized carbon dioxide. The pressurized carbon dioxide is then available for carbonation of fruits or vegetables within the firstinterior space 115. - In one embodiment, the quantity of
product 110 comprises a portion of fruits or vegetables with at least some of the fruits or vegetables capable of absorbing at least some of the carbon dioxide for acquiring an effervescent quality. As more carbon dioxide is absorbed into the tissue or fleshy part of the fruits or vegetables, the fruits or vegetables become more effervescent or “fizzy.” - The
gas generating substance sealable container 105 and just enough (perhaps between 1% to 5%) oxygen to avoid anaerobic conditions. In one embodiment, thegas generating substance interior space 125 for generation of carbon dioxide and oxygen when mixed with (or activated by) aliquid 140. The tablets may comprise active ingredients compressed to a density at least partially dependent upon a desired gas generation rate when the tablets are mixed with a predetermined amount of the liquid 140. For example, the active ingredients for generating oxygen may be compressed within the respective tablet to a greater density to control the reaction rate and generation of oxygen. Likewise, the active ingredients for generating carbon dioxide may be compressed within the respective tablet to adjust the generation rate of carbon dioxide. The desired gas generation rates for carbon dioxide and oxygen may, therefore, be adjusted based upon, in part, the particular respiration rates of the fruits or vegetables or various other parameters, such as, for example, the time between the insertion of the liquid 140 and sealing the pull-tab type lid 145 to thecup 150. - Next,
FIG. 2 is a cross-sectional view of a dynamic modifiedatmosphere package system 200 according to one embodiment. Thesystem 200 may comprise acup 205 and a pull-tab type lid 210, which together comprise a sealable container capable of retaining a positive pressure inside and holding a quantity ofproduct 215 within a firstinterior space 220. Other types of lids may be used for sealing the sealable container, and, as mentioned, the container need not take the shape of a cup. However, in one embodiment, a cup shape is useful for holding a quantity ofproduct 215, such as, for example, a portion of fruits or vegetables (depicted inFIG. 2 as de-stemmed grapes), within a firstinterior space 220. A separatingmember 225 may be inserted into the bottom portion of thecup 205 for separating the firstinterior space 220 from a secondinterior space 230. The separatingmember 225 provides space for reacting a carboxylic base with an acid to form carbon dioxide and other reactants to produce an amount of oxygen, both in gaseous form to dynamically modify the atmosphere within the container for carbonating a quantity ofproduct 215 and maintaining optimum oxygen levels at least partially in response to respiration or other changes in the quantity ofproduct 215 affecting the composition of the atmosphere within the sealable container, according to one embodiment. In other embodiments, the dynamic modifiedatmosphere package system 200 may be used to dynamically modify the atmosphere for products such as pharmaceuticals and use other reactants for producing different compositions of atmosphere within the sealable package and for dynamically modifying the composition of such atmosphere at least partially in response to changes in the pharmaceutical or other product within the firstinterior space 220. - In one embodiment, a pull-tab type lid 210 (similar, for example, to
lid 145 shown inFIG. 1 ) may be sealed upon suitably mating rim surfaces of thecup 205 using a can seaming machine. Such a machine may seal alid 210 over acup 205 by folding the lid material over the cup material. Commercially available can seaming (or can sealing) machines may be used. However, modifications may be needed so that the resulting sealed container is capable of retaining a positive pressure gaseous atmosphere. In one embodiment, the sealed container is capable of retaining at least thirty pounds per square inch of internal pressure. In one embodiment, thecup 205, thelid 210, and the seal between thelid 210 and thecup 205 are capable of retaining between thirty and fifty pounds per square inch of internal gaseous pressure. To accommodate such internal pressure, thecup 205 may incorporate structural features such as arib 235 about the circumference of thecup 205 near its rim surfaces. Therib 235 feature provides additional strength and rigidity. In addition, material thickness of thecup 205 may be increased to improve pressure retention capabilities. For example, in one embodiment thecup 205 comprises a PET plastic material with a thickness of approximately 0.6 millimeters. It was found that a material thickness of 0.3 millimeters may be too thin without additional structural changes, such as additional rib features. Thecup 205 shown inFIG. 2 includes substantially flat sides below therib 235 and extending away from thelid 210 toward thebottom 240 of thecup 205. Other shapes are possible, however, substantially flat sides allow for improved readability of shrink type labels or printing processes which may be used for product labeling. The sides ofcup 205 are shown tapering down from alarger diameter rib 235 area to smaller diameters toward the bottom 240. Other configurations are possible. For example, thecup 205 may include straight sides. However, a tapered shape allows for nesting multiple empty cups together for improved shipping densities and lowered overall material costs. - As shown in
