US3855110A

US3855110A - Cylindrical rf sputtering apparatus

Info

Publication number: US3855110A
Application number: US00416318A
Authority: US
Inventors: D Quinn; E Paradis
Original assignee: United Aircraft Corp
Current assignee: Raytheon Technologies Corp
Priority date: 1973-11-15
Filing date: 1973-11-15
Publication date: 1974-12-17
Anticipated expiration: 1991-12-17

Abstract

A cylindrical cathode is used as a vacuum chamber to permit sputtering by means of an rf potential on all sides of a workpiece located coaxially within the chamber. Both insulators and conductors may be used as target materials and as workpieces. Even deposition of the sputtered material on long or continuously fed workpieces is achieved by properly terminating the ends of the coaxial sputtering chamber with grounded chambers of larger diameter than the sputtering chamber and of sufficient length to thereby gradually reduce the plasma density along the axial direction to a relatively small value before reaching the end walls.

Description

United States Patent 11 1 1111 3,855,110 I Quinn et al. I Y Dec. 17, 1974 [54] CYLINDRICAL RF SPUTTERING I I 3,627,663 12/1971 Davidse et al. 204/298 APPARATUS Primary Examiner-Oscar R. Vertiz [75] lnvemors' 2333i; g gr z gfi sga Assistant Examiner-Wayne A. Lange] both of Com I Attorney, Agent, or Firm-Donald F. Bradley [73] Assignee: United Aircraft Corporation, East v Hartford, Conn. A cylindrical cathode is used as a vacuum chamber to [22]. 1973 permit sputtering by means of an if potential on all [21] I Appl. No.: 416,318 sides of a workpiece located coaxially within the chamber. Both insulators and conductors may be used as target materials and as workpieces. Even deposition 57 ABSTRACT 2? $551k 204/2igis20ilsl92 of the sputtered material on long or continuously fed [58] Fntid 25O workpieces is achieved by properly terminating the I 1 0 care l ends of the'coaxial sputtering chamber with grounded chambers of larger diameter than the sputtering cham- [56] References C'ted her and of sufficient length to thereby gradually re- UNITED STATES PATENTS 1 duce the plasma density along the axial direction to a- 2,916,409 12/1959 Bucek 0., 204/298 I relatively small value before reaching the end walls. 3,231,484 1/1966 Berghaus 250/531 a 3,250,694 5/1966 Maissel et al. 204/298 sclalms, 2 DraWlng Figures PATENTED DEC 1 H974 SHiET 2 BF 2 BACKGROUND OF THE INVENTION 1. Field of the Invention This invention relates to high rate sputtering apparatus for depositing films of material on a substrate. More specifically this invention relates to an improved sputtering apparatus which permits insulators as well as conductors and semiconductors to be deposited on the entire surface of any workpiece without the need for rotating the workpiece. In another aspect this invention relates to an improved-method and apparatus for sculp turing the plasma density in a chamber.

2. Description of the Prior Art Prior to the present invention, the coating of workpieces by sputtering was generally limited to coating only one side at a time, or to coating all sides by sputtering outwardly from either a planar or cylindrical target onto a rotating workpiece. Electrically conducting materials but not insulating materials can presently be applied to a workpiece using dc energization only by sputtering inwardly toward the workpiece from a cylin-- front of a sputtering target is limited in its applicability,

since the workpiece must be sufficiently strong to withstand the mechanical forces produced'by the rotation, and thus only relatively small, sturdy workpieces can be utilized. Another disadvantage of this technique is that the workpiece is thermally cycled as it rotates, thereby causing additional stress and mechanical problems. Complicated mechanical apparatus is also necessary to introduce the rotary motion into the sputtering chamher, and this requirement raises additional difficulties when connections to the workpiece or sputtering chamber are desired. For example, it may be necessary to introduce water cooling to the workpiece, or to monitor the temperature with a thermocouple, or provide BRIEF DESCRIPTION OF'THE DRAWINGS FIG. 1 is a vertical section showing the preferred f structure of the sputtering apparatus,

FIG. 2 shows in partial graph form the axial variation in thickness of deposited material on a workpiece usin the structure ofFIG. l. I

DESCRIPTION OF THE PREFERRED EMBODIMENT Referring to FIG. 1, there is shown a substrate or workpiece 10 in the form of a long rod. The workpiece may be composed of either an insulating or conducting material and may be of any shape compatible with the sputtering apparatus to be described.

