WO2004039187A3 - Multu-functional protective textiles and methods for decontamination - Google Patents

Multu-functional protective textiles and methods for decontamination Download PDF

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Publication number
WO2004039187A3
WO2004039187A3 PCT/US2003/005177 US0305177W WO2004039187A3 WO 2004039187 A3 WO2004039187 A3 WO 2004039187A3 US 0305177 W US0305177 W US 0305177W WO 2004039187 A3 WO2004039187 A3 WO 2004039187A3
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WO
WIPO (PCT)
Prior art keywords
protective
nanoparticles
textile
article
biocidal
Prior art date
Application number
PCT/US2003/005177
Other languages
French (fr)
Other versions
WO2004039187A2 (en
Inventor
Holly C Axtell
Scott M Hartley
Robert A Sallavanti
Original Assignee
Gentex Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gentex Corp filed Critical Gentex Corp
Priority to KR10-2004-7013200A priority Critical patent/KR20040091072A/en
Priority to JP2004548250A priority patent/JP2006502322A/en
Priority to CA 2477250 priority patent/CA2477250A1/en
Priority to AU2003299455A priority patent/AU2003299455A1/en
Priority to EP20030799745 priority patent/EP1487288A2/en
Publication of WO2004039187A2 publication Critical patent/WO2004039187A2/en
Publication of WO2004039187A3 publication Critical patent/WO2004039187A3/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K33/00—Medicinal preparations containing inorganic active ingredients
    • A61K33/02—Ammonia; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P43/00—Drugs for specific purposes, not provided for in groups A61P1/00-A61P41/00
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D5/00—Composition of materials for coverings or clothing affording protection against harmful chemical agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
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    • B01J20/28016—Particle form
    • B01J20/28019—Spherical, ellipsoidal or cylindrical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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    • B01J20/28023—Fibres or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28028—Particles immobilised within fibres or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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    • B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
    • B01J20/28038—Membranes or mats made from fibers or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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    • B01J20/28052—Several layers of identical or different sorbents stacked in a housing, e.g. in a column
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/28097—Shape or type of pores, voids, channels, ducts being coated, filled or plugged with specific compounds
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    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10S977/775—Nanosized powder or flake, e.g. nanosized catalyst
    • Y10S977/777—Metallic powder or flake
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10—Methods of surface bonding and/or assembly therefor
    • Y10T156/1089—Methods of surface bonding and/or assembly therefor of discrete laminae to single face of additional lamina
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2525—Coating or impregnation functions biologically [e.g., insect repellent, antiseptic, insecticide, bactericide, etc.]

Abstract

A reactive and adsorptive (i.e., multi -functional protective) textile and methods for constructing and using same which possess at least chemically reactive and biocidal properties. Nanoparticles from different classes such as metal oxides, metal hydroxides, metal hydrates and POMs are incorporated into elements which can be utilized in a wide variety of protective materials. The nanoparticles may be treated to reduce water solubility or combined with halogens, alkali metals or secondary metal oxides to specifically engineer the nanoparticle to address a particular chemical or biocidal threat. In one aspect, a protective spatially-distributed biocidal interface is provided comprising a textile having interior structures, wherein protective nanoparticles bonded to said interior structures such that an article or portions of an article which are maintained in proximity to the textile are permitted to safely pass through a contaminated environment without dispersing the nanoparticles from protective proximity to the article.
PCT/US2003/005177 2002-02-25 2003-02-21 Multu-functional protective textiles and methods for decontamination WO2004039187A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
KR10-2004-7013200A KR20040091072A (en) 2002-02-25 2003-02-21 Muti-fucntional protective textiles and methods for decontamination
JP2004548250A JP2006502322A (en) 2002-02-25 2003-02-21 Multifunctional protective fabric and decontamination method (cross-reference of related applications) This patent application claims the priority date benefit of US Provisional Application 60 / 360,050, filed February 25,2002.
CA 2477250 CA2477250A1 (en) 2002-02-25 2003-02-21 Multi-functional protective textiles and methods for decontamination
AU2003299455A AU2003299455A1 (en) 2002-02-25 2003-02-21 Multu-functional protective textiles and methods for decontamination
EP20030799745 EP1487288A2 (en) 2002-02-25 2003-02-21 Multu-functional protective textiles and methods for decontamination

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US36005002P 2002-02-25 2002-02-25
US60/360,050 2002-02-25

Publications (2)

Publication Number Publication Date
WO2004039187A2 WO2004039187A2 (en) 2004-05-13
WO2004039187A3 true WO2004039187A3 (en) 2004-07-29

