WO1990007187A1 - Electrical cable - Google Patents
Electrical cable Download PDFInfo
- Publication number
- WO1990007187A1 WO1990007187A1 PCT/US1989/005642 US8905642W WO9007187A1 WO 1990007187 A1 WO1990007187 A1 WO 1990007187A1 US 8905642 W US8905642 W US 8905642W WO 9007187 A1 WO9007187 A1 WO 9007187A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coating
- cable
- polyurethane
- film
- assembly
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/08—Flat or ribbon cables
- H01B7/0838—Parallel wires, sandwiched between two insulating layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/02—Disposition of insulation
- H01B7/0233—Cables with a predominant gas dielectric
Definitions
- This invention relates to electrical cable and to a method for 5 preparing it.
- conductive electrical wire such as copper wire
- PTFE microporous, expanded polytetrafluoroethylene
- the 0 PTFE coating provided a low dielectric, flexible, chemically resistant protective covering surrounding the conductive wire.
- This assembly is then ordinarily provided with an outer insulative covering of full density, non-expanded polytetrafluoroethylene to provide a covering that is heat resistant, is chemically inert, is 5 resistant to being cut (called cut-through resistance) and is of long flex life.
- This configuration is particularly useful for flat or ribbon cable, such as is described in U.S. Patent 4,443,657.
- An electrical cable comprising:
- an insulating layer surrounding the conductive wire comprising microporous polymeric material, such as expanded sintered Q polytetrafluoroethylene, (c) a coating of an organic solvent soluble polyurethane surrounding the insulating layer,
- Figure 1 represents a three dimensional perspective view of one embodiment of the cable of this invention.
- Figure 2 represents a cutaway enlarged view of the cable of
- the cable of the present invention is particularly adaptable for use where ribbon or flat cable containing a plurality of parallel wire conductors in coplanar configuration are desired.
- One advantage of the cable of this invention is the excellent abrasion resistance that is achieved, while further improving the good cut-through resistance of previous cable constructions.
- a plurality of center wire conductors 1, surrounded by insulation of low dielectric 2 which is a microporous polymer such as polytetrafluoroethylene made generally as described in U. S. Patent 3,953,566.
- a microporous polymer such as polytetrafluoroethylene made generally as described in U. S. Patent 3,953,566.
- Other microporous polymers useful herein include microporous polyolefins and other such polymers that are receptive to polyurethane primers.
- a layer of a polyurethane, 3 Surrounding the insulation 2 is a layer of a polyurethane, 3 that is soluble in an organic solvent, such as polyester ⁇ polyurethane, for example, Estane number 5703 provided by B.F. Goodrich Co.
- This layer is ordinarily applied by solution coating, as for example, dip-coating the insulated wire in a solution of the polyesterpolyurethane.
- a typical solution of such polyurethane is a 5-20% by weight solution in a suitable organic solvent, such as a halogenated solvent, as for example, methylene chloride.
- Suitable solvents include methyl ethyl ketone, toluene, N-methyl pyrollidone, dimethyl formamide, glycidyl methacrylate, tetrahydrofurane, and the like. Temperature and pressure are not critical.
- the coating 3 is applied as a primer solution to enable the jacket coating 4 to be applied with ease and good adherab lity. The coating 3 works its way partially into the pores of the microporous, expanded polytetrafluoroethylene and provides a firm interlocking bond therewith, thus, providing a firm foundation for the jacket coating 4.
- the jacket coating 4 is a layer of an extrudable polyurethane, such as a polyetherpolyurethane, as for example, Estane number 58202 supplied by B. F. Goodrich Co. which contains antimony trioxide flame retardant.
- the coating 4 is applied as a melt extruded film and is laminated to polyurethane coating 3 with the aid of compression rolls.
- a common flame-retardant is added to the jacket film, but such is not absolutely necessary.
- the fabrication of the conductor wire entails the initial steps of embedding the conductor 1 in top and bottom inner films of microporous polymer, such as expanded unsintered PTFE and compressing the films together around the conductor to form insulation 2.
- Compression is ordinarily carried out at room temperature in a roll nip under pressure.
