WO1998002397A1 - Lightweight-concrete roofing tile and process for producing the same - Google Patents

Lightweight-concrete roofing tile and process for producing the same Download PDF

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Publication number
WO1998002397A1
WO1998002397A1 PCT/JP1996/002005 JP9602005W WO9802397A1 WO 1998002397 A1 WO1998002397 A1 WO 1998002397A1 JP 9602005 W JP9602005 W JP 9602005W WO 9802397 A1 WO9802397 A1 WO 9802397A1
Authority
WO
WIPO (PCT)
Prior art keywords
synthetic resin
lightweight concrete
resin foam
concrete roof
roof tile
Prior art date
Application number
PCT/JP1996/002005
Other languages
French (fr)
Japanese (ja)
Inventor
Ichiro Nakajima
Kumiko Osugi
Original Assignee
Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP8014718A priority Critical patent/JPH09184247A/en
Priority claimed from JP8014718A external-priority patent/JPH09184247A/en
Application filed by Kanegafuchi Kagaku Kogyo Kabushiki Kaisha filed Critical Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
Priority to PCT/JP1996/002005 priority patent/WO1998002397A1/en
Publication of WO1998002397A1 publication Critical patent/WO1998002397A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D1/00Roof covering by making use of tiles, slates, shingles, or other small roofing elements
    • E04D1/02Grooved or vaulted roofing elements
    • E04D1/04Grooved or vaulted roofing elements of ceramics, glass or concrete, with or without reinforcement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00586Roofing materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density

Definitions

  • the present invention relates to light concrete tiles formed by processing lightweight concrete and a method for producing the same.
  • the above lightweight concrete tile uses an inorganic foam aggregate
  • the elastic deformation of the aggregate is small, and the lightweight concrete roof tile is formed at the time of kneading the inorganic foam aggregate and the cement or at the time of press molding, and a predetermined product is produced.
  • due to the presence of air bubbles there is a point that watertightness is inferior in freeze-thaw resistance and durability is reduced.
  • the water absorption of the inorganic foam aggregate is high, it is difficult to control the water cement ratio, and there is a problem that the bending strength is low.
  • the lightweight concrete roof tile of the present invention is obtained by molding and processing a hydraulic binder composition containing a synthetic resin foam as an aggregate, and has a specific gravity of approximately 1.6 to 2.0. It is characterized by.
  • synthetic resin foams can be made of crushed foamed synthetic resin or of irregular shape!
  • bead which has a spherical shape or a substantially spherical shape
  • the weight and volume measurement errors are smaller, and the specific gravity of the light-weight concrete tile mixed with this is reduced and the quality is stable. It is preferable because a broken roof tile can be obtained.
  • stress is applied to the lightweight concrete tile mixed with the synthetic resin foam, if a bead is used, this can be dispersed, and a high-strength concrete tile can be obtained.
  • stress concentration occurs and the strength is reduced. Therefore, it is desirable to use beads as much as possible.
  • the synthetic resin foam may have a mean diameter of about 0.1 to 2 mm [11, preferably about 0.1 to 1. A range of 5 mm is good. If it is less than about 0.1 mm, it becomes too small, and when kneading with water and a hydraulic binder, the fluidity of the kneaded material tends to decrease, and it is difficult to sufficiently secure the mixing amount of the synthetic resin foam. Therefore, it is likely that it is difficult to sufficiently reduce the weight of the roof tile containing this. Further, if the average diameter is about 2 mm or more, the number of synthetic resin foams per unit volume of the tile becomes small, and the strength tends to be weak. The average diameter in the case where the synthetic resin foam is a pulverized product or a rectangular shape is represented as an average value of the maximum length and the minimum length.
  • the synthetic resin foam is used as aggregate and mixed with at least cement and water.
  • the specific gravity of the roof tile obtained by molding and processing the obtained hydraulic binder composition is set to be approximately 1.6 to 2.0. When the specific gravity is less than about 1.6, it is extremely preferable from the viewpoint of weight reduction and heat insulation. However, since the mixing ratio of the synthetic resin foam increases, the flame retardancy (nonflammability) decreases. In both cases, the strength of the tiles tends to decrease, and the price tends to be expensive. If the specific gravity exceeds approximately 2.0, the tendency of the tiles becoming unfavorable from the viewpoint of weight reduction, cutting properties and heat insulation properties tends to be reduced. Have.
  • the water binder ratio (WZ C) of the hydraulic binder composite is preferably about 40% or less, and is preferably about 25% after dehydration molding.
  • the hydraulic binder such as cement is contained in the hydraulic binder composition at a volume ratio of about 20 to 35% by volume, preferably about 22 to 32% by volume, more preferably about 24 to 2% by volume. It is preferable to use 9% by volume.
  • the above-mentioned hydraulic binder composition is molded before curing to obtain a lightweight concrete roof tile.
  • the molding process is usually pressure molding, and specifically, a press mold.
  • frame forming processing and extrusion forming processing using an extruder which method to use is appropriately selected mainly depending on the desired product shape.
  • various processing methods such as sheet forming process and casting forming process may be used.
  • the concrete is cured by a normal curing process performed on a normal concrete product, for example, by curing in the air, underwater, or steam, or in an autoclave, and used as a product.
  • a normal concrete roof uses a light synthetic resin foam, the strength of the roof is reduced. Without it, roof tiles—the effect of reducing the amount can be obtained. This facilitates the work of transporting, unloading, and holding the roof tiles, and improves work efficiency.
  • we in order to reduce the load on buildings such as houses, we will not only reduce the size of the rafters that support the tiles at the ii'i junction, but also reduce the size of all structural members such as columns, beams, and foundations be able to. It is especially useful for eaves that require a large eave.
  • Another lightweight concrete roof tile according to the present invention is characterized in that the synthetic resin foamed aggregate has an average particle diameter of about 2 mra or less as beads and is a lightweight concrete roof tile. That is, when the synthetic resin foam is formed into a spherical or substantially spherical bead-like particle shape, the synthetic resin foam hardly collapses at the time of kneading or press molding, so that the designed product dimensions can be obtained. Also, since the particle size is small, it can be mixed well with cement to obtain a product with uniform density.
  • the average particle size is about 2 ⁇ or less, more preferably about 1.5 ⁇ or less, and most preferably about 1 ram or less.
  • the reason is that the buoyancy of the synthetic resin foam can be reduced by setting the average particle size to a small particle size of about 2 iniD or less, so that the lift of the synthetic resin foam in the hydraulic binder composition is effective.
  • the synthetic resin foam is evenly mixed with cement and water And a product having an average density is obtained, and the fluidity of the hydraulic binder composition is excellent.
  • the synthetic resin foam preferably has a mean particle size of about 0.1 to from the viewpoint of fluidity and dispersibility.
  • another lightweight concrete roof tile is a lightweight concrete roof tile using expanded particles of expandable polystyrene (EPS) as the synthetic resin foam.
  • synthetic resins used as raw materials for synthetic resin foams include styrene resins such as polystyrene, olefin resins such as polypropylene and polyethylene, acrylnitrile-styrene copolymer, styrene-ethylene copolymer, and the like. (Including random, block, graft, etc.), polyvinyl chloride, polyvinyl chloride resin such as polyvinylidene chloride, etc. Power, especially if foamed EPS particles are ffl, bead It is the most desirable because it is strong and cheap.
  • Another lightweight concrete roof tile according to the present invention is characterized in that the true specific gravity (hereinafter, simply referred to as specific gravity) of the synthetic resin foam is approximately 0.07 to 0.12. That is, if the specific gravity is in the range of about 0.07 to 0.12,
  • Another lightweight concrete roof tile according to the present invention is characterized in that the obtained lightweight concrete roof tile contains a synthetic resin foam at a capacity of approximately 10 to 30%.
  • the mixing amount of the synthetic resin foam is more preferably in the range of about 0 to 20%, and more preferably in the range of about 14 to 18%. At less than about 10% It tends to have an unfavorable tendency from the viewpoints of weight reduction, cutability and heat insulation. On the other hand, if it exceeds about 30%, it is extremely preferable from the viewpoint of weight reduction and heat insulation, but the flame retardancy (non-combustibility) decreases as the mixing ratio of synthetic resin foam increases. However, the strength of the tiles tends to decrease and the price tends to be high.
  • Still another lightweight concrete roof tile according to the present invention is characterized in that the obtained lightweight concrete roof tile contains fine aggregate such as sand in a volume of approximately 10 to 40%.
  • fine aggregate is mixed in order to improve the shape retention function of the hydraulic binder composition.
  • This fine aggregate in addition to the normal Sakugawa as a fine aggregate, also reduces the amount of deformation caused by the shrinkage of the synthetic resin foam inside / out of the hydraulic binder during molding. Play a role.
  • the synthetic tree foam is tt 'shrunk-it buckles if it deforms beyond a certain ffi, but it has the effect of restoring after pressure release, so small irregularities or micro-mouth cracks are likely to occur on the surface of the product,
  • the mixing of fine aggregate absorbs the pressure applied from the outside and reduces the deformation and buckling of the synthetic resin foam, thereby preventing the shape from changing after the pressure is released and providing the advantage of a smooth surface. It is preferable to use fine aggregate.
  • the particle diameter of ffl usually used as a fine aggregate for concrete is 5 mm or less, and the specific gravity may be, for example, in a range of about 2.6, and the type thereof may be different.
  • the specific gravity may be, for example, in a range of about 2.6, and the type thereof may be different.
  • a furnace slag fine aggregate (grain size of about 5 mm or less, specific gravity of about 2.0 to 2.6, for example) or JIS as specified in JIS A 5012, or JIS A lightweight fine concrete aggregate for structural use specified in A5002 (particle size of about 5 ⁇ or less, specific gravity of, for example, about 1,3 to 2.3) can be used.