Family

ID=27766180

Family Applications (4)

Application Number Title Priority Date Filing Date
PCT/US2003/005176 WO2003104534A2 (en) 2002-02-25 2003-02-21 Cross-reference to related applications
PCT/US2003/005177 WO2004039187A2 (en) 2002-02-25 2003-02-21 Multu-functional protective textiles and methods for decontamination
PCT/US2003/005561 WO2003072498A1 (en) 2002-02-25 2003-02-24 Reactive-adsorptive protective materials and methods for use
PCT/US2003/005558 WO2003072242A2 (en) 2002-02-25 2003-02-24 Multi-functional protective materials and methods for use

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Families Citing this family (117)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6713076B1 (en) * 1998-04-13 2004-03-30 Emory University Methods for removing a contaminant by a polyoxometalate-modified fabric or a polyoxometalate-modified cellulosic fiber and fabrics thereof
US6723349B1 (en) * 1999-10-12 2004-04-20 Emory University Polyoxometalate materials, metal-containing materials, and methods of use thereof
AU2003299455A1 (en) * 2002-02-25 2004-05-25 Gentex Corporation Multu-functional protective textiles and methods for decontamination
US7691289B2 (en) * 2003-02-25 2010-04-06 Emory University Compositions, materials incorporating the compositions, and methods of using the compositions, and methods of using the compositions and materials
US20040178135A1 (en) * 2003-03-13 2004-09-16 Beplate Douglas K. Filtering device incorporating nanoparticles
US11179673B2 (en) 2003-04-23 2021-11-23 Midwwest Energy Emission Corp. Sorbents for the oxidation and removal of mercury
US10828596B2 (en) 2003-04-23 2020-11-10 Midwest Energy Emissions Corp. Promoted ammonium salt-protected activated carbon sorbent particles for removal of mercury from gas streams
US7435286B2 (en) 2004-08-30 2008-10-14 Energy & Environmental Research Center Foundation Sorbents for the oxidation and removal of mercury
US7060121B2 (en) * 2003-06-25 2006-06-13 Hsing Kuang Lin Method of producing gold nanoparticle
US7704598B2 (en) 2004-05-26 2010-04-27 Gore Enterprise Holdings, Inc. Durable covering for chemical protection
US10343114B2 (en) 2004-08-30 2019-07-09 Midwest Energy Emissions Corp Sorbents for the oxidation and removal of mercury
JP4693030B2 (en) * 2004-11-08 2011-06-01 オルガノ株式会社 Method for producing activated carbon
US7549431B1 (en) * 2004-11-10 2009-06-23 Gore Enterprise Holdings, Inc. Protective enclosure
KR100613189B1 (en) * 2004-11-15 2006-08-21 미지테크주식회사 Ag nano synthetic fiber and manufacturing method thereof
US8539957B2 (en) 2005-01-14 2013-09-24 Philip Morris Usa Inc. Cigarettes and cigarette filters including activated carbon for removing nitric oxide
ATE389534T1 (en) * 2005-01-26 2008-04-15 Runlite S A THERMOPLASTIC MATERIAL, METHOD FOR PRODUCING ORTHOPEDIC DEVICES AND ORTHOPEDIC DEVICES PRODUCED THEREFROM
JP2006247527A (en) * 2005-03-10 2006-09-21 Kansai Coke & Chem Co Ltd Adsorbent
US8070705B2 (en) * 2005-06-21 2011-12-06 Hipsaver, Incorporated Protective device using a spacer fabric
DE102005040189B4 (en) * 2005-06-28 2011-08-18 Blücher GmbH, 40699 Support material with catalytically active polymer particles
JP4899396B2 (en) * 2005-09-28 2012-03-21 住友ベークライト株式会社 Carbon material, and negative electrode material and non-aqueous electrolyte secondary battery for secondary battery using the same
US20070151921A1 (en) * 2006-01-03 2007-07-05 Ceo Espinex Inc. Self-cleaning filtration nanofiber membrane
US8247072B2 (en) 2006-02-14 2012-08-21 Eastman Chemical Company Resol beads, methods of making them and methods of using them
GB0603138D0 (en) * 2006-02-16 2006-03-29 Queen Mary & Westfield College Virucidal materials
SE529942C2 (en) * 2006-05-19 2008-01-08 Callenberg Flaekt Marine Ab Ventilation system and procedure
KR101255512B1 (en) * 2006-06-30 2013-04-16 엘지디스플레이 주식회사 Method For Fabricating Thin Film Transistor Array Substrate