- the resulting insulated wire is then subjected to a coating solution of the organic solvent solution of polyurethane by any usual means.
- One such means is by immersing the insulated wire into the solution and passing the wire continuously through the solution. Room temperature and pressures are conveniently used.
- the resulting insulated wire now is coated with primer coating 3.
- a film of extrudable polyurethane is next laminated to the assembly.
- a film of extruded polyurethane is applied to each side of the coated wire, which is preferably in ribbon or flat form, simultaneously and fused to each other at the edges to entirely encapsulate the coated, insulated wire assembly.
- the polyurethane films are thermally extruded into film form and brought into contact with the assembly in film form.
- the polyurethane film is applied hot, i.e., at nearly the extrusion temperature, which is about 180 ⁇ C.
- the two films are contacted with the wire construction by passing through the nip of two compression rollers.
- the resulting assembly is then cooled.
- the polyurethane jacket film finally bonds to itself at the edges of the final construction of this invention, and finally bonds to the polyurethane primer coating already on the assembly.
- the two PTFE layers are bonded by the sintering procedure.
- the laminated wire was then dipped in a solution of Estane 5703, a polyesterpolyurethane composition, and a solvent, methylene chloride.
- the solution was 8% by weight of polyesterpolyurethane.
- the line speed was 5 feet per minute. This step was carried out at room temperature and pressure.
- the wire was then dried in steps at 65 ⁇ C, then 90°C, and then 120°C. to insure uniform complete drying.
- the coated laminate was then covered by two layers of polyetherpolyurethane fi ⁇ m in a 1-1/2" Entwistle extruder with a 24 L/D ratio screw.
- the line speed was 3-5 RPM and the extrusion zone temperatures were 135 ⁇ C, 165 ⁇ C, 170 ⁇ C, & 180 ⁇ C with a die temperature of 160°C.
- the polyetherpolyurethane was melt extruded into two continuous films that were immediately applied to each side of the coated laminate. The combination was then passed through compression rollers to bond the polyetherpolyurethane layers together.
- the abrasion resistance of the cable assembly was determined by MIL-T-5438.
- the cable was too wide to fit the testing machine and was slit to provide 8 conductors.
- the side having 11.62-12.9 mils of insulation required 534 and 476 inches of abrasive tape to wear through, respectively.
- the side having 12.25-12.52 mils insulation required 512 inches of abrasive tape to wear through.
Abstract
An electrical cable of conductive wire having an insulating layer of microporous polymeric material around it, followed by a coating of a polyesterpolyurethane surrounding the insulating layer, and an outer film of polyetherpolyurethane surrounding the coating.
Description
TITLE
ELECTRICAL CABLE
FIELD OF THE INVENTION This invention relates to electrical cable and to a method for 5 preparing it.
BACKGROUND OF THE INVENTION Heretofore, conductive electrical wire, such as copper wire, has been coated with film of microporous, expanded polytetrafluoroethylene (PTFE) to provide an insulated wire. The 0 PTFE coating provided a low dielectric, flexible, chemically resistant protective covering surrounding the conductive wire. This assembly is then ordinarily provided with an outer insulative covering of full density, non-expanded polytetrafluoroethylene to provide a covering that is heat resistant, is chemically inert, is 5 resistant to being cut (called cut-through resistance) and is of long flex life. This configuration is particularly useful for flat or ribbon cable, such as is described in U.S. Patent 4,443,657.
It is desirable to provide a cable that has the attributes of o the above-described cable, has good flex life, and has substantially improved abrasion resistance and further improved cut-thru resistance.
The invention herein possesses these desirable features.
SUMMARY OF THE INVENTION 5 An electrical cable comprising:
(a) at least one conductive wire,
(b) an insulating layer surrounding the conductive wire, said insulating layer comprising microporous polymeric material, such as expanded sintered Q polytetrafluoroethylene,
(c) a coating of an organic solvent soluble polyurethane surrounding the insulating layer,
(d) a film covering and surrounding the coating comprising a film of an extruded polyurethane.
DESCRIPTION OF THE DRAWINGS
Figure 1 represents a three dimensional perspective view of one embodiment of the cable of this invention.
