US20080277092A1 - Water cooling system and heat transfer system - Google Patents

Water cooling system and heat transfer system Download PDF

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Publication number
US20080277092A1
US20080277092A1 US12/151,767 US15176708A US2008277092A1 US 20080277092 A1 US20080277092 A1 US 20080277092A1 US 15176708 A US15176708 A US 15176708A US 2008277092 A1 US2008277092 A1 US 2008277092A1
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United States
Prior art keywords
fluid
conduit
gas transport
conductive tube
outer conduit
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
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US12/151,767
Inventor
Frederick P. Layman
Maximilian A. Biberger
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SDC Materials Inc
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SDC Materials Inc
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Publication date
Priority claimed from US11/110,341 external-priority patent/US20050233380A1/en
Application filed by SDC Materials Inc filed Critical SDC Materials Inc
Priority to US12/151,767 priority Critical patent/US20080277092A1/en
Assigned to SDC MATERIALS, INC. reassignment SDC MATERIALS, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BIBERGER, MAXIMILLIAN A., LAYMAN, FREDERICK P.
Publication of US20080277092A1 publication Critical patent/US20080277092A1/en
Abandoned legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D15/00Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28CHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
    • F28C3/00Other direct-contact heat-exchange apparatus
    • F28C3/10Other direct-contact heat-exchange apparatus one heat-exchange medium at least being a fluent solid, e.g. a particulate material
    • F28C3/12Other direct-contact heat-exchange apparatus one heat-exchange medium at least being a fluent solid, e.g. a particulate material the heat-exchange medium being a particulate material and a gas, vapour, or liquid
    • F28C3/16Other direct-contact heat-exchange apparatus one heat-exchange medium at least being a fluent solid, e.g. a particulate material the heat-exchange medium being a particulate material and a gas, vapour, or liquid the particulate material forming a bed, e.g. fluidised, on vibratory sieves
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/18Liquid substances or solutions comprising solids or dissolved gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • B01J19/0013Controlling the temperature of the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/087Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J19/088Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2/00Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
    • B01J2/16Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by suspending the powder material in a gas, e.g. in fluidised beds or as a falling curtain
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00Catalysts of the Raney type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00Catalysts of the Raney type
    • B01J25/02Raney nickel
    • B01J35/56
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06Washing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/349Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of flames, plasmas or lasers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/12Making metallic powder or suspensions thereof using physical processes starting from gaseous material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F27/00Control arrangements or safety devices specially adapted for heat-exchange or heat-transfer apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0803Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J2219/0805Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873Materials to be treated
    • B01J2219/0879Solid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0894Processes carried out in the presence of a plasma
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2203/00Controlling
    • B22F2203/13Controlling pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00Aspects linked to processes or compositions used in powder metallurgy
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/02Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being helically coiled
    • F28D7/024Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being helically coiled the conduits of only one medium being helically coiled tubes, the coils having a cylindrical configuration
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/08Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being otherwise bent, e.g. in a serpentine or zig-zag
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S623/00Prosthesis, i.e. artificial body members, parts thereof, or aids and accessories therefor
    • Y10S623/92Method or apparatus for preparing or treating prosthetic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S623/00Prosthesis, i.e. artificial body members, parts thereof, or aids and accessories therefor
    • Y10S623/92Method or apparatus for preparing or treating prosthetic
    • Y10S623/923Bone
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/0318Processes
    • Y10T137/0391Affecting flow by the addition of material or energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/206Flow affected by fluid contact, energy field or coanda effect [e.g., pure fluid device or system]
    • Y10T137/2076Utilizing diverse fluids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/15Combined or convertible surface bonding means and/or assembly means

Definitions

  • the present invention relates generally to methods of and systems for cooling gas transport conduits configured to conduct hot gasses or gaseous mixtures.
  • gas transport systems adapted to conduct gas-particle product from gas phase particle production reactors must be designed to efficiently absorb and dissipate high heat loads. Because heat transfer between two systems occurs in proportion to the temperature differential between the two systems, efficient absorption of heat from the gas-particle product depends on maintaining the gas transport system at a significantly lower temperature than the gas-particle product, while efficient dissipation of heat from the gas transport system depends on maintaining an environment of still lower temperature in contact with the gas transport system. The independent requirements of absorption and dissipation are at odds. Gas transport systems are typically incapable of absorbing large quantities of heat without increasing their temperature. In most cases, the two requirements are balanced by actively cooling the gas transport system, which provides a controlled, low temperature environment into which the gas transport system can dissipate heat.
  • Forced-gas cooling systems typically include one or more fans, configured to force gas through one or more heat exchange structures thermally coupled with the gas transport system. Heat moves from the gas-particle product into the gas transport system and then into the heat exchange structures.
  • the heat exchange structures include heat rejecters or heat sinks configured to present a large surface area interface to the gas within a heat exchange region. As gas moves through the heat exchange region and across the large surface area of the heat rejecter or heat sink, it convectively cools the heat rejecter or heat sink.
  • such systems are simple and relatively inexpensive to operate, they are less efficient than liquid cooling systems because the heat capacity of gas is generally less than that of liquid, gas cools through mostly convective means and gas cannot be cooled as readily as can liquid.
  • forced-gas cooling systems are ill suited to cool high heat load gas-particle mixtures.
  • Liquid cooling systems typically include liquid circulation system configured to deliver fluid through one or more heat exchange structures thermally coupled with the gas transport system.
  • the heat exchange structures are typically configured to present a large surface area for interaction with the liquid within a heat exchange region. Heat is absorbed into the gas-transport system and conducted into the heat exchange structures. As liquid moves across the heat exchange surface, heat dissipates from the heat exchange structures through conductive and convective means into the liquid and heated liquid flows away from the heat exchange region. Typically, heat is removed from the heated liquid via some further cooling or refrigeration mechanism.
  • a cooling system for a conduit is presented.
  • a cooling system according to the present invention is used to cool a conduit that transports gas mixtures.
  • the cooling system is primarily intended to dissipate heat absorbed by the conduit from the gas particle product it transports.
  • hot gas-particle product is emitted from gas phase particle production reactors, such as flame reactors, plasma reactors, hot wall reactors and laser reactors.
  • the conduit conducts and conditions the gas-vapor mixtures ejected from the reactor, absorbing heat from the mixtures through multiple means.
  • the cooling system functions to dissipate heat absorbed within the conduit and prevent overheating of the conduit.
  • the present invention describes a cooling system for cooling selected portions of a gas transport conduit within a conduit system.
  • the cooling system comprises at least one cooling element configured to cool a portion of the gas transport conduit, comprising a section of outer conduit having a first end and a second end.
  • the cooling element is preferably fitted around the portion of the gas transport conduit to form a toroidal channel between the inner surface of the outer conduit and the outer surface of the gas transport conduit.
  • the toroidal channel formed between the outer conduit and the gas transport conduit has a first opening at the first end of the conduit and a second opening at the second end of the conduit.
  • a highly heat conductive tube structure is placed within the outer conduit to form the toroidal channel.
  • the highly heat conductive tube structure preferably does not seal the channel to fluid flow at any point therein, so that fluid may move freely within the toroidal channel with the highly heat conductive tube structure in place.
  • the cooling system incorporates partitions within the toroidal channel, which seal the toroidal channel to fluid flow except through the highly heat conductive tube structure.
  • the toroidal channel is divided into several chambers, each of which can have a different fluid therein, with the highly conductive tube structure passing through each of the several chambers.
  • a first cap coupled with the first opening and a second cap coupled with the second opening of the toroidal channel provide a seal between the gas transport conduit and the conduit.
  • the toroidal channel is filled with a static fluid, preferably a liquid, surrounding and thermally contacting the highly heat conductive tube structure.
  • At least one of the caps is configured with a port to allow fluid delivery therethrough into the highly heat conductive tube structure.
  • a fluid reservoir system is coupled with the one or more ports and thereby with the highly heat conductive tube structure.
  • each embodiment of the present invention includes two fluid systems, separated from one another: a circulating system (referred to as “fluid” or “circulating fluid”) and a static system (referred to as “static fluid).
  • a circulating system referred to as “fluid” or “circulating fluid”
  • static fluid referred to as “static fluid”.
  • the fluids chosen for use within each system have preferred characteristics, which differ depending on the specifics of each embodiment.
  • conduit system As the conduit system conducts hot gas, it absorbs heat from the gas. Because the gas cools as it travels through the conduit system, some portions of the conduit system absorb more heat than others.
  • An exemplary portion of a gas transport conduit within the conduit system is equipped with a cooling system as described in the preceding paragraph.
  • the cooling system of the present invention operates by removing heat from the gas transport conduit via fluid flow. As heat is absorbed into the gas transport conduit from the gas within the conduit, the cooling system works to remove heat from the conduit through the external surfaces of the conduit. Heat moves from the conduit system into the static fluid, heating the static fluid. The static fluid, being in thermal contact with the highly heat conductive tube structure, conducts heat into the highly heat conductive tube structure. Fluid flows from the fluid reservoir system into the highly heat conductive tube structure, absorbing heat from the conduit system through the highly heat conductive tube structure and the static fluid. The fluid flows from the highly heat conductive tube structure back into the fluid reservoir system, or into a different fluid reservoir. As one skilled in the art will recognize, in a closed loop system (where the fluid returns to the same reservoir system), in order to maintain cooling efficiency, the fluid is preferably cooled via external means, such as refrigeration, before being resupplied to the highly heat conductive tube structure
  • each cooling cell within cooling system includes several components: a heat exchange region, and a fluid flow control and supply system. Functioning together, these components allow a cell to provide effective cooling to a specific region of a conduit system.
  • a cooling system having a plurality of such cells working in concert provides selective, extensible and configurable cooling to a conduit system.
  • the present invention includes a desired structure and function for each component of a cell within the system.
  • the highly heat conductive tube structure sits within the toroidal channel defined between the gas transport conduit and the outer conduit and filled with the static fluid.
  • the highly heat conductive structure is wound in a spiral in the toroidal chamber along the conduit.
  • the region of interface between the conduit and the static fluid within the toroidal channel forms a first heat exchange region: heat flows from the gas transport conduit into the static fluid.
  • the surface of the interface between the static fluid and the highly heat conductive tube structure within the toroidal channel forms a second heat exchange region: heat is conducted from the static fluid into the highly heat conductive tube structure.
  • the inner surface of the highly heat conductive tube structure forms a third heat exchange region: heat flows from the highly heat conductive tube structure into the circulating fluid.
  • the highly heat conductive tube structure is preferably formed from bent highly heat conductive material.
  • Preferred materials include metals, such as copper, and highly heat conductive thermoplastics.
  • the highly heat conductive tube structure permits fluid flow there-through.
  • the present invention contemplates a variety of structures to permit fluid flow.
  • the highly heat conductive tube structure comprises porous structures and/or channel structures defining fluid flow paths.
  • the structures present a high surface area for heat exchange, relative to the volume of the highly heat conductive tube structure.
  • the highly heat conductive tube structure is spirally wound to form a toroidal shape encircling the gas transport conduit within the toroidal channel, much like the shape of a coiled spring.
  • the present invention contemplates a variety of configurations of the highly heat conductive tube structure within the toroidal channel, including coiled, folded and layered configurations.
  • the highly heat conductive tube structure can be formed independently from the conduit, or formed around the conduit. Regardless of the method of formation, the highly heat conductive tube structure is configured to fit within the toroidal channel.
  • copper tubing coiled around the gas transport conduit forms the highly heat conductive tube structure.
  • the copper tubing is preferably coiled coarsely, and may but need not physically contact the gas transport conduit.
  • Placement of the outer conduit to surround the highly heat conductive tube structure forms a toroidal channel containing the highly heat conductive tube structure.
  • the toroidal channel is sealed and filled with a static fluid.
  • the filling may be accomplished following the sealing of one end of the outer conduit and prior to the sealing of the other end. Alternatively, the filling may be accomplished through a valve system positioned in either or both ends of the heat exchanger.
  • the fluid flow control system has several functions.
  • the rate of heat dissipation within a fluid cooling system depends on many factors, several of which relate to the rate and type of fluid flow within the system.
  • An effective fluid flow control system includes means to channel the fluid to the desired portions of the heat exchange region. Also, because fluids expand under heating, and because heat dissipation within a fluid cooling system depends on heating of the fluid, the fluid control system must account for pressure changes within the fluid.
  • the toroidal chamber formed within the outer conduit and the two seals preferably includes a valve system configured to account for pressure changes within the fluid.
  • the present invention presents a fluid control system comprising several parts.
  • the outer conduit provides a confining structure, which forms the toroidal chamber in which static fluid is positioned.
  • the conduit determines the total fluid volume within the toroidal chamber, exclusive of the fluid path within the highly heat conductive tube structure.
  • each of the caps sealing the ends of the outer conduit are preferably equipped with a plurality of ports. These ports determine the pattern in which fluid flows into the highly heat conductive tube structure and thus help determine, in concert with the flow structures within the highly heat conductive tube structure, the flow patterns through the highly heat conductive tube structure.
  • the cap structures preferably include one or more pressure relief valves, configured to release fluid from the system should a sudden rise in pressure occur.
  • the fluid control system can include a pump configured to deliver fluid through the plurality of ports on one of the sealing caps.
  • the outer conduit is preferably configured along with the highly heat conductive tube structure to define a predetermined fluid volume within the toroidal region.
  • the specific volume and flow rate of an embodiment depend on the heat loads for which that embodiment is designed. Roughly, higher volumes and flow rates will be required to handle higher heat loads. Conductivity and surface area are also considerations in determining required fluid volume.
  • the outer conduit is formed from a durable, heat resistant material.
  • the material forming the outer conduit need not be thermally conductive.
  • at least the outer surface preferably comprises an insulating material. This configuration separates the heat dissipation and structural functions of the cooling system.
  • the outer surface can be heat conductive to promote additional heat loss through radiation.
  • the caps couple with and seal the ends of the outer conduit.
  • the caps can be bonded, threaded, and/or bolted on to the outer conduit.
  • the present invention contemplates any coupling that creates a seal between the cap and the outer conduit.
  • the caps comprise material similar to that in the outer conduit.
  • the seal between the conduit system and the caps can be formed in a variety of ways: the caps can be bonded, pressure fitted, or held in place by o-ring type seals. The preferred method of sealing the caps provides for expansion and contraction of the caps as the heat exchanger is heated and cooled.
  • the caps each preferably include a plurality of ports.
  • one of the ports provides a pressure relief system for the fluid system, preferably at each end of the outer conduit.
  • the other ports provide fluid delivery into the highly heat conductive tube structure in a specified configuration.
  • the configuration of the ports and the configuration of the fluid channels within the highly heat conductive tube structure complement one another to form desired flow paths through the system.
  • the configuration of the paths and the rate of fluid delivery thereto partially determine the rate of heat dissipation from the gas transport conduit to the fluid.
  • the fluid control system can further include a fluid pump and fluid supply system, which can reasonably be integrated into a single device, but can also be provided modularly.
  • the fluid pump determines the rate of fluid delivery to the plurality of ports and thus the rate of fluid flow through the highly heat conductive tube structure. Higher fluid flow rates allow the system to dissipate greater amounts of heat. Accordingly the fluid flow rates are preferably varied as heat dissipation requirements vary.
  • the cooling system of the present invention can vary its fluid flow rates to accommodate varying requirements for heat dissipation.
  • a control system controls the pump and fluid supply system according to the observed temperature difference between fluid flowing into the heat exchange region and fluid flowing from the heat exchange region. If the temperature difference is beyond desired limits, the rate of flow is increased, so long as the maximum flow rate has not been exceeded.
  • the fluid supply system preferably provides cool fluid to the fluid pump.
  • This fluid can be fresh, i.e., fluid which has not been used in the system before, or this fluid can be recirculated. If recirculated fluid is used, the fluid supply system preferably cools the recirculated fluid before resupplying it to the pump.
  • the fluid supply system can incorporate a pressure relief valve.
  • Several types of fluids are contemplated by the present invention. Preferred fluids have high thermal conductivity.
  • the preferred characteristics of the fluid and the static fluid can vary. Specifically preferred characteristics can differ both between the fluid and the static fluid within a given embodiment and within a given fluid between multiple embodiments. Important characteristics of the fluid include density, heat capacity, viscosity, and conductivity.
  • a static fluid and a circulating fluid both having a low thermal mass are chosen to allow rapid changes in the temperature of the heat exchanger.
  • circulating fluid and static fluid having high heat capacities are chosen to allow removal of large quantities of heat.
  • a gas phase particle production system As a gas phase particle production system operates, hot gas product emitted from a reactor flows through a gas transport conduit within a conduit system. As the gas flows through the conduit it cools, dissipating heat into the gas transport conduit. Because heat dissipation is proportional to temperature differential, presuming a uniform rate of conduit heating, less heat is dissipated into the gas transport conduit as the gas becomes cooler, i.e., portions of the conduit further from the point at which hot gas is introduced into the conduit absorb less heat from the gas. Because of these differences, a cooling system according to the present invention preferably incorporates a variety of subsystems. The operation of one such subsystem is discussed below.
  • a highly heat conductive tube structure is coupled with the conduit and placed within a toroidal structure formed between the gas transport conduit and an outer conduit.
  • the gas transport conduit and the highly heat conductive tube structure are in thermal contact through a static fluid within the toroidal chamber, which allows heat to dissipate from the gas transport conduit into the highly heat conductive tube structure.
  • fluid flows through the highly heat conductive tube structure, which is in contact with the static fluid.
  • heat is dissipated from the highly heat conductive tube structure into the fluid, thereby heating the fluid.
  • heat dissipated from the gas transport conduit is physically removed via dissipation into a flowing fluid.
  • a heat exchanger comprises a gas transport conduit that provides a channel through which a fluid mixture can flow.
  • An outer conduit is disposed around the gas transport conduit.
  • the outer conduit has a first end, a second end opposite the first end, a first cap covering the first end, and a second cap covering the second end.
  • the gas transport conduit passes through the first cap, into the outer conduit, and through the second cap.
  • a conductive tube passes through the outer conduit, thereby providing a channel through which a circulating fluid can flow into and out of the outer conduit.
  • a static fluid chamber is formed between the conductive tube and the gas transport conduit.
  • the static fluid chamber is configured to house a static fluid.
  • the gas transport conduit is configured to conduct heat from the fluid mixture in the gas transport conduit to the static fluid in the static fluid chamber and the conductive tube is configured to conduct heat from the static fluid in the static fluid chamber to the circulating fluid flowing through the conductive tube.
  • a cooling system comprising a fluid supply system having an inlet and an outlet.
  • the fluid supply system is configured to receive a heated circulating fluid through the inlet, cool the heated circulating fluid, and supply the cooled circulating fluid through the outlet.
  • the cooling system also comprises a gas transport conduit that provides a channel through which a fluid mixture can flow and an outer conduit disposed around the gas transport conduit.
  • the outer conduit has a first end, a second end opposite the first end, a first cap covering the first end, and a second cap covering the second end. The gas transport conduit passes through the first cap, into the outer conduit, and through the second cap.
  • a conductive tube has a tube inlet fluidly coupled to the outlet of the fluid supply system and a tube outlet fluidly coupled to the inlet of the fluid supply system.
  • the conductive tube passes through the outer conduit, thereby providing a channel through which the circulating fluid can flow from the fluid supply system into the outer conduit via the tube inlet and out of the outer conduit to the fluid supply system via the tube outlet.
  • a static fluid chamber is formed between the conductive tube and the gas transport conduit.
  • the static fluid chamber is configured to house a static fluid.
  • the gas transport conduit is configured to conduct heat from the fluid mixture in the gas transport conduit to the static fluid in the static fluid chamber and the conductive tube is configured to conduct heat from the static fluid in the static fluid chamber to the circulating fluid flowing through the conductive tube.
  • a method of cooling a fluid mixture comprises providing an outer conduit and a conductive tube.
  • the outer conduit is disposed around a gas transport conduit and has a first end, a second end opposite the first end, a first cap covering the first end, and a second cap covering the second end.
  • the gas transport conduit passes through the first cap into the outer conduit and through the second cap.
  • the conductive tube passes through the outer conduit.
  • a static fluid chamber is formed between the conductive tube and the gas transport conduit.
  • the static fluid chamber houses a static fluid.
  • the fluid mixture flows through the gas transport conduit into and out of the outer conduit.
  • a circulating fluid flows through the conductive tube into and out of the outer conduit.
  • the gas transport conduit conducts heat from the fluid mixture in the gas transport conduit to the static fluid in the static fluid chamber.
  • the conductive tube conducts heat from the static fluid in the static fluid chamber to the circulating fluid flowing through the conductive tube.
  • FIG. 1 is a systematic view of one embodiment of a cooling system integrated into a particle processing system in accordance with the principles of the present invention.
  • FIG. 2 is a perspective view of one embodiment of a cooling system in accordance with the principles of the present invention.
  • FIG. 3 is a cross-sectional view of one embodiment of a heat exchanger in accordance with the principles of the present invention.
  • FIG. 4 is a partial cross-sectional view of one embodiment of a heat exchanger in accordance with the principles of the present invention.
  • FIG. 5 is a flowchart illustrating one embodiment of a method of cooling a fluid mixture in accordance with the principles of the present invention.
  • Powders that fall within the scope of the present invention may include, but are not limited to, any of the following: (a) nano-structured powders (nano-powders), having an average grain size less than 250 nanometers and an aspect ratio between one and one million; (b) submicron powders, having an average grain size less than 1 micron and an aspect ratio between one and one million; (c) ultra-fine powders, having an average grain size less than 100 microns and an aspect ratio between one and one million; and (d) fine powders, having an average grain size less than 500 microns and an aspect ratio between one and one million.
  • nano-powders nano-structured powders
  • submicron powders having an average grain size less than 1 micron and an aspect ratio between one and one million
  • ultra-fine powders having an average grain size less than 100 microns and an aspect ratio between one and one million
  • fine powders having an average grain size less than 500 microns and an aspect ratio between one and one million.
  • the particle processing system 100 includes the gas-particle mixture production system 110 coupled with the sampling zone 150 and the vacuum system 160 through the conduit system 120 .
  • the gas-particle mixture production system 110 preferably produces particles entrained within a gas stream and provides the output fluid mixture to the conduit system 120 . It is contemplated that the fluid mixture can be produced in a variety of ways. Some embodiments of the present invention revolve around the use of a nano-powder production reactor. In general, vapor phase nano-powder production means are preferred. The embodiments of the present invention can use elements of nano-powder production systems similar to those disclosed in U.S. patent application Ser. No. 11/110,341, filed on Apr. 19, 2005 and entitled, “HIGH THROUGHPUT DISCOVERY OF MATERIALS THROUGH VAPOR PHASE SYNTHESIS”, which is currently published as U.S. Publication No. 2005-0233380-A.
  • working gas is supplied from a gas source to a plasma reactor.
  • energy is delivered to the working gas, thereby creating a plasma.
  • a variety of different means can be employed to deliver this energy, including, but not limited to, DC coupling, capacitive coupling, inductive coupling, and resonant coupling.
  • One or more material dispensing devices introduce at least one material, preferably in powder form, into the plasma reactor. The combination within the plasma reactor of the plasma and the material(s) introduced by the material dispensing device(s) forms a highly reactive and energetic mixture, wherein the powder can be vaporized. This mixture of vaporized powder moves through the plasma reactor in the flow direction of the working gas.
  • the fluid mixture preferably a gas-particle stream
  • the conduit system 120 where it is conditioned and conducted to the sampling zone 150 .
  • portions of the gas-particle stream are separated and the particles therein isolated for further analysis. It is contemplated that condensed particles can be separated from the gas-particle stream in a variety of ways, including, but not limited to, the use of one or more filters.
  • the bulk of the gas-particle stream flows through the sampling zone and into the vacuum system 160 .
  • the vacuum system 160 functions to draw the gas-particle stream from the production system 110 through the conduit system 120 , forcing it through the sampling zone 150 .
  • the conduit system 120 includes the conduit 140 configured to conduct and condition the gas-particle stream from the production system 110 to the vacuum system 160 .
  • the conditioning performed in the illustrated embodiment consists primarily of the cooling and the maintenance of entrainment of the particles.
  • the gas-particle stream is cooled and its particle entrainment maintained by introduction of conditioning fluid through the port 142 .
  • the gas-particle stream transfers heat to the body of the conduit 140 , which the cooling systems 170 and 180 dissipate.
  • the conditioning fluid reservoir 130 provides conditioning fluid to the port 142 through the supply line 135 .
  • the vacuum system 160 provides a suction force within the conduit 140 , drawing conditioning fluid into the port 142 to cool the gas-particle stream and maintain entrainment of particles therein.
  • the cooling systems 170 and 180 include the heat exchangers 172 and 182 respectively, which are coupled via the fluid lines 176 and 186 to the fluid supply systems 174 and 184 .
  • the fluid supply systems 174 and 184 pump fluid through the heat exchangers 172 and 182 .
  • the fluid heats as it absorbs heat from the heat exchangers 172 and 182 , and exits the heat exchangers 172 and 182 , whereupon it returns to the fluid supply systems 174 and 184 .
  • the fluid supply systems 174 and 184 preferably cool the fluid and again pump it to the heat exchangers 172 and 182 .
  • the cooling system 170 is required to dissipate more heat than the cooling system 180 .
  • Higher rates of fluid flow through a fluid heat exchanger result in higher rates of heat dissipation from that heat exchanger. Therefore, in most circumstances, the rate of fluid flow provided thorough the heat exchanger 172 by the fluid supply system 174 will be higher than correlating flow rate within the cooling system 180 .
  • control system 190 is communicatively coupled with the production system 110 and both cooling systems 170 and 180 , and can control both the general nature of the particle content produced, as well as the cooling of the conduit 140 . Because differing production conditions can lead to different heat loads within the conduit, the control system 190 varies the flow rates within the cooling systems 170 and 180 according to the expected heat load given current production conditions. Furthermore, the control system 190 varies the flow rates based on the temperature of the fluid sensed on output by an optional temperature sensor 192 from each heat exchanger 172 and 182 .
  • the cooling system 200 incorporates the fluid supply system 220 , and the heat exchanger 230 formed around the gas transport conduit 210 .
  • the heat exchanger 230 comprises the caps 231 and 233 , with the outer conduit 232 disposed there-between.
  • the fluid supply system 220 pumps fluid from an outlet 225 and takes fluid into an inlet 224 .
  • the cap 231 includes an inlet 237 , and a pressure relief valve 235 .
  • the inlet 237 is in fluid communication with a tube structure (discussed below with respect to FIGS. 3-4 ) disposed inside of the outer conduit 232 and allows fluid to enter the heat exchanger 230 .
  • the cap 233 includes an outlet 236 , which allows fluid to exit the heat exchanger 230 .
  • the inlet and outlet are reversed.
  • the fluid supply system 220 pumps fluid from is outlet 225 through the fluid line 223 into the inlet 237 . Fluid flows through the tube structure within the heat exchanger 230 from the inlet 237 . Within the heat exchanger 230 , the fluid is heated prior to flowing from the outlet 236 . Fluid flowing out of the outlet 236 is channeled through the fluid line 222 into the inlet 224 of the fluid supply system. Because the fluid entering the inlet 224 is preferably hotter than the fluid pumped from the outlet 225 , the fluid supply system 220 is preferably configured to cool the received fluid, such as by use of a refrigeration or other cooling system. Because fluid may expand rapidly when heated, the pressure relief valve 235 is provided to relieve pressure within the heat exchanger 230 by permitting outflow of fluid during periods when pressure exceeds a predetermined threshold value. The pressure relief valve can also be mounted through a wall of the outer conduit.
  • the heat exchanger 300 includes the outer conduit 340 sealed to the gas transport conduit 310 via the caps 320 and 330 .
  • the gas transport conduit 310 and the outer conduit 340 form there-between a toroidal chamber 360 .
  • a conductive tube structure 350 is fluidly coupled to a fluid supply system, such as discussed above, thereby allowing fluid to flow from the fluid supply system into and out of the outer conduit 340 via the conductive tube structure 35 , and back to the fluid supply system.
  • the conductive tube structure 350 is preferably curved in order to form the toroidal shape of the chamber 360 .
  • a static fluid is placed within the space left within the toroidal chamber 360 by the conductive tube structure 350 .
  • As fluid flows through the conductive tube structure 350 it intimately contacts the conductive tube structure 350 , which is intimately contacted by the static fluid within the toroidal chamber 360 , which in turn is also in intimate contact with the gas transport conduit 310 .
  • hot gas flows through the gas transport conduit 310 , thereby heating the gas transport conduit 310 .
  • Heat is dissipated from the gas transport conduit 310 through the static fluid within the toroidal chamber 360 , into the heat conductive tube structure 350 , and then into the fluid flowing there-within.
  • the heat exchanger 400 includes the outer conduit 440 sealed to the gas transport conduit 410 via the caps 420 and 430 .
  • the gas transport conduit 410 and the outer conduit 440 form there-between a toroidal chamber 460 .
  • a conductive tube structure 450 is fluidly coupled to a fluid supply system, such as discussed above, thereby allowing fluid to flow from the fluid supply system into and out of the outer conduit 440 via the conductive tube structure 450 , and back to the fluid supply system.
  • the conductive tube structure 450 is preferably wound spirally around the gas transport conduit 410 , thereby forming the toroidal shape of the chamber 460 .
  • a static fluid is placed within the space left within the toroidal chamber 460 by the conductive tube structure 450 .
  • As fluid flows through the conductive tube structure 450 it intimately contacts the conductive tube structure 450 , which is intimately contacted by the static fluid within the toroidal chamber 460 , which in turn is also in intimate contact with the gas transport conduit 410 .
  • hot gas flows through the gas transport conduit 410 , thereby heating the gas transport conduit 410 . Heat is dissipated from the gas transport conduit 410 through the static fluid within the toroidal chamber 460 , into the heat conductive tube structure 450 , and then into the fluid flowing there-within.
  • FIG. 5 is a flowchart illustrating one embodiment of a method 500 of cooling a fluid mixture in accordance with the principles of the present invention.
  • the protocols, processes, and procedures described herein may be repeated continuously or as often as necessary to satisfy the needs described herein. Additionally, although the steps of method 500 are shown in a specific order, certain steps may occur simultaneously or in a different order than is illustrated. Accordingly, the method steps of the present invention should not be limited to any particular order unless either explicitly or implicitly stated in the claims.
  • a cooling system having a fluid supply system fluidly coupled to a heat exchanger.
  • the heat exchanger comprises an outer conduit and a conductive tube.
  • the outer conduit is disposed around a gas transport conduit and has a first end, a second end opposite the first end, a first cap covering the first end, and a second cap covering the second end.
  • the gas transport conduit passes through the first cap into the outer conduit and through the second cap out of the outer conduit.
  • the conductive tube passes through the outer conduit. It is contemplated that the conductive tube can pass through portions of the heat exchanger other than the first cap and the second cap in order to pass through the outer conduit.
  • a static fluid chamber is formed between the conductive tube and the gas transport conduit, the static fluid chamber housing a static fluid.
  • a mixture production system produces a fluid mixture.
  • the mixture production system is fluidly coupled to the gas transport conduit. It is contemplated that the fluid mixture can be produced in a variety of ways. However, in a preferred embodiment, the mixture production system energizes a working gas, thereby forming a plasma stream, and applies the plasma stream to powder particles, thereby vaporizing the powder particles and forming the fluid mixture, which comprises vaporized particles.
  • the fluid mixture flows through the gas transport conduit into and out of the outer conduit of the heat exchanger.
  • a circulating fluid flows through the conductive tube into and out of the outer conduit of the heat exchanger. It is noted that this step can occur at the same time that the fluid mixture flows through the heat exchanger at step 530 .
  • the gas transport conduit conducts heat from the fluid mixture in the gas transport conduit to the static fluid in the static fluid chamber.
  • the conductive tube conducts heat from the static fluid in the static fluid chamber to the circulating fluid flowing through the conductive tube.
  • the heated circulating fluid flows out of the heat exchanger.
  • the circulating fluid flows back to the fluid supply system, where it is preferably cooled before being recirculated back into the heat exchanger upon repetition of the process.

