US3575752A - Nonwoven bonding method - Google Patents
Nonwoven bonding method Download PDFInfo
- Publication number
- US3575752A US3575752A US731222A US3575752DA US3575752A US 3575752 A US3575752 A US 3575752A US 731222 A US731222 A US 731222A US 3575752D A US3575752D A US 3575752DA US 3575752 A US3575752 A US 3575752A
- Authority
- US
- United States
- Prior art keywords
- horn
- fibrous
- bonding
- nonwoven
- web
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/08—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using ultrasonic vibrations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/78—Means for handling the parts to be joined, e.g. for making containers or hollow articles, e.g. means for handling sheets, plates, web-like materials, tubular articles, hollow articles or elements to be joined therewith; Means for discharging the joined articles from the joining apparatus
- B29C65/7858—Means for handling the parts to be joined, e.g. for making containers or hollow articles, e.g. means for handling sheets, plates, web-like materials, tubular articles, hollow articles or elements to be joined therewith; Means for discharging the joined articles from the joining apparatus characterised by the feeding movement of the parts to be joined
- B29C65/7888—Means for handling of moving sheets or webs
- B29C65/7891—Means for handling of moving sheets or webs of discontinuously moving sheets or webs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/7392—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
- B29C66/73921—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic characterised by the materials of both parts being thermoplastics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/82—Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps
- B29C66/824—Actuating mechanisms
- B29C66/8242—Pneumatic or hydraulic drives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/83—General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
- B29C66/832—Reciprocating joining or pressing tools
- B29C66/8322—Joining or pressing tools reciprocating along one axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/08—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
- B29K2105/0854—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns in the form of a non-woven mat
Definitions
- a self-bonded nonwoven fibrous sheet is made by (1) disposing an at least partially thermoplastic, oriented fibrous material upon a surface in random, multi-directional, overlapping and intersecting arrangement to form a batt or web and (2) imposing a source of sonic energy upon the batt or web to selectively heat and bond the fibrous elements at their points of contact or crossover.
- the present invention relates to fibrous sheets and laminates incorporating same and, more particularly, to a method of making coherent, self-bonded, nonwoven sheets made from thermoplastic fibrous elements.
- Nonwoven sheets are generally less costly than woven sheets of similar material to the extent that the weaving operation has been eliminated.
- nonwoven structures ordinarily must be treated in some manner to cause a consolidation of the fibrous network to provide a coherent sheet having improved properties.
- the use of adhesive binders, solvents, or of felting or fiber entangling operations to achieve an adequate degree of coherency is costly and offsets the economic advantage attending the elimination of the weaving operation.
- the novel process constituting the present invention comprises the formation of a contiguous fibrous network wherein the fibrous elements overlap one ano'her, preferably in a multi-directional, uniformly random fashion, thence imposing a source of sonic energy upon said network to preferentially heat the points of fiber contact within said network to thereby effect a self-bonding of the network without a substantial reduction in the interbond orientation level of the fibrous constituents.
- the result is a bonded, nonwoven structure wherein the bond points are weaker than the interbond portions.
- One practical aspect of this feature lies in the use of such nonwovens as carpet backings wherein the piercing action of the tufting needle during carpet formation effects a bond, rather than fiber breakage, resulting in a backing member of greater structural integrity than would otherwise be obtained.
- the process may also be utilized to form laminated constructions, one or more layers of which are in the form of a Patented Apr. 20, 1971 nonwoven fibrous network, other layers being in the form of, for example, a film or netting.
- fusion bonding normally denotes a bonding by actual melting of the workpiece at the point of sonic excitation, but it is to be recognized that suitable bonding under the instant practice may as well be wrought by heating to the point of softening of the fibrous components being joined short of actual fusion, accompanied or immediately followed by a plastic deformation to effect a bond more in the nature of a mechanical interlock. It follows that the bond may take the form of and be enhanced by both fusion and mechanical interlock through deformation, wherein that portion of the bond receiving the most intense sonic excitation is in fact fused and the lesser excited bond portions are partially softened and plastically deformed.
- the bonding operation is easily controlled to accomplish a mechanically interlocked, partially fused, bond wherein a melted portion of the lower melting component is interlocked with a deformed portion of the higher melting component. It'is, however, preferred to effect a mutual interfusion of the contiguous fibrous elements in order to promote maximum bond strength.
- ultrasonic heating devices generally comprise an alternating current .generator productive of a frequency in the ultrasonic range (usually 20,000 c.p.s. or greater), a transducer assembly or sonic convertor, preferably of the piezoelectric type, wherein the electrical output of the generator is converted into high frequency longitudinal mechanical vibrations or compressional waves due to the dimensional response of the piezoelectric crystal to the varying voltage placed across it, an acoustic coupling or booster bar connected to the out-put of the transducer and being operative to amplify the magnitude of the vibrations transmitted longitudinally therethrough, and a resonant section or horn secured to the ouput end of the acoustic coupling or booster bar for vibration therewith in the direction of the longitudinal axis of the coupling bar and, finally, a rigidly supported surface or anvil positioned in a plane substantially perpendicular to the longitudinal axis of the horn and against which the horn acts through the medium of a workpiece placed therebetween.
- the horn or tool is vibrated perpendicularly to the anvil surface and against the thermoplastic structure interposed therebetween to effect a repeated and rapid compression of the thermoplastic material at the indicated ultrasonic frequency to thereby generate heat, both internally within the thermoplastic constituents and by inter-element surface friction, resulting in such a rapid build-up to the temperature of fusion that adjacent areas of the medium remain substantially at their original temperature.
- the wonking head or horn employed will generally be provided with an active surface or surfaces of small area.