Surrounding the workpiece 10 is the cylindrical target I2 composed of the material with which it is desired .to coat the workpiece, and which for purposes of this vis circulated to cool the walls of the cathode member 14. The water is pumped into and extracted from the passages 16 via conduit 18.

The target and cathode assembly are surrounded by a shield 20 of copper or other suitable material for purposes of radiation protection. Anelectromagnet 22 in the shape of a cylinder surrounds'the shield 20 outside of the cathode and provides an axial magnetic field which promotes uniform plasma formation along the axis of the cathode, stabilizes the plasma, and provides Y a degree of temperature control of the object to be ing adherence.

' SUMMARY OF THE INVENTION The present invention avoids the limitations of the prior art by allowing the use of rf energization to sputter inwardly from a cylindrical target. This eliminates the need for rotating the workpiece and permits a workpiece to be coated on all sides by conducting or insulating materials. By means of the present invention, it is also possible to coat workpieces ofconsiderable length or continuously fed workpieces.

In accordance with the present invention, a cylindrical target electrode is used as a portionof the vacuum chamber and an rf field applied to the low pressure gas in the chamber to form a plasma therein. The workpiece which may be a long, narrow rod or fiber is located on or near the axis of the cylinder. To permit the even deposition of the target material axially along the workpiece. the ends of the cylindrical vacuum chamber are modified by providing grounded chambers with dimensions sufficiently large to allow the plasma density to decay gradually. The end chambers are electrically insulated from the target electrode chamber, andthe target electrode is surrounded by a cylindrical electromagnet to enhance uniform plasma formation.

coated. The axial magnetic-field, however, is not essential to operation of'the sputtering apparatus, but merely enhances its operation.

Apparatus of the type described abovehas been used to apply a coating of a conductive material to'a workpiece byforming the target of the conductive material which it is desired to sputter onto the workpiece and applying a dc voltage to the target electrode. When a radio frequencytrf) potential was applied, however, to the target electrode, uneven coating of the workpiece resulted, and large voltages were induced on the workpiece whichresulted in sputtering of the workpiecematerial onto the cylindrical target. It was theorized that the erratic operation was caused'by the reflection of the rvf waves from the high plasma density gradient which appeared at the ends of the chamber. It was further speculated thatby gradually reducing the gradient of the plasma density, the reflections would not occur and improved operation would result. By terminating the ends of the cathode chamber with grounded cylindrical chambers of larger diameter than the cathode chamber and having dimensions large enough to allow the plasma density to decay to a relatively small'value before reaching the walls of the end chamber, it'has been found that radically improved operation of the sputtering apparatus occurs, and that with theuse of rf .potentials both insulating and conducting materials may be coated on the workpiece.

Referring again to FIG. 1, a preferred embodiment of the improved apparatus is shown. To each end of the cathode member 14 there is attached a cylindrical insulating standoff shown at 24 and 26. Onto each insulating standoff is attached a cylindrical termination chamber shown at 28 and 30 formed from a metallic material such as stainless steel. A gas inlet 32 .as well as a gas pressure gauge port 36 are provided in end cap 34 of termination chamber 30, while a gas pumpout port 38 is provided in end cap 40 of termination chamber 28. The termination chambers areattachedto the insulating standoffs 26 and 24 by

plates

42 and 44 preferably of insulating material, each plate containing an opening in the center thereof as shown at 46 and 48. O-ring seals are used between the termination chambers 28 and 30 and the respective

insulating plates

44 and 42, and also between the cathode l4 and insulating standoffs 24 and 26. Heat sinks 50 and 52 are shown positioned in contact with insulating standoffs 24 and 26, the heat sinks being cooled by

cooling coils

54 and 56. An insulated workpiece holder is shown at 58, and a connection forthe rf input is shown at 60.

