US20100044823A1 - Semiconductor photonic devices with enhanced responsivity and reduced stray light - Google Patents
Semiconductor photonic devices with enhanced responsivity and reduced stray light Download PDFInfo
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- US20100044823A1 US20100044823A1 US12/610,522 US61052209A US2010044823A1 US 20100044823 A1 US20100044823 A1 US 20100044823A1 US 61052209 A US61052209 A US 61052209A US 2010044823 A1 US2010044823 A1 US 2010044823A1
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 24
- 239000000758 substrate Substances 0.000 claims abstract description 42
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000002184 metal Substances 0.000 claims abstract description 29
- 229910021332 silicide Inorganic materials 0.000 claims abstract description 22
- 230000005855 radiation Effects 0.000 claims description 3
- 229910052732 germanium Inorganic materials 0.000 abstract description 14
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 abstract description 14
- 229910052710 silicon Inorganic materials 0.000 abstract description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 11
- 239000003990 capacitor Substances 0.000 abstract description 11
- 239000010703 silicon Substances 0.000 abstract description 11
- 229910021421 monocrystalline silicon Inorganic materials 0.000 abstract description 5
- 229910000927 Ge alloy Inorganic materials 0.000 abstract description 4
- 230000005669 field effect Effects 0.000 abstract description 3
- 239000010410 layer Substances 0.000 description 33
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 9
- 229920005591 polysilicon Polymers 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000012212 insulator Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000003384 imaging method Methods 0.000 description 3
- 238000012544 monitoring process Methods 0.000 description 3
- 229910052814 silicon oxide Inorganic materials 0.000 description 3
- 229910000676 Si alloy Inorganic materials 0.000 description 2
- 238000003491 array Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000004611 spectroscopical analysis Methods 0.000 description 2
- 208000012868 Overgrowth Diseases 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000023077 detection of light stimulus Effects 0.000 description 1
- 239000002355 dual-layer Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000407 epitaxy Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
- H01L27/14601—Structural or functional details thereof
- H01L27/1462—Coatings
- H01L27/14623—Optical shielding
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02367—Substrates
- H01L21/0237—Materials
- H01L21/02373—Group 14 semiconducting materials
- H01L21/02381—Silicon, silicon germanium, germanium
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02524—Group 14 semiconducting materials
- H01L21/02532—Silicon, silicon germanium, germanium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02612—Formation types
- H01L21/02617—Deposition types
- H01L21/0262—Reduction or decomposition of gaseous compounds, e.g. CVD
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02612—Formation types
- H01L21/02617—Deposition types
- H01L21/02636—Selective deposition, e.g. simultaneous growth of mono- and non-monocrystalline semiconductor materials
- H01L21/02639—Preparation of substrate for selective deposition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
- H01L27/14683—Processes or apparatus peculiar to the manufacture or treatment of these devices or parts thereof
- H01L27/14685—Process for coatings or optical elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0216—Coatings
- H01L31/02161—Coatings for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/02162—Coatings for devices characterised by at least one potential jump barrier or surface barrier for filtering or shielding light, e.g. multicolour filters for photodetectors
- H01L31/02164—Coatings for devices characterised by at least one potential jump barrier or surface barrier for filtering or shielding light, e.g. multicolour filters for photodetectors for shielding light, e.g. light blocking layers, cold shields for infrared detectors
Definitions
- This invention relates generally to semiconductor photonic devices such as photodetectors for visible and infrared light.
- semiconductor dual layer photonic devices configured to enhance responsivity while reducing stray light.
- Semiconductor photonic devices are highly useful in a variety of applications ranging from monitoring, analyzing and imaging light to the generation of energy from solar radiation.
- Such devices comprise semiconductor photoresponsive components such as photodiodes, photoransistors or photoresistors integrated with semiconductor processing circuitry.
- Such devices can be used as photodetectors and solar cells.
- Semiconductor photodetectors are widely used for the detection of light, both visible and infrared. They exploit the internal photoelectric effect, where electron-hole pairs are generated in a semiconductor by photon absorption and contribute to electrical conduction inside the device, leading to a corresponding current at the contacts of the detector. Such detectors are fabricated singly for monitoring, in linear arrays for spectroscopy, and in two-dimensional (2-D) arrays for imaging.