Abstract

A heat exchanger comprising: a gas transport conduit providing a channel through which a fluid mixture can flow; an outer conduit disposed around the gas transport conduit, the outer conduit having a first cap covering a first end and a second cap covering a second end, the gas transport conduit passing through the outer conduit; and a conductive tube passing through the outer conduit, providing a channel through which a circulating fluid can flow through the outer conduit, wherein a static fluid chamber is formed between the conductive tube and the gas transport conduit, the static fluid chamber configured to house a static fluid, wherein the gas transport conduit is configured to conduct heat from the fluid mixture in the gas transport conduit to the static fluid and the conductive tube is configured to conduct heat from the static fluid to the circulating fluid.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • The present application claims priority to co-pending U.S. patent application Ser. No. 11/110,341, filed on Apr. 19, 2005, entitled, “HIGH THROUGHPUT DISCOVERY OF MATERIALS THROUGH VAPOR PHASE SYNTHESIS” and to co-pending U.S. Provisional Application Ser. No. 60/928,946, filed May 11, 2007, entitled “MATERIAL PRODUCTION SYSTEM AND METHOD,” both of which are hereby incorporated by reference as if set forth herein.
  • FIELD OF THE INVENTION
  • The present invention relates generally to methods of and systems for cooling gas transport conduits configured to conduct hot gasses or gaseous mixtures.
  • BACKGROUND OF THE INVENTION
  • In a gas phase particle production reactor, basic product species are formed within extremely short time spans following ejection of hot, reactive matter from an energy delivery zone. Although particle species are formed rapidly, cooling of the gas-particle product must be carefully controlled to achieve desired particle characteristics without contamination. In many cases, this carefully controlled cooling occurs within a gas transport system configured to deliver the gas-particle product to collection points within the system.
  • Since hot gas-particle product contains and emits a large quantity of heat, gas transport systems adapted to conduct gas-particle product from gas phase particle production reactors must be designed to efficiently absorb and dissipate high heat loads. Because heat transfer between two systems occurs in proportion to the temperature differential between the two systems, efficient absorption of heat from the gas-particle product depends on maintaining the gas transport system at a significantly lower temperature than the gas-particle product, while efficient dissipation of heat from the gas transport system depends on maintaining an environment of still lower temperature in contact with the gas transport system. The independent requirements of absorption and dissipation are at odds. Gas transport systems are typically incapable of absorbing large quantities of heat without increasing their temperature. In most cases, the two requirements are balanced by actively cooling the gas transport system, which provides a controlled, low temperature environment into which the gas transport system can dissipate heat.
  • Within the prior art, the most common active cooling strategies for gas transport systems involve forced fluid cooling. A variety of forced fluid cooling systems, including forced-gas cooling systems and liquid cooling systems, are employed in prior art gas transport coolers.
  • Forced-gas cooling systems typically include one or more fans, configured to force gas through one or more heat exchange structures thermally coupled with the gas transport system. Heat moves from the gas-particle product into the gas transport system and then into the heat exchange structures. Typically, the heat exchange structures include heat rejecters or heat sinks configured to present a large surface area interface to the gas within a heat exchange region. As gas moves through the heat exchange region and across the large surface area of the heat rejecter or heat sink, it convectively cools the heat rejecter or heat sink. Although such systems are simple and relatively inexpensive to operate, they are less efficient than liquid cooling systems because the heat capacity of gas is generally less than that of liquid, gas cools through mostly convective means and gas cannot be cooled as readily as can liquid. Thus, forced-gas cooling systems are ill suited to cool high heat load gas-particle mixtures.
  • Liquid cooling systems typically include liquid circulation system configured to deliver fluid through one or more heat exchange structures thermally coupled with the gas transport system. As in forced-gas systems, the heat exchange structures are typically configured to present a large surface area for interaction with the liquid within a heat exchange region. Heat is absorbed into the gas-transport system and conducted into the heat exchange structures. As liquid moves across the heat exchange surface, heat dissipates from the heat exchange structures through conductive and convective means into the liquid and heated liquid flows away from the heat exchange region. Typically, heat is removed from the heated liquid via some further cooling or refrigeration mechanism.
  • For efficient cooling, the entire volume of the heat exchange region must be constantly supplied with fresh, cool liquid. Systems having high volume heat exchange regions require higher volumes of cool liquid to operate efficiently, resulting in high operating costs. While low volume heat exchange regions are known, fabrication methods are difficult, expensive and result in high set-up costs. Further, many low volume systems are very sensitive to contamination, and thus require sometimes expensive precautions, such as filters, and regular maintenance to run smoothly.
  • Current methods for cooling gas transport systems rely either on forced-gas cooling, which lacks sufficient efficiency to handle high heat load systems, or liquid cooling systems, which are expensive to build and maintain.
  • SUMMARY OF THE INVENTION
  • According to the present invention, a cooling system for a conduit is presented. In an exemplary aspect, a cooling system according to the present invention is used to cool a conduit that transports gas mixtures. The cooling system is primarily intended to dissipate heat absorbed by the conduit from the gas particle product it transports. In an exemplary system, hot gas-particle product is emitted from gas phase particle production reactors, such as flame reactors, plasma reactors, hot wall reactors and laser reactors. The conduit conducts and conditions the gas-vapor mixtures ejected from the reactor, absorbing heat from the mixtures through multiple means. The cooling system functions to dissipate heat absorbed within the conduit and prevent overheating of the conduit.
  • The present invention describes a cooling system for cooling selected portions of a gas transport conduit within a conduit system. Preferably, the cooling system comprises at least one cooling element configured to cool a portion of the gas transport conduit, comprising a section of outer conduit having a first end and a second end. The cooling element is preferably fitted around the portion of the gas transport conduit to form a toroidal channel between the inner surface of the outer conduit and the outer surface of the gas transport conduit. The toroidal channel formed between the outer conduit and the gas transport conduit has a first opening at the first end of the conduit and a second opening at the second end of the conduit. A highly heat conductive tube structure is placed within the outer conduit to form the toroidal channel. Furthermore, the highly heat conductive tube structure preferably does not seal the channel to fluid flow at any point therein, so that fluid may move freely within the toroidal channel with the highly heat conductive tube structure in place. However, in an alternative embodiment, the cooling system incorporates partitions within the toroidal channel, which seal the toroidal channel to fluid flow except through the highly heat conductive tube structure. In this aspect, the toroidal channel is divided into several chambers, each of which can have a different fluid therein, with the highly conductive tube structure passing through each of the several chambers.
  • With the highly heat conductive tube structure installed in the toroidal channel, a first cap coupled with the first opening and a second cap coupled with the second opening of the toroidal channel provide a seal between the gas transport conduit and the conduit. The toroidal channel is filled with a static fluid, preferably a liquid, surrounding and thermally contacting the highly heat conductive tube structure. At least one of the caps is configured with a port to allow fluid delivery therethrough into the highly heat conductive tube structure. A fluid reservoir system is coupled with the one or more ports and thereby with the highly heat conductive tube structure. Although in the preferred embodiment the caps and the outer conduit are modularly formed and sealed to one another, the caps and the outer conduit can be integrally formed in alternative embodiments.
  • Thus, each embodiment of the present invention includes two fluid systems, separated from one another: a circulating system (referred to as “fluid” or “circulating fluid”) and a static system (referred to as “static fluid). The fluids chosen for use within each system have preferred characteristics, which differ depending on the specifics of each embodiment.
  • As the conduit system conducts hot gas, it absorbs heat from the gas. Because the gas cools as it travels through the conduit system, some portions of the conduit system absorb more heat than others. An exemplary portion of a gas transport conduit within the conduit system is equipped with a cooling system as described in the preceding paragraph.
  • The cooling system of the present invention operates by removing heat from the gas transport conduit via fluid flow. As heat is absorbed into the gas transport conduit from the gas within the conduit, the cooling system works to remove heat from the conduit through the external surfaces of the conduit. Heat moves from the conduit system into the static fluid, heating the static fluid. The static fluid, being in thermal contact with the highly heat conductive tube structure, conducts heat into the highly heat conductive tube structure. Fluid flows from the fluid reservoir system into the highly heat conductive tube structure, absorbing heat from the conduit system through the highly heat conductive tube structure and the static fluid. The fluid flows from the highly heat conductive tube structure back into the fluid reservoir system, or into a different fluid reservoir. As one skilled in the art will recognize, in a closed loop system (where the fluid returns to the same reservoir system), in order to maintain cooling efficiency, the fluid is preferably cooled via external means, such as refrigeration, before being resupplied to the highly heat conductive tube structure
  • Functionally, each cooling cell within cooling system includes several components: a heat exchange region, and a fluid flow control and supply system. Functioning together, these components allow a cell to provide effective cooling to a specific region of a conduit system. A cooling system having a plurality of such cells working in concert provides selective, extensible and configurable cooling to a conduit system. The present invention includes a desired structure and function for each component of a cell within the system.
  • There are several heat exchange regions in the present invention. In an assembled system, the highly heat conductive tube structure sits within the toroidal channel defined between the gas transport conduit and the outer conduit and filled with the static fluid. Preferably, the highly heat conductive structure is wound in a spiral in the toroidal chamber along the conduit. The region of interface between the conduit and the static fluid within the toroidal channel forms a first heat exchange region: heat flows from the gas transport conduit into the static fluid. The surface of the interface between the static fluid and the highly heat conductive tube structure within the toroidal channel forms a second heat exchange region: heat is conducted from the static fluid into the highly heat conductive tube structure. The inner surface of the highly heat conductive tube structure forms a third heat exchange region: heat flows from the highly heat conductive tube structure into the circulating fluid.
  • The highly heat conductive tube structure is preferably formed from bent highly heat conductive material. Preferred materials include metals, such as copper, and highly heat conductive thermoplastics. As mentioned above, the highly heat conductive tube structure permits fluid flow there-through. The present invention contemplates a variety of structures to permit fluid flow. In various embodiments, the highly heat conductive tube structure comprises porous structures and/or channel structures defining fluid flow paths. Preferably, the structures present a high surface area for heat exchange, relative to the volume of the highly heat conductive tube structure.
  • Preferably, the highly heat conductive tube structure is spirally wound to form a toroidal shape encircling the gas transport conduit within the toroidal channel, much like the shape of a coiled spring. The present invention contemplates a variety of configurations of the highly heat conductive tube structure within the toroidal channel, including coiled, folded and layered configurations. The highly heat conductive tube structure can be formed independently from the conduit, or formed around the conduit. Regardless of the method of formation, the highly heat conductive tube structure is configured to fit within the toroidal channel.
  • In an exemplary embodiment, copper tubing coiled around the gas transport conduit forms the highly heat conductive tube structure. The copper tubing is preferably coiled coarsely, and may but need not physically contact the gas transport conduit. Placement of the outer conduit to surround the highly heat conductive tube structure forms a toroidal channel containing the highly heat conductive tube structure. The toroidal channel is sealed and filled with a static fluid. The filling may be accomplished following the sealing of one end of the outer conduit and prior to the sealing of the other end. Alternatively, the filling may be accomplished through a valve system positioned in either or both ends of the heat exchanger.
  • The fluid flow control system has several functions. The rate of heat dissipation within a fluid cooling system depends on many factors, several of which relate to the rate and type of fluid flow within the system. An effective fluid flow control system includes means to channel the fluid to the desired portions of the heat exchange region. Also, because fluids expand under heating, and because heat dissipation within a fluid cooling system depends on heating of the fluid, the fluid control system must account for pressure changes within the fluid. Similarly, the toroidal chamber formed within the outer conduit and the two seals preferably includes a valve system configured to account for pressure changes within the fluid.
  • The present invention presents a fluid control system comprising several parts. The outer conduit provides a confining structure, which forms the toroidal chamber in which static fluid is positioned. Thus, the conduit determines the total fluid volume within the toroidal chamber, exclusive of the fluid path within the highly heat conductive tube structure. Furthermore, each of the caps sealing the ends of the outer conduit are preferably equipped with a plurality of ports. These ports determine the pattern in which fluid flows into the highly heat conductive tube structure and thus help determine, in concert with the flow structures within the highly heat conductive tube structure, the flow patterns through the highly heat conductive tube structure. Additionally, the cap structures preferably include one or more pressure relief valves, configured to release fluid from the system should a sudden rise in pressure occur. Furthermore, the fluid control system can include a pump configured to deliver fluid through the plurality of ports on one of the sealing caps.
  • The outer conduit is preferably configured along with the highly heat conductive tube structure to define a predetermined fluid volume within the toroidal region. The specific volume and flow rate of an embodiment depend on the heat loads for which that embodiment is designed. Roughly, higher volumes and flow rates will be required to handle higher heat loads. Conductivity and surface area are also considerations in determining required fluid volume.
  • Preferably, the outer conduit is formed from a durable, heat resistant material. The material forming the outer conduit need not be thermally conductive. In fact, in order to minimize heat dissipation through the outer conduit, at least the outer surface preferably comprises an insulating material. This configuration separates the heat dissipation and structural functions of the cooling system. Alternatively, the outer surface can be heat conductive to promote additional heat loss through radiation.
  • The caps couple with and seal the ends of the outer conduit. In the various embodiments the caps can be bonded, threaded, and/or bolted on to the outer conduit. The present invention contemplates any coupling that creates a seal between the cap and the outer conduit. Preferably, the caps comprise material similar to that in the outer conduit. Additionally, the seal between the conduit system and the caps can be formed in a variety of ways: the caps can be bonded, pressure fitted, or held in place by o-ring type seals. The preferred method of sealing the caps provides for expansion and contraction of the caps as the heat exchanger is heated and cooled.
  • Furthermore, the caps each preferably include a plurality of ports. As mentioned, one of the ports provides a pressure relief system for the fluid system, preferably at each end of the outer conduit. The other ports provide fluid delivery into the highly heat conductive tube structure in a specified configuration. The configuration of the ports and the configuration of the fluid channels within the highly heat conductive tube structure complement one another to form desired flow paths through the system. The configuration of the paths and the rate of fluid delivery thereto partially determine the rate of heat dissipation from the gas transport conduit to the fluid.
  • The fluid control system can further include a fluid pump and fluid supply system, which can reasonably be integrated into a single device, but can also be provided modularly. The fluid pump determines the rate of fluid delivery to the plurality of ports and thus the rate of fluid flow through the highly heat conductive tube structure. Higher fluid flow rates allow the system to dissipate greater amounts of heat. Accordingly the fluid flow rates are preferably varied as heat dissipation requirements vary.
  • Preferably, since the heat production within a gas production system incorporating a cooling system of the present invention is not necessarily static, the cooling system of the present invention can vary its fluid flow rates to accommodate varying requirements for heat dissipation. In one aspect of the present invention, a control system controls the pump and fluid supply system according to the observed temperature difference between fluid flowing into the heat exchange region and fluid flowing from the heat exchange region. If the temperature difference is beyond desired limits, the rate of flow is increased, so long as the maximum flow rate has not been exceeded.
  • The fluid supply system preferably provides cool fluid to the fluid pump. This fluid can be fresh, i.e., fluid which has not been used in the system before, or this fluid can be recirculated. If recirculated fluid is used, the fluid supply system preferably cools the recirculated fluid before resupplying it to the pump. The fluid supply system can incorporate a pressure relief valve. Several types of fluids are contemplated by the present invention. Preferred fluids have high thermal conductivity.
  • Within the several embodiments of the present invention, the preferred characteristics of the fluid and the static fluid can vary. Specifically preferred characteristics can differ both between the fluid and the static fluid within a given embodiment and within a given fluid between multiple embodiments. Important characteristics of the fluid include density, heat capacity, viscosity, and conductivity. In one aspect of the present invention, a static fluid and a circulating fluid both having a low thermal mass are chosen to allow rapid changes in the temperature of the heat exchanger. In other aspects of the present invention, circulating fluid and static fluid having high heat capacities are chosen to allow removal of large quantities of heat.
  • As a gas phase particle production system operates, hot gas product emitted from a reactor flows through a gas transport conduit within a conduit system. As the gas flows through the conduit it cools, dissipating heat into the gas transport conduit. Because heat dissipation is proportional to temperature differential, presuming a uniform rate of conduit heating, less heat is dissipated into the gas transport conduit as the gas becomes cooler, i.e., portions of the conduit further from the point at which hot gas is introduced into the conduit absorb less heat from the gas. Because of these differences, a cooling system according to the present invention preferably incorporates a variety of subsystems. The operation of one such subsystem is discussed below.
  • As hot gas flows through a gas transport conduit, heat dissipates into the conduit. Within the present invention, a highly heat conductive tube structure is coupled with the conduit and placed within a toroidal structure formed between the gas transport conduit and an outer conduit. The gas transport conduit and the highly heat conductive tube structure are in thermal contact through a static fluid within the toroidal chamber, which allows heat to dissipate from the gas transport conduit into the highly heat conductive tube structure. As heat flows from the gas transport conduit into the static fluid, fluid flows through the highly heat conductive tube structure, which is in contact with the static fluid. As fluid flows, heat is dissipated from the highly heat conductive tube structure into the fluid, thereby heating the fluid. Thus, heat dissipated from the gas transport conduit is physically removed via dissipation into a flowing fluid.
  • In one aspect of the present invention, a heat exchanger is provided. The heat exchanger comprises a gas transport conduit that provides a channel through which a fluid mixture can flow. An outer conduit is disposed around the gas transport conduit. The outer conduit has a first end, a second end opposite the first end, a first cap covering the first end, and a second cap covering the second end. The gas transport conduit passes through the first cap, into the outer conduit, and through the second cap. A conductive tube passes through the outer conduit, thereby providing a channel through which a circulating fluid can flow into and out of the outer conduit. A static fluid chamber is formed between the conductive tube and the gas transport conduit. The static fluid chamber is configured to house a static fluid. The gas transport conduit is configured to conduct heat from the fluid mixture in the gas transport conduit to the static fluid in the static fluid chamber and the conductive tube is configured to conduct heat from the static fluid in the static fluid chamber to the circulating fluid flowing through the conductive tube.
  • In another aspect of the present invention, a cooling system is provided. The cooling system comprises a fluid supply system having an inlet and an outlet. The fluid supply system is configured to receive a heated circulating fluid through the inlet, cool the heated circulating fluid, and supply the cooled circulating fluid through the outlet. The cooling system also comprises a gas transport conduit that provides a channel through which a fluid mixture can flow and an outer conduit disposed around the gas transport conduit. The outer conduit has a first end, a second end opposite the first end, a first cap covering the first end, and a second cap covering the second end. The gas transport conduit passes through the first cap, into the outer conduit, and through the second cap. A conductive tube has a tube inlet fluidly coupled to the outlet of the fluid supply system and a tube outlet fluidly coupled to the inlet of the fluid supply system. The conductive tube passes through the outer conduit, thereby providing a channel through which the circulating fluid can flow from the fluid supply system into the outer conduit via the tube inlet and out of the outer conduit to the fluid supply system via the tube outlet. A static fluid chamber is formed between the conductive tube and the gas transport conduit. The static fluid chamber is configured to house a static fluid. The gas transport conduit is configured to conduct heat from the fluid mixture in the gas transport conduit to the static fluid in the static fluid chamber and the conductive tube is configured to conduct heat from the static fluid in the static fluid chamber to the circulating fluid flowing through the conductive tube.
  • In yet another aspect of the present invention, a method of cooling a fluid mixture is provided. The method comprises providing an outer conduit and a conductive tube. The outer conduit is disposed around a gas transport conduit and has a first end, a second end opposite the first end, a first cap covering the first end, and a second cap covering the second end. The gas transport conduit passes through the first cap into the outer conduit and through the second cap. The conductive tube passes through the outer conduit. A static fluid chamber is formed between the conductive tube and the gas transport conduit. The static fluid chamber houses a static fluid. The fluid mixture flows through the gas transport conduit into and out of the outer conduit. A circulating fluid flows through the conductive tube into and out of the outer conduit. The gas transport conduit conducts heat from the fluid mixture in the gas transport conduit to the static fluid in the static fluid chamber. The conductive tube conducts heat from the static fluid in the static fluid chamber to the circulating fluid flowing through the conductive tube.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a systematic view of one embodiment of a cooling system integrated into a particle processing system in accordance with the principles of the present invention.
  • FIG. 2 is a perspective view of one embodiment of a cooling system in accordance with the principles of the present invention.
  • FIG. 3 is a cross-sectional view of one embodiment of a heat exchanger in accordance with the principles of the present invention.
  • FIG. 4 is a partial cross-sectional view of one embodiment of a heat exchanger in accordance with the principles of the present invention.
  • FIG. 5 is a flowchart illustrating one embodiment of a method of cooling a fluid mixture in accordance with the principles of the present invention.
  • DETAILED DESCRIPTION OF THE INVENTION
  • The description below concerns several embodiments of the invention. The discussion references the illustrated preferred embodiment. However, the scope of the present invention is not limited to either the illustrated embodiment, nor is it limited to those discussed. To the contrary, the scope should be interpreted as broadly as possible based on the language of the Claims section of this document.
  • In the following description, numerous details and alternatives are set forth for purpose of explanation. However, one of ordinary skill in the art will realize that the invention can be practiced without the use of these specific details. In other instances, well-known structures and devices are shown in block diagram form in order not to obscure the description of the invention with unnecessary detail.
  • This disclosure refers to both particles and powders. These two terms are equivalent, except for the caveat that a singular “powder” refers to a collection of particles. The present invention may apply to a wide variety of powders and particles. Powders that fall within the scope of the present invention may include, but are not limited to, any of the following: (a) nano-structured powders (nano-powders), having an average grain size less than 250 nanometers and an aspect ratio between one and one million; (b) submicron powders, having an average grain size less than 1 micron and an aspect ratio between one and one million; (c) ultra-fine powders, having an average grain size less than 100 microns and an aspect ratio between one and one million; and (d) fine powders, having an average grain size less than 500 microns and an aspect ratio between one and one million.
  • Referring now to FIG. 1, a particle processing system 100 is provided. The particle processing system 100 includes the gas-particle mixture production system 110 coupled with the sampling zone 150 and the vacuum system 160 through the conduit system 120.
  • The gas-particle mixture production system 110 preferably produces particles entrained within a gas stream and provides the output fluid mixture to the conduit system 120. It is contemplated that the fluid mixture can be produced in a variety of ways. Some embodiments of the present invention revolve around the use of a nano-powder production reactor. In general, vapor phase nano-powder production means are preferred. The embodiments of the present invention can use elements of nano-powder production systems similar to those disclosed in U.S. patent application Ser. No. 11/110,341, filed on Apr. 19, 2005 and entitled, “HIGH THROUGHPUT DISCOVERY OF MATERIALS THROUGH VAPOR PHASE SYNTHESIS”, which is currently published as U.S. Publication No. 2005-0233380-A. In such a nano-powder production system, working gas is supplied from a gas source to a plasma reactor. Within the plasma reactor, energy is delivered to the working gas, thereby creating a plasma. A variety of different means can be employed to deliver this energy, including, but not limited to, DC coupling, capacitive coupling, inductive coupling, and resonant coupling. One or more material dispensing devices introduce at least one material, preferably in powder form, into the plasma reactor. The combination within the plasma reactor of the plasma and the material(s) introduced by the material dispensing device(s) forms a highly reactive and energetic mixture, wherein the powder can be vaporized. This mixture of vaporized powder moves through the plasma reactor in the flow direction of the working gas.
  • Referring back to FIG. 1, the fluid mixture, preferably a gas-particle stream, flows through the conduit system 120, where it is conditioned and conducted to the sampling zone 150. Within the sampling zone 150 portions of the gas-particle stream are separated and the particles therein isolated for further analysis. It is contemplated that condensed particles can be separated from the gas-particle stream in a variety of ways, including, but not limited to, the use of one or more filters. The bulk of the gas-particle stream flows through the sampling zone and into the vacuum system 160. The vacuum system 160 functions to draw the gas-particle stream from the production system 110 through the conduit system 120, forcing it through the sampling zone 150.
  • The conduit system 120 includes the conduit 140 configured to conduct and condition the gas-particle stream from the production system 110 to the vacuum system 160. The conditioning performed in the illustrated embodiment consists primarily of the cooling and the maintenance of entrainment of the particles. The gas-particle stream is cooled and its particle entrainment maintained by introduction of conditioning fluid through the port 142. Furthermore, the gas-particle stream transfers heat to the body of the conduit 140, which the cooling systems 170 and 180 dissipate. The conditioning fluid reservoir 130 provides conditioning fluid to the port 142 through the supply line 135. The vacuum system 160 provides a suction force within the conduit 140, drawing conditioning fluid into the port 142 to cool the gas-particle stream and maintain entrainment of particles therein.
  • The cooling systems 170 and 180 include the heat exchangers 172 and 182 respectively, which are coupled via the fluid lines 176 and 186 to the fluid supply systems 174 and 184. As the gas-particle stream dissipates heat into the conduit 140, that heat is conducted into the heat exchangers 172 and 182. The fluid supply systems 174 and 184 pump fluid through the heat exchangers 172 and 182. The fluid heats as it absorbs heat from the heat exchangers 172 and 182, and exits the heat exchangers 172 and 182, whereupon it returns to the fluid supply systems 174 and 184. The fluid supply systems 174 and 184 preferably cool the fluid and again pump it to the heat exchangers 172 and 182.
  • Because the gas particle stream is hotter when it passes nearest the cooling system 170 than when it passes nearest the cooling system 180, in most cases the cooling system 170 is required to dissipate more heat than the cooling system 180. Higher rates of fluid flow through a fluid heat exchanger result in higher rates of heat dissipation from that heat exchanger. Therefore, in most circumstances, the rate of fluid flow provided thorough the heat exchanger 172 by the fluid supply system 174 will be higher than correlating flow rate within the cooling system 180.
  • In a preferred embodiment, the control system 190 is communicatively coupled with the production system 110 and both cooling systems 170 and 180, and can control both the general nature of the particle content produced, as well as the cooling of the conduit 140. Because differing production conditions can lead to different heat loads within the conduit, the control system 190 varies the flow rates within the cooling systems 170 and 180 according to the expected heat load given current production conditions. Furthermore, the control system 190 varies the flow rates based on the temperature of the fluid sensed on output by an optional temperature sensor 192 from each heat exchanger 172 and 182.
  • Referring now to FIG. 2, the cooling system 200 incorporates the fluid supply system 220, and the heat exchanger 230 formed around the gas transport conduit 210. The heat exchanger 230 comprises the caps 231 and 233, with the outer conduit 232 disposed there-between. The fluid supply system 220 pumps fluid from an outlet 225 and takes fluid into an inlet 224.
  • As illustrated, the cap 231 includes an inlet 237, and a pressure relief valve 235. The inlet 237 is in fluid communication with a tube structure (discussed below with respect to FIGS. 3-4) disposed inside of the outer conduit 232 and allows fluid to enter the heat exchanger 230. Furthermore, the cap 233 includes an outlet 236, which allows fluid to exit the heat exchanger 230. In alternative embodiments, the inlet and outlet are reversed.
  • The fluid supply system 220 pumps fluid from is outlet 225 through the fluid line 223 into the inlet 237. Fluid flows through the tube structure within the heat exchanger 230 from the inlet 237. Within the heat exchanger 230, the fluid is heated prior to flowing from the outlet 236. Fluid flowing out of the outlet 236 is channeled through the fluid line 222 into the inlet 224 of the fluid supply system. Because the fluid entering the inlet 224 is preferably hotter than the fluid pumped from the outlet 225, the fluid supply system 220 is preferably configured to cool the received fluid, such as by use of a refrigeration or other cooling system. Because fluid may expand rapidly when heated, the pressure relief valve 235 is provided to relieve pressure within the heat exchanger 230 by permitting outflow of fluid during periods when pressure exceeds a predetermined threshold value. The pressure relief valve can also be mounted through a wall of the outer conduit.
  • Referring now to FIG. 3, an exemplary heat exchanger 300 is provided. The heat exchanger 300 includes the outer conduit 340 sealed to the gas transport conduit 310 via the caps 320 and 330. The gas transport conduit 310 and the outer conduit 340 form there-between a toroidal chamber 360. Within the toroidal chamber 360, a conductive tube structure 350 is fluidly coupled to a fluid supply system, such as discussed above, thereby allowing fluid to flow from the fluid supply system into and out of the outer conduit 340 via the conductive tube structure 35, and back to the fluid supply system. The conductive tube structure 350 is preferably curved in order to form the toroidal shape of the chamber 360. Furthermore, a static fluid is placed within the space left within the toroidal chamber 360 by the conductive tube structure 350.
  • Fluid flows through the conductive tube structure 350 within the heat exchanger 300 from the inlet 325 to the outlet 335. As fluid flows through the conductive tube structure 350, it intimately contacts the conductive tube structure 350, which is intimately contacted by the static fluid within the toroidal chamber 360, which in turn is also in intimate contact with the gas transport conduit 310. During operation, hot gas flows through the gas transport conduit 310, thereby heating the gas transport conduit 310. Heat is dissipated from the gas transport conduit 310 through the static fluid within the toroidal chamber 360, into the heat conductive tube structure 350, and then into the fluid flowing there-within. As fluid flows from the inlet 325 to the outlet 335, heat is transferred from the heat conductive tube structure 350 into the fluid, thereby heating the fluid. As heated fluid flows from the outlet 335 back to the fluid supply system, heat is removed from the heat exchanger and thereby removed from the gas transport conduit 310, thereby maintaining it at an operating temperature.
  • Referring now to FIG. 4, a heat exchanger 400 is provided. The heat exchanger 400 includes the outer conduit 440 sealed to the gas transport conduit 410 via the caps 420 and 430. The gas transport conduit 410 and the outer conduit 440 form there-between a toroidal chamber 460. Within the toroidal chamber 460, a conductive tube structure 450 is fluidly coupled to a fluid supply system, such as discussed above, thereby allowing fluid to flow from the fluid supply system into and out of the outer conduit 440 via the conductive tube structure 450, and back to the fluid supply system. The conductive tube structure 450 is preferably wound spirally around the gas transport conduit 410, thereby forming the toroidal shape of the chamber 460. Furthermore, a static fluid is placed within the space left within the toroidal chamber 460 by the conductive tube structure 450.
  • Fluid flows through the conductive tube structure 450 within the heat exchanger 400 from the inlet 425 to the outlet 435. As fluid flows through the conductive tube structure 450, it intimately contacts the conductive tube structure 450, which is intimately contacted by the static fluid within the toroidal chamber 460, which in turn is also in intimate contact with the gas transport conduit 410. During operation, hot gas flows through the gas transport conduit 410, thereby heating the gas transport conduit 410. Heat is dissipated from the gas transport conduit 410 through the static fluid within the toroidal chamber 460, into the heat conductive tube structure 450, and then into the fluid flowing there-within. As fluid flows from the inlet 425 to the outlet 435, heat is transferred from the heat conductive tube structure 450 into the fluid, thereby heating the fluid. As heated fluid flows from the outlet 435 back to the fluid supply system, heat is removed from the heat exchanger and thereby removed from the gas transport conduit 410, thereby maintaining it at an operating temperature.
  • FIG. 5 is a flowchart illustrating one embodiment of a method 500 of cooling a fluid mixture in accordance with the principles of the present invention. As would be appreciated by those of ordinary skill in the art, the protocols, processes, and procedures described herein may be repeated continuously or as often as necessary to satisfy the needs described herein. Additionally, although the steps of method 500 are shown in a specific order, certain steps may occur simultaneously or in a different order than is illustrated. Accordingly, the method steps of the present invention should not be limited to any particular order unless either explicitly or implicitly stated in the claims.
  • At step 510, a cooling system is provided having a fluid supply system fluidly coupled to a heat exchanger. The heat exchanger comprises an outer conduit and a conductive tube. The outer conduit is disposed around a gas transport conduit and has a first end, a second end opposite the first end, a first cap covering the first end, and a second cap covering the second end. The gas transport conduit passes through the first cap into the outer conduit and through the second cap out of the outer conduit. In this respect, the conductive tube passes through the outer conduit. It is contemplated that the conductive tube can pass through portions of the heat exchanger other than the first cap and the second cap in order to pass through the outer conduit. A static fluid chamber is formed between the conductive tube and the gas transport conduit, the static fluid chamber housing a static fluid.
  • At step 520, a mixture production system produces a fluid mixture. The mixture production system is fluidly coupled to the gas transport conduit. It is contemplated that the fluid mixture can be produced in a variety of ways. However, in a preferred embodiment, the mixture production system energizes a working gas, thereby forming a plasma stream, and applies the plasma stream to powder particles, thereby vaporizing the powder particles and forming the fluid mixture, which comprises vaporized particles.
  • At step 530, the fluid mixture flows through the gas transport conduit into and out of the outer conduit of the heat exchanger.
  • At step 540, a circulating fluid flows through the conductive tube into and out of the outer conduit of the heat exchanger. It is noted that this step can occur at the same time that the fluid mixture flows through the heat exchanger at step 530.
  • At step 550, the gas transport conduit conducts heat from the fluid mixture in the gas transport conduit to the static fluid in the static fluid chamber.
  • At step 560, the conductive tube conducts heat from the static fluid in the static fluid chamber to the circulating fluid flowing through the conductive tube.
  • At step 570, the heated circulating fluid flows out of the heat exchanger. In a preferred embodiment, the circulating fluid flows back to the fluid supply system, where it is preferably cooled before being recirculated back into the heat exchanger upon repetition of the process.
  • The present invention has been described in terms of specific embodiments incorporating details to facilitate the understanding of the principles of construction and operation of the invention. As such, references herein to specific embodiments and details thereof are not intended to limit the scope of the claims appended hereto. It will be apparent to those skilled in the art that modifications can be made to the embodiments chosen for illustration without departing from the spirit and scope of the invention.

