WO1999015938A1 - Holographically transferable images - Google Patents

Holographically transferable images Download PDF

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Publication number
WO1999015938A1
WO1999015938A1 PCT/US1997/016350 US9716350W WO9915938A1 WO 1999015938 A1 WO1999015938 A1 WO 1999015938A1 US 9716350 W US9716350 W US 9716350W WO 9915938 A1 WO9915938 A1 WO 9915938A1
Authority
WO
WIPO (PCT)
Prior art keywords
foil
substrate
holographic image
holographic
image
Prior art date
Application number
PCT/US1997/016350
Other languages
French (fr)
Inventor
Stephen B. Stepanek
Original Assignee
Hampshire Holographic Manufacturing Corp.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US08/679,349 priority Critical patent/US5723203A/en
Priority to US08/824,914 priority patent/US5902436A/en
Application filed by Hampshire Holographic Manufacturing Corp. filed Critical Hampshire Holographic Manufacturing Corp.
Priority to EP97941632A priority patent/EP1015941A4/en
Priority to AU43499/97A priority patent/AU4349997A/en
Priority to CA002303247A priority patent/CA2303247C/en
Priority to PCT/US1997/016350 priority patent/WO1999015938A1/en
Publication of WO1999015938A1 publication Critical patent/WO1999015938A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/50Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by shape, structure or physical form, e.g. products with supported structure
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/343Products for covering, coating, finishing, decorating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/10Applying flat materials, e.g. leaflets, pieces of fabrics
    • B44C1/14Metallic leaves or foils, e.g. gold leaf
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H1/00Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
    • G03H1/02Details of features involved during the holographic process; Replication of holograms without interference recording
    • G03H1/0252Laminate comprising a hologram layer
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G2220/00Products with special structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2311/00Metals, their alloys or their compounds
    • B32B2311/24Aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2398/00Unspecified macromolecular compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H1/00Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
    • G03H1/02Details of features involved during the holographic process; Replication of holograms without interference recording
    • G03H1/024Hologram nature or properties
    • G03H1/0244Surface relief holograms
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H1/00Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
    • G03H1/02Details of features involved during the holographic process; Replication of holograms without interference recording
    • G03H1/0276Replicating a master hologram without interference recording
    • G03H2001/0284Replicating a master hologram without interference recording by moulding
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H2227/00Mechanical components or mechanical aspects not otherwise provided for
    • G03H2227/04Production line for mass production
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H2250/00Laminate comprising a hologram layer
    • G03H2250/10Laminate comprising a hologram layer arranged to be transferred onto a carrier body
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H2270/00Substrate bearing the hologram
    • G03H2270/10Composition
    • G03H2270/13Metallic
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H2270/00Substrate bearing the hologram
    • G03H2270/20Shape
    • G03H2270/23Ribbon shaped, e.g. holographic foil
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/913Material designed to be responsive to temperature, light, moisture
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628Nonplanar uniform thickness material
    • Y10T428/24736Ornamental design or indicia
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24826Spot bonds connect components
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24893Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
    • Y10T428/24901Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material including coloring matter
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/269Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension including synthetic resin or polymer layer or component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2813Heat or solvent activated or sealable
    • Y10T428/2817Heat sealable
    • Y10T428/2826Synthetic resin or polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31678Of metal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31678Of metal
    • Y10T428/31681Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]

