WO2001053231A1 - Environmentally safe and biodegradable composition for manufacturing the skeet target which is used for trapshooting, as well as it's application - Google Patents

Environmentally safe and biodegradable composition for manufacturing the skeet target which is used for trapshooting, as well as it's application Download PDF

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Publication number
WO2001053231A1
WO2001053231A1 PCT/CN2000/000216 CN0000216W WO0153231A1 WO 2001053231 A1 WO2001053231 A1 WO 2001053231A1 CN 0000216 W CN0000216 W CN 0000216W WO 0153231 A1 WO0153231 A1 WO 0153231A1
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Prior art keywords
composition
weight
parts
flying saucer
shooting target
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PCT/CN2000/000216
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French (fr)
Chinese (zh)
Inventor
Guangda Liu
Yue He
Original Assignee
Li, Ping
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Application filed by Li, Ping filed Critical Li, Ping
Priority to AU2000264237A priority Critical patent/AU2000264237A1/en
Publication of WO2001053231A1 publication Critical patent/WO2001053231A1/en

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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41—WEAPONS
    • F41J—TARGETS; TARGET RANGES; BULLET CATCHERS
    • F41J1/00—Targets; Target stands; Target holders
    • F41J1/01—Target discs characterised by their material, structure or surface, e.g. clay pigeon targets characterised by their material
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0072—Biodegradable materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0074—Anti-static agents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

Definitions

  • the present invention relates to the manufacture of sports equipment, and more particularly, to a manufacturing target composition of a shooting target and its use.
  • the flying saucer shooting target widely used in flying saucer shooting is processed from asphalt as the main raw material.
  • This kind of target after the shot is broken, a large amount of asphalt raw material is scattered and left in the soil, causing serious pollution to the environment and human body. Harmful.
  • an object of the present invention is to provide a composition of environmentally friendly, naturally degradable, good temperature resistance products, and capable of stably forming a UFO shooting target manufacturing material.
  • Another object of the present invention is to provide the use of the above composition for manufacturing a flying saucer shooting target.
  • the present invention adopts the following technical solutions:
  • the flying saucer shooting target manufacturing material composition of the present invention includes the following various components and is formulated in a certain amount:
  • Base material including one or more non-metallic mineral powder, shell powder, industrial slag and waste residue
  • the non-metallic mineral powder mentioned above includes limestone, gypsum, quartz, pearl Rock, stone, pumice, marble, granite, kyanite, liquidite, dolomite, magnesite, zircon, refractory clay, high alumina clay, alumina, kaolin, feldspar, wollastonite, orthodox Rock, diopside, fluorite, barite, sulfur ore, celestite, alum stone, borax, phosphate rock, potash, serpentine, mica, calcite, garnet, talc, zeolite, bentonite, diatomite , Attapulgite, sepiolite, illite, rector, etc.
  • the above-mentioned adhesives include rosin, sodium silicate, lac and shellac.
  • the specific gravity modifiers mentioned above include diatomaceous earth, graphite, barite, asbestos and zeolite, perlite, and the like.
  • the clays mentioned above include loess, laterite, shale, river mud, lake mud, landslide and mudstone.
  • aluminosilicate, calcium carbonate, calcium silicate, calcium magnesium silicate, calcium phosphate, calcium magnesium are selected.
  • Raw materials such as silicate are used as components of the composition.
  • non-metallic minerals, shell powder, industrial slag and waste slag are the base material of the composition and the main ingredients of the shooting target;
  • the adhesive has the function of bonding the base material;
  • gypsum is used for production Retarder in the product, to reduce the shrinkage of the finished product after drying, and adjust the brittleness of the product through proper blending; adjust the proportion of lj to adjust the weight of the finished product reasonably, so that the finished product can reach the international standard weight; iron powder, silicate And clay, both are correction materials, adjusted according to different base materials, so that the finished product can be stably formed and has high temperature resistance.
  • the flying saucer shooting target conforms to international standards, and the target weighs 105 grams ⁇ 5 grams, and the flight is stable, and the flight distance is above 80 meters.
  • the products of the present invention are all selected from natural raw materials, after being pulverized by gunshot, the fragments fall into the soil, which can be naturally degraded without causing any pollution and protecting the environment. Because the invention adopts a reasonable formula, the manufactured product has high temperature resistance. After testing, it does not deform for 7 hours at a constant temperature of 70 degrees. At the same time, the product molding rate can reach 90%. The loss rate is less than 1%, and the gun crush rate is as high as 100%, which is much better than the existing UFO shooting target products in terms of performance. Best Mode of the Invention
  • Embodiment 4 is a diagrammatic representation of Embodiment 4:
  • Embodiment 5 is a diagrammatic representation of Embodiment 5:
  • a flying saucer shooting target made according to a conventional process conforms to international standards, and the target weight is 105 g + 5 g, and the flight is stable and the flight distance is above 80 meters.

