WO1999034315A9 - Use of inorganic particles and method for marking and identifying a substrate or an article - Google Patents
Use of inorganic particles and method for marking and identifying a substrate or an articleInfo
- Publication number
- WO1999034315A9 WO1999034315A9 PCT/EP1998/008452 EP9808452W WO9934315A9 WO 1999034315 A9 WO1999034315 A9 WO 1999034315A9 EP 9808452 W EP9808452 W EP 9808452W WO 9934315 A9 WO9934315 A9 WO 9934315A9
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- inorganic particles
- particles
- marking
- chemical elements
- ratio
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
- C09C1/0021—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a core coated with only one layer having a high or low refractive index
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D15/00—Printed matter of special format or style not otherwise provided for
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0078—Pigments consisting of flaky, non-metallic substrates, characterised by a surface-region containing free metal
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
- B41M3/144—Security printing using fluorescent, luminescent or iridescent effects
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/02—Amorphous compounds
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/85—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/42—Magnetic properties
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/1087—Interference pigments characterized by the core material the core consisting of bismuth oxychloride, magnesium fluoride, nitrides, carbides, borides, lead carbonate, barium or calcium sulfate, zinc sulphide, molybdenum disulphide or graphite
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2210/00—Special effects or uses of interference pigments
- C09C2210/10—Optical properties in the IR-range, e.g. camouflage pigments
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2210/00—Special effects or uses of interference pigments
- C09C2210/20—Optical properties in the UV-range
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2210/00—Special effects or uses of interference pigments
- C09C2210/50—Fluorescent, luminescent or photoluminescent properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2220/00—Methods of preparing the interference pigments
- C09C2220/20—PVD, CVD methods or coating in a gas-phase using a fluidized bed
Definitions
- This invention relates to the use of inorganic particles which comprise at least two chemical elements in a predefined and analytically identifiable ratio, a method for tagging a substrate and to a method of tagging and identifying a substrate and/or an article.
- Encoded micro-particles whose code is represented by at least three visually distinguishable coloured layers of organic resins and their use as tag and/or security feature in order to prevent counterfeiting of articles have already been described in DE 26 51 528 and US 4,329,393. Originally, these particles have been developed to allow tracing of explosives from production to detonation. These tags are sold under the trade name icrotaggant or Microtrace.
- Particle size below 30 ⁇ m is a necessary requirement for many applications, particularly printing inks and related products. Highly resolved lines and figures are difficult to produce with printing inks containing particles larger than the printed feature itself. Particles made of organic laminate can hardly be ground down to sizes in the desired range.
- a further disadvantage of these organic particles is their lack of heat resistance. This results in the destruction of a tagging or security element when the article is exposed to fire or heat.
- US 5,670,239 discloses a composition for the delocalized marking of articles, which makes the forging or improper exploitation of these articles difficult.
- the composition contains non-ubiquitous chemical elements, i.e. more or less rare elements from the main- and sub-groups of the periodic system.
- these which have an X-ray K ⁇ line in the range between 3.69 keV and 76.315 keV and which may be present either in elemental form or in the form of any desired compound.
- An information item e.g. an encrypted numerical code or a number/letter combination
- An information item can be represented by a set of specific elements or compounds, where each specific element or compound represents a digit of the code, and the concentration of the element or compound expresses the value of that digit, e.g. the figure or the letter. If a specific element or compound belonging to the set is absent from the composition, then the value of the corresponding digit is zero or blank.
- a further disadvantage of the teaching of US 5,670,239 is the sensitivity of the encryption to perturbing elements.
- One or more of the elements used for the encryption may accidentally be present for another reason in or on the marked object. This will impede a proper readout of the encoded digit.
- Perturbation of other security systems can, vice versa , occur by the presence of this type of encoding, in particular if soluble compounds of rare-earth ions are employed, which are often luminescent in the visible or infrared domain of the spectrum. This kind of interferences are likely to occur with security documents, where a plurality of security systems has to be combined.
- Another object of the invention is to provide marking means which are compatible with the existing security systems, especially those which are in use on security documents and which serve for their automated machine recognition.