US20080063679A1 (en) * 2006-08-04 2008-03-13 Quartek Corporation Nanocomposites with residual biocidal and biostatic properties
JP2008055247A (en) * 2006-08-29 2008-03-13 Matsushita Electric Ind Co Ltd Filter for removing gas
WO2008027530A1 (en) * 2006-09-01 2008-03-06 Seldon Technologies, Llc Nanostructured materials comprising support fibers coated with metal containing compounds and methods of using the same
DE202006016898U1 (en) * 2006-10-12 2007-11-22 BLüCHER GMBH High performance adsorbents based on activated carbon with high microporosity
JP5523102B2 (en) 2006-11-08 2014-06-18 キュレーターズ オブ ザ ユニバーシティ オブ ミズーリ High surface area carbon and method for producing the same
US9504946B2 (en) 2006-12-14 2016-11-29 Mycelx Technologies Corporation Process and system for separating finely aerosolized elemental mercury from gaseous streams
US7981298B2 (en) * 2006-12-14 2011-07-19 Hal Alper Process for removal of contaminants from industrial streams
US9005755B2 (en) 2007-01-03 2015-04-14 Applied Nanostructured Solutions, Llc CNS-infused carbon nanomaterials and process therefor
US20120189846A1 (en) * 2007-01-03 2012-07-26 Lockheed Martin Corporation Cnt-infused ceramic fiber materials and process therefor
US8951631B2 (en) 2007-01-03 2015-02-10 Applied Nanostructured Solutions, Llc CNT-infused metal fiber materials and process therefor
US8951632B2 (en) 2007-01-03 2015-02-10 Applied Nanostructured Solutions, Llc CNT-infused carbon fiber materials and process therefor
DE102007050971B4 (en) * 2007-03-14 2014-12-31 BLüCHER GMBH Process for the preparation of high performance adsorbents based on activated carbon with high meso- and macroporosity, high performance adsorbents and their use
US8413721B2 (en) 2007-05-22 2013-04-09 Halliburton Energy Services, Inc. Viscosified fluids for remediating subterranean damage
US8772197B2 (en) * 2007-08-17 2014-07-08 Massachusetts Institute Of Technology Compositions for chemical and biological defense
US8252969B2 (en) * 2007-09-04 2012-08-28 Science Applications International Corporation Hypernucleophilic catalysts for detoxification of chemical threat agents
US8183426B2 (en) * 2007-10-11 2012-05-22 Nanoscale Corporation Decontaminating sheet material containing reactive nanocrystalline particles and products constructed therefrom
DE202008000810U1 (en) * 2007-11-04 2008-12-24 BLüCHER GMBH sorption filter
US8555896B2 (en) 2007-12-19 2013-10-15 Philip Morris Usa Inc. Activated carbon from microcrystalline cellulose
US8037550B2 (en) * 2008-02-01 2011-10-18 Gore Enterprise Holdings, Inc. Stretchable chemical protective material
US20090218266A1 (en) * 2008-03-03 2009-09-03 Reyad Sawafta Water treatment and methods of use
WO2010027868A2 (en) 2008-08-26 2010-03-11 Nanoscale Corporation Method and apparatus for control and elimination of undesirable substances
US10368785B2 (en) 2008-10-24 2019-08-06 East Carolina University In-ear hearing test probe devices and methods and systems using same
KR101703340B1 (en) * 2009-02-27 2017-02-06 어플라이드 나노스트럭처드 솔루션스, 엘엘씨. Low temperature cnt growth using gas-preheat method
US20100227134A1 (en) * 2009-03-03 2010-09-09 Lockheed Martin Corporation Method for the prevention of nanoparticle agglomeration at high temperatures
BRPI1010288A2 (en) * 2009-04-10 2016-03-22 Applied Nanostructured Sols apparatus and method for producing carbon nanotubes on a continuously moving substrate
US20100260931A1 (en) * 2009-04-10 2010-10-14 Lockheed Martin Corporation Method and apparatus for using a vertical furnace to infuse carbon nanotubes to fiber
US20100272891A1 (en) * 2009-04-10 2010-10-28 Lockheed Martin Corporation Apparatus and method for the production of carbon nanotubes on a continuously moving substrate
US20100260998A1 (en) * 2009-04-10 2010-10-14 Lockheed Martin Corporation Fiber sizing comprising nanoparticles
CN102421704A (en) * 2009-04-30 2012-04-18 应用纳米结构方案公司 Method and system for close proximity catalysis for carbon nanotube synthesis