Abstract

The invention discloses an environmentally safe and biodegradable composition for manufacturing the skeet target which is used for trapshooting, as well as, it's application for the skeet target which is used for trapshooting. This target has the excellent resistance to temperature, and can be formed stably. This composition essentially includes one or more non-metal mineral powder or shell power or industrial slags or wastes: 65-85 weight parts; adhesive: 5-13 weight parts; gypsum: 0.3-2 weight parts; agent for adjusting specific gravity: 2-6 weight parts; iron oxide: 0-1 weight parts; silicate: 3-6 weight parts; and clay: 0-3 weight parts. The target made from this composition has the good resistance to high temperature, as well as the better resistance to deformation, and it's trapshooting debris can be biodegradable and can not pollutes environment.

Description

环保可降解飞碟射击靶制造材料组合物及其应用  Environmentally degradable flying saucer shooting target manufacturing material composition and application thereof
技术领域 Technical field
本发明涉及体育器材的制造， 更具体地说,涉及一种射击靶的制 造材料组合物和其用途. 背景技术  BACKGROUND OF THE INVENTION The present invention relates to the manufacture of sports equipment, and more particularly, to a manufacturing target composition of a shooting target and its use. BACKGROUND
飞碟靶射击与高尔夫球和网球被国际誉为世界贵族层三大运动 项目，目前,国际奥委会将此项目由原来的两枚金牌增加为六枚,同时， 随着世界经济的发展，越来越多的人们投身于飞碟射击的娱乐与运动 中来.  UFO target shooting, golf and tennis are internationally hailed as the three major sports in the aristocratic world. At present, the International Olympic Committee has increased this project from two gold medals to six. At the same time, with the development of the world economy, More and more people are devoted to the entertainment and sports of UFO shooting.
目前飞碟射击运动中广泛使用的飞碟射击靶,是由沥青为主要原 料加工而成.这种靶,在枪击破碎后，大量沥青原料散落下来,残留在泥 土中，对环境造成严重污染，对人体产生危害.  At present, the flying saucer shooting target widely used in flying saucer shooting is processed from asphalt as the main raw material. This kind of target, after the shot is broken, a large amount of asphalt raw material is scattered and left in the soil, causing serious pollution to the environment and human body. Harmful.
为了得到绿色环保型的靶，制造商采用其它材料代替沥青,开发出 新的射击靶，如芬兰，已经有绿色环保靶问世，使用性能较好，但是，由于 配方不够完善,产品耐温性差，在运输途中过赤道就产生变形,产品不 能很好使用。 发明内容  In order to obtain green targets, manufacturers use other materials instead of asphalt and develop new shooting targets. For example, Finland has already launched green targets, which have better performance. However, due to insufficient formula and poor temperature resistance, Deformation occurs across the equator during transportation, and the product cannot be used well. Summary of the Invention
针对上述问题， 本发明的目的是提供一种环保 、可自然降解， 其产品耐温性能好， 并且能够稳定成型的飞碟射击靶制造材料的组 合物。  In view of the above problems, an object of the present invention is to provide a composition of environmentally friendly, naturally degradable, good temperature resistance products, and capable of stably forming a UFO shooting target manufacturing material.
本发明的另一目的，在于提供上述组合物在制造飞碟射击靶上的 用途。  Another object of the present invention is to provide the use of the above composition for manufacturing a flying saucer shooting target.
为实现上述目的， 本发明采取以下技术方案：  To achieve the above objective, the present invention adopts the following technical solutions:
