US5594044A - Ink jet ink which is rub resistant to alcohol - Google Patents
Ink jet ink which is rub resistant to alcohol Download PDFInfo
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- US5594044A US5594044A US08/398,095 US39809595A US5594044A US 5594044 A US5594044 A US 5594044A US 39809595 A US39809595 A US 39809595A US 5594044 A US5594044 A US 5594044A
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- jet ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
Definitions
- the present invention relates to ink jet printing compositions for printing on non-porous substrates, particularly for printing on non-porous substrates such as metal, glass, and plastic containers, the jet printing composition having the characteristics of fast drying, good adhesion, and resistance to isopropyl alcohol rubs.
- Ink jet printing is a well-known technique by which printing is accomplished without contact between the printing device and the substrate on which the printed characters are deposited.
- ink jet printing involves the technique of projecting a stream of ink droplets to a surface and controlling the direction of the stream electronically so that the droplets are caused to form the desired printed image on that surface.
- This technique of noncontact printing is particularly well suited for application of Characters onto irregularly shaped surfaces, including, for example, the bottom of glass, metal, or plastic containers, used for holding cosmetic, pharmaceutical, liquor, and health care products.
- an ink jet composition must meet certain rigid requirements to be useful in ink jet printing operations. These relate to viscosity, resistivity, solubility, compatibility of components and wettability of the substrate. Further, the ink must be quick-drying and smear resistant, resist alcohol rubs, and be capable of passing through the ink jet nozzle without clogging, and permit rapid cleanup of the machine components with minimum effort.
- UK Patent Application GB 2,105,735 discloses a jet ink composition comprising an oil soluble dye-impregnated polyurethane latex dispersed in an aqueous medium.
- U.S. Pat. No. 4,680,332 discloses a jet ink composition
- a jet ink composition comprising a water insoluble polymer such as a polyacrylate dispersed in a liquid medium, the polymer containing therein an oil soluble dye, and a nonionic stabilizer permanently attached thereto.
- U.S. Pat. No. 5,207,825 discloses a jet ink composition which comprises an aqueous liquid vehicle, a colorant, and a polymeric additive which is a substituted bisphenol A derivative.
- U.S. Pat. No. 5,080,716 discloses a jet ink composition comprising a recording agent, a liquid medium capable of dissolving or dispersing the recording agent, and a substituted benzene or toluene sulfonamide compound.
- U.S. Pat. No. 5,254,158 discloses an ink composition which comprises an aqueous liquid vehicle, a colorant, and an additive selected from the group consisting of amine alkoxylates, sorbitan monoester alkoxylates, alkylene oxide adducts of glycerin, and mixtures thereof.
- U.S. Pat. Nos. 5,215,577 and 5,178,671 disclose jet ink compositions comprising a recording agent and a liquid medium for dissolution or dispersion thereof, the recording agent being an aromatic sulfonated diazo compound.
- U.S. Pat. No. 5,131,949 discloses a jet ink composition including a recording agent, a liquid medium capable of dissolving or dispersing the recording agent, and a compound having an amide group.
- U.S. Pat. No. 5,213,613 discloses a jet ink comprising a recording agent and a liquid medium capable of dissolving or dispersing the recording agent therein, wherein the ink contains an imide compound and at least one compound selected from the group consisting of urea, thiourea and derivatives thereof, and volatile alkaline compounds.
- U.S. Pat. No. 4,692,188 discloses a process for the preparation of jet ink compositions, comprising (1) dissolving in a water-immiscible organic solvent a polymer composition and an organic oil soluble dye; (2) adding an aqueous phase water surfactant mixture thereto; (3) affecting emulsification thereof; and (4) subsequently evaporating from the aforementioned mixture the solvent thereby resulting in an ink with the dye trapped in the polymer particles suspended in the aqueous phase.
- the polymer compositions include polycarbonates, polystyrene, polymethacrylates and copolymers thereof.
- the present invention provides ink compositions that are capable of adhering on glass, plastic, and metal container surfaces used for the packaging of cosmetics, pharmaceuticals, liquor, and health care products and exhibits good adhesion and isopropyl alcohol rub resistance.
- the composition comprises an organic solvent, a flexible thermoplastic polyurethane resin, a dye, a cellulose nitrate resin, and an adhesion promoter.
- the present invention also provides a method of forming printed images on the glass, plastic, and metal surfaces using the ink composition of the instant invention.
- the method comprises projecting a stream of droplets of the ink composition onto the surface of a substrate, such as glass, plastic and metal, and controlling the direction of the stream electronically so that the droplets form the desired printed image on the surface.
- the jet ink composition of the instant invention comprises an organic solvent, a dye, a polyurethane binder, a cellulose nitrate resin, and an adhesion promoter.
- the ink compositions of the present invention exhibit the following characteristics for use in ink jet printing systems: (1) a viscosity from about 1.6 to about 7.0 centipoises at 25° C.; (2) an electrical resistivity from about 50 to about 2000 ohm-cm; and (3) a sonic velocity from about 1100 to about 1300 meters/second.
- Organic solvents suitable for the ink composition of the instant invention include ketones such as acetone, methyl ethyl ketone, diethyl ketone, cyclohexanone, and the like, esters such ethyl acetate, propyl acetate, butyl acetate, amylacetate, and the like, alcohols such methanol, ethanol, n-propanol, isopropanol, n-butanol, i-butanol, t-butanol, n-pentanol, n-hexanol, and the like, hydrocarbon solvents such as hexane, cyclohexane, heptane, benzene, toluene, xylene, and the like, glycols such as ethylene glycol, propylene glycol, glycerin, diethylene glycol, and the like, glycol ethers such as ethylene glycol dimethyl ether, ethylene
- Filmcol Special Industrial Solvent C-2 from Shell Chemical Co. which is 200 proof modified specially denatured alcohol (5% methanol) is a preferred solvent.