Definitions

  • This invention relates to holographic images formed by a unique process for various security and decorative purposes. Also, this invention relates to aluminized roll-stock holographic images formed on a plastic layer. Further, this invention relates to elements and process for transferring holographic images to yet another substrate. Still further, this invention relates to a unique process for transferring holographic images to a relatively inexpensive substrate which permits a wide-spread use of said holographic image .
  • Holographically enhanced materials are well known in the prior art. These are usually made by very proprietary methods which includes passing a layer of plastic, for example, through a machine which imparts a variation (e.g. which can be an image itself) within covering or upper strata of the plastic layer. This step is somewhat similar to, but not exactly the same, as embossing. A powdered metallic element (e.g. aluminum) is then applied thereon by the so-called metallizing process. After this step, the element appears to have a holographic or 3 -dimensional image imparted on the layer of plastic. This image is extremely pleasing and is widely used within the credit card and security industries, for example, to impart an image particular to that credit card or security element thereon.
  • a variation e.g. which can be an image itself
  • foils and the like for the wrapping of individual food pieces, for example.
  • these foils are embossed with decorative or advertising logos and materials.
  • glues metallized materials to tissue like paper tissues for the wrapping of individual food pieces such as candies, gums and the like, for example.
  • this invention may be achieved in a process for transferring a holographic image to a foil substrate by laminating a holographic image, said image having been imparted on a polymeric substrate, to said foil substrate at a temperature greater than 35°C and a pressure greater than 1 pound per square inch and subsequently delaminating said foil substrate from said polymeric substrate, whereby said holographic image is transferred to said foil substrate .
  • FIG. 1 is a top view of an actual prior art holographic image prepared by the process described above and contained on a polymeric substrate.
  • FIG. 2 is a drawing of a side view of FIG. 1.
  • a foil substrate is shown directly above the holographic image which is contained on a polymeric substrate in this Figure.
  • FIG. 3 is a drawing of a side view of a holographic image that has been transferred from the element of FIG. 1 directly to the foil substrate of FIG. 2
  • FIG. 4 is a drawing of a schematic process for the lamination of a prior art polymeric substrate containing a holographic image to a foil substrate .
  • FIG. 5 is a drawing of a schematic process of direct delamination of the polymeric substrate from the foil substrate to produce the holographic image of FIG. 2 directly on the foil substrate.
  • FIG. 6 is a top view of a drawing showing a name brand as a holographic image on a foil substrate, said holographic image having been transferred from a polymeric substrate. A series of these images may be prepared and rolled up so that this holographic image can be used to wrap and advertise in a flashy method.
  • FIG. 1 is a top view of an actual holographic image 1 contained on a polymeric substrate.
  • the image has that 3-D holographic look that is well-known in the prior art, especially in the security art field.
  • FIG. 2 a side view drawing of the holographic image 1 from FIG. 1 is shown.
  • the polymeric substrate on which the holographic image is manufactured is shown as 2.
  • a foil substrate 3 is shown located directly above the image .
  • the holographic image 1 has been transferred to the foil substrate 3.
  • FIG. 4 is a schematic drawing representing a novel process of this invention for the transfer of a holographic image from a polymeric substrate to a foil substrate.
  • a holographic image 1 (not shown in this figure) on a polymeric substrate 2 is shown being pulled off an unwind roll 4 in a nip formed by opposing rollers 5 and 6.
  • roll 5 is a standard gravure coating roll
  • roll 6 is a backup roll.
  • a reverse gravure doctor blade (to control coating weight) is shown as 7 and a coating pan (holding a standard adhesive solution) is shown as 8.
  • the coated holographic image on a polymeric substrate is then carried through a drier which is indicated as 9 and 10 and subsequently down to heated rolls 11 and 12.