本发明的飞碟射击靶制造材料组合物， 包括以下各种组份按一 定量配制而成：  The flying saucer shooting target manufacturing material composition of the present invention includes the following various components and is formulated in a certain amount:
基料， 包括一种或几种非金属矿粉， 贝壳粉， 工业矿渣及废渣  Base material, including one or more non-metallic mineral powder, shell powder, industrial slag and waste residue
65-85重量份 胶粘剂 5〜13重量份 石膏 0.3〜2重量份 比重调节剂 2~6重量份 氧化铁 0〜1重量份 硅酸盐 3~6重量份 粘土 0-3重量份 上面所述非金属矿粉包括石灰石 、 石膏、 石英、 珍珠岩、 石、 浮石、 大理石、 花岗岩、 蓝晶石、 液腊石、 白云石、 菱镁矿、 锆英 石、 耐火粘土、 高铝粘土、 矾土、 高岭土、 长石、 硅灰石、 正长岩 、 透辉石、 萤石、 重晶石、 硫矿、 天青石、 明矾石、 硼砂、 磷矿、 钾矿、 蛇纹石、 云母、 方解石、 石榴石、 滑石、 沸石、 膨润土、 硅 藻土、 凹凸棒石、 海泡石、 伊利石、 累托石等。 65-85 parts by weight 0.3 ~ 2 parts by weight of gypsum, 2 ~ 6 parts by weight of iron oxide, 0 ~ 1 parts by weight of silicate, 3 ~ 6 parts by weight of clay, 0-3 parts by weight of clay, the non-metallic mineral powder mentioned above includes limestone, gypsum, quartz, pearl Rock, stone, pumice, marble, granite, kyanite, liquidite, dolomite, magnesite, zircon, refractory clay, high alumina clay, alumina, kaolin, feldspar, wollastonite, orthodox Rock, diopside, fluorite, barite, sulfur ore, celestite, alum stone, borax, phosphate rock, potash, serpentine, mica, calcite, garnet, talc, zeolite, bentonite, diatomite , Attapulgite, sepiolite, illite, rector, etc.
上面所述胶粘剂包括松香、 硅酸钠、 栲胶和紫胶等。  The above-mentioned adhesives include rosin, sodium silicate, lac and shellac.
上面所述比重调节剂包括硅藻土、 石墨、 重晶石、 石棉和沸石、 珍珠石等。  The specific gravity modifiers mentioned above include diatomaceous earth, graphite, barite, asbestos and zeolite, perlite, and the like.
上面所述粘土， 包括黄土、 红土、 页岩、 河泥、 湖泥、 山泥和泥 岩等。  The clays mentioned above include loess, laterite, shale, river mud, lake mud, landslide and mudstone.
为达到环保目的， 使破碎碎片自然降解并成为改良土壤的有益成 分， 上述所有天然原料中， 尽可能选择含有铝硅酸盐、 碳酸钙、 硅 酸钙、 镁硅酸钙、 磷酸钙、 钙镁硅酸盐等成分的原料作为组合物组 份。  In order to achieve the purpose of environmental protection, the broken fragments are naturally degraded and become a useful ingredient for improving the soil. Among all the above-mentioned natural raw materials, as far as possible, aluminosilicate, calcium carbonate, calcium silicate, calcium magnesium silicate, calcium phosphate, calcium magnesium are selected. Raw materials such as silicate are used as components of the composition.
上述技术方案中， 组合物中， 非金属矿物以及贝壳粉、 工业矿渣 及废渣， 是组合物的基料， 也是射击靶的主要配料； 胶粘剂具有将 上述基料粘合的作用； 而石膏作为生产中的缓凝剂， 减少成品干燥 后的收縮率， 并且通过适当调配， 调节产品的脆性； 加入比重调节 齐 lj， 合理调整成品的重量， 使成品能够达到国际标准重量； 铁粉、 硅酸盐和粘土， 均为校正材料， 依据不同的基料进行调整， 使成品 能够稳定成型并且具有耐高温性。  In the above technical solution, in the composition, non-metallic minerals, shell powder, industrial slag and waste slag are the base material of the composition and the main ingredients of the shooting target; the adhesive has the function of bonding the base material; and gypsum is used for production Retarder in the product, to reduce the shrinkage of the finished product after drying, and adjust the brittleness of the product through proper blending; adjust the proportion of lj to adjust the weight of the finished product reasonably, so that the finished product can reach the international standard weight; iron powder, silicate And clay, both are correction materials, adjusted according to different base materials, so that the finished product can be stably formed and has high temperature resistance.
