US2647464A - Electrography - Google Patents

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US2647464A
US2647464A US123651A US12365149A US2647464A US 2647464 A US2647464 A US 2647464A US 123651 A US123651 A US 123651A US 12365149 A US12365149 A US 12365149A US 2647464 A US2647464 A US 2647464A
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image
plate
electrographic
dielectric layer
copy
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US123651A
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James P Ebert
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Battelle Development Corp
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Battelle Development Corp
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G15/00Apparatus for electrographic processes using a charge pattern
    • G03G15/22Apparatus for electrographic processes using a charge pattern involving the combination of more than one step according to groups G03G13/02 - G03G13/20
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S101/00Printing
    • Y10S101/37Printing employing electrostatic force

Definitions

  • This invention relates to an electrical method for reproducing printed images and other images and to apparatus for effecting such electrical reproduction.
  • Yet another object of this invention is to provide a new and readily applicable method for preparing master plates for duplication and printing processes.
  • Figure 1 shows several methods of preparing a plate for use in the process of the invention
  • Figure 2 is a cross-section through a plate suitable for use in the present method
  • Figure 3 is a view showing an assembly of the various elements in position for the preliminary steps of the process.
  • Figure 4 illustrates one method of producing a latent electrostatic image of the material to be reproduced on an electrographic plate
  • Figure 5 illustrates a way of developing, or making visible, such latent electrostatic image
  • Figure 6 illustrates the accumulation of powder particles on the image areas
  • Figure 7 illustrates one of the transfer methods for transferring the developed powder image to paper or other transfer material.
  • the present invention relates to a process of image reproduction wherein an electrostatic image of the image to be reproduced is prepared on a plate coated with a dielectric material.
  • a basic element in the present process is a plate upon which the image to be reproduced is first reproduced in the form of an electrostatic image and later caused to take on a physically visible form by developing with a suitable powder.
  • a plate comprises a backing platen of metal or other suitable electrically conductive material and a layer of a dielectric material over the surface of such backing platen.
  • Such plates are hereinafter designated as electrographic plates.
  • Many methods for applying the layer of dielectric material to the metal plate have been de vised and there is nothing critical in the method of application.
  • the dielectric layer is preferably between 0.00025 and 0.0005-inch thick although thicknesses as great as 0.002-inch are operative. Examples of methods which have been successfully employed in the application of the dielectric v materials include:
  • the dielectric material may be deposited upon an electrically conductive plate by vacuum evaporation.
  • One side of a commercially prepared plastic film may be coated by vacuum evaporation with a metallic substance which is a good electrical conductor.
  • An electrostatic charge is applied to the dielectric surface through the original being copied. This may be accomplished by corona discharge from wires or needles, or by induction for example.
  • the electrographio plate is contacted by an electrically charged powder. This results in the production of a visible powder image of the lat ent electrostatic image formed in step 2. In this step the powder should have the same polarity of charge as the charge applied to the dielectric surface in step 2.
  • the transferred image is permanentlyfixed to the second surface. This may conveniently be accomplished by heating; or by chemical'zfixing, or other similar processes.
  • the steps described. above are illustrated. in the v drawings, wherein,
  • Figure l illustrates-"several:ways in-whiclnthe *dielectriclayers maybeapplied to a: backing plate.
  • (a) is shown a:top;view of a rotating device l2 to which is fastened aplate I-3 to: be coatedt-Theplate i3 is fastened to:the;whirling or rotating device I2 by:any-tsuitable; fastening means (not shown)
  • the entire-assembly issupporte'd'by a suitablebench orltable 23, as indicated.
  • FIG. 2 a crossesection-.throughfianelec- --trographic plate isshown to:illustrate that: such plates-consist of twolayers;-first,;a:;dieleotric layer 2
  • i Figure i showsamethod of producingtaneelec- -trostatic-r charge: pattern" on: the. :electrographic plate wherein plate- 40;. with copy. 4
  • plate 41;1P1ate' 4'1 - may be either a conductive or non-conductive material; If 'coninductive it should; be-r'grounded'electrically, if
  • plate 50 which has a latent electrostatic image on its dielectric face is placed in a tray 5
  • developer material 54 is caused to flow back and 5 forth across the dielectric face of plate 50 (by tilting tray 5
  • the delo- 'veloper material 54 has been permitted to flow .-.1par.t;way across the face of plate 50 making visible those portions of the image area 55 contacted zvrby the-developer. 54.
  • a transfer material such as paper sheet Share passed: under-.coronai discharge wires 431-:43 as 35 in the-chargingeten. .Note, however; that the-polarity of .the corona .wires; 43%43 is required to-be opposite in .thewtransfer step from what itrwas in the. chargingsstep. i .-.Thus,-.: as illustrated: where the corona discharge wires 43-43 are positive 40 during. the :sensitizing process; they must beineg- .-.ative during .the transfer... :Similarly, if the-corotjha zwires 43%43. are negative. in .the' charging or sensitizing step, they. must betpositive to.;efl'ect *;transfer.
  • paper sheet Share passed: under-.coronai discharge wires 431-:43 as 35 in the-chargingeten. .Note, however; that the-polarity of .the corona
  • .cernedrwith processeswhereina number of .duplications or copies offlthe originalaredesired.
  • dielectric coating .materialsand a-Jist of these would include the following: chlorinated rubber, Amberol F-71,
  • the original to be copied must comprise an image-supporting material which is neither a good electrical insulator nor a good electrical conductor, and an image which has either a somewhat higher or a somewhat lower electrical resistance than the image-supporting material.
  • the image-supporting material and the actual image material must have at least slight differences in electrical resistance properties, if optimum performance of the method is to be obtained.
  • Other factors probably contribute to the effect; for example, it appears that a thin layer of dielectric material of high resistivity on an electrically conductive backing produces superior results.
  • the powder image is developed on the electrographic plate it may be treated in any one of several ways depending upon the ultimate use to which it is to be put. For example, as previously pointed out, in one applicaiton the image is fused to the electrographic plate. Other applications require that the image be transferred to a second surface and this is conveniently done by placing the transfer material over the image and spraying said transfer material with electricity of polarity opposite to the polarity of the electricity on the powder. Other transfer methods may be used, of course. For example, various chemical transfer methods or methods involving hygroscopic action are available.
  • Example An electrographic plate was prepared by the "whirling technique previously described. In this manner a coating of Staybelite Ester #10 (a glycerine esterified rosin manufactured by the Hercules Powder Company, Wilmington, Delaware) was applied to an aluminum sheet. The solvent used was trichlorethylene and the whirling process required 5 minutes of whirling at 40 R. P. M. The aluminum surface had previously been cleaned by swabbing with acetone and cotton followed by a rinse with acetone.