- photoresponsive components such as photodiodes
- processing circuitry such as transistors and capacitors.
- the photoresponsive components and the processing components are formed in the same plane.
- the processing components are formed in a semiconductor substrate and photoresponsive components are formed in a layer overlying the substrate.
- the photoresponsive components will have a finite thickness limited by several factors, including the time and conditions needed to deposit or grow the photoresponsive components, the height of metal contacts to the substrate, and the desired planarity of the overall integrated device.
- the photoresponsive components can absorb only a portion of the light falling on them, and some of the light can be transmitted through them without being absorbed. For light near the cutoff wavelength, photodetector absorption can be quite weak. For instance 20% might be reflected, 10% might be absorbed and 70% might be transmitted through the detector.
- Light transmitted through the photoresponsive component can penetrate into the substrate, where it becomes stray light that can be absorbed (directly or after reflection) in the semiconductor circuitry, causing unexpected and undesired current to flow.
- stray light that can be absorbed (directly or after reflection) in the semiconductor circuitry, causing unexpected and undesired current to flow.
- light that enters one photoresponsive component at an oblique angle may pass through it to another component in the array.
- Such stray light causes undesired crosstalk in an analyzer or blurring in an imager.
- light that is not absorbed by the photoresponsive component can create three problems: it can degrade responsivity of the photoresponsive component, it can cause unwanted current to flow in the circuitry, and it can cause crosstalk. Accordingly there is a need for photonic devices that are configured to enhance responsivity while reducing stray light.
- a photonic device comprises a semiconductor substrate including at least one circuit component comprising a metal silicide layer and an overlying layer including at least one photoresponsive component.
- the metal silicide layer is disposed between the circuit component and the photoresponsive component to prevent entry into the circuit component of light that penetrates the photoresponsive component.
- the silicide layer advantageously reflects the light back into the photoresponsive element.
- the overlying layer can include one or more reflective layers to reduce entry of oblique light into the photoresponsive component.
- the substrate comprises single-crystal silicon including one or more insulated gate field effect transistors (IGFETs), and/or capacitors
- the photoresponsive element comprises germanium and/or germanium alloy epitaxially grown from seeds on the silicon.
- the metal silicide layer can comprise the gate of the IGFET and/or an electrode of the capacitor.
- FIGS. 1A and 1B are cross sectional and plan views, respectively, of a first exemplary photonic device in accordance with the invention.
- FIGS. 2A and 2B are cross sectional and plan views of the device of FIG. 1 including higher layers of metal;
- FIG. 3 is a cross-sectional view of an alternative photonic device in accordance with the invention.
- FIGS. 1A and 1B schematically illustrate a photonic device 9 comprising a semiconductor substrate 30 and an overlying layer, such as insulating layer 20 , including at least one semiconductor photoresponsive component 10 .
- the substrate 30 includes at least one circuit component such as an insulated-gate field effect transistor including a source and a drain (not shown) underlying an insulated gate 40 .
- the photoresponsive component 10 advantageously overlies transistor insulated gate 40 , and the gate 40 advantageously includes a layer 42 to prevent light that passes through the component 10 from entering the transistor region underlying the gate 40 .
- the layer 42 also reflects the light back into the photoresponsive component 10 .
- the substrate 30 comprises single crystal silicon
- the gate comprises polysilicon
- the gate insulator comprises silicon oxide
- the layer 42 comprises metal silicide.
- the insulator layer 20 can comprise silicon oxide.
- the photoresponsive component 10 preferably comprises single-crystal germanium.
- the germanium can be grown from a seed stem 12 that is epitaxially grown from the silicon substrate 30 .
- the photoresponsive component can comprise polycrystalline germanium, single crystal silicon, polycrystalline silicon, or alloys of silicon and germanium in either single crystal or polycrystalline form. This includes all Si/Ge alloys between pure Si and Ge.
- a silicon substrate 30 can be processed in the usual way to create transistors and other desired circuitry.
- polysilicon gates 40 are created. These gates have a metal silicide layer 42 formed on the upper surface.
