US20090267181A1 - Semiconductor device and manufacturing method thereof - Google Patents
Semiconductor device and manufacturing method thereof Download PDFInfo
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- US20090267181A1 US20090267181A1 US12/494,855 US49485509A US2009267181A1 US 20090267181 A1 US20090267181 A1 US 20090267181A1 US 49485509 A US49485509 A US 49485509A US 2009267181 A1 US2009267181 A1 US 2009267181A1
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- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/525—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body with adaptable interconnections
- H01L23/5256—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body with adaptable interconnections comprising fuses, i.e. connections having their state changed from conductive to non-conductive
- H01L23/5258—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body with adaptable interconnections comprising fuses, i.e. connections having their state changed from conductive to non-conductive the change of state resulting from the use of an external beam, e.g. laser beam or ion beam
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- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76829—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers
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- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76837—Filling up the space between adjacent conductive structures; Gap-filling properties of dielectrics
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- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
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- H01L21/76829—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers
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Definitions
- the present invention generally relates to a semiconductor device provided with repair fuses and a manufacturing method thereof, and more specifically, to a semiconductor device for a Ball Grid Allay (BGA) package and a manufacturing method thereof.
- BGA Ball Grid Allay
- a conventional semiconductor device is provided with various types of circuit elements forming circuits and wirings interconnecting the circuit elements on a silicon substrate, for example. Those wirings usually are formed in a multi-level structure. On an uppermost wiring layer, electrodes for external connections (which is defined as a pad hereinafter), and repair fuses for replacing a defective circuit with a redundant circuit are formed.
- FIG. 6 is a sectional view schematically showing the uppermost wiring layer of a conventional semiconductor device.
- a fuse 3 a, a wiring 3 b, and a pad 3 c are formed on an interlayer insulator 1 , as the uppermost wiring layer 3 .
- Under the interlayer insulator 1 there is a semiconductor substrate, on which other wiring layers and circuit elements such as transistor are formed.
- a passivation film 5 made of dense silicon nitride film is formed by Chemical Vapor Deposition process (CVD) in order to prevent a mechanical breakdown and penetration of moisture or impurities such as sodium ion that causes failure of the semiconductor device.
- CVD Chemical Vapor Deposition process
- An opening 7 for exposing a part of a surface of the pad 3 c is formed by etching on the passivation film 5 .
- the passivation film 5 on the fuse 3 a is also etched to form an opening 6 in need of carrying out the following cutting process, resulting that the thickness of the passivation film 5 becomes thinner than the other portions. For instance, while the passivation film 5 is approximately 1000 nm in thickness, the film thickness at the opening 6 is approximately 150 nm.
- the fuse 3 a as well as the wiring 3 b, consists of a metal like the aluminum alloy.
- the necessity of the fuse cutting is decided according to an analysis of electrical characteristics test through the pad 3 c. If the fuse cutting is required, the fuse 3 a is heated by irradiation of a laser or a charged beam (an ion beam, for example) through the thin passivation film 5 , and then the fuse 3 a is blown and cut by liquefying and evaporating. According to this process, the defective circuit is turned out to be replaced with the redundant circuit.
- the cutting process of the fuse 3 a can be carried out.
- the cutting process will cause damages to the other portions other than the fuse 3 a, the amount of irradiation energy of the laser cannot be increased needlessly. That is, when the fuse cutting is carried out on the fuse 3 a coated by the thick passivation film 5 , the processing time increases depending on the thickness of the passivation film 5 . Therefore, by letting passivation film 5 thinner on the fuse 3 a as mentioned above, the cutting process of the fuse 3 a can be easily carried out and the penetration of moisture or impurities into non-cutting fuses 3 a is prevented.
- a bump is formed on the passivation film 5 illustrated in FIG. 6 in a following way.
- An opening for exposing a part of the surface of the pad 3 c is formed through the surface insulating film 31 .
- a barrier metal layer 32 made of such as nickel is formed in order to improve the adhesion between a bump material (solder) filling the opening by subsequent steps and the surface insulating film 31 , and also to prevent the bump material from diffusing to the surface insulating film 31 .
- a metal mask having an opening in bump formation position that corresponds to the barrier metal layer 32 is placed, and a solder paste is patterned through the metal mask. After the patterned solder paste is reflowed, a spherical solder bump 33 is formed by the action of the surface tension.
- the respective gaps between wirings 3 b, forming the uppermost wiring layer 3 become narrow, as shown in FIG. 7 . Accordingly, at such region of wirings 3 b being in close, the passivation film 5 has excessive uneven structure due to the uneven structure of wirings 3 b. Additionally, in the process of forming the passivation film 5 in such region, the film material on the wirings 3 b has been connected before the gaps between the wirings 3 b are completely filled, whereby a void 41 being not filled with the passivation film 5 is formed between the wirings 3 b.
- the thick surface insulating film 31 is formed on the passivation film 5 , as shown in FIG. 7 .
- This structure makes it easy to generate a large stress by the heating in forming the solder bump 33 . Consequently, when the stresses are concentrated on the uneven structure of the passivation film 5 and the voids 41 are existed therein, cracks 42 will appear in the passivation film 5 and the interlayer insulator 1 .
- the passivation film 5 is formed in a two-layer structure including a first insulating film 11 and a second insulating film 12 .
- the first insulating film 11 has a high filling capability for the gaps between the wirings 3 b , and is superior in planarization of a surface of a generated film, like a silicon dioxide film deposited by CVD process using source gas including Silane (e.g. SiH 4 and O 2 mixture), for example.
- the second insulting film 12 consists of silicon nitride film placed on the first insulting film 11 that prevents moisture or impurities penetrating into the first insulating film 11 .
- the passivation film is formed in such two-layer structure wherein the first insulating film 11 with the high filling capability is placed under the second insulating film 12 , the generation of voids 41 can be prevented, and the uneven structure of the passivation film also can be improved significantly. In result, it is possible to mitigate the stress concentration and avoid the occurrence of cracks 42 .