  • the content of fine aggregate in the lightweight concrete tile is The absolute volume is preferably in the range of about 10 to 40%, more preferably in the range of about 20 to 35%, and most preferably in the range of about 27 to 31%. If the fine aggregate content ffi is less than about 10%, the synthetic resin foam will buckle and tilt during the molding process. In some cases, micro cracks are generated, and the llfl strength / metaphysical property is reduced. On the other hand, if the content of fine aggregate exceeds about 40%, it becomes less desirable from the viewpoint of lightening, cutting properties and heat insulation.
  • the total amount of the fine aggregate and the synthetic resin foam mixed is about 40 to 50% in absolute volume in the obtained tile. A good result is obtained. The reason for this is that if it is less than about 40%, the amount of dewatering tends to increase during pressure molding, and the thickness of the product may be reduced. If the total of the above-mentioned mixed S exceeds about 50%, the fluidity tends to decrease.As a result, when adding: it takes a long time during molding, or when the filling of the mold becomes poor. Because it can happen. In the present invention, the specific gravity of the hydraulic binder composition and the specific gravity of the lightweight concrete roof tile obtained by molding and curing this compact are almost the same.
  • the water in the composition for example, water binder ratio (WZ C) is 40%
  • the (W / C) is, for example, 25%
  • the specific gravity of the tile is increased by, for example, 0.1 mm, compared to the composition, Due to the hardening and drying of the tile after dehydration molding, about 5 to 6% of water is discharged from the tile in an Itffi ratio of 5 to 6% (in this case, the volume of the tile hardly changes). Is reduced by about 0.1 mm, the specific gravity of the hydraulic binder composition is substantially equal to the specific gravity of the obtained tile.
  • the hydraulic binder is cement. It is characterized by the following. That is, cement, lime, gypsum, adhesives, etc. can be cited as the hydraulic binder that solidifies the synthetic resin foam as an aggregate, but the cement among them is strong, has excellent water resistance, and is relatively Most desirable because it is inexpensive.
  • Portland cement such as ordinary Portland cement, single strength Portland cement, ultra-high strength Portland cement, medium heat Portland cement, etc., or a mixture of blast furnace cement, silica cement, fly ash cement, etc.
  • Special cement such as cement or ultra-high-strength cement, expansion cement, cosmetic cement (white cement, power cement, etc.), or alumina cement can be used, and it is preferable to use properly depending on the application. .
  • Still another lightweight concrete roof tile according to the present invention is characterized in that it is a light concrete tile in which a fiber reinforcing material is mixed in an absolute volume of approximately 0.2 to 0.6%.
  • a fiber reinforcing material By mixing a predetermined amount of the fiber reinforcing material, a tough and light-weight concrete roof tile having high bending strength can be obtained.
  • the fiber reinforcing material include alkali-resistant glass fiber, vinylon fiber, nylon fiber, and polypropylene fiber.
  • Another lightweight concrete roof tile according to the present invention is characterized in that alkali-resistant glass fibers are mixed as a fiber reinforcing material. That is, the alkali-resistant glass fiber is particularly preferably used because it has a high bending strength and is resistant to alkali.
  • the length of the alkali-resistant glass fiber is preferably about 10 mm to 20 mm on average, but is not particularly limited. If the mixing ratio of the fiber reinforcing material such as alkali-resistant glass fiber is less than approximately 0.2% in absolute volume, the bending strength is weak, and if it exceeds approximately 0.6%, the mortar fluidity tends to decrease. However, the press molding time may be longer, and the filling cost may be worse and the production cost may be higher. It is.
  • Another lightweight concrete roof tile according to the present invention is characterized in that fly ash and / or blast furnace slag are mixed with approximately 10 to 35% by weight of the amount of cement bacteria. That is, by mixing fly ash, Z or blast furnace slag, etc., the alkalinity of the cement is reduced, which is expected to have the effect of increasing the durability of fiber reinforcing materials including glass fibers. . Also, if fly ash or the like is mixed into the cement, the fluidity is improved, the surface becomes more beautiful, and there is an advantage that synthetic resin foam is less likely to appear on the tile surface. Further, the long-term strength is improved, and a strong roof tile can be obtained.
  • the mixing amount of fly ash and Z or blast furnace slag is preferably about 10 to 35%, preferably about 15 to 35% with respect to the weight of cement, and preferably about 20 to 27%. Is most preferred. If the mixing ratio exceeds approximately 35% by weight, the initial strength tends to decrease. Conversely, if the mixing ratio is lower than approximately 10% by weight, the effect of mixed people is poor.
  • These fly ash powders have a specific surface area of about 240 OcmVg or more, and the blast furnace slag has a specific surface area of about 300 on 2 / g.
  • Another lightweight concrete roof tile comprises a lightweight concrete aggregate obtained by solidifying a plurality of synthetic resin foam particles with a hydraulic binder, water, a hydraulic binder, and a synthetic resin foam. It is characterized by being molded from a lightweight concrete.
  • a plurality of synthetic resin foams are hardened with a hydraulic binder to form an integrated lightweight concrete aggregate, so that pressure is applied during press forming. Also protects the synthetic resin foam from crushing, so that it hardly shrinks during pressure molding or swells after pressure is released after pressure molding. '' Getting the goods Can be done.
  • Examples of the lightweight concrete aggregate include those described in Japanese Patent Application No. 6-71031 proposed by the present applicant earlier.
  • the synthetic resin foam or hydraulic binder used for the lightweight concrete aggregate the same ones as described above can be used.
  • Water was added to such a synthetic resin foam and hydraulic binder, and the water binder ratio (WZ C) was adjusted so that the water absorption was small, the expansion due to water absorption was small, and the strength was strong.
  • WZ C water binder ratio
  • is less than or equal to 5 and more preferably less than or equal to 3 (for example, using a bread-type granulator: see Japanese Patent Application No. 8-12085). Then, it is cured so that the true ratio is in the range of 0.8 to 1.5.
  • the proportion of light concrete aggregate can be selected as appropriate depending on the desired product weight reduction ⁇ , but it is sufficient if the volume ratio is about 15 to 50%. .
  • the water binder ratio (W / C) is preferably 40% or less, which is appropriately selected depending on the type of product, from the viewpoint of strength.
  • synthetic resin foam and hydraulic binder composition mainly composed of water, various admixtures such as AE agent, water reducing agent , AE water reducing agent, high-performance AE water reducing agent, etc., can improve the llll strength, for example, by about 10%, stabilize the product K, and obtain more favorable results.
  • the obtained lightweight concrete tile may be subjected to an acrylic coating or the like in order to improve the surface appearance.
  • a method of manufacturing a lightweight concrete roof tile according to the present invention is characterized in that the lightweight concrete roof tile is manufactured by press forming. Thereby, molding can be performed smoothly.
  • the pressure molding process has a pressing force of approximately 5 O kgf / cm 2 It is preferable to use the press mold forming process described above. That is, if the pressing force is less than about 5 Okgf / cm 2 , the pressing time is likely to be long, and there is a tendency that trouble is likely to occur in smooth forming, which is not preferable.
  • the press mold forming process has an advantage that a product having a complicated shape which cannot be formed by an extrusion forming process can be easily formed. In addition, in order to obtain the wooden tile of the present invention in a favorable manner, adjustment of the pressing force at the time of molding often has a great significance.
  • the pressing force is formed at approximately 120 to 150 k ⁇ cm 2 , and when the pressing force is 120 kgf Z cm 2 or less, the strength is reduced.
  • molding can be performed in a range of about 50 kgf / cm 2 or more, more preferably about 70 kgf / cm 2 or more, so that molding can be performed even with a press machine having a small press capacity.
  • Tables 1 to 3 below show examples which are examples of blending of the hydraulic binder composition used as the material of the lightweight concrete roof tile of the present invention. Shown together.
  • EPS or EPS beads represent expanded particles of expandable polystyrene beads.
  • the synthetic resin foam had an average diameter of 0.06, 0.10, and 0.15 obtained by expanding polystyrene. 9 mm beads (EPS beads).
  • a 13 mm alkali-resistant glass fiber was used as a fiber reinforcing material. River sand with a diameter of 2.5 mm or less was used as the sand.
  • the lightweight concrete aggregate the same synthetic resin foam, ordinary Portland cement and water as described above are kneaded at a water binder ratio of about 25% and hardened. The shape and the true specific gravity of 1.5 were used. It cured by steam curing after molding tiles applying a pressure of lightweight concrete Ichiboku press mold molding at 7 0 kgf / ciD 2 which was formulated as above.
  • Tables 4 to 6 show the characteristics of the roof tiles of the above Examples 6 to 6 compared with Comparative Examples 1 to 7.
  • Bending strength (kgi / sheet) 280 180 210 130
  • Non-combustibility Passed Passed Passed Fail JIS A 1321) X Cutability Good Good Good Good Nailability Good Good Good Small thickness Formability Good Good Density variation Good Tsukidai
  • the lightweight concrete roof tile of the embodiment of the present invention is smaller in size than the conventional concrete roof tile which is a comparative example, Yes It is ffl.
  • the flexural strength has a slightly lower value, it is sufficient for practical use.
  • Example 3 the surface property was reduced due to the mixture of fly ash, and in Example 4, the bending strength was maximized due to the mixing of Al-resistant glass fiber.
  • Comparative Example 4 no sand was used, and in Comparative Example 5, cracks tended to occur on the surface of the tile, and the flexural strength was low due to the low EPS efficiency. .
  • Example 3 the EPS beads were reduced to 1.2 mm. 7 mm.
  • An experiment was performed in which the size exceeded 2 mm but was changed to class 3 only.
  • the one having a thickness of 1.2 mm is preferable because the surface properties are good and the surface unevenness is small.
  • the one with 1.7 mm can be mixed as a hydraulic binder composition, and the product can be easily manufactured, but some surface irregularities were observed.
  • the thickness exceeds 2 mm, the composition tends to be easily separated, and it is necessary to pay attention to the mixing.
  • those having a large amount of S containing sand, such as Comparative Example I and Comparative Example 7, tended to decrease the cutting properties and nailing properties.