FIG. 2 , alower portion 245 of thecup 205 may have a slightly smaller diameter so that the separatingmember 225 may be easily and freely inserted into thecup 205. In one embodiment, the smaller diameter of thelower portion 245 provides an interference fit between the inside surfaces of thelower portion 245 of the cup and the outward (or peripheral) surfaces of the separatingmember 225. The interference fit, in one embodiment, is tight enough that the separatingmember 225 remains positioned within thelower portion 245 of thecup 205 and separates the firstinterior space 220 from the secondinterior space 230. In one embodiment, the interference fit is tight enough to prevent liquid trapped within the secondinterior space 230 from passing into the firstinterior space 220 if, for example, thecup 205 is tipped from an upright orientation or inverted. In one embodiment, the inside surfaces of thelower portion 245 of the cup and the outward surfaces of the separatingmember 225 need not be straight (as shown) but may incorporate complementary or cooperatively mating ribs or bends so that the separatingmember 225 remains in its position in thelower portion 245 of the cup. - One method for dynamically modifying an atmosphere within a package, according to one embodiment, includes providing a sealable container, such as the
cup 205 andlid 210, that is capable of retaining a positive pressure and has a firstinterior space 220 and a secondinterior space 230. A gas generating substance, such astabets interior space 230 of the sealable container. A separatingmember 225 may be inserted into the sealable container to separate the firstinterior space 220 from the secondinterior space 230. A quantity ofproduct 215, such as grapes, for example, may be introduced into the firstinterior space 220. A predetermined quantity of a liquid 260 may be introduced into the firstinterior space 220 where the liquid 260 is capable of reacting with the gas generating substance to generate a pressurized carbon dioxide rich atmosphere within the firstinterior space 220. The liquid 260, in one embodiment, is also capable of reacting with the gas generating substance to generate enough oxygen to avoid anaerobic conditions associated with the quantity ofproduct 215. After the sealable container has been filled with the gas generating substance, insert or separatingmember 225, quantity ofproduct 215, and the predetermined quantity ofliquid 260, the opening to the firstinterior space 220 may be sealed using a pull-tab type lid 210 as shown inFIG. 2 . - The above method steps may be performed in the sequence described or in different orders. For example, the liquid 260 may be introduced into the first
interior space 220 before the quantity ofproduct 215 or even before the separatingmember 225 is placed into thelower portion 245 of thecup 205. Various other embodiments may require differently ordered steps. For example, if the separatingmember 225 is integrally formed with thecup 205 such that thelower portion 245 comprises a separately formed component, the gas generating substance may be placed within thelower portion 245 before thelower portion 245 is sealably attached to the rest of the cup 205 (perhaps using a thermal welding or other process). - In one embodiment, the liquid 260 passes downward within the first
interior space 220 and through aliquid passage hole 265 in the separatingmember 225, collecting as shown inFIG. 2 in thebottom 240 of thecup 205. The bottom 240 may comprise an annular trough within which the gas generating substance such astablets liquid 260 for sufficient reaction with the gas generating substance. - In one embodiment,
tablet 250 comprises sodium bicarbonate or a mixture of sodium bicarbonate and sodium percarbonate or some other carboxylic base, andtablet 255 comprises citric acid or some other appropriate acid for generating carbon dioxide and oxygen when mixed with water or an appropriate liquid solution. In one embodiment, only a single tablet is needed, such tablet comprising all substances needed for reacting with water or an appropriate liquid solution to produce a sufficient amount carbon dioxide for carbonation of fruits or vegetables within the firstinterior space 220 and enough oxygen to prevent anaerobic conditions. In one embodiment, the oxygen generating substance may comprise a separate tablet or an oxygen generating substance mixed into or incorporated into a tablet comprising sodium bicarbonate. For example,tablet 250 may comprise an oxygen generating substance such as sodium percarbonate,tablet 255 may comprise a carbon dioxide generating substance such as sodium bicarbonate, and a third tablet (not shown) may comprise citric acid. When such tablets are mixed with a predetermined amount of a liquid solution such as water, carbon dioxide and oxygen are generated. - In one embodiment, at least one ridge or upward protrusion is formed upon the separating