- Flexible thermoplastic polyurethane resins are used as binders in the preparation of the ink compositions of the instant invention.
- Flexible thermoplastic urethanes are produced by the reaction of polyols and diisocyanates.
- polyols include ethylene glycol, propylene glycol, propanediol, butanediol, polyethylene glycol, polypropylene glycol, polyethylene glycol adipate diol, polyethylene glycol succinate diol, polytetrahydrofuran diol, and the like.
- diisocyanates include 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, 4,4,-diphenylmethane diisocyanate, hexamethylene diisocyanate, and the like.
- Polyurethanes having molecular weight in the range of about 5,000 to about 50,000 are preferred and polyurethanes having molecular weight in the range of about 20,000 to about 24,000 are even more preferred.
- urethane polymers examples include, but are not limited to, the flexible thermoplastic polyurethane solutions sold under the commercial name of Surkopak by Kane International Corp., Rye, New York.
- a variety of grades of polyurethanes are sold under this name and include Surkopak 2135, Surkopak 5299, Surkopak 5244, Surkopak 5255, Surkopak 2X, Surkopak 5322, Surkopak 5311, and Surkopak XL. They are normally used to modify nitrocellulose based printing inks for flexo and gravure applications on flexible packaging substrates such as polyethylene, polypropylene, polyester, and cellulose.
- the physical properties of the polyurethane solutions are presented in Table 1 below.
- polyurethanes are non-reactive and are essentially free of isocyanate groups.
- Surkopak 5244 is sold as a solution in ethyl acetate.
- the concentration of the polyurethane resin (active ingredient) in the ink composition is in the range of about 1 percent to about 12 percent by weight, preferably in the range of about 1 percent to about 6 percent by weight, and more preferably in the range of about 2 percent to about 5 percent by weight. If the polyurethane is commercially sold as a solution, as in the case of Surkopak, the amount of the polyurethane solution to be used to prepare the ink is calculated from the concentration of the polyurethane in the solution.
- the ink composition comprises a colorant which is a dye that imparts the desired color to the printed message.
- a colorant which is a dye that imparts the desired color to the printed message.
- Any dye that may be dissolved in the ink composition may be used in the instant invention.
- U.S. Pat. No. 5,254,158, and UK Patent Application GB 2,105,735 list several examples of dyes. All of these dyes and pigments may be used in the instant invention.
- Examples of dyes applicable to the present invention include, but are not limited to, the yellow dyes such as C.I. Solvent Yellow 19 (C.I. 13900A), C.I. Solvent Yellow 21 (C.I. 18690), C.I. Solvent Yellow 61, C.I.
- Solvent Yellow 80 FD&C Yellow #5, Yellow Shade 16948, Acid Yellow 23, Levaderm Lemon Yellow (Mobay), Spirit Fast Yellow 3G, Aizen Spilon Yellow C-GNH (Hodagaya Chemical Co.), Pergasol Yellow CGP (Ciba-Geigy), and the like
- the orange dyes such as C.I. Solvent Orange 1 (C.I. 11920), C.I. Orange 37, C.I. Orange 40, Diaresin Orange K (Mitsubishi Chemical Industries, Ltd.), Diaresin Orange G (Mitsubishi Chemical Industries, Ltd.), Sumiplast Orange 3G (Sumitomo Chemical Co., Ltd.), and the like, red dyes such as C.I.
- Solvent Red 8 C.I. Solvent Red 81, C.I. Solvent Red 82, C.I. Solvent Red 84, C.I. Solvent Red 100, Cibacron Brilliant Red 38-A (Aldrich Chemical Co.), Drimarene Brilliant Red E-6A (Pylam, Inc.), Acid Red 92, Reactive red 31 (ICI America), and the like, pink dyes such as Diaresin Pink M (Mitsubishi Chemical Industries, Ltd.), Sumiplast Pink RFF (Sumitomo Chemical Co.), Direct Brill Pink B Ground Crude (Crompton & Knowles), and the like, violet dyes such as C.I. Solvent Violet 8, C.I.
- Solvent Violet 21 Diaresin Violet (Mitsubishi), Diaresin Violet D, Sumiplast Violet RR (Sumitomo), and the like
- blue dyes such as C.I. Solvent Blue 2, C.I. Solvent Blue 11, C.I. Solvent Blue 25, C.I. Solvent Blue 36, C.I. Solvent Blue 55, and the like
- green dyes such as C.I. Solvent Green 3 and the like, brown dyes such as C.I. Solvent Brown 3 and Diaresin Brown A (Mitsubishi), and the like
- black dyes such as Valifast Black 3810 (Orient), C.I. Solvent Black 3, C.I. Solvent Black 5, C.I. Solvent Black 7, C.I. Solvent Black 22, C.I. Solvent Black 27, C.I. Solvent Black 29, Acid Black 123, and the like.
- a preferred colorant is Valifast Black 3810.
- the colorant is present in the ink composition in an amount required to produce the desired contrast and readability.
- the colorant is preferably present in the range of about 2 percent to about 12 percent by weight, more preferably in the range of about 3 percent to about 9 percent by weight, and even more preferably in the range of about 4 percent to about 6 percent by weight.