  • a tile having good nailing property means a tile in which nails can easily pass through the tile and the tile is not easily cracked by nailing.
  • the lightweight concrete tile according to the present invention can be suitably used as a roof tile of a house or the like, particularly at a site where a reduction in weight is required.

Abstract

Lightweight-concrete roofing tiles made by molding a hydraulic binder composition containing synthetic resin foams as the aggregate and having a specific gravity of about 1.6 to 2. A preferably example of the aggregate is beads of the resin foams having an average particle size of about 2 mm or less, while a suitable example of the foams is polystyrene foams.

Description

明 細 書 軽量コンクリー卜瓦及びその製造方法 技術分野  Description Lightweight concrete roof tile and method of manufacturing the same
この発明は、 軽量コンクリー卜を成形加工してなる軽厳コンクリート 瓦及びその製造方法に関する。 背景技術  BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to light concrete tiles formed by processing lightweight concrete and a method for producing the same. Background art
従来のセメン卜系の瓦は、 例えば、 厚形スレートとして JIS A 5402 に示されるように、 セメント、 水及び砂などの細骨材を混練して成形し 硬化させたものが一般的に使用されていたが、 重くて切断が困難でしか も断熱性に劣る欠点があるために、 これらの欠点を解消すべく、 ¾近に 至り、 例えば、 日本国特公昭 6 1— 3 〗 0 7 5号に示されるような断熱 性や軽量化を目的として、 無機質発泡骨材などを混入した軽量コンクリ 一ト瓦が提案されるに至っている。  Conventional cement-based roof tiles are generally formed by kneading and hardening fine aggregates such as cement, water and sand as shown in JIS A 5402 as a thick slate. However, it was heavy and difficult to cut, but it had poor heat insulation properties. Therefore, to solve these drawbacks, we came close to solving the problem. For example, Japanese Patent Publication No. Sho 61-3-075 Lightweight concrete roof tiles mixed with inorganic foamed aggregates have been proposed for the purpose of heat insulation and weight reduction as shown in (1).
しかしながら、 上記軽量コンクリ一卜瓦は、 無機発泡骨材を用いてい るため、 当該骨材の弾性変形が小さく、 無機発泡骨材とセメン卜の混練 時やプレス成形加工時に溃され、 所定の製品寸法を得ることができず、 又、 大きな軽量化を図ることができないという問題点がある。 更に気泡 が存在することから、 水密性ゃ凍結融解抵抗性が劣り、 耐久性が低下す るという ^题点がある。 加えて、 無機発泡骨材の吸水性が高いため、 水 セメン卜比の管理が難しく、 曲げ強度が低くなるという問题点がある。 この発明は、 かかる問題点を解決し、 軽量でしかも耐久性があり製造 も簡 i|にできる軽量コンクリ一ト瓦及びその製造方法を提供することを 的としている。 発明の開示 本発明の軽量コンクリ一ト瓦は、 合成樹脂発泡体を骨材として含有す る水硬性結合材組成物を成形加工してなり、 比重を略 1 . 6乃至 2 . 0 としたことを特徴とする。 However, since the above lightweight concrete tile uses an inorganic foam aggregate, the elastic deformation of the aggregate is small, and the lightweight concrete roof tile is formed at the time of kneading the inorganic foam aggregate and the cement or at the time of press molding, and a predetermined product is produced. There are problems that dimensions cannot be obtained and that a large reduction in weight cannot be achieved. Furthermore, due to the presence of air bubbles, there is a point that watertightness is inferior in freeze-thaw resistance and durability is reduced. In addition, since the water absorption of the inorganic foam aggregate is high, it is difficult to control the water cement ratio, and there is a problem that the bending strength is low. It is an object of the present invention to provide a lightweight concrete roof tile which solves such a problem, is lightweight and durable and can be manufactured easily, and a method for manufacturing the same. DISCLOSURE OF THE INVENTION The lightweight concrete roof tile of the present invention is obtained by molding and processing a hydraulic binder composition containing a synthetic resin foam as an aggregate, and has a specific gravity of approximately 1.6 to 2.0. It is characterized by.
ここで使用する合成樹脂発泡体の原料としては種々の公知ものが使用 でき、 特に限定されるものではない。 又、 合成樹脂発泡体は、 発泡合成 樹脂を粉砕した粉碎品や異形のものであつても! ¾いが、 球形又は略球形 の、 いわゆる、 ビーズに形成したものの方が、 重量及び容積の計量誤差 が少なく、 これを混人した軽量コンクリ一ト瓦の比重のバラツキが少な くなり品質の安定した瓦を得ることができるので好ましい。 また、 前記 合成樹脂発泡体を混入した軽量コンクリ一卜瓦に応力がかかった場合、 ビ一ズであればこれを分散させることができ、 強度の高いコンクリ一卜 瓦を得ることができるが、 粉砕品や異形の場合には応力集中が生じ、 強 度が くなるので、 できるだけビーズであることが望ましい。  Various known materials can be used as the raw material of the synthetic resin foam used here, and it is not particularly limited. Also, synthetic resin foams can be made of crushed foamed synthetic resin or of irregular shape! In the case of a so-called bead, which has a spherical shape or a substantially spherical shape, the weight and volume measurement errors are smaller, and the specific gravity of the light-weight concrete tile mixed with this is reduced and the quality is stable. It is preferable because a broken roof tile can be obtained. Further, when stress is applied to the lightweight concrete tile mixed with the synthetic resin foam, if a bead is used, this can be dispersed, and a high-strength concrete tile can be obtained. In the case of a crushed product or an irregular shape, stress concentration occurs and the strength is reduced. Therefore, it is desirable to use beads as much as possible.
[-Ί成樹脂発泡体は粉砕品、 異形、 ビーズのいずれの場合であっても、 その平均径が略 0 . 1乃至 2 m mの範 [11、 ¾に好ましくは略 0 . 1乃至 1 . 5 m mの範囲が良い。 略 0 . 1 m m以下になれば小さくなり過ぎて 、 水及び水硬性結合材との混練時に、 混練物の流動性が下がり易く、 合 成樹脂発泡体の混入量を充分に確保するのが困難であるため、 これを混 入した瓦を充分に軽量化することが難しくなり易い。 又、 前記平均径が 略 2 m m以上となれば、 瓦の単位体積当たりの合成樹脂発泡体の個数が 少なくなるため、 強度的に弱くなる傾向があるので、 あまり好ましくな い。 尚、 前記合成樹脂発泡体が粉砕品、 ¾形である場合の平均径は、 最 大 と最小長の平均値として表わしている。  [-The synthetic resin foam may have a mean diameter of about 0.1 to 2 mm [11, preferably about 0.1 to 1. A range of 5 mm is good. If it is less than about 0.1 mm, it becomes too small, and when kneading with water and a hydraulic binder, the fluidity of the kneaded material tends to decrease, and it is difficult to sufficiently secure the mixing amount of the synthetic resin foam. Therefore, it is likely that it is difficult to sufficiently reduce the weight of the roof tile containing this. Further, if the average diameter is about 2 mm or more, the number of synthetic resin foams per unit volume of the tile becomes small, and the strength tends to be weak. The average diameter in the case where the synthetic resin foam is a pulverized product or a rectangular shape is represented as an average value of the maximum length and the minimum length.
前記合成樹脂発泡休を骨材として川い、 少なくともセメン卜と水に混 合し、 得られた水硬性結合材組成物を成形加工して得られる瓦の比重が 略 1 . 6乃至 2 . 0になるようにする。 比重が略 1 . 6未満であれば、 軽量化及び断熱性の観点からは極めて好ましいものとなるが、 合成樹脂 発泡体の混合割合が多くなることから、 難燃性 (不燃性) が低下すると 共に瓦の強度が低下し、 また価格的にも高価なものとなる傾向があり、 また、 比重が略 2 . 0を超えれば、 軽量化及び切断性や断熱性の観点か ら好ましくなくなる傾向を有する。 The synthetic resin foam is used as aggregate and mixed with at least cement and water. The specific gravity of the roof tile obtained by molding and processing the obtained hydraulic binder composition is set to be approximately 1.6 to 2.0. When the specific gravity is less than about 1.6, it is extremely preferable from the viewpoint of weight reduction and heat insulation. However, since the mixing ratio of the synthetic resin foam increases, the flame retardancy (nonflammability) decreases. In both cases, the strength of the tiles tends to decrease, and the price tends to be expensive. If the specific gravity exceeds approximately 2.0, the tendency of the tiles becoming unfavorable from the viewpoint of weight reduction, cutting properties and heat insulation properties tends to be reduced. Have.
のような合成樹脂発泡体、 水硬性結合材等に水を加えた水硬性結 trj 材糾成物を、 所定の瓦の形状となるように脱水成形加工し硬化させて、 その比 ffiを略 1 . 6乃至 2 . 0の範囲とした。 尚、 前記水硬性結合材糾 成物の水結合材比 (WZ C ) は、 略 4 0 %以下が好ましく、 脱水成形後 、 略 2 5 %前後にすることが好適である。 セメン卜等の水硬性結合材は 、 水硬性結合材組成物中に容積比で、 略 2 0乃至 3 5容量%、 好ましく は略 2 2乃至 3 2容量%、 更に好ましくは略 2 4乃至 2 9容量%用いら れるのが好適である。  Hydraulically bonded trj material obtained by adding water to a synthetic resin foam, hydraulic binder, etc., as described above, is dehydrated and formed into a specified roof tile shape and cured, and the ratio ffi is substantially reduced. The range was 1.6 to 2.0. The water binder ratio (WZ C) of the hydraulic binder composite is preferably about 40% or less, and is preferably about 25% after dehydration molding. The hydraulic binder such as cement is contained in the hydraulic binder composition at a volume ratio of about 20 to 35% by volume, preferably about 22 to 32% by volume, more preferably about 24 to 2% by volume. It is preferable to use 9% by volume.