- the opening is formed on the fuse 3 a after the deposition of the second insulating film 12 is completed.
- FIG. 8B an enlarged view of a portion A in FIG. 8A before the deposition of the surface insulating film 31
- the structure on the fuse 3 a is that the first insulating film 11 is exposed by etching the second insulating film 12 , or the top surface of the fuse 3 a is exposed by etching the first insulating film 11 together with the second insulating film 12 .
- the semiconductor manufacturing process is categorized to two processes, a front-end process and a back-end process.
- the front-end process is for forming the semiconductor device on the semiconductor wafer, which corresponds to the steps up to the cutting process of the fuse 3 a in the above example.
- the back-end process is for sealing the semiconductor device in the BGA package, which corresponds to the steps after forming the surface insulating film 31 in the above example.
- the back-end process is carried out at a different place from the front-end process. Therefore, after the fuse 3 a is cut in the front-end process, the semiconductor device is kept in the state that the first insulating film 11 (or the fuse 3 a ) is exposed, before the device is sent to the next back-end process.
- the first insulating film 11 has no resistibility to the penetration of moisture or impurities. If moisture or impurities reach the fuse 3 a before the back-end process and the problems of corrosion and so forth are caused, that become a factor of reducing the long-term reliability of the semiconductor device.
- the present invention is suggested in view of the above conventional conditions, and has an object to provide a semiconductor device capable of avoiding the occurrence of cracks caused from the stress concentration, and preventing the penetration of moisture or impurities to the fuse, and has an object of providing the manufacturing method thereof.
- the invention premises a method of manufacturing a semiconductor device provided with a fuse to be cut to modify a circuit configuration if necessary.
- the method an uppermost wiring layer of the semiconductor device described above is coated, a first insulting film which completely fills a gap between members included in the wiring layer is formed, and a second insulating film, which have higher blocking capability against penetration of moisture or impurities than the first insulating film, is formed by coating the first insulating film.
- a third insulating film is formed so as to have the blocking capability of the same level or the higher level than that of the second insulating film, and coat at least the etched portion.
- the insulating films on the fuse may be completely etched, or may be etched so as to leave the insulating film at a thickness not disturbing the cutting of the fuse.
- the fuse not required to cut is coated by the third insulating film with the blocking capability, it is possible to prevent the penetration of moisture or impurities so as to reduce the defective fuse.
- the first insulating film may be a silicon nitride film deposited by CVD.
- silicon nitride film deposited by CVD with a high resistibility (blocking capability) to the penetration of moisture or impurities for the second and third insulating films.
- the invention can provide a semiconductor device having a structure manufactured by the above method. That is, the semiconductor device in the invention, which is provided with a fuse to be cut to modify a circuit configuration if necessary, comprises a first insulating film coating an uppermost wiring layer of the semiconductor device, and completely filling a gap between members included in the wiring layer, and a second insulating film having higher blocking capability against penetration of moisture or impurities than the first insulating film, and coating the first insulating film.
- the fuse comprises an opening formed on the fuse provided to any wiring layer of the semiconductor device, and having a specific depth from the top surface of the second insulating film, and a third insulating film having blocking capability of the same level or higher level than that of the second insulating film, and coating at least the opening.
- the penetration of moisture or impurities to the fuse can be prevented, so that the defective fuse can be reduced. Therefore, it is possible to improve the long-term reliability of the semiconductor device remarkably.
- FIG. 1 is a sectional view of a relevant part of a semiconductor device of the present invention.
- FIGS. 2A to 2C show sectional views of manufacturing processes of a semiconductor device of the present invention.
- FIGS. 3A to 3C show sectional views of manufacturing processes of a semiconductor device of the present invention.
- FIGS. 4A and 4B show sectional views of manufacturing processes of a semiconductor device of the present invention.
- FIGS. 5A to 5C show sectional views of modified manufacturing processes of a semiconductor device of the present invention.
- FIG. 6 is a sectional view of a relevant part of a semiconductor device with a conventional passivation film in a single-level structure.
- FIG. 7 is a sectional view of a relevant part of a semiconductor device with a conventional passivation film in a single-level structure.
- FIGS. 8A to 8B show sectional view of a relevant part of a semiconductor device with a conventional passivation film in a two-level structure.
- FIG. 1 is a sectional view showing a relevant part of a semiconductor device in a first embodiment of the invention.
- FIGS. 2A to 2C , FIGS. 3A to 3C and FIGS. 4A to 4B are sectional views showing the processes for manufacturing an uppermost wiring layer of the semiconductor device in FIG. 1 .
- a structure of the semiconductor device in this embodiment is illustrated hereinafter together with the manufacturing processes thereof.
- the uppermost wiring layer in the semiconductor device is formed on an interlayer insulator 1 (a base insulator 1 ) made of silicon dioxide film, so that the uppermost wiring layer may not be electrically connected to wirings and circuit elements in a lower wiring layer.
- a semiconductor substrate is formed by a conventional fabricating method, with which other wirings and circuits elements like a transistor are formed. Since the conventional fabricating method of the semiconductor substrate does not relate to the present invention directly, the description is omitted here.
- the uppermost wiring layer may be formed by a conventional microfabrication technique, using a conventional wiring material for the semiconductor device.
- the invention does not define the material and the fabrication method in particular.
- the uppermost wiring layer may be formed as following processes.
- a metal film 2 made of aluminum alloy is deposited over the base insulator 1 .
- a resist pattern (not shown in the drawing) is formed on the parts of metal film 2 on which metal patterns of such as a fuse 3 a, a wiring 3 b and a pad 3 c are formed by the photolithography.
- the metal film 2 is etched using the resist pattern as an etching mask, whereby a wiring layer 3 such as a fuse 3 a, a wiring 3 b and a pad 3 c, are formed.
- the thickness of the metal film 2 is defined as 850 nm.
- the metal film 2 is not always required to be a single-layer structure, and the structure may be a multi-layer structure depositing plural types of metals or metal alloys.
- a first insulating film 11 is formed on the fuse 3 a, the wiring 3 b and the pad 3 c.