- the jet ink composition may preferably contain a surfactant, which may be anionic, cationic, nonionic, or amphoteric.
- anionic surfactants are, but are not limited to, alkylbenzene sulfonates such as dodecylbenzene sulfonate, alkylnaphthyl sulfonates such as butyl or nonyl naphthyl sulfonate, dialkyl sulfosuccinates such as diamyl sulfosuccinate, alcohol sulfates such as sodium lauryl sulfate, and perfluorinated carboxylic acids such as perfluorodecanoic acid and perfluorododecanoic acid.
- Nonionic surfactants include the alkylesters of polyethylene glycol, fatty acid esters of glycerol, fatty acid esters of glycol, and the like, and fluorochemical surfactants such as FC 430, FC 431, FC 740, FC 120, FC 248, FC 352, FC 396, FC 807, and FC 824, which are available from 3M Co.
- Cationic surfactants include alkylamines, amine oxides, amine ethoxylates, alkyl hydroxyalkyl imidazolines, quaternary ammonium salts, and amphoteric surfactants include the alkylbetaines, the amidopropylbetaines, and the like.
- the surfactant FC 430 which is a mixture of fluoroaliphatic polymeric acrylate esters, is a preferred surfactant.
- the solid surfactant made into solution may be present in the jet ink composition in the range of about 0.01 percent to about 0.2 percent by weight, preferably in the range of about 0.01 percent to about 0.1 percent by weight, and more preferably in the range of about 0.01 percent to about 0.05 percent by weight.
- the jet ink composition may contain an additional resin to improve the ahesion and solvent resistance.
- These resins include cellulose based resins. Examples of cellulose based resins are cellulose acetate, cellulose propionate, cellulose butyrate, cellulose acetate-butyrate, ethyl cellulose, hydroxypropyl cellulose, and cellulose nitrate.
- a preferred cellulose based resin is cellulose nitrate.
- Cellulose nitrate is the reaction product of cellulose with nitric acid.
- Various grades of cellulose nitrate are characterized by the degree of substitution by nitro groups of the hydroxyl groups of cellulose.
- Cellulose nitrates which are useful in the present invention include any of a wide variety of cellulose nitrates including those which are commercially available.
- Useful cellulose nitrates include the RS, AS, and SS type cellulose nitrates wetted by isopropyl alcohol, ethanol or water sold by Hercules, Inc.
- the RS type cellulose nitrate has a nominal degree of substitution which corresponds to a nitrogen content of about 12%.
- the viscosity of a particular cellulose nitrate solution is related to its degree of polymerization.
- Cellulose nitrate resins of many different degree of polymerization are available under the RS type.
- the preferred cellulose nitrate is the one with the viscosity of 15 centipoises (for about 12.2% solution).
- the resin may be present in the jet ink composition in the range of about 1 percent to about 10 percent by weight, preferably in the range of about 2 percent to about 8 percent by weight, and more preferably in the range of about 3 percent to about 5 percent by weight.
- the jet ink composition may preferably contain a plasticizer.
- the type of plasticizer selected should be compatible with the additional resin selected for inclusion in the composition.
- plasticizers that are compatible and useful are adipic acid derivatives such as diisobutyl adipate, di-n-hexyl adipate, and the like, azelaic acid derivatives such as bis(2-ethyl hexyl)azelate, benzoic acid derivatives such as diethyleneglycol dibenzoate, citric acid derivatives such as tri-n-butyl citrate, epoxy derivatives such as epoxidized soybean oil, bisphenol A diglycidylether, glycol derivatives such as diethyleneglycol dipelargonate, glycolates such as methyl phthalyl ethyl glycolate, hydrocarbons such as hydrogenated terphenyls, isophthalic acid esters such as di-2-ethylhexyl isophthalate, oleic
- ricinoleic acid derivatives such as methyl ricinoleate, stearic acid derivatives such as n-butyl stearate, sulfonic acid derivatives such as (o,p)-toluenesulfonamide, N-ethyl-(o,p)-toluenesulfonamide, toluenesulfonamide-formaldehyde resin (Santolite MHP), and the like, tartaric acid derivatives such as dibutyl tartrate, terephthalic acid derivatives such as bis(2-ethylhexyl)terephthalate, and trimellitic acid derivatives such as tris(2-ethylhexyl)trimellitate.
- plasticizers that will be compatible with cellulose nitrate can be found, e.g., in Kirk-Othmer--Encyclopedia of Chemical Technology, vol. 18, p. 111-183, 3rd edition (John-Wiley & Sons).
- a preferred plasticizer for use in the instant invention is Santicizer 8, which is an o,p-mixture of N-ethyl-toluenesulfonamide, available from Monsanto Co.
- the plasticizer may be present in the jet ink composition in the range of about 0.1 percent to about 3 percent by weight, preferably in the range of about 0.1 percent to about 2 percent by weight, and more preferably in the range of about 0.5 percent to about 1.5 percent by weight.
- the jet ink composition may preferably contain an adhesion promoter to improve the adhesion of the jet ink to the substrate.
- adhesion promoters examples include transition metal organates such as titanium organates, zirconium organates, hafnium organates, and the like.
- Preferred organates are the titanium organates sold by DuPont Chemical Co. under the tradename of Tyzor titanates.