  • Staybelite Ester #10 a glycerine esterified rosin manufactured by the Hercules Powder Company, Wilmington, Delaware
  • the coated plate was charged negatively by a corona discharge device operating at 7000 volts (peak) half-wave rectified A.-C.
  • the charging wires were spaced -inch from the plate, and the plate was passed once under the discharge device at a speed of 1% inches per second. It is understood, of course, that the image to be reproduced was in contact with the dielectric layer of the plate during the charging operation.
  • the electrostatic image produced by the abovedescribed charging process was developed using a developer mixture wherein the powder component consisted of 20 parts Amberol F-71 (The Resinous Products & Chemical Company, Philadelphia, Pennsylvania) and 1 part Raven Bead Carbon Black (Benney 8: Smith Company, New York, N. Y.), integrally bonded together.
  • the carrier component consisted of soybean protein.
  • the developed image was transferred from the electrographic plate to a transfer paper by the electrical method previously described and illustrated in Figure 7, employing positive corona discharge at 7000 volts (peak) rectified A. C.
  • the transferred image was fixed and made permanent by heating on a hot-plate for a few seconds.
  • the plate was cleaned and readied for re-use by wiping with a damp cloth.
  • One of the striking features of the present in vention is that it permits the reproduction of copy printed or drawn on both sides of apaper by an electrical contact procedure without employing or involving any light-sensitive elements. To do this it is necessary only to follow the steps already defined and to make certain that the side bearing the image to be reproduced is placed in contact with the dielectric layer while applying the electrostatic charge. When the electrostatic image so formed is developed it will be found that the desired image has been reproduced without trace of the image on the other side of the original paper from which the copy was made.
  • the particular powders and carriers used in the present method are not criticalto its operation, the only requirement being that the powder be charged with the same polarity as the electrographic plate;
  • the image developing powder may be, and often is, of the same-materialaszthe dielectric layer on the electrographic plate.
  • the developer powder consists of two or more components integrally bonded together.
  • the electrographic plate-copy assembly with a metal plate and: connecting the metal plate to a. voltage source; andother methods of producing an electric field; in the vicinity of the plate-copy assembly.
  • escape paths should preferably be provided for'the electrical charges which arise on these areas during the. charging step. Such escape paths are sometimes inherent in the dielectric layer of the electrographic plate in the form of impurities or imperfections.
  • notinherent in the plate they may be provided either by treatment of the electrographic plate orliy treatment.
  • the-original copy For example, small holes may be made in the dielectric layer of the plate, or'the image areasof the original copy may be connected together with an electrical conducting material.
  • the required polarity either the charged areas or the non-charged'areas can be developed, thus producing a positive orv negative copy as desired, and without regardto whether the original wasa positive or a negative.
  • An electric method of reproducing copy comprisingthe steps of placing the copy to be re.- produced in contact with the dielectric layer of an electrographic plate comprising a conductive backing plate'with a dielectric coating layer, subjecting such assembly to an electrostatic discharge, removing the'original copy from the electrograp-hic plate, contacting the plate with an.
  • An electric method of reproducing copy comprising the steps of placing the copy to be reproduced so that the image contacts the dielectric layer of an electrographic platecomprising a conductivebacking plate with a dielectric coating layer, subjecting such assembly to an.elec-- trostatic discharge, removing the original copy from the electrographic plate, contacting said plate with a powder electrically charged with the polarity as the polarity of the discharge, transferring the powder image so. formed to a secend surface, fixing the transferred image to said second surface, and cleaning and-discharging the electrographic plate.
  • An electric method of reproducing copy comprising the steps of preparing an electrographic plate consisting of a dielectric-layer on a conductive backing plate, placing the copy to be reproduced so that the image contacts said dielectric layer, subjecting such assembly to an electrostatic discharge, removing the original copy from the electrographic plate, flowing a. powder electrically charged with the same polarity as the polarity of the electrostatic discharge across said plate, transferring the powder image so formed to a second surface, and fixing the transferred image to said second surface.
  • An electric method of reproducing copy comprising the steps of placing the copy to be reproduced so that the image contacts the dielectric layer of an electrographic plate comprising a conductive backing plate with a dielectric coating layer; subjecting such assembly to an electro static; discharge, removing the original copy from the electrographic plate, contacting said plate with a powder electrically charged with the same.
  • polarity as the polarity of the electrostatic discharge, electrostatically transferring the powder image so formed to a'second surface, and fixing the transferred image to said second surface.
  • An electric method of reproducing copy comprising the steps of preparing an electrographic plate consisting of a dielectric layer on a conductive. backing plate, placing the copy to be reproduced so that the image contacts said dielectric layer, subjecting such assembly to corona discharge, removing the original copy from the electrographic plate, contacting said plate with a powder electrically charged with the same polarity as the corona discharge, electrostatically transferring the powder image so formed to asecond surface, and fixing the transferred image by heat to said second surface.
  • An electric method of'reproducing copy com prising the steps of preparing an electrographic plate consisting of a dielectric layer on a conductive backing plate, placing the copy to be reproduced so that the image contacts said dielectric layer, subjecting such assembly to an electrostatic discharge, removing the original copy from the electrographic plate, flowing a powder electrically charged with the same polarity as the polarity of the electrostatic discharge across said plate, transferring the powder image so formed to a second surface, fixing the transferred image to said second surface, and cleaning and dis charging the electrographic plate with a damp cloth.
  • An electric method of reproducing copy comprising the steps of placing a copy comprising an image-supporting material and an image material of different electrical conductivity properties in contact with the dielectric layer of an ,electrographic plate consisting of a dielectric coating layer on a conduitive backin plate, sub- J'ecting such assembly to an. electrostatic discharge, removing the copy from the electrographic plate, contacting said plate with a powder electrically charged with the same polarity as the polarity of the electrostatic discharge, transferring the powder image so formed to a second surface, and fixing the transferred image to said second surface.
  • An electric method of reproducing copy comprising the steps of preparing an electrographic plate consisting of a dielectric layer on a conductive backing p1ate, placing the copy to be reproduced so that the-image contacts said dielectric layer, subjecting such assembly to an electrostatic discharge, removing the original copy from the electrographic plate, contacting said plate with a powder electrically charged with the same polarity as the polarity of the electrostatic discharge, and fixing the image so formed to the electrographic plate.
  • An electric method of reproducing engineering drawings comprising the steps of placing the drawing to be reproduced so that the drawnimage'contacts the dielectric layer of an electrographic plate consisting of a dielectric coating layer on-a conductive backing plate, subjecting such assembly to an electrostatic discharge, removing the drawing from the electrographic plate, flowing a powder electrically charged with the same polarity as the polarity of the electrostatic discharge across said plate, transferring the powder image thus formed to a second surface, and fixing the transferred image to said second surface.
