US3668054A - High bulk corrugated nonwoven fabric - Google Patents

High bulk corrugated nonwoven fabric Download PDF

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US3668054A
US3668054A US3668054DA US3668054A US 3668054 A US3668054 A US 3668054A US 3668054D A US3668054D A US 3668054DA US 3668054 A US3668054 A US 3668054A
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web
fabric
adhesive
fibers
drum
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Robert J Stumpf
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Kimberly Clark Corp
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Kimberly Clark Corp
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H11/00Non-woven pile fabrics
    • D04H11/04Non-woven pile fabrics formed by zig-zag folding of a fleece or layer of staple fibres, filaments, or yarns, strengthened or consolidated at the folds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24446Wrinkled, creased, crinkled or creped
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2904Staple length fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2738Coating or impregnation intended to function as an adhesive to solid surfaces subsequently associated therewith

Definitions

  • ABSTRACT A tough, high bulk, flexible fabric which has a grainy wrinkled texture with a multiplicity of transversely discontinuous furrows and ridges.
  • the fabric is somewhat elastic, especially in the machine direction, and comprises a corrugated web of initially alined textile fibers implanted in a continuous thin film of thermoplastic adhesive, the fiber-ad hesive web thereafter being corrugated into a multitude of furrows and grooves with irregularly rootand side-connected convolutions.
  • the fabric is produced by implanting the fibers into the thermoplastic adhesive film, adhering the resulting web onto an abherent heated surface, and advancing the surface against a gathering blade to corrugate the web and form irregularly rootand side-connected sinusoidal convolutions.
  • This invention relates to a high bulk corrugated nonwoven fabric, and in particular concerns the fabric and a method of making the same.
  • a primary object of the present invention is to provide a high bulk, flexible, fabric having a grainy wrinkled texture, the fabric being somewhat elastic especially in the machine direction.
  • the fabric has a grainy wrinkled texture somewhat reminiscent of animal skin, and somewhat resembles a tough creped rubber in appearance but not in weight.
  • a further object is to provide a high bulk flexible fabric from nonwoven textile material, which fabric offers desirable properties fromthe standpointv of durability, appearance, and high bulk rendering it useful in such applications as sound-absorbing disposable draperies, wall coverings, thermal insulation, wearing apparel,and the like.
  • Another object is to provide a method of making such material in a simple, convenient, and highly advantageous manner.
  • FIG. 1 is a schematic side elevation of one form of apparatus which may be employed to practice the method of the present invention
  • FIG. 2 is a fragmentary plan view of an illustrative web of the novel fabric, somewhat simplified and exaggerated for the sake of clarity of illustration
  • I FIGS. 3 and 4, respectively, are greatly enlarged, simplified, and somewhat exaggerated sections taken along the longitudinal lines 3-3 and the transverse lines 4-4 in FIG. 2;
  • H0. 5 is an enlarged schematic detail in side elevation of the fonning drum and gathering blade of the apparatus shown in FIG. 1;
  • FIG. 6 is a further enlarged schematic side elevation illustrating in'somewhat idealized fashion the sequence of corrugating' the fiber-adhesive web into a multitude of irregularly rootand side-connected sinusoidal convolutions;
  • FIG; 7 is an alternative fabric of the present invention in which the corrugated web is creped to form a substantially thicker fabric product
  • FIG. 8 is a greatly enlarged, simplified, and somewhat exaggerated section taken along the longitudinal lines 88 in FIG.
  • the fabric of the invention is a tough, high v bulk, flexible material having a grainy wrinkled texture with a multiplicity of transversely discontinuous furrows and ridges;
  • the fabric is somewhat elastic relative to conventional woven fabrics, and is especially elastic in the machine direction.
  • fabric itself comprises a corrugated web of initially alined textile fibers implanted in a continuous thin film of a thermoplasticadhes ive having an essentially constant thickness.
  • the resulting web-adhesive material is then corrugated to provide the multitude ,of furrows and grooves, which are irregularly connected near their roots and along their respective sides. 7 q
  • a web of alined textile fibers is implanted into a continuous thin film of thennoplastic adhesive; the resulting web is adhered onto an abherent surface heated sufiiciently to maintain the adhesive in a tacky state; the surface is advanced against a relatively moving gathering blade to loft or corrugate the web into the desired convolutions; and the corrugated web is withdrawn as a bulked fabric.
  • a-base web of textile fibers is first prepared and implanted into a continuous thinfilrn of a thermoplastic adhesive.
  • textile length, or'staple, fibers may be processed through conventional cotton card machinery to produce a carded web for the base web.
  • a carded web 50 to 70 percent of .the fibers may be oriented substantially parallel with the machine direction. It has been found, however, that a product having superiorcharacteristics has been obtained with the method of the present invention by using base webs having a higher percentage of the fibers alined with the machine direction, such as a highly drafted web in which, as a result of the drafting, to percentor more of the fibers are alined with the machine direction.
  • the fibers may be natural or synthetic, and either staple or monofilament, or various blends thereof.
  • suitable fibers include rayon, polyesters such as polyethylene terephthalate, the acrylics and modacrylics, and the olefins such as polypropylene. If desired, a blend of fibers may be used.
  • the particular adhesive selected is dependent upon the characteristics' of the textile fibers and the desired end use of the fabric.
  • the adhesive should be thermoplastic, and should soften at temperatures which will not degrade the particular fibrous-material being used.
  • the adhesive should also be applicable, to the base web by procedures which will not disarrange the fibrous structure of the web, be reactivatable by reheating in the subsequent adhesive gathering and partial consolidation stage of the process, and form a flexible, generally continuous, fil'rn in which the fabric web is secured by partial or complete embedding and adhesive attraction.
  • plastisols which are colloidal dispersions of synthetic resins in a suitable organicester plasticizer, and which under the influence of heat provide good binding power while remaining soft and flexible.
  • Those found particularly useful for incorporation in the product of the present invention include vinyl chloride polymers, and copolymers of vinyl chloride with other vinyl resins, plasticized by organic phthalates, sebacates, or adipates. These provide a fast curing plastisol adhesive characterized by relatively low viscosity, low migration tendencies, and minimum volatility. Such adhesives remain soft and flexible after curing, and may be reactivated by subsequent heating.
  • FIG. 1 schematically illustrates the apparatus for performing the method of the present invention in its preferred fonn.
  • This apparatus includes a webmaterial, and is usually in asornewhat forming section and an adhesive-compacting and web-corrugating section 30.
  • the individual fibers are drafted and spread out to form a flat striated web of substantially alined fibers as shown at 14.