- Another object of the invention is an increase of the coding capacity.
- Another object of the invention is to provide an encryption which makes the reverse-engineering difficult and which can not be broken by most of the commonly available analytic tools.
- Another object of the invention is to provide marking means which are insensitive to perturbing elements.
- Another object of the present invention is to provide marking means which do not depend on the formation of homogeneous mixtures with the base material or materials of the article, or with the coating or printing ink to be marked.
- the specific ratio of elements in that inorganic particle which is characteristic for each type of particles, represents a code, or part of a code.
- the information containing particles can be localized by scanning electron microscopy (SEM) using backscattered electron detection.
- SEM scanning electron microscopy
- the sites i.e. the particles where information is contained, must be localized in a first step.
- the ratio of chemical elements being comprised in that particle can be determined by energy- or wavelength-dispersive X-ray analysis (EDX). Both steps, i.e. the localizing of a particle and its analysis are performed on the same SEM equipment.
- EDX wavelength-dispersive X-ray analysis
- the information retrieval is not dependent on homogeneous mixing.
- SE /EDX is the best practicable method today.
- SEM/EDX a particle volume in the order of 0.01 ⁇ m 3 is sufficient to be properly read.
- a further beneficial property of the SEM/EDX analysis method is its dependency upon standards in order to get reliable quantitative results.
- the quantity of an element present in a particle is determined from the intensity of its characteristic X-ray emission. This latter, however, depends upon the precise excitation conditions i.e. the energy of the exciting electron beam. As the energy of the exciting beam is more or less attenuated in function of the density of the material, the analysis must be performed against standard materials of similar chemical nature. In the absence of such standards, the quantitative results can be quite wrong.
- the standards and their exact compositions are known to the owner of the marking, but not to the counterfeiter. The counterfeiter must therefore rely on indirect evidence, and will therefore not be able to copy the marking, even if he had at his disposition an SEM/EDX equipment and a performing materials synthesis facility.
- the marking particles can contain any chemical element. Particularly useful are elements of the second half of the periodic table as they facilitate the localization of the particle on the SEM. However, for coding purposes, one can use any element with an atomic number of at least five. Those elements are readable by the above mentioned detection and analysing devices.
- the encoding compounds used in the present invention are preferably chosen among the non-stoichiometric crystalline compounds or among the different types of glasses. Not with quite the same security potential, however satisfying for selected applications, are stoichiometric crystalline compounds. Stoichiometric compounds are such which do only exist in a defined elemental ratio. Calcium carbonate (CaC0 3 ) Quartz (Si0 2 ), Baryte (BaS0 4 ), etc. are examples of stoichiometric compounds .
- Non-stoichiometric crystals are solids with a microscopically ordered structure, i.e. the atoms are arranged in a regular fashion, called the crystal structure.
- Certain crystal structures are quite tolerant towards replacement of one type of atom by another without the need for changes in their microscopic order, given that certain general rules like atom sizes and charge neutrality are respected. Examples of such structure types are the spinels (AB 2 0 4 ) the garnets (A 3 B 2 C 3 0 12 or A 3 B 5 0 12 ), the perovskites (AB0 3 ), the lanthanide oxysul- phides (Y,Ln) 2 0 2 S, the zircones (AB0 4 ) etc.
- A,B,C stand for the different types of sites encountered in the crystal structure; these sites must be occupied by corresponding metal ions.
- Ln stands for the lanthanide series, i.e. elements 57 to 71.
- a given site in all these structures may be occupied either by a single type of metal ion, or by a mixture of different types of chemically similar metal ions.
- the compounds Fe 3 0 4 , ZnFe 2 0 4 , (Zn x Co 1 _ x )Fe 2 0 4 and Co(Fe 2 _ x Al x )0 4 all posess the spinel structure.
- the parameter x in certain of these formulas may be freely chosen, i.e. one or more concentration ratios exist which are not prescribed by stoichiometry.
- the present invention relies heavily on the existence of this type of compounds for the realization of suitable information containing particles.