Figure 2 represents a cutaway enlarged view of the cable of
Figure 1 taken along line 2-2 of Figure 1.
DETAILED DESCRIPTION OF THE INVENTION
The cable of the present invention is particularly adaptable for use where ribbon or flat cable containing a plurality of parallel wire conductors in coplanar configuration are desired. One advantage of the cable of this invention is the excellent abrasion resistance that is achieved, while further improving the good cut-through resistance of previous cable constructions.
With reference to Figures 1 and 2, there is provided a plurality of center wire conductors 1, surrounded by insulation of low dielectric 2 which is a microporous polymer such as polytetrafluoroethylene made generally as described in U. S. Patent 3,953,566. Other microporous polymers useful herein include microporous polyolefins and other such polymers that are receptive to polyurethane primers.
Surrounding the insulation 2 is a layer of a polyurethane, 3 that is soluble in an organic solvent, such as polyester¬ polyurethane, for example, Estane number 5703 provided by B.F. Goodrich Co. This layer is ordinarily applied by solution coating, as for example, dip-coating the insulated wire in a solution of the polyesterpolyurethane. A typical solution of such polyurethane is a 5-20% by weight solution in a suitable organic solvent, such as a halogenated solvent, as for example, methylene chloride. Other suitable solvents include methyl ethyl ketone, toluene, N-methyl pyrollidone, dimethyl formamide, glycidyl methacrylate, tetrahydrofurane, and the like. Temperature and pressure are not critical.
The coating 3 is applied as a primer solution to enable the jacket coating 4 to be applied with ease and good adherab lity. The coating 3 works its way partially into the pores of the microporous, expanded polytetrafluoroethylene and provides a firm interlocking bond therewith, thus, providing a firm foundation for the jacket coating 4.
The jacket coating 4 is a layer of an extrudable polyurethane, such as a polyetherpolyurethane, as for example, Estane number 58202 supplied by B. F. Goodrich Co. which contains antimony trioxide flame retardant. The coating 4 is applied as a melt extruded film and is laminated to polyurethane coating 3 with the aid of compression rolls. Preferably, a common flame-retardant is added to the jacket film, but such is not absolutely necessary. The fabrication of the conductor wire entails the initial steps of embedding the conductor 1 in top and bottom inner films of microporous polymer, such as expanded unsintered PTFE and compressing the films together around the conductor to form insulation 2. Compression is ordinarily carried out at room temperature in a roll nip under pressure. The resulting insulated wire is then subjected to a coating solution of the organic solvent solution of polyurethane by any usual means. One such means is by immersing the insulated wire into the solution and passing the wire continuously through the solution. Room temperature and pressures are conveniently used. The resulting insulated wire now is coated with primer coating 3.
A film of extrudable polyurethane is next laminated to the assembly. Conveniently a film of extruded polyurethane is applied to each side of the coated wire, which is preferably in ribbon or flat form, simultaneously and fused to each other at the edges to entirely encapsulate the coated, insulated wire assembly.
Conveniently, the polyurethane films are thermally extruded into film form and brought into contact with the assembly in film form. Thus, the polyurethane film is applied hot, i.e., at nearly the extrusion temperature, which is about 180βC. The two films are contacted with the wire construction by passing through the nip of two compression rollers. The resulting assembly is then
cooled. Thus, the polyurethane jacket film finally bonds to itself at the edges of the final construction of this invention, and finally bonds to the polyurethane primer coating already on the assembly.