上記水硬性結合材組成物を、 硬化する前に成形加工することによって 軽量コンクリート瓦を得るのであるが、 この場合の成形加工は、 通常、 加圧成形であって、 具体的には、 プレス型枠成形加工、 押出機を使用し た押し出し成形加工があるが、 いずれを採 Wするかは、 主として求める 製品の形状によって適宜選択される。 尚、 上記プレス型枠成形加工など の他に、 抄造成形加工、 キャスティ ング成形加工等の各種加工法を用い てもよい。  The above-mentioned hydraulic binder composition is molded before curing to obtain a lightweight concrete roof tile. In this case, the molding process is usually pressure molding, and specifically, a press mold. There are frame forming processing and extrusion forming processing using an extruder. Which method to use is appropriately selected mainly depending on the desired product shape. In addition, in addition to the above-described press mold forming process, various processing methods such as sheet forming process and casting forming process may be used.
成型後は、 通常のコンクリート製品になされる通常の養生工程、 例え ば、 気中養生もしくは水中赉生または蒸気養生或いはォートクレーブ養 生等することにより養生が施され、 製品として使用される。 この軽量コ ンクリ一卜瓦は、 軽い合成樹脂発泡体を用いているため、 瓦強度を低下 させず、 瓦 —量が軽減するという効架を得ることができる。 これによつ て、 瓦の運搬、 荷揚げ、 横もちなどの作業が楽になり、 作業能率が向上 する。 また、 家屋等の建造物にかかる荷 が軽減されるために、 ii'i接に 瓦を支える垂木の寸法の縮小化のみならず、 柱、 梁、 基礎等全ての構造 部材の縮小化を図ることができる。 特に、 庇を大きく出したい塲合など には有用である。 After molding, the concrete is cured by a normal curing process performed on a normal concrete product, for example, by curing in the air, underwater, or steam, or in an autoclave, and used as a product. Since this lightweight concrete roof uses a light synthetic resin foam, the strength of the roof is reduced. Without it, roof tiles—the effect of reducing the amount can be obtained. This facilitates the work of transporting, unloading, and holding the roof tiles, and improves work efficiency. In addition, in order to reduce the load on buildings such as houses, we will not only reduce the size of the rafters that support the tiles at the ii'i junction, but also reduce the size of all structural members such as columns, beams, and foundations be able to. It is especially useful for eaves that require a large eave.
また、 吸水性の殆どない合成樹脂発泡体を使用しているために、 製造 時における水と水硬性結合材との it最比の^卯も容 である。 加えて、 合成樹脂発泡体を含んでいるので、 断熱効果が生じて建造物内部への熱 の伝達を減少させることが可能となり、 その分だけ冷暖房費の節減を計 ることができる。  In addition, since a synthetic resin foam having almost no water absorption is used, the ratio of water to the hydraulic binder at the time of manufacture is also acceptable. In addition, since it contains a synthetic resin foam, a heat insulation effect is generated, and it is possible to reduce the transfer of heat to the inside of the building, thereby reducing the cost of cooling and heating.
史に、 踞などによる切断が容 にできるために、 隅部などにおいて瓦 を形状に合わせて切断する場合の加工作業が極めて容易にできる。 又、 釘打ちしても割れにくいために、 予め釘の貫通穴を設けておく必要がな いので、 成形加工が容易である。  In the past, since cutting by tsutsu, etc. can be easily performed, the work of cutting a tile in a corner or the like according to the shape can be extremely easily performed. Also, since it is difficult to break even when nailed, there is no need to provide a through hole for the nail in advance, so molding is easy.
本発明の他の軽量コンクリ―ト瓦は、 前記合成樹脂発泡休の骨材の平 均粒径が、 略 2 mra以下のビーズとした軽量コンクリ一ト瓦としたことを 特徴とする。 すなわち、 前記合成樹脂発泡体を球形又は略球状のビーズ 状の粒形状とすることによって、 混練時やブレス成形加工時に合成樹脂 発泡体が潰れ難いので、 設計通りの製品寸法が得られる。 また、 粒径が 小さいので、 セメン卜と良く混ざり密度の均一した製品が得られる。 前記平均粒径は略 2咖以下であるが、 より好ましくは略 1 . 5 πππ以下 、 最も好ましくは略 1 ram以下とする。 その理由は、 平均粒径を略 2 iniD以 下の小粒形状とすることによって、 合成樹脂発泡体の浮力を小さくでき るので、 水硬性結合材組成物中での合成樹脂発泡体の浮き上がりを有効 に阻止でき、 その結果、 合成樹脂発泡体が均一にセメントと水の混合物 に分散し、 密度の平均した製品が得られること、 及び水硬性結合材組成 物の流動性が優れることである。 尚、 合成樹脂発泡体は、 平均粒径略 0 . 1乃至】匪のものが、 流動性や分散性の観点からも好ましい。 Another lightweight concrete roof tile according to the present invention is characterized in that the synthetic resin foamed aggregate has an average particle diameter of about 2 mra or less as beads and is a lightweight concrete roof tile. That is, when the synthetic resin foam is formed into a spherical or substantially spherical bead-like particle shape, the synthetic resin foam hardly collapses at the time of kneading or press molding, so that the designed product dimensions can be obtained. Also, since the particle size is small, it can be mixed well with cement to obtain a product with uniform density. The average particle size is about 2 咖 or less, more preferably about 1.5 πππ or less, and most preferably about 1 ram or less. The reason is that the buoyancy of the synthetic resin foam can be reduced by setting the average particle size to a small particle size of about 2 iniD or less, so that the lift of the synthetic resin foam in the hydraulic binder composition is effective. As a result, the synthetic resin foam is evenly mixed with cement and water And a product having an average density is obtained, and the fluidity of the hydraulic binder composition is excellent. The synthetic resin foam preferably has a mean particle size of about 0.1 to from the viewpoint of fluidity and dispersibility.
本 ¾明の Φに他の軽置コンクリ一卜瓦は、 前記合成樹脂発泡体として 、 発泡性ポリスチレン (E P S : Expandable Polystyrene) の発泡粒子 を用いた軽量コンクリ一卜瓦としたことを特徴とする。 すなわち、 合成 樹脂発泡体の原料となる合成樹脂としては、 ポリスチレンなどのスチレ ン系樹脂、 ポリプロピレン、 ポリエチレンなどのォレフィ ン系樹脂、 ァ クリル二トリル一スチレン共重合体、 スチレン一エチレン共重合体など の各 ΐυΐτίβ合休 (ランダム、 ブロック、 グラフト休などを含む) 、 ポリ 塩化ビニル、 ポリ塩化ビニリデンなどの塩化ビニル系樹脂などが挙げら れる力 特に E P Sの発泡粒子を fflいた場合には、 ビーズの強度が強く 、 安価であることから最も望ましいものとなる。  In the present invention, another lightweight concrete roof tile is a lightweight concrete roof tile using expanded particles of expandable polystyrene (EPS) as the synthetic resin foam. . That is, synthetic resins used as raw materials for synthetic resin foams include styrene resins such as polystyrene, olefin resins such as polypropylene and polyethylene, acrylnitrile-styrene copolymer, styrene-ethylene copolymer, and the like. (Including random, block, graft, etc.), polyvinyl chloride, polyvinyl chloride resin such as polyvinylidene chloride, etc. Power, especially if foamed EPS particles are ffl, bead It is the most desirable because it is strong and cheap.
本発明の他の軽量コンクリ一ト瓦は、 前記合成樹脂発泡体の真比重 ( 以下、 単に比重と呼ぶ) を、 略 0 . 0 7乃至 0 . 1 2としたことを特徴 とする。 すなわち、 前記比重を略 0 . 0 7乃至 0 . 1 2の範囲とすれば Another lightweight concrete roof tile according to the present invention is characterized in that the true specific gravity (hereinafter, simply referred to as specific gravity) of the synthetic resin foam is approximately 0.07 to 0.12. That is, if the specific gravity is in the range of about 0.07 to 0.12,
、 適度な強度が得られることに加えて、 経済的にも比校的安価に製造で きる。 これを発泡倍率に換算すると、 およそ 8乃至 1 5倍の範囲内であ る。 比 が略 0 . 0 7未満であると完成した製品の強度が弱くなる傾 となり、 逆に略 0 . 1 2を超えると強度の観点からは優れたものとはな るものの、 難燃性 (不燃性) が低下すると共に材料コストが高くなる傾 向を有する。 In addition to obtaining appropriate strength, it can be manufactured economically at a low cost. When this is converted into the expansion ratio, it is in the range of about 8 to 15 times. If the ratio is less than about 0.07, the strength of the finished product tends to be weak. Conversely, if it exceeds about 0.12, the strength of the finished product is excellent, but the flame retardancy ( (Incombustibility) and material costs tend to increase.
本発明の他の軽量コンクリ一ト瓦は、 得られた軽量コンクリ一卜瓦中 に合成樹脂発泡体を略 1 0乃至 3 0 %の容量で含有したことを特徴とす る。 合成樹脂発泡体の混入量は、 一層好ましくは略〗 0乃至 2 0 %の範 、 も好ましくは略 1 4乃至 1 8 %の範^とする。 略 1 0 %未満では 、 軽量化及び切断性や断熱性の観点から好ましくない傾向を持ち易い。 一方、 略 3 0 %を超えると、 軽量化及び断熱性の観点からは極めて好ま しいものとなるが、 合成樹脂発泡体の混入割合が高くなることから難燃 性 (不燃性) が低下すると共に、 瓦の強度が低下し、 また価格的にも高 価なものとなる傾向がある。 Another lightweight concrete roof tile according to the present invention is characterized in that the obtained lightweight concrete roof tile contains a synthetic resin foam at a capacity of approximately 10 to 30%. The mixing amount of the synthetic resin foam is more preferably in the range of about 0 to 20%, and more preferably in the range of about 14 to 18%. At less than about 10% It tends to have an unfavorable tendency from the viewpoints of weight reduction, cutability and heat insulation. On the other hand, if it exceeds about 30%, it is extremely preferable from the viewpoint of weight reduction and heat insulation, but the flame retardancy (non-combustibility) decreases as the mixing ratio of synthetic resin foam increases. However, the strength of the tiles tends to decrease and the price tends to be high.