  • the .web 14 is fed onto a supporting surface 15, the top of which v containsa uniform thin film of a thermoplastic adhesive.
  • the conveyor surface 15 comprises an endless conveyor belt treated on atleast its outer surface with a release agent.
  • a release agent for example, a belt comprises a woven glass, fiber with an abherent surface coating of polytetrafiuoroethylene resin.
  • Other release coatings are well known, and comprise such materials as silicones, fatty acid metal complexes, certain acrylic polymers, and the like.
  • Heatresistant films or thin metal sheets, which either are inherently abherent or else are treated with release agents, may also be used as the carrier or conveyor surface. 4
  • the adhesive in a'thin film of substantially uniform thicknessFilm thickness may be controlled as one of the. variables. of the process in orderto regulate the relative weight ratio of fiber web'to thermoplastic adhesive. Ordinarily, the optimum ratio is in-the" range'of about 0.2:] to about but these may be varied within. or outside the foregoing limits to r'eg'ulateth'e texture of the fabric. It is understood that the adhesive is actually on the underside of the belt'l5, which becomes the upper surfaceafte'r passing around the roll 17 .whereby the adhesive 16 directly contacts the fiber web 14.
  • The-belt or conveyor surface 15 is fed around the roll 17 at aspeed slightly in excess of the delivery speed of the final pair of rolls l3 in-order to maintain the web 14 under slight ten- 'web are retained in their alined and tensioned condition.
  • Drive rolls 18, 1 9jf0l'lh6 conveyor surface 15 are rotated to .drivefthe belt or conveyor surface 15 at a-speed sufficient to maintain the proper tension on the web 14.
  • the belt is fed through a nip formed between'aprinting roll 20.and a back-up roll 21 maintained in very lightpressure engagementwith each other.
  • the surface of the printing roll .20 is smooth, and as the roll surface rotates adhesiveZZ is pumped, from a tank not shown, to a reservoir defined in. part'by the roll and an inclined doctor blade 24 spacedslightly away from the roll surface.
  • adhesiveZZ is pumped, from a tank not shown, to a reservoir defined in. part'by the roll and an inclined doctor blade 24 spacedslightly away from the roll surface.
  • the blade 24 may be a wire-wrapped rod of the type commonly used in paint and other surface coating application, so that the thickness and spacing of the wires regulates, the amount of adhesive remaining on the roll 20 after it passes the doctor blade 24.
  • a relatively fluid adhesive'be selected so that substantially of the fibers are implanted or embedded in the-adhesive layer. It. is not essential that all fibers be entirely coated with adhesive, as excellent fabric products have been made which exhibit a top surface characteristic of fibers which have no, adhesive coating on their respective top portions.
  • a fly roll. 294 is disposed to provide wrap for the combined belt and web asthey travel around the drum 29to insure, so far as possible, complete embedment or at least substantial implantation of the fibers in the adhesive.'
  • the fibers of the web 14 are thusbonded together whileretaining their highly drafted and substantially alined condition in which they weredeposited onthe adhesive printed on the conveyor. surface or belt 15.
  • v t f After leaving the fiy roll 29a, the combined web 14 and surface or belt 15 are preferably passed over a drive roll 19 which also serves as a cooling drum. This chills the adhesive, thereby causing it to set and lose its tackiness.
  • the bonded web 14 is then stripped from the release coated surfa'ce of the belt by the guide roll 31 as theweb leaves the cooling drum 19.
  • the web-l4 is composed of a web of alined textile fibers implanted in 'a continuous thin film of hardened'thermoplastic adhesive, with both the adhesive and the complete fabric-adhesive web having an essentially constant thickness.
  • the-web 14 is then fed into an adhesive compacting or consolidating and fiber corrugating section 30 of the apparatus Shown in FIG. 1.
  • the web 14 continues directlyfrorn the web-forming section 10 to the section 30.
  • the web 14 discharged from thefsection 10 may be rolled up for storage or transport and then subsequentlyunrolled and. fed into the section 30.
  • various other processing treatments may be employed before the web is admitted into the section 30, such as for example printing, dyeing, or the like.
  • the web 14 while still'under tension-is fed around an idler roll 32 and onto the surface of a heated forming drum 37.
  • the fonning drum 37 is maintained at a temperature which will soften the adhesive toa tacky state so that it adheres to the drum surface.
  • Either the entire drum or the cylindrical surface of the drum 37 is made of an abherent material, or one which has an abherent coating. ln its preferred embodiment, the
  • drum 37 is made of a highly polished chromium plated surface a substantial distance around the drum 37, that is, have a relatively high degree of wrap, so as to provide adequate residence and heating time.
  • the drum 37 surface is moved relative to a gathering blade to corrugate the web into a multitude of irregularly rootand side-connected sinusoidal convolutions. This is accomplished by re-forrning the fiber-adhesive web 14 by the cooperative action of the heated drum 37 and a gathering blade 38, parallel to the axis of the drum 37, and having a flat edge 39 (FIG. 5).
  • the blade edge 39 corrugates the web into the desired sinusoidal convolutions and brings adjacent roots, and occasionally adjacent side portions of the convolutions, into contact whereby the adhesive secures the contacting portions together.
  • the thus-corrugated web 14, identified as a fabric 40 then leaves the blade edge 39 onto a flat take-off surface 41 (FIG. 5) and a discharge conveyor 42 (FIG. 1).
  • FIGS. 5 and 6 the method of corrugating the fiber-adhesive web 14 into the desired connected convolutions will be explained in greater detail in connection with an illustrative sequence of the corrugating operation.
  • the series of views in this Figure illustrates how the web is formed into convolutions.
  • the heated drum carries the fiber-adhesive web 14 against the gathering blade edge 39, increments of the web 14 abut against the edge.
  • alpha angles of from about 20 to 120 may be employed, but the optimum range narrows depending upon the various factors discussed. For most applications, an initial alpha angle of between about 50 to 74 should be selected, and the angle varied to provide the required fabric thickness. Usually, so long as the alpha angle is less than about 90, fabric thicknesses within the range of about one sixty-fourth-inch to nearly three-eighth-inch may be produced.
  • the adhesive is in a somewhat tacky condition.
  • the roots of the respective loops that is, those areas near the original bunching A of the web, come in contact with each other and are adhesively joined.
  • This joining is usually not continuous over the entire width of the drum 37, and indeed appears to be quite irregular, but since the corrugated fabric is usually stretched immediately after leaving the area of the edge 39, irregular contact at the respective roots is not only permissible but is actually desired.
  • the sides of the adjacent loops P are likewise in contact with each other during part of the loop-forming steps.
