US20090113898A1 - thermoelectric water chiller and heater apparatus - Google Patents

thermoelectric water chiller and heater apparatus Download PDF

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Publication number
US20090113898A1
US20090113898A1 US11/934,545 US93454507A US2009113898A1 US 20090113898 A1 US20090113898 A1 US 20090113898A1 US 93454507 A US93454507 A US 93454507A US 2009113898 A1 US2009113898 A1 US 2009113898A1
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Prior art keywords
condenser
cold
hot
bottle receiver
boiler
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Abandoned
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US11/934,545
Inventor
Lance D. Kirol
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Rocky Research Corp
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Rocky Research Corp
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Priority to US11/934,545 priority Critical patent/US20090113898A1/en
Publication of US20090113898A1 publication Critical patent/US20090113898A1/en
Abandoned legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B21/00Machines, plants or systems, using electric or magnetic effects
    • F25B21/02Machines, plants or systems, using electric or magnetic effects using Peltier effect; using Nernst-Ettinghausen effect
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B23/00Machines, plants or systems, with a single mode of operation not covered by groups F25B1/00 - F25B21/00, e.g. using selective radiation effect
    • F25B23/006Machines, plants or systems, with a single mode of operation not covered by groups F25B1/00 - F25B21/00, e.g. using selective radiation effect boiling cooling systems
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2321/00Details of machines, plants or systems, using electric or magnetic effects
    • F25B2321/02Details of machines, plants or systems, using electric or magnetic effects using Peltier effects; using Nernst-Ettinghausen effects
    • F25B2321/025Removal of heat
    • F25B2321/0252Removal of heat by liquids or two-phase fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B29/00Combined heating and refrigeration systems, e.g. operating alternately or simultaneously