上述组合物组份经破碎、混合、挤压成型后，制成的飞碟射击靶， 符合国际标准， 靶重 105克 ±5克， 飞行稳定， 飞行距离在 80米以上 。 并且， 本发明产品由于选用的都为天然原料， 枪击粉碎后， 碎片 落入土壤中， 可以自然降解， 不会造成任何污染， 保护环境。 本发 明由于采用合理的配方， 制造的产品具耐高温性能， 经测试， 在恒 温 70摄式度下 7小时不变形， 同时， 产品成型率可达 90%， 抛碟破 损率小于 1%， 枪击粉碎率高达 100%， 从性能上， 大大优于现有的 飞碟射击靶产品。 本发明的最佳实施方式 After the above composition components are crushed, mixed, and extruded, the flying saucer shooting target conforms to international standards, and the target weighs 105 grams ± 5 grams, and the flight is stable, and the flight distance is above 80 meters. In addition, since the products of the present invention are all selected from natural raw materials, after being pulverized by gunshot, the fragments fall into the soil, which can be naturally degraded without causing any pollution and protecting the environment. Because the invention adopts a reasonable formula, the manufactured product has high temperature resistance. After testing, it does not deform for 7 hours at a constant temperature of 70 degrees. At the same time, the product molding rate can reach 90%. The loss rate is less than 1%, and the gun crush rate is as high as 100%, which is much better than the existing UFO shooting target products in terms of performance. Best Mode of the Invention
实施例一：  Embodiment one:
分别称取石灰石 77公斤， 珍珠岩 5公斤， 粘土 2.8公斤， 硅酸盐 3.2公斤,石膏 2公斤，氧化铁 1公斤，松香 9公斤，将其粉碎至 20CK300 目后， 放入高速混合器中充分混合， 然后注入挤出机中挤出， 液压 成型， 制成飞碟射击靶成品。  Weigh 77 kilograms of limestone, 5 kilograms of perlite, 2.8 kilograms of clay, 3.2 kilograms of silicate, 2 kilograms of gypsum, 1 kilogram of iron oxide, 9 kilograms of rosin, crush them to 20CK300 mesh, and put them in a high-speed mixer. Mix and inject into the extruder for extrusion and hydroforming to make the finished flying saucer target.
实施例二：  Embodiment two:
分别称取贝壳粉 80公斤， 重晶石 6公斤， 石膏 0.3公斤， 硅酸盐 3.2公斤， 氧化铁 0.5公斤， 栲胶 10公斤， 按实施例一的方法制备出 飞碟射击靶成品。  80 kg of shell powder, 6 kg of barite, 0.3 kg of gypsum, 3.2 kg of silicate, 0.5 kg of iron oxide, and 10 kg of rubber were weighed respectively, and the finished UFO shooting target was prepared according to the method of Example 1.
实施例三：  Embodiment three:
分别称取沸石粉 85公斤， 硅酸钠 13公斤， 珍珠岩 5公斤， 石 膏 2公斤， 硅酸盐 6公斤， 氧化铁 0.5公斤， 粘土 3公斤， 按实施例 一的方法制备出飞碟射击靶成品。  Weigh 85 kg of zeolite powder, 13 kg of sodium silicate, 5 kg of perlite, 2 kg of gypsum, 6 kg of silicate, 0.5 kg of iron oxide, 3 kg of clay, and prepare a finished flying saucer target according to the method of Example 1. .
实施例四：  Embodiment 4:
分别称取工业提铝矿渣 60公斤， 粉煤灰 5公斤， 珍珠岩 3公斤， 石膏 1公斤， 硅酸盐 4公斤， 硅酸钠 5公斤， 按实施例一的方法制 备出飞碟射击靶成品。  Weighed 60 kg of industrial aluminum slag, 5 kg of fly ash, 3 kg of perlite, 1 kg of gypsum, 4 kg of silicate, 5 kg of sodium silicate, and prepared the finished flying saucer target according to the method of Example 1.
实施例五：  Embodiment 5:
分别称取硅藻土 80公斤， 重晶石 2公斤， 硅酸盐 5公斤， 硅酸 钠 7公斤， 石膏 0.7公斤， 氧化铁 0.8公斤， 粘土 3公斤， 按实施例 一的方法制备出飞碟射击靶成品。 工业应用性  Weigh 80 kg of diatomite, 2 kg of barite, 5 kg of silicate, 7 kg of sodium silicate, 0.7 kg of gypsum, 0.8 kg of iron oxide, 3 kg of clay, and prepare a flying saucer shot according to the method of Example 1. Target product. Industrial applicability
将本发明的组合物组份破碎、 混合、 挤压成型后， 按照常规工艺 制成的飞碟射击靶， 符合国际标准， 靶重 105克 +5克， 飞行稳定， 飞行距离在 80米以上。  After the components of the composition of the present invention are crushed, mixed, and extruded, a flying saucer shooting target made according to a conventional process conforms to international standards, and the target weight is 105 g + 5 g, and the flight is stable and the flight distance is above 80 meters.