  • a foil substrate 3 taken from a roll 14 contacts the surface of the adhesive containing side of the dried, holographic image 1 contained on a polymeric substrate 2 and is laminated thereto.
  • the heated rolls activate the dried adhesive in order to permit such a lamination to occur.
  • the resulting sandwich 13 is passed over a chill roll 14a and then taken up by rewind roll 14.
  • FIG. 5 The process of delamination is shown in FIG. 5.
  • the laminated sandwich material 13 is drawn off unwind roll 14 and taken through the nip of two delamination rolls 16 and 17.
  • the polymeric substrate 2 is then taken up on a film rewind roll 18 (this material can subsequently be reused and recycled) .
  • the foil substrate 3 now carrying the holographic image 1 thereon is taken up to coating heads 19 and 20.
  • a protective layer is applied over the holographic image contained on this foil substrate in order to protect this image during handling. This may be applied at the nip of the coating heads and a pan 21 is graphically shown in this view.
  • the holographic image on the foil substrate is then carried into another drier to insure that the protective coating is hardened prior to be rolled up on to a final roll 21.
  • the roll of holographically imaged foil is now ready for use as a wrap for food products and the like.
  • FIG. 6 a top view of a typical foil substrate 3 having a name brand applied in a holographic image is shown.
  • This holographic image (seen here as “Wrigleys” ) was originally manufactured on a polymeric substrate in a conventional manner and then transferred to the foil substrate 3 in a manner described in Figures 4 and 5. This permits the wide-spread use of a holographic advertisement on a product such as a stick of gum.
  • the holographic image, transferred to the foil substrate, is flashy and eye catching and this is the first such use thereof.
  • a temperature greater than 35°C can be used, I prefer temperatures of 35 to 125 degrees and more preferably at temperatures of between 60 to 90 degrees at the nip of the lamination process of this invention.
  • an elevated pressure is applied to the nip to cause the two substrates, with the holographic image sandwiched between, to be laminated together.
  • a pressure greater than 1 pound per square inch and up to 1,000 pounds per square inch may be used, although I prefer 5 to 10 pounds per square inch.
  • the conditions in the drier should be such that the surface of the polymeric substrate 2 carrying the holographic image 1 and a layer of adhesive material, be somewhere between 35 and 150 degrees centigrade and most preferably 60 to 90 degrees centigrade.
  • the heated nip also should have a temperature of between 25 and 150 degrees C.
  • the purpose of the chill roll 14a is to set up the adhesive and insure that the foil substrate 3 and holographic image 1 on the polymeric substrate 2 is secured.
  • the adhesive material is well-known in the coating art and can be applied at a coating weight of between 0.5 to
  • the protective layer that is applied over the top of the holographic image that has been transferred to the foil substrate by delamination, as shown in FIG. 5, can be any of a host of conventional materials such as solvent or water based acrylics, for example.
  • This protective layer may be colored or tinted to provide additional features, for example.
  • foil substrates within the limits of this invention.
  • aluminum foils of 0.00020 to 2.0 mils in thickness are particularly useful. These foils are well- known in the food industry and are widely used to wrap up gums, candies, chocolate bars and the like.
  • novel holographic image of this invention imparted thereon, these elements may also have other advertisements and writing imparted on the surface by conventional methods .
  • the conventionally holographically imaged polymeric substrates include many of the commonly available plastics, for example. These will include polyethylenes , polypropylenes , polyethylene terephthalates, among others, for example. These substrates are usually 0.03 to 4.0 mils in thickness.
  • the foil substrates on which the holographic images have been transferred may be used in a host of applications including the wrapping of candies and gums; gifts; store wrappings; decorative wrappings; etc.
  • the holographic image may be altered for the use desired. Advertising and decorative images are also envisioned within this invention. Such applications will find wide use within the various industries that employ wrappings of this sort.