- the rapidity of temperature buildup in the workpiece is primarily a function of the mass of the workpiece or pieces, their thermal conductivity, modulus of elasticity, coefficient of friction, impact resistance and heat of conduction, the horn-tip geometry, sonic intensity (as measured by the force and velocity at which the horn tip is driven), and the pressure at which the horn is brought to bear upon the workpiece.
- a metallic screen is placed over the anvil surface upon which the nonwoven to be bonded is placed. It has been found that the use of a screen overlay minimizes any tendency towards overbonding of the fibrous cross-over points and tends to localize the sonic energy more precisely with a minimized risk of over-heating or melting.
- suitable interrelations of the screen mesh and wire gauge to the fibrous network being bonded particularly as regards density and fiber diameter, interesting variations in bond spacing and size may be accomplished with good reproducibility and uniformity.
- thermoplastic in characterizing the fibrous components utilized in the present invention is to be understood as including such as blends of fibrous elements, a portion of which may be non-thermoplastic to the extent that they not be subject to charri-ng during the bonding operation.
- the only criterion is that the fibrous network contain one or more thermoplastic constituents, preferably in a major proportion, which constituents preferably exhibit a close identity in their melting points where maximum bond strength is desired.
- the structure and mode of formation of the nonwoven network or web may vary extensively, although, where isotropic constructions are sought, the filaments in the Web should have a high degree of random positioning.
- One of the more preferred backing structures takes the form of an air-laid, random, continuous filament, uncrimped filamentary network. It is preferred for most applications that the filaments should be separate and independent from each other, except at their crossover points.
- a further form of random filamentary web amenable to the present practice may be obtained by depositing a staple fiber batt utilizing a Rando Weber. Still other suitable webs may be formed by cross-lapping or laminating unidirectional filamentary webs.
- a carded staple fiber web preferably of cross-lapped laminations, is ideally suited to processing according to the precepts of the present invention.
- laminated constructions containing one or more such webs with other layers, such as films, may also be formed according to the instant techniques.
- the nonwoven network be of a uniform thickness or density when in a fully compressed state and that the filamentary elements be uniformly disposed therewithin, whether in a random or regular fashion. This follows from the fact that irregular agglomerations of filamentary elements Within the network will provoke a more intense sonic excitation than adjacent areas result ing in the formation of indiscriminately fused masses.
- FIG. 1 is a simplified, partially sectionalized illustration of one possible implementation of the process of the present invention.
- FIG. 2 is an enlarged schematic representation of a portion of a bonded sheet product according to the invention, the sample illustrated being a thin layer of such a sheet.
- sheet 1 is made up of randomly disposed, indefinite length filaments 2 bonded together at self-bonded crossover points through sonically formed bonds 3.
- FIG. 1 there is shown a relatively simplified arrangement which may serve to implement the practice of the present invention though it is, of course, contemplated that a more sophisticated and automated implementation would likely be utilized in commercial practice.
- an arrangement may comprise an ultrasonic tool, generally indicated by arrowed reference numeral 10, which tool includes a housing 12 enclosing a suitable ultrasonic mechanical transducer, preferably in the form of a piezoelectric crystal, and an amplifying section interconnecting the horn or sonic head 14 with the transducer. Since the details of the ultrasonic transducer are well known and form no part of the present invention, they will not be further described herein.
- a mounting bracket 16 serves to rigidly interconnect the sonic tool to reciprocating bar 18, the latter being actuated in reciprocating fashion by hydraulic, pneumatic, or other suitable cyclic means, not shown.
- Any timed, tool-actuating mechanism employed should provide for a variable dwell time at either end of its stroke. For example, it will normally be desired to actuate the sonic tool into engagement with the workpiece, thence energize the horn for a brief interval to effect bonding, followed by a brief dwell period to allow partial cooling of the bond. In most instances, however, the dwell period pending partial cooling may be eliminated.
- the horn configuration is, again, a matter of art outside the contribution of the present invention.
- a horn crown or working face 20 ranging from the planar, rectangular face illustrated in FIG. 1 to various knurl-like or multi-edged configurations.
- a horn having a face area of corrugated configuration to define a series of working edges which are brought to bear upon the workpiece will be found highly effective.
- a grid pattern may be formed in the face of the horn, the raised portions of which bear upon the fibrous network to bond same at these crossover points contacted by such raised portions.
- the use of a high-low configuration for the horn face 20 helps minimize any tendency towards overbonding or indiscriminate sonic energization of the interbond network portions. This has been found especially true Where the bonding operation is carried out against a mesh-like surface, as previously alluded to.
- horn 14 Disposed below horn 14 is drive drum 22 which propels endless belt 24, the latter preferably being in the form of a metallic screen. It is upon this belt that the nonwoven to be bonded is travelled to the bonding station under horn 14. Disposed directly under horn 14 is a relatively massive, rigid anvil 15 over which endless screen 24 passes in closely spaced or sliding contact therewith. On departing the bonding station, the bonded non- Woven is conveyed about a suitably disposed idler roll 34 onward to a point of take-up. From the foregoing, it will be appreciated that the screen belt 24, in conjunction with the anvil 15, functions as a mesh-patterned anvil surface upon which horn 14 works against the intervening workpiece.
- the ultrasonic horn is lowered to bonding position B.
- An electronic timer not shown, triggers the ultrasonic circuit to the horn for the desired pulse length, dictated by the particular nonwoven network being bonded, and, optionally, momentarily retains the horn in this position pending partial solidification of the workpiece.
- the horn is then returned to position A preparatory to being cycled through another bonding stroke.
- the workpiece is indexed through the bonding station by increments chosen according to whether it is desired to effect a uniform bonding action throughout the entire surface of the nonwoven, or instead an open pattern of bonding, wherein the horn would contact spaced areas of the nonwoven surface.
- the ultrasonic transducer employed was one commercially available from Branson Instruments, Inc., designed for an input frequency of 20 kilocycles per second, the transducer assembly taking the form of a lead-zirconate-titanate piezoelectric element. As supplied, this instrument contains a timing circuit by which the duration of the energizing cycle may be readily controlled.