member 225. A gas venting hole positioned on such a ridge allows for gas generated within the secondinterior space 230 to vent into the firstinterior space 220 without becoming blocked by the liquid 260. For example, in one embodiment,ridges 270 may be formed on the separatingmember 225, andgas venting holes ridges 270, as shown. The gas venting holes 275, 280 are positioned enough above the level of theliquid passage hole 265 so that at least one of the gas venting holes remains unblocked should thecup 205 be tipped to one side or the other or if the liquid 260 accumulates at theliquid passage hole 265 at a rate faster than the liquid 260 is able to pass through thehole 265. If for example, the liquid 260 is introduced into the firstinterior space 220 using automated food packaging and processing equipment, the liquid 260 may be introduced very rapidly or at a rate that exceeds the flow rate through theliquid passage hole 265. In such situation theridges 270 permit at least onegas vent interior space 230 is able to vent into the firstinterior space 220. As shown, thegas vent 275 is positioned opposite thegas vent 280 so that if thecup 205 is tipped causing the liquid 260 to block the gas vent 275 (before the liquid 260 is able to pass downward though the liquid passage hole 265) then the oppositely positionedgas venting hole 280 will remain unblocked. Additional, perhaps smaller, venting holes may be used to improve efficiency. - In one embodiment, the
liquid passage hole 265 is substantially centered, as shown inFIG. 2 , and positioned within adepression 285 protruding into the secondinterior space 230. Thedepression 285 may help prevent theliquid passage hole 265 from becoming blocked by part of the quantity ofproduct 215 and may include grooves or uneven surfaces (not shown) to further reduce the possibility ofproduct 215 blocking theliquid passage hole 265. Thedepression 285 may be positioned to be far enough above a raised bottom portion 290 of the bottom 240 of thecup 205 protruding upward toward thedepression 285 so thatgas generating tablets depression 285 and the upper surface of the raised bottom portion 290. - In one embodiment, the
liquid passage hole 265 has a diameter large enough for the liquid 260 to pass substantially freely from said firstinterior space 220 into the secondinterior space 230 without becoming blocked due to adhesive forces between molecules of the liquid 260 and surfaces of theliquid passage hole 265. In one embodiment, theliquid passage hole 265 is sized with a diameter between two millimeters and six millimeters inclusively. It was found, in one embodiment, that a separatingmember 225 formed of PET material having at least one liquid passage hole with a diameter between two millimeters and six millimeters, inclusively, allows for liquid (such as water) to pass substantially freely through the separatingmember 225. - If the
cup 205 with separatingmember 225 fit into thelower portion 245 of thecup 205 is turned upside down, any liquid 260 will flow downward away from theliquid passage hole 265 and into the spaces formed by theridges 270, and because the gas venting holes 275, 280 are sized with a diameter too small for the liquid 260 to pass, the liquid 260 is substantially trapped within the secondinterior space 230. In one embodiment, the gas venting holes 275, 280 are each sized with a diameter between 0.25 millimeter and one millimeter inclusively. It was found, in one embodiment, that a separatingmember 225 formed of PET material having at least one gas venting hole with a diameter between 0.25 millimeter and one millimeter, inclusively, allows for gaseaous carbon dioxide and oxygen to pass substantially freely through the separatingmember 225 while preventing the liquid 260 from passing through the separatingmember 225. It was further found, in one embodiment, that having two such gas venting holes, each positioned apart from the other, provides sufficient gaseous permeability of the separatingmember 225 even in the event one of the two vents might become blocked. - In various embodiments, a quantity of product (such as fruits or vegetables) may be sealed within a package such as a sealable container comprising a
cup 205 and a pull-tab type lid 210 as shown inFIG. 2 . After the package is sealed, mechanical mixing means may be used for initiating carbonation of the fruits or vegetables. The mechanical mixing means may involve rupturing membranes filled with the reactants needed for generating carbon dioxide and oxygen. For example, the liquid 260 may be surrounded by a membrane and positioned within the secondinterior space 230. A vigorous shake or tap of the package causes the membrane to rupture, thereby allowing the liquid 260 to mix with the gas generating substance. For example, the liquid 260 may be initially contained within a membrane having a similar cross-section as thegas generating substance 250 shown inFIG. 2 . Therefore, in one embodiment, the liquid 260 may be contained in aliquid containing membrane 250, which, when ruptured, allows the liquid 260 to fill the bottom 240 and mix with agas generating substance 255, thereby initiating the generation of carbon dioxide and oxygen gas and subsequent carbonation of the fruits or vegetables within the firstinterior space 220. - In various embodiments, a convexity or