Claims (23)

1. A heat exchanger comprising:
a gas transport conduit providing a channel through which a fluid mixture can flow;
an outer conduit disposed around the gas transport conduit, the outer conduit having a first end, a second end opposite the first end, a first cap covering the first end, and a second cap covering the second end, wherein the gas transport conduit passes through the first cap, into the outer conduit, and through the second cap; and
a conductive tube passing through the outer conduit, thereby providing a channel through which a circulating fluid can flow into and out of the outer conduit, wherein a static fluid chamber is formed between the conductive tube and the gas transport conduit, the static fluid chamber configured to house a static fluid,
wherein the gas transport conduit is configured to conduct heat from the fluid mixture in the gas transport conduit to the static fluid in the static fluid chamber and the conductive tube is configured to conduct heat from the static fluid in the static fluid chamber to the circulating fluid flowing through the conductive tube.
2. The heat exchanger of claim 1, wherein the conductive tube is wound in a spiral around the gas transport conduit.
3. The heat exchanger of claim 1, wherein the conductive tube passes through the first cap and the second cap.
4. The heat exchanger of claim 1, further comprising a pressure relief valve fluidly coupled to the static fluid chamber, wherein the pressure relief valve is configured to relieve pressure from within the outer conduit by permitting outflow of fluid when a pressure within the outer conduit exceeds a predetermined value.
5. A cooling system comprising:
a fluid supply system having an inlet and an outlet, wherein the fluid supply system is configured to receive a heated circulating fluid through the inlet, cool the heated circulating fluid, and supply the cooled circulating fluid through the outlet;
a gas transport conduit providing a channel through which a fluid mixture can flow;
an outer conduit disposed around the gas transport conduit, the outer conduit having a first end, a second end opposite the first end, a first cap covering the first end, and a second cap covering the second end, wherein the gas transport conduit passes through the first cap, into the outer conduit, and through the second cap; and
a conductive tube having a tube inlet fluidly coupled to the outlet of the fluid supply system and a tube outlet fluidly coupled to the inlet of the fluid supply system, wherein the conductive tube passes through the outer conduit, thereby providing a channel through which the circulating fluid can flow from the fluid supply system into the outer conduit via the tube inlet and out of the outer conduit to the fluid supply system via the tube outlet, and wherein a static fluid chamber is formed between the conductive tube and the gas transport conduit, the static fluid chamber configured to house a static fluid,
wherein the gas transport conduit is configured to conduct heat from the fluid mixture in the gas transport conduit to the static fluid in the static fluid chamber and the conductive tube is configured to conduct heat from the static fluid in the static fluid chamber to the circulating fluid flowing through the conductive tube.
6. The system of claim 5, wherein the conductive tube is wound in a spiral around the gas transport conduit.
7. The system of claim 5, wherein the conductive tube passes through the first cap and the second cap.
8. The system of claim 5, further comprising a pressure relief valve fluidly coupled to the static fluid chamber, wherein the pressure relief valve is configured to relieve pressure from within the outer conduit by permitting outflow of fluid when a pressure within the outer conduit exceeds a predetermined value.
9. The system of claim 5, wherein a mixture production system is fluidly coupled to the gas transport conduit, the mixture production system configured to produce the fluid mixture and supply the fluid mixture to the gas transport conduit and through the outer conduit.
10. The system of claim 9, wherein the mixture production system is configured to:
energize a working gas to form a plasma stream; and
apply the plasma stream to a plurality of powder particles to vaporize the particles and form the fluid mixture, wherein the fluid mixture comprises the vaporized particles entrained within the plasma stream.
11. The system of claim 10, wherein a sampling system is fluidly coupled to the gas transport conduit and configured to receive the fluid mixture from the outer conduit and to separate condensed particles from the fluid mixture.
12. The system of claim 5, further comprising:
a temperature sensor thermally coupled to the gas transport conduit and configured to sense the temperature of the fluid mixture received from the outer conduit; and
a control system communicatively connected to the temperature sensor and to the fluid supply system, wherein the control system is configured to adjust the flow rate of the circulating fluid from the fluid supply system to the outer conduit based on the temperature of the fluid mixture sensed by the temperature sensor.
13. The system of claim 5, further comprising:
a second fluid supply system having an inlet and an outlet, wherein the second fluid supply system is configured to receive a second heated circulating fluid through the inlet, cool the second heated circulating fluid, and supply the cooled second circulating fluid through the outlet;
a second gas transport conduit fluidly coupled to the gas transport conduit of the outer conduit, thereby providing a channel through which the fluid mixture can flow from the outer conduit;
a second outer conduit disposed around the second gas transport conduit, the second outer conduit having a first end, a second end opposite the first end, a first cap covering the first end, and a second cap covering the second end, wherein the second gas transport conduit passes through the first cap, into the second outer conduit, and through the second cap; and
a second conductive tube having a tube inlet fluidly coupled to the outlet of the second fluid supply system and a tube outlet fluidly coupled to the inlet of the second fluid supply system, wherein the second conductive tube passes through the second outer conduit, thereby providing a channel through which the second circulating fluid can flow from the second fluid supply system into the second outer conduit via the tube inlet and out of the second outer conduit to the second fluid supply system via the tube outlet, and wherein a second static fluid chamber is formed between the second conductive tube and the second gas transport conduit, the second static fluid chamber configured to house a second static fluid,
wherein the second gas transport conduit is configured to conduct heat from the fluid mixture in the second gas transport conduit to the second static fluid in the second static fluid chamber and the second conductive tube is configured to conduct heat from the second static fluid in the second static fluid chamber to the second circulating fluid flowing through the second conductive tube.
14. The system of claim 13, further comprising:
a temperature sensor thermally coupled to the second gas transport conduit and configured to sense the temperature of the fluid mixture received from the second outer conduit; and
a control system communicatively connected to the temperature sensor, the fluid supply system and the second fluid supply system, wherein the control system is configured to adjust the flow rate of the circulating fluid from the fluid supply system to the outer conduit and the flow rate of the second circulating fluid from the second fluid supply system to the second outer conduit based on the temperature of the fluid mixture sensed by the temperature sensor.
15. A method of cooling a fluid mixture, the method comprising:
providing an outer conduit and a conductive tube, the outer conduit disposed around a gas transport conduit and having a first end, a second end opposite the first end, a first cap covering the first end, and a second cap covering the second end, wherein the gas transport conduit passes through the first cap into the outer conduit and through the second cap, the conductive tube passing through the outer conduit, wherein a static fluid chamber is formed between the conductive tube and the gas transport conduit, the static fluid chamber housing a static fluid,
flowing the fluid mixture through the gas transport conduit into and out of the outer conduit;
flowing a circulating fluid through the conductive tube into and out of the outer conduit;
the gas transport conduit conducting heat from the fluid mixture in the gas transport conduit to the static fluid in the static fluid chamber; and
the conductive tube conducting heat from the static fluid in the static fluid chamber to the circulating fluid flowing through the conductive tube.
16. The method of claim 15, wherein the conductive tube is wound in a spiral around the gas transport conduit.
17. The method of claim 15, wherein the conductive tube passes through the first cap and the second cap.
18. The method of claim 15, wherein a fluid supply system comprises an inlet and an outlet and the method further comprises:
the fluid supply system receiving a heated circulating fluid through the inlet from the outer conduit;
the fluid supply system cooling the heated circulating fluid, thereby forming cooled circulating fluid; and
the fluid supply system supplying the cooled circulating fluid as the circulating fluid to the outer conduit through the outlet.
19. The method of claim 15, wherein a mixture production system is fluidly coupled to the gas transport conduit, the mixture production system configured to produce the fluid mixture and supply the fluid mixture to the gas transport conduit and through the outer conduit.
20. The method of claim 19, further comprising the steps of:
the mixture production system energizing a working gas to form a plasma stream;
the mixture production system applying the plasma stream to a plurality of powder particles, thereby vaporizing the particles and forming the fluid mixture, wherein the fluid mixture comprises the vaporized particles entrained within the plasma stream; and
the mixture production system supplying the fluid mixture to the gas transport conduit in the outer conduit.
21. The method of claim 20, wherein a sampling system is fluidly coupled to the gas transport conduit and configured to receive the fluid mixture from the outer conduit, and wherein the method further comprises the steps of:
the sampling system receiving the fluid mixture from the outer conduit, wherein the fluid mixture comprises condensed particles; and
the sampling system separating the condensed particles from the fluid mixture.
22. The method of claim 15, wherein a temperature sensor is thermally coupled to the gas transport conduit and a control system is communicatively connected to the temperature sensor and to the fluid supply system, and wherein the method further comprises the steps of:
the temperature sensor sensing the temperature of the fluid mixture from the outer conduit;
the control system receiving an indication from the temperature sensor of the sensed temperature; and
the control system adjusting the flow rate of the circulating fluid from the fluid supply system to the outer conduit based on the sensed temperature.
23. The method of claim 15, further comprising the steps of:
providing a second outer conduit and a second conductive tube, the second outer conduit disposed around a second gas transport conduit and having a first end, a second end opposite the first end, a first cap covering the first end, and a second cap covering the second end, the second gas transport conduit fluidly coupled downstream from the gas transport conduit, wherein the second gas transport conduit passes through the first cap into the second outer conduit and through the second cap, the second conductive tube passing through the second outer conduit, wherein a second static fluid chamber is formed between the second conductive tube and the second gas transport conduit, the second static fluid chamber housing a second static fluid,
the second gas transport conduit receiving the fluid mixture from the gas transport conduit of the outer conduit;
flowing the fluid mixture through the second gas transport conduit into and out of the second outer conduit;
flowing a second circulating fluid through the second conductive tube into and out of the second outer conduit; and
the second gas transport conduit conducting heat from the fluid mixture in the second gas transport conduit to the second static fluid in the second static fluid chamber; and the second conductive tube conducting heat from the second static fluid in the second static fluid chamber to the second circulating fluid flowing through the second conductive tube.
US12/151,767 2005-04-19 2008-05-08 Water cooling system and heat transfer system Abandoned US20080277092A1 (en)

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Applications Claiming Priority (3)

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US11/110,341 US20050233380A1 (en) 2004-04-19 2005-04-19 High throughput discovery of materials through vapor phase synthesis
US92894607P 2007-05-11 2007-05-11
US12/151,767 US20080277092A1 (en) 2005-04-19 2008-05-08 Water cooling system and heat transfer system

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US12/151,805 Expired - Fee Related US9173967B1 (en) 2007-05-11 2008-05-08 System for and method of processing soft tissue and skin with fluids using temperature and pressure changes
US12/151,765 Active 2031-08-26 US8574408B2 (en) 2005-04-19 2008-05-08 Fluid recirculation system for use in vapor phase particle production system
US12/151,841 Expired - Fee Related US8945219B1 (en) 2007-05-11 2008-05-08 System for and method of introducing additives to biological materials using supercritical fluids
US12/151,840 Expired - Fee Related US8007718B1 (en) 2007-05-11 2008-05-08 System for and method of processing bone material using supercritical fluids
US12/151,935 Active 2033-07-01 US9180423B2 (en) 2005-04-19 2008-05-08 Highly turbulent quench chamber
US12/151,766 Expired - Fee Related US8142619B2 (en) 2007-05-11 2008-05-08 Shape of cone and air input annulus
US12/151,807 Expired - Fee Related US8051724B1 (en) 2007-05-11 2008-05-08 Long cool-down tube with air input joints
US12/151,932 Expired - Fee Related US7678419B2 (en) 2007-05-11 2008-05-08 Formation of catalytic regions within porous structures using supercritical phase processing
US12/151,830 Active 2032-05-10 US8893651B1 (en) 2007-05-11 2008-05-08 Plasma-arc vaporization chamber with wide bore
US12/151,767 Abandoned US20080277092A1 (en) 2005-04-19 2008-05-08 Water cooling system and heat transfer system
US12/151,860 Active 2029-04-07 US7897127B2 (en) 2007-05-11 2008-05-09 Collecting particles from a fluid stream via thermophoresis
US12/152,098 Expired - Fee Related US8076258B1 (en) 2007-05-11 2008-05-09 Method and apparatus for making recyclable catalysts
US12/152,095 Expired - Fee Related US7905942B1 (en) 2007-05-11 2008-05-09 Microwave purification process
US12/152,109 Active 2028-07-08 US8524631B2 (en) 2005-04-19 2008-05-09 Nano-skeletal catalyst
US12/152,096 Active 2031-10-26 US8663571B2 (en) 2005-04-19 2008-05-09 Method and apparatus for making uniform and ultrasmall nanoparticles
US12/152,097 Active 2032-08-29 US9132404B2 (en) 2005-04-19 2008-05-09 Gas delivery system with constant overpressure relative to ambient to system with varying vacuum suction
US12/879,853 Active 2028-10-10 US8956574B2 (en) 2007-05-11 2010-09-10 Gas delivery system with constant overpressure relative to ambient to system with varying vacuum suction
US12/943,909 Expired - Fee Related US8604398B1 (en) 2007-05-11 2010-11-10 Microwave purification process
US13/289,955 Abandoned US20120045373A1 (en) 2007-05-11 2011-11-04 Method and apparatus for making recyclable catalysts
US13/291,983 Abandoned US20120285548A1 (en) 2007-05-11 2011-11-08 Long cool-down tube with air input joints
US13/907,667 Active US8906316B2 (en) 2005-04-19 2013-05-31 Fluid recirculation system for use in vapor phase particle production system
US13/954,614 Active US9023754B2 (en) 2005-04-19 2013-07-30 Nano-skeletal catalyst
US14/165,438 Active US9216398B2 (en) 2005-04-19 2014-01-27 Method and apparatus for making uniform and ultrasmall nanoparticles
US14/542,377 Active 2028-11-09 US9719727B2 (en) 2005-04-19 2014-11-14 Fluid recirculation system for use in vapor phase particle production system
US14/682,978 Abandoned US20150314260A1 (en) 2005-04-19 2015-04-09 Nano-skeletal catalyst
US14/750,857 Abandoned US20150367331A1 (en) 2005-04-19 2015-06-25 Nano-skeletal catalyst
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US12/151,841 Expired - Fee Related US8945219B1 (en) 2007-05-11 2008-05-08 System for and method of introducing additives to biological materials using supercritical fluids
US12/151,840 Expired - Fee Related US8007718B1 (en) 2007-05-11 2008-05-08 System for and method of processing bone material using supercritical fluids
US12/151,935 Active 2033-07-01 US9180423B2 (en) 2005-04-19 2008-05-08 Highly turbulent quench chamber
US12/151,766 Expired - Fee Related US8142619B2 (en) 2007-05-11 2008-05-08 Shape of cone and air input annulus
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US12/152,095 Expired - Fee Related US7905942B1 (en) 2007-05-11 2008-05-09 Microwave purification process
US12/152,109 Active 2028-07-08 US8524631B2 (en) 2005-04-19 2008-05-09 Nano-skeletal catalyst
US12/152,096 Active 2031-10-26 US8663571B2 (en) 2005-04-19 2008-05-09 Method and apparatus for making uniform and ultrasmall nanoparticles
US12/152,097 Active 2032-08-29 US9132404B2 (en) 2005-04-19 2008-05-09 Gas delivery system with constant overpressure relative to ambient to system with varying vacuum suction
US12/879,853 Active 2028-10-10 US8956574B2 (en) 2007-05-11 2010-09-10 Gas delivery system with constant overpressure relative to ambient to system with varying vacuum suction
US12/943,909 Expired - Fee Related US8604398B1 (en) 2007-05-11 2010-11-10 Microwave purification process
US13/289,955 Abandoned US20120045373A1 (en) 2007-05-11 2011-11-04 Method and apparatus for making recyclable catalysts
US13/291,983 Abandoned US20120285548A1 (en) 2007-05-11 2011-11-08 Long cool-down tube with air input joints
US13/907,667 Active US8906316B2 (en) 2005-04-19 2013-05-31 Fluid recirculation system for use in vapor phase particle production system
US13/954,614 Active US9023754B2 (en) 2005-04-19 2013-07-30 Nano-skeletal catalyst
US14/165,438 Active US9216398B2 (en) 2005-04-19 2014-01-27 Method and apparatus for making uniform and ultrasmall nanoparticles
US14/542,377 Active 2028-11-09 US9719727B2 (en) 2005-04-19 2014-11-14 Fluid recirculation system for use in vapor phase particle production system
US14/682,978 Abandoned US20150314260A1 (en) 2005-04-19 2015-04-09 Nano-skeletal catalyst
US14/750,857 Abandoned US20150367331A1 (en) 2005-04-19 2015-06-25 Nano-skeletal catalyst
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Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110143041A1 (en) * 2009-12-15 2011-06-16 SDCmaterials, Inc. Non-plugging d.c. plasma gun
US8470112B1 (en) 2009-12-15 2013-06-25 SDCmaterials, Inc. Workflow for novel composite materials
US8481449B1 (en) 2007-10-15 2013-07-09 SDCmaterials, Inc. Method and system for forming plug and play oxide catalysts
GB2498820A (en) * 2012-04-05 2013-07-31 R B Radley & Co Ltd Condenser
US8524631B2 (en) 2007-05-11 2013-09-03 SDCmaterials, Inc. Nano-skeletal catalyst
US8545652B1 (en) 2009-12-15 2013-10-01 SDCmaterials, Inc. Impact resistant material
US8557727B2 (en) 2009-12-15 2013-10-15 SDCmaterials, Inc. Method of forming a catalyst with inhibited mobility of nano-active material
US8652992B2 (en) 2009-12-15 2014-02-18 SDCmaterials, Inc. Pinning and affixing nano-active material
US8668803B1 (en) 2009-12-15 2014-03-11 SDCmaterials, Inc. Sandwich of impact resistant material
US8669202B2 (en) 2011-02-23 2014-03-11 SDCmaterials, Inc. Wet chemical and plasma methods of forming stable PtPd catalysts
US8679433B2 (en) 2011-08-19 2014-03-25 SDCmaterials, Inc. Coated substrates for use in catalysis and catalytic converters and methods of coating substrates with washcoat compositions
US9126191B2 (en) 2009-12-15 2015-09-08 SDCmaterials, Inc. Advanced catalysts for automotive applications
US9149797B2 (en) 2009-12-15 2015-10-06 SDCmaterials, Inc. Catalyst production method and system
US9156025B2 (en) 2012-11-21 2015-10-13 SDCmaterials, Inc. Three-way catalytic converter using nanoparticles
US9427732B2 (en) 2013-10-22 2016-08-30 SDCmaterials, Inc. Catalyst design for heavy-duty diesel combustion engines
US9511352B2 (en) 2012-11-21 2016-12-06 SDCmaterials, Inc. Three-way catalytic converter using nanoparticles
US9517448B2 (en) 2013-10-22 2016-12-13 SDCmaterials, Inc. Compositions of lean NOx trap (LNT) systems and methods of making and using same
US9586179B2 (en) 2013-07-25 2017-03-07 SDCmaterials, Inc. Washcoats and coated substrates for catalytic converters and methods of making and using same
US9687811B2 (en) 2014-03-21 2017-06-27 SDCmaterials, Inc. Compositions for passive NOx adsorption (PNA) systems and methods of making and using same
CN107810655A (en) * 2015-06-26 2018-03-16 英特尔Ip公司 The apparatus and method for merging concurrently to send by conditional signal
US10124322B2 (en) 2015-02-11 2018-11-13 Umicore Ag & Co. Kg Lean NOx traps, trapping materials, washcoats, and methods of making and using the same
CN111793838A (en) * 2020-05-27 2020-10-20 崔建中 Melt-blown cooling device applied to automatic production line of non-woven fabric