  • the loops are irregularly interconnected at their roots and sides. Defining, in cross-section, a series of sinusoidal convolutions (FIG. 3), these loops contribute a light-weight, high bulk, fabric product.
  • the furrows and ridges on the creped web product 40 are irregular and discontinuous along a direction transverse to the machine direction of the apparatus.
  • the resulting furrows and ridges provide the grainy wrinkled texture illustrated in FIG. 2, and in this regard attention is invited to FIG. 4 illustrating the randomness of an individual sinusoidal wrinkle.
  • An additional variable in the process of the invention is the speed at which the corrugated web 40 is withdrawn, or taken away, from the edge 39.
  • the optimal ratio of the surface speed of the heating drum 37 to the take-away speed should be maintained in the range of from about 5:1 to about 10:1, with a ratio of about 7 to 8:1 being preferred.
  • the slowly withdrawn product of FIGS. 7 and 8 has exceptionally high bulk, and is usually from three to four times the thickness of an uncreped product as depicted in FIG. 2.
  • a fabric is obtained which is sufi'rciently thick to serve as a protective packaging medium.
  • the corrugated web 40 is withdrawn from the blade edge 39, advantageously immediately after corrugation has been effected.
  • the fabric exit end of the conveyor 42 may be provided with a roll 44 to form a nip, and
  • the take-away surface 41 may likewise have an abherent surface to prevent or minimize adhesion of the still hot and tacky adhesive.
  • the belt of the conveyor 52 is desirably cooled, again to minimize adherence, by streams of chilled air blown against the underside of the belt from a suitably placed air nozzle 54. Preliminary heating or cooling of the conveyor may be effected by a nozzle 43 immediately adjacent the blade edge 39.
  • EXAMPLE I In this EXAMPLE, a high bulk'uncreped product as depicted in FIG. 2 is prepared.
  • the apparatus of FIG. 1 is employed.
  • Rayon 40 in the form of three inch staple at 1.5 denier is used as the textile fiber, while the adhesive is a polyvinyl chloride plastisol.
  • Plastisol is formulated from about parts by weight of Geon l35 f7 polyvinyl chloride resin (BF; Goodrich, Akron, Ohio), about 60 parts of GP-26l dioctyl phthalate plasticizer (Goodrich),
  • the weight of thebase fiber web alone was about 56 grams per square yard, that of the adhesive alone being about 7574 grams per'square yard.
  • the adhesive curing and preheat drum 29 in the first stage of forming the web was'maintained at about 300 F.
  • the base web 14 was thus carried to the heating drum 37 at a surface speed of 65 feet per minute.
  • the roll 37 temperature was about 250 F.
  • the gathering blade'38 was positioned at an angle of 34 and maintained against the heating drum 37 with a pressure of about 28 psi.
  • the drum nine inches in diameter, was internally heated and maintained at a temperature of about 250 F.
  • the take-away ratio that is, surface speed around the drum divided by take-away speed in consistent units, was about 7-,.
  • Adhesive was applied to the rotogravure roll 20 with a No. 60 Meyer rod at the end of the doctor blade 24.
  • the resultingproduct had a final weight of about 600 grams per yard and was about one-sixteenth-inch-thick. It exhibited a pleasing drape, was slightly porous, and displayed some resiliency in the transverse direction and more in the machine direction. 1
  • resulting material had an animalskin like texture and was an ideal material for womens purses.
  • the finished material weighed 1,204 grams per square yard. g
  • a tough, high-bulk, flexible fabric having a grainy mnkled texture with a multiplicity of transversely discontinuous furrows and ridges, said fabric being somewhat elastic especially in the machine direction, said fabric comprising:
  • said continuous thin film of adhesive with implanted fibers having been longitudinally gathered while said adhesive is tacky to produce transversely discontinuous convolutions wherein the roots and sides of said convolutions are randomly connected by means of the adhesive, said random root and side connections providing added strength and durability.

Abstract

A tough, high bulk, flexible fabric is provided which has a grainy wrinkled texture with a multiplicity of transversely discontinuous furrows and ridges. The fabric is somewhat elastic, especially in the machine direction, and comprises a corrugated web of initially alined textile fibers implanted in a continuous thin film of thermoplastic adhesive, the fiber-adhesive web thereafter being corrugated into a multitude of furrows and grooves with irregularly root- and side-connected convolutions. The fabric is produced by implanting the fibers into the thermoplastic adhesive film, adhering the resulting web onto an abherent heated surface, and advancing the surface against a gathering blade to corrugate the web and form irregularly rootand side-connected sinusoidal convolutions.

Description

United States Patent Stuinpf I 3,668,054 1 June 6, 1972 22 Filed:
[541 HIGH BULK CORRUGATED NONWOVEN FABRIC [72] Inventor: Robert J. Stumpf, Appleton, Wis.
[73] Assignee: Kimberly-Clark Corporation, Neenah,
Wis.
Mar. 31, 1970 21 Appl. No.1 24,197
[52] U.S.Cl "161/128, 156/183, 161/132,
. 161/133 511 1111.0. 1/00,D04h3/00 581 Field ofSearch ..l61/l28,129,132,133,134, 161/135; 156/183, 205, 206, 207, 210
[56] References Cited UNITED STATES PATENTS 3,236,718 2/1966 -C0h1'| etal. ..'..l61/128 Walton ..161/l28 ux 2,407,548 9/1946 Goldman ..l6l/l56X Primary Examiner-Robert F. Burnett Assistant Examiner-Raymond O. Linker, Jr.
. Attorney-Wolfe, Hubbard, Leydig, Voit & Osann [57] ABSTRACT A tough, high bulk, flexible fabric is provided which has a grainy wrinkled texture with a multiplicity of transversely discontinuous furrows and ridges. The fabric is somewhat elastic, especially in the machine direction, and comprises a corrugated web of initially alined textile fibers implanted in a continuous thin film of thermoplastic adhesive, the fiber-ad hesive web thereafter being corrugated into a multitude of furrows and grooves with irregularly rootand side-connected convolutions. The fabric is produced by implanting the fibers into the thermoplastic adhesive film, adhering the resulting web onto an abherent heated surface, and advancing the surface against a gathering blade to corrugate the web and form irregularly rootand side-connected sinusoidal convolutions.
