US20110101377A1 - High temperature ion implantation of nitride based hemts - Google Patents

High temperature ion implantation of nitride based hemts Download PDF

Info

Publication number
US20110101377A1
US20110101377A1 US12/983,655 US98365511A US2011101377A1 US 20110101377 A1 US20110101377 A1 US 20110101377A1 US 98365511 A US98365511 A US 98365511A US 2011101377 A1 US2011101377 A1 US 2011101377A1
Authority
US
United States
Prior art keywords
nitride layer
implantation
group iii
carried out
gallium nitride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US12/983,655
Inventor
Alexander Suvorov
Scott T. Sheppard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wolfspeed Inc
Original Assignee
Cree Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cree Inc filed Critical Cree Inc
Priority to US12/983,655 priority Critical patent/US20110101377A1/en
Publication of US20110101377A1 publication Critical patent/US20110101377A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/26Bombardment with radiation
    • H01L21/263Bombardment with radiation with high-energy radiation
    • H01L21/265Bombardment with radiation with high-energy radiation producing ion implantation
    • H01L21/2654Bombardment with radiation with high-energy radiation producing ion implantation in AIIIBV compounds
    • H01L21/26546Bombardment with radiation with high-energy radiation producing ion implantation in AIIIBV compounds of electrically active species
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/43Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/45Ohmic electrodes
    • H01L29/452Ohmic electrodes on AIII-BV compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66446Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET]
    • H01L29/66462Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET] with a heterojunction interface channel or gate, e.g. HFET, HIGFET, SISFET, HJFET, HEMT
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/12Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/20Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds
    • H01L29/2003Nitride compounds