button 295 may comprise a deformable structure capable of deflecting upward and into the secondinterior space 230 enough for causing a liquid containing membrane 250 (or a gas generating substance filled membrane) to rupture, thereby allowing the appropriate reactants to mix to initiate the generation of carbon dioxide and oxygen and subsequent carbonation of the fruits or vegetables within the package. For example, the exterior convexity orbutton 295, according to one embodiment, comprises a deformable structure that may be deflected inward using a finger or thumb. In one embodiment, the deformable structure deflects upward into the secondinterior space 230 but does not deflect back into its original position even as pressure builds within the first and second interior spaces. In one embodiment, the deformable structure deflects upward into the secondinterior space 230 for initiating a modification of the atmosphere within the package and then relaxes back into its former position as pressure builds within the package. - For these embodiments involving mechanical mixing means to initiate atmosphere modification after the package has been sealed, the separating member need not include a
liquid passage hole 265 since the liquid 260 may be introduced into thebottom 240 of the cup 205 (or second interior space 230) before insertion of the separating member. The separating member for such systems may have at least one gas vent hole for allowing the generated gas to vent into the firstinterior space 220. - Moving on,
FIG. 3 is an exploded view of selected components of a dynamic modified atmosphere package system according to one embodiment. The structural components of a package suitable for dynamically modifying the atmosphere within the package, according to one embodiment, include a pull-tab type lid 300, an insert or separatingmember 305, and acup 310. The pull-tab type lid 300, as mentioned, may comprise any of a wide variety of commercially produced pull-tab type tops that may be sealed to a cup such as thecup 310 shown. However, in one embodiment, the pull-tab type lid 300 comprises a lid modified to retain a higher than typical internal pressure and to allow for a slowed release of internal pressure when the pull-tab 315 is pulled away from thelid 300 to open the top for access to the contents within thecup 310. In one embodiment, thelid 300 is made of aluminum. In other embodiments, thelid 300 may be made of other materials such as plastics, laminate (or composite) materials, or any material or combination of materials that may be formed into a lid capable of retaining an internal pressure of at least thirty pounds per square inch. In one embodiment, thelid 300 is capable of retaining an internal pressure of between thirty and fifty pounds per square inch internal gaseous pressure. - In one embodiment, the
lid 300 includes modifications for slowing a release of pressure from within the sealed and pressurized package. The modifications for slowing the release of pressure may include a pressure release score line capable of puncturing a portion of thelid 300 when the pull-tab 315 is initially pulled in an outward direction away from thelid 300 and the interior space within thecup 310. The pressure release score line may include a rivet score line 320 (running through or on both sides of arivet 325 formed upon the lid 300) or a score line beneath pull-tab 315 (not shown) or a combination of score line features that provide a puncturing of thelid 300 to release pressure from within the sealed package prior to the pull-tab tip 330 puncturing anopening score line 335 for removal of the pull-tab 315 andlid material 340 circumscribed by theopening score line 335 about a periphery of thelid 300. - In one embodiment, the
lid 300 includes modifications for reducing sharpness of the edge exposed after removal of the pull-tab 315 andlid material 340 circumscribed by theopening score line 335 about a periphery of thelid 300. Thelid 300 may also incorporate “double protection” features so that both the inside edge at theopening score line 335 exposed after removal of thelid material 340 and the edge of the removedlid material 340 have reduced sharpness. - As shown in
FIG. 3 , the insert or separatingmember 305 for a package suitable for dynamically modifying the atmosphere within the package, according to one embodiment, includes at least oneliquid passage hole 345 configured so that a liquid is able to pass from a first interior space on oneside 360 of the separatingmember 305 through theliquid passage hole 345 into a second interior space on the other side (opposite side 360) of the separatingmember 305 and at least onegas venting hole 350 configured so that a gas is able to vent from the second interior space into the first interior space, with the liquid that passed through theliquid passage hole 345 into the second interior space becoming substantially trapped within said second interior space. The separatingmember 305 may further include aridge portion 355 having agas venting hole 350 thereon so that a predetermined quantity