5 Claims; 8 DrawingiFigures SHEET 2 OF 2 2 MM MM Z 4/ w/ #6 WJ W zm/ w 1 y, 7 WW fi W \Ull) J. E
HIGH BULKCORRUGATED NONWOVEN FABRIC CROSS-REFERENCE TO-RELATED APPLICATIONS Robert J. Stumpf, U.S. application, Ser. Nos. 498,929 filed Oct. 20, 1965, now abandoned, 553,483 now U.S. Pat. No. 3,553,065, 769,959, filed Oct.23, 1968, now abandoned.
' v I DESCRIPTION or THE INVENTION This invention relates to a high bulk corrugated nonwoven fabric, and in particular concerns the fabric and a method of making the same.
. A primary object of the present invention is to provide a high bulk, flexible, fabric having a grainy wrinkled texture, the fabric being somewhat elastic especially in the machine direction. The fabric has a grainy wrinkled texture somewhat reminiscent of animal skin, and somewhat resembles a tough creped rubber in appearance but not in weight. A further object is to provide a high bulk flexible fabric from nonwoven textile material, which fabric offers desirable properties fromthe standpointv of durability, appearance, and high bulk rendering it useful in such applications as sound-absorbing disposable draperies, wall coverings, thermal insulation, wearing apparel,and the like.
Another object is to provide a method of making such material in a simple, convenient, and highly advantageous manner. I 7
Other and further aims, advantages, and objects of the invention will become apparent as the description thereof proceeds, which description is to be taken with reference m1 the attached drawings inwhich:
' FIG. 1 is a schematic side elevation of one form of apparatus which may be employed to practice the method of the present invention; l FIG. 2 is a fragmentary plan view of an illustrative web of the novel fabric, somewhat simplified and exaggerated for the sake of clarity of illustration; I FIGS. 3 and 4, respectively, are greatly enlarged, simplified, and somewhat exaggerated sections taken along the longitudinal lines 3-3 and the transverse lines 4-4 in FIG. 2;
H0. 5 is an enlarged schematic detail in side elevation of the fonning drum and gathering blade of the apparatus shown in FIG. 1;
FIG. 6 is a further enlarged schematic side elevation illustrating in'somewhat idealized fashion the sequence of corrugating' the fiber-adhesive web into a multitude of irregularly rootand side-connected sinusoidal convolutions;
FIG; 7 is an alternative fabric of the present invention in which the corrugated web is creped to form a substantially thicker fabric product; and
FIG. 8 is a greatly enlarged, simplified, and somewhat exaggerated section taken along the longitudinal lines 88 in FIG.
Broadly stated, the fabric of the invention is a tough, high v bulk, flexible material having a grainy wrinkled texture with a multiplicity of transversely discontinuous furrows and ridges; The fabric is somewhat elastic relative to conventional woven fabrics, and is especially elastic in the machine direction. The
fabric itself comprises a corrugated web of initially alined textile fibers implanted in a continuous thin film of a thermoplasticadhes ive having an essentially constant thickness. The resulting web-adhesive material is then corrugated to provide the multitude ,of furrows and grooves, which are irregularly connected near their roots and along their respective sides. 7 q
To manufacture the inventive fabric, a web of alined textile fibers is implanted into a continuous thin film of thennoplastic adhesive; the resulting web is adhered onto an abherent surface heated sufiiciently to maintain the adhesive in a tacky state; the surface is advanced against a relatively moving gathering blade to loft or corrugate the web into the desired convolutions; and the corrugated web is withdrawn as a bulked fabric.
I Various parameters, to be discussed further below, may be chosen to alterthe nature and characteristics of the product. Thus, selection'of fibers and adhesive, weight and denier of the fibers, thickness (or weight per unit area) of the adhesive, andthe like maybe chosen with a view. toward regulating the properties of the fabric. Additionally, processing conditions such as gathering blade angle-with'respect to the advancing web-containing surface, corrugated web withdrawal conditions (take-away ratio), and the like permit further alteration ofthefabric. 4
ln practicing the method of the present invention in its preferred form, a-base web of textile fibers is first prepared and implanted into a continuous thinfilrn of a thermoplastic adhesive.
Different procedures may be-used in preparing the base web. For example, textile length, or'staple, fibers may be processed through conventional cotton card machinery to produce a carded web for the base web. In such a carded web 50 to 70 percent of .the fibers may be oriented substantially parallel with the machine direction. It has been found, however, that a product having superiorcharacteristics has been obtained with the method of the present invention by using base webs having a higher percentage of the fibers alined with the machine direction, such as a highly drafted web in which, as a result of the drafting, to percentor more of the fibers are alined with the machine direction.
A variety of different textile fibers, fiber lengths, and fiber deniers are suitable for the present invention. The fibers may be natural or synthetic, and either staple or monofilament, or various blends thereof. Among-the suitable fibers are included rayon, polyesters such as polyethylene terephthalate, the acrylics and modacrylics, and the olefins such as polypropylene. If desired, a blend of fibers may be used.
While various known adhesives may be employed, it should be recognized that the particular adhesive selected is dependent upon the characteristics' of the textile fibers and the desired end use of the fabric. The adhesive should be thermoplastic, and should soften at temperatures which will not degrade the particular fibrous-material being used. in addition, the adhesive should also be applicable, to the base web by procedures which will not disarrange the fibrous structure of the web, be reactivatable by reheating in the subsequent adhesive gathering and partial consolidation stage of the process, and form a flexible, generally continuous, fil'rn in which the fabric web is secured by partial or complete embedding and adhesive attraction. I
While various well knownadhesives" maybe employed in the foregoing process, advantages reside" in the use of plastisols, which are colloidal dispersions of synthetic resins in a suitable organicester plasticizer, and which under the influence of heat provide good binding power while remaining soft and flexible. Those found particularly useful for incorporation in the product of the present invention include vinyl chloride polymers, and copolymers of vinyl chloride with other vinyl resins, plasticized by organic phthalates, sebacates, or adipates. These provide a fast curing plastisol adhesive characterized by relatively low viscosity, low migration tendencies, and minimum volatility. Such adhesives remain soft and flexible after curing, and may be reactivated by subsequent heating.
It has been found that other adhesive systems may be employed in particular circumstances, such as the organisols utilizing resins such as the vinyl chloride polymers and copolymers. Other adhesives may be employed provided they satisfy the indicated characteristics in the base web forming stage and meet the product requirements of the final fabric. For example, emulsions of thermoplastic resins such as acrylics and rubber-like compounds illustrated by acrylonitrile-butadiene-styrene usually have the requisite properties to serve as the bonding adhesive for the web.