Families Citing this family (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7857972B2 (en) 2003-09-05 2010-12-28 Foret Plasma Labs, Llc Apparatus for treating liquids with wave energy from an electrical arc
US8981250B2 (en) 2001-07-16 2015-03-17 Foret Plasma Labs, Llc Apparatus for treating a substance with wave energy from plasma and an electrical Arc
US8764978B2 (en) 2001-07-16 2014-07-01 Foret Plasma Labs, Llc System for treating a substance with wave energy from an electrical arc and a second source
US8734654B2 (en) 2001-07-16 2014-05-27 Foret Plasma Labs, Llc Method for treating a substance with wave energy from an electrical arc and a second source
US7422695B2 (en) 2003-09-05 2008-09-09 Foret Plasma Labs, Llc Treatment of fluids with wave energy from a carbon arc
US8734643B2 (en) 2001-07-16 2014-05-27 Foret Plasma Labs, Llc Apparatus for treating a substance with wave energy from an electrical arc and a second source
US10188119B2 (en) 2001-07-16 2019-01-29 Foret Plasma Labs, Llc Method for treating a substance with wave energy from plasma and an electrical arc
US7622693B2 (en) 2001-07-16 2009-11-24 Foret Plasma Labs, Llc Plasma whirl reactor apparatus and methods of use
US20050195966A1 (en) * 2004-03-03 2005-09-08 Sigma Dynamics, Inc. Method and apparatus for optimizing the results produced by a prediction model
US20050233380A1 (en) * 2004-04-19 2005-10-20 Sdc Materials, Llc. High throughput discovery of materials through vapor phase synthesis
CN100392316C (en) * 2006-03-27 2008-06-04 博奥生物有限公司 Flow structure of controlling liquid continuously flowing in micro-pipeline
CA2683165C (en) 2006-04-05 2013-06-11 Foret Plasma Labs, Llc System, method and apparatus for treating liquids with wave energy from plasma
CA2945295C (en) * 2007-06-15 2020-01-14 Warsaw Orthopedic, Inc. Method of treating tissue
US20110175264A1 (en) * 2009-07-24 2011-07-21 Pujari Vimal K High Toughness Ceramic Composites
DE102009034773A1 (en) 2009-07-25 2011-01-27 Bayer Materialscience Ag Process for producing chlorine by gas-phase oxidation on nanostructured ruthenium-supported catalysts
DE102009052430A1 (en) * 2009-11-10 2011-06-01 Brückner, Manuela Method for cooling and cleaning of particulate or condensate-prone hot gases, involves cooling cooling surface of cooling element, particularly by liquid or gaseous cooling medium
US20110143930A1 (en) * 2009-12-15 2011-06-16 SDCmaterials, Inc. Tunable size of nano-active material on nano-support
EP2512656A4 (en) * 2009-12-15 2014-05-28 Sdcmaterails Inc Advanced catalysts for fine chemical and pharmaceutical applications
KR101158188B1 (en) * 2010-02-01 2012-06-19 삼성전기주식회사 Apparatus for synthesizing nano particles, and method for synthesizing the nano particles with the same
JP5408054B2 (en) * 2010-06-28 2014-02-05 東ソー株式会社 Method for producing ceramic beads having a smooth surface
EP2601042B1 (en) 2010-08-06 2022-03-23 Immunolight, Llc. Color enhancement utilizing up converters and down converters
US8422008B2 (en) 2010-09-29 2013-04-16 General Electric Company Electrical machine component monitoring system and method
WO2012146436A1 (en) * 2011-04-28 2012-11-01 Basf Se Noble metal catalysts having low metal charge for oxidative dehydrations
US8409537B2 (en) * 2011-08-29 2013-04-02 General Electric Company Method for removing contaminants from boron powder
WO2013033726A1 (en) * 2011-09-02 2013-03-07 Quinonez Carlo Joseph Universal hardware platform and toolset for operating and fabricating microfluidic devices
KR101661054B1 (en) * 2012-08-03 2016-09-28 제이에프이 스틸 가부시키가이샤 Crystallizer and crystallization method
WO2014159736A1 (en) * 2013-03-14 2014-10-02 SDCmaterials, Inc. High-throughput particle production using a plasma system
WO2014093560A1 (en) 2012-12-11 2014-06-19 Foret Plasma Labs, Llc High temperature countercurrent vortex reactor system, method and apparatus
KR101478286B1 (en) 2012-12-31 2015-01-06 국민대학교산학협력단 Manufacturing method of metal foam and metal foam manufactured thereby
CN105163829A (en) 2013-03-06 2015-12-16 Sdc材料公司 Particle-based systems for removal of pollutants from gases and liquids
EP2971488B1 (en) 2013-03-12 2018-09-26 Foret Plasma Labs, Llc Apparatus and method for sintering proppants
US20140263190A1 (en) * 2013-03-14 2014-09-18 SDCmaterials, Inc. High-throughput particle production using a plasma system
US9327252B2 (en) * 2013-03-15 2016-05-03 Applied Materials, Inc. Compact device for enhancing the mixing of gaseous species
KR101331027B1 (en) * 2013-04-19 2013-11-19 주식회사 셀모티브 Manufacturing method of metal foam with uniformly distributed nano-sized pores and metal foam manufactured thereby
KR101514968B1 (en) * 2013-04-24 2015-04-24 한국생산기술연구원 Method of manufacturing amorphous metal foams using vacuum solvent extraction
US9550694B2 (en) 2014-03-31 2017-01-24 Corning Incorporated Methods and apparatus for material processing using plasma thermal source
US9533909B2 (en) 2014-03-31 2017-01-03 Corning Incorporated Methods and apparatus for material processing using atmospheric thermal plasma reactor
US20160200618A1 (en) 2015-01-08 2016-07-14 Corning Incorporated Method and apparatus for adding thermal energy to a glass melt
US10675854B2 (en) * 2015-01-16 2020-06-09 Raytheon Technologies Corporation Additive processing apparatus and method
KR102024503B1 (en) 2015-03-13 2019-11-04 에이이에스 글로벌 홀딩스 피티이 리미티드 Plasma source device and methods
DE102015004474B4 (en) * 2015-04-08 2020-05-28 Kai Klinder Plant for the production of metal powder with a defined grain size range
CN104999579B (en) * 2015-05-12 2018-08-28 青岛科技大学 A kind of preparation method of nanocomposite
JP6590203B2 (en) * 2015-11-12 2019-10-16 パナソニックIpマネジメント株式会社 Fine particle production apparatus and fine particle production method
CN105517312A (en) * 2015-12-25 2016-04-20 中国航天空气动力技术研究院 Super-high-enthalpy arc heater anode
JP6512484B2 (en) 2016-03-25 2019-05-15 パナソニックIpマネジメント株式会社 Microparticle production apparatus and method
KR101954905B1 (en) * 2016-08-08 2019-03-08 주식회사 도프 Method for Preparing Collagen from Liposuction extract Using Supercritical Process
US10428306B2 (en) * 2016-08-12 2019-10-01 Warsaw Orthopedic, Inc. Method and system for tissue treatment with critical/supercritical carbon dioxide
TWI787215B (en) * 2016-11-22 2022-12-21 美商W R 康格雷氏公司 Catalysts with reduced attrition and method for manufacturing the same
WO2018197654A1 (en) 2017-04-27 2018-11-01 Umicore Ag & Co. Kg Porous nanoparticle-composite-based catalysts
WO2018202827A1 (en) 2017-05-04 2018-11-08 Umicore Ag & Co. Kg Plasma gun and plasma system for low melting point or low boiling point materials
WO2019046843A1 (en) * 2017-09-01 2019-03-07 Somnio Global Holdings, Llc Free radical generator and methods of use
US10921224B2 (en) * 2017-11-14 2021-02-16 Aerodyne Microsystems Inc. Thermophoretic particle detection system with variable channel geometry
WO2019131777A1 (en) * 2017-12-28 2019-07-04 国立大学法人愛媛大学 Device and method for forming diamond film or the like
JP2019122926A (en) * 2018-01-17 2019-07-25 太平洋セメント株式会社 Process for producing microparticle by spray pyrolysis
TWI647435B (en) * 2018-01-19 2019-01-11 國立清華大學 Thermally actuated oscillating suspended particle sensing device and suspended particle sensing method
US10865899B2 (en) 2018-09-27 2020-12-15 United States Of America As Represented By The Secretary Of The Navy System and method for protecting a pressure vessel from excessive differential pressure
CN109250835B (en) * 2018-11-21 2023-11-14 华北电力大学 Gravity type supercritical water fine particle thermophoresis removing device
US20230016029A1 (en) * 2019-12-24 2023-01-19 Battelle Energy Alliance, Llc Laser ablation methods and systems for producing feedstock powder suitable for laser-based additive manufacturing
CN111397396A (en) * 2020-03-19 2020-07-10 中国成达工程有限公司 Powder material cooling system and cooling process thereof
JP7236063B1 (en) * 2021-11-10 2023-03-09 コリア インスティチュート オブ インダストリアル テクノロジー Inorganic powder production apparatus and production method

Citations (92)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2419042A (en) * 1945-10-06 1947-04-15 Todd Floyd Vacuum distillation apparatus and pressure regulator therefor
US3181947A (en) * 1957-01-15 1965-05-04 Crucible Steel Co America Powder metallurgy processes and products
US3235700A (en) * 1962-07-27 1966-02-15 Air Liquide Apparatus for projecting materials in powder form by means of a concentrated electric arc
US3552653A (en) * 1968-01-10 1971-01-05 Inoue K Impact deposition of particulate materials
US3667111A (en) * 1969-03-05 1972-06-06 Chausson Usines Sa Process for fluxing and brazing parts made of aluminium or aluminium alloy
US3804034A (en) * 1972-05-09 1974-04-16 Boride Prod Inc Armor
US3871448A (en) * 1973-07-26 1975-03-18 Vann Tool Company Inc Packer actuated vent assembly
US3959094A (en) * 1975-03-13 1976-05-25 The United States Of America As Represented By The United States Energy Research And Development Administration Electrolytic synthesis of methanol from CO2
US4021021A (en) * 1976-04-20 1977-05-03 Us Energy Wetter for fine dry powder
US4146654A (en) * 1967-10-11 1979-03-27 Centre National De La Recherche Scientifique Process for making linings for friction operated apparatus
US4189925A (en) * 1978-05-08 1980-02-26 Northern Illinois Gas Company Method of storing electric power
US4253917A (en) * 1979-08-24 1981-03-03 Kennecott Copper Corporation Method for the production of copper-boron carbide composite
US4260649A (en) * 1979-05-07 1981-04-07 The Perkin-Elmer Corporation Laser induced dissociative chemical gas phase processing of workpieces
US4315874A (en) * 1979-04-11 1982-02-16 Mitsui Petrochemical Industries Ltd. Process for the production of spherical carrier particles for olefin polymerization catalysts
US4326492A (en) * 1980-04-07 1982-04-27 Runfree Enterprise, Inc. Method and apparatus for preheating fuel
US4369167A (en) * 1972-03-24 1983-01-18 Weir Jr Alexander Process for treating stack gases
US4436075A (en) * 1982-01-07 1984-03-13 Daniel D. Bailey Fuel pre-heat device
US4440733A (en) * 1980-11-06 1984-04-03 California Institute Of Technology Thermochemical generation of hydrogen and carbon dioxide
US4458138A (en) * 1980-12-15 1984-07-03 Adrian Glenn J Fast recovery electric fluid
US4523981A (en) * 1984-03-27 1985-06-18 Texaco Inc. Means and method for reducing carbon dioxide to provide a product
US4723589A (en) * 1986-05-19 1988-02-09 Westinghouse Electric Corp. Method for making vacuum interrupter contacts by spray deposition
US4921586A (en) * 1989-03-31 1990-05-01 United Technologies Corporation Electrolysis cell and method of use
US5006163A (en) * 1985-03-13 1991-04-09 Inco Alloys International, Inc. Turbine blade superalloy II
US5015863A (en) * 1989-05-31 1991-05-14 Sumitomo Heavy Industries, Ltd. Radiation shield and shielding material with excellent heat-transferring property
US5192130A (en) * 1990-03-06 1993-03-09 Konica Corporation Method for producing an emulsion and an apparatus therefor
US5486675A (en) * 1991-02-22 1996-01-23 Idaho Research Foundation Plasma production of ultra-fine ceramic carbides
US5596973A (en) * 1995-06-05 1997-01-28 Grice; Franklin R. Fuel expander
US5714644A (en) * 1994-07-06 1998-02-03 Basf Aktiengesellschaft Process and catalyst for the selective hydrogenation of butynediol to butenediol
US5723187A (en) * 1996-06-21 1998-03-03 Ford Global Technologies, Inc. Method of bonding thermally sprayed coating to non-roughened aluminum surfaces
US5723027A (en) * 1994-09-07 1998-03-03 W.C. Heraeus Gmbh Method for preparing a powder in a plasma arc and device for carrying out said method
US5733662A (en) * 1994-09-26 1998-03-31 Plas Plasma, Ltd. Method for depositing a coating onto a substrate by means of thermal spraying and an apparatus for carrying out said method
US5858470A (en) * 1994-12-09 1999-01-12 Northwestern University Small particle plasma spray apparatus, method and coated article
US5884473A (en) * 1995-06-23 1999-03-23 Ngk Insulators, Ltd. System for exhaust gas purification and method for exhaust gas purification using said system
US6012647A (en) * 1997-12-01 2000-01-11 3M Innovative Properties Company Apparatus and method of atomizing and vaporizing
US6045765A (en) * 1996-02-08 2000-04-04 Sakai Chemical Industry Co., Ltd. Catalyst and method for catalytic reduction of nitrogen oxides
US6066587A (en) * 1996-09-26 2000-05-23 Mazda Motor Corporation Catalyst for purifying exhaust gas
US6168694B1 (en) * 1999-02-04 2001-01-02 Chemat Technology, Inc. Methods for and products of processing nanostructure nitride, carbonitride and oxycarbonitride electrode power materials by utilizing sol gel technology for supercapacitor applications
US6190627B1 (en) * 1999-11-30 2001-02-20 Engelhard Corporation Method and device for cleaning the atmosphere
US20010004009A1 (en) * 1999-01-25 2001-06-21 Mackelvie Winston Drainwater heat recovery system
US20020018815A1 (en) * 1992-03-06 2002-02-14 Sievers Robert E. Methods and apparatus for fine particle formation
US6362449B1 (en) * 1998-08-12 2002-03-26 Massachusetts Institute Of Technology Very high power microwave-induced plasma
US6506995B1 (en) * 2001-06-21 2003-01-14 General Electric Company Conforming welding torch shroud
US20030036786A1 (en) * 2000-04-10 2003-02-20 Duren Albert Philip Van System, combination and method for controlling airflow in convective treatment
US20030047617A1 (en) * 2000-06-30 2003-03-13 Subramaniam Shanmugham Method of pepositing materials
US6562304B1 (en) * 1997-10-22 2003-05-13 Clue As Scrubber for the treatment of flue gases
US20040044513A1 (en) * 2002-09-02 2004-03-04 Noriaki Kitahara Distributed simulation system
US6706660B2 (en) * 2001-12-18 2004-03-16 Caterpillar Inc Metal/metal oxide doped oxide catalysts having high deNOx selectivity for lean NOx exhaust aftertreatment systems
US20040077494A1 (en) * 2002-10-22 2004-04-22 Labarge William J. Method for depositing particles onto a catalytic support
US20050000321A1 (en) * 2003-07-02 2005-01-06 O'larey Philip M. Method for producing metal fibers
US6841509B1 (en) * 2003-07-21 2005-01-11 Industrial Technology Research Institute Carbon nanocapsule supported catalysts
US6855410B2 (en) * 1992-07-14 2005-02-15 Theresa M. Buckley Phase change material thermal capacitor clothing
US6858170B2 (en) * 1994-02-24 2005-02-22 Atofina Research Silica-alumina catalyst carriers preparation
US20050070431A1 (en) * 2003-09-26 2005-03-31 Siemens Westinghouse Power Corporation Catalytic combustors
US20050066805A1 (en) * 2003-09-17 2005-03-31 Park Andrew D. Hard armor composite
US20050077034A1 (en) * 2003-10-14 2005-04-14 King Leonard Tony Static mixer-heat exchanger
US6891319B2 (en) * 2001-08-29 2005-05-10 Motorola, Inc. Field emission display and methods of forming a field emission display
US20050097988A1 (en) * 1997-02-24 2005-05-12 Cabot Corporation Coated nickel-containing powders, methods and apparatus for producing such powders and devices fabricated from same
US20050106865A1 (en) * 2001-09-26 2005-05-19 Applied Materials, Inc. Integration of ALD tantalum nitride for copper metallization
US20070049484A1 (en) * 2005-02-24 2007-03-01 Kear Bernard H Nanocomposite ceramics and process for making the same
US20070084834A1 (en) * 2005-09-30 2007-04-19 Hanus Gary J Plasma torch with corrosive protected collimator
US20080006954A1 (en) * 2004-09-07 2008-01-10 Kazuhiro Yubuta Process and Apparatus for Producing Fine Particles
US20080026041A1 (en) * 2005-09-12 2008-01-31 Argonide Corporation Non-woven media incorporating ultrafine or nanosize powders
US20080045405A1 (en) * 2006-06-09 2008-02-21 Tilman Wolfram Beutel Pt-Pd diesel oxidation catalyst with CO/HC light-off and HC storage function
US20080047261A1 (en) * 2006-08-28 2008-02-28 Heesung Catalysts Corporation Three-layered catalyst system for purifying exhaust gases of internal engines
US20080057212A1 (en) * 2006-08-30 2008-03-06 Sulzer Metco Ag Plasma spraying device and a method for introducing a liquid precursor into a plasma gas stream
US20080104735A1 (en) * 2006-05-01 2008-05-08 Warwick Mills, Inc. Mosaic extremity protection system with transportable solid elements
US20080125313A1 (en) * 2006-11-27 2008-05-29 Fujdala Kyle L Engine Exhaust Catalysts Containing Palladium-Gold
US20080125308A1 (en) * 2006-11-27 2008-05-29 Fujdala Kyle L Engine Exhaust Catalysts Containing Palladium-Gold
US20090054230A1 (en) * 2007-08-20 2009-02-26 Badri Veeraraghavan Catalyst production process
US20090092887A1 (en) * 2007-10-05 2009-04-09 Quantumsphere, Inc. Nanoparticle coated electrode and method of manufacture
US7517826B2 (en) * 2006-11-27 2009-04-14 Nanostellar, Inc. Engine exhaust catalysts containing zeolite and zeolite mixtures
US20090098402A1 (en) * 2007-10-10 2009-04-16 Jeung-Ku Kang Nanocrater catalyst in metal nanoparticles and method for preparing the same
US7674744B2 (en) * 2004-03-31 2010-03-09 Nissan Motor Co., Ltd. Catalyst powder, method of producing the catalyst powder, and exhaust gas purifying catalyst
US7678419B2 (en) * 2007-05-11 2010-03-16 Sdc Materials, Inc. Formation of catalytic regions within porous structures using supercritical phase processing
US20100092358A1 (en) * 2006-08-19 2010-04-15 Umicore Ag & Co.Kg Catalytically coated diesel particle filter, process for producing it and its use
US20100089002A1 (en) * 2008-10-15 2010-04-15 Merkel Composite Technologies, Inc. Composite structural elements and method of making same
US7704369B2 (en) * 2007-07-13 2010-04-27 University Of Southern California Electrolysis of carbon dioxide in aqueous media to carbon monoxide and hydrogen for production of methanol
US7709414B2 (en) * 2006-11-27 2010-05-04 Nanostellar, Inc. Engine exhaust catalysts containing palladium-gold
US7709411B2 (en) * 2004-11-17 2010-05-04 Headwaters Technology Innovation, Llc Method of manufacturing multicomponent nanoparticles
US20100124514A1 (en) * 2006-09-14 2010-05-20 The Timken Company Method of producing uniform blends of nano and micron powders
US20110052467A1 (en) * 2008-03-20 2011-03-03 University Of Akron Ceramic nanofibers containing nanosize metal catalyst particles and medium thereof
US7902104B2 (en) * 2004-06-23 2011-03-08 Arkema France Divided solid composition composed of grains provided with continuous metal deposition, method for the production and use thereof in the form of a catalyst
US7935655B2 (en) * 2005-11-04 2011-05-03 Kent State University Nanostructured core-shell electrocatalysts for fuel cells
US8089495B2 (en) * 2001-04-06 2012-01-03 T-Mobile Deutschland Gmbh Method for the display of standardized large-format internet pages with for example HTML protocol on hand-held devices with a mobile radio connection
US20120023909A1 (en) * 2011-08-17 2012-02-02 Ford Global Technologies, Llc Methods and systems for an engine emission control system
US20120097033A1 (en) * 2009-02-26 2012-04-26 Johnson Matthey Public Limited Company Filter for filtering particulate matter from exhaust gas emitted from a compression ignition engine
US8168561B2 (en) * 2008-07-31 2012-05-01 University Of Utah Research Foundation Core shell catalyst
US8173572B2 (en) * 2004-06-21 2012-05-08 Johnson Matthey Plc Metal oxide sols
US20120122660A1 (en) * 2010-02-01 2012-05-17 Johnson Matthey Public Limited Company Oxidation catalyst
US20120124974A1 (en) * 2010-11-24 2012-05-24 Basf Corporation Advanced Catalyzed Soot Filters And Method Of Making And Using The Same
US8349761B2 (en) * 2010-07-27 2013-01-08 Toyota Motor Engineering & Manufacturing North America, Inc. Dual-oxide sinter resistant catalyst
US20140018230A1 (en) * 2009-12-15 2014-01-16 SDCmaterials, Inc. Method of forming a catalyst with inhibited mobility of nano-active material