- the polysilicon layer 40 which can be used as the gate of a transistor, can also be used as one plate of a capacitor whose other plate is the substrate below the polysilicon, or the polysilicon plate may be grounded.
- the photoresponsive component 10 made of crystalline or polycrystalline semiconductor material, can be formed on or in the dielectric.
- Dielectric layer 20 can then be deposited over the silicon substrate 30 and the transistor gate and be planarized.
- the photoresponsive components comprise germanium islands 10 formed by epitaxy lateral overgrowth (ELO) from seed stems 12 using the substrate silicon as a template.
- the ELO technique is used to form a high quality germanium seed stem 12 embedded in the insulator 20 on top of the silicon substrate 30 .
- insulator 20 can be formed as an oxide layer overlying a single crystal silicon substrate 30 . Seed windows can be lithographically defined in the oxide and opened by etching down to the substrate. The exposed silicon surface can be cleaned for germanium growth. Then, germanium can be grown selectively on the exposed silicon by selective CVD growth. The growth should be continued until the germanium overgrows the seed stem 12 and fills the region of the island 10 .
- the seed stems 12 and islands 10 can be shaped and dimensioned so that defects originating at the Ge/Si interface are terminated at the walls of stem 12 before reaching the germanium island 10 . This provides a region of germanium over the oxide mask that is essentially defect-free. Further details concerning this technique are set forth in U.S. Patent Application Publication No. 2004/0121507 to Bude et al., herein incorporated by reference.
- the photoresponsive component might comprise epitaxially grown silicon, polysilicon or polygermanium material deposited and patterned using standard semiconductor processing techniques. The photoresponsive component can be processed in accordance with well known techniques to form a photodiode, phototransistor or photosensitive resistor.
- the gate 40 / 42 underneath the photodetector is preferably sized and dimensioned to completely overlap the bottom of the photoresponsive component 10 . If a seed is used, the gate can be shaped around the stem (e.g. donut-shaped) to allow the seed stem to penetrate through it.
- the metal silicide 42 will prevent the light from penetrating into the transistor gate and advantageously, will reflect it back through the photoresponsive component 20 , where it will have a chance to be absorbed on the second pass.
- the probability of absorption will be approximately doubled.
- the light incident on the component will be absorbed.
- Light that is not absorbed does not reach the substrate.
- FIGS. 2A (cross-section) and 2 B (plan-view) shows the device of FIG. 1 provided with higher levels of metal.
- Metal wires 50 embedded in the upper level dielectric 22 are provided to contact the photoresponsive component, and will block oblique light to the underlying substrate.
- the dielectric 22 may or may not be the same as dielectric 20 .
- a level of metal 52 higher in level than the metal 50 can be used as a light shield for the substrate. This light shield will have openings only above the photonic device in order to prevent oblique light from reaching the substrate.
- the light shield can have breaks above another metal layer as shown in FIG. 2B , since the lower metal will reflect light.
- An extra piece of light shield 52 can be disposed overlying the stem 12 in order to block light that might pass from the stem to substrate.
- the silicide coated gate is sandwiched between the semiconductor substrate in which the transistor is formed and the photoresponsive component is formed in a higher level. By blocking light which passes through the component, it prevents transmitted light from reaching the substrate and inducing unwanted currents in the circuits, thus acting as a light shield. It can also reflect light back into the photoresponsive component.
- FIG. 3 illustrates an alternative photonic device in accordance with the invention where the circuit component is a capacitor underlying photoresponsive component 10 .
- the capacitor is composed of polysilicon electrode 40 , substrate electrode 30 and an intervening layer of insulator 20 A.
- the polysilicon electrode 40 is covered with a layer of metal silicide 42 to block from the underlying region of the capacitor light that passes through the overlying photoresponsive component 10 .
- the metal silicide layer 42 is peripherally larger than the photoresponsive component.
- Higher layers of metal 50 , 52 are advantageously configured to block oblique light from the device.
- the invention is a photonic device comprising a semiconductor substrate including at least one circuit component. Overlying the substrate is a layer comprising at least one photoresponsive component that overlaps the circuit component.