Tuming now to the drawings, FIG. 1 schematically illustrates the apparatus for performing the method of the present invention in its preferred fonn. This apparatus includes a webmaterial, and is usually in asornewhat forming section and an adhesive-compacting and web-corrugating section 30.
pair being driven by appropriate gearing at a peripheral rate of speed slightly faster than the rate of the preceding pair. As the juxtaposed sliverspass through the draw frame 12, the individual fibers are drafted and spread out to form a flat striated web of substantially alined fibers as shown at 14. The .web 14 is fed onto a supporting surface 15, the top of which v containsa uniform thin film of a thermoplastic adhesive.
- in the depictedembodiment, the conveyor surface 15 comprises an endless conveyor belt treated on atleast its outer surface with a release agent. One example of such a belt comprises a woven glass, fiber with an abherent surface coating of polytetrafiuoroethylene resin. Other release coatings are well known, and comprise such materials as silicones, fatty acid metal complexes, certain acrylic polymers, and the like. Heatresistant films or thin metal sheets, which either are inherently abherent or else are treated with release agents, may also be used as the carrier or conveyor surface. 4
Prior to the time the web 14 is picked up by the belt 15, the latter has been .coated on its web-contacting surface with a flexible thermoplastic. adhesive" in a'thin film of substantially uniform thicknessFilm thickness may be controlled as one of the. variables. of the process in orderto regulate the relative weight ratio of fiber web'to thermoplastic adhesive. Ordinarily, the optimum ratio is in-the" range'of about 0.2:] to about but these may be varied within. or outside the foregoing limits to r'eg'ulateth'e texture of the fabric. It is understood that the adhesive is actually on the underside of the belt'l5, which becomes the upper surfaceafte'r passing around the roll 17 .whereby the adhesive 16 directly contacts the fiber web 14.
{The-belt or conveyor surface 15 is fed around the roll 17 at aspeed slightly in excess of the delivery speed of the final pair of rolls l3 in-order to maintain the web 14 under slight ten- 'web are retained in their alined and tensioned condition. Drive rolls 18, 1 9jf0l'lh6 conveyor surface 15 are rotated to .drivefthe belt or conveyor surface 15 at a-speed sufficient to maintain the proper tension on the web 14.
ln the method shown fQr'appIying adhesive to the belt or conveyor surface 15, the belt ,is fed through a nip formed between'aprinting roll 20.and a back-up roll 21 maintained in very lightpressure engagementwith each other. The surface of the printing roll .20 is smooth, and as the roll surface rotates adhesiveZZ is pumped, from a tank not shown, to a reservoir defined in. part'by the roll and an inclined doctor blade 24 spacedslightly away from the roll surface. Thus, as the print-- ingroll20 rotates (in a counterclockwise direction as viewed in FlG. .l-), t.he roll surface is coated with adhesive 22, excess adhesive is removed by the doctor blade 24 and a metered amount of adhesive is then transferred tothe underside of the release coated belt .16. The blade 24 may be a wire-wrapped rod of the type commonly used in paint and other surface coating application, so that the thickness and spacing of the wires regulates, the amount of adhesive remaining on the roll 20 after it passes the doctor blade 24. 3
"Since thesurface of the belt or conveyor surface 15 is treated with arelease coating, the adhesive remains substantially on the surface with no penetration to the interior. The adhesive is applied as a cold viscous (3,5004,000 c.p.s.) tacky condition before his curedon the roll 19. r
' 'The printed belt is drawn from the printing nip around the roll 17 positioned closely adjacent the output end of the draw 7 20:1-in 'termsof weight of adhesive per unit weightof fiber,
sion. imagine individual highly drafted fibers constituting the I frame 12, and, as stated above, travels at a speed slightly in exferential. Thiscontinuous tension preventsthefibersin the web from losing theirhi'ghly drafied and alined condition.
Under optimum practice,the-fiber web 14 will have the individual fibers positioned side by-side with-no spaces between fibers. in practice however, this optimurn is difficult or impossible to achieve. Accordingly, there'zinevitably are 'ar'eas-of the web 14 which, on a microscopicscale, have no fibers present and others where theweb.is=several fibers thick. Neither condition is .entirely disadvantageoustopracticing the invention, and in fact there is sufiicient versatility in both the present productandprocess such that fiber webs with, on the one hand, widev spacing between individual fibers or, on, the other, webs of many fibers thick,- may be accommodated. In the latter case, it is desirable that a relatively fluid adhesive'be selected so that substantially of the fibers are implanted or embedded in the-adhesive layer. It. is not essential that all fibers be entirely coated with adhesive, as excellent fabric products have been made which exhibit a top surface characteristic of fibers which have no, adhesive coating on their respective top portions. t I
Following deposition of the web component 14 on the adhesive printed belt or conveyorsurface 15,'-the belt is drawn around a heated drum 29 where fusing any necessary curing of the adhesive is substantially completed'whil'e the web 14 is maintained in finn contact with theadhe'sive to bond the individual fibers. To insure effective heating and fusing of ;.the adhesive, it is desirable-that travel of the combined belt and web be around a substantial portion of the heated drum 29, In
the illustrated embodiment, a fly roll. 294 is disposed to provide wrap for the combined belt and web asthey travel around the drum 29to insure, so far as possible, complete embedment or at least substantial implantation of the fibers in the adhesive.' The fibers of the web 14 are thusbonded together whileretaining their highly drafted and substantially alined condition in which they weredeposited onthe adhesive printed on the conveyor. surface or belt 15. v t f After leaving the fiy roll 29a, the combined web 14 and surface or belt 15 are preferably passed over a drive roll 19 which also serves as a cooling drum. This chills the adhesive, thereby causing it to set and lose its tackiness. The bonded web 14 is then stripped from the release coated surfa'ce of the belt by the guide roll 31 as theweb leaves the cooling drum 19.
At this stage of'the process, the web-l4 is composed of a web of alined textile fibers implanted in 'a continuous thin film of hardened'thermoplastic adhesive, with both the adhesive and the complete fabric-adhesive web having an essentially constant thickness. In this condition, the-web 14 is then fed into an adhesive compacting or consolidating and fiber corrugating section 30 of the apparatus Shown in FIG. 1. As portrayed,the web 14 continues directlyfrorn the web-forming section 10 to the section 30. lt should be appreciated, however, that the web 14 discharged from thefsection 10 may be rolled up for storage or transport and then subsequentlyunrolled and. fed into the section 30. Also, if'desired various other processing treatments may be employed before the web is admitted into the section 30, such as for example printing, dyeing, or the like. f
The web 14 while still'under tension-is fed around an idler roll 32 and onto the surface of a heated forming drum 37. The fonning drum 37 is maintained at a temperature which will soften the adhesive toa tacky state so that it adheres to the drum surface. Either the entire drum or the cylindrical surface of the drum 37 is made of an abherent material, or one which has an abherent coating. ln its preferred embodiment, the
drum 37 is made of a highly polished chromium plated surface a substantial distance around the drum 37, that is, have a relatively high degree of wrap, so as to provide adequate residence and heating time. 1
As the web 14 is fed onto the drum 37, heat from the drum surface reactivates and re-softens the adhesive on the underside of the web 14, causing it to become tacky. The web accordingly adheres slightly to the drum surface, thereby maintaining the web under constant tension.