  • An electric method of reproducing either side of copy printed on both sides comprising the steps of placing the side of the copy desired to be reproduced in contact with the dielectric layer of an electrographic plate consisting of a dielectric coating layer on a conductive backing plate, subjecting such assembly to an electrostatic discharge, removing the copy from the electrographic plate, contacting said plate with a powder electrically charged with the same polarity as the polarity of the electrostatic discharge, transferring the powder image thus formed to a second surface, and fixing said transferred image to said second surface.
  • An electric method of reproducing copy comprising the steps of preparing an electrographic plate consisting of a dielectric layer 0.00025 to 0.0005-inch thick on a conductive backing plate, placing the copy to be reproduced so that the image contacts said dielectric layer, subjecting such assembly to an electrostatic discharge, removing the original copy from the electrographic plate, flowing a powder electrically charged with the same polarity as the polarity of the electrostatic discharge across said plate, transferring the powder image so formed to a second surface, and fixing the transferred image to said second surface.
  • An electric method of reproducing copy comprising the steps of preparing an electrographic plate consisting of a dielectric layer less than 0.002-inch thick on a conductive backing plate, placing the copy to be reproduced so that the image contacts said dielectric layer, subjecting such assembly to an electrostatic discharge, removing the original copy from the electrographic plate, flowing a powder electrically charged with the same polarity as the polarity of the electrostatic discharge across said plate,
  • An electrical method of reproducing an image formed upon a material having a different electrical resistance from said image comprising the steps of bringing the image bearing material into contiguous relation with the dielectric layer of an electrographic plate comprising a dielectric coating layer on a conductive backing plate, and subjecting said contactingimage bearing material and dielectric layer to an electrical discharge, thereby to form an electrostatic image of said design on said dielectric layer.
  • An electrical method of reproducing an image formed upon one side of sheet material having a different electrical resistance from said image comprising the steps of bringing the image bearing side of said materialinto face to face contact with the dielectric layer of an electro graphic plate comprising a dielectric coating layer on a conductive backing plate, and imposing an electric charge upon said dielectric face through said sheet material, thereby to form an electrostatic image upon the dielectric layer of rial having a difierent electrical resistance from said image and having a second image formed upon a second parallel surface of said material on the opposite side of said material from said first surface, comprising the steps of bringing the first surface of said image bearing material into contiguous relation with the dielectric layer of electrographic plate comprising a dielectric coating layer on a conductive backing plate, and subjecting said contacting image bearing material and dielectric layer to an electrical discharge to form an electrostatic image of the image on the first surface on said dielectric material.
  • An electrical method of reproducing an image formed upon a material having a diiTerent electrical resistance from said image comprising the steps of bringing the image bearing material into contiguous relation with a dielectric layer adhered to an electrically conductive plate, subjecting said contacting dielectric layer and image bearing material to an electrical discharge to form an electrostatic image of said image on said dielectric layer, removing the image bearing material from said dielectric layer, and bringing said dielectric layer into contact with a finely divided electrostatically attractable material thereby to make visible said electrostatic image.
  • An electrical method of copying an image formed upon a surface having a different electril l cal resistance from said image upon a dielectric layer-adhering to an electrically conductive plate comprising the steps of bringing the image bearing surface into contact with said dielectric material, subjecting said contacting image bearing I surface and dielectric layer to an electrical discharge to form an electrostatic image of said image on said dielectric layer, removing the image bearing surface from said dielectric layer,
  • An electrical method of copying an image formed upon a surface having a different electrical resistance from said image comprising the steps of bringing the image bearing surface into contact with the dielectric layer'of an electrographic plate comprising a dielectric coating layer on a-conductive backing plate, subjecting said contacting image bearing surface-and dielectric layer'to an electrical discharge to form an electrostatic image of said image on said dielectric'layer, removing the image bearing surface from said dielectric layer, bringing said-dielectric'layer into contact'with-a finely divided elec- -trostaticallyattractable material thereby to form I a transferable image on said layer corresponding to the image to be copied, and transferring said image on to a secondsurface.
  • An electrical method-of copying an image formed upon asurface having different electrical resistance fromsaid image comprising the steps of bringing theimage bearing surface into contact with the "dielectric layer of an electrographic plate "comprising a "dielectric coating layer-on a conductive backing plate, subjecting said contacting image bearing surface and dielectric layer to an electrical discharge to form an electrostatic image of said image on said dielectric layer, removing the image bearing surface from said dielectric layer, bringing'thesai'd dielectric layer into contact-with Ranely divided 'electrostatically attractable material thereby to form a transferable image on said layer corresponding to the'image to b'e copied, transferring "layer 'on a conductive backing plate, subjecting said contacting image bearing surface and dielectric layer to an electrical discharge to form an electrostatic image of said image on said dielectric layer, removing the image bearingsur-face from said dielectric layer, bringing said dielectric layer into contact with a :finely divided electrostatically attractable material thereby to form
  • steps comprising exposing the plate to an electrostatic discharge through the copy while the copy is in contact with the plate, and removing said .copyfrom said plate.

Description

Au 4, 1953 J. P. EBERT 2,647,464
ELECTROGRAPHY Filed Oct. 26, 1949 3 Sheets-Sheet 1 FIGURE FIGURE 2 IN VEN TOR. Jo mes P. Ebert RM W M AGENTS J. P. EBERT ELECTROGRAPHY Aug. 4, 1953 3 Sheets-Sheet 2 Filed Oct. 26, 1949 FIGURE 4 FIGURE 5 INVENTOR. James P. Ebert AGENTS.
Aug. 4, 1953 J. P. EBERT 2,647,464
ELECTROGRAPHY Filed Oct. 26, 1949 3 Sheets-Sheet 3 FIGURE 7 FIGURE 6 IN V EN TOR. Jo mes P. Ebert BY v A a AGENTS.
Patented Aug. 4, 1953 ELECTROGRAPHY James P. Ebert, Columbus, Ohio, assignor, by mesne assignments, to Battelle Development Corporation, Columbus, Ohio, a corporation of Delaware Application October 26, 1949, Serial No. 123,651
21 Claims. (Cl. 101-426) This invention relates to an electrical method for reproducing printed images and other images and to apparatus for effecting such electrical reproduction.
Various methods for reproducing images printed on paper or otherwise superimposed on various materials have recently been proposed and developed. For example, U. S. Patent No. 2,297,691 to Chester F. Carlson describes an electrophotographic method for obtaining images on conductive plates having a photosensitive or photoconductive layer of material applied thereto.