本発明の更に他の軽量コンクリ―ト瓦は、 得られた軽量コンクリ一卜 瓦中に略 1 0乃至 4 0 %の容積の砂等の細骨材を含有したことを特徴と する。 ここでは、 成形加工時に、 水硬性結合材組成物の形状保持機能を 向上させるために細骨材を混入したものである。 この細骨材は、 細骨材 としての通常の作川の他に、 加) :成形 に合成樹脂発泡体が水硬性結合 材糾成物の内部で/王縮されて生ずる変形量を低減させる役割を果たす。 合成樹胎¾泡体が tt'縮され -定 ffi以上変形すると座屈するが、 圧力解放 後には復元する作用が生じるために、 製品の表而に小さな凹凸またはマ イク口クラックができ易いが、 細骨材の混入によって外部から加えられ た圧力が吸収され、 合成樹脂発泡体の変形、 座屈を低減させる結果、 圧 力解放後の形状変化を防止し、 滑らかな表面になる利点が生じるので、 細骨材を使用するのが好ましい。  Still another lightweight concrete roof tile according to the present invention is characterized in that the obtained lightweight concrete roof tile contains fine aggregate such as sand in a volume of approximately 10 to 40%. Here, at the time of molding, fine aggregate is mixed in order to improve the shape retention function of the hydraulic binder composition. This fine aggregate, in addition to the normal Sakugawa as a fine aggregate, also reduces the amount of deformation caused by the shrinkage of the synthetic resin foam inside / out of the hydraulic binder during molding. Play a role. The synthetic tree foam is tt 'shrunk-it buckles if it deforms beyond a certain ffi, but it has the effect of restoring after pressure release, so small irregularities or micro-mouth cracks are likely to occur on the surface of the product, The mixing of fine aggregate absorbs the pressure applied from the outside and reduces the deformation and buckling of the synthetic resin foam, thereby preventing the shape from changing after the pressure is released and providing the advantage of a smooth surface. It is preferable to use fine aggregate.
前記細骨材として砂を用いる場合、 コンクリート用細骨材として通常 使 fflされる粒径が 5 mm以下、 比重としては、 例えば、 略 2 . 6程度の範 囲のものでよく、 その種類も特に限定されるものではない。 乂、 砂の代 わりに、 JIS A 5012に規定されるごとき、 A炉スラグ細骨材 (粒の大き さ略 5咖以下、 比重が、 例えば、 略 2 . 0乃至 2 . 6程度) や、 JIS A 5002に規定される構造用軽量コンクリー卜骨材の細骨材 (粒の大きさ略 5 ππη以下、 比重が、 例えば、 略 1 , 3乃至 2 . 3程度) のものを使用し 得る。  In the case where sand is used as the fine aggregate, the particle diameter of ffl usually used as a fine aggregate for concrete is 5 mm or less, and the specific gravity may be, for example, in a range of about 2.6, and the type thereof may be different. There is no particular limitation. In place of azai and sand, A furnace slag fine aggregate (grain size of about 5 mm or less, specific gravity of about 2.0 to 2.6, for example) or JIS as specified in JIS A 5012, or JIS A lightweight fine concrete aggregate for structural use specified in A5002 (particle size of about 5ππη or less, specific gravity of, for example, about 1,3 to 2.3) can be used.
前記軽量コンクリ一卜瓦中での細骨材の含有量は、 得られる瓦の中で の絶対容積で略 1 0乃至 4 0 %の範囲が好ましく、 略 2 0乃至 3 5 %が 一層好ましく、 略 2 7乃至 3 1 %の範囲が最も好ましい。 細骨材の含有 ffiが略 1 0 %未満の埸合、 成形加工時、 合成樹脂発泡体が座屈し い傾 | となり、 また座屈した合成樹脂発泡休の復元力により瓦の ¾ffii或いは 内部にマイクロクラックが発生し、 llflげ強度ゃ表而性の低下が起こる場 合もある。 一方、 細骨材の含有量が略 4 0 %を超える場合、 軽鱟化及び 切断性や断熱性の観点から余り望ましくなくなる。 The content of fine aggregate in the lightweight concrete tile is The absolute volume is preferably in the range of about 10 to 40%, more preferably in the range of about 20 to 35%, and most preferably in the range of about 27 to 31%. If the fine aggregate content ffi is less than about 10%, the synthetic resin foam will buckle and tilt during the molding process. In some cases, micro cracks are generated, and the llfl strength / metaphysical property is reduced. On the other hand, if the content of fine aggregate exceeds about 40%, it becomes less desirable from the viewpoint of lightening, cutting properties and heat insulation.
更に、 本発明の軽量コンクリー卜瓦は、 細骨材の混入量と合成樹脂発 泡体の混入量の合計が、 得られる瓦の中での絶対容積で略 4 0乃至 5 0 %となるようにすると、 好ましい結 が^られる。 その理由は、 略 4 0 %未満であると、 加圧成形時に脱水量が多くなり易く、 製品の厚みが薄 くなるような場合も起こり得る。 上記混入 Sの台計が略 5 0 %を超える と、 流動性が低下する傾向があり、 その結果、 加 Π:成形時^が長く掛か つたり、 金型への充塡性が悪くなる場合も起こり得るからである。 本発 明において、 水硬性結合材組成物の比- ΠΪと、 この糾成物を成形加工し、 養生して得られる軽量コンクリート瓦の比重は、 ほぼ同一となる。 その 理由は、 組成物 (例えば、 水結合材比 (WZ C ) が 4 0 %) 中の水は、 脱水成形することにより一部排除され (前記 (W/ C ) は、 例えば、 2 5 %程度まで低下する) 、 この際、 脱水による容積の減少率が重量の減 少率より大きいために、 瓦の比重は、 前記組成物に比べて、 例えば、 0 . 1 ΐ:度上昇するが、 脱水成形後の瓦の硬化乾燥により、 Itffi比で 5乃 至 6 %程度の水が瓦から放出され (この問、 瓦の容積は殆ど変化しない ) 、 結果として、 硬化乾燥中に瓦の比 ffiが 0 . 〗程度減少するため、 前 記水硬性結合材組成物の比重と、 得られる瓦の比重とは、 ほぼ等しくな る。  Furthermore, in the lightweight concrete roof tile of the present invention, the total amount of the fine aggregate and the synthetic resin foam mixed is about 40 to 50% in absolute volume in the obtained tile. A good result is obtained. The reason for this is that if it is less than about 40%, the amount of dewatering tends to increase during pressure molding, and the thickness of the product may be reduced. If the total of the above-mentioned mixed S exceeds about 50%, the fluidity tends to decrease.As a result, when adding: it takes a long time during molding, or when the filling of the mold becomes poor. Because it can happen. In the present invention, the specific gravity of the hydraulic binder composition and the specific gravity of the lightweight concrete roof tile obtained by molding and curing this compact are almost the same. The reason is that the water in the composition (for example, water binder ratio (WZ C) is 40%) is partially removed by dehydration molding (the (W / C) is, for example, 25% At this time, since the rate of decrease in volume due to dehydration is greater than the rate of decrease in weight, the specific gravity of the tile is increased by, for example, 0.1 mm, compared to the composition, Due to the hardening and drying of the tile after dehydration molding, about 5 to 6% of water is discharged from the tile in an Itffi ratio of 5 to 6% (in this case, the volume of the tile hardly changes). Is reduced by about 0.1 mm, the specific gravity of the hydraulic binder composition is substantially equal to the specific gravity of the obtained tile.
本発明の他の軽量コンクリ一ト瓦は、 水硬性結合材がセメン卜である ことを特徴とする。 すなわち、 骨材としての合成樹脂発泡体を固める水 硬性結合材としては、 セメ ント、 石灰、 石膏、 接着剤などが挙げられる が、 この内のセメントは強度が強く、 耐水性に優れ、 比較的安価である から最も望ましい。 セメントとしては、 普通ポル卜ランドセメン卜、 単 強ポルトランドセメント、 超早強ポル卜ランドセメン卜、 中庸熱ポルト ランドセメン卜などのポルトランドセメント、 または、 高炉セメン卜、 シリカセメント、 フライアツシュセメン卜などの混合セメン卜、 或いは 、 超早強セメン卜、 膨張セメン卜、 化粧用セメン卜 (白色セメント、 力 ラーセメントなど) の特殊セメント、 もしくは、 アルミナセメン卜など を用いることができ、 用途により使い分けるのが好ましい。 In another lightweight concrete roof tile according to the present invention, the hydraulic binder is cement. It is characterized by the following. That is, cement, lime, gypsum, adhesives, etc. can be cited as the hydraulic binder that solidifies the synthetic resin foam as an aggregate, but the cement among them is strong, has excellent water resistance, and is relatively Most desirable because it is inexpensive. Portland cement such as ordinary Portland cement, single strength Portland cement, ultra-high strength Portland cement, medium heat Portland cement, etc., or a mixture of blast furnace cement, silica cement, fly ash cement, etc. Special cement such as cement or ultra-high-strength cement, expansion cement, cosmetic cement (white cement, power cement, etc.), or alumina cement can be used, and it is preferable to use properly depending on the application. .
本発明の更に他の軽量コンクリ一卜瓦は、 繊維補強材を絶対容積で略 0 . 2乃至 0 . 6 %混入した軽 コンクリート瓦としたことを特徴とす る。 繊維補強材を所定量混入することによって、 強靱で曲げ強度の強い 軽量コンクリー卜瓦を得ることができる。 、 繊維補強材としては、 耐 アルカリガラス繊維、 ビニロン繊維、 ナイロン繊維、 ポリプロピレン繊 維等が挙げられる。  Still another lightweight concrete roof tile according to the present invention is characterized in that it is a light concrete tile in which a fiber reinforcing material is mixed in an absolute volume of approximately 0.2 to 0.6%. By mixing a predetermined amount of the fiber reinforcing material, a tough and light-weight concrete roof tile having high bending strength can be obtained. Examples of the fiber reinforcing material include alkali-resistant glass fiber, vinylon fiber, nylon fiber, and polypropylene fiber.