In keeping with the invention, the drum 37 surface is moved relative to a gathering blade to corrugate the web into a multitude of irregularly rootand side-connected sinusoidal convolutions. This is accomplished by re-forrning the fiber-adhesive web 14 by the cooperative action of the heated drum 37 and a gathering blade 38, parallel to the axis of the drum 37, and having a flat edge 39 (FIG. 5). The blade edge 39 corrugates the web into the desired sinusoidal convolutions and brings adjacent roots, and occasionally adjacent side portions of the convolutions, into contact whereby the adhesive secures the contacting portions together. The thus-corrugated web 14, identified as a fabric 40, then leaves the blade edge 39 onto a flat take-off surface 41 (FIG. 5) and a discharge conveyor 42 (FIG. 1).
Turning now to FIGS. 5 and 6, the method of corrugating the fiber-adhesive web 14 into the desired connected convolutions will be explained in greater detail in connection with an illustrative sequence of the corrugating operation.
Referring to FIG. 6, the series of views in this Figure illustrates how the web is formed into convolutions. As the heated drum carries the fiber-adhesive web 14 against the gathering blade edge 39, increments of the web 14 abut against the edge.
At this stage, pressure is being applied to the gathering blade 38 in a direction radially inward of the drum 37 so that essentially all of the adhesive is being scraped from the abherent surface of the drum.
As rotation of the drum 37 continues, successive increments of the web 14 are being brought against the edge 39. These increments are unable to pass beyond the edge 39, and accordingly begin to bunch up, as shown at A in the second view of FIG. 6. While rotation of the drum 37 continues further, the bunching up of the web 14 increment continues, with A gradually forming an open loop P. The loop increases in size as the drum 37 rotates further, but for reasons which are not clear there appears to be a rather definite size of loop P which can form before loop growth terminates and the fomration of a new loop begins. I 7 One of the major variables in determining loop size, and
consequent fabric thickness, is the angle alpha (FIG. 5)
formed between the blade edge 39 and a line T tangent to the surface of the drum 37 at the point of blade contact. The optimum blade angle is generally best determined empirically,
depending upon the desired fabric thickness and the interrelationship among fiber stiffness, type and thickness of adhesive, and temperature of the drum 37. Usually alpha angles of from about 20 to 120 may be employed, but the optimum range narrows depending upon the various factors discussed. For most applications, an initial alpha angle of between about 50 to 74 should be selected, and the angle varied to provide the required fabric thickness. Usually, so long as the alpha angle is less than about 90, fabric thicknesses within the range of about one sixty-fourth-inch to nearly three-eighth-inch may be produced.
Returning to FIG. 6, as the loops P form, the adhesive is in a somewhat tacky condition. As a result, the roots of the respective loops, that is, those areas near the original bunching A of the web, come in contact with each other and are adhesively joined. This joining is usually not continuous over the entire width of the drum 37, and indeed appears to be quite irregular, but since the corrugated fabric is usually stretched immediately after leaving the area of the edge 39, irregular contact at the respective roots is not only permissible but is actually desired.
Further, the sides of the adjacent loops P are likewise in contact with each other during part of the loop-forming steps.
To the extent that adhesive has penetrated to the outside of the respective loops P, these outside surfaces also are irregularly connected to each other at randomly, spaced intervals. The combination of non-regularadhesive connection at the roots of the successive loops P and along thesides of adjacent loops permits the fabric product, after slight stretching, to exhibit its creped-rubber or animal-like skin appearance, as well as adding to the strength and durability of the fabric.
In the final (right) view in FIG. 6, the loops are irregularly interconnected at their roots and sides. Defining, in cross-section, a series of sinusoidal convolutions (FIG. 3), these loops contribute a light-weight, high bulk, fabric product. By reason of the random nature of the loop-forming steps depicted in FIG. 6, the furrows and ridges on the creped web product 40 are irregular and discontinuous along a direction transverse to the machine direction of the apparatus. The resulting furrows and ridges provide the grainy wrinkled texture illustrated in FIG. 2, and in this regard attention is invited to FIG. 4 illustrating the randomness of an individual sinusoidal wrinkle.
An additional variable in the process of the invention is the speed at which the corrugated web 40 is withdrawn, or taken away, from the edge 39. With'the blade 38 having an edge alpha angle within the preferred range, and assuming the takeaway surface 41 (FIG. 5) is cooled to substantially an ambient temperature, the optimal ratio of the surface speed of the heating drum 37 to the take-away speed should be maintained in the range of from about 5:1 to about 10:1, with a ratio of about 7 to 8:1 being preferred. By decreasing the ratio, or in other words by increasing the fabric take-away speed, a more open final product is obtained, where the loops or convolutions P tend to be pulled apart. At extremely low ratios, or in other words at take-away speeds approaching the peripheral speed of the drum 37, a point is ultimately reached at which no gathering at the edge 39, and consequent loop formation, occurs.
On the other hand, by increasing the take-away ratio, that is, by slowing down the fabric take-away speed, an interesting effect is produced that is illustrated by the products depicted in FIGS. 7 and 8. Here the corrugated fabric 40 has actually been permitted to crepe by establishing corrugations of the already convoluted and corrugated web.
The slowly withdrawn product of FIGS. 7 and 8 has exceptionally high bulk, and is usually from three to four times the thickness of an uncreped product as depicted in FIG. 2. Thus, merely by utilizing a slow withdrawal rate, as opposed to a rapid one, a fabric is obtained which is sufi'rciently thick to serve as a protective packaging medium.
Returning to FIG. 1, the corrugated web 40 is withdrawn from the blade edge 39, advantageously immediately after corrugation has been effected. The fabric exit end of the conveyor 42 may be provided with a roll 44 to form a nip, and
with a pair of rolls 45 forming a second nip. Drawing is accomplished by driving the rolls 45 at a higher speed in order to open up the corrugations somewhat. If desired, the take-away surface 41 may likewise have an abherent surface to prevent or minimize adhesion of the still hot and tacky adhesive. Further, the belt of the conveyor 52 is desirably cooled, again to minimize adherence, by streams of chilled air blown against the underside of the belt from a suitably placed air nozzle 54. Preliminary heating or cooling of the conveyor may be effected by a nozzle 43 immediately adjacent the blade edge 39.