Definitions

  • the present invention relates to semiconductor devices and, more particularly, to Group-III nitride based high electron mobility transistors (HEMTs).
  • HEMTs Group-III nitride based high electron mobility transistors
  • HEMTs are semiconductor devices that can be used for a variety of applications including microwave and millimeter-wave communications, radar, radio astronomy, cell phones, direct broadcast satellite receivers, and electronic warfare systems.
  • HEMTs are field effect transistors that utilize the heterojunction between two materials having different bandgaps to form a conductive channel rather than a doped region. HEMTs typically do not require impurities to form the conductive layer and therefore allow for higher electron mobility.
  • HEMTs are regularly fabricated from semiconductor materials such as silicon (Si) and gallium arsenide (GaAs).
  • Si has a low electron mobility, which generates a high source resistance; therefore, Si semiconductor materials may not be well suited for high power, high frequency, and high temperature applications.
  • GaAs semiconductor materials have higher electron mobility and a lower source resistance than Si, which allows them to operate at higher frequencies.
  • GaAs has, however, a relatively small bandgap preventing the use of GaAs HEMTs in high power at high frequency applications.
  • GaN gallium nitride
  • AlGaN aluminum nitride and gallium nitride
  • the use of AlGaN layered upon GaN and the mismatch of the crystal structures of the two materials and their different bandgap energies results in the creation of a two-dimensional electron gas (2DEG) under certain circumstances.
  • the 2DEG layer accumulates in the smaller bandgap material and contains a very high electron concentration. Electrons originating in the wider-bandgap material transfer to the 2DEG allowing for a higher electron mobility.
  • AlGaN/GaN HEMTs greater performance than metal-semiconductor field effect transistors (MESFETs) for high-frequency applications.
  • MESFETs metal-semiconductor field effect transistors
  • One method of fabricating an AlGaN/GaN HEMT includes forming a layer of GaN on a substrate (typically silicon carbide (SiC)), forming a thin layer of AlGaN on the GaN layer, and providing ohmic contacts and a gate contact on the AlGaN layer.
  • a substrate typically silicon carbide (SiC)
  • SiC silicon carbide
  • Another method of forming low-resistive ohmic contacts on AlGaN/GaN HEMTs generally well-understood within the art employs ion implantation at the ohmic contact region. Implantation in this manner allows the use of a Ti/Ni/Al contact, thus eliminating the poor morphology created by the use of Au.
  • this implantation process creates another problem because of the high doses of implantation ions that must be used in order to get sufficient activation rates within the implanted regions.
  • the high doses of implantation ions create large amounts of crystal destruction. This destruction can be corrected by annealing the device; however, SiC and AlGaN are difficult to recrystallize by annealing. In order to recrystallize SiC and AlGaN properly, longer annealing temperatures can be used. Longer anneal times, however, damage other features of the device.
  • the invention is a method of forming a high electron mobility transistor.
  • the method includes implanting a Group III nitride layer at a defined position with ions that when implanted produce an improved ohmic contact between the layer and contact metals.
  • Implantation is carried out at a temperature higher than room temperature and hot enough to reduce the amount of damage done to the Group III nitride layer, but below a temperature at which surface problems causing leakage at the gate or epitaxial layer dissociation would occur.
  • An ohmic contact s is added to the implanted defined position on the Group III nitride layer.
  • the method includes carrying out the implantation with an ion beam current high enough to successfully implant ions within the Group III nitride layer, but below a current that would melt or destroy the Group III nitride layer and at a temperature higher than room temperature and hot enough to reduce the amount of damage done to the Group III nitride layer, but below a temperature at which surface problems causing leakage at the gate or epitaxial layer dissociation would occur.
  • the invention is a transistor precursor that includes a growth substrate selected from the group consisting of silicon carbide and sapphire, a layer of gallium nitride on the growth substrate, a layer of aluminum gallium nitride on the gallium nitride layer for generating a two dimensional electron gas at the interface between the layers when a current is applied in a HEMT orientation and defined implanted regions in the aluminum gallium nitride and gallium nitride layers for improving the ohmic characteristics of the layers when an ohmic metal is added to the defined implanted regions, with the defined implanted regions of the transistor precursor having a temperature of between about 250° and 900° C.
  • FIG. 1 is a schematic cross-sectional view of an AlGaN/GaN HEMT according to an embodiment of the present invention.
  • FIGS. 2-4 are photographs of three gallium nitride wafers implanted with silicon ions under different conditions.
  • FIG. 5 depicts the transmission spectrums in the visible range of wafers implanted with silicon ions under various conditions.
  • FIG. 1 illustrates a schematic cross-section of an AlGaN/GaN based HEMT 10 constructed in accordance with an embodiment of the present invention.
  • the HEMT includes a substrate 11 formed from materials generally well-understood within the art (e.g., silicon carbide (SiC) or sapphire (Al 2 O 3 )).
  • a GaN layer 12 is provided on the substrate 11 .
  • the HEMT 10 includes an AlGaN layer 13 provided on top of the GaN layer 12 .
  • SiC forms the substrate 11 .
  • the crystal lattice structure of SiC matches more closely to the Group-III nitrides than sapphire, resulting in higher quality Group-III nitride films.
  • SiC has a very high thermal conductivity which allows for higher total output power of the device.
  • the AlGaN layer 13 has a wider bandgap than the GaN layer 12 which results in a free charge transfer from the AlGaN layer 13 to the GaN layer 12 .
  • Charge accumulates at the interface of the AlGaN layer 13 and the GaN layer 12 forming a two-dimensional electron gas (2DEG) (not shown).
  • the 2DEG has very high electron mobility resulting in a HEMT 10 with very high transconductance at high frequencies.
  • the voltage applied to the gate 14 controls the electron flow in the 2DEG under the gate 14 , allowing for control over the total electron flow.
  • the gate 14 is a Schottky gate.
  • the source contact 15 and drain contact 16 provided on the AlGaN layer 13 are preferably formed of alloys of titanium (Ti), aluminum (Al), and nickel (Ni).
  • Traditional alloys used for ohmic contacts 15 and 16 are formed of Ti, Al, Ni as well as gold (Au).
  • Au gold
  • the addition of Au gives the alloy poor morphology, so the contacts 15 and 16 of the present invention preferably do not include Au.
  • Other candidate compositions for the ohmic contact include titanium-tungsten-nitride (Ti—W—N), titanium-nitride (Ti—N), molybdenum (Mo) and molybdenum silicides.
  • High temperature ion implantation using a high ion beam current of an n-type dopant creates the implanted regions 20 and 21 .
  • the dopant ions are Si + .
  • These implanted regions 20 and 21 allow the contacts 15 and 16 to be ohmic towards the 2DEG.
  • High temperature should be understood to include temperatures that are below a temperature at which surface problems causing leakage at the gate 14 or epitaxial layer dissociation would occur but higher than room temperature.
  • the temperature at which implantation occurs is between about 250° C. and 900° C.
  • High ion beam current as used herein should be understood to include a beam current below that which would melt or destroy the crystal, but high enough to successfully implant ions within the AlGaN and GaN layers 13 and 12 .
  • the beam current is between 30 ⁇ A and 130 ⁇ A.
  • the present invention is an AlGaN/GaN HEMT wherein implanted regions 20 and 21 have been implanted at a temperature of 650° C. using an ion beam current of 40 ⁇ A.
  • the present invention is an AlGaN/GaN HEMT wherein implanted regions 20 and 21 have been implanted at a temperature of 650° C. using an ion beam current of 120 ⁇ A.
  • the present invention is an AlGaN/GaN HEMT wherein implanted regions 20 and 21 have been implanted at a temperature of 350° C. using an ion beam current of 40 ⁇ A.
  • the present invention is an AlGaN/GaN HEMT wherein implanted regions 20 and 21 have been implanted at a temperature of 350° C. using an ion beam current of 120 ⁇ A.
  • the present invention also includes methods for fabricating HEMTs using high temperature ion implantation.
  • U.S. Pat. No. 7,230,284 discloses a method for forming the GaN layer 12 on the substrate 11 and forming the AlGaN layer 13 on the GaN layer 12 .
  • a mask layer protects only the portion of the AlGaN layer that will not be implanted leaving the crystal exposed in the regions to be implanted.
  • the mask layer is a material capable of withstanding the conditions of the high temperature, high ion beam current implantation without otherwise adversely affecting either the implantation step or the device.
  • the mask layer may be formed of an oxide.
  • the device is then maintained at a high temperature and a high current beam implants n-type dopant ions (e.g. Si + ions) through the AlGaN layer 13 into the GaN layer 12 to form implanted regions 20 and 21 .
  • n-type dopant ions e.g. Si + ions
  • the ions are implanted to a depth that allows the ohmic contacts 15 and 16 to act ohmic towards the 2DEG.
  • a protective layer may be placed over the regions to be implanted.
  • silicon nitride Si 3 N 4 is the protective layer.
  • the protective layer reduces the amount of damage to the AlGaN layer created by the ion beam.
  • the use of a protective layer is preferred because AlGaN can be particularly difficult to recrystallize using annealing methods.
  • an annealing process improves the damaged implanted regions 20 and 21 . Shorter anneal times are desired because the anneal has the potential to damage other parts of the device. Implantation at high temperature results in less damage to the implanted regions and therefore allows shorter anneal times, which reduces the possibility for anneal-based secondary damage.
  • Ohmic contacts 15 and 16 are then formed on the AlGaN layer 13 over the implanted regions 20 and 21 .
  • the ohmic contacts 15 and 16 connect with the 2DEG electronically through the implanted regions 20 and 21 .
  • an alloy of Ti, Ni, and Al forms the ohmic contacts 15 and 16 .
  • a gate 14 can be formed on the AlGaN layer 13 over the 2DEG.
  • the voltage applied to the gate 14 controls the electron flow in the 2DEG, allowing for control over the total electron flow.
  • the gate 14 is a Schottky gate.
  • FIGS. 2-4 Each wafer in FIGS. 2-4 is GaN that has been implanted with Si + ions.
  • FIGS. 2-4 illustrate that conducting the implantation step of this method at high temperature avoids damaging the implanted crystals as much as implantation at room temperature.
  • the lighter shades indicate more light passage based upon less crystal damage, while darker shades indicate less light passage resulting from more crystal damage.
  • the top left quarter of the wafer 30 has been implanted using an ion beam current of 120 ⁇ A to at a temperature of 350° C.
  • the bottom right quarter of the wafer 31 has been implanted using an ion beam current of 120 ⁇ A to at room temperature.
  • the top left quarter 30 is significantly lighter than the bottom right quarter 31 , indicating significantly less damage because of the higher temperature during implantation.
  • the top left quarter of the wafer 32 has been implanted using an ion beam current of 120 ⁇ A to at a temperature of 650° C.
  • the bottom right quarter of the wafer 33 has been implanted using an ion beam current of 120 ⁇ A to at room temperature.
  • the top left quarter 32 is significantly lighter than the bottom right quarter 33 , indicating significantly less damage because of the higher temperature during implantation.
  • a comparison of the top left quarter of the wafer 30 in FIG. 2 and the top left quarter of the wafer 32 in FIG. 3 also indicates that implantation at higher temperatures decreases the amount of crystal damage created by the implantation process.
  • a high current ion beam provides two distinct advantages over a lower current ion beam. Using a high current ion beam reduces the time it takes to implant a given dose of dopant ions therefore reducing costs. Additionally, the use of a high current ion beam further increases the temperature of the wafer during implantation, resulting in less damage to the implanted crystal.
  • the wafer in FIG. 4 illustrates the second advantage of using a higher current ion beam.
  • the top left quarter of the wafer 34 has been implanted using an ion beam current of 120 ⁇ A to at a temperature of 350° C.
  • the bottom right quarter of the wafer 35 has been implanted using an ion beam current of 40 ⁇ A to at a temperature of 350° C.
  • the top left quarter 34 is significantly lighter than the bottom right quarter 35 , indicating significantly less damage because of the higher ion beam current during implantation.
  • Some of the reduced damage in the top left quarter 34 may be attributable to the fact that it was effectively annealed at 350° C. while the bottom right quarter of the wafer 35 was being implanted.
  • the difference in clarity created by the anneal is believed to be less significant than the difference in clarity created by the higher ion beam current.
  • FIG. 5 illustrates the previously mentioned lightness and darkness comparisons in a more concrete manner.
  • the graph plots the percentage of light transmitted through GaN wafers that have been implanted with Si + versus the wavelength of the light for the visible range.
  • the two highest plots one formed of squares and the other of diamonds, indicate the transmission percentages of two GaN wafers that have not been implanted. As shown in FIG. 5 , these unimplanted wafers transmit the highest percentage of visible light.
  • the lowest plot, formed of downward pointing triangles indicates the transmission percentage of a GaN wafer implanted with Si + at room temperature with an ion beam current of 120 ⁇ A to over the visible range. As shown in FIG. 5 , this wafer transmits the lowest percentage of visible light.
  • the mid-level plot formed of circles indicates the transmission percentage of a GaN wafer implanted with Si + at a temperature of 650° C. with an ion beam current of 120 ⁇ A to over the visible range.
  • the mid-level plot formed of diamonds indicates the transmission percentage of a GaN wafer implanted with Si + at a temperature of 350° C. with an ion beam current of 120 ⁇ A over the visible range.
  • the mid-level plot formed of downward pointing triangles indicates the transmission percentage of a GaN wafer implanted with Si + at a temperature of 350° C. with an ion beam current of 40 ⁇ A to over the visible range.
  • These three mid-level plots indicate the transmission spectrums of three different wafers that are embodiments of the present invention. As shown in FIG. 5 , these three wafers transmit more light over the visible range than the wafer implanted at room temperature. FIG. 5 also indicates that these three wafers transmit less light over the visible range than the unimplanted wafers.
  • mid-level plot formed of diamonds i.e., the wafer implanted at 350° C. with a current of 120 ⁇ A
  • mid-level plot formed of downward pointing triangles i.e, the wafer implanted at 350° C. with a current of 40 ⁇ A
  • the plots show that implantation at high temperatures (e.g., the three mid-level plots) produces a wafer that transmits a much higher percentage of visible light than implantation at room temperature (e.g., the lowest plot).
  • the transmission percentage correlates with less damage to the crystal structure of the wafer. Therefore, implantation at high temperatures creates less damage to the crystal structure of the wafer than implantation at room temperature.
  • the plot also shows that a wafer implanted using a higher ion beam current (e.g., the mid-level plot formed of diamonds) transmits a higher percentage of visible light than a wafer implanted using a lower ion beam current (e.g., the mid-level plot formed of downward pointing triangles).
  • a higher ion beam current e.g., the mid-level plot formed of diamonds
  • a lower ion beam current e.g., the mid-level plot formed of downward pointing triangles.
  • the method of the present invention produces HEMTs with significantly less damage to the crystal than previously disclosed methods. As a result, HEMTs produced using the method of the present invention perform superiorly to prior HEMTs.
  • the following table contains data on the performance of a HEMT device implanted at room temperature and a HEMT device implanted at high temperature in accordance with the present invention:
  • the wafers of the table received the same implant dose of 1.00 ⁇ 10 16 atoms/cm 2 of Si + and the same temperature anneal (1080° C.).
  • the data shows that both wafers were supplied with the same RF power, gate-source voltage, drain-source voltage, and current.
  • the high temperature implanted HEMT had a higher gain, output power, power added efficiency and drain source current as well as a lower average on-resistance. This data indicates that devices formed according to the present invention have better device performance than devices formed using ion implantation at room temperature.