- the horns utilized are generally characterized by a half-wave resonance section made of a titanium alloy, selected for its strength-toweight ratio to withstand the intense internal stresses generated within the horn element, as well as its excellent sonic conductivity.
- a conventional time-delay mechanism was employed to control the dwell time of the horn against the workpiece for a pre-set length of time after the sonic excitation period to allow at least a partial solidification of the bond points.
- a source of variable pneumatic pressure in the form of a pair of double-acting air cylinders having a 4-inch diameter was employed to control the force with which the horn was brought to bear upon the workpiece.
- the air cylinder pressure is reported as a measure of the horn pressure upon the workpiece.
- EXAMPLES 1-8 A web of continuous, uncrimped filaments was air-laid in random fashion and collected on a moving, endless screen conveyor belt.
- the yarn used consisted of 6 d.p.f. oriented isotactic polypropylene continuous multifilaments.
- the yarn was not bulked and had a denier and filament count of 210/35 with zero twist.
- the melting point of the yarn was 333 F., with a tendency to stick at 305-315 F. and the initial shrinkage temperature was 265 F. when in a relaxed state.
- the yarn was further characterized by a breaking tenacity of 3.07.0 g./d. and a tensile strength of 35,00080,000 p.s.i.
- test results of the above ultrasonically bonded nonwovens are set forth in Table II. Testing of the material was conducted at both room temperature (72 F.) and at an elevated temperature of 250 F. In determining this strip tensile strength data, the procedure of ASTM D-1117 was followed. The crosshead sped of the -Instron tester was 5 inches per minute, and the span was 5 inches.
- Webs may be formed by many methods and, though the method of web formation constitutes no critical aspect of the present practice, the present web was formed by supplying the above described yarn to a series of air jet Spreaders which were positioned on one-inch centers and supplied with compressed air at 10 p.s.i.g.
- the spreader is essentially an air-operated eductor.
- a thin-flared tube receives and guides the yarn to its lower end where an encompassing high-velocity air stream entraps the yarn and carries it downward. It then passes through that portion of the spreader which converts the air stream from a circular cross section to a narrow slit whose length is equal to the lateral spacing of the adjacent jets.
- the bottom portion of the spreader is essentially a divergent nozzle section. The separated filaments were then directed downward in a turbulent air stream onto the moving collecting screen.
- the web consisted, therefore, of continuous filaments of the yarn described above lying in random orientation.
- the web itself had no strength. It was not self-sustaining.
- the density of the deposited web (conventionally in terms of weight per square yard) was controlled primarily by the speed of the collecting screen. Webs were collected of various thicknesses ranging from approximately 4 to 6 ounces per square yard.
- Bonding of the fibrous webs thus obtained was accomplished ultrasonically using horns with a flat surface and at various operating conditions, as set forth in Table I below.
- the web being bonded was intermittently indexed under the horn tip to provide a uniformly bonded nonwoven material. Bonding data using two different horns is reported in the tabulations: (1) a horn having a rectangular contact tip 4 inch wide and 2 inches long and (2) an exponentially shaped horn having a contact tip /2 inch in diameter. Bonding was performed with the fibrous web on either a smooth surface anvil or on a 30-mesh wire screen adequately supported.
- a method for producing a coherent nonwoven fibrous sheet of improved tensile strength which comprises in combination:
- thermoplastic filaments subjecting oriented thermoplastic filaments to a turbulent air stream to obtain a random arrangement of the filaments On a movable collecting screen therby forming a sheet of thermoplastic material having a multiplicity of cross-over points;
- thermoplastic material comprises oriented filaments of indefinite length.
- thermoplastic material comprises oriented filaments of staple FOREIGN PATENTS length.
Abstract
A SELF-BONDED NONWOVEN FIBROUS SHEET IS MADE BY (1) DISPOSING AN AT LEAST PARTIALLY THERMOPLASTIC, ORIENTED FIBROUS MATERIAL UPON A SURFACE IN RANDOM, MULTI-DIRECTIONAL, OVERLAPPING AND INTERSECTING ARRANGEMENT TO FORM A BATT OR WEB AND (2) IMPOSING A SOURCE OF SONIC ENERGY UPON THE BATT OR WEB TO SELECTIVELY HEAT AND BOND THE FIBROUS ELEMENTS AT THEIR POINTS OF CONTACT OR CROSSOVER.
Description
ATTORNEY United States Patent 3,575,752 NONWOVEN BUNDIN G METHOD Charles W. Carpenter, Green Acres, Del, assignor to Hercules Incorporated, Wilmington, Del. Filed May 22, 1968, Ser. No. 731,222 Int. Cl. 32% 27/08, 1532b 31/16 U.S. Cl. 156-73 5 Claims ABSTRACT OF THE DISCLOSURE A self-bonded nonwoven fibrous sheet is made by (1) disposing an at least partially thermoplastic, oriented fibrous material upon a surface in random, multi-directional, overlapping and intersecting arrangement to form a batt or web and (2) imposing a source of sonic energy upon the batt or web to selectively heat and bond the fibrous elements at their points of contact or crossover.
The present invention relates to fibrous sheets and laminates incorporating same and, more particularly, to a method of making coherent, self-bonded, nonwoven sheets made from thermoplastic fibrous elements.