The invention will be illustrated further in conjunction with specific embodiments directed to the illustrative preparation of high bulk fabrics according to the invention.
EXAMPLE I In this EXAMPLE, a high bulk'uncreped product as depicted in FIG. 2 is prepared.
The apparatus of FIG. 1 is employed. Rayon 40, in the form of three inch staple at 1.5 denier is used as the textile fiber, while the adhesive is a polyvinyl chloride plastisol. Plastisol is formulated from about parts by weight of Geon l35 f7 polyvinyl chloride resin (BF; Goodrich, Akron, Ohio), about 60 parts of GP-26l dioctyl phthalate plasticizer (Goodrich),
about 2.5 parts of Cab-O-Sil pyrogenic silica (Cabot Corp.,
Boston, Mass), and sufficient mineral spirits to bring the viscosity into the desired range (generally from about 3 to percent by weight based on total weight of other components) to achieve a viscosity, by Brookfield viscometer with a No. 4
- spindle at rpm. of about 3,800 c.p.s.
The weight of thebase fiber web alone was about 56 grams per square yard, that of the adhesive alone being about 7574 grams per'square yard.
The adhesive curing and preheat drum 29 in the first stage of forming the web was'maintained at about 300 F. and
operated at a surface speed of 65 feet per minute. The base web 14 was thus carried to the heating drum 37 at a surface speed of 65 feet per minute. The roll 37 temperature was about 250 F.
The gathering blade'38 was positioned at an angle of 34 and maintained against the heating drum 37 with a pressure of about 28 psi. The drum, nine inches in diameter, was internally heated and maintained at a temperature of about 250 F. The take-away ratio, that is, surface speed around the drum divided by take-away speed in consistent units, was about 7-,.
Adhesive was applied to the rotogravure roll 20 with a No. 60 Meyer rod at the end of the doctor blade 24.
The resultingproduct had a final weight of about 600 grams per yard and was about one-sixteenth-inch-thick. It exhibited a pleasing drape, was slightly porous, and displayed some resiliency in the transverse direction and more in the machine direction. 1
EXAMPLE n In this EXAMPLE, using the apparatus of EXAMPLE I, a
creped product as depicted in FIGS. 7 and 8 was made. The
resulting material had an animalskin like texture and was an ideal material for womens purses.
All process conditions were as set forth in EXAMPLE 1, except that the original adhesive weight was 73 grams per square yard, the original fiber weight was 7 grams per square yard,
and the take-away ratio was roughly 15 so as to re-gather the product. The finished material weighed 1,204 grams per square yard. g
Thus it is apparent that there has been provided, according to the invention, an exceptional product and method which fully satisfy the objects set forth earlier. While the'invention has been described in conjunction with specific embodiments, it is evident that many alternatives, modifications, and variations will be apparent to those skilled in the art in view of the foregoing description. Accordingly, it is intended to embrace all such alternatives, modifications, and variations as fall within the spirit and broad scope of the appended claims.
I claim as my invention:
1. A tough, high-bulk, flexible fabric having a grainy mnkled texture with a multiplicity of transversely discontinuous furrows and ridges, said fabric being somewhat elastic especially in the machine direction, said fabric comprising:
a corrugated web ofinitialiy aligned textile fibers implanted in a continuous thin film of flexible thermoplastic adhesive having an essentially constant thickness,
said continuous thin film of adhesive with implanted fibers having been longitudinally gathered while said adhesive is tacky to produce transversely discontinuous convolutions wherein the roots and sides of said convolutions are randomly connected by means of the adhesive, said random root and side connections providing added strength and durability.
2. A fabric as defined in claim 1 wherein said fabric has been creped to provide a creped structure superposed on said corrugations. g
3. Fabric of claim 1 wherein said textile fibers are fibers of staple length.
4. Fabric of claim 1 wherein said textile fibers are synthetic plastisol. I

Claims (4)

  1. 2. A fabric as defined in claim 1 wherein said fabric has been creped to provide a creped structure superposed on said corrugations.
  2. 3. Fabric of claim 1 wherein said textile fibers are fibers of staple length.
  3. 4. Fabric of claim 1 wherein said textile fibers are synthetic plastic monofilaments.
  4. 5. Fabric of claim 1 wherein said thermoplastic adhesive is a plastisol.
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Cited By (25)

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US3775230A (en) * 1971-11-01 1973-11-27 R Hilton Rigid laminate of creped secondary fiber sheets
US4078958A (en) * 1974-06-27 1978-03-14 Cie Des Ets. De La Risle-Papeteries De Pont-Audemer Manufacture of a wiping article having a paper base
US5151240A (en) * 1989-09-06 1992-09-29 Kanebo, Ltd. Leather-like material having excellent water vapor permeability and suppleness and its manufacture
US5763041A (en) * 1995-12-21 1998-06-09 Kimberly-Clark Worldwide, Inc. Laminate material
US5931823A (en) * 1997-03-31 1999-08-03 Kimberly-Clark Worldwide, Inc. High permeability liner with improved intake and distribution
EP1050612A1 (en) * 1999-05-07 2000-11-08 Japan Absorbent Technology Institute Bulky non-woven fabric, method for manufacturing it and absorbent products using such fabric
US6150002A (en) * 1997-10-31 2000-11-21 Kimberly-Clark Worldwide, Inc. Creped nonwoven liner with gradient capillary structure
US6264776B1 (en) 1999-09-15 2001-07-24 Kimberly-Clark Worldwide, Inc. Method for forming an absorbent structure having vertically orientated absorbent members
US6413338B1 (en) 1999-09-15 2002-07-02 Kimberly-Clark Worldwide, Inc. Method for forming an absorbent structure having vertically orientated flow regulating walls
US6436328B1 (en) 1999-09-15 2002-08-20 Kimberly-Clark Worldwide, Inc. Method for forming an absorbent structure