Abstract

A method is disclosed for forming a high electron mobility transistor. The method includes the steps of implanting a Group III nitride layer at a defined position with ions that when implanted produce an improved ohmic contact between the layer and contact metals, with the implantation being carried out at a temperature higher than room temperature and hot enough to reduce the amount of damage done to the Group III nitride layer, but below a temperature at which surface problems causing leakage at the gate or epitaxial layer dissociation would occur. An ohmic contact selected from the group consisting of titanium, aluminum, nickel and alloys thereof is added to the implanted defined position on the Group III nitride layer.

Description

    STATEMENT OF GOVERNMENT INTEREST
  • This invention was developed, at least in part, under DARPA Contract No. 4400121759. The Government may have certain rights in this invention.
  • BACKGROUND
  • The present invention relates to semiconductor devices and, more particularly, to Group-III nitride based high electron mobility transistors (HEMTs).
  • HEMTs are semiconductor devices that can be used for a variety of applications including microwave and millimeter-wave communications, radar, radio astronomy, cell phones, direct broadcast satellite receivers, and electronic warfare systems.
  • Traditional semiconductors usually require a conductive layer that is doped with n-type impurities to generate free electrons; however, the electrons within the layer tend to collide with these impurities, which slows them down. HEMTs are field effect transistors that utilize the heterojunction between two materials having different bandgaps to form a conductive channel rather than a doped region. HEMTs typically do not require impurities to form the conductive layer and therefore allow for higher electron mobility.
  • HEMTs are regularly fabricated from semiconductor materials such as silicon (Si) and gallium arsenide (GaAs). Si has a low electron mobility, which generates a high source resistance; therefore, Si semiconductor materials may not be well suited for high power, high frequency, and high temperature applications.
  • Signal amplification devices in radar, cellular, and satellite communications frequently use GaAs based HEMTs. GaAs semiconductor materials have higher electron mobility and a lower source resistance than Si, which allows them to operate at higher frequencies. GaAs has, however, a relatively small bandgap preventing the use of GaAs HEMTs in high power at high frequency applications.
  • Improvements in the manufacturing of gallium nitride (GaN) semi-conductor materials and semi-conductor materials made from an alloy consisting of aluminum nitride and gallium nitride (AlGaN) have focused interest on the use of AlGaN/GaN HEMTs for use in high frequency, high power and high temperature applications. AlGaN and GaN have large bandgaps making them superior to Si and GaAs for these types of applications.
  • The use of AlGaN layered upon GaN and the mismatch of the crystal structures of the two materials and their different bandgap energies results in the creation of a two-dimensional electron gas (2DEG) under certain circumstances. The 2DEG layer accumulates in the smaller bandgap material and contains a very high electron concentration. Electrons originating in the wider-bandgap material transfer to the 2DEG allowing for a higher electron mobility.
  • The combination of high electron concentration and high electron mobility gives AlGaN/GaN HEMTs greater performance than metal-semiconductor field effect transistors (MESFETs) for high-frequency applications.
  • One method of fabricating an AlGaN/GaN HEMT includes forming a layer of GaN on a substrate (typically silicon carbide (SiC)), forming a thin layer of AlGaN on the GaN layer, and providing ohmic contacts and a gate contact on the AlGaN layer.
  • Traditionally an alloy of titanium (Ti), aluminum (Al), nickel (Ni), and gold (Au) forms the ohmic contacts. In order to function as an electronic contact the alloy must be ohmic towards the 2DEG layer rather than the AlGaN layer on which it is placed. The addition of Au to this alloy enables the contacts to be ohmic towards the 2DEG; however, the Au also gives the alloy bad morphology.
  • Another method of forming low-resistive ohmic contacts on AlGaN/GaN HEMTs generally well-understood within the art employs ion implantation at the ohmic contact region. Implantation in this manner allows the use of a Ti/Ni/Al contact, thus eliminating the poor morphology created by the use of Au.
  • Nevertheless, this implantation process creates another problem because of the high doses of implantation ions that must be used in order to get sufficient activation rates within the implanted regions. The high doses of implantation ions create large amounts of crystal destruction. This destruction can be corrected by annealing the device; however, SiC and AlGaN are difficult to recrystallize by annealing. In order to recrystallize SiC and AlGaN properly, longer annealing temperatures can be used. Longer anneal times, however, damage other features of the device.
  • Therefore, there is a need for an implantation process that uses high doses of ions and creates less damage to the implanted crystal thus requiring less annealing.
  • SUMMARY
  • In one aspect, the invention is a method of forming a high electron mobility transistor. The method includes implanting a Group III nitride layer at a defined position with ions that when implanted produce an improved ohmic contact between the layer and contact metals.
  • Implantation is carried out at a temperature higher than room temperature and hot enough to reduce the amount of damage done to the Group III nitride layer, but below a temperature at which surface problems causing leakage at the gate or epitaxial layer dissociation would occur. An ohmic contact s is added to the implanted defined position on the Group III nitride layer.
  • In another aspect the method includes carrying out the implantation with an ion beam current high enough to successfully implant ions within the Group III nitride layer, but below a current that would melt or destroy the Group III nitride layer and at a temperature higher than room temperature and hot enough to reduce the amount of damage done to the Group III nitride layer, but below a temperature at which surface problems causing leakage at the gate or epitaxial layer dissociation would occur.
  • In yet another aspect, the invention is a transistor precursor that includes a growth substrate selected from the group consisting of silicon carbide and sapphire, a layer of gallium nitride on the growth substrate, a layer of aluminum gallium nitride on the gallium nitride layer for generating a two dimensional electron gas at the interface between the layers when a current is applied in a HEMT orientation and defined implanted regions in the aluminum gallium nitride and gallium nitride layers for improving the ohmic characteristics of the layers when an ohmic metal is added to the defined implanted regions, with the defined implanted regions of the transistor precursor having a temperature of between about 250° and 900° C.
  • The foregoing and other objects and advantages of the invention and the manner in which the same are accomplished will become clearer based on the followed detailed description taken in conjunction with the accompanying drawings.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a schematic cross-sectional view of an AlGaN/GaN HEMT according to an embodiment of the present invention.
  • FIGS. 2-4 are photographs of three gallium nitride wafers implanted with silicon ions under different conditions.
  • FIG. 5 depicts the transmission spectrums in the visible range of wafers implanted with silicon ions under various conditions.
  • DETAILED DESCRIPTION
  • FIG. 1 illustrates a schematic cross-section of an AlGaN/GaN based HEMT 10 constructed in accordance with an embodiment of the present invention. The HEMT includes a substrate 11 formed from materials generally well-understood within the art (e.g., silicon carbide (SiC) or sapphire (Al2O3)). A GaN layer 12 is provided on the substrate 11. The HEMT 10 includes an AlGaN layer 13 provided on top of the GaN layer 12.
  • Preferably, SiC forms the substrate 11. The crystal lattice structure of SiC matches more closely to the Group-III nitrides than sapphire, resulting in higher quality Group-III nitride films. Furthermore, SiC has a very high thermal conductivity which allows for higher total output power of the device.
  • The AlGaN layer 13 has a wider bandgap than the GaN layer 12 which results in a free charge transfer from the AlGaN layer 13 to the GaN layer 12. Charge accumulates at the interface of the AlGaN layer 13 and the GaN layer 12 forming a two-dimensional electron gas (2DEG) (not shown). The 2DEG has very high electron mobility resulting in a HEMT 10 with very high transconductance at high frequencies. The voltage applied to the gate 14 controls the electron flow in the 2DEG under the gate 14, allowing for control over the total electron flow. Preferably, the gate 14 is a Schottky gate.
  • The source contact 15 and drain contact 16 provided on the AlGaN layer 13 are preferably formed of alloys of titanium (Ti), aluminum (Al), and nickel (Ni). Traditional alloys used for ohmic contacts 15 and 16 are formed of Ti, Al, Ni as well as gold (Au). The addition of Au gives the alloy poor morphology, so the contacts 15 and 16 of the present invention preferably do not include Au. Other candidate compositions for the ohmic contact include titanium-tungsten-nitride (Ti—W—N), titanium-nitride (Ti—N), molybdenum (Mo) and molybdenum silicides.
  • High temperature ion implantation using a high ion beam current of an n-type dopant creates the implanted regions 20 and 21. Preferably, the dopant ions are Si+. These implanted regions 20 and 21 allow the contacts 15 and 16 to be ohmic towards the 2DEG.
  • High temperature as used herein should be understood to include temperatures that are below a temperature at which surface problems causing leakage at the gate 14 or epitaxial layer dissociation would occur but higher than room temperature. Preferably, the temperature at which implantation occurs is between about 250° C. and 900° C.
  • High ion beam current as used herein should be understood to include a beam current below that which would melt or destroy the crystal, but high enough to successfully implant ions within the AlGaN and GaN layers 13 and 12. Preferably, the beam current is between 30 μA and 130 μA.