EXAMPLE 1
Twenty six conductors, each of 28 gauge 19 strand bare copper wire #135, spaced on .050 inch centers in a planar configuration, obtained from Hudson International Conductors, Inc., were continuously coated with two layers of expanded microporous, 10 mil thick PTFE tape obtained from W. L. Gore & Associates, Newark, Delaware, by passing the wires and the tape on each side thereof through the nip of two compression rolls at 80 lbs. pressure at a pull weight of 20 lbs., and then the PTFE layers were sintered by feeding into a bath of molten salt at a line speed of 15 feet per minute and then cooled by subjecting to water at 15°C. This procedure embeds the conductors between the two layers of PTFE tape. The two PTFE layers are bonded by the sintering procedure. The laminated wire was then dipped in a solution of Estane 5703, a polyesterpolyurethane composition, and a solvent, methylene chloride. The solution was 8% by weight of polyesterpolyurethane. The line speed was 5 feet per minute. This step was carried out at room temperature and pressure. The wire was then dried in steps at 65βC, then 90°C, and then 120°C. to insure uniform complete drying. The coated laminate was then covered by two layers of polyetherpolyurethane fiϊm in a 1-1/2" Entwistle extruder with a 24 L/D ratio screw. The line speed was 3-5 RPM and the extrusion zone temperatures were 135βC, 165βC, 170βC, & 180βC with a die temperature of 160°C. In operation, the polyetherpolyurethane was melt extruded into two continuous films that were immediately applied to each side of the coated laminate. The combination was then passed through compression rollers to bond the polyetherpolyurethane layers together.
The abrasion resistance of the cable assembly was determined by MIL-T-5438. The cable was too wide to fit the testing machine and was slit to provide 8 conductors.
The side having 11.62-12.9 mils of insulation required 534 and 476 inches of abrasive tape to wear through, respectively. The side having 12.25-12.52 mils insulation required 512 inches of abrasive tape to wear through. A conventional construction of a 16 strand ribbon cable wire having the microporous expanded PTFE insulation with a protective covering of unexpanded PTFE, in which the total thickness was about 12 mil, used only 222 inches and 218 inches, in two tests, of abrasive tape before the insulation was worn through (when the protective covering contained blue pigment) and only 153 inches and 166 inches (two tests) to wear through (when the protective covering contained grey pigment).
Wire coated in a similar manner as that set forth in Example I exhibited good flex life.
Claims
1 . An electrical cable compri sing:
(a) at l east one conductive wi re
(b) an i nsul ating layer surroundi ng the conductive wi re, sai d insulating layer compri sing a mi croporous polymeri c material ,
(c) a coating of an organic solvent soluble polyurethane surrounding the insulating layer,
(d) a film covering and surrounding the coating comprising a film of extruded polyurethane.
2. The cable of Claim 1 wherein the polyurethane coating is formed from a solution of a polyesterpolyurethane in an organic solvent.
3. The cable of Claim 1 wherein the extruded polyurethane film s a polyetherpolyurethane.
4. An electrical cable comprising a series of side-by-side parallel conductive wires arranged in a coplaner configuration to form a flat construction; said wires covered and surrounded by an insulative layer of expanded, microporous polytetrafluoroethylene; o said insulative layer containing an outer covering of a polyesterpolyurethane; said cable having a layer of polyetherpolyurethylene laminated to each side of said flat construction, so as to form a solid protective film coating surrounding the assembly within. 5 5. A process for making the cable of Claim 1 which comprises:
(a) applying microporous polymeric material around a conductive wire to form an insulative coating,