本発明の他の軽量コンクリ一卜瓦は、 繊維補強材として耐ァルカリガ ラス繊維を混合したことを特徴とする。 すなわち、 耐アルカリガラス繊 維は、 高い曲げ強度が得られ、 アルカリに対する抵抗性があることから 、 特に好ましく使用される。  Another lightweight concrete roof tile according to the present invention is characterized in that alkali-resistant glass fibers are mixed as a fiber reinforcing material. That is, the alkali-resistant glass fiber is particularly preferably used because it has a high bending strength and is resistant to alkali.
前記耐アルカリガラス繊維の長さは、 平均して 1 0咖乃至 2 0 mm程度 が好ましいが、 特に限定されるものではない。 耐アルカリガラス繊維等 の繊維補強材の混入割合を絶対容積で略 0 . 2 %未満とすると曲げ強度 が弱く、 略 0 . 6 %を超えると、 モルタルの流動性が低下し易い傾向が あったり、 加圧成形時間が長くなつたりすることもあり、 充塡性が悪く なって製造原価が高くなる場合も起こり^るので、 上記した範剛が適当 である。 The length of the alkali-resistant glass fiber is preferably about 10 mm to 20 mm on average, but is not particularly limited. If the mixing ratio of the fiber reinforcing material such as alkali-resistant glass fiber is less than approximately 0.2% in absolute volume, the bending strength is weak, and if it exceeds approximately 0.6%, the mortar fluidity tends to decrease. However, the press molding time may be longer, and the filling cost may be worse and the production cost may be higher. It is.
本発明の他の軽量コンクリ一ト瓦は、 フライアツシュおよび または 高炉スラグをセメン卜菌量の略 1 0乃至 3 5重量%混入したことを特徴 とするものである。 すなわち、 フライアッシュおよび Zまたは高炉スラ グなどを混入することによりセメントの持つアルカリ性を低下させ、 こ れにより、 ガラス繊維を含む繊維補強材などの耐久性を高める効果が期 待されるので、 好ましい。 また、 セメントにフライアッシュなどを混入 すると流動性が向上し、 表面が美麗化すると共に、 合成樹脂発泡休が瓦 の表面に表われにく くなる利点も生じる。 更に、 長期強度が向上し、 強 度の強い瓦が得られる。  Another lightweight concrete roof tile according to the present invention is characterized in that fly ash and / or blast furnace slag are mixed with approximately 10 to 35% by weight of the amount of cement bacteria. That is, by mixing fly ash, Z or blast furnace slag, etc., the alkalinity of the cement is reduced, which is expected to have the effect of increasing the durability of fiber reinforcing materials including glass fibers. . Also, if fly ash or the like is mixed into the cement, the fluidity is improved, the surface becomes more beautiful, and there is an advantage that synthetic resin foam is less likely to appear on the tile surface. Further, the long-term strength is improved, and a strong roof tile can be obtained.
フライアツシュおよび Zまたは高炉スラグの混入量は、 セメント重量 に対して略 1 0乃至 3 5 %が好ましく、 略 1 5尸 j至 3 5 %がー-屑好まし く、 略 2 0乃至 2 7 %が最も好ましい。 混入率が略 3 5重量%を超える と、 初期強度が低下し易くなる傾向があり、 逆に、 混入率が略 1 0重量 %未満であれば、 混人による効果が乏しい。 これらフライアッシュは比 表面積が約 2 4 0 O cmVg以上、 高炉スラグは比表面積が約 3 0 0 0 on2/g上の粉末状のものが使用される。 The mixing amount of fly ash and Z or blast furnace slag is preferably about 10 to 35%, preferably about 15 to 35% with respect to the weight of cement, and preferably about 20 to 27%. Is most preferred. If the mixing ratio exceeds approximately 35% by weight, the initial strength tends to decrease. Conversely, if the mixing ratio is lower than approximately 10% by weight, the effect of mixed people is poor. These fly ash powders have a specific surface area of about 240 OcmVg or more, and the blast furnace slag has a specific surface area of about 300 on 2 / g.
本発明の他の軽量コンクリ―ト瓦は、 複数の合成樹脂発泡体粒子を水 硬性結合材で固めて一体とした軽量コンクリ一卜骨材、 水、 水硬性結合 材及び合成樹脂発泡体を混練した軽量コンクリ一トを成形加工してなる ことを特徴とするものである。 すなわち、 合成樹脂発泡体の骨材に加え て、 更に複数の合成樹脂発泡体を水硬性結合材で固めて一体とした軽量 コンクリー卜骨材を存在させることによって、 プレス成形加工時に圧力 が加わっても合成樹脂発泡体が潰れないように保護し、 従って、 加圧成 形時においても収縮したり、 加圧成形後における圧力解放時にも後膨れ するようなことがほとんどなくなり、 瓦表而のきれいな' 品を得ること ができるものである。 この軽量コンク リート骨材としては、 本出願人ら が先に提案した日本国特願平 6 - 7 1 0 3 1号明細書に記載したものが 挙げられる。 Another lightweight concrete roof tile according to the present invention comprises a lightweight concrete aggregate obtained by solidifying a plurality of synthetic resin foam particles with a hydraulic binder, water, a hydraulic binder, and a synthetic resin foam. It is characterized by being molded from a lightweight concrete. In other words, in addition to the synthetic resin foam aggregate, a plurality of synthetic resin foams are hardened with a hydraulic binder to form an integrated lightweight concrete aggregate, so that pressure is applied during press forming. Also protects the synthetic resin foam from crushing, so that it hardly shrinks during pressure molding or swells after pressure is released after pressure molding. '' Getting the goods Can be done. Examples of the lightweight concrete aggregate include those described in Japanese Patent Application No. 6-71031 proposed by the present applicant earlier.
この軽量コンクリ一卜骨材に使 J する合成樹脂発泡体或いは水硬性結 合材としては、 前記のものと同じものを使用できる。 このような合成榭 脂発泡体、 水硬性結合材に水を加えて、 吸水率が小さく、 吸水による膨 張率も小さく、 且つ強度も強くなるように水結合材比 (WZ C ) を調整 したものを、 ίίί が 5關以下、 より好ましくは 3誦以下となるように略 球形に形成 (例えば、 パン型造粒機等を用いる : 日本国特願平 8 - 1 2 0 8 5号参照) し、 硬化させて、 その真比 ΪΒが 0 . 8乃至 1 . 5の範囲 となるようにしたものである。  As the synthetic resin foam or hydraulic binder used for the lightweight concrete aggregate, the same ones as described above can be used. Water was added to such a synthetic resin foam and hydraulic binder, and the water binder ratio (WZ C) was adjusted so that the water absorption was small, the expansion due to water absorption was small, and the strength was strong. Are formed in a substantially spherical shape such that ίίί is less than or equal to 5 and more preferably less than or equal to 3 (for example, using a bread-type granulator: see Japanese Patent Application No. 8-12085). Then, it is cured so that the true ratio is in the range of 0.8 to 1.5.
輕^コンクリ―卜骨材の Λ·める割合は、 求める製品の輕量化 βΐί合によ つて適宜選択することができるが、 容量比で約 1 5乃至 5 0 %の範閥で あれば良い。 水結合材比 (W/ C ) も、 製品の種類によって適宜選択さ れる力 4 0 %以下とするのが強度の点から好ましい。  The proportion of light concrete aggregate can be selected as appropriate depending on the desired product weight reduction β, but it is sufficient if the volume ratio is about 15 to 50%. . The water binder ratio (W / C) is preferably 40% or less, which is appropriately selected depending on the type of product, from the viewpoint of strength.
前 Iklした軽量コンクリート瓦を製造するに際して、 水硬性結合材、 合 成樹脂発泡体および水を主成分とする水硬性結合材組成物中に、 更に各 種混和剤、 例えば、 A E剤、 減水剤、 A E減水剤、 高性能 A E減水剤等 を混入しておくと、 llllげ強度が、 例えば、 1 0 %程 向上し、 品 Kの安 定化を図ることができ、 更に好ましい結果が得られる。 更に、 得られた 軽量コンクリート瓦に、 表面の美観を向上させるために、 アクリル塗装 等を施してもよい。  When manufacturing lightweight concrete roof tiles with Ikl before, in the hydraulic binder composition, synthetic resin foam and hydraulic binder composition mainly composed of water, various admixtures such as AE agent, water reducing agent , AE water reducing agent, high-performance AE water reducing agent, etc., can improve the llll strength, for example, by about 10%, stabilize the product K, and obtain more favorable results. . Further, the obtained lightweight concrete tile may be subjected to an acrylic coating or the like in order to improve the surface appearance.
本発明の軽量コンクリー卜瓦の製造方法は、 前記軽量コンクリ一卜瓦 を加圧'成形加工により製造するようにしたことを特徴とする。 これによ り、 成形を円滑に行うことができる。  A method of manufacturing a lightweight concrete roof tile according to the present invention is characterized in that the lightweight concrete roof tile is manufactured by press forming. Thereby, molding can be performed smoothly.