Nonwoven sheets are generally less costly than woven sheets of similar material to the extent that the weaving operation has been eliminated. To achieve adequate strucural coherency and stability, nonwoven structures ordinarily must be treated in some manner to cause a consolidation of the fibrous network to provide a coherent sheet having improved properties. The use of adhesive binders, solvents, or of felting or fiber entangling operations to achieve an adequate degree of coherency is costly and offsets the economic advantage attending the elimination of the weaving operation. In an effort to avoid the complications attending the use of adhesive binders or the added processing steps involved in such as interfelting, there is the present practice of effecting a self-bonding of nonwoven fibrous networks by heating the entire network, such as by the use of a pair of heated platens or nip rolls, to a temperature sufiicient to effect a fused bond of the fibrous elements at their crossover points. However, where the network is composed of oriented fibrous elements, such a fusion-bonding operation precipitates what is ofttimes undesired shrinkage and loss in orientation, with a consequent reduction in valuable mechanical properties, par ticularly as regards tensile strength.
Accordingly, it becomes an object of the present invention to provide a method for effecting the self-bonding of nonwoven fibrous sheet-like networks and laminated constructions containing same while substantially preserving the orientation level of the fibrous elements along their interbond portions. Other objects and advantages will become apparent from the discussion which follows.
In general, the novel process constituting the present invention comprises the formation of a contiguous fibrous network wherein the fibrous elements overlap one ano'her, preferably in a multi-directional, uniformly random fashion, thence imposing a source of sonic energy upon said network to preferentially heat the points of fiber contact within said network to thereby effect a self-bonding of the network without a substantial reduction in the interbond orientation level of the fibrous constituents. The result is a bonded, nonwoven structure wherein the bond points are weaker than the interbond portions. One practical aspect of this feature lies in the use of such nonwovens as carpet backings wherein the piercing action of the tufting needle during carpet formation effects a bond, rather than fiber breakage, resulting in a backing member of greater structural integrity than would otherwise be obtained. The process may also be utilized to form laminated constructions, one or more layers of which are in the form of a Patented Apr. 20, 1971 nonwoven fibrous network, other layers being in the form of, for example, a film or netting.
As employed herein, the term fusion bonding normally denotes a bonding by actual melting of the workpiece at the point of sonic excitation, but it is to be recognized that suitable bonding under the instant practice may as well be wrought by heating to the point of softening of the fibrous components being joined short of actual fusion, accompanied or immediately followed by a plastic deformation to effect a bond more in the nature of a mechanical interlock. It follows that the bond may take the form of and be enhanced by both fusion and mechanical interlock through deformation, wherein that portion of the bond receiving the most intense sonic excitation is in fact fused and the lesser excited bond portions are partially softened and plastically deformed. Where the two fibrous components being joined exhibit more than a small difference in melting point, the bonding operation is easily controlled to accomplish a mechanically interlocked, partially fused, bond wherein a melted portion of the lower melting component is interlocked with a deformed portion of the higher melting component. It'is, however, preferred to effect a mutual interfusion of the contiguous fibrous elements in order to promote maximum bond strength.
Most existing ultrasonic heating devices generally comprise an alternating current .generator productive of a frequency in the ultrasonic range (usually 20,000 c.p.s. or greater), a transducer assembly or sonic convertor, preferably of the piezoelectric type, wherein the electrical output of the generator is converted into high frequency longitudinal mechanical vibrations or compressional waves due to the dimensional response of the piezoelectric crystal to the varying voltage placed across it, an acoustic coupling or booster bar connected to the out-put of the transducer and being operative to amplify the magnitude of the vibrations transmitted longitudinally therethrough, and a resonant section or horn secured to the ouput end of the acoustic coupling or booster bar for vibration therewith in the direction of the longitudinal axis of the coupling bar and, finally, a rigidly supported surface or anvil positioned in a plane substantially perpendicular to the longitudinal axis of the horn and against which the horn acts through the medium of a workpiece placed therebetween.
In the fusion bonding of thermoplastic elements by the use of an ultrasonic device of the type above described, the horn or tool is vibrated perpendicularly to the anvil surface and against the thermoplastic structure interposed therebetween to effect a repeated and rapid compression of the thermoplastic material at the indicated ultrasonic frequency to thereby generate heat, both internally within the thermoplastic constituents and by inter-element surface friction, resulting in such a rapid build-up to the temperature of fusion that adjacent areas of the medium remain substantially at their original temperature. In order to focus and intensify the vibratory energy in the desired areas, the wonking head or horn employed will generally be provided with an active surface or surfaces of small area. As will readily be recognized by those conversant in the art of heating and forming by ultrasonic energy, the rapidity of temperature buildup in the workpiece is primarily a function of the mass of the workpiece or pieces, their thermal conductivity, modulus of elasticity, coefficient of friction, impact resistance and heat of conduction, the horn-tip geometry, sonic intensity (as measured by the force and velocity at which the horn tip is driven), and the pressure at which the horn is brought to bear upon the workpiece.
In a preferred mode of practice, a metallic screen is placed over the anvil surface upon which the nonwoven to be bonded is placed. It has been found that the use of a screen overlay minimizes any tendency towards overbonding of the fibrous cross-over points and tends to localize the sonic energy more precisely with a minimized risk of over-heating or melting. By suitable interrelations of the screen mesh and wire gauge to the fibrous network being bonded, particularly as regards density and fiber diameter, interesting variations in bond spacing and size may be accomplished with good reproducibility and uniformity.
The use of the term thermoplastic in characterizing the fibrous components utilized in the present invention is to be understood as including such as blends of fibrous elements, a portion of which may be non-thermoplastic to the extent that they not be subject to charri-ng during the bonding operation. The only criterion is that the fibrous network contain one or more thermoplastic constituents, preferably in a major proportion, which constituents preferably exhibit a close identity in their melting points where maximum bond strength is desired.