(b) subjecting the coated wire to a solution of an organic solvent soluble polyurethane and drying the resulting Q assembly,
(c) laminating film of an extruded polyurethane around said resulting assembly in a manner that encapsulates said assembly.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE90901402T DE68909614T2 (en) | 1988-12-20 | 1989-12-11 | ELECTRIC CABLE. |
JP90501589A JPH04503729A (en) | 1988-12-20 | 1989-12-11 | electric cable |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/286,919 US4924037A (en) | 1988-12-20 | 1988-12-20 | Electrical cable |
US286,919 | 1994-08-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1990007187A1 true WO1990007187A1 (en) | 1990-06-28 |
Family
ID=23100714
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1989/005642 WO1990007187A1 (en) | 1988-12-20 | 1989-12-11 | Electrical cable |
Country Status (6)
Country | Link |
---|---|
US (1) | US4924037A (en) |
EP (1) | EP0449959B1 (en) |
JP (1) | JPH04503729A (en) |
AU (1) | AU4814590A (en) |
DE (1) | DE68909614T2 (en) |
WO (1) | WO1990007187A1 (en) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4978813A (en) * | 1989-08-29 | 1990-12-18 | W. L. Gore & Associates, Inc. | Electrical cable |
US4988835A (en) * | 1989-10-16 | 1991-01-29 | W. L. Gore & Associates, Inc. | Polyvinylidene fluoride electrical cable |
US5025115A (en) * | 1990-05-22 | 1991-06-18 | W. L. Gore & Associates, Inc. | Insulated power cables |
US5223062A (en) * | 1990-12-03 | 1993-06-29 | Fujikura Ltd. | Resin-insulated cable and method for manufacturing the same |
CA2031676C (en) * | 1990-12-03 | 1995-10-17 | Kazuo Tanihira | Resin-insulated cable and method for manufacturing the same |
US5360944A (en) * | 1992-12-08 | 1994-11-01 | Minnesota Mining And Manufacturing Company | High impedance, strippable electrical cable |
AU2037597A (en) | 1996-03-21 | 1997-10-10 | Yorklite Limited | Electrical fittings for suspended ceilings |
US5744756A (en) * | 1996-07-29 | 1998-04-28 | Minnesota Mining And Manufacturing Company | Blown microfiber insulated cable |
US5945631A (en) * | 1996-09-16 | 1999-08-31 | Sony Corporation | IEEE 1394 active wall disconnect and aircraft qualified cable |
US6310286B1 (en) | 1996-09-16 | 2001-10-30 | Sony Corporation | Quad cable construction for IEEE 1394 data transmission |
US6296725B1 (en) | 1998-09-29 | 2001-10-02 | Litton Systems, Inc. | High frequency ribbon cable for twist capsule cable applications |
US6392155B1 (en) * | 1999-05-07 | 2002-05-21 | Hitachi Cable, Ltd. | Flat cable and process for producing the same |
US6730622B2 (en) * | 1999-12-21 | 2004-05-04 | The Procter & Gamble Company | Electrical cable |
US7002928B1 (en) | 2000-06-21 | 2006-02-21 | Sony Corporation | IEEE 1394-based protocol repeater |
US7542474B2 (en) * | 2001-02-26 | 2009-06-02 | Sony Corporation | Method of and apparatus for providing isochronous services over switched ethernet including a home network wall plate having a combined IEEE 1394 and ethernet modified hub |
JP2002313148A (en) * | 2001-04-06 | 2002-10-25 | Hitachi Cable Ltd | Flat cable |
US6717058B2 (en) * | 2002-04-19 | 2004-04-06 | Amphenol Corporation | Multi-conductor cable with transparent jacket |
AU2003272229A1 (en) * | 2002-08-19 | 2004-03-03 | Don W. Phillips | Ratchet with substantially silent movement-prevention mechanism |
WO2004051675A1 (en) * | 2002-12-02 | 2004-06-17 | Carl Freudenberg Kg | Three-dimensional moulded planar cable, method for production and use thereof |
CN102333572A (en) * | 2008-12-29 | 2012-01-25 | 德瓦尔工业公司 | Chemical barrier lamination and method |
US9065265B2 (en) * | 2010-01-25 | 2015-06-23 | Apple, Inc. | Extruded cable structures and systems and methods for making the same |
JP5578443B2 (en) * | 2011-04-21 | 2014-08-27 | 日立金属株式会社 | Multi-core shielded flat cable and method of manufacturing multi-core shielded flat cable |
JP5644716B2 (en) * | 2011-08-17 | 2014-12-24 | 日立金属株式会社 | Adhesive film and flat cable |
KR20160113603A (en) * | 2014-01-28 | 2016-09-30 | 니폰 덴신 덴와 가부시끼가이샤 | Vital sign detection garment |