  • In one embodiment, the present invention is an AlGaN/GaN HEMT wherein implanted regions 20 and 21 have been implanted at a temperature of 650° C. using an ion beam current of 40 μA.
  • In another embodiment, the present invention is an AlGaN/GaN HEMT wherein implanted regions 20 and 21 have been implanted at a temperature of 650° C. using an ion beam current of 120 μA.
  • In a third embodiment, the present invention is an AlGaN/GaN HEMT wherein implanted regions 20 and 21 have been implanted at a temperature of 350° C. using an ion beam current of 40 μA.
  • In a fourth embodiment, the present invention is an AlGaN/GaN HEMT wherein implanted regions 20 and 21 have been implanted at a temperature of 350° C. using an ion beam current of 120 μA.
  • The present invention also includes methods for fabricating HEMTs using high temperature ion implantation. U.S. Pat. No. 7,230,284 discloses a method for forming the GaN layer 12 on the substrate 11 and forming the AlGaN layer 13 on the GaN layer 12.
  • A mask layer protects only the portion of the AlGaN layer that will not be implanted leaving the crystal exposed in the regions to be implanted. The mask layer is a material capable of withstanding the conditions of the high temperature, high ion beam current implantation without otherwise adversely affecting either the implantation step or the device. For example, the mask layer may be formed of an oxide.
  • The device is then maintained at a high temperature and a high current beam implants n-type dopant ions (e.g. Si+ ions) through the AlGaN layer 13 into the GaN layer 12 to form implanted regions 20 and 21. The ions are implanted to a depth that allows the ohmic contacts 15 and 16 to act ohmic towards the 2DEG.
  • In a particular embodiment of this method, a protective layer may be placed over the regions to be implanted. In a more particular embodiment, silicon nitride (Si3N4) is the protective layer. The protective layer reduces the amount of damage to the AlGaN layer created by the ion beam. The use of a protective layer is preferred because AlGaN can be particularly difficult to recrystallize using annealing methods.
  • After implantation, an annealing process improves the damaged implanted regions 20 and 21. Shorter anneal times are desired because the anneal has the potential to damage other parts of the device. Implantation at high temperature results in less damage to the implanted regions and therefore allows shorter anneal times, which reduces the possibility for anneal-based secondary damage.
  • Ohmic contacts 15 and 16 are then formed on the AlGaN layer 13 over the implanted regions 20 and 21. The ohmic contacts 15 and 16 connect with the 2DEG electronically through the implanted regions 20 and 21. Preferably, an alloy of Ti, Ni, and Al forms the ohmic contacts 15 and 16.
  • A gate 14 can be formed on the AlGaN layer 13 over the 2DEG. The voltage applied to the gate 14 controls the electron flow in the 2DEG, allowing for control over the total electron flow. Preferably, the gate 14 is a Schottky gate.
  • Each wafer in FIGS. 2-4 is GaN that has been implanted with Si+ ions. FIGS. 2-4 illustrate that conducting the implantation step of this method at high temperature avoids damaging the implanted crystals as much as implantation at room temperature. In FIGS. 2-4, the lighter shades indicate more light passage based upon less crystal damage, while darker shades indicate less light passage resulting from more crystal damage.
  • In FIG. 2, the top left quarter of the wafer 30 has been implanted using an ion beam current of 120 μA to at a temperature of 350° C. The bottom right quarter of the wafer 31 has been implanted using an ion beam current of 120 μA to at room temperature. The top left quarter 30 is significantly lighter than the bottom right quarter 31, indicating significantly less damage because of the higher temperature during implantation.
  • Similarly, in FIG. 3, the top left quarter of the wafer 32 has been implanted using an ion beam current of 120 μA to at a temperature of 650° C. The bottom right quarter of the wafer 33 has been implanted using an ion beam current of 120 μA to at room temperature. The top left quarter 32 is significantly lighter than the bottom right quarter 33, indicating significantly less damage because of the higher temperature during implantation.
  • A comparison of the top left quarter of the wafer 30 in FIG. 2 and the top left quarter of the wafer 32 in FIG. 3 also indicates that implantation at higher temperatures decreases the amount of crystal damage created by the implantation process.
  • The use of a high current ion beam provides two distinct advantages over a lower current ion beam. Using a high current ion beam reduces the time it takes to implant a given dose of dopant ions therefore reducing costs. Additionally, the use of a high current ion beam further increases the temperature of the wafer during implantation, resulting in less damage to the implanted crystal.
  • The wafer in FIG. 4 illustrates the second advantage of using a higher current ion beam. In FIG. 4 the top left quarter of the wafer 34 has been implanted using an ion beam current of 120 μA to at a temperature of 350° C. The bottom right quarter of the wafer 35 has been implanted using an ion beam current of 40 μA to at a temperature of 350° C. The top left quarter 34 is significantly lighter than the bottom right quarter 35, indicating significantly less damage because of the higher ion beam current during implantation. Some of the reduced damage in the top left quarter 34 may be attributable to the fact that it was effectively annealed at 350° C. while the bottom right quarter of the wafer 35 was being implanted. The difference in clarity created by the anneal is believed to be less significant than the difference in clarity created by the higher ion beam current.
  • FIG. 5 illustrates the previously mentioned lightness and darkness comparisons in a more concrete manner. The graph plots the percentage of light transmitted through GaN wafers that have been implanted with Si+ versus the wavelength of the light for the visible range.
  • The two highest plots, one formed of squares and the other of diamonds, indicate the transmission percentages of two GaN wafers that have not been implanted. As shown in FIG. 5, these unimplanted wafers transmit the highest percentage of visible light.
  • The lowest plot, formed of downward pointing triangles indicates the transmission percentage of a GaN wafer implanted with Si+ at room temperature with an ion beam current of 120 μA to over the visible range. As shown in FIG. 5, this wafer transmits the lowest percentage of visible light.
  • The mid-level plot formed of circles indicates the transmission percentage of a GaN wafer implanted with Si+ at a temperature of 650° C. with an ion beam current of 120 μA to over the visible range. The mid-level plot formed of diamonds indicates the transmission percentage of a GaN wafer implanted with Si+ at a temperature of 350° C. with an ion beam current of 120 μA over the visible range. The mid-level plot formed of downward pointing triangles indicates the transmission percentage of a GaN wafer implanted with Si+ at a temperature of 350° C. with an ion beam current of 40 μA to over the visible range. These three mid-level plots indicate the transmission spectrums of three different wafers that are embodiments of the present invention. As shown in FIG. 5, these three wafers transmit more light over the visible range than the wafer implanted at room temperature. FIG. 5 also indicates that these three wafers transmit less light over the visible range than the unimplanted wafers.
  • It should also be noted that the mid-level plot formed of diamonds (i.e., the wafer implanted at 350° C. with a current of 120 μA) has higher values over the visible range than the mid-level plot formed of downward pointing triangles (i.e, the wafer implanted at 350° C. with a current of 40 μA). This comparison indicates that wafers implanted at higher beam currents typically transmit a greater percentage of light than wafers implanted at lower beam currents.
  • The plots show that implantation at high temperatures (e.g., the three mid-level plots) produces a wafer that transmits a much higher percentage of visible light than implantation at room temperature (e.g., the lowest plot). The transmission percentage correlates with less damage to the crystal structure of the wafer. Therefore, implantation at high temperatures creates less damage to the crystal structure of the wafer than implantation at room temperature.
  • The plot also shows that a wafer implanted using a higher ion beam current (e.g., the mid-level plot formed of diamonds) transmits a higher percentage of visible light than a wafer implanted using a lower ion beam current (e.g., the mid-level plot formed of downward pointing triangles). Once again, the transmission percentage correlates with less damage to the crystal structure of the wafer. Therefore, implantation using higher ion beam currents creates less damage to the crystal structure of the wafer than implantation at lower ion beam currents.
  • The method of the present invention produces HEMTs with significantly less damage to the crystal than previously disclosed methods. As a result, HEMTs produced using the method of the present invention perform superiorly to prior HEMTs.
  • The following table contains data on the performance of a HEMT device implanted at room temperature and a HEMT device implanted at high temperature in accordance with the present invention:
  • RF Gate- Drain- Power Average Drain
    Implant Power Source Source Current Output Added On- Source
    Temperature (GHz) Voltage Voltage (mA/mm) Gain Power Efficiency Resistance Current
    350° C. 10 −2.8 48 43.0 13.7 9.13 51.6 3.54 1007.8
    Room 10 −2.8 48 43.0 11.7 8.42 48.4 3.90 936.4
    Temperature
  • The wafers of the table received the same implant dose of 1.00×1016 atoms/cm2 of Si+ and the same temperature anneal (1080° C.). The data shows that both wafers were supplied with the same RF power, gate-source voltage, drain-source voltage, and current. The high temperature implanted HEMT had a higher gain, output power, power added efficiency and drain source current as well as a lower average on-resistance. This data indicates that devices formed according to the present invention have better device performance than devices formed using ion implantation at room temperature.
  • In the drawings and specification there has been set forth a preferred embodiment of the invention, and although specific terms have been employed, they are used in a generic and descriptive sense only and not for purposes of limitation, the scope of the invention being defined in the claims.