Definitions

  • thermoelectric water chiller and heater appliance for the U.S. Army.
  • the appliance provides chilled water, heated water, or both chilled and heated water simultaneously.
  • the primary intended use is in military vehicles, but the appliance may be used in any environment where heated and/or chilled liquid is desired.
  • the aforesaid appliance is illustrated in FIG. 1 as prior art.
  • the apparatus includes a hot bottle receiver 10 and a cold bottle receiver 20 .
  • Liquid to be heated or cooled is placed in tapered aluminum bottles and inserted into bottle receivers of the appliance. Liquid to be heated is always placed in a top bottle receiver, and liquid to be cooled in a lower receiver.
  • Three thermoelectric modules 21 , 22 and 23 provide heating and cooling. Phase-change refrigerant is heated in boilers 11 , 12 and 13 in which the refrigerant is vaporized by heat from the hot side of the thermoelectric module.
  • thermosyphon loop comprising a first pipe ( 18 ) for directing vaporized refrigerant to the hot bottle receiver 10 and a return pipe ( 17 ) for directing refrigerant to a separate auxiliary condenser and back to the boiler.
  • first pipe ( 18 ) for directing vaporized refrigerant to the hot bottle receiver 10
  • return pipe ( 17 ) for directing refrigerant to a separate auxiliary condenser and back to the boiler.
  • three different hot side thermosyphon loops and piping are required as are three separate auxiliary condensers 27 , 28 and 29 .
  • An equalization or liquid equilibration pipe 14 is also required and extends and communicates between the three boilers for liquid flow to maintain equal levels of refrigerant.
  • the thermosyphon loops communicate with each other at the bottle receiver.
  • three condensers 24 , 25 and 26 are in thermal communication with the cold side of the three thermoelectric modules, respectively.
  • Each of the condensers also cooperates with a separate phase-change thermosyphon loop for directing condensed refrigerant from a condenser via a pipe ( 15 ) to the cold bottle receiver 20 and a return pipe ( 16 ) for directing vaporized refrigerant back to the condenser.
  • the cold side thermosyphon loops communicate at the bottle receiver.
  • Removable aluminum bottles are used and received in the respective hot and cold bottle receivers which are tapered to match the taper of the aluminum bottles and provide good thermal contact.
  • Auxiliary fans not shown, provide heat rejection for the auxiliary condensers.
  • the apparatus of the present invention simplifies the design by utilizing counter-flow liquid and vapor ducts between the boiler and hot bottle receiver and between the condenser and cold bottle receiver, respectively.
  • a single boiler is used, and in a preferred embodiment, a single condenser is also used.
  • FIG. 1 a perspective view of the prior art design, previously described, is shown
  • FIG. 2 is a schematic view of components of the improved apparatus design
  • FIG. 3 is a perspective view showing the components of the improved apparatus.
  • FIG. 4 is a perspective view of a preferred thermosyphon boiler and condenser design.
  • the apparatus includes a hot bottle receiver 30 comprising a tapered cylindrical jacket having an annular space in which heated refrigerant vapor from boiler 31 provides heat to the receiver for heating a bottle 41 inserted into the bottle receiver.
  • An auxiliary condenser 36 is positioned along the counter-flow thermosyphon ducts 38 which communicates the boiler 31 with the hot bottle receiver 30 .
  • Each thermosyphon duct 38 provides counter-flow of liquid and vapor simultaneously between the bottle receiver and boiler in each tube.
  • auxiliary condenser 36 is cooled by a fan 37 .
  • the auxiliary condenser design is modular, incorporating a plurality of flat, planar fins each of which physically contacts and substantially envelops the thermosyphon ducts or tubes.
  • the modular auxiliary condenser is a fintube assembly replacing the individual finned tube auxiliary condensers used in the prior art appliance.
  • Such a modular auxiliary condenser design simplifies the assembly, provides better air flow without complicated fan or ducting arrangements, and also provides improved heat rejection.
  • the auxiliary condensers are used to reject heat after the hot water has reached target temperature, e.g., 140° F.
  • target hot water temperature will be reached before the cold water target temperature, e.g., 60° F.
  • Such continued heat rejection permits continued cooling of water in the cold bottle receiver after the hot water target temperature is reached.
  • Such hot-side heat rejection provides for maintenance of a heat balance around the thermoelectric module independent of heat flow to or from the fluid containing bottles.
  • a cold bottle receiver 32 On the cold side, a cold bottle receiver 32 , always the lower receiver, is tapered in a manner as previously described regarding the hot bottle receiver.
  • a condenser 33 communicates with the cold bottle receiver 32 via counter-flow liquid and vapor thermosyphon ducts 39 in which liquid and vapor flow simultaneously during operation of the appliance apparatus.
  • a plurality of counter-flow ducts are used on the hot and/or the cold sides of the apparatus.
  • the condenser is sized so that in most ambient temperature conditions, hot-side temperature drops when fans are operated.
  • the apparatus includes a plurality of thermoelectric (TE) modules 35 positioned end-to-end.
  • thermoelectric modules typically comprise two ceramic plates with bismuth telluride pellets between the ceramic plates. A direct electrical current flows through the device moving heat from one side to the other, one side becoming cool, the other side hot.
  • thermoelectric modules are well known to those skilled in the art and are not described further in this specification.
  • the ceramic plates on each side of the thermoelectric device have a substantially flat, planar surface against which the respective condenser and boiler are juxtapositioned.
  • Each condenser and boiler is provided with a substantially flat, planar surface portion which is juxtapositioned against the respective hot and cold side of the thermoelectric modules.
  • the boiler comprises a single extrusion contacting all three thermoelectric modules.
  • a single extrusion design 40 is illustrated having a substantially flat, planar exterior surface portion 45 , and a plurality of heat exchange surfaces 46 formed on the interior of the component.
  • the condenser is of the single extrusion design illustrated, similar to the boiler extrusion.
  • the condenser and/or the boiler may be divided into three separate extrusions of the same design which are aligned end-to-end. Using separate extrusions for each TE module on at least one side will provide good thermal contact with all TE modules without imposing excessively restrictive thickness tolerances on the modules.
  • nominal specifications of an apparatus as described above may include the following:
  • heating and cooling may be carried out irrespective of starting water temperatures or the mass of liquid (water) in either bottle. Moreover, heating or cooling may be accomplished independently, with only one bottle positioned in a bottle receiver, hot or cold. Operation of the appliance will continue after target temperatures are reached. Preferably, the apparatus will be configured to stop heating at a maximum 170° F. hot bottle temperature. Chilled water cooling may be continued with freeze protection shut down configuration preferred.

Abstract

The appliance provides chilled water, heated water, or both chilled and heated water simultaneously. The primary intended use is in military vehicles, but the appliance may be used in any environment where heated and/or chilled liquid is desired.