この場合、 前記加圧成形加工は成形加工時の加圧力を略 5 O kgf/cm2 上としたプレス型枠成形加工とすることが好ましい。 すなわち、 加圧力 が略 5 Okgf/cm2未満であると、 加圧時問が長く掛かり易くなると共に 成形を円滑に行うのに支障が起き易い傾向があり、 好ましくない。 前記 プレス型枠成形加工は、 押出し成形加工などでは不可能な複雑な形状の 製品を容易に成形できる利点がある。 又、 木発明の瓦を曳好に得るには 、 成形加工時の加圧力の調整が大きな意味を持つことが多い。 In this case, the pressure molding process has a pressing force of approximately 5 O kgf / cm 2 It is preferable to use the press mold forming process described above. That is, if the pressing force is less than about 5 Okgf / cm 2 , the pressing time is likely to be long, and there is a tendency that trouble is likely to occur in smooth forming, which is not preferable. The press mold forming process has an advantage that a product having a complicated shape which cannot be formed by an extrusion forming process can be easily formed. In addition, in order to obtain the wooden tile of the present invention in a favorable manner, adjustment of the pressing force at the time of molding often has a great significance.
例えば、 通常の厚形スレートの成形においては、 プレス 力が略 1 2 0乃至 1 5 0 k ί c m2 で成形されており、 1 2 0 k g f Z c m2 以下の成形では強度の低下が生じる。 一 、 本発明の成形では、 略 5 0 k g f / c m2 以上、 更に好ましくは略 7 0 k g f / c m2 以上の範閉 で成形可能となるので、 プレス容量の小さなプレス機でも成形可能とな り、 工業的に好ましい。 発明を実施するための最良の形態 For example, in the forming of a normal thick slate, the pressing force is formed at approximately 120 to 150 kίcm 2 , and when the pressing force is 120 kgf Z cm 2 or less, the strength is reduced. On the other hand, in the molding of the present invention, molding can be performed in a range of about 50 kgf / cm 2 or more, more preferably about 70 kgf / cm 2 or more, so that molding can be performed even with a press machine having a small press capacity. Industrially preferred. BEST MODE FOR CARRYING OUT THE INVENTION
この発明をより詳細に説明するために、 以下、 第 1表乃至第 3表に本 発明の軽量コンクリ一卜瓦の材料となる水硬性結合材組成物の配合例で ある実施例を比絞例とともに示す。 尚、 E P Sあるいは E P Sビーズは 、 発泡性ポリスチレンビーズの発泡粒子を表す。 In order to explain the present invention in more detail, Tables 1 to 3 below show examples which are examples of blending of the hydraulic binder composition used as the material of the lightweight concrete roof tile of the present invention. Shown together. Incidentally, EPS or EPS beads represent expanded particles of expandable polystyrene beads.
軽量コンクリート瓦の配合例表 A ( 1 £当たり) Mixing example table of lightweight concrete tile A (per £)
Figure imgf000014_0001
Figure imgf000014_0001
第 1表乃至第 3表中の ( ) 内は、 水硬性結合材 組成物全体を 1とした場合の容積比率を示す。 軽量コンクリート瓦の配合例表 B (1 £当たり) 実施例 実施例 比較例 比較例 1 2 5 6 水硬性結合材 The values in parentheses in Tables 1 to 3 indicate the volume ratio when the entire hydraulic binder composition is set to 1. Mixing example of lightweight concrete tile B (per £) Example Example Comparative example Comparative example 1 2 5 6 Hydraulic binder
糾成物の比 Si: 1.6 1.8 1.8 1.8 ijfiポル卜ラ: 'セ 卜 7 16 w5e 765e 765B [比重 3.14] (0· 24) (0· 24) (0.24) (0· 24) Ratio of alleged substances Si: 1.6 1.8 1.8 1.8 ijfi portra: 'set 7 16 w5e 765e 765B [specific gravity 3.14] (0 · 24) (0 · 24) (0.24) (0 · 24)
1 z 1  1 z 1
[比 IB2.10]  [Comparative IB2.10]
 water
[比重 1.00] (0.31) (0.31) (0.31) (0.31) —ラィ 卜  [Specific gravity 1.00] (0.31) (0.31) (0.31) (0.31) — Light
[比重 0.10]  [Specific gravity 0.10]
E P Sビーズ 26g 18g llg 27g  E P S beads 26g 18g llg 27g
CO 26 C VO 1 _18 o) CO 18) V «. JLO [比重 〗 [0.10] [0.10] [0.06] [0.15] 砂 503g 711g 718g 702g CO 26 C VO 1 _18 o) CO 18) V «. JLO [specific gravity〗 [0.10] [0.10] [0.06] [0.15] Sand 503g 711g 718g 702g
[比重 2.60] (0.19) (0.27) (0.27) (0.27) 耐アルカリ ラス繊維 [Specific gravity 2.60] (0.19) (0.27) (0.27) (0.27) Alkali resistant lath fiber
[比重 2.50〗  [Specific gravity 2.50〗
軽量〕ンクリ -ト骨材 Lightweight] concrete
[比重 1.20]  [Specific gravity 1.20]
E P S E P S  E P S E P S
配合の特徴 の比重 の比重 小 大 Mixing characteristics Specific gravity Specific gravity Small Large
3表 Table 3
軽量コンクリート瓦の配合例表 C ( ] £当たり)
Figure imgf000016_0001
Mixing example table of lightweight concrete tiles C (per £)
Figure imgf000016_0001
上記各比較例および実施例の軽量コンクリ一卜瓦の配合例において、 合成樹脂発泡体としては、 ポリスチレンを発泡させた比重 0 . 0 6、 0 . 1 0、 0 . 1 5の平均径が 0 . 9 mmのビーズ状のもの (E P SビーズIn the blending examples of the lightweight concrete roof tiles of the above Comparative Examples and Examples, the synthetic resin foam had an average diameter of 0.06, 0.10, and 0.15 obtained by expanding polystyrene. 9 mm beads (EPS beads
) を使用した。 セメントとしては、 普iポルトランドセメントを使用した。 また) It was used. As the cement, Portland cement was used. Also
、 繊維補強材として、 1 3 mmの耐アルカリガラス繊維を使用した。 砂と しては、 径が 2 . 5 mm以下の川砂を使用した。 軽量コンクリート骨材と しては、 前記と同様の合成樹脂発泡体、 普通ポルトランドセメント及び水とを、 水結合材比 2 5 %前後で混練して硬化させた平均径が約 3 mmの略球形状 で、 その真比重が 1 . 5のものを使用した。 以上のように配合した軽量 コンクリ一卜をプレス型枠成形にて 7 0 kgf/ciD 2 の圧力を加え瓦に成形 してから蒸気養生して硬化させた。 A 13 mm alkali-resistant glass fiber was used as a fiber reinforcing material. River sand with a diameter of 2.5 mm or less was used as the sand. As the lightweight concrete aggregate, the same synthetic resin foam, ordinary Portland cement and water as described above are kneaded at a water binder ratio of about 25% and hardened. The shape and the true specific gravity of 1.5 were used. It cured by steam curing after molding tiles applying a pressure of lightweight concrete Ichiboku press mold molding at 7 0 kgf / ciD 2 which was formulated as above.
上記 ¾施例】乃至 6の瓦の特性を、 比校例 1乃至 7と比絞した結粜を 第 4表乃至第 6表に示す。 Tables 4 to 6 show the characteristics of the roof tiles of the above Examples 6 to 6 compared with Comparative Examples 1 to 7.
4表 特忡の比 ί^ Α Table 4 Ratio of features ί ^ Α
し :  Then:
比 例 比! x例 比 例 比 IX例 Ratio Example Ratio! X Example Ratio Example Ratio IX Example
1 2 3 41 2 3 4
2. 2 2. 0 1. 5 1. 62.2 2.0 1.1.5.6
X Λ X Λ
曲げ強さ(kgi/ 枚) 280 180 210 130Bending strength (kgi / sheet) 280 180 210 130
(JIS A 5402) Δ X 吸水率 (wtx) 7 20 Π 10(JIS A 5402) Δ X Water absorption (wtx) 7 20 Π 10
(JIS A 5402) 雲 X - 不燃性 合格 合格 不合格 合格 (JIS A 1321 ) X (JIS A 5402) Cloud X-Flammability Pass Pass Fail Pass (JIS A 1321) X
切断性 困難  Difficult to cut
X  X
釘打ち性 瞧 i¾  Nailing 瞧 i¾
X  X
み小 ^み小 成形性 密度バラ 密度バラ ツキ大 ツキ大 Small Small Small Small Formability Density Variation Density Variation Large
X X X X
表面性 良 良 良 クラ 7ク有  Surface good good good good
X X
5表 特性の比較表 BTable 5 Comparison of characteristics B
^ //US V LP ■=例  ^ // US V LP ■ = Example
1 2 5 6 1 2 5 6
1 β 1 1 . ϋ 1 R 曲げ強さ(kgf/ 枚) 230 250 180 250 ( JIS A 5402) △ 1 β 1 1 .ϋ 1 R Flexural strength (kgf / sheet) 230 250 180 250 (JIS A 5402) △
吸水率(Wt%) 10 9 9 9 ( JIS A 5402)  Water absorption (Wt%) 10 9 9 9 (JIS A 5402)
不燃性 合格 合格 合格 不合格 (JIS A 1321 ) X 切断性 良 良 良 良 釘打ち性 良 良 良 厚み小 成形性 良 良 密度バラ 良 ツキ大  Non-combustibility Passed Passed Passed Fail (JIS A 1321) X Cutability Good Good Good Good Nailability Good Good Good Small thickness Formability Good Good Density variation Good Tsukidai
X  X
表面性 良 良 クラ 7ク有 良  Good surface good Good
X X
第 6表 特性の比較表 C Table 6 Characteristics comparison table C
Figure imgf000020_0001
第 4表乃至第 6表から明らかなように、 本発明の実施例の軽量コンク リ一ト瓦は、 比絞例である従来のコンクリ一卜瓦と比餃して、 密麼が小 さく、 有 fflなものである。 曲げ強さは若千低い値となっているが、 実用 上問题ない充分な強度である。 実施例 3はフライアッシュを混人したこ とにより、 表面性が くなつており、 実施例 4は耐アル力リガラス繊維 を混入したことにより、 曲げ強さが最も強くなつている。 一方、 比絞例 4は砂を使用しなかったために、 また比較例 5は E P Sの比 ffiが小さい ために、 いずれも瓦の表面にクラックが発生し易く、 曲げ強度が低い値 となっている。
Figure imgf000020_0001
As is evident from Tables 4 to 6, the lightweight concrete roof tile of the embodiment of the present invention is smaller in size than the conventional concrete roof tile which is a comparative example, Yes It is ffl. Although the flexural strength has a slightly lower value, it is sufficient for practical use. In Example 3, the surface property was reduced due to the mixture of fly ash, and in Example 4, the bending strength was maximized due to the mixing of Al-resistant glass fiber. On the other hand, in Comparative Example 4, no sand was used, and in Comparative Example 5, cracks tended to occur on the surface of the tile, and the flexural strength was low due to the low EPS efficiency. .