- Glasses are non-crystalline solid state materials, characterized by the absence of microscopic order. At the atomic level, the structure of a glass resembles that of a liquid. One could therefore describe a glass as being an extremely viscous liquid at room temperature.
- the composition of a glass can be changed to a large extent; and a great variety of additional metal ions can be introduced (dissolved) into the glass forming base material.
- Such glass formers are known in the field of oxides (B 2 0 3 , Si0 2 , etc.), of fluorides (BeF 2 , etc.), of nitrides, etc.. Glass compositions are non- stoichiometric per definition, as they do not have a crystal structure with respect to which stoichiometry could be defined.
- glass formation is solubility, i.e. if all desired constituents are able to mix up homogeneously in a single melt and to stay so during cooling down.
- Very exotic glasses are feasible for marking purposes in the present invention, e.g. glasses containing Si, Ge, Al, La, Ta, Er and 0 in various elemental ratios. Glasses can be ground to the desired particle size, although such grinding requires enhanced technology, if very fine particles in the order of 3 - 5 ⁇ m. are to be achieved.
- the particle is of metal alloy such as alnico, brass, bronze, etc..
- the information containing particle consists of superposed layers which comprise the chemical elements in non-stoichiometric or stoichiometric form.
- the inorganic particles can be of any shape, including irregularly formed as well as regularly formed particles.
- the size of said particles is substantially in a range of between 0.1 to 30 micrometers, preferably in a range of between 0.5 to 10 micrometers and even more preferably in a range of between 1 to 5 micrometers. Substantially means that 80 % or more of the total weight of the material falls within the range.
- the volume of the individual particles is substantially comprised within the range between 0.01 ⁇ m 3 to 10000 ⁇ m 3 , preferably within the range of between 0.1 ⁇ m 3 to 1000 ⁇ 3 , more preferably within the range of between 1 ⁇ m 3 to 100 ⁇ m 3 .
- the inorganic particles of the present invention can be blended into any carrier medium which is able to form stable dispersions of said particles and to hold the particles in place for localization and analysis.
- those particles are blended into any kind of coating composition and printing ink which are applied onto any kind of substrate to be marked.
- the film forming carrier medium is chosen to be transparent in the visible range of the electromagnetic spectrum.
- the particles are incorporated into bulk materials which thereafter will obtain their desired form by extrusion, casting, injection moulding, rolling, etc..
- Coating compositions or printing inks comprising said particles can be applied to the underlying substrate by any of the known techniques. These include spraying, brushing, dipping, printing. Printing can be performed e.g. by intaglio, gravure, offset, silkscreen, letterpress, flexography and related techniques .
- the information containing particles can also be incorporated into powder coating compositions, toners, etc., as well as into paper, security foils, plastic sheets and into fibre, in particular for valued papers, banknotes, checks, etc., and for security documents, passports, driving licences etc.. They can furthermore be used in credit cards, ID-cards, access cards and all other type of cards conferring a right or carrying a value.
- the useful amount of particles necessary for a reliable detection and analysis ranges from 0.0001 % to 10 %, preferably from 0.001% to 1% and even more preferably from 0.01% to 0.1% by weight of the total weight of the overall composition or material to which it is added.
- Coating compositions and/or printing inks can be applied to any security document to prevent counterfeiting or unauthorised trade and use of said document.
- the reading of the codes according to he present invention can be done with any currently available scanning electron microscope (SEM), foreseen that it is equipped with a back- scattered electron detector and an energy- or wavelength- dispersive X-ray detector.
- SEM scanning electron microscope
- the data of the examples below stem from three different instruments (a LEO 435VP, a Philips XL30 and a Hitachi S-3500N), which could be used indiscriminately for the same purpose.
- the sample In scanning electron microscopy, the sample is scanned by a very fine focused electron beam, of 5 to 10 nm spot size and 1 to 30 kV electron energy. When this primary beam hits the sample, different types of secondary radiation are produced which can be detected with the help of appropriate devices. A plot of the corresponding detector intensity as a function of the scanning electron beam's co-ordinates yields the SEM picture.