Description

    BACKGROUND OF THE INVENTION
  • Rocky Research, of Boulder City, Nev., has developed a prototype thermoelectric water chiller and heater appliance for the U.S. Army. The appliance provides chilled water, heated water, or both chilled and heated water simultaneously. The primary intended use is in military vehicles, but the appliance may be used in any environment where heated and/or chilled liquid is desired.
  • The aforesaid appliance is illustrated in FIG. 1 as prior art. The apparatus includes a hot bottle receiver 10 and a cold bottle receiver 20. Liquid to be heated or cooled is placed in tapered aluminum bottles and inserted into bottle receivers of the appliance. Liquid to be heated is always placed in a top bottle receiver, and liquid to be cooled in a lower receiver. Three thermoelectric modules 21, 22 and 23 provide heating and cooling. Phase-change refrigerant is heated in boilers 11, 12 and 13 in which the refrigerant is vaporized by heat from the hot side of the thermoelectric module. Each of the three boilers cooperates with a thermosyphon loop comprising a first pipe (18) for directing vaporized refrigerant to the hot bottle receiver 10 and a return pipe (17) for directing refrigerant to a separate auxiliary condenser and back to the boiler. Thus, three different hot side thermosyphon loops and piping are required as are three separate auxiliary condensers 27, 28 and 29. An equalization or liquid equilibration pipe 14 is also required and extends and communicates between the three boilers for liquid flow to maintain equal levels of refrigerant. The thermosyphon loops communicate with each other at the bottle receiver.
  • On the cold side of the appliance, three condensers 24, 25 and 26 are in thermal communication with the cold side of the three thermoelectric modules, respectively. Each of the condensers also cooperates with a separate phase-change thermosyphon loop for directing condensed refrigerant from a condenser via a pipe (15) to the cold bottle receiver 20 and a return pipe (16) for directing vaporized refrigerant back to the condenser. Like the hot side, the cold side thermosyphon loops communicate at the bottle receiver.
  • Removable aluminum bottles are used and received in the respective hot and cold bottle receivers which are tapered to match the taper of the aluminum bottles and provide good thermal contact. Auxiliary fans, not shown, provide heat rejection for the auxiliary condensers.
  • SUMMARY OF THE INVENTION
  • The apparatus of the present invention simplifies the design by utilizing counter-flow liquid and vapor ducts between the boiler and hot bottle receiver and between the condenser and cold bottle receiver, respectively. In the apparatus, a single boiler is used, and in a preferred embodiment, a single condenser is also used. These improvements will be further described in the detailed description.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • In FIG. 1, a perspective view of the prior art design, previously described, is shown;
  • FIG. 2 is a schematic view of components of the improved apparatus design;
  • FIG. 3 is a perspective view showing the components of the improved apparatus; and
  • FIG. 4 is a perspective view of a preferred thermosyphon boiler and condenser design.
  • DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
  • Referring to FIGS. 2 and 3, the apparatus includes a hot bottle receiver 30 comprising a tapered cylindrical jacket having an annular space in which heated refrigerant vapor from boiler 31 provides heat to the receiver for heating a bottle 41 inserted into the bottle receiver. An auxiliary condenser 36 is positioned along the counter-flow thermosyphon ducts 38 which communicates the boiler 31 with the hot bottle receiver 30. Each thermosyphon duct 38 provides counter-flow of liquid and vapor simultaneously between the bottle receiver and boiler in each tube.
  • An auxiliary condenser 36 is cooled by a fan 37. The auxiliary condenser design is modular, incorporating a plurality of flat, planar fins each of which physically contacts and substantially envelops the thermosyphon ducts or tubes. The modular auxiliary condenser is a fintube assembly replacing the individual finned tube auxiliary condensers used in the prior art appliance. Such a modular auxiliary condenser design simplifies the assembly, provides better air flow without complicated fan or ducting arrangements, and also provides improved heat rejection. The auxiliary condensers are used to reject heat after the hot water has reached target temperature, e.g., 140° F. Normally, target hot water temperature will be reached before the cold water target temperature, e.g., 60° F. Such continued heat rejection permits continued cooling of water in the cold bottle receiver after the hot water target temperature is reached. Such hot-side heat rejection provides for maintenance of a heat balance around the thermoelectric module independent of heat flow to or from the fluid containing bottles.
  • On the cold side, a cold bottle receiver 32, always the lower receiver, is tapered in a manner as previously described regarding the hot bottle receiver. A condenser 33 communicates with the cold bottle receiver 32 via counter-flow liquid and vapor thermosyphon ducts 39 in which liquid and vapor flow simultaneously during operation of the appliance apparatus. Typically, a plurality of counter-flow ducts are used on the hot and/or the cold sides of the apparatus.
  • The condenser is sized so that in most ambient temperature conditions, hot-side temperature drops when fans are operated. The apparatus includes a plurality of thermoelectric (TE) modules 35 positioned end-to-end. Such thermoelectric modules typically comprise two ceramic plates with bismuth telluride pellets between the ceramic plates. A direct electrical current flows through the device moving heat from one side to the other, one side becoming cool, the other side hot. Such thermoelectric modules are well known to those skilled in the art and are not described further in this specification. The ceramic plates on each side of the thermoelectric device have a substantially flat, planar surface against which the respective condenser and boiler are juxtapositioned. Each condenser and boiler is provided with a substantially flat, planar surface portion which is juxtapositioned against the respective hot and cold side of the thermoelectric modules.
  • In the design of the improved appliance of the invention, the boiler comprises a single extrusion contacting all three thermoelectric modules. In FIG. 4, such a single extrusion design 40 is illustrated having a substantially flat, planar exterior surface portion 45, and a plurality of heat exchange surfaces 46 formed on the interior of the component. In a preferred embodiment of the appliance of the invention, the condenser is of the single extrusion design illustrated, similar to the boiler extrusion. Alternatively, the condenser and/or the boiler may be divided into three separate extrusions of the same design which are aligned end-to-end. Using separate extrusions for each TE module on at least one side will provide good thermal contact with all TE modules without imposing excessively restrictive thickness tolerances on the modules.
  • The design improvements of the appliance described hereinabove reduce manufacturing cost and provide a more compact package. The use of a modular auxiliary condenser also provides improved performance and operating efficiency.
  • By way of example only, nominal specifications of an apparatus as described above may include the following:
      • Cool 16 oz. water to 60° F. and heat 16 oz. water to 140° F. in 20 min. or less from 76° F. ambient.
      • Size: 12″×7¾″×6¾
      • Weight: 8.3 lbs.
      • Power consumption: 250 W max.
      • R134a refrigerant
  • In operation of the above-described apparatus, heating and cooling may be carried out irrespective of starting water temperatures or the mass of liquid (water) in either bottle. Moreover, heating or cooling may be accomplished independently, with only one bottle positioned in a bottle receiver, hot or cold. Operation of the appliance will continue after target temperatures are reached. Preferably, the apparatus will be configured to stop heating at a maximum 170° F. hot bottle temperature. Chilled water cooling may be continued with freeze protection shut down configuration preferred.