|V.'j. 施例 3の処 にて、 E P Sビーズの 均拉 ¾を 1 . 2 m m. . 7 mm. 2 mmを超えたものの 3嵇類に変更しただけの実験を行った 。 その結果は、 1 . 2 m mのものは表面性が良で、 表面の凹凸は少なく 、 好ましい。 又、 1 . 7 m mのものは水硬性結合材組成物としての混合 が可能であり、 製品は容易に製造し得るが、 表面の凹凸が多少観察され た。 2 m mを超えたものでは、 該組成物が分離し易い傾向が見られ、 混 合に注意が必要であつた。 又、 比較例〗や比铰例 7のように砂の含有 S の多いものでは、 切断性や釘打ち性が低下する傾向があった。 尚、 釘打 ち性が良好な瓦とは、 瓦に釘が通り易く、 釘打ちに伴う瓦の割れが生じ にくい瓦を意味する。 産業上の利用可能性 | V.'j. In Example 3, the EPS beads were reduced to 1.2 mm. 7 mm. An experiment was performed in which the size exceeded 2 mm but was changed to class 3 only. As a result, the one having a thickness of 1.2 mm is preferable because the surface properties are good and the surface unevenness is small. Also, the one with 1.7 mm can be mixed as a hydraulic binder composition, and the product can be easily manufactured, but some surface irregularities were observed. When the thickness exceeds 2 mm, the composition tends to be easily separated, and it is necessary to pay attention to the mixing. In addition, those having a large amount of S containing sand, such as Comparative Example I and Comparative Example 7, tended to decrease the cutting properties and nailing properties. In addition, a tile having good nailing property means a tile in which nails can easily pass through the tile and the tile is not easily cracked by nailing. Industrial applicability
以上のように、 本発明に係る軽量コンクリ一ト瓦は、 住宅の屋根瓦等 して、 特に軽量化の要求される部位に好適に使用できる。  As described above, the lightweight concrete tile according to the present invention can be suitably used as a roof tile of a house or the like, particularly at a site where a reduction in weight is required.

Claims

請 求 の 範 囲 The scope of the claims
1. 合成樹脂発泡体を骨材として含有する水硬性結合材組成物を成形加 ェしてなる、 比 Φ:が略 1. 6乃至 2. 0である軽量コンクリート瓦。1. A lightweight concrete tile having a ratio Φ: of approximately 1.6 to 2.0, which is formed by molding a hydraulic binder composition containing a synthetic resin foam as an aggregate.
2. 合成樹脂発泡体の骨材を、 平均粒径が略 2 IDID以下のビーズとした請 求の範 Umii 1项 iLi載の ½逢コンクリート瓦。 2. An aggregate of synthetic resin foam made of beads with an average particle size of about 2 IDID or less.
3. 合成樹脂発泡体として、 ポリスチレン発泡体を用いた請求の範囲第 1項又は第 2項記載の軽盪コンクリ一卜瓦。  3. The light mixing concrete tile according to claim 1 or 2, wherein a polystyrene foam is used as the synthetic resin foam.
4. 合成樹脂発泡体の比重が、 略 0. 07乃至 0. 1 2である請求の範 西第 1¾又は第 2 ¾記載の軽量コンクリート瓦。  4. The lightweight concrete tile according to claim 1 or 2, wherein the specific gravity of the synthetic resin foam is approximately 0.07 to 0.12.
5. 得られた軽量コンクリ一卜瓦中に合成樹脂発泡体を略 1 0乃至 30 %の容世で含 ¾ "した if 求の範 第 1项乂は第 2项記載の軽 コンクリ― ト瓦。  5. Synthetic resin foam is included in the obtained lightweight concrete roof at about 10 to 30%. The range of if request is as follows. .
6. られた軽 ilコンクリ一卜瓦屮に略 1 0乃 0 %の ' 稂の砂等の 細骨材を含有したものである 求の範囲第 1 ¾又は第 2 ¾ί記載の軽量コ ンクリート瓦。  6. The lightweight concrete roof tile described in item 1 or 2 above, which contains approximately 100% to 0% of fine aggregate such as sand, etc. .
7. 水硬性結合材がセメ ントである請求の範囲第 1項記載の軽量コンク リ―卜瓦。  7. The lightweight concrete roof tile according to claim 1, wherein the hydraulic binder is a cement.
8. 繊維補強材を絶対容積で略 0. 2乃至 0. 6%混入した請求の範囲 第 1項又は第 2項記載の軽量コンクリート瓦。  8. The lightweight concrete tile according to claim 1 or 2, wherein a fiber reinforcing material is mixed in an absolute volume of approximately 0.2 to 0.6%.
9. 繊維補強材として酎アル力リガラス繊維を混合してなる諧求の範囲 第 8項記載の軽量コンクリ一卜瓦。  9. The range of gradations obtained by mixing shochu liquor glass fiber as a fiber reinforcing material.
1 0. フライアッシュおよび Ζまたは高炉スラグをセメ ン ト重量の略 1 0乃至 35 ΪΒ量%混入した請求の範 7项記載の軽量コンクリート瓦 o  10 0. Light-weight concrete roof tile according to claim 7 in which fly ash and Ζ or blast furnace slag are mixed in an amount of about 10 to 35% by weight of cement weight o
1 1. 複数の合成樹脂発泡休を水硬性結合材で固めて一体とした軽量コ 2 】 ンクリ一卜骨材を前記合成樹脂発泡体と共に使用する請求の範囲第 1 ¾ 又は第 2項記載の軽量コンクリート瓦。 1 1. Lightweight core made by integrating a plurality of synthetic resin foam with hydraulic binder 3. The lightweight concrete roof tile according to claim 1, wherein the concrete aggregate is used together with the synthetic resin foam.
1 2 . 前記軽量コンクリ一ト瓦を加圧成形加工により製造する請求の範 囲第 1 ¾又は第 2項記載の軽量コンクリート瓦の製造方法。  12. The method for manufacturing a lightweight concrete roof tile according to claim 1 or 2, wherein the lightweight concrete roof tile is manufactured by pressure molding.
1 3 . 加圧成形加工が成形加工時の加圧力を略 5 O kgf/cm 2 以とした プレス型枠成形加工である請求の範囲第 1 2项記載の軽量コンクリート 瓦の製造方法。 1 3. Method for producing lightweight concrete roof tiles ranging first 2 Para claimed according pressing process is press-mold molding was approximately 5 O kgf / cm 2 or less applied pressure during molding.
PCT/JP1996/002005 1995-01-31 1996-07-17 Lightweight-concrete roofing tile and process for producing the same WO1998002397A1 (en)

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WO2007111850A2 (en) 2006-03-22 2007-10-04 Nova Chemicals Inc. Lightweight concrete compositions
US7632348B2 (en) 2005-03-22 2009-12-15 Nova Chemicals Inc. Lightweight concrete compositions containing antimicrobial agents
US7644548B2 (en) 2005-03-22 2010-01-12 Nova Chemicals Inc. Lightweight concrete compositions
US7648574B2 (en) 2005-03-22 2010-01-19 Nova Chemicals Inc. Lightweight concrete compositions
US7874112B2 (en) 2008-06-20 2011-01-25 Nova Chemicals Inc. Footer cleat for insulating concrete form
US8357240B2 (en) 2005-03-22 2013-01-22 Syntheon Inc. Method of making concrete
US8726594B2 (en) 2005-02-25 2014-05-20 Syntheon Inc. Composite pre-formed building panels

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Cited By (14)

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Publication number Priority date Publication date Assignee Title
US8726594B2 (en) 2005-02-25 2014-05-20 Syntheon Inc. Composite pre-formed building panels
US7820094B2 (en) 2005-03-22 2010-10-26 Nova Chemicals Inc. Lightweight concrete compositions
US7644548B2 (en) 2005-03-22 2010-01-12 Nova Chemicals Inc. Lightweight concrete compositions
US7648574B2 (en) 2005-03-22 2010-01-19 Nova Chemicals Inc. Lightweight concrete compositions
US7658797B2 (en) 2005-03-22 2010-02-09 Nova Chemicals Inc. Lightweight concrete compositions
US7744692B2 (en) 2005-03-22 2010-06-29 Nova Chemicals, Inc. Lightweight concrete compositions
EP2364959A1 (en) 2005-03-22 2011-09-14 Nova Chemicals Inc. Lightweight concrete compositions
US8029617B2 (en) 2005-03-22 2011-10-04 Nova Chemicals Inc. Lightweight concrete compositions
USRE43253E1 (en) 2005-03-22 2012-03-20 Nova Chemicals Inc. Lightweight concrete compositions
US8167998B2 (en) 2005-03-22 2012-05-01 Nova Chemicals Inc. Lightweight concrete compositions
US8357240B2 (en) 2005-03-22 2013-01-22 Syntheon Inc. Method of making concrete
US7632348B2 (en) 2005-03-22 2009-12-15 Nova Chemicals Inc. Lightweight concrete compositions containing antimicrobial agents
WO2007111850A2 (en) 2006-03-22 2007-10-04 Nova Chemicals Inc. Lightweight concrete compositions
US7874112B2 (en) 2008-06-20 2011-01-25 Nova Chemicals Inc. Footer cleat for insulating concrete form

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