The structure and mode of formation of the nonwoven network or web may vary extensively, although, where isotropic constructions are sought, the filaments in the Web should have a high degree of random positioning. One of the more preferred backing structures takes the form of an air-laid, random, continuous filament, uncrimped filamentary network. It is preferred for most applications that the filaments should be separate and independent from each other, except at their crossover points. A further form of random filamentary web amenable to the present practice may be obtained by depositing a staple fiber batt utilizing a Rando Weber. Still other suitable webs may be formed by cross-lapping or laminating unidirectional filamentary webs. Also, a carded staple fiber web, preferably of cross-lapped laminations, is ideally suited to processing according to the precepts of the present invention. Further, it is as well contemplated that laminated constructions containing one or more such webs with other layers, such as films, may also be formed according to the instant techniques.
For optimum uniformity in bond spacing and size, it is necessary that the nonwoven network be of a uniform thickness or density when in a fully compressed state and that the filamentary elements be uniformly disposed therewithin, whether in a random or regular fashion. This follows from the fact that irregular agglomerations of filamentary elements Within the network will provoke a more intense sonic excitation than adjacent areas result ing in the formation of indiscriminately fused masses.
For a more detailed understanding of the practice of the present invention, reference is now made to the accompanyin g drawing in which:
FIG. 1 is a simplified, partially sectionalized illustration of one possible implementation of the process of the present invention, and
FIG. 2 is an enlarged schematic representation of a portion of a bonded sheet product according to the invention, the sample illustrated being a thin layer of such a sheet. In the figure, sheet 1 is made up of randomly disposed, indefinite length filaments 2 bonded together at self-bonded crossover points through sonically formed bonds 3.
Referring now to FIG. 1, there is shown a relatively simplified arrangement which may serve to implement the practice of the present invention though it is, of course, contemplated that a more sophisticated and automated implementation would likely be utilized in commercial practice. As there shown, such an arrangement may comprise an ultrasonic tool, generally indicated by arrowed reference numeral 10, which tool includes a housing 12 enclosing a suitable ultrasonic mechanical transducer, preferably in the form of a piezoelectric crystal, and an amplifying section interconnecting the horn or sonic head 14 with the transducer. Since the details of the ultrasonic transducer are well known and form no part of the present invention, they will not be further described herein. A mounting bracket 16 serves to rigidly interconnect the sonic tool to reciprocating bar 18, the latter being actuated in reciprocating fashion by hydraulic, pneumatic, or other suitable cyclic means, not shown. Any timed, tool-actuating mechanism employed should provide for a variable dwell time at either end of its stroke. For example, it will normally be desired to actuate the sonic tool into engagement with the workpiece, thence energize the horn for a brief interval to effect bonding, followed by a brief dwell period to allow partial cooling of the bond. In most instances, however, the dwell period pending partial cooling may be eliminated.
The horn configuration is, again, a matter of art outside the contribution of the present invention. For the purposes here involved, it has generally been found desirable to provide a horn crown or working face 20 ranging from the planar, rectangular face illustrated in FIG. 1 to various knurl-like or multi-edged configurations. For example, where it is desired to vary the incidence of bonded crossover points within the network, a horn having a face area of corrugated configuration to define a series of working edges which are brought to bear upon the workpiece will be found highly effective. Similarly, a grid pattern may be formed in the face of the horn, the raised portions of which bear upon the fibrous network to bond same at these crossover points contacted by such raised portions. Generally, it has been found that the use of a high-low configuration for the horn face 20 helps minimize any tendency towards overbonding or indiscriminate sonic energization of the interbond network portions. This has been found especially true Where the bonding operation is carried out against a mesh-like surface, as previously alluded to.
Disposed below horn 14 is drive drum 22 which propels endless belt 24, the latter preferably being in the form of a metallic screen. It is upon this belt that the nonwoven to be bonded is travelled to the bonding station under horn 14. Disposed directly under horn 14 is a relatively massive, rigid anvil 15 over which endless screen 24 passes in closely spaced or sliding contact therewith. On departing the bonding station, the bonded non- Woven is conveyed about a suitably disposed idler roll 34 onward to a point of take-up. From the foregoing, it will be appreciated that the screen belt 24, in conjunction with the anvil 15, functions as a mesh-patterned anvil surface upon which horn 14 works against the intervening workpiece.
The principle of operation briefly follows. Beginning with the horn 14 in the solid line position A indicated in FIG. 1, the ultrasonic horn is lowered to bonding position B. An electronic timer, not shown, triggers the ultrasonic circuit to the horn for the desired pulse length, dictated by the particular nonwoven network being bonded, and, optionally, momentarily retains the horn in this position pending partial solidification of the workpiece. The horn is then returned to position A preparatory to being cycled through another bonding stroke. As will be apparent, the workpiece is indexed through the bonding station by increments chosen according to whether it is desired to effect a uniform bonding action throughout the entire surface of the nonwoven, or instead an open pattern of bonding, wherein the horn Would contact spaced areas of the nonwoven surface.
The following examples will serve to further illustrate the practice of the present invention, but are not to be taken as a measure of its limitations. The ultrasonic transducer employed was one commercially available from Branson Instruments, Inc., designed for an input frequency of 20 kilocycles per second, the transducer assembly taking the form of a lead-zirconate-titanate piezoelectric element. As supplied, this instrument contains a timing circuit by which the duration of the energizing cycle may be readily controlled. The horns utilized are generally characterized by a half-wave resonance section made of a titanium alloy, selected for its strength-toweight ratio to withstand the intense internal stresses generated within the horn element, as well as its excellent sonic conductivity. Though not essential, a conventional time-delay mechanism was employed to control the dwell time of the horn against the workpiece for a pre-set length of time after the sonic excitation period to allow at least a partial solidification of the bond points. A source of variable pneumatic pressure (in the form of a pair of double-acting air cylinders having a 4-inch diameter) was employed to control the force with which the horn was brought to bear upon the workpiece. In the tabulated results set forth in the examples, the air cylinder pressure is reported as a measure of the horn pressure upon the workpiece.