Claims (6)

1. An apparatus for providing hot and/or cold liquid comprising:
a hot bottle receiver;
a cold bottler receiver;
one or more thermoelectric modules having a hot side and a cold side;
a boiler in thermal communication with the thermoelectric module hot side;
a condenser in thermal communication with the thermoelectric module cold side;
one or more first counter-flow refrigerant thermosyphon ducts extending between said boiler and said hot bottle receiver and configured for concurrently directing refrigerant vapor from said boiler to said hot bottle receiver and condensed refrigerant from said hot bottle receiver to said boiler;
an auxiliary condenser comprising a fan and a modular fintube assembly juxtapositioned along said one or more first thernosyphon ducts and configured for condensing refrigerant vapor therein; and
one or more second counter-flow refrigerant thermosyphon ducts extending between said condenser and said cold bottle receiver and configured for concurrently directing refrigerant vapor from said cold bottle receiver to said condenser and condensed refrigerant from said condenser to said cold bottle receiver.
2. An apparatus for providing hot and/or cold liquid comprising:
a plurality of thermoelectric modules aligned side-by-side, and having substantially flat, coplanar hot side surfaces, and substantially flat, coplanar cold side surfaces;
a hot bottle receiver positioned above the said thermoelectric modules, and a cold bottle receiver positioned below said thermoelectric modules;
a boiler comprising a single boiler module having a substantially flat, planar exterior surface portion juxtapositioned against the flat, coplanar hot side surfaces of all of said plurality of thermoelectric modules;
a condenser assembly comprising one or more modules having a substantially flat, planar surface portion juxtapositioned against the flat, coplanar cold side surfaces of said thermoelectric modules;
one or more first counter-flow refrigerant thermosyphon ducts extending between said boiler and said hot bottle receiver and configured for concurrently directing refrigerant vapor from said boiler to said hot bottle receiver and condensed refrigerant from said hot bottle receiver to said boiler;
an auxiliary condenser comprising a fan and a modular fintube assembly juxtapositioned along said one or more first thermosyphon tubes and configured for condensing refrigerant vapor therein; and
a second counter-flow refrigerant thermosyphon duct extending between said condenser and said cold bottle receiver and configured for concurrently directing refrigerant vapor from said cold bottle receiver to said condenser and condensed refrigerant from said condenser to said cold bottle receiver.
3. An apparatus of claim 2 comprising three said thermoelectric modules and wherein said condenser assembly comprises three said condenser modules aligned end-to-end along said substantially flat, coplanar cold side surfaces of said thermoelectric modules.
4. An apparatus of claim 2 wherein said condenser assembly comprises a single condenser module having a substantially flat, planar exterior surface portion juxtapositioned against the flat, coplanar cold side surfaces of said thermoelectric module.
5. An apparatus of claim 4 comprising three said thermoelectric modules.
6. An apparatus of claim 1 wherein said fintube assembly comprises a plurality of fins each of which physically contacts and substantially envelopes said one or more first thermosyphon ducts.
US11/934,545 2007-11-02 2007-11-02 thermoelectric water chiller and heater apparatus Abandoned US20090113898A1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11103830B2 (en) 2015-09-02 2021-08-31 Electrophor, Inc. Method for purifying a liquid
US11439955B2 (en) 2015-09-02 2022-09-13 Electrophor, Inc. System for purifying a liquid