Claims (48)

1. A transistor precursor comprising:
a layer of gallium nitride;
a layer of aluminum gallium nitride on said gallium nitride layer for generating a two dimensional electron gas at an interface between the layers when a current is applied in a HEMT orientation;
defined implanted regions in the aluminum gallium nitride and gallium nitride layers for improving ohmic characteristics of the layers when an ohmic metal is added to the defined implanted regions; and
said defined implanted regions of said transistor precursor having a temperature of between about 250° and 900° C.
2. A transistor precursor according to claim 1 wherein said growth substrate is selected from a group consisting of silicon carbide and sapphire.
3. A transistor precursor according to claim 1 further comprising a mask on said aluminum gallium nitride layer, said mask having to find openings that in turn define the implanted regions.
4. A transistor precursor according to claim 3 wherein said mask is selected from a group consisting of silicon dioxide, silicon nitride, and combinations of silicon dioxide and silicon nitride.
5. A transistor precursor according to claim 1 wherein said defined implanted regions have a temperature of between about 350° and 800° C.
6. An apparatus formed by a process comprising:
implanting a Group III nitride layer at a defined position with ions to provide an ion-implanted region, the implantation being carried out at a temperature between 250° C. and 900° C.; and
adding a contact over the ion-implanted region to thereby form an ohmic contact.
7. An apparatus according to claim 6 wherein the contact is formed of a metal selected from a group consisting of titanium, aluminum, nickel, and alloys thereof.
8. An apparatus according to claim 6 wherein the contact is formed of a material selected from a group consisting of titanium-tungsten-nitride, titanium-nitride, molybdenum, and molybdenum silicides.
9. An apparatus according to claim 6 wherein the implantation is carried out at a temperature of at least 350° C.
10. An apparatus according to claim 6 wherein the implantation is carried out at a temperature of at least 650° C.
11. An apparatus according to claim 6 wherein the implantation is carried out at a temperature of at least 800° C.
12. An apparatus according to claim 6 wherein the implantation is carried out with an ion beam current between about 30 μA and 130 μA.
13. An apparatus according to claim 6 wherein the implantation is carried out with an ion beam current of about 40 μA.
14. An apparatus according to claim 13 wherein the implantation is carried out at a temperature of at least 350° C.
15. An apparatus according to claim 13 wherein the implantation is carried out at a temperature of at least 650° C.
16. An apparatus according to claim 6 wherein the implantation is carried out with an ion beam current of about 120 μA.
17. An apparatus according to claim 16 wherein the implantation is carried out at a temperature of at least 350° C.
18. An apparatus according to claim 16 wherein the implantation is carried out at a temperature of at least 650° C.
19. An apparatus according to claim 6 wherein the contact is comprised of an alloy of titanium, aluminum, and nickel.
20. An apparatus according to claim 6 wherein implanting the Group III nitride layer at the defined position with ions to provide the ion-implanted region comprises implanting the Group III nitride layer at the defined position with ions through a protective layer placed on top of the Group III nitride layer to reduce the amount of damage to the Group III nitride layer.
21. An apparatus according to claim 20 wherein the protective layer is a silicon nitride protective layer.
22. An apparatus according to claim 6 wherein the process further comprises placing a mask layer on the Group III nitride layer before the step of implanting to prevent implantation at positions other than the defined position.
23. An apparatus according to claim 22 wherein the mask layer is an oxide mask layer.
24. An apparatus according to claim 6 wherein:
the apparatus comprises a gallium nitride layer and the Group III nitride layer is an aluminum gallium nitride layer formed on the gallium nitride layer;
implanting the Group III nitride layer comprises implanting the aluminum gallium nitride layer at the defined position with ions to provide the ion-implanted region such that the ion-implanted region extends through the aluminum gallium nitride layer into the gallium nitride layer; and
adding the contact comprises adding the contact over the ion-implanted region to thereby form the ohmic contact to a 2-DEG formed at an interface of the gallium nitride layer and the aluminum gallium nitride layer.
25. An apparatus formed by a process comprising:
placing a protective layer on a Group III nitride layer;
implanting the Group III nitride layer through the protective layer at a defined position with ions to provide an ion-implanted region, the implantation being carried out with an ion beam current between about 30 μA and 130 μA; and
adding an ohmic contact over the ion-implanted region.
26. An apparatus according to claim 25 wherein the protective layer is a silicon nitride protective layer.
27. An apparatus according to claim 25 wherein the implantation of the Group III nitride layer with ions is carried out at a temperature of between about 250° C. and 900° C.
28. An apparatus according to claim 25 wherein the contact is comprised of an alloy of titanium, aluminum, and nickel.
29. An apparatus according to claim 25 wherein:
the apparatus comprises a gallium nitride layer and the Group III nitride layer is an aluminum gallium nitride layer formed on the gallium nitride layer;
implanting the Group III nitride layer comprises implanting the aluminum gallium nitride layer at the defined position with ions to provide the ion-implanted region such that the ion-implanted region extends through the aluminum gallium nitride layer into the gallium nitride layer; and
adding the contact comprises adding the contact over the ion-implanted region to thereby form the ohmic contact to a 2-DEG formed at an interface of the gallium nitride layer and the aluminum gallium nitride layer.
30. An apparatus comprising:
a Group III nitride layer;
an ion-implanted region in the Group III nitride layer; and
adding a contact over the ion-implanted region to thereby form an ohmic contact;
wherein, after the ion-implanted region has been formed in the Group III nitride layer, at least 25 percent of all visible light having a wavelength in a range of and including 400 nanometers (nm) to 700 nm transmits through the Group III nitride layer.
31. An apparatus according to claim 30 wherein, after the ion-implanted region has been formed in the Group III nitride layer, at least 40 percent of all visible light having a wavelength in a range of and including 450 nm to 700 nm transmits through the Group III nitride layer.
32. An apparatus according to claim 30 wherein, after the ion-implanted region has been formed in the Group III nitride layer, at least 50 percent of all visible light having a wavelength in a range of and including 550 nm to 700 nm transmits through the Group III nitride layer.
33. An apparatus according to claim 30 wherein, after the ion-implanted region has been formed in the Group III nitride layer, at least 56 percent of all visible light having a wavelength in a range of and including 600 nm to 700 nm transmits through the Group III nitride layer.
34. An apparatus according to claim 30 wherein the ion-implanted region is formed by implanting the Group III nitride layer at a defined position with ions, the implantation being carried out at a temperature between 250° C. and 900° C.
35. An apparatus according to claim 30 wherein the contact is formed of a metal selected from a group consisting of titanium, aluminum, nickel, and alloys thereof.
36. An apparatus according to claim 30 wherein the contact is formed of a material selected from a group consisting of titanium-tungsten-nitride, titanium-nitride, molybdenum, and molybdenum silicides.
37. An apparatus according to claim 30 wherein the implantation is carried out at a temperature of at least 350° C.
38. An apparatus according to claim 30 wherein the implantation is carried out at a temperature of at least 650° C.
39. An apparatus according to claim 30 wherein the implantation is carried out at a temperature of at least 800° C.
40. An apparatus according to claim 30 wherein the implantation is carried out with an ion beam current between about 30 μA and 130 μA.
41. An apparatus according to claim 30 wherein the implantation is carried out with an ion beam current of about 40 μA.
42. An apparatus according to claim 41 wherein the implantation is carried out at a temperature of at least 350° C.
43. An apparatus according to claim 41 wherein the implantation is carried out at a temperature of at least 650° C.
44. An apparatus according to claim 30 wherein the implantation is carried out with an ion beam current of about 120 μA.
45. An apparatus according to claim 44 wherein the implantation is carried out at a temperature of at least 350° C.
46. An apparatus according to claim 44 wherein the implantation is carried out at a temperature of at least 650° C.
47. An apparatus according to claim 30 wherein the contact is comprised of an alloy of titanium, aluminum, and nickel.
48. An apparatus according to claim 30 wherein:
the apparatus comprises a gallium nitride layer and the Group III nitride layer is an aluminum gallium nitride layer formed on the gallium nitride layer;
the ion-implanted region extends through the aluminum gallium nitride layer into the gallium nitride layer; and
the contact forms the ohmic contact to a 2-DEG formed at an interface of the gallium nitride layer and the aluminum gallium nitride layer.
US12/983,655 2007-08-29 2011-01-03 High temperature ion implantation of nitride based hemts Abandoned US20110101377A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US12/983,655 US20110101377A1 (en) 2007-08-29 2011-01-03 High temperature ion implantation of nitride based hemts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/846,605 US7875537B2 (en) 2007-08-29 2007-08-29 High temperature ion implantation of nitride based HEMTs
US12/983,655 US20110101377A1 (en) 2007-08-29 2011-01-03 High temperature ion implantation of nitride based hemts