- Tyzor titanates examples include Tyzor TBT, which is titanium tetra-n-butoxide, Tyzor TPT, which is titanium tri-isopropoxide, Tyzor GBA, which is titanium diisopropoxide bis(2,4-pentanedionate), Tyzor LA, which is titanium ammoniumlactate, and Tyzor AA, which is titanium acetylacetonate.
- Tyzor GBA is titanium diisopropoxide bis(2,4-pentanedionate
- Tyzor LA which is titanium ammoniumlactate
- Tyzor AA which is titanium acetylacetonate.
- a preferred Tyzor titanate for use in the instant invention is Tyzor GBA.
- the titanate (the active ingredient) may be present in the jet ink composition in the range of about 0.1 percent to about 5 percent by weight, preferably in the range of about 0.5 percent to about 3 percent by weight, and more preferably in the range of about 1 percent to about 2 percent by weight.
- the jet ink composition may contain in addition additives for adjusting the viscosity, electrical resistivity, and the speed of evaporation.
- the preferred range of viscosity is about 1.5 centipoise to about 6.0 centipoise.
- the preferred resistivity is about 500 ohm-cm to about 1500 ohm-cm.
- compositions of the present invention may contain conductivity agents. If present, they usually are present in amounts of from about 0.0 percent to about 2.0 percent.
- suitable conductivity agents include dimethylamine hydrochloride, diethylamine hydrochloride, lithium nitrate, and hydroxylamine hydrochloride. Sufficient conductivity is offered by the dye, Valifast Black 3810, in the presence of the solvent used in the ink.
- Humectants may be used in the formulations. Humectants include glycerin, ethylene glycol, and the like.
- Various, known viscosity modifying agents may be added, as needed, to adjust the viscosity of any given ink formulation.
- the jet ink formulation may be prepared by any known methods. In one method, all the desired ingredients are combined in a mixer or a mixing vessel and mixed sequentially until a homogeneous solution is obtained.
- the jet ink composition may be generally jet printed onto the surface of a wet glass, plastic, and metal article such as a glass bottle, plastic bottle, or aluminum container.
- the jet ink of the instant invention may be jet applied onto a variety of glasses, including soda-lime glasses, borosilicate glasses, alumino-silicate glasses, lead glasses, borate glasses, and the like.
- the above specified types of glass may contain a coating.
- the jet ink composition may be jet applied onto plastic bottles or containers.
- the bottle or container may be made by any kind of plastic.
- plastics include polyethylene, polypropylene, PVC, nylons, polyesters such as PET, polycarbonate, polyacetals, polyacrylates, polyurethanes, polyethers, polystyrene, polyimides, and the like. If necessary, these plastic containers may be pretreated, for example, by oxidation, corona treatment, plasma treatment, and the like, to prepare the surface for jet printing.
- the jet ink composition may also be applied on metal containers.
- Any metal container may be jet printed using the jet ink of the instant invention.
- metal containers include containers made of aluminum, steel, tin, copper, and the like. Certain containers may need to be pretreated, such as sandblasting, acid cleaning, and the like, to prepare the surface for jet printing.
- a jet ink composition was prepared by employing the following formulation:
- the above ink formulation was prepared and tested on a variety of metal cans. Printer runnability testing was also carried out. The jet ink performed satisfactorily. The drying time was also satisfactory. The printed images had isopropyl alcohol rub resistance. The images were capable of resisting at least 20 medium force rubs from an isopropyl alcohol soaked cotton swab.
- Images can be printed on glass, plastic, and metal surfaces using the jet ink composition of the instant invention by projecting a stream of droplets of the ink to the surface and controlling the direction of the stream electronically so that the droplets form the desired printed image on the surface.
Abstract
Description
TABLE 1 __________________________________________________________________________ Properties of the Surkopak Polyurethane Resins Grade 2135 5299 5244* 5255 2X 5322** 5311 XL __________________________________________________________________________ Solids % 80-85 80-85 73-78 73-78 65-70 68-73 63-68 68-73 Viscosity 15-25 25-30 12-16 25-30 40-50 6-8 30-40 15-20 Solvent A A E E E E/A E E/A Flash Point, °C. 12 12 -4 -4 -4 -4 -4 -4 __________________________________________________________________________ A = Alcohol; E = Ester; E/A = Mixture of E and A *Weight Average Molecular Weight Range 18,000-22,000 **Weight Average Molecular Weight Range 7,000-9,000