Claims

权利要求 Rights request
1、 一种飞碟射击靶制造材料的组合物， 其特征在于， 包括以下各 种组份按一定量配制而成： 1. A composition of a flying saucer shooting target manufacturing material, which is characterized in that it comprises the following various components formulated in a certain amount:
基料， 包括一种或几种非金属矿粉， 贝壳粉， 工业矿渣及废渣  Base material, including one or more non-metallic mineral powder, shell powder, industrial slag and waste residue
65-85重量份 胶粘剂 5-13重量份 石膏 0.3-2重量份 比重调节剂 2-6重量份 氧化铁 0-1重量份 硅酸盐 3〜6重量份 粘土 0-3重量份 65-85 parts by weight Adhesive 5-13 parts by weight Gypsum 0.3-2 parts by weight Specific gravity modifier 2-6 parts by weight Iron oxide 0-1 parts by weight Silicate 3-6 parts by weight Clay 0-3 parts by weight
2、根据权利要求 1的飞碟射击靶制造材料的组合物 ， 其特征在于: 所述非金属矿粉包括石灰石 、 石膏、 石英、 珍珠岩 石、 浮石、 大 理石、 花岗岩、 蓝晶石、 液腊石、 白云石、 菱镁矿、 锆英石、 耐火 粘土、 高铝粘土、 矾土、 高岭土、 长石、 硅灰石、 正长岩、 透辉石 、 萤石、 重晶石、 硫矿、 天青石、 明矾石、 硼砂、 磷矿、 钾矿、 蛇 纹石、 云母、 方解石、 石榴石、 滑石、 沸石、 膨润土、 硅藻土、 凹 凸棒石、 海泡石、 伊利石、 累托石等。 2. The composition of a flying saucer shooting target manufacturing material according to claim 1, characterized in that the non-metallic mineral powder includes limestone, gypsum, quartz, perlite, pumice, marble, granite, kyanite, limonite, Dolomite, magnesite, zircon, refractory clay, high alumina clay, alumina, kaolin, feldspar, wollastonite, orthoclase, diopside, fluorite, barite, sulfur ore, celestite , Alumite, borax, phosphate rock, potash, serpentine, mica, calcite, garnet, talc, zeolite, bentonite, diatomaceous earth, attapulgite, sepiolite, illite, rector, etc.
3、根据权利要求 1的飞碟射击靶制造材料的组合物 ， 其特征在于： 所述胶粘剂包括松香、 硅酸钠、 栲胶和紫胶等。  3. The composition of a flying saucer shooting target manufacturing material according to claim 1, wherein the adhesive comprises rosin, sodium silicate, lac, shellac, and the like.
4、 根据权利要求 1的飞碟射击靶制造材料的组合物， 其特征在于： 所述比重调节剂包括硅藻土、 石墨、 重晶石、 石棉和沸石、 珍珠石 等 。  4. The composition of a flying saucer shooting target manufacturing material according to claim 1, wherein the specific gravity adjusting agent comprises diatomaceous earth, graphite, barite, asbestos and zeolite, perlite, and the like.
5、权利要求 1所述的飞碟射击靶制造材料的组合物作为原材料在制 造飞碟射击靶上的应用。  5. Use of the composition of a flying saucer shooting target manufacturing material according to claim 1 as a raw material for manufacturing a flying saucer shooting target.