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US11/846,605 Division US7875537B2 (en) 2007-08-29 2007-08-29 High temperature ion implantation of nitride based HEMTs

Publications (1)

Publication Number Publication Date
US20110101377A1 true US20110101377A1 (en) 2011-05-05

Family

ID=39768481

Family Applications (2)

Application Number Title Priority Date Filing Date
US11/846,605 Active 2029-03-21 US7875537B2 (en) 2007-08-29 2007-08-29 High temperature ion implantation of nitride based HEMTs
US12/983,655 Abandoned US20110101377A1 (en) 2007-08-29 2011-01-03 High temperature ion implantation of nitride based hemts

Family Applications Before (1)

Application Number Title Priority Date Filing Date
US11/846,605 Active 2029-03-21 US7875537B2 (en) 2007-08-29 2007-08-29 High temperature ion implantation of nitride based HEMTs

Country Status (6)

Country Link
US (2) US7875537B2 (en)
EP (3) EP2690653B1 (en)
JP (1) JP5579064B2 (en)
KR (1) KR20100050527A (en)
CN (2) CN102254802B (en)
WO (1) WO2009029329A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9202703B2 (en) 2012-11-05 2015-12-01 Cree, Inc. Ni-rich Schottky contact
US9640627B2 (en) 2012-03-07 2017-05-02 Cree, Inc. Schottky contact
EP4181184A3 (en) * 2017-05-15 2023-08-16 Wolfspeed, Inc. Silicon carbide power module

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9218991B2 (en) 2007-06-25 2015-12-22 Infineon Technologies Americas Corp. Ion implantation at high temperature surface equilibrium conditions
US8395132B2 (en) 2007-06-25 2013-03-12 International Rectifier Corporation Ion implanting while growing a III-nitride layer
GB2450934B (en) * 2007-07-13 2009-10-07 Rolls Royce Plc A Component with a damping filler
GB2450935B (en) * 2007-07-13 2009-06-03 Rolls Royce Plc Component with internal damping
US7875537B2 (en) * 2007-08-29 2011-01-25 Cree, Inc. High temperature ion implantation of nitride based HEMTs
US20090072269A1 (en) * 2007-09-17 2009-03-19 Chang Soo Suh Gallium nitride diodes and integrated components
US8519438B2 (en) 2008-04-23 2013-08-27 Transphorm Inc. Enhancement mode III-N HEMTs
GB0808840D0 (en) * 2008-05-15 2008-06-18 Rolls Royce Plc A compound structure
GB2462102B (en) * 2008-07-24 2010-06-16 Rolls Royce Plc An aerofoil sub-assembly, an aerofoil and a method of making an aerofoil
US8289065B2 (en) 2008-09-23 2012-10-16 Transphorm Inc. Inductive load power switching circuits
US7898004B2 (en) 2008-12-10 2011-03-01 Transphorm Inc. Semiconductor heterostructure diodes
GB0901235D0 (en) * 2009-01-27 2009-03-11 Rolls Royce Plc An article with a filler
GB0901318D0 (en) * 2009-01-28 2009-03-11 Rolls Royce Plc A method of joining plates of material to form a structure
US8742459B2 (en) 2009-05-14 2014-06-03 Transphorm Inc. High voltage III-nitride semiconductor devices
US8390000B2 (en) 2009-08-28 2013-03-05 Transphorm Inc. Semiconductor devices with field plates
US8389977B2 (en) 2009-12-10 2013-03-05 Transphorm Inc. Reverse side engineered III-nitride devices
GB201009216D0 (en) 2010-06-02 2010-07-21 Rolls Royce Plc Rotationally balancing a rotating part
GB2485831B (en) 2010-11-26 2012-11-21 Rolls Royce Plc A method of manufacturing a component
US8742460B2 (en) 2010-12-15 2014-06-03 Transphorm Inc. Transistors with isolation regions
US8643062B2 (en) 2011-02-02 2014-02-04 Transphorm Inc. III-N device structures and methods
US8772842B2 (en) 2011-03-04 2014-07-08 Transphorm, Inc. Semiconductor diodes with low reverse bias currents
US8716141B2 (en) 2011-03-04 2014-05-06 Transphorm Inc. Electrode configurations for semiconductor devices
TWI441303B (en) * 2011-06-10 2014-06-11 Univ Nat Chiao Tung Semiconductor device apply to copper plating process
US8901604B2 (en) 2011-09-06 2014-12-02 Transphorm Inc. Semiconductor devices with guard rings
US9257547B2 (en) 2011-09-13 2016-02-09 Transphorm Inc. III-N device structures having a non-insulating substrate
US8598937B2 (en) 2011-10-07 2013-12-03 Transphorm Inc. High power semiconductor electronic components with increased reliability
US9165766B2 (en) 2012-02-03 2015-10-20 Transphorm Inc. Buffer layer structures suited for III-nitride devices with foreign substrates
US8916909B2 (en) * 2012-03-06 2014-12-23 Infineon Technologies Austria Ag Semiconductor device and method for fabricating a semiconductor device
US9093366B2 (en) 2012-04-09 2015-07-28 Transphorm Inc. N-polar III-nitride transistors
JP2013232578A (en) * 2012-05-01 2013-11-14 Advanced Power Device Research Association Schottky barrier diode
EP2662884B1 (en) * 2012-05-09 2015-04-01 Nxp B.V. Group 13 nitride semiconductor device and method of its manufacture
US10522670B2 (en) 2012-06-26 2019-12-31 Nxp Usa, Inc. Semiconductor device with selectively etched surface passivation
US10825924B2 (en) 2012-06-26 2020-11-03 Nxp Usa, Inc. Semiconductor device with selectively etched surface passivation
US10957790B2 (en) 2012-06-26 2021-03-23 Nxp Usa, Inc. Semiconductor device with selectively etched surface passivation
US9184275B2 (en) 2012-06-27 2015-11-10 Transphorm Inc. Semiconductor devices with integrated hole collectors
US9076850B2 (en) 2012-07-30 2015-07-07 Samsung Electronics Co., Ltd. High electron mobility transistor
EP2765596B1 (en) * 2013-02-12 2018-07-11 Infineon Technologies Americas Corp. Ion implantation at high temperature surface equilibrium conditions
CN105164811B (en) 2013-02-15 2018-08-31 创世舫电子有限公司 Electrode of semiconductor devices and forming method thereof
US9087718B2 (en) 2013-03-13 2015-07-21 Transphorm Inc. Enhancement-mode III-nitride devices
US9245993B2 (en) 2013-03-15 2016-01-26 Transphorm Inc. Carbon doping semiconductor devices
US9443938B2 (en) 2013-07-19 2016-09-13 Transphorm Inc. III-nitride transistor including a p-type depleting layer
US9318593B2 (en) 2014-07-21 2016-04-19 Transphorm Inc. Forming enhancement mode III-nitride devices
US9536967B2 (en) 2014-12-16 2017-01-03 Transphorm Inc. Recessed ohmic contacts in a III-N device
US9536966B2 (en) 2014-12-16 2017-01-03 Transphorm Inc. Gate structures for III-N devices
US11322599B2 (en) 2016-01-15 2022-05-03 Transphorm Technology, Inc. Enhancement mode III-nitride devices having an Al1-xSixO gate insulator
TWI762486B (en) 2016-05-31 2022-05-01 美商創世舫科技有限公司 Iii-nitride devices including a graded depleting layer
US11502178B2 (en) 2020-10-27 2022-11-15 Wolfspeed, Inc. Field effect transistor with at least partially recessed field plate
US11749726B2 (en) 2020-10-27 2023-09-05 Wolfspeed, Inc. Field effect transistor with source-connected field plate
US11658234B2 (en) 2020-10-27 2023-05-23 Wolfspeed, Inc. Field effect transistor with enhanced reliability
US11791389B2 (en) 2021-01-08 2023-10-17 Wolfspeed, Inc. Radio frequency transistor amplifiers having widened and/or asymmetric source/drain regions for improved on-resistance performance

