WO2000041831A1

WO2000041831A1 - Hot chamber die casting of semisolid metals

Info

Publication number: WO2000041831A1
Application number: PCT/US2000/000725
Authority: WO
Inventors: Merton C. Flemings; Sergio Gallo
Original assignee: Teksid, S.P.A.
Priority date: 1999-01-12
Filing date: 2000-01-12
Publication date: 2000-07-20
Also published as: US20030079854A1; US20010037868A1; US20020084053A1; JP2002534272A

Abstract

A hot chamber method of die casting metals in a semisolid state. The semisolid metal has a high viscosity, which can be controlled by controlling the fraction of solid phase and the morphology of the solid phase. By controlling the viscosity of the melt, turbulence and consequent gas entrapment can be minimized or eliminated. Further, shrinkage is substantially reduced, thereby reducing porosity and hot tearing to form stronger, more reliable castings.

Description

HOT CHAMBER DIE CASTING OF SEMISOLID METALS

Field of the Invention

This application relates to methods and apparatus for hot chamber die casting of semisolid materials.

Background of the Invention

Die casting has traditionally been divided into cold chamber processes and hot chamber processes. Hot chamber processes are distinguished by the fact that the injection cylinder is at least partially immersed in the molten metal, and thus is at the same temperature as the molten metal. Hot chamber die casting is widely used for light alloys such as magnesium- and zinc-based alloys, but has not been found to be commercially viable for casting aluminum alloys. These alloys generally have a higher melting temperature, and thus tend to rapidly degrade steel die casters using a hot chamber process.

Advantages of the hot chamber casting process include higher productivity, reduced scrap and metal losses, reduced die closing pressures, and reduced die wear. Both hot and cold chamber processes, however, suffer from the disadvantage that it is difficult to produce fully sound castings. Liquid metal generally enters the die in a turbulent fashion, entrapping mold gases and forming oxide inclusions in the finished part. Further, solidification shrinkage produces porosity and sometimes tears in the finished casting. It is an object of the present invention to provide a hot-chamber die casting system which minimizes or eliminates these disadvantages.

Summary of the Invention

The present invention supplies a hot chamber method of die casting material in a semisolid state. The semisolid material has a high viscosity, which can be controlled by controlling the fraction of solid phase and the morphology of the solid phase. By controlling the viscosity of the melt, turbulence and consequent gas entrapment can be minimized or eliminated. Further, shrinkage is substantially reduced, thereby reducing porosity and hot tearing to form stronger, more reliable castings. In one aspect, the invention provides a method of die casting, in which a semisolid composition is held between its liquidus and solidus temperatures, and agitated to prevent the formation of interconnected dendritic networks. The composition forms a slurry of solid particles in liquid, which is pumped into a die by an immersed pump. The material is then cooled to cast it in the die. The material may be, for example, a light alloy such as a magnesium, zinc, or aluminum alloy.

In another aspect, the invention includes a hot chamber die caster adapted to cast semisolid materials. The die caster includes a container for holding a composition in the semisolid state, and a pump for pumping the semisolid material into a die. Agitation means prevent the formation of dendrites, holding the material in a semisolid slurry state. The agitation means may be, for example, mechanical or electromagnetic. The caster may be used to cast a variety of light alloys, such as magnesium, zinc, and aluminum alloys. The pump may comprise ferrous materials such as stainless steel.

Brief Description of the Drawing The invention is described with reference to the several figures of the drawing, in which,

Figure 1 is an illustration of a typical hot chamber die casting machine; Figure 2 is an illustration of one embodiment of a hot chamber die caster according to the invention; and

Figure 3 is an illustration of another embodiment of a hot chamber die caster according to the invention.

Detailed Description

Figure 1 shows a typical hot chamber die caster 10, such as is commonly used for casting of magnesium and zinc alloys. The caster works on a "sump pump" principle, using an immersed piston 12 to force molten metal into the casting chamber 14. A hydraulic cylinder 16 reciprocates the piston 12, within a piston chamber 17 whose end is connected to a gooseneck chamber 18 leading to the casting chamber 14. As the piston 12 reaches the top of its stroke, molten metal 20 flows into the piston chamber 17 and the gooseneck chamber 18 through an aperture 22. When the piston 12 then moves down into the chamber 18, it seals the aperture 22 and forces molten metal into the casting chamber 14. The casting chamber 14 is defined by two mold halves 24 and 26. Once the molten metal 20 in the casting chamber 14 has solidified, mold half 26 is moved to release the cast part. The mold is then closed and another cycle of the system can be performed. The gooseneck 18 and cylinder head 16 are thus continuously exposed to molten metal in this process.