______________________________________ Ingredient Percent by weight ______________________________________ Methyl ethyl ketone (Harcos) 61.2 Filmcol (Shell) 20.0 Nitrocellulose; RS type, 15 cps (Hercules) 6.0 Surkopak Polyurethane 5244 5.0 Santicizer 8 (Monsanto) 1.0 Tyzor GBA (DuPont) 1.5 Valifast Black Dye 3810 (Orient) 5.0 FC 430 10% in NEK (3M Co.) 0.3 100.0 ______________________________________
Claims (19)
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/398,095 US5594044A (en) | 1995-03-03 | 1995-03-03 | Ink jet ink which is rub resistant to alcohol |
DE69612773T DE69612773T2 (en) | 1995-03-03 | 1996-02-27 | Ink-jet ink resistant to alcohol abrasion |
EP96301331A EP0730014B1 (en) | 1995-03-03 | 1996-02-27 | Ink jet ink which is rub resistant to alcohol |
CA002170691A CA2170691A1 (en) | 1995-03-03 | 1996-02-29 | Ink jet ink which is rub resistant to alcohol |
MX9600818A MX9600818A (en) | 1995-03-03 | 1996-03-01 | Ink jet which is rub resistant to alcohol. |
JP04442296A JP3923105B2 (en) | 1995-03-03 | 1996-03-01 | Jet ink resistant to alcohol friction |
US08/690,697 US5825391A (en) | 1995-03-03 | 1996-07-31 | Method for forming images using a jet ink which is rub resistant to alcohol |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/398,095 US5594044A (en) | 1995-03-03 | 1995-03-03 | Ink jet ink which is rub resistant to alcohol |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US08/690,697 Division US5825391A (en) | 1995-03-03 | 1996-07-31 | Method for forming images using a jet ink which is rub resistant to alcohol |
Publications (1)
Publication Number | Publication Date |
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US5594044A true US5594044A (en) | 1997-01-14 |
Family
ID=23573976
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US08/398,095 Expired - Lifetime US5594044A (en) | 1995-03-03 | 1995-03-03 | Ink jet ink which is rub resistant to alcohol |
US08/690,697 Expired - Lifetime US5825391A (en) | 1995-03-03 | 1996-07-31 | Method for forming images using a jet ink which is rub resistant to alcohol |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US08/690,697 Expired - Lifetime US5825391A (en) | 1995-03-03 | 1996-07-31 | Method for forming images using a jet ink which is rub resistant to alcohol |
Country Status (6)
Country | Link |
---|---|
US (2) | US5594044A (en) |
EP (1) | EP0730014B1 (en) |
JP (1) | JP3923105B2 (en) |
CA (1) | CA2170691A1 (en) |
DE (1) | DE69612773T2 (en) |
MX (1) | MX9600818A (en) |
Cited By (67)
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US6060537A (en) * | 1995-12-12 | 2000-05-09 | Matthews International Corporation | Water based ink jet printing ink |
US6063834A (en) * | 1997-12-08 | 2000-05-16 | Lexmark International, Inc. | Wet-rub resistant ink compositions |
US6083310A (en) * | 1998-05-28 | 2000-07-04 | Marconi Data Systems, Inc. | Colored inks comprising polymeric colorants for binary array printing and method of using |
US6135654A (en) * | 1996-01-26 | 2000-10-24 | Tetra Laval Holdings & Finance, Sa | Method and apparatus for printing digital images on plastic bottles |
US6302536B1 (en) | 1997-07-31 | 2001-10-16 | Trident International, Inc. | Fast drying ink jet ink compositions for capping ink jet printer nozzles |
US6336711B1 (en) | 1997-12-19 | 2002-01-08 | Samsung Electronics Co., Ltd. | Spraying device of an ink jet printer |
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US6439709B1 (en) | 1998-09-04 | 2002-08-27 | Trident International, Inc. | Method for reducing cavitation in impulse ink jet printing device |
US6444019B1 (en) * | 1998-11-06 | 2002-09-03 | Videojet Technologies Inc. | Ink jet ink composition |
WO2002100960A1 (en) * | 2001-06-08 | 2002-12-19 | Bic Corporation | Polyurethane based inks for writing instruments |
US20030004225A1 (en) * | 1998-09-04 | 2003-01-02 | Sarma Deverakonda S. | High resolution pigment ink for impulse ink jet printing |
US20030032697A1 (en) * | 2001-03-23 | 2003-02-13 | Brother Kogyo Kabushiki Kaisha | Ink for ink-jet recording |
US6688738B2 (en) | 1998-09-04 | 2004-02-10 | Illinois Tool Works Inc | Method for reducing cavitation in impulse ink jet printing devices |
US6726756B1 (en) | 2000-05-26 | 2004-04-27 | Videojet Technologies Inc. | Continuous ink jet printing ink composition |
JP3538661B2 (en) | 2001-12-25 | 2004-06-14 | コニカミノルタホールディングス株式会社 | INK JET RECORDING INK AND INK JET RECORDING METHOD USING THE INK JET RECORDING INK |
US20040154495A1 (en) * | 2003-02-12 | 2004-08-12 | Videojet Technologies Inc. | Jet ink composition for low surface energy substrates |
US6794425B1 (en) * | 1999-03-01 | 2004-09-21 | Avecia Limited | Pigment printing composition |
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US20050039634A1 (en) * | 2003-07-11 | 2005-02-24 | Hermansky Clarence Gaetano | Non-aqueous ink jet inks with improved decap |
US6865988B1 (en) * | 1999-09-07 | 2005-03-15 | Sumitomo Rubber Industries Limited | Transfer foil for golf balls |