PCT/CN2000/000216 2000-01-19 2000-07-28 Environmentally safe and biodegradable composition for manufacturing the skeet target which is used for trapshooting, as well as it's application WO2001053231A1 (en)

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AU2000264237A AU2000264237A1 (en) 2000-01-19 2000-07-28 Environmentally safe and biodegradable composition for manufacturing the skeet target which is used for trapshooting, as well as it's application

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CN00100371.2 2000-01-19
CN00100371A CN1123605C (en) 2000-01-19 2000-01-19 Degradable skeet material composite and its application in making skeet

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JP2006266531A (en) * 2005-03-22 2006-10-05 Asahi Kasei Chemicals Corp Clay composition for shooting
CN114436615A (en) * 2020-09-11 2022-05-06 内江师范学院 Flying saucer target

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CN1303395C (en) * 2005-04-05 2007-03-07 陈露丝 Flying disk target made from degradable compound fertilizer in green environmental protection
CN101852572A (en) * 2010-05-13 2010-10-06 王秀华 Dry-free, environment-friendly, energy-saving and degradable flaying saucer by taking tailings powder as raw material and manufacturing method thereof

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US5649707A (en) * 1993-09-09 1997-07-22 Auramatrix Ifo Oy Clay pigeon and a method for the preparation thereof
CN1241597A (en) * 1999-07-07 2000-01-19 刘永丰 Degradable material for producing flying saucer target without environment pollution

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US5389142A (en) * 1994-02-04 1995-02-14 Moore; Patrick T. Method and composition for making an improved frangible biodegradable clay target
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Publication number Priority date Publication date Assignee Title
JP2006266531A (en) * 2005-03-22 2006-10-05 Asahi Kasei Chemicals Corp Clay composition for shooting
CN114436615A (en) * 2020-09-11 2022-05-06 内江师范学院 Flying saucer target
CN114436615B (en) * 2020-09-11 2023-01-24 内江师范学院 Flying saucer target

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CN1123605C (en) 2003-10-08
AU2000264237A1 (en) 2001-07-31
CN1258696A (en) 2000-07-05

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