EXAMPLES 1-8 A web of continuous, uncrimped filaments was air-laid in random fashion and collected on a moving, endless screen conveyor belt. The yarn used consisted of 6 d.p.f. oriented isotactic polypropylene continuous multifilaments. The yarn was not bulked and had a denier and filament count of 210/35 with zero twist. The melting point of the yarn was 333 F., with a tendency to stick at 305-315 F. and the initial shrinkage temperature was 265 F. when in a relaxed state. The yarn was further characterized by a breaking tenacity of 3.07.0 g./d. and a tensile strength of 35,00080,000 p.s.i.
The following nonwoven examples based upon the above-described fibrous web are illustrative of the present invention. They are not to be construed as limiting the scope of the invention.
The test results of the above ultrasonically bonded nonwovens are set forth in Table II. Testing of the material was conducted at both room temperature (72 F.) and at an elevated temperature of 250 F. In determining this strip tensile strength data, the procedure of ASTM D-1117 was followed. The crosshead sped of the -Instron tester was 5 inches per minute, and the span was 5 inches.
TABLE II Test sample L Tensile weight Test Basis 5% Elon- Tensile strength strength 1" x 7, temp welght, strain, Breaking gation, 5% strain, breaking, Example grams 0Z./yd. lbs. load, lbs. percent lb./in./oZ./yd. lb./in./0z./yd.
72 5. 32 0. 3 l3. 7 l2. 5 l. 75 2. 58 250 4. 23 3. 8 10. 1 22. 3 0. 90 2. 39 72 4. 24 10. l 14. 1 8. 1 2. 38 3. 33 250 4. 34 3. 6 6. 6 19. 8 0. 83 l. 52 72 5. 57 18. 2 39. 9 14. 8 3. 27 7. 16 250 5. 81 7. 5 31. 4 25. 7 1. 29 5. 40 72 4. 24 12. 7 29. 2 13. 7 3. 00 6. 89 250 4. 68 5. 3 15. 4 l6. 6 l. 13 3. 29
Webs may be formed by many methods and, though the method of web formation constitutes no critical aspect of the present practice, the present web was formed by supplying the above described yarn to a series of air jet Spreaders which were positioned on one-inch centers and supplied with compressed air at 10 p.s.i.g. The spreader is essentially an air-operated eductor. A thin-flared tube receives and guides the yarn to its lower end where an encompassing high-velocity air stream entraps the yarn and carries it downward. It then passes through that portion of the spreader which converts the air stream from a circular cross section to a narrow slit whose length is equal to the lateral spacing of the adjacent jets. The bottom portion of the spreader is essentially a divergent nozzle section. The separated filaments were then directed downward in a turbulent air stream onto the moving collecting screen.
The web consisted, therefore, of continuous filaments of the yarn described above lying in random orientation. The web itself had no strength. It was not self-sustaining. The density of the deposited web (conventionally in terms of weight per square yard) was controlled primarily by the speed of the collecting screen. Webs were collected of various thicknesses ranging from approximately 4 to 6 ounces per square yard.
Bonding of the fibrous webs thus obtained was accomplished ultrasonically using horns with a flat surface and at various operating conditions, as set forth in Table I below. The web being bonded was intermittently indexed under the horn tip to provide a uniformly bonded nonwoven material. Bonding data using two different horns is reported in the tabulations: (1) a horn having a rectangular contact tip 4 inch wide and 2 inches long and (2) an exponentially shaped horn having a contact tip /2 inch in diameter. Bonding was performed with the fibrous web on either a smooth surface anvil or on a 30-mesh wire screen adequately supported.
From the foregoing discussion and examples it will be recognized that there has been herewith disclosed a novel and most beneficial method of manufacturing bonded nonwovens, the bonding operation being accomplished in a rapid, efficient manner without loss of inter-bond orientation level. Numerous obvious variations from the disclosed details of nonwoven formation and manipulation may be wrought without departing from the spirit of the invention, as set forth in the appended claims.
What I claim and desire to protect by Letters Patent is:
1. A method for producing a coherent nonwoven fibrous sheet of improved tensile strength which comprises in combination:
(a) subjecting oriented thermoplastic filaments to a turbulent air stream to obtain a random arrangement of the filaments On a movable collecting screen therby forming a sheet of thermoplastic material having a multiplicity of cross-over points;
(b) subjecting the sheet of thermoplastic material to bonding at preferential cross-over points by indexing an ultrasonic horn with the movable collecting screen and ultrasonically bonding the sheet at said preferential cross-over points, and
(c) removing the sheet from the movable collecting screen whereby the coherent nonwoven fibrous sheet aforesaid obtained has an interbond orientation level substantially equivalent to that of the original oriented thermoplastic filaments.
2. The method of claim 1 wherein the preferential cross-over points are bonded substantially throughout the entire surface of the sheet with orientation of the interbond portions thereof substantially preserved.
3. The method of claim 1 wherein the sheet of thermoplastic material comprises oriented filaments of indefinite length.
4. The method of claim 1 wherein the sheet of thermoplastic material comprises oriented filaments of staple FOREIGN PATENTS length.