- the first insulating film 11 is formed thick enough to completely fill at least the gap between the wirings 3 b so as not to allow any space.
- the method and material for forming the first insulating film 11 is not limited in particular.
- the first insulating film 11 high Density Plasma—Non Doped Silicon Glass, using SiH 4 and O 2 as source gas
- high-density plasma CVD such as Microwave Excited High Density plasma CVD, ECR (Electron Cyclotron Resonance) CVD, and ICP (Inductively Coupled Plasma) CVD are used.
- This HDP-NSG film has a superior gap filling capability that can fill gaps with high aspect ratio, and allows a subsequent layer to be deposited smoothly.
- the thickness of the first insulating film 11 in the embodiment, is defined as 1100 nm which is thick enough to fill gaps between the wirings 3 b without any space.
- a silicon nitride film by Plasma CVD using SiH 4 and NH 3 as source gas, or a silicon dioxide film by Plasma CVD or Thermal CVD as TEOS (Tetraethoxysilane)/O 2 system or TEOS/O 3 system can be also used.
- TEOS Tetraethoxysilane
- TEOS/O 3 system TEOS/O 3 system
- a second insulating film 12 which is denser than the first insulating film 11 is formed on the first insulating film 11 .
- the second insulating film 12 has a high resistibility to the penetration of moisture or impurities.
- the silicon nitride film deposited by Plasma CVD which is widely used as the passivation film so far, is used as the second insulating film 12 .
- the second insulating film 12 may be desirably deposited in thickness enough to prevent the penetration of moisture or impurities, which is defined as approximately 600 nm.
- an opening 21 is formed in the insulting layers above the fuse 3 a (the first insulating film 11 and the second insulating film 12 ) by removing the insulating films up to the specific depth from a top surface of the second insulating film 12 .
- a conventional etching technique may be used for forming the opening 21 .
- resist is coated on the second insulating film 12 , before a resist pattern with openings at a projected place of the opening 21 is formed by the photolithography.
- the second insulating film 12 and the first insulating film 11 are dry-etched sequentially by using etching gases suitable for respective insulating films (for example, CF 4 or Halogen).
- etching gases suitable for respective insulating films for example, CF 4 or Halogen.
- a part of the first insulating film 11 is left as a coating film 11 a .
- the thickness of the coating film 11 a is 150 nm.
- the thickness of the coating film 11 a is decided by controlling the amount of etching in the above etching process.
- an etch-stop film may be formed. That is, the first insulating film 11 is deposited in thickness up to the thickness of being left as the coating film 11 a , and the deposition of the first insulating film 11 is stopped temporarily. Then the etch-stop film is formed on the position at least facing to the fuse 3 a (above the fuse 3 a ) on the first insulting film 11 , using a material which can secure the etching selectivity against the first insulating film 11 . Next, the deposition of the insulating film 11 is restarted.
- the deposition of the first insulating film 11 is completed.
- the silicon nitride film can be used as the etch-stop film.
- the amount of etching of the first insulating film 11 can be limited by the etch-stop film. Therefore, an over-etching can be performed, and the film thickness of the coating film 11 a can be controlled in a simple manner. Moreover, since the thickness of the coating film 11 a on the fuse 3 a across a semiconductor wafer on which the semiconductor device is formed is extremely uniform, the laser irradiation condition for the cutting of the fuse 3 a can be fixed, and the fuse cutting can be performed effectively.
- a third insulating film 13 having a resistibility to the penetration of the moisture or impurities is formed thin in the same way as the second insulating film 12 as shown in FIG. 3B .
- the silicon nitride film which is deposited by Plasma CVD, is used to the third insulating film 13 as well as the second insulating film 12 , and the film thickness is defined as approximately 200 nm.
- the third insulating film 13 is desired to be deposited as thick as possible so as not to prevent the cutting of the fuse 3 a , and therefore the thickness of all the films on the fuse 3 a is desired to be 500 nm or less.
- the third insulating film 13 may be deposited at least over a surface of the opening 21 above the fuse 3 a. In an example shown in FIGS. 3A to 3C , however, the third insulating film 13 is formed over a whole surface in order to simplify the manufacturing process. After the third insulating film 13 is formed, the opening 22 for the external connection is formed on the pad 3 c as shown in FIG. 3C .
- the semiconductor device is completed. That is to say, the electric characteristics of the semiconductor device is measured through the pad 3 c, and in accordance with the measurement result, it is decided whether or not to cut the fuse 3 a.
- the fuse 3 a is irradiated by laser (or charging beam, and so on), and then is cut together with the insulating films thereon (the coating film la and the third insulating film 13 ).
- the cutting process is not performed on the fuse 3 a.
- the third insulating film 13 made of the silicon nitride film with the blocking capability against moisture or impurities is formed on the fuse 3 a without being subjected to the cutting process, so that the fuse 3 a can be protected from the penetration of moisture or impurities. Therefore, there is no possibility of corrosion of the uncut fuse 3 a. That is, it is possible to improve the long-term reliability of the semiconductor device.
- the third insulating film 13 on the fuse 3 a that is subjected to the cutting process is removed together with the fuse 3 a , and, in such part, the penetration of moisture or impurities is allowed.
- the fuse 3 a is originally configured that, if the circuit is decided as defective by the electric characteristics measurement, the fuse 3 a is cut to be replaced the defective circuit with the redundant circuit.
- the cut fuse 3 a is electrically separated from the peripheral circuits close to the fuse 3 a . Even if moisture or impurities reach the fuse 3 a, and the fuse 3 a is corroded thereby, there is little possibility that the long-term reliability of the semiconductor device is reduced.
- the process of forming the solder bump 33 after the cutting process is the same as the aforementioned conventional process. Specifically, as shown in FIG. 4A , a surface insulating film 31 made of BCB is formed on the third insulating film 13 . On the surface insulating film 31 , an opening 30 is formed for exposing a part of the surface of the pad 3 c. On the surface and periphery of the opening 30 , a barrier metal layer 32 is formed. By reflowing a solder paste that is patterned through the metal mask on the barrier metal layer 32 , a spherical solder bump 33 can be formed as shown in FIG. 4B .