Citations (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5866925A (en) * 1997-01-09 1999-02-02 Sandia Corporation Gallium nitride junction field-effect transistor
US20010017370A1 (en) * 1998-06-12 2001-08-30 Sheppard Scott Thomas Nitride based transistors on semi-insulating silicon carbide substrates
US20030020092A1 (en) * 2001-07-24 2003-01-30 Primit Parikh Insulating gate AlGaN/GaN HEMT
US6534801B2 (en) * 2000-12-19 2003-03-18 The Furukawa Electric Co., Ltd. GaN-based high electron mobility transistor
US20030201459A1 (en) * 2001-03-29 2003-10-30 Sheppard Scott Thomas Nitride based transistors on semi-insulating silicon carbide substrates
US20040021152A1 (en) * 2002-08-05 2004-02-05 Chanh Nguyen Ga/A1GaN Heterostructure Field Effect Transistor with dielectric recessed gate
US20040041169A1 (en) * 2002-08-26 2004-03-04 Fan Ren GaN-type enhancement MOSFET using hetero structure
US20040144991A1 (en) * 2003-01-15 2004-07-29 Fujitsu Limited Compound semiconductor device and method for fabricating the same
US20040173816A1 (en) * 2003-03-03 2004-09-09 Saxler Adam William Integrated nitride-based acoustic wave devices and methods of fabricating integrated nitride-based acoustic wave devices
US6849882B2 (en) * 2001-05-11 2005-02-01 Cree Inc. Group-III nitride based high electron mobility transistor (HEMT) with barrier/spacer layer
US20050133818A1 (en) * 2003-12-17 2005-06-23 Johnson Jerry W. Gallium nitride material devices including an electrode-defining layer and methods of forming the same
US20050258451A1 (en) * 2004-05-20 2005-11-24 Saxler Adam W Methods of fabricating nitride-based transistors having regrown ohmic contact regions and nitride-based transistors having regrown ohmic contact regions
US20060006414A1 (en) * 2004-06-30 2006-01-12 Marianne Germain AlGaN/GaN high electron mobility transistor devices
US20060118823A1 (en) * 2004-12-06 2006-06-08 Primit Parikh Field effect transistors (FETs) having multi-watt output power at millimeter-wave frequencies
US20060197109A1 (en) * 2005-03-03 2006-09-07 Saxler Adam W High electron mobility transistor
US20060214188A1 (en) * 2005-03-22 2006-09-28 Eudyna Devices Inc. Semiconductor device having GaN-based semiconductor layer
US20060226442A1 (en) * 2005-04-07 2006-10-12 An-Ping Zhang GaN-based high electron mobility transistor and method for making the same
US20070018210A1 (en) * 2005-07-21 2007-01-25 Cree, Inc. Switch mode power amplifier using MIS-HEMT with field plate extension
US20070018199A1 (en) * 2005-07-20 2007-01-25 Cree, Inc. Nitride-based transistors and fabrication methods with an etch stop layer
US20070018198A1 (en) * 2005-07-20 2007-01-25 Brandes George R High electron mobility electronic device structures comprising native substrates and methods for making the same
US20070138506A1 (en) * 2003-11-17 2007-06-21 Braddock Walter D Nitride metal oxide semiconductor integrated transistor devices
US7236053B2 (en) * 2004-12-31 2007-06-26 Cree, Inc. High efficiency switch-mode power amplifier
US20070158683A1 (en) * 2005-12-13 2007-07-12 Sheppard Scott T Semiconductor devices including implanted regions and protective layers and methods of forming the same
US20070164321A1 (en) * 2006-01-17 2007-07-19 Cree, Inc. Methods of fabricating transistors including supported gate electrodes and related devices
US20070228416A1 (en) * 2005-11-29 2007-10-04 The Hong Kong University Of Science And Technology Monolithic Integration of Enhancement- and Depletion-mode AlGaN/GaN HFETs
US20070269968A1 (en) * 2006-05-16 2007-11-22 Cree, Inc. Semiconductor devices including self aligned refractory contacts and methods of fabricating the same
US20070278518A1 (en) * 2005-11-29 2007-12-06 The Hong Kong University Of Science And Technology Enhancement-Mode III-N Devices, Circuits, and Methods
US20080023727A1 (en) * 2006-07-27 2008-01-31 Oki Electric Industry Co., Ltd. Field effect transistor having its breakdown voltage enhanced
US20080121895A1 (en) * 2006-11-06 2008-05-29 Cree, Inc. Methods of fabricating semiconductor devices including implanted regions for providing low-resistance contact to buried layers and related devices
US20080128753A1 (en) * 2006-11-30 2008-06-05 Cree, Inc. Transistors and method for making ohmic contact to transistors
US20080258150A1 (en) * 2007-03-09 2008-10-23 The Regents Of The University Of California Method to fabricate iii-n field effect transistors using ion implantation with reduced dopant activation and damage recovery temperature
US20090057718A1 (en) * 2007-08-29 2009-03-05 Alexander Suvorov High Temperature Ion Implantation of Nitride Based HEMTS

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3820424B2 (en) * 2001-03-27 2006-09-13 独立行政法人産業技術総合研究所 Activation method of impurity ion implantation layer
US6982204B2 (en) * 2002-07-16 2006-01-03 Cree, Inc. Nitride-based transistors and methods of fabrication thereof using non-etched contact recesses