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US3986550A (en) * 1973-10-11 1976-10-19 Mitsubishi Denki Kabushiki Kaisha Heat transferring apparatus
US4353415A (en) * 1979-07-30 1982-10-12 United Kingdom Atomic Energy Authority Heat pipes and thermal siphons
US4715431A (en) * 1986-06-09 1987-12-29 Air Products And Chemicals, Inc. Reboiler-condenser with boiling and condensing surfaces enhanced by extrusion
US4785875A (en) * 1987-11-12 1988-11-22 Stirling Thermal Motors, Inc. Heat pipe working liquid distribution system
US4833888A (en) * 1987-01-29 1989-05-30 James M. Kerner Thermoelectric heating and/or cooling system using liquid for heat exchange
US5269146A (en) * 1990-08-28 1993-12-14 Kerner James M Thermoelectric closed-loop heat exchange system
US5308920A (en) * 1992-07-31 1994-05-03 Itoh Research & Development Laboratory Co., Ltd. Heat radiating device
US5343940A (en) * 1992-10-29 1994-09-06 Amigo Jean Flexible heat transfer device
US5647429A (en) * 1994-06-16 1997-07-15 Oktay; Sevgin Coupled, flux transformer heat pipes
US5720171A (en) * 1996-06-11 1998-02-24 Atoma International, Inc. Device for heating and cooling a beverage
US5737923A (en) * 1995-10-17 1998-04-14 Marlow Industries, Inc. Thermoelectric device with evaporating/condensing heat exchanger
US5970719A (en) * 1998-03-02 1999-10-26 Merritt; Thomas Heating and cooling device
US6170267B1 (en) * 1998-08-28 2001-01-09 Shimadzu Corporation Sample cooling apparatus and methods
US6412287B1 (en) * 2000-12-21 2002-07-02 Delphi Technologies, Inc. Heated/cooled console storage unit and method
US6418729B1 (en) * 1998-05-14 2002-07-16 Consejo Superior De Investigaciones Cientificas Domestic refrigerator with peltier effect, heat accumulators and evaporative thermosyphons
US6732533B1 (en) * 2002-08-23 2004-05-11 John P. Giles Combined bottle cooling and heating device

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2928253A (en) * 1958-04-07 1960-03-15 Whirlpool Co Thermoelectric apparatus for cooling and heating liquids
US3986550A (en) * 1973-10-11 1976-10-19 Mitsubishi Denki Kabushiki Kaisha Heat transferring apparatus
US4353415A (en) * 1979-07-30 1982-10-12 United Kingdom Atomic Energy Authority Heat pipes and thermal siphons
US4715431A (en) * 1986-06-09 1987-12-29 Air Products And Chemicals, Inc. Reboiler-condenser with boiling and condensing surfaces enhanced by extrusion
US4833888A (en) * 1987-01-29 1989-05-30 James M. Kerner Thermoelectric heating and/or cooling system using liquid for heat exchange
US4785875A (en) * 1987-11-12 1988-11-22 Stirling Thermal Motors, Inc. Heat pipe working liquid distribution system
US5269146A (en) * 1990-08-28 1993-12-14 Kerner James M Thermoelectric closed-loop heat exchange system
US5308920A (en) * 1992-07-31 1994-05-03 Itoh Research & Development Laboratory Co., Ltd. Heat radiating device
US5343940A (en) * 1992-10-29 1994-09-06 Amigo Jean Flexible heat transfer device
US5647429A (en) * 1994-06-16 1997-07-15 Oktay; Sevgin Coupled, flux transformer heat pipes
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US6418729B1 (en) * 1998-05-14 2002-07-16 Consejo Superior De Investigaciones Cientificas Domestic refrigerator with peltier effect, heat accumulators and evaporative thermosyphons
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11103830B2 (en) 2015-09-02 2021-08-31 Electrophor, Inc. Method for purifying a liquid
US11439955B2 (en) 2015-09-02 2022-09-13 Electrophor, Inc. System for purifying a liquid

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