Typical operation involves loading a clean workpiece into the cylindrical sputtering chamber as shown in FIG. 1. The chamber is then evacuated to about 10 torr. A gas, generally but not necessarily inert, is next admitted to the sputtering chamber to a pressure ofabout 10 torr. A dc axial magnetic field of about l5O gauss is imposed in the cylindrical cathode cavity. With cooling water flowing, the desired rf power density is applied to the cathode. If sputter cleaning or bias sputtering of the workpiece is desired, the workpiece'is electrically connected to a lead of the insulatedfeed through 58, and a bias potential of either rf or dc is applied. An rf bias would be required if the workpiece were being coated with an insulator. A special feature of this cylindrical cathode is thata self-induced rf bias will appear on the workpiece if the insulated feed through lead is externally connected to ground. The magnitude of the self-induced bias can be decreased by adding electrical resistance between the lead and ground.

An example of a preferred embodiment of the apparatus has a target 15 inches long and 2.5 inches in inside diameter, with termination chambers 6 inches in diameter and 10 inches long. With applied rf power densities of 8.6 w/in. to 25 w/in. coatings were applied successfully to fibers of a 0.004 inch diameter as well as rods of 0.5 inch diameter. Sputtering targets were of insulating as well as conducting materials, and coatings were applied to insulating as well as conducting workpieces. For example, a coating of AI O has been applied to a workpiece of tungsten at a rate of 85A/min., and a coating of Ni has been applied to a workpiece of alumina at a rate of 75OA/min., both coatings being applied with a power input of 8.6 w/in. with an rf frequency of 13.56 MHZ.

To illustrate the effect of the use of the terminating chambers on a workpiece, FIG. 2 shows in graph form a typical coating thickness profile for workpieces placed along the axis of the cylindrical target. The coating thickness is substantially uniform along the length of the workpiece.

It is apparent that the apparatus described may be made larger or smaller by varying the diameter and/or the length of the cathode chamber. The cathode chamber length, however, must be short compared to a quarter wavelength of applied rf potential, or several sections may be connected in line to achieve the desired length. Each section, by itself, must be less than a quarter wavelength and electrically insulated from the other cathode chambers. This insulation couldbe achieved by the use of insulating standoffs and grounded end chambers. By connecting the chambers in line, a continuous feeding of a long workpiece through the chambers is possible.

Other variations of the chamber construction may be used to gradually reduce the plasma density at the desired rate at the end walls. For example, external electric or magnetic fields may be used separately or in combination to sculpture the plasma to any desired density gradient along the axial length of the chamber. ln some applications it may be desired to coat a workpiece in an irregular manner, or to use a termination chamber at one end of the chamber only. in other applications it may be desired to utilize the reflections of the rf energy from the plasmadensity gradient for irregularly shaped workpieces.

Other modifications of the structure and operation of this invention will be apparent to those skilled in the art. a

We claim:

1. Plasma utilization apparatus comprising a cylindrical electrode adapted to support a target material on the inner circumference thereof, said electrode defining a workpiece chamber adapted to contain a workpiece,

means including a source of rf potential applied to said electrode for forming a plasma within said workpiece chamber, said plasma interacting'with said target material and said workpiece,

and a grounded cylindrical termination chamber connected to at least one end of said workpiece chamber and being electrically insulated from said workpiece chamber, said termination chamber having a cross-sectional area greater than the crosssectional area of said workpiece chamber, said termination chamber having an aperture therein aligned with said workpiece chamber to permit expansion of said plasma into said termination chamber.

2. Apparatus as in claim 1 and including a second said termination chamber connected to the other end of said workpiece chamber and electrically insulated therefrom.

3. Apparatus as in claim 1 and including a cylindrical magnet surrounding said electrode.

4. Apparatus as in claim 1 and including means for cooling the walls of said electrode.

' 5. Apparatus as in claim 1 in which said termination chamber is formed from a metallic material and is attached to said workpiece chamber by an annular insulating member.

Claims

1. Plasma utilization apparatus comprising a cylindrical electrode adapted to support a target material on the inner circumference thereof, said electrode defining a workpiece chamber adapted to contain a workpiece, means including a source of rf potential applied to said electrode for forming a plasma within said workpiece chamber, said plasma interacting with said target material and said workpiece, and a grounded cylindrical termination chamber connected to at least one end of said workpiece chamber and being electrically insulated from said workpiece chamber, said termination chamber having a cross-sectional area greater than the cross-sectional area of said workpiece chamber, said termination chamber having an aperture therein aligned with said workpiece chamber to permit expansion of said plasma into said termination chamber.

5. Apparatus as in claim 1 in which said termination chamber is formed from a metallic material and is attached to said workpiece chamber by an annular insulating member.