Patent Citations (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5866925A (en) * 1997-01-09 1999-02-02 Sandia Corporation Gallium nitride junction field-effect transistor
US20010017370A1 (en) * 1998-06-12 2001-08-30 Sheppard Scott Thomas Nitride based transistors on semi-insulating silicon carbide substrates
US6316793B1 (en) * 1998-06-12 2001-11-13 Cree, Inc. Nitride based transistors on semi-insulating silicon carbide substrates
US6486502B1 (en) * 1998-06-12 2002-11-26 Cree, Inc. Nitride based transistors on semi-insulating silicon carbide substrates
US6583454B2 (en) * 1998-06-12 2003-06-24 Cree, Inc. Nitride based transistors on semi-insulating silicon carbide substrates
US6534801B2 (en) * 2000-12-19 2003-03-18 The Furukawa Electric Co., Ltd. GaN-based high electron mobility transistor
US20030201459A1 (en) * 2001-03-29 2003-10-30 Sheppard Scott Thomas Nitride based transistors on semi-insulating silicon carbide substrates
US6849882B2 (en) * 2001-05-11 2005-02-01 Cree Inc. Group-III nitride based high electron mobility transistor (HEMT) with barrier/spacer layer
US20030020092A1 (en) * 2001-07-24 2003-01-30 Primit Parikh Insulating gate AlGaN/GaN HEMT
US20060138456A1 (en) * 2001-07-24 2006-06-29 Cree, Inc. Insulating gate AlGaN/GaN HEMT
US20090315078A1 (en) * 2001-07-24 2009-12-24 Cree, Inc. INSULATING GATE AlGaN/GaN HEMT
US20070205433A1 (en) * 2001-07-24 2007-09-06 Cree, Inc. Insulating gate AlGaN/GaN HEMTs
US7230284B2 (en) * 2001-07-24 2007-06-12 Cree, Inc. Insulating gate AlGaN/GaN HEMT
US20040021152A1 (en) * 2002-08-05 2004-02-05 Chanh Nguyen Ga/A1GaN Heterostructure Field Effect Transistor with dielectric recessed gate
US20040041169A1 (en) * 2002-08-26 2004-03-04 Fan Ren GaN-type enhancement MOSFET using hetero structure
US6914273B2 (en) * 2002-08-26 2005-07-05 University Of Florida Research Foundation, Inc. GaN-type enhancement MOSFET using hetero structure
US20040144991A1 (en) * 2003-01-15 2004-07-29 Fujitsu Limited Compound semiconductor device and method for fabricating the same
US20040173816A1 (en) * 2003-03-03 2004-09-09 Saxler Adam William Integrated nitride-based acoustic wave devices and methods of fabricating integrated nitride-based acoustic wave devices
US7112860B2 (en) * 2003-03-03 2006-09-26 Cree, Inc. Integrated nitride-based acoustic wave devices and methods of fabricating integrated nitride-based acoustic wave devices
US20070138506A1 (en) * 2003-11-17 2007-06-21 Braddock Walter D Nitride metal oxide semiconductor integrated transistor devices
US20050133818A1 (en) * 2003-12-17 2005-06-23 Johnson Jerry W. Gallium nitride material devices including an electrode-defining layer and methods of forming the same
US7071498B2 (en) * 2003-12-17 2006-07-04 Nitronex Corporation Gallium nitride material devices including an electrode-defining layer and methods of forming the same
US20050258451A1 (en) * 2004-05-20 2005-11-24 Saxler Adam W Methods of fabricating nitride-based transistors having regrown ohmic contact regions and nitride-based transistors having regrown ohmic contact regions
US20060006414A1 (en) * 2004-06-30 2006-01-12 Marianne Germain AlGaN/GaN high electron mobility transistor devices
US20060118823A1 (en) * 2004-12-06 2006-06-08 Primit Parikh Field effect transistors (FETs) having multi-watt output power at millimeter-wave frequencies
US7236053B2 (en) * 2004-12-31 2007-06-26 Cree, Inc. High efficiency switch-mode power amplifier
US20070268071A1 (en) * 2004-12-31 2007-11-22 Cree, Inc. High efficiency switch-mode power amplifier
US20060197109A1 (en) * 2005-03-03 2006-09-07 Saxler Adam W High electron mobility transistor
US7253454B2 (en) * 2005-03-03 2007-08-07 Cree, Inc. High electron mobility transistor
US20060214188A1 (en) * 2005-03-22 2006-09-28 Eudyna Devices Inc. Semiconductor device having GaN-based semiconductor layer
US7521707B2 (en) * 2005-03-22 2009-04-21 Eudyna Devices Inc. Semiconductor device having GaN-based semiconductor layer
US20060226442A1 (en) * 2005-04-07 2006-10-12 An-Ping Zhang GaN-based high electron mobility transistor and method for making the same
US20070018199A1 (en) * 2005-07-20 2007-01-25 Cree, Inc. Nitride-based transistors and fabrication methods with an etch stop layer
US20070018198A1 (en) * 2005-07-20 2007-01-25 Brandes George R High electron mobility electronic device structures comprising native substrates and methods for making the same
US20070018210A1 (en) * 2005-07-21 2007-01-25 Cree, Inc. Switch mode power amplifier using MIS-HEMT with field plate extension
US20070228416A1 (en) * 2005-11-29 2007-10-04 The Hong Kong University Of Science And Technology Monolithic Integration of Enhancement- and Depletion-mode AlGaN/GaN HFETs
US20070278518A1 (en) * 2005-11-29 2007-12-06 The Hong Kong University Of Science And Technology Enhancement-Mode III-N Devices, Circuits, and Methods
US20070158683A1 (en) * 2005-12-13 2007-07-12 Sheppard Scott T Semiconductor devices including implanted regions and protective layers and methods of forming the same
US7419892B2 (en) * 2005-12-13 2008-09-02 Cree, Inc. Semiconductor devices including implanted regions and protective layers and methods of forming the same
US20070164321A1 (en) * 2006-01-17 2007-07-19 Cree, Inc. Methods of fabricating transistors including supported gate electrodes and related devices
US7592211B2 (en) * 2006-01-17 2009-09-22 Cree, Inc. Methods of fabricating transistors including supported gate electrodes
US20070269968A1 (en) * 2006-05-16 2007-11-22 Cree, Inc. Semiconductor devices including self aligned refractory contacts and methods of fabricating the same
US20080023727A1 (en) * 2006-07-27 2008-01-31 Oki Electric Industry Co., Ltd. Field effect transistor having its breakdown voltage enhanced
US20080121895A1 (en) * 2006-11-06 2008-05-29 Cree, Inc. Methods of fabricating semiconductor devices including implanted regions for providing low-resistance contact to buried layers and related devices
US20080128753A1 (en) * 2006-11-30 2008-06-05 Cree, Inc. Transistors and method for making ohmic contact to transistors
US20080258150A1 (en) * 2007-03-09 2008-10-23 The Regents Of The University Of California Method to fabricate iii-n field effect transistors using ion implantation with reduced dopant activation and damage recovery temperature
US20090057718A1 (en) * 2007-08-29 2009-03-05 Alexander Suvorov High Temperature Ion Implantation of Nitride Based HEMTS

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9640627B2 (en) 2012-03-07 2017-05-02 Cree, Inc. Schottky contact
US9202703B2 (en) 2012-11-05 2015-12-01 Cree, Inc. Ni-rich Schottky contact
EP4181184A3 (en) * 2017-05-15 2023-08-16 Wolfspeed, Inc. Silicon carbide power module

Also Published As

Publication number Publication date
US7875537B2 (en) 2011-01-25
EP2183768B1 (en) 2013-07-24
KR20100050527A (en) 2010-05-13
EP2261959A2 (en) 2010-12-15
US20090057718A1 (en) 2009-03-05
EP2690653A2 (en) 2014-01-29
WO2009029329A1 (en) 2009-03-05
CN102254802A (en) 2011-11-23
CN101790779B (en) 2012-07-04
CN102254802B (en) 2015-11-25
EP2690653B1 (en) 2017-05-31
CN101790779A (en) 2010-07-28
EP2690653A3 (en) 2014-03-05
EP2183768A1 (en) 2010-05-12
JP2010537447A (en) 2010-12-02
EP2261959B1 (en) 2017-01-04
EP2261959A3 (en) 2011-04-27
JP5579064B2 (en) 2014-08-27

Similar Documents

Publication Publication Date Title
US7875537B2 (en) High temperature ion implantation of nitride based HEMTs
US9711633B2 (en) Methods of forming group III-nitride semiconductor devices including implanting ions directly into source and drain regions and annealing to activate the implanted ions
JP6357037B2 (en) Always-off semiconductor device and manufacturing method thereof
US9040398B2 (en) Method of fabricating seminconductor devices including self aligned refractory contacts
US9318594B2 (en) Semiconductor devices including implanted regions and protective layers
US5866925A (en) Gallium nitride junction field-effect transistor
JP2009507396A (en) Robust transistor using fluorine treatment
KR20140013247A (en) Nitride based semiconductor device and preparing method for the same
TWI663635B (en) Semiconductor material growth of a high resistivity nitride buffer layer using ion implantation
CN115244683A (en) Group III HEMTs and capacitors sharing structural features
US11276765B2 (en) Composite-channel high electron mobility transistor
EP2117039B1 (en) Semiconductor devices including shallow inplanted regions and methods of forming the same
US20240120202A1 (en) Implanted Regions for Semiconductor Structures with Deep Buried Layers

Legal Events

Date Code Title Description
STCB Information on status: application discontinuation

Free format text: ABANDONED -- AFTER EXAMINER'S ANSWER OR BOARD OF APPEALS DECISION