5. The methocl of claim 1 wherein the thermoplastic 1018971 2/1966 Great Bntam 156 73 mammal 18 180mm polypropylene- LELAND A. SEBASTIAN, Primary Examiner References Cit d 5 R. L. TATE, AssistantExaminer UNITED STATES PATENTS KR- 3,184,354 5/1965 Strother 156-73 156--166, 1 81 3,312,250 4/1967 Sirignano 15673X 3,437,783 4/1969 Lemelson 7520O 10
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US73122268A | 1968-05-22 | 1968-05-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3575752A true US3575752A (en) | 1971-04-20 |
Family
ID=24938611
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US731222A Expired - Lifetime US3575752A (en) | 1968-05-22 | 1968-05-22 | Nonwoven bonding method |
Country Status (1)
Country | Link |
---|---|
US (1) | US3575752A (en) |
Cited By (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3774157A (en) * | 1971-01-30 | 1973-11-20 | Ibm | Method of and arrangement for the distribution of timing pulses in an electronic data processor |
US3956044A (en) * | 1974-05-15 | 1976-05-11 | Surgicot, Inc. | Method and means for fabricating surgical sponges |
US4075046A (en) * | 1976-10-12 | 1978-02-21 | Thomas Taylor & Sons, Inc. | Tipped lace |
US4214612A (en) * | 1972-11-06 | 1980-07-29 | Wavin B.V. | Tube of non woven material for reversed osmosis |
US4259399A (en) * | 1978-08-31 | 1981-03-31 | Burlington Industries, Inc. | Ultrasonic nonwoven bonding |
US4311540A (en) * | 1978-08-31 | 1982-01-19 | Burlington Industries, Inc. | Ultrasonic bonding process |
US4394208A (en) * | 1981-08-06 | 1983-07-19 | Burlington Industries, Inc. | Ultrasonic bonding |
US4400227A (en) * | 1982-01-26 | 1983-08-23 | The Procter & Gamble Company | Dynamic ultrasonic laminating apparatus having post-bonding pressure roll, and concomitant method |
US4406720A (en) * | 1981-11-06 | 1983-09-27 | Burlington Industries, Inc. | Ultrasonic production of nonwovens |
US4419160A (en) * | 1982-01-15 | 1983-12-06 | Burlington Industries, Inc. | Ultrasonic dyeing of thermoplastic non-woven fabric |
US4659614A (en) * | 1985-07-18 | 1987-04-21 | Perfect Fit Industries | Ultrasonically bonded non-woven fabric |
US5087320A (en) * | 1990-05-18 | 1992-02-11 | Kimberly-Clark Corporation | Ultrasonic rotary horn having improved end configuration |
US5096532A (en) * | 1990-01-10 | 1992-03-17 | Kimberly-Clark Corporation | Ultrasonic rotary horn |
US5110403A (en) * | 1990-05-18 | 1992-05-05 | Kimberly-Clark Corporation | High efficiency ultrasonic rotary horn |
EP0535575A1 (en) * | 1991-09-30 | 1993-04-07 | Kimberly-Clark Corporation | Process for hydrosonically area thinning thin sheet materials |
EP0535581A1 (en) * | 1991-09-30 | 1993-04-07 | Kimberly-Clark Corporation | Process for hydrosonically microaperturing thin sheet materials |
US5269981A (en) * | 1991-09-30 | 1993-12-14 | Kimberly-Clark Corporation | Process for hydrosonically microaperturing |
US5336452A (en) * | 1992-09-23 | 1994-08-09 | Kimberly-Clark Corporation | Process for hydrosonically area embossing thin thermoplastic film materials |
US5370830A (en) * | 1992-09-23 | 1994-12-06 | Kimberly-Clark Corporation | Hydrosonic process for forming electret filter media |
US5443886A (en) * | 1991-09-30 | 1995-08-22 | Kimberly-Clark Corporation | Hydrosonically embedded soft thin film materials |
US5591298A (en) * | 1988-01-19 | 1997-01-07 | Kimberly-Clark Corporation | Machine for ultrasonic bonding |
US5735984A (en) * | 1994-11-08 | 1998-04-07 | Minnesota Mining And Manufacturing Company | Method of aperturing thin sheet materials |
US5879494A (en) * | 1996-09-23 | 1999-03-09 | Minnesota Mining And Manufacturing Company | Method of aperturing thin sheet materials |
US6057024A (en) * | 1997-10-31 | 2000-05-02 | Kimberly-Clark Worldwide, Inc. | Composite elastic material with ribbon-shaped filaments |
US6107220A (en) * | 1996-10-18 | 2000-08-22 | E. I. Du Pont De Nemours And Company | Rapid fabric forming |
US6413377B1 (en) | 1999-11-09 | 2002-07-02 | Astenjohnson, Inc. | Double layer papermaking forming fabric |
US6503602B1 (en) | 2000-07-26 | 2003-01-07 | Astenjohnson, Inc. | Dryer fabric with reinforced edges |
US20110061705A1 (en) * | 2009-09-11 | 2011-03-17 | Miasole | Rotatable junction box for a solar module |
US8123565B2 (en) * | 2009-06-30 | 2012-02-28 | Miasole | External electrical connectors for solar modules |
-
1968
- 1968-05-22 US US731222A patent/US3575752A/en not_active Expired - Lifetime
Cited By (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3774157A (en) * | 1971-01-30 | 1973-11-20 | Ibm | Method of and arrangement for the distribution of timing pulses in an electronic data processor |
US4214612A (en) * | 1972-11-06 | 1980-07-29 | Wavin B.V. | Tube of non woven material for reversed osmosis |
US3956044A (en) * | 1974-05-15 | 1976-05-11 | Surgicot, Inc. | Method and means for fabricating surgical sponges |
US4075046A (en) * | 1976-10-12 | 1978-02-21 | Thomas Taylor & Sons, Inc. | Tipped lace |
FR2367591A1 (en) * | 1976-10-12 | 1978-05-12 | Taylor Thomas & Sons Inc | METHOD AND APPARATUS |
US4259399A (en) * | 1978-08-31 | 1981-03-31 | Burlington Industries, Inc. | Ultrasonic nonwoven bonding |
US4311540A (en) * | 1978-08-31 | 1982-01-19 | Burlington Industries, Inc. | Ultrasonic bonding process |