US20160233006A1 (en) * | 2015-02-09 | 2016-08-11 | Commscope Technologies Llc | Interlocking ribbon cable units and assemblies of same |
CN105186155B (en) * | 2015-07-30 | 2018-04-13 | 凡甲电子(苏州)有限公司 | Wire and cable connector |
EP3408093B1 (en) | 2016-01-28 | 2023-08-02 | Rogers Corporation | Fluoropolymer composite film wrapped wires and cables |
US10324087B2 (en) | 2016-04-11 | 2019-06-18 | Universiteit Maastricht | Thermocouples comprising a polymer for detecting analytes and related methods |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE8633630U1 (en) * | 1986-12-16 | 1987-05-14 | Dietz, Volker, 8011 Baldham, De |
Family Cites Families (19)
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US3914363A (en) * | 1972-09-08 | 1975-10-21 | Raychem Corp | Method of forming self-limiting conductive extrudates |
US3792409A (en) * | 1973-04-02 | 1974-02-12 | Ransburg Corp | Electrostatic hand gun cable |
DE2320197C3 (en) * | 1973-04-19 | 1979-05-17 | Beiersdorf Ag, 2000 Hamburg | Process for the production of web-like or sheet-like materials with a carrier with a polyurethane self-adhesive layer |
US3857996A (en) * | 1973-06-18 | 1974-12-31 | Anaconda Co | Flexible power cable |
US3980807A (en) * | 1975-03-17 | 1976-09-14 | Northern Electric Company Limited | Polyurethane jacketing of metal sheathed cable |
DE2614807A1 (en) * | 1976-04-06 | 1977-10-20 | Kabel Metallwerke Ghh | Flexible electric cable with rubber sheath - has sheath covered with intermediate layer of plastics strips coated with polyurethane sleeve |
US4010619A (en) * | 1976-05-24 | 1977-03-08 | The United States Of America As Represented By The Secretary Of The Navy | Remote unmanned work system (RUWS) electromechanical cable system |
JPS54102514A (en) * | 1978-01-28 | 1979-08-13 | Osamu Ide | Automatic polarity inverting charge circuit system for static condenser |
US4281210A (en) * | 1978-02-15 | 1981-07-28 | Nl Industries, Inc. | Electrical devices containing a grease compatible, mineral oil extended polyurethane |
GB2051460A (en) * | 1979-05-01 | 1981-01-14 | Gore & Ass | Stripping cables |
US4250351A (en) * | 1979-08-08 | 1981-02-10 | The Bendix Corporation | Cable construction |
DE3020622C2 (en) * | 1980-05-30 | 1985-05-15 | W.L. Gore & Associates, Inc., Newark, Del. | Ribbon cable and process for its manufacture |
JPS5719529A (en) * | 1980-07-09 | 1982-02-01 | Toshiba Corp | High-frequency heater |
US4423282A (en) * | 1981-06-29 | 1983-12-27 | Hirosuke Suzuki | Flat cable |
US4529564A (en) * | 1982-08-23 | 1985-07-16 | Carlisle Corporation | Manufacture of low density sintered polytetrafluoroethylene insulated cable |
JPS6086515A (en) * | 1983-10-18 | 1985-05-16 | Junkosha Co Ltd | Light transmitting linear body and flat cable using it |
JPS60169904U (en) * | 1984-04-20 | 1985-11-11 | 株式会社 潤工社 | stripline cable |
JPS61203507A (en) * | 1985-03-06 | 1986-09-09 | 古河電気工業株式会社 | Thin covered wire |
JPS6321709A (en) * | 1986-07-14 | 1988-01-29 | 古河電気工業株式会社 | Manufacture of double-layer insulated wire |
-
1988
- 1988-12-20 US US07/286,919 patent/US4924037A/en not_active Expired - Fee Related
-
1989
- 1989-12-11 WO PCT/US1989/005642 patent/WO1990007187A1/en active IP Right Grant
- 1989-12-11 DE DE90901402T patent/DE68909614T2/en not_active Expired - Fee Related
- 1989-12-11 AU AU48145/90A patent/AU4814590A/en not_active Abandoned
- 1989-12-11 EP EP90901402A patent/EP0449959B1/en not_active Expired - Lifetime
- 1989-12-11 JP JP90501589A patent/JPH04503729A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE8633630U1 (en) * | 1986-12-16 | 1987-05-14 | Dietz, Volker, 8011 Baldham, De |
Also Published As
Publication number | Publication date |
---|---|
EP0449959B1 (en) | 1993-09-29 |
JPH04503729A (en) | 1992-07-02 |
DE68909614D1 (en) | 1993-11-04 |
EP0449959A1 (en) | 1991-10-09 |
DE68909614T2 (en) | 1994-04-28 |
AU4814590A (en) | 1990-07-10 |
US4924037A (en) | 1990-05-08 |
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