of a liquid may be contained within the first interior space on oneside 360 of the separatingmember 305 without blocking at least one gas venting hole thereby permitting gas to vent from the second interior space on the other side (opposite side 360) into the first interior space even if liquid accumulates within the first interior space at theliquid passage hole 345 at a liquid accumulation rate that exceeds a liquid passage rate through theliquid passage hole 345. In one embodiment, for a package having a first interior space of approximately four ounces, approximately eight milliliters of a liquid such as water may be contained within the first interior space on oneside 360 of the separatingmember 305 without blocking at least one gas venting hole. That is, in one embodiment, for a package having a first interior space of approximately four ounces, theridge portion 355 having agas venting hole 350 thereon protrudes above the lower surfaces (and depression regions which funnel into the liquid passage hole 345) enough so that approximately eight milliliters of a liquid such as water may be contained without blocking thegas venting hole 350. - In one embodiment, the
liquid passage hole 345 has a diameter large enough for a liquid to pass substantially freely from the first interior space on oneside 360 of the separatingmember 305 through theliquid passage hole 345 into the second interior space on the other side of the separatingmember 305 without becoming blocked due to adhesive forces (surface tension) between molecules of the liquid and surfaces of theliquid passage hole 345. In one embodiment, the liquid passage hole diameter may be between two milimeters and six milimeters inclusively, depending upon the type of material used and thickness of the separatingmember 305 proximate to theliquid passage hole 345. It was found that a liquid passage hole diameter of about two millimeters provides sufficient liquid flow through the separatingmember 305, according to one embodiment. If thinner material is used for the separatingmember 305, for example, then a small diameterliquid passage hole 345 may be used. - In one embodiment, the
gas venting hole 350 has a diameter large enough for gas to vent substantially freely through thegas venting hole 350 from the second interior space (opposite side 360) into the first interior space onside 360 and small enough to substantially block passage of a liquid through thegas venting hole 360 from the second interior space into the first interior space. In one embodiment, the gas venting hole diameter may be between 0.25 millimeter and one millimeter inclusively. It was found that a gas venting hole diameter of about 0.25 millimeter provides sufficient gas flow through the separatingmember 305, according to one embodiment. - In one embodiment, one
gas venting hole 350 is positioned near afirst edge area 365 of the separatingmember 305 and anothergas venting hole 370 is positioned near asecond edge area 375 of the separatingmember 305, with thefirst edge area 365 and saidsecond edge area 375 being substantially opposite from one another. In one embodiment, theliquid passage hole 345 is substantially centrally positioned between thefirst edge area 365 and thesecond edge area 375, with thefirst edge area 365 and thesecond edge area 375 being substantially opposite from one another. In one embodiment, at least a portion of the separatingmember 305 in communication with the first interior space, for example,side 360, includes a formeddepression 380 protruding into the second interior space (opposite side 360) and having theliquid passage hole 345 positioned therein. The formeddepression region 380 may also include at least onegroove 385 protruding into the second interior space (opposite side 360) and oriented to channel liquid to theliquid passage hole 345. As shown, eachgroove 385 may be V-shaped or U-shaped to improve the channeling of liquid to theliquid passage hole 345. Thedepression 380 withgrooves 385 leading to theliquid passage hole 345 may be cooperatively sized and oriented so that the chosen quantity of product packaged within the first interior space is less likely to block theliquid passage hole 345. For example, thedepression 380 andgrooves 385 may be sized so as to reduce the likelihood that one of a quantity of grapes might block theliquid passage hole 345. Thedepression 380 may be somewhat shorter than the longest dimension of a typical grape, and each of the V-shapedgrooves 385 may be sized small enough so that the smallest radius on a typical grape is still larger than the radius needed to block one of the V-shapedgooves 385. Thegrooves 385 may be formed with any shape, depth, length, and so forth. In one embodiment, thegooves 385 are designed based at least partially upon the shape of the product to be enclosed within the package and a likelihood that some portion of the product may block the passage of liquid through the separating member or the venting of gas through the separating member. - Additional depression areas and additional liquid passage holes may be incorporated into the separating