Abstract

A holographic image (2) that has been transferred from a conventional polymeric support (2) to a foil support (3) is described in this invention. This image on a foil support (3) may then be wound up in a roll (14), it can be used as a wrapping element for a host of applications. This element and process permits the wide spread use of such holographic images, such use not being available until now.

Description

TITLE
HOLOGRAPHICALLY TRANSFERABLE IMAGES
CROSS REFERENCE TO RELATED APPLICATIONS This application is related to assignee's issued U. S. Patent No. 5,662,986, September 2,
1997.
BACKGROUND OF THE INVENTION
1. Field of the Invention: This invention relates to holographic images formed by a unique process for various security and decorative purposes. Also, this invention relates to aluminized roll-stock holographic images formed on a plastic layer. Further, this invention relates to elements and process for transferring holographic images to yet another substrate. Still further, this invention relates to a unique process for transferring holographic images to a relatively inexpensive substrate which permits a wide-spread use of said holographic image .
2. Description of the Prior Art:
Holographically enhanced materials are well known in the prior art. These are usually made by very proprietary methods which includes passing a layer of plastic, for example, through a machine which imparts a variation (e.g. which can be an image itself) within covering or upper strata of the plastic layer. This step is somewhat similar to, but not exactly the same, as embossing. A powdered metallic element (e.g. aluminum) is then applied thereon by the so-called metallizing process. After this step, the element appears to have a holographic or 3 -dimensional image imparted on the layer of plastic. This image is extremely pleasing and is widely used within the credit card and security industries, for example, to impart an image particular to that credit card or security element thereon. The resulting image is difficult to duplicate and thus these elements assist in the prevention of fraud by counterfeiting, for example . The draw-back to the use of these images is the cost since the machines to produce the image are complicated and costly in and of themselves. Additionally, holographic elements produced by this method (the so-called "shim" method") are usually small in size and thus cannot be imprinted with larger images. Thus, this material has not been widely used outside of the credit card and novelty industry.
Within the food packaging industry it is known use foils and the like for the wrapping of individual food pieces, for example. Sometimes, these foils are embossed with decorative or advertising logos and materials. In addition, it is known in this industry to laminate with glues metallized materials to tissue like paper tissues for the wrapping of individual food pieces such as candies, gums and the like, for example.
Recently, a process for making large sheets of holographically enhanced material has been developed. Thus, the costs of such holographically enhanced material have been significantly reduced. However, these large sheets of material are usually placed on a plastic surface which is also rather expensive and thus the use of this material is still rather limited. If the holographic image could be further transferred to yet another substrate, one which was less expensive and one which had higher utility (e.g. thin foils and the like), the use of such holographically prepared images would find wider use in decorative wrappings and in advertising, for example.
SUMMARY OF THE INVENTION
It is an object of this invention to provide a holographic image that can be transferred to another substrate. It is a further object to utilize a unique transferring process that can place a holographic image directly on a less expensive foil substrate, for example. These and yet other objects are achieved in a thin foil -like wrapping element, said wrapping element having a holographic image having imparted thereto by laminating to a thin foil-like wrapping substrate a holographic image on a polymeric substrate under elevated temperatures and pressure and subsequently delaminating said thin foil-like wrapping substrate from said polymeric substrate.
In yet another embodiment, this invention may be achieved in a process for transferring a holographic image to a foil substrate by laminating a holographic image, said image having been imparted on a polymeric substrate, to said foil substrate at a temperature greater than 35°C and a pressure greater than 1 pound per square inch and subsequently delaminating said foil substrate from said polymeric substrate, whereby said holographic image is transferred to said foil substrate . BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a top view of an actual prior art holographic image prepared by the process described above and contained on a polymeric substrate.
FIG. 2 is a drawing of a side view of FIG. 1. A foil substrate is shown directly above the holographic image which is contained on a polymeric substrate in this Figure. FIG. 3 is a drawing of a side view of a holographic image that has been transferred from the element of FIG. 1 directly to the foil substrate of FIG. 2
FIG. 4 is a drawing of a schematic process for the lamination of a prior art polymeric substrate containing a holographic image to a foil substrate .
FIG. 5 is a drawing of a schematic process of direct delamination of the polymeric substrate from the foil substrate to produce the holographic image of FIG. 2 directly on the foil substrate.
FIG. 6 is a top view of a drawing showing a name brand as a holographic image on a foil substrate, said holographic image having been transferred from a polymeric substrate. A series of these images may be prepared and rolled up so that this holographic image can be used to wrap and advertise in a flashy method.
DETAILS OF THE INVENTION Looking now specifically at the drawings which schematically show the holographic image which is transferable from a polymeric substrate to a more useable foil substrate, FIG. 1 is a top view of an actual holographic image 1 contained on a polymeric substrate. The image has that 3-D holographic look that is well-known in the prior art, especially in the security art field.
In FIG. 2, a side view drawing of the holographic image 1 from FIG. 1 is shown. In this figure, the polymeric substrate on which the holographic image is manufactured, is shown as 2. A foil substrate 3 is shown located directly above the image . In FIG. 3, the holographic image 1 has been transferred to the foil substrate 3.