US20050101694A1 (en) * | 2003-11-03 | 2005-05-12 | Gem Gravure Company, Inc. | Inkjet inks, methods for applying inkjet ink, and articles printed with inkject ink |
US20050113481A1 (en) * | 2003-11-21 | 2005-05-26 | Imaje S.A. | Ink composition for continuous deflected jet printing, especially on letters and postal articles |
US20050134664A1 (en) * | 2003-12-19 | 2005-06-23 | Pavlin Mark S. | Jet printing inks containing polymerized fatty acid-based polyamides |
US20050179708A1 (en) * | 2004-02-12 | 2005-08-18 | Kornit Digital Ltd. | Digital printing machine |
US20060023031A1 (en) * | 2002-09-27 | 2006-02-02 | Eastman Kodak Company | Apparatus and method of inkjet printing on untreated hydrophobic media |
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US20060203062A1 (en) * | 2003-04-01 | 2006-09-14 | Murray Figov | Method and media for printing aqueous ink jet inks on plastic surfaces |
US20060256176A1 (en) * | 2005-05-13 | 2006-11-16 | Ravi Prasad | Inkjet ink for use on polymeric substrate |
US20070104899A1 (en) * | 2003-06-16 | 2007-05-10 | Kornit Digital Ltd. | Process for printing images on dark surfaces |
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Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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Citations (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3060429A (en) * | 1958-05-16 | 1962-10-23 | Certificate of correction | |
US3298030A (en) * | 1965-07-12 | 1967-01-10 | Clevite Corp | Electrically operated character printer |
US3373437A (en) * | 1964-03-25 | 1968-03-12 | Richard G. Sweet | Fluid droplet recorder with a plurality of jets |
US3416153A (en) * | 1965-10-08 | 1968-12-10 | Hertz | Ink jet recorder |
US3673601A (en) * | 1969-04-02 | 1972-06-27 | Hertz Carl H | Liquid jet recorder |
US3776864A (en) * | 1971-11-01 | 1973-12-04 | Kee Lox Mfg Co | Transfer coating for carbon paper and the like |
JPS56142430A (en) * | 1980-03-24 | 1981-11-06 | Morita Mfg Co Ltd | Biting pressure sensor |
GB2105735A (en) * | 1981-09-11 | 1983-03-30 | Konishiroku Photo Ind | Ink composition for ink jet printing |
DE3226368A1 (en) * | 1982-07-14 | 1984-03-01 | Basf Farben + Fasern Ag, 2000 Hamburg | Printing ink |
GB2161817A (en) * | 1984-07-20 | 1986-01-22 | Tioxide Group Plc | Compositions incorporating adhesion-promoting titanium compounds |
JPS6264874A (en) * | 1985-09-18 | 1987-03-23 | Dainichi Color & Chem Mfg Co Ltd | Ultraviolet-curing ink composition for ink jet recording and its preparation |
US4659848A (en) * | 1984-07-20 | 1987-04-21 | Tioxide Group Plc | Titanium compositions |
US4659387A (en) * | 1984-08-18 | 1987-04-21 | Wolff Walsrode Ag | Nitrocellulose moistened with tertiary alcohols and the use thereof in polyurethane lacquers |
US4680332A (en) * | 1986-01-24 | 1987-07-14 | Xerox Corporation | Ink jet compositions and process for preparation thereof |
US4692188A (en) * | 1985-10-15 | 1987-09-08 | Xerox Corporation | Preparation of ink jet compositions |
US4759968A (en) * | 1986-04-01 | 1988-07-26 | Minnesota Mining And Manufacturing Company | Transfer graphic article |
JPS6411156A (en) * | 1987-07-03 | 1989-01-13 | Asahi Chemical Ind | Composite material composition and production thereof |
US4880465A (en) * | 1987-03-09 | 1989-11-14 | Videojet Systems International, Inc. | Opaque ink composition containing hollow microspheres for use in ink jet printing |
US4975117A (en) * | 1987-02-24 | 1990-12-04 | Dainippon Ink And Chemicals Inc. | Organic solvent-based ink for ink-jet printer |
US5080716A (en) * | 1990-02-09 | 1992-01-14 | Canon Kabushiki Kaisha | Ink having use in ink-jet recording |
US5131949A (en) * | 1990-02-09 | 1992-07-21 | Canon Kabushiki Kaisha | Ink, ink-jet recording process, and instrument making use of the ink |
US5178671A (en) * | 1990-02-09 | 1993-01-12 | Canon Kabushiki Kaisha | Ink, and ink-jet recording method and apparatus employing the ink |
US5207825A (en) * | 1991-07-30 | 1993-05-04 | Xerox Corporation | Ink compositions for ink jet printing |
US5213613A (en) * | 1991-09-26 | 1993-05-25 | Canon Kabushiki Kaisha | Ink, and ink-jet recording method and instrument using the same |
US5215577A (en) * | 1990-01-30 | 1993-06-01 | Canon Kabushiki Kaisha | Ink, and ink-jet recording method and apparatus employing the ink |
US5254158A (en) * | 1992-09-17 | 1993-10-19 | Xerox Corporation | Ink jet ink compositions |
US5316575A (en) * | 1992-10-08 | 1994-05-31 | Videojet Systems, International, Inc. | Pigmented, low volatile organic compound, ink jet composition and method |
US5385957A (en) * | 1992-08-24 | 1995-01-31 | Videojet Systems International, Inc. | Hotmelt ink jet comprising ionomers having melting points from about 50° C. to about 130° or a softening point below about 80° C., and an image-forming agent |
US5393331A (en) * | 1993-09-14 | 1995-02-28 | Videojet Systems International, Inc. | Drop-on-demand ink composition with environmental advantages |