AU2010279709A1 (en) * 2009-08-03 2012-01-19 Applied Nanostructured Solutions, Llc. Incorporation of nanoparticles in composite fibers
US20110045218A1 (en) * 2009-08-21 2011-02-24 Harper Nancy L Dynamic inks and coatings
CA2772072C (en) 2009-08-28 2017-08-01 Hal Alper Method and system for analyzing concentrations of diverse mercury species present in a fluid medium
CN103140613B (en) * 2009-11-02 2015-03-25 应用纳米结构方案公司 CNT-infused aramid fiber materials and process therefor
JP5398483B2 (en) * 2009-11-11 2014-01-29 ユニチカ株式会社 Sanitary mask
FR2952651B1 (en) * 2009-11-17 2012-02-24 Commissariat Energie Atomique USE OF A FABRIC COMPRISING A SPECIFIC MATERIAL FOR DETECTING THE PRESENCE OF A CHEMICAL SUBSTANCE
US11298657B2 (en) 2010-10-25 2022-04-12 ADA-ES, Inc. Hot-side method and system
US8951487B2 (en) 2010-10-25 2015-02-10 ADA-ES, Inc. Hot-side method and system
US8496894B2 (en) 2010-02-04 2013-07-30 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
CN104475313B (en) 2010-09-14 2017-05-17 应用奈米结构公司 Glass substrates having carbon nanotubes grown thereon and methods for production thereof
US8815341B2 (en) 2010-09-22 2014-08-26 Applied Nanostructured Solutions, Llc Carbon fiber substrates having carbon nanotubes grown thereon and processes for production thereof
KR101315112B1 (en) * 2011-04-28 2013-10-08 고등기술연구원연구조합 Methode for preparing nano pore on carbon matrix
US8845986B2 (en) 2011-05-13 2014-09-30 ADA-ES, Inc. Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers
US9849512B2 (en) 2011-07-01 2017-12-26 Attostat, Inc. Method and apparatus for production of uniformly sized nanoparticles
CN102897760A (en) * 2011-07-29 2013-01-30 中国科学院过程工程研究所 Method for preparing activated carbon by using eupatorium adenophorum
DE102011114132A1 (en) 2011-08-14 2013-02-14 BLüCHER GMBH Filter material useful e.g. in or as filter for gas treatment and in filters for removing pollutants, comprises activated carbon, which is present in form of discrete activated carbon particles, preferably in spherical or granular shape
WO2013023932A1 (en) * 2011-08-17 2013-02-21 BLüCHER GMBH Adsorbent precipitated on a carrier, method for producing said adsorbent, and use of said adsorbent
WO2013070809A2 (en) * 2011-11-07 2013-05-16 Delcath Systems, Inc. Apparatus for removing chemotherapy compounds from blood
US20150336081A1 (en) * 2012-03-07 2015-11-26 Clear Carbon Innovations LLC Magnetic adsorbents, methods for manufacturing a magnetic adsorbent, and methods of removal of contaminants from fluid streams
US8883099B2 (en) 2012-04-11 2014-11-11 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US9421293B2 (en) 2012-04-17 2016-08-23 Ngee Ann Polytechnic Filtration medium with electrospun metal oxide nanofiber layer
US9011805B2 (en) 2012-04-23 2015-04-21 Energy & Environmental Research Center Foundation Carbon nanocomposite sorbent and methods of using the same for separation of one or more materials from a gas stream
US11052375B2 (en) 2012-04-26 2021-07-06 Lawrence Livermore National Security, Llc Adsorption cooling system using carbon aerogel
US11000823B2 (en) 2012-04-26 2021-05-11 Lawrence Livermore National Security, Llc Adsorption cooling system using carbon aerogel
US9011789B2 (en) 2012-05-18 2015-04-21 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Treatment system for removing halogenated compounds from contaminated sources
US11911727B2 (en) 2012-06-15 2024-02-27 Carbonxt, Inc. Magnetic adsorbents, methods for manufacturing a magnetic adsorbent, and methods of removal of contaminants from fluid streams
KR101222694B1 (en) * 2012-08-02 2013-01-16 (주)성한코퍼레이션 The fabric for cbr defense and the cbr defense clothes using the same
US9957454B2 (en) 2012-08-10 2018-05-01 ADA-ES, Inc. Method and additive for controlling nitrogen oxide emissions
EP2892859A2 (en) 2012-09-04 2015-07-15 OCV Intellectual Capital, LLC Dispersion of carbon enhanced reinforcement fibers in aqueous or non-aqueous media