Family Cites Families (616)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US657267A (en) * 1900-06-05 1900-09-04 Morris Epstein Match-box.
US1477664A (en) 1920-10-21 1923-12-18 Harry D Rankin Process of and apparatus for treating materials
US2021936A (en) 1930-12-08 1935-11-26 Univ Illinois Removal of so2 from flue gases
US2284554A (en) 1940-08-03 1942-05-26 Standard Oil Dev Co Condensation catalysts of increased activity and process of producing the same
US2519531A (en) 1945-07-21 1950-08-22 Lummus Co Ejector apparatus
US2562753A (en) 1948-05-24 1951-07-31 Micronizer Company Anvil grinder
US2689780A (en) * 1948-12-27 1954-09-21 Hall Lab Inc Method of and apparatus for producing ammonium phosphate
US3067025A (en) 1957-04-05 1962-12-04 Dow Chemical Co Continuous production of titanium sponge
US3042511A (en) 1959-02-09 1962-07-03 Dow Chemical Co Apparatus for condensation of a metal vapor
US3108006A (en) 1959-07-13 1963-10-22 M & T Chemicals Inc Plating on aluminum
US3001402A (en) 1959-08-06 1961-09-26 Koblin Abraham Vapor and aerosol sampler
US3145287A (en) 1961-07-14 1964-08-18 Metco Inc Plasma flame generator and spray gun
US3179782A (en) 1962-02-07 1965-04-20 Matvay Leo Plasma flame jet spray gun with a controlled arc region
US3178121A (en) 1962-04-24 1965-04-13 Du Pont Process for comminuting grit in pigments and supersonic fluid energy mill therefor
DE1571153A1 (en) 1962-08-25 1970-08-13 Siemens Ag Plasma spray gun
NL299680A (en) 1962-10-26
US3309873A (en) 1964-08-31 1967-03-21 Electro Optical Systems Inc Plasma accelerator using hall currents
JPS4931571B1 (en) 1966-02-21 1974-08-22
US3520656A (en) 1966-03-30 1970-07-14 Du Pont Silicon carbide compositions
US3313908A (en) * 1966-08-18 1967-04-11 Giannini Scient Corp Electrical plasma-torch apparatus and method for applying coatings onto substrates
US3450926A (en) * 1966-10-10 1969-06-17 Air Reduction Plasma torch
US3401465A (en) * 1966-12-23 1968-09-17 Nat Lead Co Means for cooling solid particulate materials with fluids
US3457788A (en) * 1966-12-29 1969-07-29 Continental Carbon Co Apparatus for sampling carbon black
US3460523A (en) 1967-08-28 1969-08-12 Du Pont Catalytic oven coating compositions
US3617358A (en) 1967-09-29 1971-11-02 Metco Inc Flame spray powder and process
US3537513A (en) 1968-03-11 1970-11-03 Garrett Corp Three-fluid heat exchanger
JPS4721256Y1 (en) 1968-12-13 1972-07-14
GB1307941A (en) 1969-02-13 1973-02-21 Shinku Yakin Kk Method and an apparatus for manufacturing fine powders of metal or alloy
US3857744A (en) 1970-01-19 1974-12-31 Coors Porcelain Co Method for manufacturing composite articles containing boron carbide
US3589351A (en) 1970-03-16 1971-06-29 Westinghouse Electric Corp Cutting of rocks, glass and the like
US3743708A (en) 1970-11-20 1973-07-03 American Cyanamid Co Submicron metal oxide particles and their process for manufacture
US3761360A (en) 1971-01-20 1973-09-25 Allied Chem Re entrainment charging of preheated coal into coking chambers of a coke oven battery
US3676638A (en) 1971-01-25 1972-07-11 Sealectro Corp Plasma spray device and method
JPS4721256U (en) * 1971-02-27 1972-11-09
US3914573A (en) 1971-05-17 1975-10-21 Geotel Inc Coating heat softened particles by projection in a plasma stream of Mach 1 to Mach 3 velocity
US3752172A (en) * 1971-06-14 1973-08-14 United Aircraft Corp Jet penetration control
US3730827A (en) 1971-11-22 1973-05-01 Norton Research Corp Ltd Boron carbide ballistic armor modified with copper
US3774442A (en) 1972-01-05 1973-11-27 Bahco Ab Particle sampling devices
US3741001A (en) 1972-03-20 1973-06-26 Nasa Apparatus for sampling particulates in gases
US3959420A (en) 1972-05-23 1976-05-25 Stone & Webster Engineering Corporation Direct quench apparatus
JPS4931571A (en) 1972-07-24 1974-03-22
US3830756A (en) 1972-08-04 1974-08-20 Grace W R & Co Noble metal catalysts
JPS4987821A (en) * 1972-12-28 1974-08-22
US3892882A (en) 1973-05-25 1975-07-01 Union Carbide Corp Process for plasma flame spray coating in a sub-atmospheric pressure environment
JPS517582Y1 (en) * 1973-06-14 1976-03-01
SU493241A1 (en) 1973-07-02 1975-11-28 Московский Ордена Ленина И Ордена Трудового Красного Знамени Химикотехнологический Институт Им.Д.И.Менделеева Ammonia synthesis catalyst
FR2245779B1 (en) 1973-09-28 1978-02-10 Cit Alcatel
US3969482A (en) 1974-04-25 1976-07-13 Teller Environmental Systems, Inc. Abatement of high concentrations of acid gas emissions
JPS543391B2 (en) 1974-05-07 1979-02-22
JPS5626158Y2 (en) 1974-07-05 1981-06-20
US4127760A (en) * 1975-06-09 1978-11-28 Geotel, Inc. Electrical plasma jet torch and electrode therefor
MX4509E (en) 1975-08-27 1982-06-02 Engelhard Min & Chem IMPROVED CATALYTIC COMPOSITION FOR SIMULTANEOUS OXIDATION GASCOUS HYDROCARBONS AND CARBON MONOXIDE AND REDUCE NITROGEN OXIDES
US4018388A (en) 1976-05-13 1977-04-19 Andrews Norwood H Jet-type axial pulverizer
JPS52165360U (en) * 1976-06-07 1977-12-14
US4252843A (en) 1977-02-18 1981-02-24 Minnesota Mining And Manufacturing Company Process for forming a microstructured transmission and reflectance modifying coating
US4139497A (en) * 1977-04-04 1979-02-13 The Dow Chemical Company Dehydrogenation catalyst tablet and method for making same
US4284609A (en) 1977-07-11 1981-08-18 Quad Environmental Technologies Corp. Condensation cleaning of particulate laden gases
US4335080A (en) 1977-08-01 1982-06-15 Thermo Electron Corporation Apparatus for producing selective particle sized oxide
US4171288A (en) 1977-09-23 1979-10-16 Engelhard Minerals & Chemicals Corporation Catalyst compositions and the method of manufacturing them
US4174298A (en) 1978-01-09 1979-11-13 Uop Inc. Activated multimetallic catalytic composite
US4227928A (en) 1978-05-01 1980-10-14 Kennecott Copper Corporation Copper-boron carbide composite particle and method for its production
US4248387A (en) 1979-05-09 1981-02-03 Norandy, Inc. Method and apparatus for comminuting material in a re-entrant circulating stream mill
US4459327A (en) 1979-08-24 1984-07-10 Kennecott Corporation Method for the production of copper-boron carbide composite
USRE32244E (en) 1979-10-30 1986-09-09 Armotek Industries, Inc. Methods and apparatus for applying wear resistant coatings to rotogravure cylinders
JPS56146804U (en) 1980-04-04 1981-11-05
JPS56146804A (en) 1980-04-10 1981-11-14 Kobe Steel Ltd Gas atomizer for molten metal
US4388274A (en) * 1980-06-02 1983-06-14 Xerox Corporation Ozone collection and filtration system
US4344779A (en) 1980-08-27 1982-08-17 Isserlis Morris D Air pollution control system
JPS58160794A (en) 1982-03-17 1983-09-24 Matsushita Electric Ind Co Ltd Heat exchanger
US4513149A (en) 1982-04-05 1985-04-23 Olin Corporation Raney nickel alloy expanded mesh hydrogenation catalysts
US4419331A (en) 1982-04-12 1983-12-06 Michael F. Walters Sulphur dioxide converter and pollution arrester system
US4431750A (en) 1982-05-19 1984-02-14 Phillips Petroleum Company Platinum group metal catalyst on the surface of a support and a process for preparing same
JPS5959410A (en) * 1982-09-30 1984-04-05 Toshiba Corp Spheroidizing device of thermoplastic grain
US4506136A (en) 1982-10-12 1985-03-19 Metco, Inc. Plasma spray gun having a gas vortex producing nozzle
FR2545007B1 (en) 1983-04-29 1986-12-26 Commissariat Energie Atomique METHOD AND DEVICE FOR COATING A WORKPIECE BY PLASMA SPRAYING
JPS59227765A (en) 1983-06-04 1984-12-21 科学技術庁金属材料技術研究所長 Manufacture of ceramic super fine particle
FR2550467B1 (en) 1983-08-08 1989-08-04 Aerospatiale METHOD AND DEVICE FOR INJECTING A FINELY DIVIDED MATERIAL INTO A HOT GAS FLOW AND APPARATUS USING THE SAME
SE461095B (en) 1983-09-09 1990-01-08 Berol Kemi Ab AMINING PROCEDURE USING A RUTENIUM DOPPED NICKEL AND / OR COVOLT CATALYST
JPS60111890A (en) * 1983-11-22 1985-06-18 Mitsubishi Electric Corp Meandering double tube type heat exchanger
JPS60175537A (en) 1984-02-22 1985-09-09 Toyota Motor Corp Preparation of ultra-fine ceramic particles
US4545872A (en) 1984-03-27 1985-10-08 Texaco Inc. Method for reducing carbon dioxide to provide a product
US4665296A (en) 1984-04-28 1987-05-12 Neturen Co., Ltd. Method of and apparatus for igniting a high-frequency torch to create a high-temperature plasma of high purity
JPS6186815A (en) 1984-10-05 1986-05-02 Hitachi Ltd Minute pressure controller
DE3445273A1 (en) * 1984-12-12 1986-06-19 Wilfried 8672 Selb Müller Heat exchanger
US4824624A (en) * 1984-12-17 1989-04-25 Ceradyne, Inc. Method of manufacturing boron carbide armor tiles
JPS61242644A (en) 1985-04-18 1986-10-28 Toyota Motor Corp Production of catalyst for purifying exhaust gas
US4764283A (en) * 1985-04-24 1988-08-16 Ashbrook Clifford L Method and apparatus for treating cooling tower water
JPS62102827A (en) 1985-10-29 1987-05-13 Natl Res Inst For Metals Production of metallic or ceramic fine grain
DE3538390A1 (en) 1985-10-29 1987-04-30 Deutsche Forsch Luft Raumfahrt COATING FOR A SUBSTRATE AND METHOD FOR THE PRODUCTION THEREOF
US4609441A (en) 1985-12-18 1986-09-02 Gas Research Institute Electrochemical reduction of aqueous carbon dioxide to methanol
US4751021A (en) 1985-12-30 1988-06-14 Aar Corporation Bendable sheet material
DE3603511A1 (en) 1986-02-05 1987-08-06 Standard Elektrik Lorenz Ag METHOD AND DEVICE FOR REMOVING DUST AND GASEOUS POLLUTANTS FROM EXHAUST GAS, ESPECIALLY EXHAUST GASES IN THE LIGHTWAVE LEAD PREFORMING
NL8600449A (en) 1986-02-22 1987-09-16 Delft Tech Hogeschool ARMOR PLATE-COMPOSITE WITH CERAMIC COLLECTION COAT.
US4731517A (en) 1986-03-13 1988-03-15 Cheney Richard F Powder atomizing methods and apparatus
US4885038A (en) 1986-05-01 1989-12-05 International Business Machines Corporation Method of making multilayered ceramic structures having an internal distribution of copper-based conductors
US4780591A (en) 1986-06-13 1988-10-25 The Perkin-Elmer Corporation Plasma gun with adjustable cathode
US4801435A (en) 1986-09-08 1989-01-31 Plasma Holdings N.V. Hybrid plasma reactor
US4982050A (en) 1986-10-06 1991-01-01 Mobil Oil Corporation Natural gas treating system including mercury trap
JPH0720553B2 (en) 1986-11-07 1995-03-08 軽質留分新用途開発技術研究組合 Method for producing platinum-supported catalyst
DE3642375A1 (en) 1986-12-11 1988-06-23 Castolin Sa METHOD FOR APPLYING AN INTERNAL COATING INTO TUBES OD. DGL. CAVITY NARROW CROSS SECTION AND PLASMA SPLASH BURNER DAFUER
JPS63214342A (en) 1987-03-02 1988-09-07 Natl Res Inst For Metals Preparation of compound
US5269848A (en) 1987-03-20 1993-12-14 Canon Kabushiki Kaisha Process for preparing a functional thin film by way of the chemical reaction among active species and apparatus therefor
US4983555A (en) 1987-05-06 1991-01-08 Coors Porcelain Company Application of transparent polycrystalline body with high ultraviolet transmittance
US20020102674A1 (en) 1987-05-20 2002-08-01 David M Anderson Stabilized microporous materials
US4868013A (en) * 1987-08-21 1989-09-19 Ethyl Corporation Fluidized bed process
US5230844A (en) 1987-09-04 1993-07-27 Skis Rossignol, S.A. Process for producing a complex elastic molded structure of the sandwich type
DE3740289A1 (en) 1987-11-27 1989-06-08 Degussa CATALYST FOR THE SELECTIVE REDUCTION OF NITROGEN OXIDES WITH AMMONIA
JP2584805B2 (en) 1987-12-19 1997-02-26 富士通株式会社 Method for synthesizing diamond particles
US4869936A (en) 1987-12-28 1989-09-26 Amoco Corporation Apparatus and process for producing high density thermal spray coatings
JPH01275708A (en) 1988-04-28 1989-11-06 Natl Res Inst For Metals Production of composite superfine particles with joined structure of superfine particles of nickel and titanium nitride
US5041713A (en) 1988-05-13 1991-08-20 Marinelon, Inc. Apparatus and method for applying plasma flame sprayed polymers
CH676681A5 (en) * 1988-06-13 1991-02-28 Battelle Memorial Institute
JP2662986B2 (en) 1988-06-24 1997-10-15 高周波熱錬株式会社 Method for producing ultrafine tungsten or tungsten oxide particles
US4866240A (en) 1988-09-08 1989-09-12 Stoody Deloro Stellite, Inc. Nozzle for plasma torch and method for introducing powder into the plasma plume of a plasma torch
JPH02160040A (en) 1988-12-15 1990-06-20 Mitsubishi Heavy Ind Ltd Production of superfine particle of mineral matter
US4987033A (en) 1988-12-20 1991-01-22 Dynamet Technology, Inc. Impact resistant clad composite armor and method for forming such armor
US5371049A (en) 1989-01-09 1994-12-06 Fmc Corporation Ceramic composite of silicon carbide and aluminum nitride
US5562966A (en) 1989-01-27 1996-10-08 Science Applications International Corporation Method of applying oxidation resistant coating on carbon fibers
JPH02203932A (en) 1989-01-31 1990-08-13 Idemitsu Petrochem Co Ltd Method and apparatus for producing ultrafine particles
US5043548A (en) 1989-02-08 1991-08-27 General Electric Company Axial flow laser plasma spraying
JP2578514B2 (en) 1989-03-03 1997-02-05 三井石油化学工業株式会社 Method for removing mercury from liquid hydrocarbon compounds
US4902870A (en) 1989-03-31 1990-02-20 General Electric Company Apparatus and method for transfer arc cleaning of a substrate in an RF plasma system
WO1990012126A1 (en) 1989-03-31 1990-10-18 Canon Kabushiki Kaisha Method of forming polycrystalline film by chemical vapor deposition
US5070064A (en) 1989-08-07 1991-12-03 Exxon Research And Engineering Company Catalyst pretreatment method
US5187140A (en) 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
JPH03150341A (en) 1989-11-07 1991-06-26 Onoda Cement Co Ltd Conjugate torch type plasma generator and plasma generating method using the same
DE3940758A1 (en) 1989-12-09 1991-06-13 Degussa METHOD FOR PURIFYING THE EXHAUST GAS FROM DIESEL ENGINES
JPH03226509A (en) 1990-01-31 1991-10-07 Sumitomo Metal Ind Ltd Apparatus for generating plasma and manufacture of super fine particle powder
DE4109979C2 (en) 1990-03-28 2000-03-30 Nisshin Flour Milling Co Process for the production of coated particles from inorganic or metallic materials
JPH0665772B2 (en) 1990-03-31 1994-08-24 株式会社スリーデイコンポリサーチ Method and device for manufacturing three-dimensional fabric
US5013883A (en) 1990-05-18 1991-05-07 The Perkin-Elmer Corporation Plasma spray device with external powder feed
EP0586756B1 (en) 1990-05-29 2002-04-17 Sulzer Metco AG Plasma systems for thermal spraying of powders
US5225656A (en) 1990-06-20 1993-07-06 General Electric Company Injection tube for powder melting apparatus
US5073193A (en) * 1990-06-26 1991-12-17 The University Of British Columbia Method of collecting plasma synthesize ceramic powders
US5296667A (en) 1990-08-31 1994-03-22 Flame-Spray Industries, Inc. High velocity electric-arc spray apparatus and method of forming materials
WO1992005902A1 (en) 1990-10-09 1992-04-16 Iowa State University Research Foundation, Inc. Environmentally stable reactive alloy powders and method of making same
US5217746A (en) 1990-12-13 1993-06-08 Fisher-Barton Inc. Method for minimizing decarburization and other high temperature oxygen reactions in a plasma sprayed material
JPH06135797A (en) 1991-01-24 1994-05-17 Idemitsu Petrochem Co Ltd Method and device for synthesizing diamond
US5133190A (en) 1991-01-25 1992-07-28 Abdelmalek Fawzy T Method and apparatus for flue gas cleaning by separation and liquefaction of sulfur dioxide and carbon dioxide
DE4105408C1 (en) 1991-02-21 1992-09-17 Plasma-Technik Ag, Wohlen, Ch
US5330945A (en) 1991-04-08 1994-07-19 General Motors Corporation Catalyst for treatment of diesel exhaust particulate
US5164945A (en) 1991-07-01 1992-11-17 Laser Centers Of America, Inc. Laser device with intermediate refraction index layer for reduced fresnel losses
JP3200464B2 (en) 1991-08-27 2001-08-20 株式会社エステック Liquid material vaporizer
DE69221047T2 (en) 1991-09-13 1998-02-26 Tsuyoshi Masumoto Construction element with high strength and method of its production
US5294242A (en) 1991-09-30 1994-03-15 Air Products And Chemicals Method for making metal powders
JP3100084B2 (en) 1991-11-25 2000-10-16 日清製粉株式会社 Ultrafine particle manufacturing equipment
DK201791D0 (en) 1991-12-17 1991-12-17 Boerge Holm Christensen METHOD OF COATING
JP2673978B2 (en) 1991-12-26 1997-11-05 大平洋金属 株式会社 Ultrafine particle manufacturing method and manufacturing apparatus
US5233153A (en) 1992-01-10 1993-08-03 Edo Corporation Method of plasma spraying of polymer compositions onto a target surface
JP3229353B2 (en) 1992-01-21 2001-11-19 トヨタ自動車株式会社 Method for producing metal oxide powder
US5280757A (en) 1992-04-13 1994-01-25 Carter George W Municipal solid waste disposal process
JPH0665772U (en) * 1992-05-11 1994-09-16 田村 悦夫 Exhaust heat utilization type road heating device
JPH05324094A (en) 1992-05-15 1993-12-07 Tlv Co Ltd Liquid pressure controller
JP3285614B2 (en) 1992-07-30 2002-05-27 日本碍子株式会社 Exhaust gas purification catalyst and method for producing the same
US5260241A (en) 1992-08-12 1993-11-09 Corning Incorporated Controlled pore size phosphate-alumina material and method for producing same
JPH0665772A (en) 1992-08-19 1994-03-08 Mitsubishi Kasei Corp Method for cleaning oil sticking material therefor
JP2863675B2 (en) 1992-09-01 1999-03-03 井上 明久 Manufacturing method of particle reinforced composite material
US5804155A (en) 1992-11-19 1998-09-08 Engelhard Corporation Basic zeolites as hydrocarbon traps for diesel oxidation catalysts
US5338716A (en) 1992-12-01 1994-08-16 Akzo Nobel Nv Non-oxide metal ceramic catalysts comprising metal oxide support and intermediate ceramic passivating layer
DE4240991A1 (en) 1992-12-05 1994-06-09 Plasma Technik Ag Plasma spray gun
JP3254278B2 (en) 1992-12-09 2002-02-04 高周波熱錬株式会社 Method for producing mixed / composite ultrafine particles and apparatus for producing the same
FR2699408B1 (en) 1992-12-21 1995-03-24 Bioland Method for treating bone tissue and corresponding implantable biomaterials.
GB9302387D0 (en) 1993-02-06 1993-03-24 Osprey Metals Ltd Production of powder
JPH06272012A (en) 1993-03-19 1994-09-27 Hirofumi Shimura Formation of high functional coating film by laser-plasma hybrid thermal spraying
JPH08506901A (en) 1993-06-10 1996-07-23 ラプレット アンド パタシュニック カンパニー,インコーポレーテッド Airborne particle sampling monitoring device
JP2751136B2 (en) 1993-07-21 1998-05-18 科学技術庁無機材質研究所長 Method for producing self-grading composite particles
US5460701A (en) 1993-07-27 1995-10-24 Nanophase Technologies Corporation Method of making nanostructured materials
US5444209A (en) 1993-08-11 1995-08-22 Miller Thermal, Inc. Dimensionally stable subsonic plasma arc spray gun with long wearing electrodes
US5543173A (en) 1993-10-12 1996-08-06 Aluminum Company Of America Surface treating aluminum trihydrate powders with prehydrolized silane
US5408066A (en) 1993-10-13 1995-04-18 Trapani; Richard D. Powder injection apparatus for a plasma spray gun
CA2118081C (en) 1993-10-14 2006-10-03 Jacobus Swanepoel Production of fluorocarbon compounds
JPH07120176A (en) 1993-10-28 1995-05-12 Toray Ind Inc Cooling apparatus
JPH07130490A (en) 1993-11-02 1995-05-19 Komatsu Ltd Plasma torch
JP3483282B2 (en) 1993-11-12 2004-01-06 高周波熱錬株式会社 Method for producing ultrafine titanium dioxide composite oxide
US5392797A (en) * 1994-03-10 1995-02-28 Vq Corporation Single motive pump, clean-in-place system, for use with piping systems and with vessels
JPH07256116A (en) 1994-03-25 1995-10-09 Calsonic Corp Metallic catalyst carrier of catalytic converter and production thereof
JPH07279648A (en) 1994-04-05 1995-10-27 Isao Yamamoto Exhaust emission control system
JPH07280469A (en) * 1994-04-14 1995-10-27 Suzuki Motor Corp Water-cooled oil cooler
DE4418931C2 (en) 1994-05-31 1997-06-19 Degussa Process for separating catalyst-free working solution from the hydrogenation cycle of the anthraquinone process for the production of hydrogen peroxide
DE4422588C2 (en) * 1994-06-28 1999-09-23 Ald Vacuum Techn Gmbh Process for quenching workpieces with gases and heat treatment system to carry out the process
US5492627A (en) 1994-06-29 1996-02-20 Minnesota Mining And Manufacturing Company Method for separating mercury from fluids using composite articles
US5485941A (en) * 1994-06-30 1996-01-23 Basf Corporation Recirculation system and method for automated dosing apparatus
US5679167A (en) 1994-08-18 1997-10-21 Sulzer Metco Ag Plasma gun apparatus for forming dense, uniform coatings on large substrates
US5985356A (en) 1994-10-18 1999-11-16 The Regents Of The University Of California Combinatorial synthesis of novel materials
US5582807A (en) 1994-11-04 1996-12-10 Tek-Kol Method and apparatus for removing particulate and gaseous pollutants from a gas stream
JPH08158033A (en) 1994-12-02 1996-06-18 Nisshin Steel Co Ltd Production of fine-structure thick film material and device therefor
US5534270A (en) 1995-02-09 1996-07-09 Nanosystems Llc Method of preparing stable drug nanoparticles
JPH08215576A (en) 1995-02-16 1996-08-27 Ykk Kk Composite superfine particle, its production and catalyst for synthesis and refining of methanol using the same
JP3645931B2 (en) 1995-02-16 2005-05-11 Ykk株式会社 Method for producing composite ultrafine particles
US5676912A (en) 1995-02-22 1997-10-14 Mobil Oil Corporation Process for exhaust gas NOx, CO, and hydrocarbon removal
US5749937A (en) 1995-03-14 1998-05-12 Lockheed Idaho Technologies Company Fast quench reactor and method
US7576296B2 (en) 1995-03-14 2009-08-18 Battelle Energy Alliance, Llc Thermal synthesis apparatus
DE19512615A1 (en) 1995-04-05 1996-10-10 Bayer Ag Supported catalysts containing platinum metal and process for the preparation of diaryl carbonates
US5510086A (en) 1995-04-10 1996-04-23 General Motors Corporation Adcat exhaust treatment device
US5793013A (en) 1995-06-07 1998-08-11 Physical Sciences, Inc. Microwave-driven plasma spraying apparatus and method for spraying
US5652304A (en) 1995-08-31 1997-07-29 The Goodyear Tire & Rubber Company Vapor phase synthesis of rubbery polymers
US5837959A (en) 1995-09-28 1998-11-17 Sulzer Metco (Us) Inc. Single cathode plasma gun with powder feed along central axis of exit barrel
JP3806847B2 (en) 1995-11-24 2006-08-09 イーシー化学株式会社 Powder processing method and apparatus using atmospheric pressure glow discharge plasma
CA2250962C (en) 1996-04-04 2003-06-03 Nanophase Technologies Corporation Siloxane star-graft polymers, ceramic powders coated therewith and method of preparing coated ceramic powders
US5726415A (en) 1996-04-16 1998-03-10 The Lincoln Electric Company Gas cooled plasma torch
JP3193294B2 (en) 1996-05-24 2001-07-30 財団法人ファインセラミックスセンター Composite ceramic powder, method for producing the same, electrode for solid oxide fuel cell, and method for producing the same
WO1998002241A1 (en) * 1996-07-11 1998-01-22 The University Of Cincinnati Electrically assisted synthesis of particles and films with precisely controlled characteristics
US6001426A (en) 1996-07-25 1999-12-14 Utron Inc. High velocity pulsed wire-arc spray
US5905000A (en) * 1996-09-03 1999-05-18 Nanomaterials Research Corporation Nanostructured ion conducting solid electrolytes
US6933331B2 (en) * 1998-05-22 2005-08-23 Nanoproducts Corporation Nanotechnology for drug delivery, contrast agents and biomedical implants
US5851507A (en) 1996-09-03 1998-12-22 Nanomaterials Research Corporation Integrated thermal process for the continuous synthesis of nanoscale powders
US6652967B2 (en) 2001-08-08 2003-11-25 Nanoproducts Corporation Nano-dispersed powders and methods for their manufacture
US6855749B1 (en) * 1996-09-03 2005-02-15 Nanoproducts Corporation Polymer nanocomposite implants with enhanced transparency and mechanical properties for administration within humans or animals
US6202471B1 (en) 1997-10-10 2001-03-20 Nanomaterials Research Corporation Low-cost multilaminate sensors
US6832735B2 (en) * 2002-01-03 2004-12-21 Nanoproducts Corporation Post-processed nanoscale powders and method for such post-processing
US6344271B1 (en) 1998-11-06 2002-02-05 Nanoenergy Corporation Materials and products using nanostructured non-stoichiometric substances
US5788738A (en) 1996-09-03 1998-08-04 Nanomaterials Research Corporation Method of producing nanoscale powders by quenching of vapors
US6569397B1 (en) 2000-02-15 2003-05-27 Tapesh Yadav Very high purity fine powders and methods to produce such powders
DE69728341T2 (en) 1996-10-07 2004-12-30 Kabushiki Kaisha Toyota Chuo Kenkyusho Compound oxide, composite oxide carrier and catalyst
JP3605969B2 (en) 1996-10-31 2004-12-22 石川島播磨重工業株式会社 Method of producing titanium oxide film for corrosion protection and titanium oxide film for corrosion protection
DE69733660T2 (en) 1996-11-04 2006-05-18 Materials Modification, Inc. MICROWAVE PLASMA CHEMICAL SYNTHESIS OF ULTRAFINE POWDER
US6117376A (en) 1996-12-09 2000-09-12 Merkel; Michael Method of making foam-filled composite products
US6322756B1 (en) 1996-12-31 2001-11-27 Advanced Technology And Materials, Inc. Effluent gas stream treatment system having utility for oxidation treatment of semiconductor manufacturing effluent gases
US6780350B1 (en) 1997-02-24 2004-08-24 Superior Micropowders Llc Metal-carbon composite powders, methods for producing powders and devices fabricated from same
US6683783B1 (en) 1997-03-07 2004-01-27 William Marsh Rice University Carbon fibers formed from single-wall carbon nanotubes
JPH10249198A (en) 1997-03-10 1998-09-22 Toyota Central Res & Dev Lab Inc Catalyst for purifying exhaust gas and production thereof
US5993967A (en) 1997-03-28 1999-11-30 Nanophase Technologies Corporation Siloxane star-graft polymers, ceramic powders coated therewith and method of preparing coated ceramic powders
US6093306A (en) 1997-04-07 2000-07-25 Solar Reactor Technologies Inc. Comprehensive system for utility load leveling, hydrogen production, stack gas cleanup, greenhouse gas abatement, and methanol synthesis
US5989648A (en) 1997-05-06 1999-11-23 The Penn State Research Foundation Plasma generation of supported metal catalysts
US6093378A (en) 1997-05-07 2000-07-25 Engelhard Corporation Four-way diesel exhaust catalyst and method of use
US5928806A (en) 1997-05-07 1999-07-27 Olah; George A. Recycling of carbon dioxide into methyl alcohol and related oxygenates for hydrocarbons
GB9711876D0 (en) * 1997-06-10 1997-08-06 Secr Defence Dispersion-strengthened aluminium alloy
US6213049B1 (en) 1997-06-26 2001-04-10 General Electric Company Nozzle-injector for arc plasma deposition apparatus
US6576906B1 (en) 1999-10-08 2003-06-10 Symyx Technologies, Inc. Method and apparatus for screening combinatorial libraries for semiconducting properties
ID24625A (en) 1997-08-08 2000-07-27 Abb Lummus Global Inc COMPOSITE PRODUCTION WITH PORIAL FIBER STRUCTURES
US20020068026A1 (en) * 1997-08-08 2002-06-06 Lawrence L. Murrell Reactor
DE19734910A1 (en) * 1997-08-12 1999-02-18 Windmoeller & Hoelscher Doctor device for a rinsing inking unit of a rotary printing machine
DE19734974A1 (en) 1997-08-13 1999-02-25 Hoechst Ag Production of supported catalyst for vinyl acetate production
JP3478468B2 (en) * 1997-08-25 2003-12-15 電気化学工業株式会社 Method and apparatus for producing inorganic spherical particles
US6482584B1 (en) 1998-11-13 2002-11-19 Regeneration Technologies, Inc. Cyclic implant perfusion cleaning and passivation process
US5984997A (en) 1997-08-29 1999-11-16 Nanomaterials Research Corporation Combustion of emulsions: A method and process for producing fine powders
US6514453B2 (en) 1997-10-21 2003-02-04 Nanoproducts Corporation Thermal sensors prepared from nanostructureed powders
GB9723762D0 (en) 1997-11-12 1998-01-07 Rolls Royce Plc A method of coating a component
DE19753738A1 (en) 1997-12-04 1999-06-10 Degussa Process for producing a catalyst
JP2001527189A (en) 1997-12-24 2001-12-25 エンゲルハード・コーポレーシヨン Catalytic converter for internal combustion engine powered vehicles
US6076597A (en) 1997-12-31 2000-06-20 Flowserve Management Company Helical coil heat exchanger with removable end plates
GB9803554D0 (en) 1998-02-20 1998-04-15 Johnson Matthey Plc Improvements in automotive catalysts
US7517606B2 (en) 1998-02-24 2009-04-14 Cabot Corporation Fuel cells and batteries including metal-carbon composite powders
US7138354B2 (en) 1998-02-24 2006-11-21 Cabot Corporation Method for the fabrication of an electrocatalyst layer
US6491423B1 (en) 1998-03-11 2002-12-10 Mc21, Incorporated Apparatus for mixing particles into a liquid medium
JPH11300198A (en) 1998-04-23 1999-11-02 Hitachi Plant Eng & Constr Co Ltd Method for controlling reaction temperature and supercritical water oxidizing device
US6084197A (en) 1998-06-11 2000-07-04 General Electric Company Powder-fan plasma torch
US6149864A (en) 1998-06-25 2000-11-21 Massachusetts Institute Of Technology Supercritical fluid sterilization method
US6524662B2 (en) 1998-07-10 2003-02-25 Jin Jang Method of crystallizing amorphous silicon layer and crystallizing apparatus thereof
US6416818B1 (en) 1998-08-17 2002-07-09 Nanophase Technologies Corporation Compositions for forming transparent conductive nanoparticle coatings and process of preparation therefor
US6379419B1 (en) * 1998-08-18 2002-04-30 Noranda Inc. Method and transferred arc plasma system for production of fine and ultrafine powders
US6576214B2 (en) 2000-12-08 2003-06-10 Hydrocarbon Technologies, Inc. Catalytic direct production of hydrogen peroxide from hydrogen and oxygen feeds
US6531704B2 (en) * 1998-09-14 2003-03-11 Nanoproducts Corporation Nanotechnology for engineering the performance of substances
US6267864B1 (en) 1998-09-14 2001-07-31 Nanomaterials Research Corporation Field assisted transformation of chemical and material compositions
US6214195B1 (en) * 1998-09-14 2001-04-10 Nanomaterials Research Corporation Method and device for transforming chemical compositions
US6576199B1 (en) 1998-09-18 2003-06-10 Alliedsignal Inc. Environmental control system including ozone-destroying catalytic converter having anodized and washcoat layers
DE19847161A1 (en) * 1998-10-14 2000-04-20 Degussa Fumed silica doped with aerosol
US6716525B1 (en) 1998-11-06 2004-04-06 Tapesh Yadav Nano-dispersed catalysts particles
US6395214B1 (en) * 1998-11-30 2002-05-28 Rutgers, The State University Of New Jersey High pressure and low temperature sintering of nanophase ceramic powders
US6139813A (en) 1998-12-18 2000-10-31 Ford Global Technologies, Inc. NOx trapping by metal-zirconia materials during lean-burn automotive engine operation
WO2000038831A1 (en) * 1998-12-31 2000-07-06 Hexablock, Inc. Magneto absorbent
JP2000220978A (en) 1999-01-27 2000-08-08 Mitsubishi Cable Ind Ltd Cooling storage heat exchanger
DE19908394A1 (en) 1999-02-26 2000-08-31 Degussa Catalyst material and process for its manufacture
DE19909168A1 (en) 1999-03-03 2000-09-07 Basf Ag Process for the production of amines
DE10010466A1 (en) 1999-03-05 2000-10-12 Sumitomo Chemical Co Acrylic resin film laminate for internal and external use is highly flexible and retains its transparency on dyeing, has a layer containing acrylic rubber particles in an acrylic resin and an acrylic resin-only layer
US6365016B1 (en) 1999-03-17 2002-04-02 General Electric Company Method and apparatus for arc plasma deposition with evaporation of reagents
US6413781B1 (en) 1999-04-06 2002-07-02 Massachusetts Institute Of Technology Thermophoretic pump and concentrator
BR0001560B1 (en) 1999-04-09 2010-04-06 process for producing a ceramic catalyst body and a ceramic catalyst body.
AU4237300A (en) 1999-04-19 2000-11-02 Engelhard Corporation Catalyst composition comprising ceria and a platinum group metal
WO2000072965A1 (en) 1999-05-27 2000-12-07 The Regents Of The University Of Michigan Zeolite catalysts for selective catalytic reduction of nitric oxide by ammonia and method of making
US6399030B1 (en) 1999-06-04 2002-06-04 The Babcock & Wilcox Company Combined flue gas desulfurization and carbon dioxide removal system
JP3940546B2 (en) 1999-06-07 2007-07-04 株式会社東芝 Pattern forming method and pattern forming material
AU4397899A (en) * 1999-06-15 2001-01-02 Yong Soo Kim An effective dry etching process of actinide oxides and their mixed oxides in CF4/O2/N2 plasma
CN1101335C (en) * 1999-06-16 2003-02-12 中国科学院金属研究所 Hydrogn arc discharging method for large scale prodn. of single wall nanometer carbon tube
US6468490B1 (en) 2000-06-29 2002-10-22 Applied Materials, Inc. Abatement of fluorine gas from effluent
US20070044513A1 (en) 1999-08-18 2007-03-01 Kear Bernard H Shrouded-plasma process and apparatus for the production of metastable nanostructured materials
US6972115B1 (en) 1999-09-03 2005-12-06 American Inter-Metallics, Inc. Apparatus and methods for the production of powders
US6452338B1 (en) 1999-12-13 2002-09-17 Semequip, Inc. Electron beam ion source with integral low-temperature vaporizer
MXPA02006446A (en) 1999-12-28 2002-11-29 Corning Inc Zeolitealumina catalyst support compositions and method of making the same.
EP1257376B1 (en) * 2000-02-10 2004-01-21 Tetronics Limited Plasma arc reactor for the production of fine powders
CA2399138C (en) * 2000-02-10 2009-12-01 South African Nuclear Energy Corporation Limited Treatment of fluorocarbon feedstocks
EP1134302A1 (en) 2000-03-17 2001-09-19 Consorzio Interuniversitario per lo Sviluppo dei Sistemi a Grande Interfase, C.S.G.I New process for the production of nanostructured solid powders and nano-particles films by compartimentalised solution thermal spraying (CSTS)
US7834349B2 (en) 2000-03-29 2010-11-16 Georgia Tech Research Corporation Silicon based nanospheres and nanowires
RU2267239C2 (en) 2000-04-10 2005-12-27 Тетроникс Лимитед Twin plasma burner
GB2358629B (en) * 2000-05-18 2001-12-19 Mark William Youds Formulae, methods and apparatus for the: treatment of; processing of; pasteurisation; dissociating water in; and the communication of: materials;
EP1287242A1 (en) 2000-06-01 2003-03-05 Blue Planet Co., Ltd Apparatus for removing soot and no x? in exhaust gas from diesel engines
DE10035679A1 (en) 2000-07-21 2002-01-31 Inst Neue Mat Gemein Gmbh Nanoscale corundum powder, sintered bodies made therefrom and process for their production
JP3908447B2 (en) 2000-08-11 2007-04-25 株式会社荏原製作所 Ejector
US6261484B1 (en) 2000-08-11 2001-07-17 The Regents Of The University Of California Method for producing ceramic particles and agglomerates
WO2002014854A1 (en) 2000-08-14 2002-02-21 Chevron U.S.A. Inc. Use of microchannel reactors in combinatorial chemistry
JP2002088486A (en) 2000-09-13 2002-03-27 Chubu Electric Power Co Inc High-frequency induction heat plasma apparatus
KR100814702B1 (en) 2000-09-28 2008-03-18 롬 앤드 하스 캄파니 Methods for producing unsaturated nitriles
EP1195196A1 (en) 2000-10-06 2002-04-10 Akzo Nobel N.V. Catalyst carrier comprising a fibre paper impregnated with micro fibres, process for its production and its uses
US6862970B2 (en) 2000-11-21 2005-03-08 M Cubed Technologies, Inc. Boron carbide composite bodies, and methods for making same
US6896958B1 (en) * 2000-11-29 2005-05-24 Nanophase Technologies Corporation Substantially transparent, abrasion-resistant films containing surface-treated nanocrystalline particles
US6491985B2 (en) 2000-12-20 2002-12-10 Honda Giken Kogyo Kabushiki Kaisha Method for enhancing the surface of a metal substrate
US6464919B2 (en) * 2000-12-22 2002-10-15 Husky Injection Molding Systems, Ltd. Device and method for temperature adjustment of an object
US7591957B2 (en) 2001-01-30 2009-09-22 Rapt Industries, Inc. Method for atmospheric pressure reactive atom plasma processing for surface modification
US6905555B2 (en) * 2001-02-15 2005-06-14 Micell Technologies, Inc. Methods for transferring supercritical fluids in microelectronic and other industrial processes
JP2002241812A (en) 2001-02-20 2002-08-28 Murata Mfg Co Ltd Method and equipment for manufacturing metallic ultrafine particle
JP2002263496A (en) 2001-03-13 2002-09-17 Honda Motor Co Ltd Catalyst composition, manufacturing method thereof and method of manufacturing carbon nanofiber
JP4677679B2 (en) 2001-03-27 2011-04-27 株式会社デンソー Characteristics adjustment method in product manufacturing process
US6444009B1 (en) * 2001-04-12 2002-09-03 Nanotek Instruments, Inc. Method for producing environmentally stable reactive alloy powders
WO2002085812A1 (en) 2001-04-20 2002-10-31 Sumitomo Electric Industries, Ltd. Silicon nitride based composite sintered product and method for production thereof
CA2443845A1 (en) 2001-04-23 2002-10-31 P. Lee Kang Enhancement of fluid replacement in porous media through pressure modulation
US6994837B2 (en) 2001-04-24 2006-02-07 Tekna Plasma Systems, Inc. Plasma synthesis of metal oxide nanopowder and apparatus therefor
US20020155059A1 (en) * 2001-04-24 2002-10-24 Tekna Plasma Systems Inc. Plasma synthesis of titanium dioxide nanopowder and powder doping and surface modification process
US6915964B2 (en) 2001-04-24 2005-07-12 Innovative Technology, Inc. System and process for solid-state deposition and consolidation of high velocity powder particles using thermal plastic deformation
DE10122491A1 (en) 2001-05-10 2002-11-14 Bayer Ag Device and method for carrying out experiments in parallel
US6652822B2 (en) 2001-05-17 2003-11-25 The Regents Of The University Of California Spherical boron nitride particles and method for preparing them
JP2002336688A (en) 2001-05-18 2002-11-26 Tdk Corp Method for treating powder, method for manufacturing inorganic powder and apparatus for treating object to be treated
US7622693B2 (en) 2001-07-16 2009-11-24 Foret Plasma Labs, Llc Plasma whirl reactor apparatus and methods of use
WO2003011784A2 (en) 2001-08-02 2003-02-13 3M Innovative Properties Company Ceramic materials, abrasive particles, abrasive articles, and methods of making and using the same
US6855426B2 (en) 2001-08-08 2005-02-15 Nanoproducts Corporation Methods for producing composite nanoparticles
US6596187B2 (en) 2001-08-29 2003-07-22 Motorola, Inc. Method of forming a nano-supported sponge catalyst on a substrate for nanotube growth
ATE301496T1 (en) 2001-08-31 2005-08-15 Apit Corp Sa METHOD AND DEVICE FOR PRODUCING POWDER FROM COMPOSITE MATERIAL
JP3543149B2 (en) 2001-09-03 2004-07-14 島津工業有限会社 Torch head for plasma spraying
KR100711687B1 (en) 2001-10-01 2007-05-02 엔테그리스, 아이엔씨. Apparatus for conditioning the temperature of a fluid
US6693253B2 (en) 2001-10-05 2004-02-17 Universite De Sherbrooke Multi-coil induction plasma torch for solid state power supply
CN1273113C (en) * 2001-10-10 2006-09-06 贝林格尔·英格海姆药物公司 Powder processing with pressurized gaseous fluids
US7008591B2 (en) * 2001-10-17 2006-03-07 Edwards Lifesciences Corporation Supercritical fluid extraction process for tissue preparation
JP2003126694A (en) 2001-10-25 2003-05-07 Toyota Motor Corp Catalyst for cleaning exhaust gas
WO2003040223A2 (en) * 2001-11-03 2003-05-15 Nanophase Technology Corporation Nanostructured compositions
JP3854134B2 (en) 2001-12-04 2006-12-06 本田技研工業株式会社 Exhaust gas purification device for internal combustion engine
JP2003170043A (en) 2001-12-10 2003-06-17 Toyota Motor Corp Exhaust gas treatment catalyst and production method of the same
US6623559B2 (en) * 2001-12-10 2003-09-23 Nanotek Instruments, Inc. Method for the production of semiconductor quantum particles
US20030108459A1 (en) * 2001-12-10 2003-06-12 L. W. Wu Nano powder production system
US6689192B1 (en) * 2001-12-13 2004-02-10 The Regents Of The University Of California Method for producing metallic nanoparticles
JP4356313B2 (en) 2001-12-19 2009-11-04 住友金属鉱山株式会社 Method for producing metal compound fine powder
US7119418B2 (en) 2001-12-31 2006-10-10 Advanced Technology Materials, Inc. Supercritical fluid-assisted deposition of materials on semiconductor substrates
JP4404961B2 (en) * 2002-01-08 2010-01-27 双葉電子工業株式会社 A method for producing carbon nanofibers.
US6680279B2 (en) 2002-01-24 2004-01-20 General Motors Corporation Nanostructured catalyst particle/catalyst carrier particle system
JP2003240457A (en) * 2002-02-08 2003-08-27 Toyo Radiator Co Ltd Heat exchanger for hot-water supply
US7052777B2 (en) 2002-02-15 2006-05-30 Nanophase Technologies Corporation Composite nanoparticle materials and method of making the same
EP1476397A4 (en) 2002-02-19 2008-03-05 Tal Materials Mixed-metal oxide particles by liquid feed flame spray pyrolysis of oxide precursors in oxygenated solvents
US6635357B2 (en) 2002-02-28 2003-10-21 Vladimir S. Moxson Bulletproof lightweight metal matrix macrocomposites with controlled structure and manufacture the same
US7147894B2 (en) 2002-03-25 2006-12-12 The University Of North Carolina At Chapel Hill Method for assembling nano objects
US6579446B1 (en) 2002-04-04 2003-06-17 Agrimond, Llc Multi-process disinfectant delivery control system
US6625246B1 (en) 2002-04-12 2003-09-23 Holtec International, Inc. System and method for transferring spent nuclear fuel from a spent nuclear fuel pool to a storage cask
DE10219643B4 (en) 2002-05-02 2010-04-29 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Process for the preparation of catalysts
WO2003093518A1 (en) 2002-05-06 2003-11-13 Nelson Sidney G Jr Sorbents and methods for the removal of mercury from combustion gases
KR100483886B1 (en) * 2002-05-17 2005-04-20 (주)엔피씨 Plasma reaction apparatus
US6738452B2 (en) 2002-05-28 2004-05-18 Northrop Grumman Corporation Gasdynamically-controlled droplets as the target in a laser-plasma extreme ultraviolet light source
US6777639B2 (en) 2002-06-12 2004-08-17 Nanotechnologies, Inc. Radial pulsed arc discharge gun for synthesizing nanopowders
US6669823B1 (en) 2002-06-17 2003-12-30 Nanophase Technologies Corporation Process for preparing nanostructured materials of controlled surface chemistry
EP1378489A1 (en) 2002-07-03 2004-01-07 Eidgenössische Technische Hochschule Zürich Metal oxides prepared by flame spray pyrolysis
FR2842125B1 (en) 2002-07-09 2006-03-31 Sicat PROCESS FOR THE PREPARATION BY BIPHASIC IMPREGNATION OF NEW CATALYSTS FOR HETEROGENEOUS CATALYSIS, AND THE USE OF SAID CATALYSTS
US7357910B2 (en) 2002-07-15 2008-04-15 Los Alamos National Security, Llc Method for producing metal oxide nanoparticles
CN100441501C (en) 2002-09-09 2008-12-10 张芬红 System for preparing nanometer silicon nitride powder
US7557324B2 (en) 2002-09-18 2009-07-07 Volvo Aero Corporation Backstream-preventing thermal spraying device
US20040065171A1 (en) 2002-10-02 2004-04-08 Hearley Andrew K. Soild-state hydrogen storage systems
US6838072B1 (en) 2002-10-02 2005-01-04 The United States Of America As Represented By The United States Department Of Energy Plasma synthesis of lithium based intercalation powders for solid polymer electrolyte batteries
US6960242B2 (en) 2002-10-02 2005-11-01 The Boc Group, Inc. CO2 recovery process for supercritical extraction
US6902699B2 (en) 2002-10-02 2005-06-07 The Boeing Company Method for preparing cryomilled aluminum alloys and components extruded and forged therefrom
US20040065170A1 (en) 2002-10-07 2004-04-08 L. W. Wu Method for producing nano-structured materials
DE60335394D1 (en) 2002-10-09 2011-01-27 Nat Inst For Materials Science METHOD FOR PRODUCING A METAL FUEL WITH A HVOF SPRAYING GUN AND DEVICE FOR THERMAL SPRAYING
AU2003301268A1 (en) 2002-10-16 2004-05-04 Conocophillips Company A stabilized transition alumina catalyst support from boehmite and catalysts made therefrom
CN1705512A (en) 2002-10-28 2005-12-07 三菱丽阳株式会社 Carbon intersticed metallic palladium, palladium catalyst and method for preparation thereof, and method for producing alpha, beta-unsaturated carboxylic acid
AU2003268752A1 (en) 2002-10-30 2004-05-25 Sumitomo Chemical Company, Limited High-molecular compounds and polymerer light emitting devices made by using the same
US6913740B2 (en) 2002-11-14 2005-07-05 Catalytic Materials, Inc. Graphite nanocatalysts
GB0227081D0 (en) 2002-11-20 2002-12-24 Exxonmobil Res & Eng Co Methods for preparing catalysts
WO2005015579A2 (en) 2002-12-02 2005-02-17 North Carolina State University Methods of forming three-dimensional nanodot arrays in a matrix
US6824585B2 (en) 2002-12-03 2004-11-30 Adrian Joseph Low cost high speed titanium and its alloy production
WO2004056461A2 (en) 2002-12-17 2004-07-08 E.I. Du Pont De Nemours And Company Method of producing nanoparticles using a evaporation-condensation process with a reaction chamber plasma reactor system
EP1433745A2 (en) 2002-12-26 2004-06-30 Matsushita Electric Industrial Co., Ltd. Catalyst for the removal of carbon monoxide, its method of manufacture and its uses
DE10261717A1 (en) * 2002-12-30 2004-07-15 Meyer, Gerhard, Prof. Dr. Leucite glass ceramic doped with nanoscale metal oxide powder
US7858185B2 (en) 2003-09-08 2010-12-28 Nantero, Inc. High purity nanotube fabrics and films
JP2004233007A (en) 2003-01-31 2004-08-19 Sumitomo Chem Co Ltd Vent gas condenser
CA2418836A1 (en) 2003-02-12 2004-08-12 Resorption Canada Ltd. Multiple plasma generator hazardous waste processing system
JP4227816B2 (en) 2003-02-20 2009-02-18 日本ニューマチック工業株式会社 Powder heat treatment equipment
US20050126338A1 (en) 2003-02-24 2005-06-16 Nanoproducts Corporation Zinc comprising nanoparticles and related nanotechnology
US20040167009A1 (en) * 2003-02-26 2004-08-26 The Regents Of The University Of California, A California Corporation Ceramic materials reinforced with metal and single-wall carbon nanotubes
US20040176246A1 (en) 2003-03-05 2004-09-09 3M Innovative Properties Company Catalyzing filters and methods of making
CN1514243A (en) 2003-04-30 2004-07-21 成都夸常科技有限公司 Method of preceeding qualitative and lor quantitative analysis against target substance its device and marker and detecting reagent box
DE10312494A1 (en) * 2003-03-20 2004-10-07 Association pour la Recherche et le Développement des Méthodes et Processus Industriels (Armines) Carbon nanostructures and methods of making nanotubes, nanofibers, and carbon-based nanostructures
US7070342B2 (en) 2003-03-24 2006-07-04 Aurora Instruments, Inc. Low profile system for joining optical fiber waveguides
JP4396811B2 (en) * 2003-03-25 2010-01-13 Tdk株式会社 Method for producing composite particles, method for producing spherical composite particles
US20040235657A1 (en) 2003-05-21 2004-11-25 Fina Technology, Inc. Freeze dry process for the preparation of a high surface area and high pore volume catalyst
US7279655B2 (en) 2003-06-11 2007-10-09 Plasmet Corporation Inductively coupled plasma/partial oxidation reformation of carbonaceous compounds to produce fuel for energy production
US20070003432A1 (en) 2004-06-17 2007-01-04 Christensen Timothy W Sterilization methods and apparatus which employ additive-containing supercritical carbon dioxide sterilant
WO2005001059A2 (en) * 2003-06-23 2005-01-06 Novasterilis Inc. Inactivating organisms using carbon dioxide at or near its supercritical pressure and temperature conditions
JP4434659B2 (en) * 2003-08-08 2010-03-17 Ihiプラント建設株式会社 Cryogenic liquid heating method and apparatus
US6956007B2 (en) 2003-08-25 2005-10-18 General Motors Corporation Noble metal catalyst
CA2551020C (en) * 2003-08-28 2011-10-18 Tekna Plasma Systems Inc. Process for the synthesis, separation and purification of powder materials
RU2242532C1 (en) 2003-09-09 2004-12-20 Гуревич Сергей Александрович Method of production of nanoparticles
US7217407B2 (en) 2003-09-11 2007-05-15 E. I. Du Pont De Nemours And Company Plasma synthesis of metal oxide nanoparticles
US20050119398A1 (en) 2003-09-11 2005-06-02 Lu Zhang Plasma synthesis of metal oxide nanoparticles
WO2005046855A2 (en) 2003-10-16 2005-05-26 Conocophillips Company Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same
JP4342266B2 (en) 2003-10-20 2009-10-14 トヨタ自動車株式会社 Decompressor
KR100708642B1 (en) 2003-11-21 2007-04-18 삼성에스디아이 주식회사 Mesoporous carbon molecular sieve and supported catalyst employing the same
US7282167B2 (en) 2003-12-15 2007-10-16 Quantumsphere, Inc. Method and apparatus for forming nano-particles
KR100682886B1 (en) * 2003-12-18 2007-02-15 삼성전자주식회사 Process for preparing nanoparticles
US20050133121A1 (en) 2003-12-22 2005-06-23 General Electric Company Metallic alloy nanocomposite for high-temperature structural components and methods of making
TW200536776A (en) 2003-12-25 2005-11-16 Mitsui Mining & Smelting Co Method and device of manufacturing microparticles
JP3912377B2 (en) 2003-12-25 2007-05-09 日産自動車株式会社 Method for producing exhaust gas purification catalyst powder
JP4564263B2 (en) 2004-01-16 2010-10-20 日本板硝子株式会社 Ultrafine metal particle-containing photocatalyst and method for producing the same
US7285312B2 (en) * 2004-01-16 2007-10-23 Honeywell International, Inc. Atomic layer deposition for turbine components
US7547418B2 (en) 2004-01-23 2009-06-16 Gm Global Technology Operations, Inc. Fluidized-bed reactor system
US7494527B2 (en) 2004-01-26 2009-02-24 Tekna Plasma Systems Inc. Process for plasma synthesis of rhenium nano and micro powders, and for coatings and near net shape deposits thereof and apparatus therefor
JP4420690B2 (en) 2004-02-04 2010-02-24 ホソカワミクロン株式会社 Fine particle production method and fine particle production apparatus
JP4976642B2 (en) 2004-02-10 2012-07-18 三井金属鉱業株式会社 High crystalline silver powder and method for producing the same
US7604843B1 (en) 2005-03-16 2009-10-20 Nanosolar, Inc. Metallic dispersion
AU2005215337B2 (en) 2004-02-24 2009-12-03 Cosmo Oil Co., Ltd. Catalyst for producing hydrocarbons, method for preparing the same, and method for producing hydrocarbons using the same
US6886545B1 (en) 2004-03-05 2005-05-03 Haldex Hydraulics Ab Control scheme for exhaust gas circulation system
US7208126B2 (en) * 2004-03-19 2007-04-24 E. I. Du Pont De Nemours And Company Titanium dioxide nanopowder manufacturing process
JP4199691B2 (en) 2004-03-25 2008-12-17 田中貴金属工業株式会社 catalyst
US7794690B2 (en) 2004-04-06 2010-09-14 Socpra Sciences Et Genie S.E.C. Carbon sequestration and dry reforming process and catalysts to produce same
US20050233380A1 (en) 2004-04-19 2005-10-20 Sdc Materials, Llc. High throughput discovery of materials through vapor phase synthesis
US7648676B2 (en) 2004-04-20 2010-01-19 Rti Biologics, Inc. Process and apparatus for treating implants comprising soft tissue
US7547400B1 (en) 2004-06-01 2009-06-16 The United States Of America As Represented By The Secretary Of The Navy Nanoparticle nickel zinc ferrites synthesized using reverse micelles
JP4624006B2 (en) 2004-06-02 2011-02-02 財団法人電力中央研究所 Spherical composite particle manufacturing method and manufacturing apparatus thereof
US7736582B2 (en) 2004-06-10 2010-06-15 Allomet Corporation Method for consolidating tough coated hard powders
US20050274646A1 (en) 2004-06-14 2005-12-15 Conocophillips Company Catalyst for hydroprocessing of Fischer-Tropsch products
JP4649586B2 (en) 2004-06-16 2011-03-09 独立行政法人物質・材料研究機構 Production method of SiC nanoparticles by nitrogen plasma
US7446335B2 (en) * 2004-06-18 2008-11-04 Regents Of The University Of Minnesota Process and apparatus for forming nanoparticles using radiofrequency plasmas
KR20050121426A (en) 2004-06-22 2005-12-27 삼성에스디아이 주식회사 Method for preparing catalyst for manufacturing carbon nano tubes
US7541012B2 (en) 2004-07-07 2009-06-02 The Hong Kong University Of Science And Technology Catalytic material and method of production thereof
US7465430B2 (en) * 2004-07-20 2008-12-16 E. I. Du Pont De Nemours And Company Apparatus for making metal oxide nanopowder
DE102004037752A1 (en) 2004-08-04 2006-03-16 Cognis Deutschland Gmbh & Co. Kg Equipped fibers and textile fabrics
AU2005328642A1 (en) 2004-08-04 2006-09-14 Nanotechnologies, Inc. Carbon and metal nanomaterial composition and synthesis
US7713908B2 (en) 2004-08-30 2010-05-11 Kabushiki Kaisha Toyota Chuo Kenkyusho Porous composite metal oxide and method of producing the same
EP1796154A4 (en) 2004-09-01 2008-10-22 Shibaura Mechatronics Corp Plasma treatment apparatus and method of plasma treatment
JP4640961B2 (en) 2005-07-27 2011-03-02 株式会社日清製粉グループ本社 Fine particle manufacturing method and apparatus
JP4988164B2 (en) 2005-03-08 2012-08-01 株式会社日清製粉グループ本社 Fine particle manufacturing method and apparatus
US6996958B1 (en) * 2004-09-10 2006-02-14 Chi-Yee Yeh Wrapping machine for paper and plastic packing
JP5168683B2 (en) 2004-09-17 2013-03-21 独立行政法人産業技術総合研究所 Nanocapsule structure
JP4560621B2 (en) 2004-09-21 2010-10-13 国立大学法人山梨大学 Method for producing fine particle catalyst, alloy fine particle catalyst or composite oxide fine particle catalyst, apparatus therefor, and method for using the same
TW200611449A (en) 2004-09-24 2006-04-01 Hon Hai Prec Ind Co Ltd A catalyst layer of a fuel cell, a method for fabricating the same and a fuel cell utilizing the same
CN101076716B (en) * 2004-10-08 2011-04-13 Sdc材料有限责任公司 An apparatus for and method of sampling and collecting powders flowing in a gas stream
US7601671B2 (en) 2004-10-28 2009-10-13 Umicore Ag & Co. Kg Drying method for exhaust gas catalyst
JP4282586B2 (en) 2004-11-02 2009-06-24 Spsシンテックス株式会社 Nano precision sintering system
US7375302B2 (en) 2004-11-16 2008-05-20 Hypertherm, Inc. Plasma arc torch having an electrode with internal passages
US7750265B2 (en) * 2004-11-24 2010-07-06 Vladimir Belashchenko Multi-electrode plasma system and method for thermal spraying
CN1647858A (en) 2004-12-01 2005-08-03 天津大学 Method for reducing loaded metal catalyst using low temperature plasma
DE102004059375A1 (en) 2004-12-09 2006-06-22 Consortium für elektrochemische Industrie GmbH Platinum catalysts supported on nanoscale titanium dioxide, their use in hydrosilylation, a hydrosilylation process with such catalysts, and compositions containing such catalysts
JP4245051B2 (en) 2004-12-14 2009-03-25 日産自動車株式会社 Exhaust gas purification catalyst
US7507495B2 (en) 2004-12-22 2009-03-24 Brookhaven Science Associates, Llc Hydrogen absorption induced metal deposition on palladium and palladium-alloy particles
JP2006181484A (en) 2004-12-27 2006-07-13 Nissan Motor Co Ltd Catalyst, exhaust gas cleaning catalyst and method for preparing the catalyst
US20060153728A1 (en) 2005-01-10 2006-07-13 Schoenung Julie M Synthesis of bulk, fully dense nanostructured metals and metal matrix composites
IE20050018A1 (en) * 2005-01-19 2006-11-01 Nat Univ Ireland Tissue graft scaffold
US7618919B2 (en) 2005-01-28 2009-11-17 Kabushiki Kaisha Toyota Chuo Kenkyusho Catalyst support and method of producing the same
ES2366917T3 (en) 2005-01-28 2011-10-26 Tekna Plasma Systems, Inc. SYNTHESIS OF NANOPOLVES THROUGH INDUCTION PLASMA.
WO2006099509A1 (en) 2005-03-11 2006-09-21 Regents Of The University Of Minnesota Air pollutant removal using magnetic sorbent particles
US7666773B2 (en) 2005-03-15 2010-02-23 Asm International N.V. Selective deposition of noble metal thin films
US7332454B2 (en) 2005-03-16 2008-02-19 Sud-Chemie Inc. Oxidation catalyst on a substrate utilized for the purification of exhaust gases
JP2006260385A (en) 2005-03-18 2006-09-28 Osaka Gas Co Ltd Pressure governor and processing method
US7799111B2 (en) 2005-03-28 2010-09-21 Sulzer Metco Venture Llc Thermal spray feedstock composition
JP4634199B2 (en) * 2005-03-30 2011-02-16 関東電化工業株式会社 Surface modification method and apparatus using fluorine-containing gas
US7611686B2 (en) 2005-05-17 2009-11-03 Max-Planck-Gesellschaft Zur Forderung Der Wissenschaften E.V. Materials purification by treatment with hydrogen-based plasma
JP2006326554A (en) 2005-05-30 2006-12-07 Nissan Motor Co Ltd Catalyst for purifying exhaust gas, and method for producing it
US8034441B2 (en) 2005-07-08 2011-10-11 Arkema France Multilayer composition
US20070014919A1 (en) 2005-07-15 2007-01-18 Jani Hamalainen Atomic layer deposition of noble metal oxides
US20070272664A1 (en) 2005-08-04 2007-11-29 Schroder Kurt A Carbon and Metal Nanomaterial Composition and Synthesis
KR100711967B1 (en) 2005-08-08 2007-05-02 삼성전기주식회사 Method for making silver nanoparticles and comductive ink
JP2007044585A (en) 2005-08-08 2007-02-22 Toyota Central Res & Dev Lab Inc Manufacturing method of porous composite metal oxide material
US7695705B2 (en) 2005-08-26 2010-04-13 Ppg Industries Ohio, Inc. Method and apparatus for the production of ultrafine silica particles from solid silica powder and related coating compositions
CN1931423A (en) * 2005-09-13 2007-03-21 鸿富锦精密工业(深圳)有限公司 Nanometer particle synthesizing apparatus and process
US20080031806A1 (en) 2005-09-16 2008-02-07 John Gavenonis Continuous process for making nanocrystalline metal dioxide
US8063315B2 (en) 2005-10-06 2011-11-22 Endicott Interconnect Technologies, Inc. Circuitized substrate with conductive paste, electrical assembly including said circuitized substrate and method of making said substrate
US7678955B2 (en) * 2005-10-13 2010-03-16 Exxonmobil Chemical Patents Inc Porous composite materials having micro and meso/macroporosity
US7615097B2 (en) 2005-10-13 2009-11-10 Plasma Processes, Inc. Nano powders, components and coatings by plasma technique
TWI402117B (en) * 2005-10-17 2013-07-21 Nisshin Seifun Group Inc Process for producing ultrafine particles
JP4963586B2 (en) 2005-10-17 2012-06-27 株式会社日清製粉グループ本社 Method for producing ultrafine particles
KR101193163B1 (en) 2005-10-21 2012-10-19 삼성에스디아이 주식회사 Catalyst for oxidizing carbon monoxide and method of producing the same
EP3308846A1 (en) 2005-11-01 2018-04-18 Nissan Motor Co., Ltd. Exhaust gas purifying catalyst and production method thereof
US7936595B2 (en) 2005-12-31 2011-05-03 Institute Of Physics, Chinese Academy Of Sciences Close shaped magnetic multi-layer film comprising or not comprising a metal core and the manufacture method and the application of the same
JP4565191B2 (en) 2006-01-30 2010-10-20 国立大学法人山梨大学 Fine particle catalyst production method, fine particle catalyst, and reformer
US7951428B2 (en) 2006-01-31 2011-05-31 Regents Of The University Of Minnesota Electrospray coating of objects
US7402899B1 (en) 2006-02-03 2008-07-22 Pacesetter, Inc. Hermetically sealable silicon system and method of making same
JP5055788B2 (en) 2006-02-22 2012-10-24 日産自動車株式会社 Electrocatalyst
JP2007253037A (en) 2006-03-22 2007-10-04 Nissan Motor Co Ltd Catalyst for cleaning exhaust gas and manufacturing method therefor
CN101415489B (en) 2006-04-03 2012-06-27 日产自动车株式会社 Exhaust gas purifying catalyst and method for producing the same
KR100807806B1 (en) * 2006-04-04 2008-02-27 제주대학교 산학협력단 DC arc plasmatron and the method using the same
CA2683165C (en) 2006-04-05 2013-06-11 Foret Plasma Labs, Llc System, method and apparatus for treating liquids with wave energy from plasma
FR2899594A1 (en) 2006-04-10 2007-10-12 Commissariat Energie Atomique METHOD FOR ASSEMBLING SUBSTRATES WITH THERMAL TREATMENTS AT LOW TEMPERATURES
US7601294B2 (en) 2006-05-02 2009-10-13 Babcock & Wilcox Technical Services Y-12, Llc High volume production of nanostructured materials
US20070259768A1 (en) 2006-05-03 2007-11-08 Kear Bernard H Nanocomposite ceramic and method for producing the same
CN101479020B (en) 2006-05-05 2012-07-18 普拉斯科能源Ip控股公司毕尔巴鄂-沙夫豪森分公司 A gas conditioning system
MX2008013830A (en) 2006-05-08 2008-11-10 Bp Corp North America Inc Process and catalyst for oxidizing aromatic compounds.
US7541309B2 (en) 2006-05-16 2009-06-02 Headwaters Technology Innovation, Llc Reforming nanocatalysts and methods of making and using such catalysts
US7417008B2 (en) 2006-05-31 2008-08-26 Exxonmobil Chemical Patents Inc. Supported polyoxometalates and process for their preparation
WO2007144446A1 (en) 2006-06-15 2007-12-21 Ecocat Oy Coating for particulate filters
JP4294041B2 (en) 2006-07-31 2009-07-08 本田技研工業株式会社 NOx purification catalyst
US7803210B2 (en) 2006-08-09 2010-09-28 Napra Co., Ltd. Method for producing spherical particles having nanometer size, crystalline structure, and good sphericity
US7776303B2 (en) 2006-08-30 2010-08-17 Ppg Industries Ohio, Inc. Production of ultrafine metal carbide particles utilizing polymeric feed materials
JP2008100152A (en) 2006-10-18 2008-05-01 Cataler Corp Catalyst for cleaning exhaust gas
JP5052291B2 (en) 2006-11-02 2012-10-17 株式会社日清製粉グループ本社 Alloy fine particles and method for producing the same
US7803295B2 (en) 2006-11-02 2010-09-28 Quantumsphere, Inc Method and apparatus for forming nano-particles
US7878430B2 (en) 2006-11-20 2011-02-01 The University Of Western Ontario Method and apparatus for uniformly dispersing additive particles in fine powders
US8030592B2 (en) 2006-11-22 2011-10-04 Reintjes Marine Surface Technologies, Llc Apparatus and method for applying antifoulants to marine vessels
US8258070B2 (en) 2006-11-27 2012-09-04 WGCH Technology Limited Engine exhaust catalysts containing palladium-gold
WO2008130451A2 (en) 2006-12-04 2008-10-30 Battelle Memorial Institute Composite armor and method for making composite armor
US20100050868A1 (en) 2006-12-11 2010-03-04 Governors Of The University Of Alberta Mercury absorption using chabazite supported metallic nanodots
CN100479918C (en) 2007-01-09 2009-04-22 大连理工大学 Method for preparing metal phosphide hydrogenation refining catalyst by using hydrogen plasma reduction method
US20080206562A1 (en) 2007-01-12 2008-08-28 The Regents Of The University Of California Methods of generating supported nanocatalysts and compositions thereof
CN101683622B (en) 2007-01-17 2013-03-06 纳米星公司 Engine exhaust catalysts containing palladium-gold
WO2008089221A1 (en) 2007-01-18 2008-07-24 Shell Oil Company A catalyst, its preparation and use
JP4971918B2 (en) 2007-01-25 2012-07-11 日産自動車株式会社 Exhaust gas purification catalyst and method for producing the same
EP2055367A3 (en) 2007-01-25 2009-05-27 Nissan Motor Co., Ltd. Exhaust gas purifying catalyst and manufacturing method thereof
CA2676909C (en) 2007-02-02 2015-12-08 Plasma Technologies Ltd. Plasma spraying device and method
US8679291B2 (en) 2007-03-13 2014-03-25 Heartland Technology Partners Llc Compact wastewater concentrator using waste heat
US8124043B2 (en) 2007-03-16 2012-02-28 Honda Motor Co., Ltd. Method of preparing carbon nanotube containing electrodes
US7635218B1 (en) 2007-04-19 2009-12-22 Vortex Systems (International) Ci Method for dust-free low pressure mixing
US8085894B2 (en) 2007-04-23 2011-12-27 Lawrence Livermore National Security, Llc Swelling-resistant nuclear fuel
JP5125202B2 (en) 2007-04-24 2013-01-23 トヨタ自動車株式会社 Method for producing Ni nanoparticles
US20080268270A1 (en) 2007-04-30 2008-10-30 Wenjie Chen High impact polymer interlayers
US7772150B2 (en) 2007-05-01 2010-08-10 Ut-Battelle, Llc Method to prepare nanoparticles on porous mediums
WO2008134871A1 (en) 2007-05-04 2008-11-13 Principle Energy Solutions, Inc. Production of hydrocarbons from carbon and hydrogen sources
US20080277264A1 (en) 2007-05-10 2008-11-13 Fluid-Quip, Inc. Alcohol production using hydraulic cavitation
US20090010801A1 (en) 2007-05-15 2009-01-08 Murphy Oliver J Air cleaner
FR2917405B1 (en) 2007-06-18 2010-12-10 Vibro Meter France PROCESS FOR PREPARING A SINTERED CERAMIC, CERAMIC THUS OBTAINED AND IGNITION CANDLE COMPRISING SAME
JP2009022895A (en) 2007-07-20 2009-02-05 Toyota Motor Corp Powder treatment apparatus
JP5322524B2 (en) * 2007-07-23 2013-10-23 ホソカワミクロン株式会社 Metal oxide production equipment
CA2694949A1 (en) 2007-07-31 2009-02-05 Perry Equipment Corporation Systems and methods for removal of heavy metal contaminants from fluids
US7589473B2 (en) 2007-08-06 2009-09-15 Plasma Surgical Investments, Ltd. Pulsed plasma device and method for generating pulsed plasma
US8012414B2 (en) * 2007-08-10 2011-09-06 Novasterilis Sterilization of drugs using supercritical carbon dioxide sterilant
US20090081092A1 (en) 2007-09-24 2009-03-26 Xiaolin David Yang Pollutant Emission Control Sorbents and Methods of Manufacture and Use
DE102007048313B4 (en) 2007-10-09 2011-07-28 Süd-Chemie AG, 80333 Coating of substrates while ensuring a high porosity with high abrasion resistance of the coating
US8481449B1 (en) 2007-10-15 2013-07-09 SDCmaterials, Inc. Method and system for forming plug and play oxide catalysts
KR101496916B1 (en) 2007-10-29 2015-02-27 유미코어 니폰 쇼쿠바이 가부시키가이샤 Catalyst for the removal of nitrogen oxides and method for the removal of nitrogen oxides with the same
US20100183497A1 (en) 2007-11-06 2010-07-22 Quantumsphere, Inc. System and method for ammonia synthesis
JP4888470B2 (en) 2007-11-08 2012-02-29 日産自動車株式会社 Method for producing noble metal-supported powder and exhaust gas purifying catalyst
US7759212B2 (en) 2007-12-26 2010-07-20 Stats Chippac, Ltd. System-in-package having integrated passive devices and method therefor
RU2410402C2 (en) 2007-12-28 2011-01-27 Александр Метталинович Тишин Porous materials with embedded nanoparticles, preparation methods and use thereof
JP5371247B2 (en) 2008-01-06 2013-12-18 Dowaエレクトロニクス株式会社 Silver paint and production method thereof
JP5228495B2 (en) 2008-01-11 2013-07-03 富士通セミコンダクター株式会社 Manufacturing method of semiconductor device
US20120171098A1 (en) 2008-01-22 2012-07-05 Ppg Industries Ohio, Inc Method of consolidating ultrafine metal carbide and metal boride particles and products made therefrom
FR2927085B1 (en) 2008-02-04 2012-10-26 Centre Nat Rech Scient NEW MATERIAL WITH BACTERIOSTATIC PROPERTIES
US8252244B2 (en) 2008-02-08 2012-08-28 Peat International, Inc. Method and apparatus of treating waste
US20090208367A1 (en) 2008-02-19 2009-08-20 Rosario Sam Calio Autoclavable bucketless cleaning system
JP2009226261A (en) 2008-03-19 2009-10-08 Fujifilm Corp Liquid mixing method and liquid mixing apparatus
KR101407650B1 (en) 2008-04-04 2014-06-13 성균관대학교산학협력단 A method for preparing a nanoparticle, a nanoparticle and a lithium battery comprising an electrode comprising the nanoparticle
JP2009254929A (en) 2008-04-14 2009-11-05 Japan Energy Corp Reforming catalyst for manufacturing hydrogen suitable for hydrogen manufacture at low temperature, and hydrogen manufacturing method using the catalyst
US8431102B2 (en) 2008-04-16 2013-04-30 The Regents Of The University Of California Rhenium boride compounds and uses thereof
US8716165B2 (en) 2008-04-30 2014-05-06 Corning Incorporated Catalysts on substrates and methods for providing the same
USD627900S1 (en) 2008-05-07 2010-11-23 SDCmaterials, Inc. Glove box
JP5465842B2 (en) 2008-05-23 2014-04-09 トヨタ自動車株式会社 Core-shell structure and exhaust gas-purifying catalyst including the core-shell structure
CN101601999B (en) 2008-06-14 2012-05-23 比亚迪股份有限公司 Automobile exhaust purifying catalyst and preparation method thereof
US20090324468A1 (en) 2008-06-27 2009-12-31 Golden Stephen J Zero platinum group metal catalysts
US8475752B2 (en) 2008-06-27 2013-07-02 Basf Corporation NOx adsorber catalyst with superior low temperature performance
US20110049045A1 (en) 2008-10-07 2011-03-03 Brown University Nanostructured sorbent materials for capturing environmental mercury vapor
EP2352700A1 (en) 2008-10-27 2011-08-10 Basf Se Method for preparing a suspension of nanoparticulate metal borides
TWI363357B (en) 2008-12-09 2012-05-01 Univ Nat Pingtung Sci & Tech Method for manufacturing composite metal conductive particules
CA2746179A1 (en) 2008-12-11 2010-06-17 Robin Ernest Fossey An autoclave
WO2010077843A2 (en) 2008-12-29 2010-07-08 Basf Catalysts Llc Oxidation catalyst with low co and hc light-off and systems and methods
US8252258B2 (en) 2009-01-16 2012-08-28 Basf Corporation Diesel oxidation catalyst with layer structure for improved hydrocarbon conversion
US8329607B2 (en) 2009-01-16 2012-12-11 Basf Corporation Layered diesel oxidation catalyst composites
US8211392B2 (en) 2009-01-16 2012-07-03 Basf Corporation Diesel oxidation catalyst composite with layer structure for carbon monoxide and hydrocarbon conversion
DE102009010711A1 (en) 2009-02-27 2010-09-30 Umicore Ag & Co. Kg Nitrogen storage catalytic converter for use in motor vehicles in close-up position
US20110247336A9 (en) 2009-03-10 2011-10-13 Kasra Farsad Systems and Methods for Processing CO2
WO2010122855A1 (en) 2009-04-24 2010-10-28 国立大学法人山梨大学 Catalyst for selective methanation of carbon monoxide, process for producing same, and device using same
KR20120036817A (en) 2009-05-01 2012-04-18 더 리젠츠 오브 더 유니버시티 오브 미시건 In-situ plasma/laser hybrid scheme
US8309489B2 (en) 2009-06-18 2012-11-13 University Of Central Florida Research Foundation, Inc. Thermally stable nanoparticles on supports
CN101602018B (en) 2009-07-23 2011-05-04 上海交通大学 Method for preparing rare-earth element doped composite metal oxide mercury removal catalyst
US8758695B2 (en) 2009-08-05 2014-06-24 Basf Se Treatment system for gasoline engine exhaust gas
NZ598311A (en) 2009-08-14 2013-11-29 Univ Michigan DIRECT THERMAL SPRAY SYNTHESIS OF Li ION BATTERY COMPONENTS
US8176830B1 (en) 2009-09-24 2012-05-15 Wright Materials Research Co. Ballistic shield
JP5683598B2 (en) 2009-11-12 2015-03-11 ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフトUmicore AG & Co.KG Improved diesel oxidation catalyst
US8765625B2 (en) 2009-12-10 2014-07-01 Shubin, Inc. Engine exhaust catalysts containing copper-ceria
US8652992B2 (en) 2009-12-15 2014-02-18 SDCmaterials, Inc. Pinning and affixing nano-active material
US8470112B1 (en) 2009-12-15 2013-06-25 SDCmaterials, Inc. Workflow for novel composite materials
US8803025B2 (en) 2009-12-15 2014-08-12 SDCmaterials, Inc. Non-plugging D.C. plasma gun
US9126191B2 (en) 2009-12-15 2015-09-08 SDCmaterials, Inc. Advanced catalysts for automotive applications
US20110143930A1 (en) 2009-12-15 2011-06-16 SDCmaterials, Inc. Tunable size of nano-active material on nano-support
US8545652B1 (en) 2009-12-15 2013-10-01 SDCmaterials, Inc. Impact resistant material
US9119309B1 (en) 2009-12-15 2015-08-25 SDCmaterials, Inc. In situ oxide removal, dispersal and drying
EP2512656A4 (en) 2009-12-15 2014-05-28 Sdcmaterails Inc Advanced catalysts for fine chemical and pharmaceutical applications
US9149797B2 (en) 2009-12-15 2015-10-06 SDCmaterials, Inc. Catalyst production method and system
US8124798B2 (en) 2009-12-17 2012-02-28 Lyondell Chemical Technology, Lp Direct epoxidation catalyst and process
CN102892506A (en) 2009-12-17 2013-01-23 巴斯夫欧洲公司 Metal oxide support material containing nanoscaled iron-platinum group metal particles
GB0922195D0 (en) 2009-12-21 2010-02-03 Johnson Matthey Plc Improvements in NOx traps
US9394632B2 (en) 2010-03-22 2016-07-19 The Regents Of The University Of California Method and device to synthesize boron nitride nanotubes and related nanoparticles
US8080495B2 (en) 2010-04-01 2011-12-20 Cabot Corporation Diesel oxidation catalysts
WO2011127095A2 (en) 2010-04-05 2011-10-13 Gonano Technologies, Inc. Catalytic converters, insert materials for catalytic converters, and methods of making
US8734743B2 (en) 2010-06-10 2014-05-27 Basf Se NOx storage catalyst with improved hydrocarbon conversion activity
US8895962B2 (en) 2010-06-29 2014-11-25 Nanogram Corporation Silicon/germanium nanoparticle inks, laser pyrolysis reactors for the synthesis of nanoparticles and associated methods
EP2611948A2 (en) 2010-09-01 2013-07-10 Facultés Universitaires Notre-Dame de la Paix Method for depositing nanoparticles on substrates
US9242242B2 (en) 2010-09-02 2016-01-26 Basf Se Catalyst for gasoline lean burn engines with improved NO oxidation activity
US9120077B2 (en) 2010-10-01 2015-09-01 Basf Corporation Surface-coated zeolite materials for diesel oxidation applications
CA2816903C (en) 2010-12-15 2019-12-03 Sulzer Metco (Us) Inc. Pressure based liquid feed system for suspension plasma spray coatings
DE102010063342A1 (en) 2010-12-17 2012-06-21 Laser Zentrum Hannover E.V. Process for the preparation of micro-nanocombined active systems
GB201021887D0 (en) 2010-12-21 2011-02-02 Johnson Matthey Plc Oxidation catalyst for a lean burn internal combustion engine
US8669202B2 (en) 2011-02-23 2014-03-11 SDCmaterials, Inc. Wet chemical and plasma methods of forming stable PtPd catalysts
EP2495032A1 (en) 2011-03-03 2012-09-05 Umicore Ag & Co. Kg SCR catalyst with improved hydrocarbon resistance
AU2012299065B2 (en) 2011-08-19 2015-06-04 SDCmaterials, Inc. Coated substrates for use in catalysis and catalytic converters and methods of coating substrates with washcoat compositions
JP5938819B2 (en) 2011-10-06 2016-06-22 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company Oxidation catalyst for exhaust gas treatment
ES2402147B1 (en) 2011-10-17 2014-03-04 Universitat Politècnica De Catalunya PROCEDURE FOR OBTAINING A SUBSTRATE WITH NANOCLUSTERS OF AU FIXED IN THEIR SURFACE, AND SUBSTRATE AND CATALYST OBTAINED THROUGH SUCH PROCEDURE.
CN102430325A (en) 2011-11-14 2012-05-02 江苏大学 Method for mercury removal of coal-fired flue gas
KR101273567B1 (en) 2011-11-22 2013-06-11 한국과학기술연구원 A counter electrodes for dye-sensitized solar cells and preparation method thereof
WO2013093597A2 (en) 2011-12-22 2013-06-27 Johnson Matthey Public Limited Company Improved nox trap
KR101950545B1 (en) 2012-04-06 2019-02-20 바스프 코포레이션 LEAN NOxTRAP DIESEL OXIDATION CATALYST WITH HYDROCARBON STORAGE FUNCTION
US8920756B2 (en) 2012-05-07 2014-12-30 GM Global Technology Operations LLC Silver promoted close-coupled NOx absorber
US20160030910A1 (en) 2012-08-17 2016-02-04 SDCmaterials, Inc. High-throughput particle production using a plasma system
GB201219600D0 (en) 2012-10-31 2012-12-12 Johnson Matthey Plc Catalysed soot filter
US9511352B2 (en) 2012-11-21 2016-12-06 SDCmaterials, Inc. Three-way catalytic converter using nanoparticles
US9156025B2 (en) 2012-11-21 2015-10-13 SDCmaterials, Inc. Three-way catalytic converter using nanoparticles
US8679434B1 (en) 2013-01-28 2014-03-25 Basf Corporation Catalytic articles, systems and methods for the oxidation of nitric oxide
CN105163829A (en) 2013-03-06 2015-12-16 Sdc材料公司 Particle-based systems for removal of pollutants from gases and liquids
WO2014160159A1 (en) 2013-03-14 2014-10-02 Basf Corporation Catalytic article with segregated washcoat and methods of making same
US20140263190A1 (en) 2013-03-14 2014-09-18 SDCmaterials, Inc. High-throughput particle production using a plasma system
US20140369912A1 (en) 2013-06-13 2014-12-18 Basf Corporation Integrated Supports for Emission Control Catalysts
CN105592921A (en) 2013-07-25 2016-05-18 Sdc材料公司 Washcoats and coated substrates for catalytic converters and method for manufacturing and using same
GB201315892D0 (en) 2013-07-31 2013-10-23 Johnson Matthey Plc Zoned diesel oxidation catalyst
WO2015042598A1 (en) 2013-09-23 2015-03-26 SDCmaterials, Inc. High surface area catalyst
KR20160074574A (en) 2013-10-22 2016-06-28 에스디씨머티리얼스, 인코포레이티드 COMPOSITIONS OF LEAN NOx TRAP
JP2016536120A (en) 2013-10-22 2016-11-24 エスディーシーマテリアルズ, インコーポレイテッド Catalyst design for heavy duty diesel combustion engines
EP3119500A4 (en) 2014-03-21 2017-12-13 SDC Materials, Inc. Compositions for passive nox adsorption (pna) systems
CN106999913A (en) 2014-07-29 2017-08-01 Sdc材料公司 The catalytic substrate of region coating with passive nitrogen oxide absorbent area
JP2017529228A (en) 2014-07-29 2017-10-05 エスディーシーマテリアルズ, インコーポレイテッド Three-way catalytic converter using hybrid catalyst particles
WO2016033526A1 (en) 2014-08-29 2016-03-03 SDCmaterials, Inc. Composition comprising nanoparticles with desired sintering and melting point temperatures and methods of making thereof
US20170274367A1 (en) 2014-08-29 2017-09-28 SDCmaterials, Inc. Primer washcoats for metal substrates
US10124322B2 (en) 2015-02-11 2018-11-13 Umicore Ag & Co. Kg Lean NOx traps, trapping materials, washcoats, and methods of making and using the same
WO2016130926A2 (en) 2015-02-13 2016-08-18 SDCmaterials, Inc. Zoned catalytic converters for gasoline engines with reduced rhodium content
WO2016144729A1 (en) 2015-03-06 2016-09-15 SDCmaterials, Inc. Plasma-based production of nanoferrite particles
WO2016144811A1 (en) 2015-03-06 2016-09-15 SDCmaterials, Inc. Coated magnetic particle and methods of making and using the same
WO2016149367A1 (en) 2015-03-16 2016-09-22 SDCmaterials, Inc. Catalytic converters for gasoline engines with reduced rhodium content