member 305. However, in one embodiment, only a singleliquid passage hole 345 is needed for sufficient liquid flow through the separatingmember 305, and having only one suchliquid passage hole 345 minimizes the likelihood that liquid may flow back from the second interior space into the first interior space and potentially tainting the product. - The separating
member 305 may comprise an insert that fits into a bottom portion of acup 310. As shown inFIG. 3 , the separatingmember 305 may be formed or molded of PET material with a material thickness similar to the material thickness of thecup 310. The separating member may comprise a thinner (or thicker) material than thecup 310. The material thickness of the separatingmember 305, or for that matter, the material thickness of thecup 310, may vary throughout the component. For instance, theedge areas member 305 fits more tightly into the bottom of thecup 310. As another example, thecup rim 390 may be formed to include somewhat thicker material than other areas of thecup 310 so that therim 390 provides additional rigidity for improved sealing characteristics when theoutward rim 395 of the pull-tab type lid 300 is sealably folded over therim 390 of thecup 310, according to one embodiment. In one embodiment, the material thicknesses of the separatingmember 305 and thecup 310 are substantially similar with the cross-sectional material thicknesses for the separatingmember 225 and thecup 205 depicted inFIG. 2 . In one embodiment, the material thicknesses of the separatingmember 305 and thecup 310 are substantially uniform throughout each of the respective components. In one embodiment, the material thicknesses of the package components may vary throughout and incorporate molded features such as ribs to achieve desired rigidity and strength characteristics. -
FIG. 4 is a bottom view of a pull-tab type lid 400 according to one embodiment. In one embodiment, thelid 400 incorporates modifications for slowing a release of pressure from within a pressurized package sealably closed with thelid 400. The modifications for slowing the release of pressure may include a pressure release score line capable of puncturing a portion of thelid 400 when the pull-tab 405 (shown in dashed lines) is initially pulled in an outward direction away from thelid 400. The pressure release score line may include arivet score line 410 that runs through or on both sides of arivet 415 formed upon thelid 400 or a neighboringscore line 420 that runs near therivet 415 or a combination of score line features that provide a puncturing of thelid 400 to release pressure from within the sealed package prior to the pull-tab tip 425 (positioned on the other side or top side of lid 400) puncturing anopening score line 430 for removal of the pull-tab 405 andlid material 435 circumscribed by theopening score line 430 about a periphery of thelid 400 just inside arim 440 of thelid 400. In one embodiment, one or both of therivet score line 410 and the neighboringscore line 420 provide a first stage pressure release mechanism for thelid 400. That is, when the pull-tab 405 is pulled to open thelid 400, either or both of the score lines proximate to therivet 415 puncture through the lid material 435 (the place of puncture being along one or both of the score lines near the rivet 415) before the pull-tab tip 425 punctures through theopening score line 430. In one embodiment, thelid 400 includes at least one score line feature, such as, for example, rivetscore line 410, for slowing a release of pressurized gas when thelid 400 is opened. The score line feature may comprise at least one pressure release score line designed to puncture through a portion of thelid 400 when the pull-tab 405 on thelid 400 is pulled in an outward direction away from thelid 400. In one embodiment, the score line feature may provide a two-stage opening mechanism for slowing the release of pressurized gas from the pressurized sealed package. The first stage opening mechanism may comprise a pressure release score line, such as one or both or therivet score line 410 and the neighboringscore line 420, capable of puncturing a portion of thelid 400 when the pull-tab 405 is initially pulled in an outward direction away from thelid 400. The second stage opening mechanism may comprise anopening score line 430 about a periphery of thelid 400 that breaks away for removal of the pull-tab 405 andlid material 435 circumscribed by theopening score line 430. -
FIG. 5 is a cross-sectional view of the pull-tab type lid 300 at the cut line shown inFIG. 3 , according to one embodiment. Theoutward rim 395 of the pull-tab lid 300 is shown in an unfolded, unsealed position (to be consistent withFIG. 3 ). Thecup rim 390 may fit within thearea 505 under theoutward rim 395. In one embodiment, theoutward rim 395 may be sealed to thecup rim 390 using a can seaming (or sealing) machine, which folds theoutward rim 395 andcup rim 390 down to create a sealed edge as shown inFIG. 2 . Therivet 325 is shown as a formed protrusion or bubble in thelid material 340 which is then headed down around the pull-tab 315 material, thereby fastening the pull-tab 315 to thelid material 340. The pull-tab tip 330 is shown in an unopened, as sealed, position. In one embodiment, when the pull-tab end 510 is lifted outward, away from thelid material 340, the rivet score line 320 (hidden) and neighboringscore line 420 deflect and the pull-tab tip 330 plunges into atrough 515 having theopening score line 335 therein. As the pull-tab end 510 is moved outward, away from thelid material 340, thelid material 340 is punctured along one or both of the rivet and neighboring score lines, providing a slowed release of pressure, according to one embodiment. As the pull-tab end 510 continues to move outward, the pull-tab tip 330 punctures theopening score line 335. Finally, the pull-tab 315 may be pulled away from the rest of thelid 300 for removing both the pull-tab 315 and thelid material 340. - The score lines may be made on one or both surfaces of the