- the first insulating film 11 with the high filling capability is formed just above the wirings 3 b formed in narrow pitches, it is possible to prevent a generation of voids 41 in a gap between the wirings 3 b.
- the uneven structure caused by the wirings 3 b can be minimized, too. Therefore, if the stress is generated at forming the solder bump 33 , there is no possibility that a crack is generated.
- the invention can prevent that moisture or impurities reach the fuse 3 a, and also can restrict the defective factor such as the corrosion, so that it is possible to improve the long-term reliability of the semiconductor device.
- FIGS. 5A to 5C there is another embodiment as shown in FIGS. 5A to 5C . That is, without leaving the coating layer 11 a on the fuse 3 a in forming the opening 21 , all the insulating films can be etched.
- the second insulating film 12 is formed in the same way as above ( FIG. 2C ).
- a resist pattern is formed on the second insulating film 12 to be an etching mask.
- the second insulating film 12 and the first insulating film 11 are etched in sequence by the dry-etching, whereby the top surface of the fuse 3 a is exposed ( FIG. 5A ).
- the subsequent processes are the same as the foregoing embodiment, and the explanation is not described here.
- the fuse 3 a may be formed by employing the multi-layer structure wherein a protecting layer with a high etching resistibility is disposed on the metal film 2 .
- the present invention can provide an effect that it is possible to improve the long-term reliability of the semiconductor device, and the invention is useful for the semiconductor device with repair fuses.
Abstract
A semiconductor device with a fuse 3 a to be cut for a circuit modification, of which passivation film coating the uppermost wiring layer is formed in a two-layer structure including a first insulating film 11 with high filling capability and a second insulating film 12 blocking penetration of moisture or impurities. An opening 21 formed in a specific depth through the insulating films on the fuse 3 a is coated by a third insulating film 13 with the blocking capability. This prevents the penetration of moisture or impurities, and the corrosion of the fuse 3 a.
Description
- This present application claims the benefit of patent application number 2004-339424, filed in Japan on Nov. 24, 2004, the subject matter of which is hereby incorporated herein by reference.
- The present invention generally relates to a semiconductor device provided with repair fuses and a manufacturing method thereof, and more specifically, to a semiconductor device for a Ball Grid Allay (BGA) package and a manufacturing method thereof.
- A conventional semiconductor device is provided with various types of circuit elements forming circuits and wirings interconnecting the circuit elements on a silicon substrate, for example. Those wirings usually are formed in a multi-level structure. On an uppermost wiring layer, electrodes for external connections (which is defined as a pad hereinafter), and repair fuses for replacing a defective circuit with a redundant circuit are formed.
-
FIG. 6 is a sectional view schematically showing the uppermost wiring layer of a conventional semiconductor device. InFIG. 6 , afuse 3 a, awiring 3 b, and apad 3 c are formed on aninterlayer insulator 1, as theuppermost wiring layer 3. Under theinterlayer insulator 1, there is a semiconductor substrate, on which other wiring layers and circuit elements such as transistor are formed. - As shown in
FIG. 6 , on theuppermost wiring layer 3 formed by etching a metal such as an aluminum alloy, apassivation film 5 made of dense silicon nitride film is formed by Chemical Vapor Deposition process (CVD) in order to prevent a mechanical breakdown and penetration of moisture or impurities such as sodium ion that causes failure of the semiconductor device. - An
opening 7 for exposing a part of a surface of thepad 3 c is formed by etching on thepassivation film 5. Thepassivation film 5 on thefuse 3 a is also etched to form anopening 6 in need of carrying out the following cutting process, resulting that the thickness of thepassivation film 5 becomes thinner than the other portions. For instance, while thepassivation film 5 is approximately 1000 nm in thickness, the film thickness at theopening 6 is approximately 150 nm. - The
fuse 3 a, as well as thewiring 3 b, consists of a metal like the aluminum alloy. The necessity of the fuse cutting is decided according to an analysis of electrical characteristics test through thepad 3 c. If the fuse cutting is required, thefuse 3 a is heated by irradiation of a laser or a charged beam (an ion beam, for example) through thethin passivation film 5, and then thefuse 3 a is blown and cut by liquefying and evaporating. According to this process, the defective circuit is turned out to be replaced with the redundant circuit. - Even if the
fuse 3 a is in the state of being coated by thethick passivation film 5 as well as the other portions, the cutting process of thefuse 3 a can be carried out. In such case, since the cutting process will cause damages to the other portions other than thefuse 3 a, the amount of irradiation energy of the laser cannot be increased needlessly. That is, when the fuse cutting is carried out on thefuse 3 a coated by thethick passivation film 5, the processing time increases depending on the thickness of thepassivation film 5. Therefore, by lettingpassivation film 5 thinner on thefuse 3 a as mentioned above, the cutting process of thefuse 3 a can be easily carried out and the penetration of moisture or impurities intonon-cutting fuses 3 a is prevented. - In case of the semiconductor device for the BGA Package (Flip Chip Bonding), a bump is formed on the
passivation film 5 illustrated inFIG. 6 in a following way. As shown inFIG. 7 , asurface insulating film 31 made of BCB (benzocycrobuten), which is for the planarization and the surface protection, is formed on thepassivation film 5. An opening for exposing a part of the surface of thepad 3 c is formed through thesurface insulating film 31. - On a surface and a periphery of the opening, a
barrier metal layer 32 made of such as nickel is formed in order to improve the adhesion between a bump material (solder) filling the opening by subsequent steps and thesurface insulating film 31, and also to prevent the bump material from diffusing to thesurface insulating film 31. - Next, on an upper surface of the
insulating film 31, a metal mask having an opening in bump formation position that corresponds to thebarrier metal layer 32, is placed, and a solder paste is patterned through the metal mask. After the patterned solder paste is reflowed, aspherical solder bump 33 is formed by the action of the surface tension. - In the semiconductor device for the BGA package, as the number of pins are increased and each pin pitch is reduced, the respective gaps between