Patent Citations (101)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2419042A (en) * 1945-10-06 1947-04-15 Todd Floyd Vacuum distillation apparatus and pressure regulator therefor
US3181947A (en) * 1957-01-15 1965-05-04 Crucible Steel Co America Powder metallurgy processes and products
US3235700A (en) * 1962-07-27 1966-02-15 Air Liquide Apparatus for projecting materials in powder form by means of a concentrated electric arc
US4146654A (en) * 1967-10-11 1979-03-27 Centre National De La Recherche Scientifique Process for making linings for friction operated apparatus
US3552653A (en) * 1968-01-10 1971-01-05 Inoue K Impact deposition of particulate materials
US3667111A (en) * 1969-03-05 1972-06-06 Chausson Usines Sa Process for fluxing and brazing parts made of aluminium or aluminium alloy
US4369167A (en) * 1972-03-24 1983-01-18 Weir Jr Alexander Process for treating stack gases
US3804034A (en) * 1972-05-09 1974-04-16 Boride Prod Inc Armor
US3871448A (en) * 1973-07-26 1975-03-18 Vann Tool Company Inc Packer actuated vent assembly
US3959094A (en) * 1975-03-13 1976-05-25 The United States Of America As Represented By The United States Energy Research And Development Administration Electrolytic synthesis of methanol from CO2
US4021021A (en) * 1976-04-20 1977-05-03 Us Energy Wetter for fine dry powder
US4189925A (en) * 1978-05-08 1980-02-26 Northern Illinois Gas Company Method of storing electric power
US4315874A (en) * 1979-04-11 1982-02-16 Mitsui Petrochemical Industries Ltd. Process for the production of spherical carrier particles for olefin polymerization catalysts
US4260649A (en) * 1979-05-07 1981-04-07 The Perkin-Elmer Corporation Laser induced dissociative chemical gas phase processing of workpieces
US4253917A (en) * 1979-08-24 1981-03-03 Kennecott Copper Corporation Method for the production of copper-boron carbide composite
US4326492A (en) * 1980-04-07 1982-04-27 Runfree Enterprise, Inc. Method and apparatus for preheating fuel
US4440733A (en) * 1980-11-06 1984-04-03 California Institute Of Technology Thermochemical generation of hydrogen and carbon dioxide
US4458138A (en) * 1980-12-15 1984-07-03 Adrian Glenn J Fast recovery electric fluid
US4436075A (en) * 1982-01-07 1984-03-13 Daniel D. Bailey Fuel pre-heat device
US4523981A (en) * 1984-03-27 1985-06-18 Texaco Inc. Means and method for reducing carbon dioxide to provide a product
US5006163A (en) * 1985-03-13 1991-04-09 Inco Alloys International, Inc. Turbine blade superalloy II
US4723589A (en) * 1986-05-19 1988-02-09 Westinghouse Electric Corp. Method for making vacuum interrupter contacts by spray deposition
US4921586A (en) * 1989-03-31 1990-05-01 United Technologies Corporation Electrolysis cell and method of use
US5015863A (en) * 1989-05-31 1991-05-14 Sumitomo Heavy Industries, Ltd. Radiation shield and shielding material with excellent heat-transferring property
US5192130A (en) * 1990-03-06 1993-03-09 Konica Corporation Method for producing an emulsion and an apparatus therefor
US5486675A (en) * 1991-02-22 1996-01-23 Idaho Research Foundation Plasma production of ultra-fine ceramic carbides
US20020018815A1 (en) * 1992-03-06 2002-02-14 Sievers Robert E. Methods and apparatus for fine particle formation
US6855410B2 (en) * 1992-07-14 2005-02-15 Theresa M. Buckley Phase change material thermal capacitor clothing
US6858170B2 (en) * 1994-02-24 2005-02-22 Atofina Research Silica-alumina catalyst carriers preparation
US5714644A (en) * 1994-07-06 1998-02-03 Basf Aktiengesellschaft Process and catalyst for the selective hydrogenation of butynediol to butenediol
US5723027A (en) * 1994-09-07 1998-03-03 W.C. Heraeus Gmbh Method for preparing a powder in a plasma arc and device for carrying out said method
US5733662A (en) * 1994-09-26 1998-03-31 Plas Plasma, Ltd. Method for depositing a coating onto a substrate by means of thermal spraying and an apparatus for carrying out said method
US5858470A (en) * 1994-12-09 1999-01-12 Northwestern University Small particle plasma spray apparatus, method and coated article
US5596973A (en) * 1995-06-05 1997-01-28 Grice; Franklin R. Fuel expander
US5884473A (en) * 1995-06-23 1999-03-23 Ngk Insulators, Ltd. System for exhaust gas purification and method for exhaust gas purification using said system
US6045765A (en) * 1996-02-08 2000-04-04 Sakai Chemical Industry Co., Ltd. Catalyst and method for catalytic reduction of nitrogen oxides
US5723187A (en) * 1996-06-21 1998-03-03 Ford Global Technologies, Inc. Method of bonding thermally sprayed coating to non-roughened aluminum surfaces
US6066587A (en) * 1996-09-26 2000-05-23 Mazda Motor Corporation Catalyst for purifying exhaust gas
US20050097988A1 (en) * 1997-02-24 2005-05-12 Cabot Corporation Coated nickel-containing powders, methods and apparatus for producing such powders and devices fabricated from same
US6562304B1 (en) * 1997-10-22 2003-05-13 Clue As Scrubber for the treatment of flue gases
US6012647A (en) * 1997-12-01 2000-01-11 3M Innovative Properties Company Apparatus and method of atomizing and vaporizing
US6362449B1 (en) * 1998-08-12 2002-03-26 Massachusetts Institute Of Technology Very high power microwave-induced plasma
US20010004009A1 (en) * 1999-01-25 2001-06-21 Mackelvie Winston Drainwater heat recovery system
US6168694B1 (en) * 1999-02-04 2001-01-02 Chemat Technology, Inc. Methods for and products of processing nanostructure nitride, carbonitride and oxycarbonitride electrode power materials by utilizing sol gel technology for supercapacitor applications
US6190627B1 (en) * 1999-11-30 2001-02-20 Engelhard Corporation Method and device for cleaning the atmosphere
US6569393B1 (en) * 1999-11-30 2003-05-27 Engelhard Corporation Method and device for cleaning the atmosphere
US20030036786A1 (en) * 2000-04-10 2003-02-20 Duren Albert Philip Van System, combination and method for controlling airflow in convective treatment
US20030047617A1 (en) * 2000-06-30 2003-03-13 Subramaniam Shanmugham Method of pepositing materials
US8089495B2 (en) * 2001-04-06 2012-01-03 T-Mobile Deutschland Gmbh Method for the display of standardized large-format internet pages with for example HTML protocol on hand-held devices with a mobile radio connection
US6506995B1 (en) * 2001-06-21 2003-01-14 General Electric Company Conforming welding torch shroud
US6891319B2 (en) * 2001-08-29 2005-05-10 Motorola, Inc. Field emission display and methods of forming a field emission display
US20050106865A1 (en) * 2001-09-26 2005-05-19 Applied Materials, Inc. Integration of ALD tantalum nitride for copper metallization
US6706660B2 (en) * 2001-12-18 2004-03-16 Caterpillar Inc Metal/metal oxide doped oxide catalysts having high deNOx selectivity for lean NOx exhaust aftertreatment systems
US20040044513A1 (en) * 2002-09-02 2004-03-04 Noriaki Kitahara Distributed simulation system
US20040077494A1 (en) * 2002-10-22 2004-04-22 Labarge William J. Method for depositing particles onto a catalytic support
US20050000321A1 (en) * 2003-07-02 2005-01-06 O'larey Philip M. Method for producing metal fibers
US6841509B1 (en) * 2003-07-21 2005-01-11 Industrial Technology Research Institute Carbon nanocapsule supported catalysts
US20050066805A1 (en) * 2003-09-17 2005-03-31 Park Andrew D. Hard armor composite
US20050070431A1 (en) * 2003-09-26 2005-03-31 Siemens Westinghouse Power Corporation Catalytic combustors
US20050077034A1 (en) * 2003-10-14 2005-04-14 King Leonard Tony Static mixer-heat exchanger
US7674744B2 (en) * 2004-03-31 2010-03-09 Nissan Motor Co., Ltd. Catalyst powder, method of producing the catalyst powder, and exhaust gas purifying catalyst
US8173572B2 (en) * 2004-06-21 2012-05-08 Johnson Matthey Plc Metal oxide sols
US7902104B2 (en) * 2004-06-23 2011-03-08 Arkema France Divided solid composition composed of grains provided with continuous metal deposition, method for the production and use thereof in the form of a catalyst
US20080006954A1 (en) * 2004-09-07 2008-01-10 Kazuhiro Yubuta Process and Apparatus for Producing Fine Particles
US7709411B2 (en) * 2004-11-17 2010-05-04 Headwaters Technology Innovation, Llc Method of manufacturing multicomponent nanoparticles
US20070049484A1 (en) * 2005-02-24 2007-03-01 Kear Bernard H Nanocomposite ceramics and process for making the same
US20080026041A1 (en) * 2005-09-12 2008-01-31 Argonide Corporation Non-woven media incorporating ultrafine or nanosize powders
US20070084834A1 (en) * 2005-09-30 2007-04-19 Hanus Gary J Plasma torch with corrosive protected collimator
US7935655B2 (en) * 2005-11-04 2011-05-03 Kent State University Nanostructured core-shell electrocatalysts for fuel cells
US20080104735A1 (en) * 2006-05-01 2008-05-08 Warwick Mills, Inc. Mosaic extremity protection system with transportable solid elements
US7874239B2 (en) * 2006-05-01 2011-01-25 Warwick Mills, Inc. Mosaic extremity protection system with transportable solid elements
US20080045405A1 (en) * 2006-06-09 2008-02-21 Tilman Wolfram Beutel Pt-Pd diesel oxidation catalyst with CO/HC light-off and HC storage function
US7875573B2 (en) * 2006-06-09 2011-01-25 Basf Corporation Pt-Pd diesel oxidation catalyst with CO/HC light-off and HC storage function
US20100092358A1 (en) * 2006-08-19 2010-04-15 Umicore Ag & Co.Kg Catalytically coated diesel particle filter, process for producing it and its use
US20080047261A1 (en) * 2006-08-28 2008-02-28 Heesung Catalysts Corporation Three-layered catalyst system for purifying exhaust gases of internal engines
US20080057212A1 (en) * 2006-08-30 2008-03-06 Sulzer Metco Ag Plasma spraying device and a method for introducing a liquid precursor into a plasma gas stream
US20100124514A1 (en) * 2006-09-14 2010-05-20 The Timken Company Method of producing uniform blends of nano and micron powders
US20080125313A1 (en) * 2006-11-27 2008-05-29 Fujdala Kyle L Engine Exhaust Catalysts Containing Palladium-Gold
US7534738B2 (en) * 2006-11-27 2009-05-19 Nanostellar, Inc. Engine exhaust catalysts containing palladium-gold
US7709414B2 (en) * 2006-11-27 2010-05-04 Nanostellar, Inc. Engine exhaust catalysts containing palladium-gold
US20080125308A1 (en) * 2006-11-27 2008-05-29 Fujdala Kyle L Engine Exhaust Catalysts Containing Palladium-Gold
US7517826B2 (en) * 2006-11-27 2009-04-14 Nanostellar, Inc. Engine exhaust catalysts containing zeolite and zeolite mixtures
US7905942B1 (en) * 2007-05-11 2011-03-15 SDCmaterials, Inc. Microwave purification process
US8142619B2 (en) * 2007-05-11 2012-03-27 Sdc Materials Inc. Shape of cone and air input annulus
US7897127B2 (en) * 2007-05-11 2011-03-01 SDCmaterials, Inc. Collecting particles from a fluid stream via thermophoresis
US7678419B2 (en) * 2007-05-11 2010-03-16 Sdc Materials, Inc. Formation of catalytic regions within porous structures using supercritical phase processing
US20110006463A1 (en) * 2007-05-11 2011-01-13 Sdc Materials, Inc. Gas delivery system with constant overpressure relative to ambient to system with varying vacuum suction
US20120045373A1 (en) * 2007-05-11 2012-02-23 Sdc Materials, Inc. Method and apparatus for making recyclable catalysts
US7704369B2 (en) * 2007-07-13 2010-04-27 University Of Southern California Electrolysis of carbon dioxide in aqueous media to carbon monoxide and hydrogen for production of methanol
US20090054230A1 (en) * 2007-08-20 2009-02-26 Badri Veeraraghavan Catalyst production process
US20090092887A1 (en) * 2007-10-05 2009-04-09 Quantumsphere, Inc. Nanoparticle coated electrode and method of manufacture
US20090098402A1 (en) * 2007-10-10 2009-04-16 Jeung-Ku Kang Nanocrater catalyst in metal nanoparticles and method for preparing the same
US20110052467A1 (en) * 2008-03-20 2011-03-03 University Of Akron Ceramic nanofibers containing nanosize metal catalyst particles and medium thereof
US8168561B2 (en) * 2008-07-31 2012-05-01 University Of Utah Research Foundation Core shell catalyst
US20100089002A1 (en) * 2008-10-15 2010-04-15 Merkel Composite Technologies, Inc. Composite structural elements and method of making same
US20120097033A1 (en) * 2009-02-26 2012-04-26 Johnson Matthey Public Limited Company Filter for filtering particulate matter from exhaust gas emitted from a compression ignition engine
US20140018230A1 (en) * 2009-12-15 2014-01-16 SDCmaterials, Inc. Method of forming a catalyst with inhibited mobility of nano-active material
US20120122660A1 (en) * 2010-02-01 2012-05-17 Johnson Matthey Public Limited Company Oxidation catalyst
US8349761B2 (en) * 2010-07-27 2013-01-08 Toyota Motor Engineering & Manufacturing North America, Inc. Dual-oxide sinter resistant catalyst
US20120124974A1 (en) * 2010-11-24 2012-05-24 Basf Corporation Advanced Catalyzed Soot Filters And Method Of Making And Using The Same
US20120023909A1 (en) * 2011-08-17 2012-02-02 Ford Global Technologies, Llc Methods and systems for an engine emission control system