It is an important object of this invention to provide means and methods for reproducing images without requiring the use of photosensitive layers of materials, whereby the step of light exposure may be eliminated in image reproduction.
It is another object of this invention to provide means and methods for reproducing either side of material having images on both sides by a simple contact procedure.
Yet another object of this invention is to provide a new and readily applicable method for preparing master plates for duplication and printing processes.
Other objects and advantages of this invention will be apparent in view of the following description thereof, considered in the light of the attached drawings wherein,
Figure 1 shows several methods of preparing a plate for use in the process of the invention,
Figure 2 is a cross-section through a plate suitable for use in the present method,
Figure 3 is a view showing an assembly of the various elements in position for the preliminary steps of the process, and
Figure 4 illustrates one method of producing a latent electrostatic image of the material to be reproduced on an electrographic plate,
Figure 5 illustrates a way of developing, or making visible, such latent electrostatic image,
Figure 6 illustrates the accumulation of powder particles on the image areas, and
Figure 7 illustrates one of the transfer methods for transferring the developed powder image to paper or other transfer material.
Essentially the present invention relates to a process of image reproduction wherein an electrostatic image of the image to be reproduced is prepared on a plate coated with a dielectric material.
A basic element in the present process is a plate upon which the image to be reproduced is first reproduced in the form of an electrostatic image and later caused to take on a physically visible form by developing with a suitable powder. Such a plate comprises a backing platen of metal or other suitable electrically conductive material and a layer of a dielectric material over the surface of such backing platen. Such plates are hereinafter designated as electrographic plates. Many methods for applying the layer of dielectric material to the metal plate have been de vised and there is nothing critical in the method of application. The dielectric layer is preferably between 0.00025 and 0.0005-inch thick although thicknesses as great as 0.002-inch are operative. Examples of methods which have been successfully employed in the application of the dielectric v materials include:
trically conducting plate.
(3) The dielectric material may be deposited upon an electrically conductive plate by vacuum evaporation.
(4) One side of a commercially prepared plastic film may be coated by vacuum evaporation with a metallic substance which is a good electrical conductor.
(5) Other miscellaneous methods such as dipping the plate in a solution of the dielectric material or flowing the solution over the plate and removing the excess by scraping with a metal or wooden blade, etc, may also'be used in the preparation of electrographic plates.
Once the 'electrographic plate has been prepared as above described it is ready for repeated use in the process as hereinafter set forth. Briefly the steps of this process may be stated as follows:
'1. The original to be copied is placed so that the image to be reproduced is in contact with the dielectric layer of the electrographic plate. (See Figure 3.)
2. An electrostatic charge is applied to the dielectric surface through the original being copied. This may be accomplished by corona discharge from wires or needles, or by induction for example.
3. The original which is being copied is stripped from the plate.
4. The electrographio plate is contacted by an electrically charged powder. This results in the production of a visible powder image of the lat ent electrostatic image formed in step 2. In this step the powder should have the same polarity of charge as the charge applied to the dielectric surface in step 2.
5. The developed powder image istransferred to a second surface by suitable electrical, me-
chanical, or chemical process.
6. The transferred image is permanentlyfixed to the second surface. This may conveniently be accomplished by heating; or by chemical'zfixing, or other similar processes.
'7. The electrographic plate is=-cleaned* of-any-- remaining powder particles and is discharged of any electrostatic chargesr. remaining: rthereon. This is readily accomplished by scrubbing the plate surface with a damp rag and permitting the plate to dry, for example. The steps described. above are illustrated. in the v drawings, wherein,
Figure l illustrates-"several:ways in-whiclnthe *dielectriclayers maybeapplied to a: backing plate. In (a) is shown a:top;view of a rotating device l2 to which is fastened aplate I-3 to: be coatedt-Theplate i3 is fastened to:the;whirling or rotating device I2 by:any-tsuitable; fastening means (not shown) l A dielectric-material which -has-been dissolved in .asolvent is represented: at I5." It will=be seen :thatzuponrotating l2; the dielectricm-ateriat I5- will be caused to flow and -cover the entire area of. plate [3; evenly;andtuni- -formly. In (1)) it isillustrated-how aplate l3 can-begiven a coating of.dielectric material by spraying thedis'solved dielectric l5 from a spray device l6, shown schematically.':.ln '(C) a vacuum ---evaporatio'n technique is illustrated." Plate 13 is suspended by wires [4- 441 within a: vacuum chamber l-l wherein -a:dielectric material-held in a container is vaporized;bythe -.applicationi of --heat- :supp1ied;-for-:example; -by a;-rresistance heater coil *device [9 energized.= zthrough= rleads 22- -22. The entire-assembly issupporte'd'by a suitablebench orltable 23, as indicated.
In Figure 2 a crossesection-.throughfianelec- --trographic plate isshown to:illustrate that: such plates-consist of twolayers;-first,;a:;dieleotric layer 2|, and, second, a backing layer of metal or mother :conductive material.
1* Figure 3 1 illustrates the iinitialstep in the process, wherein the original 'copyj32 tobe'reproduced is placed with the material to be-icopiedinicon- -.--tact= with the-.-dielectric layer 3.1 ofi an electrowgraphic plate; 33cconsisting of. dielectric 3l;-;and wmetal backing; 39.
iFigure i showsamethod of producingtaneelec- -trostatic-r charge: pattern" on: the. :electrographic plate wherein plate- 40;. with copy. 4| bOzbBTBIJI'O- -.-duced-.pr.operly placed thereonras shown in Fi ure 3, is passedvundencorona:dischargei'wires i- 43:.43- .energizedby highvoltagesource 44:; The wcorona. wires 4Si'43:.-are :strung between metal bars 4545 supported by posts 4646 of wood,
- Trplastic or other non-conductive material, which,
" in turnymayrestupon or befastened to and sup- 'ported by. plate 41;1P1ate' 4'1 -may be either a conductive or non-conductive material; If 'coninductive it should; be-r'grounded'electrically, if
- non-conductive, it will-:be necessary to-provide a.
-:,-;:ground .connectionforplate 49, as illustrated,
figure 5illustratesoneway of carrying. out the step of developing the latent electrostaticiimage produced,onnanzelecuographic;plate by. the operation shown in Figure 4. =;;Ani:elect1'ographic;
plate 50 which has a latent electrostatic image on its dielectric face is placed in a tray 5|, provided with stops 52-52 to position plate 50. A
developer material 54 is caused to flow back and 5 forth across the dielectric face of plate 50 (by tilting tray 5| first one Way and then the other) :inwhereupon theeelectrostatic image is made visible by reason of the adherence of the developer material 54 thereto. In the drawing the delo- 'veloper material 54 has been permitted to flow .-.1par.t;way across the face of plate 50 making visible those portions of the image area 55 contacted zvrby the-developer. 54.