- the circuit component comprises a metal silicide layer positioned to block from the circuit component light passing through the photoresponsive component.
- the metal silicide reflects light back into the photoresponsive component.
- the semiconductor substrate is advantageously a single-crystal semiconductor, preferably silicon.
- the circuit component is advantageously an IGFET or a capacitor.
- the layer overlying the substrate is advantageously an insulating layer such as silicon oxide, and the photoresponsive component advantageously comprises a semiconductor, such as germanium.
- the metal silicide can be part of the gate of the IGFET and/or an electrode of the capacitor.
- the photoresponsive component is preferably epitaxial with the semiconductor substrate.
- the component can comprise a stem region of a first lateral area and thickness epitaxially grown from the substrate and a larger lateral area island region epitaxially grown from the stem region.
- the area and vertical thickness of the stem region can be chosen to grow an island region substantially free of dislocation defects arising from the substrate interface.
- the metal silicide is peripherally larger than the photoresponsive component covers the underlying portions of the circuit component to block stray light from the underlying portions.
- Such photodetectors can be utilized individually, as for light monitoring, or a plurality of such photodetectors can be disposed in a one-dimensional (linear) array, as for spectroscopy, or in a two-dimensional array, as for imaging.
- Reflective layers such as metal
- the reflective layers in combination with the metal silicide, can be configured to substantially preclude light from the circuit components in the substrate.
- a region of reflective layer can be vertically aligned with the stem region.
Abstract
In accordance with the invention, a photonic device comprises a semiconductor substrate including at least one circuit component comprising a metal silicide layer and an overlying layer including at least one photoresponsive component. The metal silicide layer is disposed between the circuit component and the photoresponsive component to prevent entry into the circuit component of light that penetrates the photoresponsive component. The silicide layer advantageously reflects the light back into the photoresponsive element. In addition, the overlying layer can include one or more reflective layers to reduce entry of oblique light into the photoresponsive component. In an advantageous embodiment, the substrate comprises single-crystal silicon including one or more insulated gate field effect transistors (IGFETs), and/or capacitors, and the photoresponsive element comprises germanium and/or germanium alloy epitaxially grown from seeds on the silicon. The metal silicide layer can comprise the gate of the IGFET and/or an electrode of the capacitor.
Description
- The United States Government has certain rights in this invention pursuant to NSF Phase II SBIR Award DMI-0450487.
- This invention relates generally to semiconductor photonic devices such as photodetectors for visible and infrared light. In particular, it concerns semiconductor dual layer photonic devices configured to enhance responsivity while reducing stray light.
- Semiconductor photonic devices are highly useful in a variety of applications ranging from monitoring, analyzing and imaging light to the generation of energy from solar radiation. Typically such devices comprise semiconductor photoresponsive components such as photodiodes, photoransistors or photoresistors integrated with semiconductor processing circuitry. Such devices can be used as photodetectors and solar cells.
- Semiconductor photodetectors are widely used for the detection of light, both visible and infrared. They exploit the internal photoelectric effect, where electron-hole pairs are generated in a semiconductor by photon absorption and contribute to electrical conduction inside the device, leading to a corresponding current at the contacts of the detector. Such detectors are fabricated singly for monitoring, in linear arrays for spectroscopy, and in two-dimensional (2-D) arrays for imaging.
- One approach to the fabrication of photonic devices is to integrate photoresponsive components, such as photodiodes, with components for processing circuitry, such as transistors and capacitors. Most commonly, the photoresponsive components and the processing components are formed in the same plane. In some variations, the processing components are formed in a semiconductor substrate and photoresponsive components are formed in a layer overlying the substrate. In such devices the photoresponsive components will have a finite thickness limited by several factors, including the time and conditions needed to deposit or grow the photoresponsive components, the height of metal contacts to the substrate, and the desired planarity of the overall integrated device. As a consequence, the photoresponsive components can absorb only a portion of the light falling on them, and some of the light can be transmitted through them without being absorbed. For light near the cutoff wavelength, photodetector absorption can be quite weak. For
instance 20% might be reflected, 10% might be absorbed and 70% might be transmitted through the detector. - Light transmitted through the photoresponsive component can penetrate into the substrate, where it becomes stray light that can be absorbed (directly or after reflection) in the semiconductor circuitry, causing unexpected and undesired current to flow. Also, in a photodetector array, light that enters one photoresponsive component at an oblique angle may pass through it to another component in the array. Such stray light causes undesired crosstalk in an analyzer or blurring in an imager. Thus light that is not absorbed by the photoresponsive component can create three problems: it can degrade responsivity of the photoresponsive component, it can cause unwanted current to flow in the circuitry, and it can cause crosstalk. Accordingly there is a need for photonic devices that are configured to enhance responsivity while reducing stray light.