Cited By (69)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9719727B2 (en) 2005-04-19 2017-08-01 SDCmaterials, Inc. Fluid recirculation system for use in vapor phase particle production system
US9216398B2 (en) 2005-04-19 2015-12-22 SDCmaterials, Inc. Method and apparatus for making uniform and ultrasmall nanoparticles
US9180423B2 (en) 2005-04-19 2015-11-10 SDCmaterials, Inc. Highly turbulent quench chamber
US9132404B2 (en) 2005-04-19 2015-09-15 SDCmaterials, Inc. Gas delivery system with constant overpressure relative to ambient to system with varying vacuum suction
US9023754B2 (en) 2005-04-19 2015-05-05 SDCmaterials, Inc. Nano-skeletal catalyst
US9599405B2 (en) 2005-04-19 2017-03-21 SDCmaterials, Inc. Highly turbulent quench chamber
US8604398B1 (en) 2007-05-11 2013-12-10 SDCmaterials, Inc. Microwave purification process
US8663571B2 (en) 2007-05-11 2014-03-04 SDCmaterials, Inc. Method and apparatus for making uniform and ultrasmall nanoparticles
US8524631B2 (en) 2007-05-11 2013-09-03 SDCmaterials, Inc. Nano-skeletal catalyst
US8906316B2 (en) 2007-05-11 2014-12-09 SDCmaterials, Inc. Fluid recirculation system for use in vapor phase particle production system
US8956574B2 (en) 2007-05-11 2015-02-17 SDCmaterials, Inc. Gas delivery system with constant overpressure relative to ambient to system with varying vacuum suction
US8574408B2 (en) 2007-05-11 2013-11-05 SDCmaterials, Inc. Fluid recirculation system for use in vapor phase particle production system
US8893651B1 (en) 2007-05-11 2014-11-25 SDCmaterials, Inc. Plasma-arc vaporization chamber with wide bore
US9592492B2 (en) 2007-10-15 2017-03-14 SDCmaterials, Inc. Method and system for forming plug and play oxide catalysts
US8481449B1 (en) 2007-10-15 2013-07-09 SDCmaterials, Inc. Method and system for forming plug and play oxide catalysts
US9186663B2 (en) 2007-10-15 2015-11-17 SDCmaterials, Inc. Method and system for forming plug and play metal compound catalysts
US9737878B2 (en) 2007-10-15 2017-08-22 SDCmaterials, Inc. Method and system for forming plug and play metal catalysts
US9089840B2 (en) 2007-10-15 2015-07-28 SDCmaterials, Inc. Method and system for forming plug and play oxide catalysts
US8507402B1 (en) 2007-10-15 2013-08-13 SDCmaterials, Inc. Method and system for forming plug and play metal catalysts
US8759248B2 (en) 2007-10-15 2014-06-24 SDCmaterials, Inc. Method and system for forming plug and play metal catalysts
US8507401B1 (en) 2007-10-15 2013-08-13 SDCmaterials, Inc. Method and system for forming plug and play metal catalysts
US9597662B2 (en) 2007-10-15 2017-03-21 SDCmaterials, Inc. Method and system for forming plug and play metal compound catalysts
US8575059B1 (en) 2007-10-15 2013-11-05 SDCmaterials, Inc. Method and system for forming plug and play metal compound catalysts
US9302260B2 (en) 2007-10-15 2016-04-05 SDCmaterials, Inc. Method and system for forming plug and play metal catalysts
US8906498B1 (en) 2009-12-15 2014-12-09 SDCmaterials, Inc. Sandwich of impact resistant material
US9126191B2 (en) 2009-12-15 2015-09-08 SDCmaterials, Inc. Advanced catalysts for automotive applications
US8865611B2 (en) 2009-12-15 2014-10-21 SDCmaterials, Inc. Method of forming a catalyst with inhibited mobility of nano-active material
US8545652B1 (en) 2009-12-15 2013-10-01 SDCmaterials, Inc. Impact resistant material
US8859035B1 (en) 2009-12-15 2014-10-14 SDCmaterials, Inc. Powder treatment for enhanced flowability
US8932514B1 (en) 2009-12-15 2015-01-13 SDCmaterials, Inc. Fracture toughness of glass
US8828328B1 (en) 2009-12-15 2014-09-09 SDCmaterails, Inc. Methods and apparatuses for nano-materials powder treatment and preservation
US8821786B1 (en) 2009-12-15 2014-09-02 SDCmaterials, Inc. Method of forming oxide dispersion strengthened alloys
US8992820B1 (en) 2009-12-15 2015-03-31 SDCmaterials, Inc. Fracture toughness of ceramics
US8803025B2 (en) 2009-12-15 2014-08-12 SDCmaterials, Inc. Non-plugging D.C. plasma gun
US20110143041A1 (en) * 2009-12-15 2011-06-16 SDCmaterials, Inc. Non-plugging d.c. plasma gun
US8877357B1 (en) 2009-12-15 2014-11-04 SDCmaterials, Inc. Impact resistant material
US9533289B2 (en) 2009-12-15 2017-01-03 SDCmaterials, Inc. Advanced catalysts for automotive applications
US9149797B2 (en) 2009-12-15 2015-10-06 SDCmaterials, Inc. Catalyst production method and system
US8668803B1 (en) 2009-12-15 2014-03-11 SDCmaterials, Inc. Sandwich of impact resistant material
US8652992B2 (en) 2009-12-15 2014-02-18 SDCmaterials, Inc. Pinning and affixing nano-active material
US9522388B2 (en) 2009-12-15 2016-12-20 SDCmaterials, Inc. Pinning and affixing nano-active material
US8470112B1 (en) 2009-12-15 2013-06-25 SDCmaterials, Inc. Workflow for novel composite materials
US9332636B2 (en) 2009-12-15 2016-05-03 SDCmaterials, Inc. Sandwich of impact resistant material
US8557727B2 (en) 2009-12-15 2013-10-15 SDCmaterials, Inc. Method of forming a catalyst with inhibited mobility of nano-active material
US9308524B2 (en) 2009-12-15 2016-04-12 SDCmaterials, Inc. Advanced catalysts for automotive applications
US9216406B2 (en) 2011-02-23 2015-12-22 SDCmaterials, Inc. Wet chemical and plasma methods of forming stable PtPd catalysts
US8669202B2 (en) 2011-02-23 2014-03-11 SDCmaterials, Inc. Wet chemical and plasma methods of forming stable PtPd catalysts
US9433938B2 (en) 2011-02-23 2016-09-06 SDCmaterials, Inc. Wet chemical and plasma methods of forming stable PTPD catalysts
US8679433B2 (en) 2011-08-19 2014-03-25 SDCmaterials, Inc. Coated substrates for use in catalysis and catalytic converters and methods of coating substrates with washcoat compositions
US8969237B2 (en) 2011-08-19 2015-03-03 SDCmaterials, Inc. Coated substrates for use in catalysis and catalytic converters and methods of coating substrates with washcoat compositions
US9498751B2 (en) 2011-08-19 2016-11-22 SDCmaterials, Inc. Coated substrates for use in catalysis and catalytic converters and methods of coating substrates with washcoat compositions
US10704837B2 (en) 2012-04-05 2020-07-07 R.B. Radley & Company Limited Laboratory condensers with passive heat exchange
GB2498820A (en) * 2012-04-05 2013-07-31 R B Radley & Co Ltd Condenser
WO2013150318A1 (en) 2012-04-05 2013-10-10 R.B. Radley & Company Limited Laboratory condensers with passive heat exchange
GB2498820B (en) * 2012-04-05 2014-04-16 R B Radley & Co Ltd Condensers
US9533299B2 (en) 2012-11-21 2017-01-03 SDCmaterials, Inc. Three-way catalytic converter using nanoparticles
US9156025B2 (en) 2012-11-21 2015-10-13 SDCmaterials, Inc. Three-way catalytic converter using nanoparticles
US9511352B2 (en) 2012-11-21 2016-12-06 SDCmaterials, Inc. Three-way catalytic converter using nanoparticles
US9586179B2 (en) 2013-07-25 2017-03-07 SDCmaterials, Inc. Washcoats and coated substrates for catalytic converters and methods of making and using same
US9566568B2 (en) 2013-10-22 2017-02-14 SDCmaterials, Inc. Catalyst design for heavy-duty diesel combustion engines
US9427732B2 (en) 2013-10-22 2016-08-30 SDCmaterials, Inc. Catalyst design for heavy-duty diesel combustion engines
US9950316B2 (en) 2013-10-22 2018-04-24 Umicore Ag & Co. Kg Catalyst design for heavy-duty diesel combustion engines
US9517448B2 (en) 2013-10-22 2016-12-13 SDCmaterials, Inc. Compositions of lean NOx trap (LNT) systems and methods of making and using same
US9687811B2 (en) 2014-03-21 2017-06-27 SDCmaterials, Inc. Compositions for passive NOx adsorption (PNA) systems and methods of making and using same
US10086356B2 (en) 2014-03-21 2018-10-02 Umicore Ag & Co. Kg Compositions for passive NOx adsorption (PNA) systems and methods of making and using same
US10413880B2 (en) 2014-03-21 2019-09-17 Umicore Ag & Co. Kg Compositions for passive NOx adsorption (PNA) systems and methods of making and using same
US10124322B2 (en) 2015-02-11 2018-11-13 Umicore Ag & Co. Kg Lean NOx traps, trapping materials, washcoats, and methods of making and using the same
CN107810655A (en) * 2015-06-26 2018-03-16 英特尔Ip公司 The apparatus and method for merging concurrently to send by conditional signal
CN111793838A (en) * 2020-05-27 2020-10-20 崔建中 Melt-blown cooling device applied to automatic production line of non-woven fabric