wirings 3 b, forming theuppermost wiring layer 3, become narrow, as shown inFIG. 7 . Accordingly, at such region ofwirings 3 b being in close, thepassivation film 5 has excessive uneven structure due to the uneven structure ofwirings 3 b. Additionally, in the process of forming thepassivation film 5 in such region, the film material on thewirings 3 b has been connected before the gaps between thewirings 3 b are completely filled, whereby avoid 41 being not filled with thepassivation film 5 is formed between thewirings 3 b. - Moreover, in the semiconductor device for the BGA package, the thick
surface insulating film 31 is formed on thepassivation film 5, as shown inFIG. 7 . This structure makes it easy to generate a large stress by the heating in forming thesolder bump 33. Consequently, when the stresses are concentrated on the uneven structure of thepassivation film 5 and thevoids 41 are existed therein,cracks 42 will appear in thepassivation film 5 and theinterlayer insulator 1. - As a solution, in the semiconductor device for the BGA package, a structure as shown in
FIG. 8A is adopted in order to avoid thevoids 41 being formed. In the structure that is disclosed in Kohyo (National Publication of Translated Version) No. 2002-500440, thepassivation film 5 is formed in a two-layer structure including a firstinsulating film 11 and a secondinsulating film 12. The firstinsulating film 11 has a high filling capability for the gaps between thewirings 3 b, and is superior in planarization of a surface of a generated film, like a silicon dioxide film deposited by CVD process using source gas including Silane (e.g. SiH4 and O2 mixture), for example. The secondinsulting film 12 consists of silicon nitride film placed on the firstinsulting film 11 that prevents moisture or impurities penetrating into the firstinsulating film 11. - Since the passivation film is formed in such two-layer structure wherein the first
insulating film 11 with the high filling capability is placed under the secondinsulating film 12, the generation ofvoids 41 can be prevented, and the uneven structure of the passivation film also can be improved significantly. In result, it is possible to mitigate the stress concentration and avoid the occurrence ofcracks 42. - Even when the passivation film with the above two-layer structure is employed, the opening is formed on the
fuse 3 a after the deposition of the secondinsulating film 12 is completed. As shown inFIG. 8B (an enlarged view of a portion A inFIG. 8A before the deposition of the surface insulating film 31), the structure on thefuse 3 a is that the firstinsulating film 11 is exposed by etching the secondinsulating film 12, or the top surface of thefuse 3 a is exposed by etching the firstinsulating film 11 together with the secondinsulating film 12. - The semiconductor manufacturing process is categorized to two processes, a front-end process and a back-end process. The front-end process is for forming the semiconductor device on the semiconductor wafer, which corresponds to the steps up to the cutting process of the
fuse 3 a in the above example. The back-end process is for sealing the semiconductor device in the BGA package, which corresponds to the steps after forming thesurface insulating film 31 in the above example. Generally, the back-end process is carried out at a different place from the front-end process. Therefore, after thefuse 3 a is cut in the front-end process, the semiconductor device is kept in the state that the first insulating film 11 (or thefuse 3 a) is exposed, before the device is sent to the next back-end process. - Despite of the superior filling capability, the first
insulating film 11 has no resistibility to the penetration of moisture or impurities. If moisture or impurities reach thefuse 3 a before the back-end process and the problems of corrosion and so forth are caused, that become a factor of reducing the long-term reliability of the semiconductor device. - The present invention is suggested in view of the above conventional conditions, and has an object to provide a semiconductor device capable of avoiding the occurrence of cracks caused from the stress concentration, and preventing the penetration of moisture or impurities to the fuse, and has an object of providing the manufacturing method thereof.
- In order to achieve the object described above, the invention employs following means. First of all, the invention premises a method of manufacturing a semiconductor device provided with a fuse to be cut to modify a circuit configuration if necessary. In the method, an uppermost wiring layer of the semiconductor device described above is coated, a first insulting film which completely fills a gap between members included in the wiring layer is formed, and a second insulating film, which have higher blocking capability against penetration of moisture or impurities than the first insulating film, is formed by coating the first insulating film. Then, after etching the insulating films deposited on the fuse provided to any wiring layer of the semiconductor device, a third insulating film is formed so as to have the blocking capability of the same level or the higher level than that of the second insulating film, and coat at least the etched portion.
- In the etching process described above, the insulating films on the fuse may be completely etched, or may be etched so as to leave the insulating film at a thickness not disturbing the cutting of the fuse.
- In the present invention, since the fuse not required to cut is coated by the third insulating film with the blocking capability, it is possible to prevent the penetration of moisture or impurities so as to reduce the defective fuse.
- Additionally, it is possible to use a Non Doped Silicon Glass (NSG) film deposited by high density plasma Chemical Vapor Deposition process as the first insulating film. Under a depositing condition with high filling capability, the first insulating film may be a silicon nitride film deposited by CVD.
- It is possible to employ silicon nitride film deposited by CVD with a high resistibility (blocking capability) to the penetration of moisture or impurities for the second and third insulating films.
- Moreover, the invention can provide a semiconductor device having a structure manufactured by the above method. That is, the semiconductor device in the invention, which is provided with a fuse to be cut to modify a circuit configuration if necessary, comprises a first insulating film coating an uppermost wiring layer of the semiconductor device, and completely filling a gap between members included in the wiring layer, and a second insulating film having higher blocking capability against penetration of moisture or impurities than the first insulating film, and coating the first insulating film. Further, it comprises an opening formed on the fuse provided to any wiring layer of the semiconductor device, and having a specific depth from the top surface of the second insulating film, and a third insulating film having blocking capability of the same level or higher level than that of the second insulating film, and coating at least the opening.
- According to the present invention, the penetration of moisture or impurities to the fuse can be prevented, so that the defective fuse can be reduced. Therefore, it is possible to improve the long-term reliability of the semiconductor device remarkably.