US6479728B1 (en) 1999-09-15 2002-11-12 Kimberly-Clark Worldwide, Inc. Absorbent structure with angularly orientated absorbent members
US6623837B2 (en) 2000-12-27 2003-09-23 Kimberly-Clark Worldwide, Inc. Biaxially extendible material
US6645187B1 (en) 1999-09-15 2003-11-11 Kimberly-Clark Worldwide, Inc. Absorbent article having vertically oriented flow regulating walls
US6689933B1 (en) 1999-09-15 2004-02-10 Kimberly-Clark Worldwide, Inc. Absorbent article having vertically orientated absorbent members
US20040122396A1 (en) * 2002-12-24 2004-06-24 Maldonado Jose E. Apertured, film-coated nonwoven material
US20040118534A1 (en) * 2002-12-19 2004-06-24 Anderson Ralph Lee Low formaldehyde creping composition and product and process incorporating same
US6835264B2 (en) 2001-12-20 2004-12-28 Kimberly-Clark Worldwide, Inc. Method for producing creped nonwoven webs
US6838154B1 (en) 1997-10-31 2005-01-04 Kimberly-Clark Worldwide, Inc. Creped materials
US20050276828A1 (en) * 2004-06-14 2005-12-15 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Bar soap with fibrous assembly
US20070049512A1 (en) * 2005-09-01 2007-03-01 Conopco, Inc., D/B/A Unilever Rapid dissolving bar soap with fibrous assembly
US9913764B2 (en) 2013-12-18 2018-03-13 Kimberly-Clark Worldwide, Inc. Post-bonded grooved elastic materials
US10792194B2 (en) 2014-08-26 2020-10-06 Curt G. Joa, Inc. Apparatus and methods for securing elastic to a carrier web
US11701268B2 (en) 2018-01-29 2023-07-18 Curt G. Joa, Inc. Apparatus and method of manufacturing an elastic composite structure for an absorbent sanitary product
US11744744B2 (en) 2019-09-05 2023-09-05 Curt G. Joa, Inc. Curved elastic with entrapment
US11925538B2 (en) 2019-01-07 2024-03-12 Curt G. Joa, Inc. Apparatus and method of manufacturing an elastic composite structure for an absorbent sanitary product

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US2407548A (en) * 1940-08-01 1946-09-10 Fibre Products Lab Inc Fibrous structural material and method and apparatus for making same
US3236718A (en) * 1958-07-15 1966-02-22 Samcoe Holding Corp Method of treating webs and product resulting therefrom
US3220056A (en) * 1959-11-27 1965-11-30 Richard R Walton Treatment of sheet materials

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3775230A (en) * 1971-11-01 1973-11-27 R Hilton Rigid laminate of creped secondary fiber sheets
US4078958A (en) * 1974-06-27 1978-03-14 Cie Des Ets. De La Risle-Papeteries De Pont-Audemer Manufacture of a wiping article having a paper base
US5151240A (en) * 1989-09-06 1992-09-29 Kanebo, Ltd. Leather-like material having excellent water vapor permeability and suppleness and its manufacture
US5763041A (en) * 1995-12-21 1998-06-09 Kimberly-Clark Worldwide, Inc. Laminate material
US5931823A (en) * 1997-03-31 1999-08-03 Kimberly-Clark Worldwide, Inc. High permeability liner with improved intake and distribution
US6150002A (en) * 1997-10-31 2000-11-21 Kimberly-Clark Worldwide, Inc. Creped nonwoven liner with gradient capillary structure
US6197404B1 (en) 1997-10-31 2001-03-06 Kimberly-Clark Worldwide, Inc. Creped nonwoven materials
US6838154B1 (en) 1997-10-31 2005-01-04 Kimberly-Clark Worldwide, Inc. Creped materials
US6592960B1 (en) 1999-05-07 2003-07-15 Japan Absorbent Technology Bulky non-woven fabric and method for manufacturing the same
EP1050612A1 (en) * 1999-05-07 2000-11-08 Japan Absorbent Technology Institute Bulky non-woven fabric, method for manufacturing it and absorbent products using such fabric
US6645187B1 (en) 1999-09-15 2003-11-11 Kimberly-Clark Worldwide, Inc. Absorbent article having vertically oriented flow regulating walls
US6264776B1 (en) 1999-09-15 2001-07-24 Kimberly-Clark Worldwide, Inc. Method for forming an absorbent structure having vertically orientated absorbent members
US6436328B1 (en) 1999-09-15 2002-08-20 Kimberly-Clark Worldwide, Inc. Method for forming an absorbent structure
US6479728B1 (en) 1999-09-15 2002-11-12 Kimberly-Clark Worldwide, Inc. Absorbent structure with angularly orientated absorbent members
US6413338B1 (en) 1999-09-15 2002-07-02 Kimberly-Clark Worldwide, Inc. Method for forming an absorbent structure having vertically orientated flow regulating walls
US6689933B1 (en) 1999-09-15 2004-02-10 Kimberly-Clark Worldwide, Inc. Absorbent article having vertically orientated absorbent members
US6623837B2 (en) 2000-12-27 2003-09-23 Kimberly-Clark Worldwide, Inc. Biaxially extendible material
US6835264B2 (en) 2001-12-20 2004-12-28 Kimberly-Clark Worldwide, Inc. Method for producing creped nonwoven webs
US20040118534A1 (en) * 2002-12-19 2004-06-24 Anderson Ralph Lee Low formaldehyde creping composition and product and process incorporating same
US20040122396A1 (en) * 2002-12-24 2004-06-24 Maldonado Jose E. Apertured, film-coated nonwoven material
US7381692B2 (en) 2004-06-14 2008-06-03 Unilever Home & Personal Care, Usa Division Of Conopco, Inc. Bar soap with fibrous assembly
US20050276828A1 (en) * 2004-06-14 2005-12-15 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Bar soap with fibrous assembly
US20070049512A1 (en) * 2005-09-01 2007-03-01 Conopco, Inc., D/B/A Unilever Rapid dissolving bar soap with fibrous assembly
US9913764B2 (en) 2013-12-18 2018-03-13 Kimberly-Clark Worldwide, Inc. Post-bonded grooved elastic materials
US10632027B2 (en) 2013-12-18 2020-04-28 Kimberly-Clark Worldwide, Inc. Method of making post-bonded grooved elastic materials
US10792194B2 (en) 2014-08-26 2020-10-06 Curt G. Joa, Inc. Apparatus and methods for securing elastic to a carrier web
US11690767B2 (en) 2014-08-26 2023-07-04 Curt G. Joa, Inc. Apparatus and methods for securing elastic to a carrier web
US11701268B2 (en) 2018-01-29 2023-07-18 Curt G. Joa, Inc. Apparatus and method of manufacturing an elastic composite structure for an absorbent sanitary product
US11925538B2 (en) 2019-01-07 2024-03-12 Curt G. Joa, Inc. Apparatus and method of manufacturing an elastic composite structure for an absorbent sanitary product
US11744744B2 (en) 2019-09-05 2023-09-05 Curt G. Joa, Inc. Curved elastic with entrapment

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