- the primary beam penetrates more or less into the sample material. For example, a beam of 20 keV penetrates about 5 to 8 ⁇ m into an organic ink matrix.
- Secondary electrons i.e. electrons of the sample material which are ejected after collision with electrons of the primary beam. Secondary electrons have low energies (lower than 50 eV), and can therefore only escape from the very surface of the sample. As a consequence, secondary electron detection yields a surface topographic image of the sample ("topographic contrast").
- Backscattered electrons i.e. electrons of the primary beam which are scattered at the nuclei or cores of the sample atoms.
- Backscattered electrons have high energies, close to the energy of the primary beam, and can escape from the whole penetrated sample volume.
- backscattered electrons yield an image of the chemical nature of the sample ("chemical contrast").
- X-rays resulting from the refilling of the sample atoms' vacant electron shells after collisions with electrons of the primary beam.
- Each atom emits its characteristic X-ray spectrum, consisting of K, L, M, etc. line series, which can be used to conclude to the presence of a certain chemical element in the sample, as well as to determine its relative amount, if a comparison standard is available.
- the intensity of the received X-ray emission depends noteworthy upon the energy of the exciting primary electron beam, as well as upon the presence of X-ray absorbing material in the ray path.
- the scanning electron beam energy has to be about at least the double of the energy of the emission lines to be observed, and emission lines with energies lower than 2 keV will already suffer absorption losses in an organic ink matrix.
- a usual primary beam energy in SEM work is 20 keV.
- elements up to about bromine (atomic number 35) can be determined preferably on their K-lines, whereas the elements from rubidium to bismuth (atomic numbers 37 to 83) have to be determined preferably on their L-lines.
- the M-lines are also of some interest, and they serve preferably for the determination of the actinides.
- the peak areas of the K-, L- and M-line series are separately integrated and taken into account according to the device-specific calculation methods.
- Figure 1 shows a SEM picture of a crystalline non- stoichiometric inorganic information containing particle of the present invention, incorporated in a printed intaglio ink, under backscattered electron detection ("chemical contrast").
- Figure 2 shows a SEM picture of several crystalline non- stoichiometric inorganic information containing particles of the present invention in a printed optically variable silk screen ink.
- Figure 3 shows a SEM picture of the same particles as in
- Figure 2 in a printed optically variable intaglio ink.
- Figure 4 shows a SEM picture of a bulk quantity of crystalline non-stoichiometric inorganic information containing particles, visualized by backscattered electron detection.
- Figure 5 shows the energy dispersive X-ray spectrum of one of the crystalline non-stoichiometric particles localized in Figure 2.
- Figure 6 shows a table of SEM/EDX analyses, obtained on inorganic particles according to the invention.
- Figure 7 shows a SEM picture of inorganic information containing particles of the glass type, according to the present invention.
- Figure 8 shows the energy dispersive X-ray spectrum of one of the particles of Figure 7.
- the chemical composition is (Ge0 2 -Si0 2 -La 2 0 3 -Er 2 0 3 -Ta 2 0 5 ) .
- Figure 6 shows a table of SEM/EDX analyses, obtained on inorganic particles according to the invention.
- the first column shows SEM/EDX results, as obtained on the neat particle of Figure 4, using the instrument's internal standardisation and algorithms against the elemental ratio of the standard particle which will only be available to the owner of said standard.
- Columns 2,3 and 4 show SEM/EDX results for each an individual crystal of the marker, present at concentrations of 1 % and 0.1 %, respectively, in two different intaglio inks. These analyses were performed on customary printing of these inks.