EP0688837A2 (en) * | 1994-06-22 | 1995-12-27 | Tioxide Specialties Limited | Compositions containing zirconium compounds |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4207577A (en) * | 1978-09-13 | 1980-06-10 | Whittaker Corporation | Opaque jet inks |
-
1995
- 1995-03-03 US US08/398,095 patent/US5594044A/en not_active Expired - Lifetime
-
1996
- 1996-02-27 EP EP96301331A patent/EP0730014B1/en not_active Expired - Lifetime
- 1996-02-27 DE DE69612773T patent/DE69612773T2/en not_active Expired - Lifetime
- 1996-02-29 CA CA002170691A patent/CA2170691A1/en not_active Abandoned
- 1996-03-01 JP JP04442296A patent/JP3923105B2/en not_active Expired - Fee Related
- 1996-03-01 MX MX9600818A patent/MX9600818A/en not_active IP Right Cessation
- 1996-07-31 US US08/690,697 patent/US5825391A/en not_active Expired - Lifetime
Patent Citations (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3060429A (en) * | 1958-05-16 | 1962-10-23 | Certificate of correction | |
US3373437A (en) * | 1964-03-25 | 1968-03-12 | Richard G. Sweet | Fluid droplet recorder with a plurality of jets |
US3298030A (en) * | 1965-07-12 | 1967-01-10 | Clevite Corp | Electrically operated character printer |
US3416153A (en) * | 1965-10-08 | 1968-12-10 | Hertz | Ink jet recorder |
US3673601A (en) * | 1969-04-02 | 1972-06-27 | Hertz Carl H | Liquid jet recorder |
US3776864A (en) * | 1971-11-01 | 1973-12-04 | Kee Lox Mfg Co | Transfer coating for carbon paper and the like |
JPS56142430A (en) * | 1980-03-24 | 1981-11-06 | Morita Mfg Co Ltd | Biting pressure sensor |
GB2105735A (en) * | 1981-09-11 | 1983-03-30 | Konishiroku Photo Ind | Ink composition for ink jet printing |
DE3226368A1 (en) * | 1982-07-14 | 1984-03-01 | Basf Farben + Fasern Ag, 2000 Hamburg | Printing ink |
GB2161817A (en) * | 1984-07-20 | 1986-01-22 | Tioxide Group Plc | Compositions incorporating adhesion-promoting titanium compounds |
US4659848A (en) * | 1984-07-20 | 1987-04-21 | Tioxide Group Plc | Titanium compositions |
US4659387A (en) * | 1984-08-18 | 1987-04-21 | Wolff Walsrode Ag | Nitrocellulose moistened with tertiary alcohols and the use thereof in polyurethane lacquers |
JPS6264874A (en) * | 1985-09-18 | 1987-03-23 | Dainichi Color & Chem Mfg Co Ltd | Ultraviolet-curing ink composition for ink jet recording and its preparation |
US4692188A (en) * | 1985-10-15 | 1987-09-08 | Xerox Corporation | Preparation of ink jet compositions |
US4680332A (en) * | 1986-01-24 | 1987-07-14 | Xerox Corporation | Ink jet compositions and process for preparation thereof |
US4759968A (en) * | 1986-04-01 | 1988-07-26 | Minnesota Mining And Manufacturing Company | Transfer graphic article |
US4975117A (en) * | 1987-02-24 | 1990-12-04 | Dainippon Ink And Chemicals Inc. | Organic solvent-based ink for ink-jet printer |
US4880465A (en) * | 1987-03-09 | 1989-11-14 | Videojet Systems International, Inc. | Opaque ink composition containing hollow microspheres for use in ink jet printing |
JPS6411156A (en) * | 1987-07-03 | 1989-01-13 | Asahi Chemical Ind | Composite material composition and production thereof |
US5215577A (en) * | 1990-01-30 | 1993-06-01 | Canon Kabushiki Kaisha | Ink, and ink-jet recording method and apparatus employing the ink |
US5080716A (en) * | 1990-02-09 | 1992-01-14 | Canon Kabushiki Kaisha | Ink having use in ink-jet recording |
US5131949A (en) * | 1990-02-09 | 1992-07-21 | Canon Kabushiki Kaisha | Ink, ink-jet recording process, and instrument making use of the ink |
US5178671A (en) * | 1990-02-09 | 1993-01-12 | Canon Kabushiki Kaisha | Ink, and ink-jet recording method and apparatus employing the ink |
US5207825A (en) * | 1991-07-30 | 1993-05-04 | Xerox Corporation | Ink compositions for ink jet printing |
US5213613A (en) * | 1991-09-26 | 1993-05-25 | Canon Kabushiki Kaisha | Ink, and ink-jet recording method and instrument using the same |
US5385957A (en) * | 1992-08-24 | 1995-01-31 | Videojet Systems International, Inc. | Hotmelt ink jet comprising ionomers having melting points from about 50° C. to about 130° or a softening point below about 80° C., and an image-forming agent |
US5254158A (en) * | 1992-09-17 | 1993-10-19 | Xerox Corporation | Ink jet ink compositions |
US5316575A (en) * | 1992-10-08 | 1994-05-31 | Videojet Systems, International, Inc. | Pigmented, low volatile organic compound, ink jet composition and method |
US5393331A (en) * | 1993-09-14 | 1995-02-28 | Videojet Systems International, Inc. | Drop-on-demand ink composition with environmental advantages |
EP0688837A2 (en) * | 1994-06-22 | 1995-12-27 | Tioxide Specialties Limited | Compositions containing zirconium compounds |
Non-Patent Citations (4)
Title |
---|
Keeling, "Ink Jet Printing", Phys. Technol., 12(5), 196-203 (1981). |
Keeling, Ink Jet Printing , Phys. Technol. , 12(5), 196 203 (1981). * |