Fig'ure 6 illustrates the manner in which the l5-developer-- particles 54 accumulate on the image areas 55 of the plate 50 during the developing jij process; This figure shows a section through the apparatus of Figure 5 along the line 66. As --indicated in Figure 5, the particles 54 have not 20 yet been cascaded entirely across the plate 50, and: most of theseparticles are still in the .upper -corner oftray 5l.l :However', itisialready: ap- -=-parent thatthe particles 54 arebuilding. up; in
the image area 55, while in the neighboring :nonzs' image areas, as-156, there is no accumulation of particles.
nc-transfer method for'transferringra developed image from an electrographic plate. to a transfer :material is: illustrated in Figure 7. .Itzmwill 30-be-.-noted that the same equipment-shown inFig- :ure 4 may be used for the .transf.er.s tep,;.Intransferring, :plate. 6!). bearing; the: powder. .image:and
a transfer material, such as paper sheet Share passed: under-.coronai discharge wires 431-:43 as 35 in the-chargingeten. .Note, however; that the-polarity of .the corona .wires; 43%43 is required to-be opposite in .thewtransfer step from what itrwas in the. chargingsstep. i .-.Thus,-.: as illustrated: where the corona discharge wires 43-43 are positive 40 during. the :sensitizing process; they must beineg- .-.ative during .the transfer... :Similarly, if the-corotjha zwires 43%43. are negative. in .the' charging or sensitizing step, they. must betpositive to.;efl'ect *;transfer.
1 It willbezunderstood that for 'certain; applica- .ztions ofithe'present process thedevelopedimage may be fused to the electrographic plate instead ofaxbeing transferredto a secondsurface. as de- -'::scribed instep 5... Suchrapplications are:.con-
.cernedrwith' processeswhereina number of .duplications or copies offlthe originalaredesired. The c :electrographic plateziwith theimage. fused theretormayiberaiscd in thezmanner of a master-plate in suchprocesses.
55 The methodabove. descrihedihas been-employed .:.in.;ma-king 'copiesof'manykinds of original subjeots including thograph oicopyclndia ink drawings, pencil drawings, typewritten copy; mimeograph opy, endamany types. of:printedcopy.
Theseoriginals'may: be-thought of as stencils,- or
better electric-stencils?in:the present process. 3-, As a-matter of fact, astencil made-by cutting a pattern to: be --printed into an electrically: in- .sulatingor. electrically conducting material will 55 serve as an original for the process.
There are many satisfactory dielectric coating .materialsand a-Jist of these would include the following: chlorinated rubber, Amberol F-71,
.Staybelite- Ester a? 10, polystyrene,- polyethylene,
Vinyl VU 1900,.Pliof1lm, ethyl cellulose,various combinations of .Parlonand-Rezyl, certain resin ItblEhdS made up of 7 various combinations ofzthe above-named resins, anthracene, and various 1 Ether; materials which possess-dielectric proper- ;..ies.
While the exact mechanism by which the pres ent invention operates is not known or established, the following explanation is now generally accepted and is believed to possess considerable merit. The theory supposes that to insure optimum operation of the invention both the original to be copied and the electrographic plate to be used should meet certain requirements and specifications. Broadly it appears that the original to be copied must comprise an image-supporting material which is neither a good electrical insulator nor a good electrical conductor, and an image which has either a somewhat higher or a somewhat lower electrical resistance than the image-supporting material. In other words, it appears that the image-supporting material and the actual image material must have at least slight differences in electrical resistance properties, if optimum performance of the method is to be obtained. Other factors probably contribute to the effect; for example, it appears that a thin layer of dielectric material of high resistivity on an electrically conductive backing produces superior results.
It is believed that when an original of either of the types mentioned above is placed upon an electrographic plate of the type described heretofore and subjected to an electrical discharge as previously stipulated, those areas of the electrographic plate directly below the background portions of the original become more highly charged than those areas directly below the image portions. Consequently, an electrostatic image of the original is formed on the electrographic plate in the form of an electrostatic pattern of varying charge intensity. This electrostatic image is made visibile by applying an electrically charged powdered material to the plate. This powder should be electrically charged with electricity of the same polarity as the electricity applied by the electrostatic discharge operation and is, therefore, repelled from areas of high charge intensity, and is deposited upon the areas of low charge intensity, which are the image areas. Experience has shown that this is always the case no matter whether the original copy consisted of a conductive image on an insulating background or an insulating image on a conductive background. Once the powder image is developed on the electrographic plate it may be treated in any one of several ways depending upon the ultimate use to which it is to be put. For example, as previously pointed out, in one applicaiton the image is fused to the electrographic plate. Other applications require that the image be transferred to a second surface and this is conveniently done by placing the transfer material over the image and spraying said transfer material with electricity of polarity opposite to the polarity of the electricity on the powder. Other transfer methods may be used, of course. For example, various chemical transfer methods or methods involving hygroscopic action are available.
Whatever may be the exact mechanism by which the present method effects reproduction of images, it is certain that the adoption of the steps described above will result in such reproduction in a rapid and satisfactory manner. The following example shows the specific operations carried out in preparing reproductions of either (1) images more conductive than the supporting medium or (2) images less conductive than the supporting medium. Of course, it will be understood that this example has been selected 6 for illustrative purposes only and is not intended to be considered restrictive in any way.
Example An electrographic plate was prepared by the "whirling technique previously described. In this manner a coating of Staybelite Ester #10 (a glycerine esterified rosin manufactured by the Hercules Powder Company, Wilmington, Delaware) was applied to an aluminum sheet. The solvent used was trichlorethylene and the whirling process required 5 minutes of whirling at 40 R. P. M. The aluminum surface had previously been cleaned by swabbing with acetone and cotton followed by a rinse with acetone.
The coated plate was charged negatively by a corona discharge device operating at 7000 volts (peak) half-wave rectified A.-C. The charging wires were spaced -inch from the plate, and the plate was passed once under the discharge device at a speed of 1% inches per second. It is understood, of course, that the image to be reproduced was in contact with the dielectric layer of the plate during the charging operation.
The electrostatic image produced by the abovedescribed charging process was developed using a developer mixture wherein the powder component consisted of 20 parts Amberol F-71 (The Resinous Products & Chemical Company, Philadelphia, Pennsylvania) and 1 part Raven Bead Carbon Black (Benney 8: Smith Company, New York, N. Y.), integrally bonded together. The carrier component consisted of soybean protein.
The developed image was transferred from the electrographic plate to a transfer paper by the electrical method previously described and illustrated in Figure 7, employing positive corona discharge at 7000 volts (peak) rectified A. C. The transferred image was fixed and made permanent by heating on a hot-plate for a few seconds. The plate was cleaned and readied for re-use by wiping with a damp cloth.
The above-described procedure was followed in detail in reproducing both the conductive-image and the insulating-image type original. It is also possible to use positive electrostatic discharge in sensitizing the plate, provided an appropriate developer combination is selected.
One of the striking features of the present in vention is that it permits the reproduction of copy printed or drawn on both sides of apaper by an electrical contact procedure without employing or involving any light-sensitive elements. To do this it is necessary only to follow the steps already defined and to make certain that the side bearing the image to be reproduced is placed in contact with the dielectric layer while applying the electrostatic charge. When the electrostatic image so formed is developed it will be found that the desired image has been reproduced without trace of the image on the other side of the original paper from which the copy was made.
In the step of developing the electrostatic image it has been found that various resinous powders are very satisfactory. These powders should be caused to assume an electric charge of the same polarity as the polarity of the charge on the electrographic plates. This may be done by means of devices which spray electric charges or may be effected by triboelectric action in a mixture of the developer powder and a carrier material, the particular materials chosen being determined and selected in accordance with a triboelectric series, wherein it may be ascertained that the developer ace-7,464.-
component will assume the proper' polarity"- tact with: any material belowit' in the series. A'
primary function of the: carrier material is to insure that the developer powder'assumes the proper electrostatic charge polarity (by contact withthe carrier). Additional data as to the properties and specifications'of developerrmaterials-and carrier'particles" are included in 00- pendi-ng"applicationsaserial'No. 24,674, filed May 1, 1948, by L. E. Walkup andE. N. Wise, and. Serial No. 55,645,.filedz0ctober 20, 1948., by L. E. Walkup, now PatentNo. 2,618,551. The particular powders and carriers used in the present method are not criticalto its operation, the only requirement being that the powder be charged with the same polarity as the electrographic plate; In this connectionit should be noted that the image developing powder. may be, and often is, of the same-materialaszthe dielectric layer on the electrographic plate. Also in many cases the developer powder consists of two or more components integrally bonded together.
The particular apparatus or technique employed in forming theel'ectrostatic image on electrographic plates' is' not: critical and many variations in: design and application are possible. Methods which can and have been used include producingacorona; discharge from wires or needles and passing the electrographic plate through the discharge area;v induction, as by covr1;
ering: the electrographic plate-copy assembly with a metal plate: and: connecting the metal plate to a. voltage source; andother methods of producing an electric field; in the vicinity of the plate-copy assembly.
In the electrographic. reproduction; of images which are made up of material which is more conductive: than the image-supporting material, it has been found that escape paths should preferably be provided for'the electrical charges which arise on these areas during the. charging step. Such escape paths are sometimes inherent in the dielectric layer of the electrographic plate in the form of impurities or imperfections.
When notinherent in the plate they may be provided either by treatment of the electrographic plate orliy treatment. of the-original copy- For example, small holes may be made in the dielectric layer of the plate, or'the image areasof the original copy may be connected together with an electrical conducting material.
It will be appreciated theta new and useful method for reproducing copy has been described. Throughout the specification and claims the word; copy is used to describe material to be reproduced. It will be readily understood that the term, so used, is broad enough to include originals to be copied as well as actual copy material' to be. recopied. It is again pointed out for purposes of emphasis that no light-sensitive elements are required and no light sensitizing steps are performed. The operation is based entirely upon electrical principles as has already been pointed out and explained. It will be apparent that the present method provides for the production of either a positive or negative of the copy being reproduced. This is so. since the operation of the novel steps is to produce charged areas corresponding to the non-image areas of the original and areas having little'or nocharge ISU which correspond tetheimageareas ofthe: original; By selecting a developer carrying a charge of.
the required polarity either the charged areas or the non-charged'areas can be developed, thus producinga positive orv negative copy as desired, and without regardto whether the original wasa positive or a negative.
What is claimed is:
1. An electric method of reproducing copy, comprisingthe steps of placing the copy to be re.- produced in contact with the dielectric layer of an electrographic plate comprising a conductive backing plate'with a dielectric coating layer, subjecting such assembly to an electrostatic discharge, removing the'original copy from the electrograp-hic plate, contacting the plate with an.
electrically charged powder, transferring the powder image-so formed to a second surface, and fixing the transferred image to said second surface.
2. An electric method of reproducing copy, comprising the steps of placing the copy to be reproduced so that the image contacts the dielectric layer of an electrographic platecomprising a conductivebacking plate with a dielectric coating layer, subjecting such assembly to an.elec-- trostatic discharge, removing the original copy from the electrographic plate, contacting said plate with a powder electrically charged with the polarity as the polarity of the discharge, transferring the powder image so. formed to a secend surface, fixing the transferred image to said second surface, and cleaning and-discharging the electrographic plate.
An electric method of reproducing copy, comprising the steps of preparing an electrographic plate consisting of a dielectric-layer on a conductive backing plate, placing the copy to be reproduced so that the image contacts said dielectric layer, subjecting such assembly to an electrostatic discharge, removing the original copy from the electrographic plate, flowing a. powder electrically charged with the same polarity as the polarity of the electrostatic discharge across said plate, transferring the powder image so formed to a second surface, and fixing the transferred image to said second surface.
4. An electric method of reproducing copy, comprising the steps of placing the copy to be reproduced so that the image contacts the dielectric layer of an electrographic plate comprising a conductive backing plate with a dielectric coating layer; subjecting such assembly to an electro static; discharge, removing the original copy from the electrographic plate, contacting said plate with a powder electrically charged with the same. polarity as the polarity of the electrostatic discharge, electrostatically transferring the powder image so formed to a'second surface, and fixing the transferred image to said second surface.
5. An electric method of reproducing copy, comprising the steps of preparing an electrographic plate consisting of a dielectric layer on a conductive. backing plate, placing the copy to be reproduced so that the image contacts said dielectric layer, subjecting such assembly to corona discharge, removing the original copy from the electrographic plate, contacting said plate with a powder electrically charged with the same polarity as the corona discharge, electrostatically transferring the powder image so formed to asecond surface, and fixing the transferred image by heat to said second surface.
6. An electric method of'reproducing copy, com prising the steps of preparing an electrographic plate consisting of a dielectric layer on a conductive backing plate, placing the copy to be reproduced so that the image contacts said dielectric layer, subjecting such assembly to an electrostatic discharge, removing the original copy from the electrographic plate, flowing a powder electrically charged with the same polarity as the polarity of the electrostatic discharge across said plate, transferring the powder image so formed to a second surface, fixing the transferred image to said second surface, and cleaning and dis charging the electrographic plate with a damp cloth.
7. An electric method of reproducing copy, comprising the steps of placing a copy comprising an image-supporting material and an image material of different electrical conductivity properties in contact with the dielectric layer of an ,electrographic plate consisting of a dielectric coating layer on a conduitive backin plate, sub- J'ecting such assembly to an. electrostatic discharge, removing the copy from the electrographic plate, contacting said plate with a powder electrically charged with the same polarity as the polarity of the electrostatic discharge, transferring the powder image so formed to a second surface, and fixing the transferred image to said second surface.
8. An electric method of reproducing copy, comprising the steps of preparing an electrographic plate consisting of a dielectric layer on a conductive backing p1ate, placing the copy to be reproduced so that the-image contacts said dielectric layer, subjecting such assembly to an electrostatic discharge, removing the original copy from the electrographic plate, contacting said plate with a powder electrically charged with the same polarity as the polarity of the electrostatic discharge, and fixing the image so formed to the electrographic plate.
9. An electric method of reproducing engineering drawings, comprising the steps of placing the drawing to be reproduced so that the drawnimage'contacts the dielectric layer of an electrographic plate consisting of a dielectric coating layer on-a conductive backing plate, subjecting such assembly to an electrostatic discharge, removing the drawing from the electrographic plate, flowing a powder electrically charged with the same polarity as the polarity of the electrostatic discharge across said plate, transferring the powder image thus formed to a second surface, and fixing the transferred image to said second surface.
10. An electric method of reproducing either side of copy printed on both sides, comprising the steps of placing the side of the copy desired to be reproduced in contact with the dielectric layer of an electrographic plate consisting of a dielectric coating layer on a conductive backing plate, subjecting such assembly to an electrostatic discharge, removing the copy from the electrographic plate, contacting said plate with a powder electrically charged with the same polarity as the polarity of the electrostatic discharge, transferring the powder image thus formed to a second surface, and fixing said transferred image to said second surface.
11. An electric method of reproducing copy, comprising the steps of preparing an electrographic plate consisting of a dielectric layer 0.00025 to 0.0005-inch thick on a conductive backing plate, placing the copy to be reproduced so that the image contacts said dielectric layer, subjecting such assembly to an electrostatic discharge, removing the original copy from the electrographic plate, flowing a powder electrically charged with the same polarity as the polarity of the electrostatic discharge across said plate, transferring the powder image so formed to a second surface, and fixing the transferred image to said second surface.
12. An electric method of reproducing copy, comprising the steps of preparing an electrographic plate consisting of a dielectric layer less than 0.002-inch thick on a conductive backing plate, placing the copy to be reproduced so that the image contacts said dielectric layer, subjecting such assembly to an electrostatic discharge, removing the original copy from the electrographic plate, flowing a powder electrically charged with the same polarity as the polarity of the electrostatic discharge across said plate,
transferring the powder image so formed to a second surface, and fixing the transferred image to said second surface.
13. An electrical method of reproducing an image formed upon a material having a different electrical resistance from said image, comprising the steps of bringing the image bearing material into contiguous relation with the dielectric layer of an electrographic plate comprising a dielectric coating layer on a conductive backing plate, and subjecting said contactingimage bearing material and dielectric layer to an electrical discharge, thereby to form an electrostatic image of said design on said dielectric layer.
14. An electrical method of reproducing an image formed upon one side of sheet material having a different electrical resistance from said image, comprising the steps of bringing the image bearing side of said materialinto face to face contact with the dielectric layer of an electro graphic plate comprising a dielectric coating layer on a conductive backing plate, and imposing an electric charge upon said dielectric face through said sheet material, thereby to form an electrostatic image upon the dielectric layer of rial having a difierent electrical resistance from said image and having a second image formed upon a second parallel surface of said material on the opposite side of said material from said first surface, comprising the steps of bringing the first surface of said image bearing material into contiguous relation with the dielectric layer of electrographic plate comprising a dielectric coating layer on a conductive backing plate, and subjecting said contacting image bearing material and dielectric layer to an electrical discharge to form an electrostatic image of the image on the first surface on said dielectric material.
16. An electrical method of reproducing an image formed upon a material having a diiTerent electrical resistance from said image, comprising the steps of bringing the image bearing material into contiguous relation with a dielectric layer adhered to an electrically conductive plate, subjecting said contacting dielectric layer and image bearing material to an electrical discharge to form an electrostatic image of said image on said dielectric layer, removing the image bearing material from said dielectric layer, and bringing said dielectric layer into contact with a finely divided electrostatically attractable material thereby to make visible said electrostatic image.
17. An electrical method of copying an image formed upon a surface having a different electril l cal resistance from said image upon a dielectric layer-adhering to an electrically conductive plate, comprising the steps of bringing the image bearing surface into contact with said dielectric material, subjecting said contacting image bearing I surface and dielectric layer to an electrical discharge to form an electrostatic image of said image on said dielectric layer, removing the image bearing surface from said dielectric layer,
bringing said dielectric layer into contact with a finely divided electrostatically attractable material thereby to form a transferable image, and subjecting-said transferable image and said second surface to an electrical discharge thereby to transfer said image from said dielectric layer to said second surface.
18. An electrical method of copying an image formed upon a surface having a different electrical resistance from said image comprising the steps of bringing the image bearing surface into contact with the dielectric layer'of an electrographic plate comprising a dielectric coating layer on a-conductive backing plate, subjecting said contacting image bearing surface-and dielectric layer'to an electrical discharge to form an electrostatic image of said image on said dielectric'layer, removing the image bearing surface from said dielectric layer, bringing said-dielectric'layer into contact'with-a finely divided elec- -trostaticallyattractable material thereby to form I a transferable image on said layer corresponding to the image to be copied, and transferring said image on to a secondsurface.
19. An electrical method-of copying an image formed upon asurface having different electrical resistance fromsaid image, comprising the steps of bringing theimage bearing surface into contact with the "dielectric layer of an electrographic plate "comprising a "dielectric coating layer-on a conductive backing plate, subjecting said contacting image bearing surface and dielectric layer to an electrical discharge to form an electrostatic image of said image on said dielectric layer, removing the image bearing surface from said dielectric layer, bringing'thesai'd dielectric layer into contact-with afinely divided 'electrostatically attractable material thereby to form a transferable image on said layer corresponding to the'image to b'e copied, transferring "layer 'on a conductive backing plate, subjecting said contacting image bearing surface and dielectric layer to an electrical discharge to form an electrostatic image of said image on said dielectric layer, removing the image bearingsur-face from said dielectric layer, bringing said dielectric layer into contact with a :finely divided electrostatically attractable material thereby to form a transferable image on said layer corresponding to the image to be copied, bringing a secondsurface 'into contact with said transferable image, subfleeting-said transferable image and said second surface to an electrical discharge thereby to transfer'said image from said dielectric layer to said second surface, and fixing said transferred image to said-second surface.
21. In an electric method'of reproducing copy wherein an electrostatic image of the copy is produced; on an electrographic plateconsisting of an insulating coating on a conductive backing, the
steps comprising exposing the plate to an electrostatic discharge through the copy while the copy is in contact with the plate, and removing said .copyfrom said plate.
JAMES P. EBERT.
References .Cited in thefilezof this patent UNITED "STATES PATENTS Number Name Date 1,784,912 .Scott Dec-16, 1930 2,152,077 Meston etal :Mar. 28, 1939 2,221,776 Carlson Nov. 19, 1940 2,297,691 Carlson Oct. 6, 1942 2,357,809 Carlson .Sept.;12, 1944
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US2758948A (en) * 1953-02-02 1956-08-14 Lockheed Aircraft Corp Method of forming a light-transparent electrically conductive coating on a surface and article formed thereby
US2817277A (en) * 1955-01-07 1957-12-24 Haloid Co Electrophotographic camera
US2834132A (en) * 1954-12-14 1958-05-13 American Type Founders Co Inc Electrostatic applying and holding device
US2838997A (en) * 1953-10-30 1958-06-17 Rca Corp Electrostatic image copying method
US2879395A (en) * 1955-06-08 1959-03-24 Haloid Xerox Inc Charging device
US2900515A (en) * 1956-03-16 1959-08-18 Edward L Criscuolo Radiography by gas ionization
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US2914403A (en) * 1955-05-17 1959-11-24 Rca Corp Electrostatic printing
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US2923964A (en) * 1953-12-22 1960-02-09 Treatment of surfaces of polyethylene resins
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US2935418A (en) * 1953-06-03 1960-05-03 Olin Mathieson Method for treating preformed polyethylene with an electrical glow discharge
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US2995108A (en) * 1958-06-02 1961-08-08 Haloid Xerox Inc Xerographic powder image transfer apparatus
US3003892A (en) * 1957-10-17 1961-10-10 Eastman Kodak Co Method of marking polyethylene and resultant article
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US4761668A (en) * 1986-09-29 1988-08-02 Xerox Corporation Highlight color printer
US4771314A (en) * 1986-12-29 1988-09-13 Xerox Corporation Developer apparatus for a highlight printing apparatus
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US2740895A (en) * 1950-08-21 1956-04-03 Minnesota Mining & Mfg Thermoprinting apparatus
US2758948A (en) * 1953-02-02 1956-08-14 Lockheed Aircraft Corp Method of forming a light-transparent electrically conductive coating on a surface and article formed thereby
US2935418A (en) * 1953-06-03 1960-05-03 Olin Mathieson Method for treating preformed polyethylene with an electrical glow discharge
US2838997A (en) * 1953-10-30 1958-06-17 Rca Corp Electrostatic image copying method
US2923964A (en) * 1953-12-22 1960-02-09 Treatment of surfaces of polyethylene resins
US2834132A (en) * 1954-12-14 1958-05-13 American Type Founders Co Inc Electrostatic applying and holding device
US2910351A (en) * 1955-01-03 1959-10-27 Gen Electric Method of making printed circuit
US2817277A (en) * 1955-01-07 1957-12-24 Haloid Co Electrophotographic camera
US2922883A (en) * 1955-03-03 1960-01-26 Rca Corp Electrostatic charging means and method
US2932742A (en) * 1955-03-22 1960-04-12 Haloid Xerox Inc Xerographic charging device and method
US2914403A (en) * 1955-05-17 1959-11-24 Rca Corp Electrostatic printing
US2879395A (en) * 1955-06-08 1959-03-24 Haloid Xerox Inc Charging device
US2965482A (en) * 1955-09-08 1960-12-20 Haloid Zerox Inc Method for fixing xerographic images
US2930711A (en) * 1955-11-03 1960-03-29 Gen Dynamics Corp Electrostatic printing
US2900515A (en) * 1956-03-16 1959-08-18 Edward L Criscuolo Radiography by gas ionization
US3057997A (en) * 1956-05-21 1962-10-09 Edward K Kaprelian Exposure charged electrophotography
US3004860A (en) * 1957-04-24 1961-10-17 Xerox Corp Induction powder transfer
US2953470A (en) * 1957-06-27 1960-09-20 Ncr Co Method for electrostatic printing
US3003892A (en) * 1957-10-17 1961-10-10 Eastman Kodak Co Method of marking polyethylene and resultant article
US3038799A (en) * 1958-01-13 1962-06-12 Commw Of Australia Method of reversing the image in xerography
US3441437A (en) * 1958-02-12 1969-04-29 Burroughs Corp Recording medium and process of developing latent electrostatic image on a recording medium
US2995108A (en) * 1958-06-02 1961-08-08 Haloid Xerox Inc Xerographic powder image transfer apparatus
US3280741A (en) * 1958-12-31 1966-10-25 Burroughs Corp Electrostatic recording
US3089953A (en) * 1959-04-15 1963-05-14 Kalle Ag Reproduction process
US3145655A (en) * 1959-06-23 1964-08-25 Xerox Corp Equipotential xeroprinting member and process of printing therewith
US3654461A (en) * 1959-12-04 1972-04-04 Gevaert Photo Prod Nv Electrothermographic image recording process
US3321768A (en) * 1960-05-12 1967-05-23 Burroughs Corp Electrostatic recording with interchangeable stencils
US3247794A (en) * 1963-04-25 1966-04-26 Dick Co Ab Transfer process
US3326709A (en) * 1963-10-18 1967-06-20 Eastman Kodak Co Electrostatic printing
US3306198A (en) * 1963-12-04 1967-02-28 Continental Can Co Electrostatic printing process
US4076858A (en) * 1974-10-10 1978-02-28 Xerox Corporation Electrostatic copying process with charging of the original
US4705696A (en) * 1984-09-27 1987-11-10 Olin Hunt Specialty Products Inc. Method of making a lithographic printing plate, printing plates made by the method, and the use of such printing plates to make lithographic prints
US4761668A (en) * 1986-09-29 1988-08-02 Xerox Corporation Highlight color printer
US4731634A (en) * 1986-11-03 1988-03-15 Xerox Corporation Apparatus for printing black and plural highlight color images in a single pass
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