- In accordance with the invention, a photonic device comprises a semiconductor substrate including at least one circuit component comprising a metal silicide layer and an overlying layer including at least one photoresponsive component. The metal silicide layer is disposed between the circuit component and the photoresponsive component to prevent entry into the circuit component of light that penetrates the photoresponsive component. The silicide layer advantageously reflects the light back into the photoresponsive element. In addition, the overlying layer can include one or more reflective layers to reduce entry of oblique light into the photoresponsive component. In an advantageous embodiment, the substrate comprises single-crystal silicon including one or more insulated gate field effect transistors (IGFETs), and/or capacitors, and the photoresponsive element comprises germanium and/or germanium alloy epitaxially grown from seeds on the silicon. The metal silicide layer can comprise the gate of the IGFET and/or an electrode of the capacitor.
- The advantages, nature and various additional features of the invention will appear more fully upon consideration of the illustrative embodiments now to be described in detail in connection with the accompanying drawings. In the drawings:
-
FIGS. 1A and 1B are cross sectional and plan views, respectively, of a first exemplary photonic device in accordance with the invention; and -
FIGS. 2A and 2B are cross sectional and plan views of the device ofFIG. 1 including higher layers of metal; and -
FIG. 3 is a cross-sectional view of an alternative photonic device in accordance with the invention. - It is to be understood that these drawings are for purposes of illustrating the concepts of the invention and are not to scale.
- Referring to the drawings,
FIGS. 1A and 1B schematically illustrate a photonic device 9 comprising asemiconductor substrate 30 and an overlying layer, such asinsulating layer 20, including at least one semiconductorphotoresponsive component 10. Thesubstrate 30 includes at least one circuit component such as an insulated-gate field effect transistor including a source and a drain (not shown) underlying aninsulated gate 40. - The
photoresponsive component 10 advantageously overlies transistor insulatedgate 40, and thegate 40 advantageously includes alayer 42 to prevent light that passes through thecomponent 10 from entering the transistor region underlying thegate 40. Advantageously, thelayer 42 also reflects the light back into thephotoresponsive component 10. - In a preferred embodiment, the
substrate 30 comprises single crystal silicon, the gate comprises polysilicon, the gate insulator comprises silicon oxide, and thelayer 42 comprises metal silicide. Theinsulator layer 20 can comprise silicon oxide. Thephotoresponsive component 10 preferably comprises single-crystal germanium. The germanium can be grown from aseed stem 12 that is epitaxially grown from thesilicon substrate 30. Alternatively, the photoresponsive component can comprise polycrystalline germanium, single crystal silicon, polycrystalline silicon, or alloys of silicon and germanium in either single crystal or polycrystalline form. This includes all Si/Ge alloys between pure Si and Ge. - As an exemplary process for fabricating the preferred device, a
silicon substrate 30 can be processed in the usual way to create transistors and other desired circuitry. As part of the processing,polysilicon gates 40 are created. These gates have ametal silicide layer 42 formed on the upper surface. Thepolysilicon layer 40 which can be used as the gate of a transistor, can also be used as one plate of a capacitor whose other plate is the substrate below the polysilicon, or the polysilicon plate may be grounded. - After one or more transistors are created, they can be covered with a transparent dielectric layer. The
photoresponsive component 10, made of crystalline or polycrystalline semiconductor material, can be formed on or in the dielectric.Dielectric layer 20 can then be deposited over thesilicon substrate 30 and the transistor gate and be planarized. - In a preferred embodiment, the photoresponsive components comprise