US4394208A (en) * | 1981-08-06 | 1983-07-19 | Burlington Industries, Inc. | Ultrasonic bonding |
US4406720A (en) * | 1981-11-06 | 1983-09-27 | Burlington Industries, Inc. | Ultrasonic production of nonwovens |
US4419160A (en) * | 1982-01-15 | 1983-12-06 | Burlington Industries, Inc. | Ultrasonic dyeing of thermoplastic non-woven fabric |
US4400227A (en) * | 1982-01-26 | 1983-08-23 | The Procter & Gamble Company | Dynamic ultrasonic laminating apparatus having post-bonding pressure roll, and concomitant method |
US4659614A (en) * | 1985-07-18 | 1987-04-21 | Perfect Fit Industries | Ultrasonically bonded non-woven fabric |
US5591298A (en) * | 1988-01-19 | 1997-01-07 | Kimberly-Clark Corporation | Machine for ultrasonic bonding |
US5096532A (en) * | 1990-01-10 | 1992-03-17 | Kimberly-Clark Corporation | Ultrasonic rotary horn |
US5087320A (en) * | 1990-05-18 | 1992-02-11 | Kimberly-Clark Corporation | Ultrasonic rotary horn having improved end configuration |
US5110403A (en) * | 1990-05-18 | 1992-05-05 | Kimberly-Clark Corporation | High efficiency ultrasonic rotary horn |
EP0535581A1 (en) * | 1991-09-30 | 1993-04-07 | Kimberly-Clark Corporation | Process for hydrosonically microaperturing thin sheet materials |
US5269981A (en) * | 1991-09-30 | 1993-12-14 | Kimberly-Clark Corporation | Process for hydrosonically microaperturing |
US5314737A (en) * | 1991-09-30 | 1994-05-24 | Kimberly-Clark Corporation | Area thinned thin sheet materials |
US5443886A (en) * | 1991-09-30 | 1995-08-22 | Kimberly-Clark Corporation | Hydrosonically embedded soft thin film materials |
US5514308A (en) * | 1991-09-30 | 1996-05-07 | Kimberly-Clark Corporation | Method for hydrosonically embedding a material in a soft thin film material |
EP0535575A1 (en) * | 1991-09-30 | 1993-04-07 | Kimberly-Clark Corporation | Process for hydrosonically area thinning thin sheet materials |
US5336452A (en) * | 1992-09-23 | 1994-08-09 | Kimberly-Clark Corporation | Process for hydrosonically area embossing thin thermoplastic film materials |
US5370830A (en) * | 1992-09-23 | 1994-12-06 | Kimberly-Clark Corporation | Hydrosonic process for forming electret filter media |
US5735984A (en) * | 1994-11-08 | 1998-04-07 | Minnesota Mining And Manufacturing Company | Method of aperturing thin sheet materials |
US5879494A (en) * | 1996-09-23 | 1999-03-09 | Minnesota Mining And Manufacturing Company | Method of aperturing thin sheet materials |
US6107220A (en) * | 1996-10-18 | 2000-08-22 | E. I. Du Pont De Nemours And Company | Rapid fabric forming |
US6579815B1 (en) | 1996-10-18 | 2003-06-17 | E. I. Du Pont De Nemours And Company | Rapid fabric forming |
US6323145B1 (en) | 1997-10-17 | 2001-11-27 | E. I. Du Pont De Nemours And Company | Rapid fabric forming for penetration resistant fabric |
US6057024A (en) * | 1997-10-31 | 2000-05-02 | Kimberly-Clark Worldwide, Inc. | Composite elastic material with ribbon-shaped filaments |
US6413377B1 (en) | 1999-11-09 | 2002-07-02 | Astenjohnson, Inc. | Double layer papermaking forming fabric |
US6503602B1 (en) | 2000-07-26 | 2003-01-07 | Astenjohnson, Inc. | Dryer fabric with reinforced edges |
US8123565B2 (en) * | 2009-06-30 | 2012-02-28 | Miasole | External electrical connectors for solar modules |
US20110061705A1 (en) * | 2009-09-11 | 2011-03-17 | Miasole | Rotatable junction box for a solar module |
US8558102B2 (en) | 2009-09-11 | 2013-10-15 | Miasole | Rotatable junction box for a solar module |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3575752A (en) | Nonwoven bonding method | |
US3640786A (en) | Pile fabric and method of making the same | |
US3494821A (en) | Patterned nonwoven fabric of hydraulically entangled textile fibers and reinforcing fibers | |
KR100586280B1 (en) | High strength nonwoven fabric and process for making | |
US3966519A (en) | Method of bonding fibrous webs and resulting products | |
US3498874A (en) | Apertured tanglelaced nonwoven textile fabric | |
US4451314A (en) | Method for the manufacture of a fluffy, light-weight, soft nonwoven fabric | |
US4391866A (en) | Cut pile fabric with texturized loops | |
US3378429A (en) | Method and apparatus for treating material with sonic energy | |
US3730821A (en) | Interconnected network structure | |
JPS5935760B2 (en) | Ultrasonic cutting and welding equipment | |
US3817802A (en) | Ultrasonic sewing | |
KR850005025A (en) | Woven Fabrics with Ultrasonic Cutting Suture Edges and Apparatus and Method for Constructing the Edges | |
KR850005520A (en) | Manufacturing method of cylindrical fibrous structure | |
CN113226140B (en) | Vacuum cleaner filter bag with improved weld seam strength | |
GB1339952A (en) | Non-woven material | |
JPH08503271A (en) | Hydraulically entangled flash-spun webs with adjustable bulk and permeability | |
JPS5911707B2 (en) | Self-sized patterned bonded continuous filament web | |
US20030021970A1 (en) | Nonwoven comprising a batt of continuous filaments, its manufacturing process and its application as a cleaning cloth | |
US3708384A (en) | Pile fabric | |
US5972814A (en) | Reinforced nonwoven metal fabric | |
EP0105730B1 (en) | Open mesh belt bonded fabric | |
US3736209A (en) | Apparatus for making pile fabric | |
GB1495564A (en) | Non-woven fabric | |
US4119447A (en) | Method of reordering fibres in a web |