FIG. 4 is a schematic drawing representing a novel process of this invention for the transfer of a holographic image from a polymeric substrate to a foil substrate. In this figure, a holographic image 1 (not shown in this figure) on a polymeric substrate 2 is shown being pulled off an unwind roll 4 in a nip formed by opposing rollers 5 and 6. In this view, roll 5 is a standard gravure coating roll and roll 6 is a backup roll. A reverse gravure doctor blade (to control coating weight) is shown as 7 and a coating pan (holding a standard adhesive solution) is shown as 8. The coated holographic image on a polymeric substrate is then carried through a drier which is indicated as 9 and 10 and subsequently down to heated rolls 11 and 12. In the nip formed by these last two rolls, a foil substrate 3 taken from a roll 14 contacts the surface of the adhesive containing side of the dried, holographic image 1 contained on a polymeric substrate 2 and is laminated thereto. The heated rolls activate the dried adhesive in order to permit such a lamination to occur. The resulting sandwich 13 is passed over a chill roll 14a and then taken up by rewind roll 14.
The process of delamination is shown in FIG. 5. In this schematic drawing, the laminated sandwich material 13 is drawn off unwind roll 14 and taken through the nip of two delamination rolls 16 and 17. The polymeric substrate 2 is then taken up on a film rewind roll 18 (this material can subsequently be reused and recycled) . The foil substrate 3 now carrying the holographic image 1 thereon is taken up to coating heads 19 and 20. A protective layer is applied over the holographic image contained on this foil substrate in order to protect this image during handling. This may be applied at the nip of the coating heads and a pan 21 is graphically shown in this view. The holographic image on the foil substrate is then carried into another drier to insure that the protective coating is hardened prior to be rolled up on to a final roll 21. The roll of holographically imaged foil is now ready for use as a wrap for food products and the like.
In FIG. 6, a top view of a typical foil substrate 3 having a name brand applied in a holographic image is shown. This holographic image (seen here as "Wrigleys" ) was originally manufactured on a polymeric substrate in a conventional manner and then transferred to the foil substrate 3 in a manner described in Figures 4 and 5. This permits the wide-spread use of a holographic advertisement on a product such as a stick of gum. The holographic image, transferred to the foil substrate, is flashy and eye catching and this is the first such use thereof.
Although a temperature greater than 35°C can be used, I prefer temperatures of 35 to 125 degrees and more preferably at temperatures of between 60 to 90 degrees at the nip of the lamination process of this invention. At the same time, an elevated pressure is applied to the nip to cause the two substrates, with the holographic image sandwiched between, to be laminated together. A pressure greater than 1 pound per square inch and up to 1,000 pounds per square inch may be used, although I prefer 5 to 10 pounds per square inch.
It is most important that the temperature of any step of this process not be greater than 150°C in order not to harm or deform the holographic images in any way. Looking again at FIG. 4, the conditions in the drier should be such that the surface of the polymeric substrate 2 carrying the holographic image 1 and a layer of adhesive material, be somewhere between 35 and 150 degrees centigrade and most preferably 60 to 90 degrees centigrade. One can design a drier which has a proper length and can emanate the proper degree of heat to match up with the web speed which is passing through this drier. The heated nip also should have a temperature of between 25 and 150 degrees C. The purpose of the chill roll 14a is to set up the adhesive and insure that the foil substrate 3 and holographic image 1 on the polymeric substrate 2 is secured. The adhesive material is well-known in the coating art and can be applied at a coating weight of between 0.5 to
8 pounds (dry) per ream of foil, wherein a ream is 500 sheets of foil of 24 inches by 36 inches in size, and can be applied either to the foil substrate or to the holographic image layer. Within the drawings which make up some of the best modes as envisioned at the time of filing of this invention, the adhesive layer is shown being applied to the holographic image first. Then, the foil substrate contacts this layer at the heated nip rolls and is adhered thereto.
The protective layer that is applied over the top of the holographic image that has been transferred to the foil substrate by delamination, as shown in FIG. 5, can be any of a host of conventional materials such as solvent or water based acrylics, for example. This protective layer may be colored or tinted to provide additional features, for example.
I can use a host of foil substrates within the limits of this invention. For example, aluminum foils of 0.00020 to 2.0 mils in thickness are particularly useful. These foils are well- known in the food industry and are widely used to wrap up gums, candies, chocolate bars and the like. In addition to having the novel holographic image of this invention imparted thereon, these elements may also have other advertisements and writing imparted on the surface by conventional methods . The conventionally holographically imaged polymeric substrates include many of the commonly available plastics, for example. These will include polyethylenes , polypropylenes , polyethylene terephthalates, among others, for example. These substrates are usually 0.03 to 4.0 mils in thickness.
The foil substrates on which the holographic images have been transferred may be used in a host of applications including the wrapping of candies and gums; gifts; store wrappings; decorative wrappings; etc. The holographic image may be altered for the use desired. Advertising and decorative images are also envisioned within this invention. Such applications will find wide use within the various industries that employ wrappings of this sort.
The ability to dry-bond laminate and then to delaminate the elements described within this invention represents a unique process since it was not widely known that holographic images could be so transferred. The process as described above uses some unique equipment that is designed to hold, laminate and then delaminate some fairly flimsy material. It is necessary to insure that all of the elements of the process are carefully maintained within processing limits. The use of elements produced within the scope of this invention greatly increases the utility of holographic images within a broader scope. This means that holographic images with larger images, images that can utilize advertising and logos and the like, are now possible.