- The present disclosure is illustrated by way of example, and not by way of limitation, in the figures of the accompanying drawings and in which like reference numerals refer to similar elements and in which:
-
FIG. 1 is a sectional view of a relevant part of a semiconductor device of the present invention. -
FIGS. 2A to 2C show sectional views of manufacturing processes of a semiconductor device of the present invention. -
FIGS. 3A to 3C show sectional views of manufacturing processes of a semiconductor device of the present invention. -
FIGS. 4A and 4B show sectional views of manufacturing processes of a semiconductor device of the present invention. -
FIGS. 5A to 5C show sectional views of modified manufacturing processes of a semiconductor device of the present invention. -
FIG. 6 is a sectional view of a relevant part of a semiconductor device with a conventional passivation film in a single-level structure. -
FIG. 7 is a sectional view of a relevant part of a semiconductor device with a conventional passivation film in a single-level structure. -
FIGS. 8A to 8B show sectional view of a relevant part of a semiconductor device with a conventional passivation film in a two-level structure. - Embodiments of the invention are discussed here in accordance with attached drawings.
FIG. 1 is a sectional view showing a relevant part of a semiconductor device in a first embodiment of the invention.FIGS. 2A to 2C ,FIGS. 3A to 3C andFIGS. 4A to 4B are sectional views showing the processes for manufacturing an uppermost wiring layer of the semiconductor device inFIG. 1 . - A structure of the semiconductor device in this embodiment is illustrated hereinafter together with the manufacturing processes thereof.
- As shown in
FIG. 1 ,FIG. 2A andFIG. 2B , the uppermost wiring layer in the semiconductor device is formed on an interlayer insulator 1 (a base insulator 1) made of silicon dioxide film, so that the uppermost wiring layer may not be electrically connected to wirings and circuit elements in a lower wiring layer. Under thebase insulator 1, a semiconductor substrate is formed by a conventional fabricating method, with which other wirings and circuits elements like a transistor are formed. Since the conventional fabricating method of the semiconductor substrate does not relate to the present invention directly, the description is omitted here. - The uppermost wiring layer may be formed by a conventional microfabrication technique, using a conventional wiring material for the semiconductor device. The invention does not define the material and the fabrication method in particular. For instance, the uppermost wiring layer may be formed as following processes.
- As shown in
FIG. 2A , ametal film 2 made of aluminum alloy is deposited over thebase insulator 1. Next, a resist pattern (not shown in the drawing) is formed on the parts ofmetal film 2 on which metal patterns of such as afuse 3 a, awiring 3 b and apad 3 c are formed by the photolithography. Themetal film 2 is etched using the resist pattern as an etching mask, whereby awiring layer 3 such as afuse 3 a, awiring 3 b and apad 3 c, are formed. The thickness of themetal film 2 is defined as 850 nm. Themetal film 2 is not always required to be a single-layer structure, and the structure may be a multi-layer structure depositing plural types of metals or metal alloys. - Subsequently, a first insulating
film 11 is formed on thefuse 3 a, thewiring 3 b and thepad 3 c. The first insulatingfilm 11 is formed thick enough to completely fill at least the gap between thewirings 3 b so as not to allow any space. - If it is possible to achieve a gap filling capability enough to fill the gap between the
wirings 3 b without spaces, the method and material for forming the first insulatingfilm 11 is not limited in particular. In this embodiment, as the first insulatingfilm 11, HDP-NSG film (High Density Plasma—Non Doped Silicon Glass, using SiH4 and O2 as source gas) formed by high-density plasma CVD, such as Microwave Excited High Density plasma CVD, ECR (Electron Cyclotron Resonance) CVD, and ICP (Inductively Coupled Plasma) CVD are used. This HDP-NSG film has a superior gap filling capability that can fill gaps with high aspect ratio, and allows a subsequent layer to be deposited smoothly. The thickness of the first insulatingfilm 11, in the embodiment, is defined as 1100 nm which is thick enough to fill gaps between thewirings 3 b without any space. - As the first insulating
film 11, a silicon nitride film by Plasma CVD using SiH4 and NH3 as source gas, or a silicon dioxide film by Plasma CVD or Thermal CVD as TEOS (Tetraethoxysilane)/O2 system or TEOS/O3 system can be also used. In case of using the silicon nitride film to the first insulatingfilm 11, in order to enhance the gap filling capability of the silicon nitride film, it is necessary to properly adjust a deposition pressure and a plasma excitation power (RF power) that is different from the general conditions of deposition as the passivation film. - Next, as shown in
FIG. 2C , a second insulatingfilm 12 which is denser than the first insulatingfilm 11 is formed on the first insulatingfilm 11. The second insulatingfilm 12 has a high resistibility to the penetration of moisture or impurities. In the embodiment, the silicon nitride film deposited by Plasma CVD, which is widely used as the passivation film so far, is used as the second insulatingfilm 12. The second insulatingfilm 12 may be desirably deposited in thickness enough to prevent the penetration of moisture or impurities, which is defined as approximately 600 nm. - As shown in
FIG. 3A , after the completion of deposition of the second insulatingfilm 12, anopening 21 is formed in the insulting layers above thefuse 3 a (the first insulatingfilm 11 and the second insulating film 12) by removing the insulating films up to the specific depth from a top surface of the second insulatingfilm 12. - A conventional etching technique may be used for forming the
opening 21. In the embodiment, resist is coated on the second insulatingfilm 12, before a resist pattern with openings at a projected place of theopening 21 is formed by the photolithography. By using the resist pattern as a mask, the second insulatingfilm 12 and the first insulatingfilm 11 are dry-etched sequentially by using etching gases suitable for respective insulating films (for example, CF4 or Halogen). In order to avoid the damages of thefuse 3 a caused by the exposure of thefuse 3 a during the etching, without removing the insulating films on thefuse 3 a thoroughly, a part of the first insulatingfilm 11 is left as acoating film 11 a. In the embodiment, the thickness of thecoating film 11 a is 150 nm. - The thickness of the
coating film 11 a is decided by controlling the amount of etching in the above etching process. To make it easy to control the film thickness of thecoating film 11 a, an etch-stop film may be formed. That is, the first insulatingfilm 11 is deposited in thickness up to the thickness of being left as thecoating film 11 a, and the deposition of the first insulatingfilm 11 is stopped temporarily. Then the etch-stop film is formed on the position at least facing to thefuse 3 a (above thefuse 3 a) on the firstinsulting film 11, using a material which can secure the etching selectivity against the first insulatingfilm 11. Next, the deposition of the insulatingfilm 11 is restarted. When the thickness reaches to the above-mentioned thickness (1100 nm), the deposition of the first insulatingfilm 11 is completed. For instance, in case of using HDP-NSG film as the first insulatingfilm 11, the silicon nitride film can be used as the etch-stop film. - Accordingly, in the process of etching in forming the
opening 21, the amount of etching of the first insulatingfilm 11 can be limited by the etch-stop film. Therefore, an over-etching can be performed, and the film thickness of thecoating film 11 a can be controlled in a simple manner. Moreover, since the thickness of thecoating film 11 a on thefuse 3 a across a semiconductor wafer on which the semiconductor device is formed is extremely uniform, the laser irradiation condition for the cutting of thefuse 3 a can be fixed, and the fuse cutting can be performed effectively. - After the
opening 21 is formed on thefuse 3 a as mentioned above, a third insulatingfilm 13 having a resistibility to the penetration of the moisture or impurities is formed thin in the same way as the second insulatingfilm 12 as shown inFIG. 3B . In the embodiment, the silicon nitride film, which is deposited by Plasma CVD, is used to the third insulatingfilm 13 as well as the second insulatingfilm 12, and the film thickness is defined as approximately 200 nm. Besides, the third insulatingfilm 13 is desired to be deposited as thick as possible so as not to prevent the cutting of thefuse 3 a, and therefore the thickness of all the films on thefuse 3 a is desired to be 500 nm or less. - The third
insulating film 13 may be deposited at least over a surface of theopening 21 above thefuse 3 a. In an example shown inFIGS. 3A to 3C , however, the third insulatingfilm 13 is formed over a whole surface in order to simplify the manufacturing process. After the third insulatingfilm 13 is formed, theopening 22 for the external connection is formed on thepad 3 c as shown inFIG. 3C . - When the
opening 22 is thus formed on thepad 3 c, the semiconductor device is completed. That is to say, the electric characteristics of the semiconductor device is measured through thepad 3 c, and in accordance with the measurement result, it is decided whether or not to cut thefuse 3 a. - When the cutting of the
fuse 3 a is decided as required, thefuse 3 a is irradiated by laser (or charging beam, and so on), and then is cut together with the insulating films thereon (the coating film la and the third insulating film 13). When the cutting of thefuse 3 a is decided as not required, the cutting process is not performed on thefuse 3 a. - As described above, in the invention of the embodiment, the third insulating
film 13 made of the silicon nitride film with the blocking capability against moisture or impurities is formed on thefuse 3 a without being subjected to the cutting process, so that thefuse 3 a can be protected from the penetration of moisture or impurities. Therefore, there is no possibility of corrosion of theuncut fuse 3 a. That is, it is possible to improve the long-term reliability of the semiconductor device. - The third
insulating film 13 on thefuse 3 a that is subjected to the cutting process is removed together with thefuse 3 a, and, in such part, the penetration of moisture or impurities is allowed. However, thefuse 3 a is originally configured that, if the circuit is decided as defective by the electric characteristics measurement, thefuse 3 a is cut to be replaced the defective circuit with the redundant circuit. Furthermore, in the semiconductor device, thecut fuse 3 a is electrically separated from the peripheral circuits close to thefuse 3 a. Even if moisture or impurities reach thefuse 3 a, and thefuse 3 a is corroded thereby, there is little possibility that the long-term reliability of the semiconductor device is reduced. - The process of forming the
solder bump 33 after the cutting process is the same as the aforementioned conventional process. Specifically, as shown inFIG. 4A , asurface insulating film 31 made of BCB is formed on the third insulatingfilm 13. On thesurface insulating film 31, anopening 30 is formed for exposing a part of the surface of thepad 3 c. On the surface and periphery of theopening 30, abarrier metal layer 32 is formed. By reflowing a solder paste that is patterned through the metal mask on thebarrier metal layer 32, aspherical solder bump 33 can be formed as shown inFIG. 4B . - In the present invention, since the first insulating
film 11 with the high filling capability is formed just above thewirings 3 b formed in narrow pitches, it is possible to prevent a generation ofvoids 41 in a gap between thewirings 3 b. The uneven structure caused by thewirings 3 b can be minimized, too. Therefore, if the stress is generated at forming thesolder bump 33, there is no possibility that a crack is generated. - As discussed above, the invention can prevent that moisture or impurities reach the
fuse 3 a, and also can restrict the defective factor such as the corrosion, so that it is possible to improve the long-term reliability of the semiconductor device. - The above discussion is concerned with a configuration that the first insulating
film 11 is left thin on the surface on thefuse 3 a. Further, there is another embodiment as shown inFIGS. 5A to 5C . That is, without leaving thecoating layer 11 a on thefuse 3 a in forming theopening 21, all the insulating films can be etched. - The following discusses about the modified embodiment.
- After the second insulating
film 12 is formed in the same way as above (FIG. 2C ), a resist pattern is formed on the second insulatingfilm 12 to be an etching mask. Then, the second insulatingfilm 12 and the first insulatingfilm 11 are etched in sequence by the dry-etching, whereby the top surface of thefuse 3 a is exposed (FIG. 5A ). The subsequent processes are the same as the foregoing embodiment, and the explanation is not described here. - This makes it possible to perform the over-etching of the first insulating
film 11, so that a process margin can be expanded as compared with the example shown inFIG. 3A . In this case, it is desirable to etch the first insulatingfilm 11 by using an etching gas with higher etching selectivity against the material of thefuse 3 a. In order to avoid the etching damages to thefuse 3 a, thefuse 3 a may be formed by employing the multi-layer structure wherein a protecting layer with a high etching resistibility is disposed on themetal film 2. - The above mentioned embodiments are based on a configuration wherein the fuse is formed on the uppermost wiring layer. However, it is nevertheless to say that the invention can be used to a case where the fuse is formed in any wiring layer of the semiconductor device.