germanium islands 10 formed by epitaxy lateral overgrowth (ELO) fromseed stems 12 using the substrate silicon as a template. The ELO technique is used to form a high qualitygermanium seed stem 12 embedded in theinsulator 20 on top of thesilicon substrate 30. As an example,insulator 20 can be formed as an oxide layer overlying a singlecrystal silicon substrate 30. Seed windows can be lithographically defined in the oxide and opened by etching down to the substrate. The exposed silicon surface can be cleaned for germanium growth. Then, germanium can be grown selectively on the exposed silicon by selective CVD growth. The growth should be continued until the germanium overgrows theseed stem 12 and fills the region of theisland 10. The seed stems 12 andislands 10 can be shaped and dimensioned so that defects originating at the Ge/Si interface are terminated at the walls ofstem 12 before reaching thegermanium island 10. This provides a region of germanium over the oxide mask that is essentially defect-free. Further details concerning this technique are set forth in U.S. Patent Application Publication No. 2004/0121507 to Bude et al., herein incorporated by reference. Alternatively, the photoresponsive component might comprise epitaxially grown silicon, polysilicon or polygermanium material deposited and patterned using standard semiconductor processing techniques. The photoresponsive component can be processed in accordance with well known techniques to form a photodiode, phototransistor or photosensitive resistor. - The
gate 40/42 underneath the photodetector is preferably sized and dimensioned to completely overlap the bottom of thephotoresponsive component 10. If a seed is used, the gate can be shaped around the stem (e.g. donut-shaped) to allow the seed stem to penetrate through it. - In operation, light is incident from above. If light is not absorbed in the photoresponsive component and is transmitted through it, the
metal silicide 42 will prevent the light from penetrating into the transistor gate and advantageously, will reflect it back through thephotoresponsive component 20, where it will have a chance to be absorbed on the second pass. Thus for low levels of absorption, the probability of absorption will be approximately doubled. For high levels of absorption, virtually all the light incident on the component will be absorbed. Light that is not absorbed does not reach the substrate. -
FIGS. 2A (cross-section) and 2B (plan-view) shows the device ofFIG. 1 provided with higher levels of metal.Metal wires 50 embedded in the upper level dielectric 22 are provided to contact the photoresponsive component, and will block oblique light to the underlying substrate. The dielectric 22 may or may not be the same asdielectric 20. A level ofmetal 52 higher in level than themetal 50 can be used as a light shield for the substrate. This light shield will have openings only above the photonic device in order to prevent oblique light from reaching the substrate. The light shield can have breaks above another metal layer as shown inFIG. 2B , since the lower metal will reflect light. An extra piece oflight shield 52 can be disposed overlying thestem 12 in order to block light that might pass from the stem to substrate. - The silicide coated gate is sandwiched between the semiconductor substrate in which the transistor is formed and the photoresponsive component is formed in a higher level. By blocking light which passes through the component, it prevents transmitted light from reaching the substrate and inducing unwanted currents in the circuits, thus acting as a light shield. It can also reflect light back into the photoresponsive component.
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FIG. 3 illustrates an alternative photonic device in accordance with the invention where the circuit component is a capacitor underlyingphotoresponsive component 10. The capacitor is composed ofpolysilicon electrode 40,substrate electrode 30 and an intervening layer ofinsulator 20A. Thepolysilicon electrode 40 is covered with a layer ofmetal silicide 42 to block from the underlying region of the capacitor light that passes through the overlyingphotoresponsive component 10. Advantageously, themetal silicide layer 42 is peripherally larger than the photoresponsive component. Higher layers ofmetal - It can now be seen that in one broad aspect, the invention is a photonic device comprising a semiconductor substrate including at least one circuit component. Overlying the substrate is a layer comprising at least one photoresponsive component that overlaps the circuit component. The circuit component comprises a metal silicide layer positioned to block from the circuit component light passing through the photoresponsive component. Advantageously the metal silicide reflects light back into the photoresponsive component. The semiconductor substrate is advantageously a single-crystal semiconductor, preferably silicon. The circuit component is advantageously an IGFET or a capacitor. The layer overlying the substrate is advantageously an insulating layer such as silicon oxide, and the photoresponsive component advantageously comprises a semiconductor, such as germanium. The metal silicide can be part of the gate of the IGFET and/or an electrode of the capacitor.