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JP6174639B2 (en) 2017-08-02
EP2150971A4 (en) 2013-05-01
EP2150971A1 (en) 2010-02-10
JP2014139509A (en) 2014-07-31
WO2008140819A1 (en) 2008-11-20
US20080277268A1 (en) 2008-11-13
US9173967B1 (en) 2015-11-03
JP6174635B2 (en) 2017-08-02
US20080277267A1 (en) 2008-11-13
US8956574B2 (en) 2015-02-17
JP2010526663A (en) 2010-08-05
US9132404B2 (en) 2015-09-15
JP2016027940A (en) 2016-02-25
US20080277271A1 (en) 2008-11-13
US20120045373A1 (en) 2012-02-23
WO2008143793A1 (en) 2008-11-27
US9023754B2 (en) 2015-05-05
EP2150641B1 (en) 2018-11-28
US20140209451A1 (en) 2014-07-31
WO2008143792A1 (en) 2008-11-27
EP2153157A1 (en) 2010-02-17
WO2008140785A1 (en) 2008-11-20
JP6069454B2 (en) 2017-02-01
US20080277270A1 (en) 2008-11-13
US7678419B2 (en) 2010-03-16
JP2010526661A (en) 2010-08-05
EP2152399A4 (en) 2013-05-01
EP2150641A1 (en) 2010-02-10
EP2150641A4 (en) 2013-05-01
US20080280756A1 (en) 2008-11-13
US20080280049A1 (en) 2008-11-13
US20080277269A1 (en) 2008-11-13
JP2010526986A (en) 2010-08-05
US8663571B2 (en) 2014-03-04
US9216398B2 (en) 2015-12-22
US9599405B2 (en) 2017-03-21
US8906316B2 (en) 2014-12-09
US8524631B2 (en) 2013-09-03
US20150314260A1 (en) 2015-11-05
EP2152453A1 (en) 2010-02-17
JP2015231626A (en) 2015-12-24

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