lid material 340. For example, therivet score line 320 depicted inFIG. 3 may have a cross-section similar to the neighboringscore line 420 shown inFIG. 5 , having both atop score 520 and abottom score 525, or therivet score line 320 may have only one of a top score or a bottom score. Likewise, the neighboringscore line 420 may include only one of atop score 520 or abottom score 525. Theopening score line 335 may likewise include both atop score 530 and abottom score 535, as shown, or just atop score 530 or just abottom score 535. In one embodiment, therivet score line 320 includes both top and bottom scores, the neighboringscore line 420 includes both top 520 and bottom 525 scores (as shown), and theopening score line 335 includes only atop score 530. - In one embodiment, the
lid 300 includes a reducedprofile 540opening score line 410 about a periphery of thelid 300 that breaks away for removal of the pull-tab 315 andlid material 340 circumscribed by theopening score line 335. The reducedprofile 540opening score line 335, in one embodiment, reduces the sharpness of the edge along theopening score line 335 left after removal of the pull-tab 315 andlid material 340. The reducedprofile 540, in one embodiment, comprises a compressed S-shapedprofile 545 as shown inFIG. 5 . Typical pull-tab type lids do not incorporate a similarly compressed S-shapedprofile 545, instead having a deeper orlarger profile 540 between a portion of thelid material 340 having theopening score line 335 thereon and apoint 550 where the lid bends upward toward theoutward rim 395. -
FIG. 6 is a cross-sectional view of a pull-tab type lid 600, according to one embodiment.FIG. 6 is a cross-sectional view of a pull-tab type lid as inFIG. 5 but with a pull-tab type lid 600 that incorporates a “double protection” design for reducing sharpness of both theopen container edge 605 along theopening score line 610 and thelid material edge 615 on the removedlid material 620. As shown, the double protection design includes an open container edge S-shapedfold 625, whereby theopen container edge 605 comprises a fold of lid material covering theopening score line 610 that serves to reduce the effective sharpness of the inside edge of the opened container, and a removed lid material edge S-shapedfold 630, whereby the outwardlid material edge 615 comprises a fold of lid material covering theopening score line 610 that serves to reduce the effective sharpness of the outward edge of the removedlid material 620. In one embodiment, a double protection pull-tab type lid 600 is used to minimize open container edge sharpness, referred to as “can end safety” or cut protection. Other pull-tab type designs may be used. - The terms and expressions which have been employed in the foregoing specification are used therein as terms of description and not of limitation, and there is no intention in the use of such terms and expressions of excluding equivalents of the features shown and described or portions thereof, it being recognized that the scope of the invention is defined and limited only by the claims which follow.
Claims (78)
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US11/453,712 US20070292568A1 (en) | 2006-06-14 | 2006-06-14 | Dynamic modified atmosphere package system |
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US11/453,712 US20070292568A1 (en) | 2006-06-14 | 2006-06-14 | Dynamic modified atmosphere package system |
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US20210031973A1 (en) * | 2019-07-29 | 2021-02-04 | Ball Corporation | Domed container with nitrogen well and closure mechanism |
CN114229207A (en) * | 2021-11-23 | 2022-03-25 | 安庆大群包装有限公司 | Corrugated carton that waterproof nature is strong |
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US20100255162A1 (en) * | 2009-04-06 | 2010-10-07 | Cryovac, Inc. | Packaging with on-demand oxygen generation |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: FIZZY FRUIT COMPANY, THE, OREGON Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:LING, QINGYUE;KAUFMAN, GALEN;LINDEMANN, ADAM;REEL/FRAME:017977/0613;SIGNING DATES FROM 20060602 TO 20060612 |
|
AS | Assignment |
Owner name: THE FIZZY FRUIT COMPANY, OREGON Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:KAUFMAN, GALEN;LINDEMANN, ADAM;REEL/FRAME:019602/0960;SIGNING DATES FROM 20060602 TO 20060612 Owner name: OREGON STATE UNIVERSITY, OREGON Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:LING, QINGYUE;REEL/FRAME:019602/0873 Effective date: 20060626 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |