US3153166A

US3153166A - Electroluminescent device having connections on the base

Info

Publication number: US3153166A
Application number: US47793A
Authority: US
Inventors: Jr William A Thornton; Robert L Fitzmaurice
Original assignee: Westinghouse Electric Corp
Current assignee: CBS Corp
Priority date: 1960-08-05
Filing date: 1960-08-05
Publication date: 1964-10-13
Anticipated expiration: 1981-10-13

Description

Oct. 13,1964

ELECTROLUMINESCENT DEVICE HAVING CONNECTIONS ON THE BASE Filed Aug. 5, 1950- I A. C. SU PPLY W. A. THORNTON, JR., ETAL 2 Sheets-Sheet 1 IN VEN TOR5 WILL/19M H. THOKNM/V, Jr. ROBERT L. F'ITZMfll/E/CE'.

HTTJZA/EK Oct. 13, 1964 w. A. THORNTON, JR.. ETAL 3,153,166

ELECTROLUMINESCENT DEVICE HAVING CONNECTIONS ON THE BASEi Filed Aug; 5, 1960 2 Sheets-Sheet 2 FIG].

A.C.SUPPLY FIG.8.

WQM

United States Patent a rss 166 ELEcrnoLm rmnscnhr nnvicn HAVING coNNncrroNs on 'rrn: BASE William A. Thornton, Jr., Cranford, and Robert L. Fitz- This invention relates to electroluminescent devices and, more particularly, to electroluminescent devices which are adapted to be energized to produce radiations of different colors and color blends.

Electroluminescent devices which produce radiations of different colors are well known and such devices usually comprise a pluarlity of stacked or superimposed individual electroluminescent cells. Each of the individual cells of the stack can be energized to produce a different color. By selectively energizing different cells of the stack, any preselected color or blend of such colors can be obtained. In the fabrication of such stacked cells, difficulties have been encountered in making electrical connections to the intermediate electrodes and in properly insulating the several superimposed electrodes which are required.

It is the general object of this invention to avoid and overcome the foregoing and other difliculties of and objections to prior-art practices by the provision of an electroluminescent device which can be energized to produce different preselected colors and color blends and which device is very positive inoperati'on.

It is another object to provide an electroluminescent device which can be energized to produce different colors or color blends and which device is very simple to fabricate.

f It is a further object to provide a stacked electroluminescent device to which electrical connections can be readilyjmade.

.It .is an additional object to. provide alternative constructions for an electroluminescent device which can be energized to produce different colors and color blends.

The aforesaid objects of the invention, and other objects which-will become apparent as the description proceeds, are achieved by providing an electroluminescent device which is formed as a plurality of stacked or superimposed individual cells. In the construction ofthis device, an insulating foundation. has provided thereon a first conducting layer, an edge portion of which provides a'first contact area for purposes of energization. At least three other contactv areas are provided on the foundation and all of the contact areas are electrically insulated from one another. The first phosphor layer of the combination is coated or carried over the firstconducting coating in such manner that the phosphor layer overlaps the first conducting coatingand also overlaps onto a portion of all contact areas. Over this first phosphor coating is applied a second conducting coating which is light transmitting and electrically connects to one of the contact areas. Second and third phosphor coatings and the respective successive conducting coatings are similarly applied, with the latter electrically connecting to predetermined individual contact areas which are provided on the foundation- In this manner, all electrical contacts as required to energize the device are made to the foundation supported contact areas. Because of the foundation support, these contact areas are readily adapted to be connected to an energizing source. By properly preselecting the contact areasacross which anenergizing potential is applied, any individual cell of the stacked combination, or any combination of cells, can be cause to electroluminesce to produce any preselected color of light. e

3,153,165 Patented Oct. 13., 1964 For a better understanding of the invention, reference should be had to the accompanying drawings. wherein:

FIG. 1 is a plan view of an electroluminescent device constructed in accordance with the present invention, together with the energizing source therefor;

FIG. 2 is a sectional elevational view of the device as shown in FIG. 1, taken on the line IIII in FIG. 1 in the direction of the arrows;

FIG. 3 is a side elevational view of the device as shown in FIG. 1, taken on the line IlIIII in FIG. 1 in the direction of the arrows;

FIG. 4 is a plan View of the foundation portion of the device as shown in FIG. 1, illustrating the arrangement of the contact areas carried thereon;

FIG. Sis a fragmentary sectional view of a device generally as shown in FIGS. 1-3, but illustrating an alternative construction;

FIG. 6 is a fragmentary elevational view of a device I generally similar to that shown in FIG. 5, but illustrating still another alternative construction;

FIG. 7 is a sectional view of yet another alternative construction, taken on the line VIIVII in FIG. 8 in 'th direction of the arrows; V

FIG. 8 is a sectional view of the device as shown in FIG. 7, taken on the line VIII-VIII in FIG. 7 in the direction of the arrows.

With specific reference to the form of the invention illustrated in the drawing, the electroluminescent device 10 as shown in FIGS. 1, 2 and 3 is adapted to be energized to emit different preselected colors or color blends and comprises an electrically insulating foundation 12 with the operative portions of the device carried thereon. Considering FIGS. 1 and 3, a first conducting layer 14 is carried on a substantial portion of the insulating foundation 12 and a portion of the conducting layer 14 which is proximate one edge of the foundation 12 serves as a first contact area 1.6. Also carried on the foundation 12 is a second contact area 18, a third contact area 20 and a fourth contact area 22. The contact areas are each positioned proximate edge portions of the foundation 12 and all contact areas .1622 are electrically insulated from one another, both by a spacing therebetween and the phosphor-dielectric insulating material which is car.-

ried thereon. The arrangement of the contact areas 16-22 on the foundation 12 is shown in detail in FIG. 4. Over a substantial portion of the first conducting layer 14, and extending onto portions of the contact area 1642, is carried a first electrically insulating, light-transmitting layer 24 comprising phosphor, which electroluminesces when energized, with a first preselected color, such as red. Over a substantial portion of the first phosphor layer 24 is carried a light-transmitting electrically conducting layer 26 which also electrically connects to the electrically conducting contact area 18, as shown in FIGS. 1 and 2. Coated over the second conducting layer 26 is a second insulating layer 28 comprising phosphor material which electroluminesces when energized to emit a second predetermined color, such as blue. The second phosphor layer 28 also overlaps all contact areas 16-22 in order to insure that individual conducting coatings which are interposed between the phcsphor layers are insulated from one another. Over a substantial portion of the second phosphor layer 28 is a third light-transmitting, conducting layer 30 which also electrically connects to the third contact area third phosphor layer 32 is a fourth conducting layer 34,

which also electrically connects to the fourth contact area 22, as shown in FIGS. 1 and 3.

As a specific preferred example, the electroluminescent device as shown in FIGS. l-3 is formed on a lighttransmitting foundation which preferably is fabricated of glass. In this embodiment, the foundation l2 and conducting layer 14 comprise the viewing face for the device 10. The first conducting layer 14 and the contact areas 16-22 are all fabricated of electrically conducting, lighttransmitting tin oxide which is applied to the glass foundation 12 in accordance with well-known techniques. Other known conducting material such as indium oxide can be substituted for the tin oxide. The second, third and fourth contact areas 1822 are all insulated from the first contact area 16, such as by scribing or abrading the tin oxide, as initially applied, from the surface of the foundation 12. As a specific example, the first phosphor layer 24 comprises zinc-cadmium-mercuric sulfide activated by copper. Such phosphor has a red electroluminescent emission and is described in detail in copending application SN. 807,730, filed April 20, 1959, by A. Wachtel and owned by the present assignee. The phosphor desirably is in finely divided form and for best performance is mixed with a light-transmitting dielectric material. As an example, the phosphor is mixed with equal parts by weight of polyvinyl-chloride acetate and the layer 24 is applied by spraying to a thickness of approximately two mils. The second conducting coating is formed of light-transmitting, electrically conducting copper iodide. Such copper iodide coatings are well known in the art and are formed by vacuum metallizing a thin layer of copper onto the surface which is to be coated and thereafter passing the copper surface through iodine vapor until the copper is converted to copper iodide and becomes light transmitting in nature. The second phosphor layer 28 is preferably formed of zinc sulfide which is activated by copper and coactivated by chlorine and has a blue emission. Such phosphors are known. As

'in the case of the first phosphor layer 24, the phosphor material comprising the layer 28 desirably is mixed with a light-transmitting dielectric material, as previously desscribed. The third conducting layer 36 is also formed of copper iodide, as previously described. The third phosphor layer 32 preferably comprises zinc sulfide phosphor which is activated by copper and coactivated with chlorine and has a green emission. Such green-emitting phosphors are well known and the emission color is readily obtained by controlling the amounts of copper and chlorine with respect to one another, in accordance with well-known procedures. The uppermost fourth conducting layer 34 is preferably formed of vacuum-metallized, reflecting aluminum or silver, although it can be formed of copper iodide if both sides of the device are desired to serve as viewing faces.

Energization for the device as shown in FIGS. 1-3 is preferably accomplished with a conventional potentiometer-transformer arrangement, wherein three potentiometers 36 are each connected across the supply line with the slide contacts for the potentiometers each connecting to the primary windings of conventional transformers 38, the secondary windings of which connect to the contact areas 16-22. By adjusting the individual potentiometers 36 to energize predetermined electroluminescent layers of the device 10, any color from red through blue or any preselected desired color blend can be readily obtained.

In contrast to previous multi-layer electroluminescent devices, electrical connections to all of the individual electrically conducting layers are very simple to make and are very positive, as well as rugged in performance. As an example, electrical connections can be made by means of conventional bus bars 40 to a portion of each individual contact area 16-22 which is uncoated with phosphor material. Alternatively, a clamp or pressure contact can be readily made by clamping across the sides of the foundation 12.

As a possible alternative embodiment, the device 10a as shown in FIGS can be provided with a plastic foundation 12a which can be either opaque or light transmitting in nature. Urea formaldehyde is a suitable opaque plastic and polystyrene is a suitable light-transmitting plastic. With such a construction, the first electrode layer 14:; and the contact segments adjacent thereto are formed of copper iodide or similar light-transmitting material which does not require high temperatures of formation which could melt or damage the plastic foundation 12a. The embodiment 10a is also modified from the embodiment 10 as shown in FIGS. l-3 in that an additional layer 42 of insulating material is provided over the fourth electrode layer 34 in order to prevent shock hazard. The additional insulating layer 42 can be made light transmitting or opaque, depending on which side of the device 10a is to serve as the viewing face. A further additional separate layer 4-4 of dielectric material has also been included adjacent the third phosphor layer 32, in order to improve the electrical breakdown characteristics of this phosphor layer. Any of the device embodiments as illustrated and described hereinbefore can incorporate additional separate dielectric layers between the individual electrodes or conducting layers which define each electroluminescent cell or layer of the combination devices.

In FIG. 6 is shown a further alternative embodiment which is modified from the embodiment as shown in FIGS. 1-3 in that metal mesh electrodes 46 are utilized, wherein the interstices between the individual meshes serve to transmit the light which is generated. Such mesh-type electrodes are well known. Conducting glass fiber mesh electrodes can be substituted for the metal mesh electrodes and are generally described in US. Patent No. 2,774,004, dated December 11, 1956. The plastic foundation 12b can also be made flexible to enable the device 1017 to be conformed into desired shapes and better withstand shock hazards. In the embodiment 101) as shown, the metal mesh electrodes are embedded in light-transmitting plastic material.

In FIGS. 7 and 8 are shown yet another alternative embodiment 190, which generally corresponds to the device embodiment 10 as shown in FIGS. 1-3, except that an additionallayer 47 comprising electroluminescent phosphor has been provided over the fourth conducting layer 340, which is formed of light-transmitting copper iodide. Over the fourth phosphor layer 47 is provided a fifth conducting layer 48 which is formed of vacuummetallized silver or aluminum or copper iodide. The contact areas on the foundation 12 are also slightly modified in that the contact area 18, as shown in FIG. 1, has

been broken into two insulated segments 18c and 50, in order to provide the additional contact area 50 which electrically connects to the fifth conducting layer 48. As in the previous embodiments, the phosphor comprising the layer 47 is selected to electroluminesce with a preselected color, such as yellow. Zinc sulfide phosphor which is activated by copper and manganese electrolurninesces with a yellow color and such a phosphor is well known. Additional phosphor layers can be provided if it is desired to add other preselected colors to the output of the device 10c. If additional phosphor layers are desired, an additional electrically conducting electrode layer is provided over each such additional phosphor layer, with, the electrically conducting electrode layers positioned between such additional phosphor layers being formed of light-transmitting material such as copper iodide, for example, in order to transmit the generated light. An additional contact area on the device foundation, proximate the edge portions thereof, is also required for each additional conducting layer which is utilized and each of these additional contact areas are necessarily insulated from all' of the other contact areas. Such a modified construction is readily obtained byfurther dividing any of the contactareas 1322 inthe device emvided, either by means of a bus bar connection or by clamping across the foundation of the device.

The devices as illustrated and described hereinbefore are subject to further considerable modification. As an example, the device as shown in FIG. 1 can be fabricated entirely of ceramic material and the plastic dielectric which has been described hereinbefore replaced by suitable ceramic dielectric mixed with the phosphor. In addition, while the phosphors as described emit respectively in red, blue and green, phosphors which emit in colors different from those indicated can be substituted therefor and such phosphors are well known. It is preferred, however, that the phosphors emit in the primary red, blue and green colors in order that by selectively energizing the device, any predetermined color can be achieved merely by controlling the energization of the individual cells which comprise the combination device.

It will be recognized that the objects of the invention have been achieved by providing an electroluminescent device which can be energized to produce different preselected colors and color blends and which device is very positive in operation. The device is simple to fabricate and electrical connections thereto can be readily made.

In addition, alternative constructions for such a device have beenprovided.

While best embodiments of the invention have been illustrated and described in detail, it is to be particularly understood that the invention is not limited thereto or thereby.

We claim:

1. An electroluminescent device adapted to emit in different predetermined colors and comprising: an electrically insulating foundation; a first conducting layer carried on a substantial portion of said foundation; a first contact area formed by a portion of said first conducting layer proximate an edge portion of said foundation; second, third and fourth electrically conducting contact areas carried on portions of said foundation which are uncoated with said first conducting layer and each positioned proximate edge portions of said foundation; said contact areas each electrically insulated from one another; a first electrically insulating light-transmitting layer comprising phosphor which electroluminesces with a first preselected color carried on a substantial portion of said first conducting layer and overlapping onto said contact areas; a second electrically conducting layer which is light transmitting carried on a substantial portion of said first insulating layer comprising phosphor and also connecting to a portion of said-second contact area; a second electrically insulating light-transmitting layer comprising phosphor which electroluminesces with a second predetermined color carried on said second conducting layer and overlapping onto said contact areas; a third electrically conducting layer which is light transmitting 7 carried on a substantial portion of said second insulating layer comprising phosphor and also connecting to a 1 portion of said third contact area; a third insulating lighttransmitting layer comprising phosphor 'which electro,

luminesces with a third preselected color carried on said third conducting layer and overlapping onto said contact areas; a fourth electrically conducting layer carried on a substantial portion of said third insulating layer comprising phosphor and also connecting to a portion of .said fourth contact area; at least one of said first and fourth electrically conducting layers comprising a viewing face for said device with all material comprising such viewing face being light transmitting; and energizing potentials adapted to be electrically connected to said first, second, third and fourth contact areas.

2. In the electroluminescent device as specified in claim 1, wherein said foundation and said first conducting layer are light transmitting.

3. An electroluminescent device as specified in claim 2, wherein said foundation is glass.

4. An electroluminescent device as specified in claim 3, wherein said first conducting layer is formed of tin oxide.

5. An electroluminescent device as specified in claim 4, wherein said fourth conducting layer is formed of metallic material which is opaque and reflecting.

' 6. An electroluminescent device as specified in claim 1, wherein said foundation is formed of plastic material.

7. An electroluminescent device as specified in claim 6, wherein said foundation is flexible.

8. An electroluminescent device as specified in claim 1, wherein said foundation and said first and fourth conducting layers are light transmitting.

9. An electroluminescent device as specified in claim 1, wherein said foundation is opaque and said fourth conducting layer is light transmitting.

10. An electroluminescent device as specified in claim 1, wherein said second and third conducting layers are formed of copper iodide.

11. An electroluminescent device as specified in claim 1, wherein said second and third conducting layers are formed of electrically conducting mesh.

12. An electroluminescent device as specified in claim 1, wherein at least one additional layer of electrically insulating dielectric material is included adjacent at least one of said insulating layers comprising phosphor.

13. An electroluminescent device as specified in claim 1, wherein said insulating layers comprising phosphor electroluminesce respectively when energized to emit in the red, blue and green regions of the visible spectrum.

14. An electroluminescent device as specified in claim 1, wherein each of said layers comprising phosphor are adapted to be energized in predetermined fashion.

15. An electroluminescent deviceas specified in claim 1: wherein said fourth electrically conducting layer is light transmitting; at least one additional electrically insulating light-transmitting layer comprising phosphor superimposed over said. fourth conducting layer; an additional electrically conducting layer carried over each said additional phosphor layer, with any said additional conducting layer having any said additional phosphor layer carried thereover being light transmitting; an additional contact area carried on said foundation, proximate an edge portion thereof, provided for each said additional conducting layer and electrically connecting thereto and insulated from all other of said contact areas; each said additional layer comprising phosphor electrolum-inescing with a predetermined color; and an energizing potential adapted to be electrically connected to each said additional contact area.

References Cited in the file of this patent UNITED STATES PATENTS

Claims

1. AN ELETROLUMINESCENT DEVICE ADAPTED TO EMIT IN DIFFERENT PREDETERMINED COLORS AND COMPRISING: AND ELECTRICALLY INSULATING FOUNDATION; A FIRST CONDUCTING LAYER CARRIED ON A SUBSTANTIAL PORTION OF SAID FOUNDATION; A FIRST CONTACT AREA FORMED BY A PORTION OF SAID FIRST CONDUCTING LAYER PROXIMATE AN EDGE PORTION OF SAID FONDATION; SECOND, THIRD AND FOURTH ELECTRICALLY CONDCTING CONTACT AREAS CARRIED ON PORTIONS OF SAID FONDATION WHICH ARE UNCOATED WITH SAID FIRST CONDUCTING LAYER AND EACH POSITIONED PROXIMATE EDGE PORTIONS OF SAID FONDATION; SAID CONTACT AREAS EACH ELECTRICALLY INSULATED FROM ONE ANOTHER; A FIRST ELECTRICALLY INSULATING LIGHT-TRANSMITTING LAYER COMPRISING POSPHOR WHICH ELECTROLUMINESCES WITH A FIRST PRESELECTED COLOR CARRIED ON A SUBSTANTIAL PORTION OF SAID FIRST CONDUCTING LAYER AND OVERLAPPING ONTO SAID CONTACT AREAS; A SECOND ELECTRICALLY CONDUCTING LAYER WHICH IS LIGHT TRANSMITTING CARRIED ON A SUBSTANTIAL PORTION OF SAID FIRST INSULATING LAYER COMPRISING PHOSPHOR AND ALSO CONNECTING TO A PORTION OF SAID SECOND CONTACT AREA; A SECOND ELECTRICALLY INSULATING LIGHT-TRANSMITTING LAYER COMPRISING PHOSPHOR WHICH ELECTROLUMINESCES WITH A SECOND PREDETERMINED COLOR CARRIED ON SAID SECOND CONDUCTING LAYER AND OVERLAPPING ONTO SAID CONTACT AREAS; A THIRD ELECTRICALLY CONDUCTING LAYER WHICH IS LIGHT TRANSMITTING CARRIED ON A SUBSTANTIAL POSTION OF SAID SECOND INSULATING LAYER COMPRISING PHOSPHOR AND ALSO CONNECTING TO A PORTION OF SAID THIRD CONTACT AREA; A THIRD INSULATING LIGHTTRANSMITTING LAYER COMPRISING PHOSPHOR WHICH ELECTROLUMINESCES WITH A THIRD PRESELECTED COLOR CARRIED ON SAID THIRD CONDUCTING LAYER AND OVERLAPPING ONTO SAID CONTACT AREAS; A FOURTH ELECTRICALLY CONDUCTIN GLAYER CARRIED ON A SUBSTANTIAL PORTION OF SAID THIRD INSULATING LAYER COMPRISING PHOSPHOR AND ALSO CONNECTING TO A PORTION OF SAID FOURTH CONTACT AREA; AT LEAST ONE OF SAID FIRST AND FOURTH ELECTRICALLY CONDUCTING LAYERS COMPRISING A VIEWING FACE FOR SAID DEVICE WITH ALL MATERIAL COMPRISING SUCH VIEWING FACE BEING LIGHT TRANSMITTING; AND ENERGIZING POTENTIALS ADAPTED TO E ELECTRICALLY CONNECTED TO SAID FIRST, SECOND, THIRD AND FOURTH CONTACT AREAS.