Claims

What is claimed is :CLAIMS
1. A product comprising a foil wrapping element, said element comprising a foil substrate having two sides surfaces, one of said side surfaces being holographically enhanced, said product made by the process of laminating, at elevated temperature and pressure, a holographic image contained on a polymeric substrate to said side surface of said foil substrate and subsequently delaminating said foil substrate from said polymeric substrate whereby said holographic image is transferred to said surface of said foil substrate .
2. The product of Claim 1 wherein said holographic image is transferred to said foil substrate at a temperature between 30 and 150┬░C and a pressure between 1 and 1,000 pounds.
3. The product of Claim 1 wherein said temperature is between 60 and 90┬░C and said pressure is between 5 and 10 pounds per square inch.
4. The product of Claim 1 wherein said holographically enhanced foil wrapping element is a food wrapping element.
5. The holographically enhanced foil wrapping element of Claim 4 wherein said holographic enhancement is a logo.
6. The product of Claim 1 wherein said foil wrapping element is used as a gift wrap and said element is tinted.
7. The product of Claim 1 wherein said foil substrate has a thickness of between 0.00020 to 2.0 mils.
PCT/US1997/016350 1996-07-09 1997-09-19 Holographically transferable images WO1999015938A1 (en)

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Application Number Priority Date Filing Date Title
US08/679,349 US5723203A (en) 1996-07-09 1996-07-09 Holographically transferable images
US08/824,914 US5902436A (en) 1996-07-09 1997-03-27 Method for transferring a metallized holographic image
EP97941632A EP1015941A4 (en) 1996-07-09 1997-09-19 Holographically transferable images
AU43499/97A AU4349997A (en) 1997-09-19 1997-09-19 Holographically transferable images
CA002303247A CA2303247C (en) 1997-09-19 1997-09-19 Holographically transferable images
PCT/US1997/016350 WO1999015938A1 (en) 1996-07-09 1997-09-19 Holographically transferable images

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US08/679,349 US5723203A (en) 1996-07-09 1996-07-09 Holographically transferable images
PCT/US1997/016350 WO1999015938A1 (en) 1996-07-09 1997-09-19 Holographically transferable images

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