- Encoding particles Pi (Y 1-6 Nd 0 . 2 Gd 0 . 2 )O 2 S
- Camouflaging material C2 Gd 2 0 3
Abstract
Description
Claims
Priority Applications (12)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002315064A CA2315064C (en) | 1997-12-29 | 1998-12-22 | Use of inorganic particles and method for marking and identifying a substrate or an article |
UA2000074073A UA46169C2 (en) | 1997-12-29 | 1998-12-22 | METHOD OF PROTECTION OF PRODUCTS, SUBSTRATES AND OTHER SECURITIES FROM COUNTERFEITS (OPTIONS), METHOD OF MARKING PRODUCTS FOR METHOD OF PROTECTION, PROTECTION PROTECTION |
KR1020007007202A KR100564708B1 (en) | 1997-12-29 | 1998-12-22 | Use of inorganic particles and method for marking and identifying a substrate or an article |
MXPA00006430A MXPA00006430A (en) | 1997-12-29 | 1998-12-22 | Use of inorganic particles and method for marking and identifying a substrate or an article. |
JP2000526889A JP4498600B2 (en) | 1997-12-29 | 1998-12-22 | Use of inorganic particles and methods for labeling and identifying supports or articles |
HU0100329A HUP0100329A3 (en) | 1997-12-29 | 1998-12-22 | Use of inorganic particles and method for marking and identifying a substrate or an article |
AU22761/99A AU749608B2 (en) | 1997-12-29 | 1998-12-22 | Use of inorganic particles and method for marking and identifying a substrate or an article |
PL98342101A PL189318B1 (en) | 1997-12-29 | 1998-12-22 | Application of inorganic particles and method of marking and identifying substrates or products |
BRPI9814559-2A BR9814559B1 (en) | 1997-12-29 | 1998-12-22 | use of inorganic particles, coating composition, printing ink or materials, article and method to identify an article. |
NZ505861A NZ505861A (en) | 1997-12-29 | 1998-12-22 | Use of inorganic particles comprising chemical elements in a predefined ratio in marking means |
NO20003385A NO333807B1 (en) | 1997-12-29 | 2000-06-28 | Use of inorganic particles and method for labeling and identifying a substrate or article |
HK01104159A HK1033470A1 (en) | 1997-12-29 | 2001-06-15 | Use of inorganic particles and method for marking and identifying a substrate or an article. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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EP97811029.4 | 1997-12-29 | ||
EP97811029A EP0927749B1 (en) | 1997-12-29 | 1997-12-29 | Coating composition, use of particles, method for tagging and identifying a security document comprising said coating composition |
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WO1999034315A2 WO1999034315A2 (en) | 1999-07-08 |
WO1999034315A3 WO1999034315A3 (en) | 1999-09-16 |
WO1999034315B1 WO1999034315B1 (en) | 1999-10-21 |
WO1999034315A9 true WO1999034315A9 (en) | 1999-11-18 |
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PCT/EP1998/008452 WO1999034315A2 (en) | 1997-12-29 | 1998-12-22 | Use of inorganic particles and method for marking and identifying a substrate or an article |
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US (1) | US6200628B1 (en) |
EP (2) | EP0927749B1 (en) |
JP (1) | JP4498600B2 (en) |
KR (1) | KR100564708B1 (en) |
CN (1) | CN1145681C (en) |
AT (2) | ATE233300T1 (en) |
AU (1) | AU749608B2 (en) |
BR (1) | BR9814559B1 (en) |
CA (1) | CA2315064C (en) |
CZ (1) | CZ302570B6 (en) |
DE (2) | DE69719343T2 (en) |
DK (2) | DK0927749T3 (en) |
ES (2) | ES2193342T3 (en) |
HK (1) | HK1033470A1 (en) |
HU (1) | HUP0100329A3 (en) |
ID (1) | ID26027A (en) |
MX (1) | MXPA00006430A (en) |
NO (1) | NO333807B1 (en) |
NZ (1) | NZ505861A (en) |
PL (1) | PL189318B1 (en) |
PT (2) | PT927749E (en) |
RU (1) | RU2222829C2 (en) |
TR (1) | TR200001875T2 (en) |
TW (1) | TWI250080B (en) |
UA (1) | UA46169C2 (en) |
WO (1) | WO1999034315A2 (en) |
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- 1998-12-22 BR BRPI9814559-2A patent/BR9814559B1/en not_active IP Right Cessation
- 1998-12-22 MX MXPA00006430A patent/MXPA00006430A/en active IP Right Grant
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- 1998-12-22 KR KR1020007007202A patent/KR100564708B1/en not_active IP Right Cessation
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2000
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