- The photoresponsive component is preferably epitaxial with the semiconductor substrate. The component can comprise a stem region of a first lateral area and thickness epitaxially grown from the substrate and a larger lateral area island region epitaxially grown from the stem region. The area and vertical thickness of the stem region can be chosen to grow an island region substantially free of dislocation defects arising from the substrate interface.
- In an advantageous embodiment, the metal silicide is peripherally larger than the photoresponsive component covers the underlying portions of the circuit component to block stray light from the underlying portions.
- Such photodetectors can be utilized individually, as for light monitoring, or a plurality of such photodetectors can be disposed in a one-dimensional (linear) array, as for spectroscopy, or in a two-dimensional array, as for imaging.
- Reflective layers, such as metal, can be disposed and patterned on the layer overlying the substrate. The reflective layers, in combination with the metal silicide, can be configured to substantially preclude light from the circuit components in the substrate. Where the photoresponsive component includes a stem, a region of reflective layer can be vertically aligned with the stem region.
- It is to be understood that the above-described embodiments are illustrative of only a few of the many possible embodiments which can represent applications of the invention. Numerous and varied other arrangements can be made by those skilled in the art without departing from the spirit and scope of the invention.
Claims (5)
1.-27. (canceled)
28. A device comprising:
a photoresponsive component integrated with a substrate; and
a layer configured to preclude substantially all light passing through the photoresponsive component from reaching the substrate.
29. The device of claim 28 , wherein the layer configured to preclude substantially all light passing through the photoresponsive component from reaching the substrate comprises a metal silicide.
30. The device of claim 28 , wherein the substrate comprises at least one circuit component, and wherein the layer is further configured to preclude substantially all light passing through the photoresponsive component from reaching the at least one circuit component.
31. An apparatus comprising:
a semiconductor substrate comprising at least one circuit component;
a semiconductor photoresponsive component overlying at least part of the substrate, the photoresponsive component having a first surface configured to receive incident radiation, the first surface having a first periphery; and
a metal silicide layer disposed at least partially between the photoresponsive component and the at least one circuit component, the metal silicide layer having a second surface configured to receive incident radiation passing through the photoresponsive component, the second surface having a second periphery greater than the first periphery.
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US12/610,522 US20100044823A1 (en) | 2006-02-10 | 2009-11-02 | Semiconductor photonic devices with enhanced responsivity and reduced stray light |
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US11/351,638 US7629661B2 (en) | 2006-02-10 | 2006-02-10 | Semiconductor devices with photoresponsive components and metal silicide light blocking structures |
US12/610,522 US20100044823A1 (en) | 2006-02-10 | 2009-11-02 | Semiconductor photonic devices with enhanced responsivity and reduced stray light |
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US11/351,638 Continuation US7629661B2 (en) | 2006-02-10 | 2006-02-10 | Semiconductor devices with photoresponsive components and metal silicide light blocking structures |
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US11/351,638 Active 2027-01-09 US7629661B2 (en) | 2006-02-10 | 2006-02-10 | Semiconductor devices with photoresponsive components and metal silicide light blocking structures |
US12/610,522 Abandoned US20100044823A1 (en) | 2006-02-10 | 2009-11-02 | Semiconductor photonic devices with enhanced responsivity and reduced stray light |
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EP (1) | EP1987542A2 (en) |
JP (1) | JP2009526406A (en) |
KR (1) | KR20080100199A (en) |
TW (1) | TW200739929A (en) |
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Also Published As
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US20070187796A1 (en) | 2007-08-16 |
JP2009526406A (en) | 2009-07-16 |
WO2007095142A2 (en) | 2007-08-23 |
TW200739929A (en) | 2007-10-16 |
US7629661B2 (en) | 2009-12-08 |
EP1987542A2 (en) | 2008-11-05 |
KR20080100199A (en) | 2008-11-14 |
WO2007095142A3 (en) | 2007-10-04 |
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