The semisolid (or rheocasting) process was discovered about twenty years ago in the laboratory of one of the present inventors. It was found that mechanical stirring of a material between the liquidus and solidus temperatures could break up dendrites, forming a slurry of spheroidized solid particles in liquid. The viscosity of the material can be set to a value in the range of 10^"'-10⁸ poise, simply by controlling the stirring rate. Detailed descriptions of semisolid processing techniques can be found, for example, in U.S. Patent Nos. 3,954,455 and 3,948,650 to Flemings, et al, both of which are incorporated herein by reference. Rheocast castings are generally of more uniform strength and of lower porosity than conventional castings.

The present invention uses semisolid processing to die cast materials using a hot chamber process. Figure 2 shows a die caster designed to carry out this process. It is similar to the die caster shown in Figure 1, but includes a mechanical stirrer 28 for agitating semimolten metal 21. In the embodiment shown, the furnace is provided with a cover 29 and a pressure inlet 30 to aid in forcing semimolten metal 21 through the aperture 22 into the piston chamber 17. Added pressure is not necessary in standard hot-chamber casting processes, because of the very low viscosity of fully molten metal (typically on the order of 10^"2 poise). The higher viscosity of the semisolid compositions of the present invention may make applied pressure preferable or even essential, depending on the properties of the semisolid composition and of the caster material.

The optimum applied pressure for any given embodiment depends on the solid fraction of the semisolid metal and the speed with which it is desired to fully fill the piston chamber 17. It is preferred that die casters according to the invention be able to apply a pressure of at least 30 psi gauge {i.e., 30 psi above atmospheric pressure). If desired, applied pressure and the viscosity of the semisolid metal can be adjusted to provide a relatively high fill rate while minimizing the turbulence of flow into the casting chamber 14.

A temperature controller maintains the melt 20 within a relatively narrow temperature range, in order to ensure that it stays between the liquidus and solidus temperatures. For example, the liquidus and solidus temperatures differ by about

120°C for Mg-8%Al-l%Zn, a common magnesium casting alloy. Known process- control techniques can be used to ensure that the metal temperature and viscosity are kept within acceptable limits.

Figure 3 depicts an embodiment of the die caster related to that of Figure 2, but using electromagnetic, rather than mechanical, stirring means. A set of coils 32 is provided for heating and stirring the semimolten metal 20. The use of electromagnetic stirring and heating may simplify the application of pressure, since the coils 32 do not need to be placed within the semimolten metal 21.

Hot chamber die casting of semisolid materials offers several advantages. The lower temperatures required may provide reduced energy costs and reduced wear rates for casters, and may expand the list of materials which can be inexpensively die cast by the hot chamber method. Further, the increased viscosity of the melt reduces turbulence as the melt enters the die. Reduced turbulence leads to minimal gas entrapment and thus to a reduced concentration of oxide inclusions. In addition, the shrinkage from the semisolid to the solid state is substantially less than that from the fully liquid to the solid state. Thus, shrinkage porosity and hot tearing are reduced in the present process, allowing simpler and less expensive mold designs to be used.

Other embodiments of the invention will be apparent to those skilled in the art from a consideration of the specification or practice of the invention disclosed herein. It is intended that the specification and examples be considered as exemplary only, with the true scope and spirit of the invention being indicated by the following claims. What is claimed is:

Claims

L A method of die casting, comprising holding a composition at a temperature between the liquidus temperature and the solidus temperature of the composition; agitating the composition to form a slurry of primary solids comprising discrete solid particles in liquid while preventing the formation of interconnected solid dendritic networks; pumping the composition into a die with a pump at least partially immersed in the composition; and solidifying the material in the die.

2. The method of claim 1, wherein agitating is accomplished by mechanical stirring.

3. The method of claim 1, wherein agitating is accomplished by electromagnetic stirring.

4. The method of claim 1, wherein the composition comprises a majority component of a metal selected from the group consisting of magnesium, zinc, and aluminum.

5. The method of claim 4, wherein a surface of the pump in contact with the composition comprises a ferrous material.

6. The method of claim 1, further comprising applying a pressure greater than atmospheric pressure to the slurry.

7. A hot-chamber die caster, comprising: a container for holding a semisolid composition between its liquidus and solidus temperatures; means for agitating the semisolid composition to form a slurry of primary solids comprising discrete solid particles in liquid while preventing the formation of interconnected solid dendritic networks; a die for casting the composition; and a pump, at least partially immersed in the semisolid composition and arranged to pump the composition into the die.

8. The hot-chamber die caster of claim 7, wherein the agitation means comprise a mechanical agitator.

9. The hot-chamber die caster of claim 7, wherein the agitation means comprise an electromagnetic agitator.

10. The hot-chamber die caster of claim 7, wherein the caster is adapted to cast an alloy comprising a metal selected from the group consisting of aluminum, magnesium, and zinc.

11. The hot-chamber die caster of claim 10, wherein a surface of the pump in contact with the semisolid composition comprises a ferrous material.

12. The hot-chamber die caster of claim 7, further comprising a pressure inlet for applying a pressure greater than atmospheric pressure to the semisolid composition.