- The embodiments illustrated herein are for illustrative purpose only. They should not be construed to limit the scope of the claims. For instance, the materials and processes mentioned herein can be replaced with various equivalent materials and processes.
- The present invention can provide an effect that it is possible to improve the long-term reliability of the semiconductor device, and the invention is useful for the semiconductor device with repair fuses.
Claims (21)
1-13. (canceled)
14. A method of manufacturing a semiconductor device, comprising the steps of:
(a) forming an interlayer insulator in which a first wiring layer including a fuse is provided;
(b) forming a second wiring layer including a wiring on the interlayer insulator;
(c) forming a first insulating film so as to coat the wiring;
(d) forming a second insulating film so as to coat the first insulating film;
(e) forming an opening above the fuse by etching the first and second insulating films; and
(f) forming a third insulating film so as to coat at least the opening.
15. A method of manufacturing a semiconductor device according to claim 14 , wherein, in step (f), the third insulating film formed on the opening substantially conformally coats the opening.
16. A method of manufacturing a semiconductor device according to claim 14 , wherein, in step (f), the third insulating film formed on the opening is formed along a surface of the opening.
17. A method of manufacturing a semiconductor device according to claim 14 , wherein, in step (e), a part of the interlayer insulator above the fuse is further removed.
18. A method of manufacturing a semiconductor device according to claim 14 , wherein, in step (e), the interlayer insulator above the fuse is further removed and the fuse is exposed.
19. A method of manufacturing a semiconductor device according to claim 14 , wherein, in step (e), a part of the interlayer insulator above the fuse is further removed and the thinned interlayer insulator is left above the fuse.
20. A method of manufacturing a semiconductor device according to claim 14 , wherein, in step (e), a part of the interlayer insulator and a part of the first insulating film are left above the fuse.
21. A method of manufacturing a semiconductor device according to claim 14 , wherein the second insulating film has blocking capability against penetration of moisture or impurities higher than that of the first insulating film.
22. A method of manufacturing a semiconductor device according to claim 14 , wherein the third insulating film has blocking capability against penetration of moisture or impurities same as or higher than that of the second insulating film.
23. A method of manufacturing a semiconductor device according to claim 14 , wherein the first insulating film is a Non Doped Silicon Glass film deposited by High-Density Plasma Chemical Vapor Deposition process.
24. A method of manufacturing a semiconductor device according to claim 14 , wherein the first insulating film is a silicon nitride film deposited by Chemical Vapor Deposition process.
25. A method of manufacturing a semiconductor device according to claim 14 , wherein the second insulating film and the third insulating film are silicon nitride films deposited by Chemical Vapor Deposition process.
26. A semiconductor device, comprising:
a interlayer insulator in which a first wiring layer including a fuse is provided;
a second wiring layer including a wiring formed on the interlayer insulator;
a first insulating film formed on the wiring;
a second insulating film formed on the first insulating film;
an opening formed above the fuse; and
a third insulating film coating at least the opening.
27. A semiconductor device according to claim 26 , wherein the third insulating film coating the opening is substantially a conformal coating film.
28. A semiconductor device according to claim 26 , wherein a surface of the third insulating film coating the opening is along a surface of the opening.
29. A semiconductor device according to claim 26 , wherein the third insulating film contacts with the fuse.
30. A semiconductor device according to claim 26 , wherein a portion of the first insulating film, the portion being partially reduced in thickness, is located on the fuse.
31. A semiconductor device according to claim 26 , wherein the second wiring layer includes a plurality of wirings and the first insulating film coats the wirings, and the first insulating film fills a gap between the wirings without voids.
32. A semiconductor device according to claim 26 , wherein the second insulating film has blocking capability against penetration of moisture or impurities higher than that of the first insulating film.
33. A semiconductor device according to claim 26 , wherein the third insulating film has blocking capability against penetration of moisture or impurities same as or higher than that of the second insulating film.
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JP2004339424A JP4504791B2 (en) | 2004-11-24 | 2004-11-24 | Semiconductor circuit device and manufacturing method thereof |
US11/283,849 US7576014B2 (en) | 2004-11-24 | 2005-11-22 | Semiconductor device and manufacturing method thereof |
US12/494,855 US20090267181A1 (en) | 2004-11-24 | 2009-06-30 | Semiconductor device and manufacturing method thereof |
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US12/494,855 Abandoned US20090267181A1 (en) | 2004-11-24 | 2009-06-30 | Semiconductor device and manufacturing method thereof |
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US20130334656A1 (en) * | 2012-06-13 | 2013-12-19 | Samsung Electronics Co., Ltd. | Electrical interconnection structures including stress buffer layers |
CN104253083A (en) * | 2013-06-26 | 2014-12-31 | 中芯国际集成电路制造(上海)有限公司 | Manufacturing method of fusing device |
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US7491585B2 (en) * | 2006-10-19 | 2009-02-17 | International Business Machines Corporation | Electrical fuse and method of making |
TW200843063A (en) * | 2007-04-16 | 2008-11-01 | Phoenix Prec Technology Corp | Structure of semiconductor chip and package structure having semiconductor chip embedded therein |
CN103094248B (en) * | 2011-11-04 | 2015-10-14 | 上海华虹宏力半导体制造有限公司 | Metal fuse wire structure and manufacture method thereof |
JP2017034187A (en) * | 2015-08-05 | 2017-02-09 | ローム株式会社 | Semiconductor device |
US9490143B1 (en) * | 2015-11-25 | 2016-11-08 | Texas Instruments Incorporated | Method of fabricating semiconductors |
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Also Published As
Publication number | Publication date |
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JP2006148021A (en) | 2006-06-08 |
US7576014B2 (en) | 2009-08-18 |
JP4504791B2 (en) | 2010-07-14 |
US20060110935A1 (en) | 2006-05-25 |
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