Kuhn et al., "Ink-Jet Printing" , Scientific American, Apr., 1979, 162-166, 168, 170, 172, 175, 176, 178. |
Kuhn et al., Ink Jet Printing , Scientific American , Apr., 1979, 162 166, 168, 170, 172, 175, 176, 178. * |
Cited By (112)
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US6135654A (en) * | 1996-01-26 | 2000-10-24 | Tetra Laval Holdings & Finance, Sa | Method and apparatus for printing digital images on plastic bottles |
US5755860A (en) * | 1996-12-19 | 1998-05-26 | Videojet Systems International, Inc. | Invisible fluorescent jet ink |
US6302536B1 (en) | 1997-07-31 | 2001-10-16 | Trident International, Inc. | Fast drying ink jet ink compositions for capping ink jet printer nozzles |
US6010564A (en) * | 1997-10-16 | 2000-01-04 | Videojet Systems International, Inc. | Jet ink composition |
US6063834A (en) * | 1997-12-08 | 2000-05-16 | Lexmark International, Inc. | Wet-rub resistant ink compositions |
US6336711B1 (en) | 1997-12-19 | 2002-01-08 | Samsung Electronics Co., Ltd. | Spraying device of an ink jet printer |
US6083310A (en) * | 1998-05-28 | 2000-07-04 | Marconi Data Systems, Inc. | Colored inks comprising polymeric colorants for binary array printing and method of using |
US6391943B2 (en) * | 1998-09-04 | 2002-05-21 | Trident International, Inc. | High resolution pigment ink for impulse ink jet printing |
US6439709B1 (en) | 1998-09-04 | 2002-08-27 | Trident International, Inc. | Method for reducing cavitation in impulse ink jet printing device |
US7030173B2 (en) | 1998-09-04 | 2006-04-18 | Illinois Tool Works, Inc. | High resolution pigment ink for impulse ink jet printing |
US6688738B2 (en) | 1998-09-04 | 2004-02-10 | Illinois Tool Works Inc | Method for reducing cavitation in impulse ink jet printing devices |
US20030004225A1 (en) * | 1998-09-04 | 2003-01-02 | Sarma Deverakonda S. | High resolution pigment ink for impulse ink jet printing |
US6444019B1 (en) * | 1998-11-06 | 2002-09-03 | Videojet Technologies Inc. | Ink jet ink composition |
US6794425B1 (en) * | 1999-03-01 | 2004-09-21 | Avecia Limited | Pigment printing composition |
USH2113H1 (en) * | 1999-08-16 | 2005-01-04 | Xerox Corporation | Ink compositions |
US6865988B1 (en) * | 1999-09-07 | 2005-03-15 | Sumitomo Rubber Industries Limited | Transfer foil for golf balls |
US6726756B1 (en) | 2000-05-26 | 2004-04-27 | Videojet Technologies Inc. | Continuous ink jet printing ink composition |
US6758889B2 (en) * | 2001-03-23 | 2004-07-06 | Brother Kogyo Kabushiki Kaisha | Ink for ink-jet recording |
US20030032697A1 (en) * | 2001-03-23 | 2003-02-13 | Brother Kogyo Kabushiki Kaisha | Ink for ink-jet recording |
US6797748B2 (en) * | 2001-06-08 | 2004-09-28 | Bic Corporation | Polyurethane based inks for writing instruments |
KR100789039B1 (en) | 2001-06-08 | 2007-12-26 | 빅 코포레이션 | Polyurethane based inks for writing instruments |
CN100352869C (en) * | 2001-06-08 | 2007-12-05 | 碧克公司 | Polyurethane based inks for writing instruments |
WO2002100960A1 (en) * | 2001-06-08 | 2002-12-19 | Bic Corporation | Polyurethane based inks for writing instruments |
JP3538661B2 (en) | 2001-12-25 | 2004-06-14 | コニカミノルタホールディングス株式会社 | INK JET RECORDING INK AND INK JET RECORDING METHOD USING THE INK JET RECORDING INK |
US7401911B2 (en) * | 2002-09-27 | 2008-07-22 | Eastman Kodak Company | Apparatus and method of inkjet printing on untreated hydrophobic media |
US20060023031A1 (en) * | 2002-09-27 | 2006-02-02 | Eastman Kodak Company | Apparatus and method of inkjet printing on untreated hydrophobic media |
US20040154495A1 (en) * | 2003-02-12 | 2004-08-12 | Videojet Technologies Inc. | Jet ink composition for low surface energy substrates |
US7309388B2 (en) | 2003-02-12 | 2007-12-18 | Videojet Technologies Inc. | Jet ink composition for low surface energy substrates |
US20060203062A1 (en) * | 2003-04-01 | 2006-09-14 | Murray Figov | Method and media for printing aqueous ink jet inks on plastic surfaces |
US7370956B2 (en) * | 2003-04-01 | 2008-05-13 | Kodak Il Ltd. | Method and media for printing aqueous ink jet inks on plastic surfaces |
US20070104899A1 (en) * | 2003-06-16 | 2007-05-10 | Kornit Digital Ltd. | Process for printing images on dark surfaces |
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US20070103529A1 (en) * | 2003-06-16 | 2007-05-10 | Kornit Digital Ltd. | Process and system for printing images on absorptive surfaces |
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US11680178B2 (en) | 2019-12-17 | 2023-06-20 | General Co., Ltd. | Inkjet ink |
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US5825391A (en) | 1998-10-20 |
DE69612773D1 (en) | 2001-06-21 |
EP0730014A1 (en) | 1996-09-04 |
MX9600818A (en) | 1997-02-28 |
CA2170691A1 (en) | 1996-09-04 |
JPH0920875A (en) | 1997-01-21 |
DE69612773T2 (en) | 2001-09-20 |
JP3923105B2 (en) | 2007-05-30 |
EP0730014B1 (en) | 2001-05-16 |
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