JP2014128773A (en) * 2012-12-28 2014-07-10 Nbc Meshtec Inc Virus adsorbent and virus adsorbing component with use of the same
US10130930B2 (en) 2013-03-06 2018-11-20 Midwest Energy Emissions Corp Sorbent comprising carbon and nitrogen and methods of using the same
CN105188910B (en) 2013-03-06 2018-10-19 能源及环境研究中心基金会 Nitrogenous acticarbon and use its method
US10695717B2 (en) 2013-04-16 2020-06-30 Carbonxt, Inc. Systems and methods for post combustion mercury control using sorbent injection and wet scrubbing
GB201405488D0 (en) 2014-03-26 2014-05-07 Infre S A Decaffeination methods and systems
US9034289B1 (en) * 2014-04-04 2015-05-19 The United States Of America As Represented By The Secretary Of The Army Method and apparatus for prolonging the service life of a collective protection filter using a guard bed
US9885001B2 (en) 2014-09-23 2018-02-06 Attostat, Inc. Fuel additive composition and related methods
US9883670B2 (en) 2014-09-23 2018-02-06 Attostat, Inc. Compositions and methods for treating plant diseases
US9919363B2 (en) 2014-09-23 2018-03-20 Attostat, Inc. System and method for making non-spherical nanoparticles and nanoparticle compositions made thereby
US9434006B2 (en) 2014-09-23 2016-09-06 Attostat, Inc. Composition containing spherical and coral-shaped nanoparticles and method of making same
US10190253B2 (en) 2014-09-23 2019-01-29 Attostat, Inc Nanoparticle treated fabrics, fibers, filaments, and yarns and related methods
DE102015000813A1 (en) * 2015-01-21 2016-07-21 Smart Material Printing B.V. Method of destroying drugs and toxins and their metabolites using polyoxometalate micro and / or nanoparticles
US9839652B2 (en) 2015-04-01 2017-12-12 Attostat, Inc. Nanoparticle compositions and methods for treating or preventing tissue infections and diseases
US10774429B2 (en) 2015-04-13 2020-09-15 Attostat, Inc. Anti-corrosion nanoparticle compositions
US11473202B2 (en) 2015-04-13 2022-10-18 Attostat, Inc. Anti-corrosion nanoparticle compositions
JP2018533471A (en) 2015-10-30 2018-11-15 コーニング インコーポレイテッド Porous ceramic filter and method of manufacturing the same
US10201571B2 (en) 2016-01-25 2019-02-12 Attostat, Inc. Nanoparticle compositions and methods for treating onychomychosis
EP3507005B1 (en) * 2016-08-30 2021-07-21 LightOre SA Use of a volume body as filtration means and/or sorption means for regeneration by backwashing
WO2018044501A1 (en) 2016-09-01 2018-03-08 Exxonmobil Upstream Research Company Swing adsorption processes for removing water using 3a zeolite structures
CA3045034C (en) 2016-12-21 2021-06-29 Exxonmobil Upstream Research Company Self-supporting structures having active materials
US10549230B2 (en) 2016-12-21 2020-02-04 Exxonmobil Upstream Research Company Self-supporting structures having active materials
JP7187109B2 (en) 2017-10-31 2022-12-12 コーニング インコーポレイテッド Honeycomb bodies and particulate filters containing honeycomb bodies
US11646453B2 (en) 2017-11-28 2023-05-09 Attostat, Inc. Nanoparticle compositions and methods for enhancing lead-acid batteries
US11018376B2 (en) 2017-11-28 2021-05-25 Attostat, Inc. Nanoparticle compositions and methods for enhancing lead-acid batteries
DE102018003906A1 (en) 2018-05-07 2019-11-07 Smart Material Printing Use of polyoxometalates against the infestation of eukaryotic cultures, viral cultures and microorganism populations by mollicutes and mollicutene-inhibiting and killing polyoxometalate-containing substances and processes
US11318410B2 (en) 2018-12-21 2022-05-03 Exxonmobil Upstream Research Company Flow modulation systems, apparatus, and methods for cyclical swing adsorption
WO2020222932A1 (en) 2019-04-30 2020-11-05 Exxonmobil Upstream Research Company Rapid cycle adsorbent bed
KR102172856B1 (en) * 2019-06-13 2020-11-02 국방과학연구소 Reactive fibers, method for manufacturing the same, and jacket of chemical protection comprising same
US10828873B1 (en) * 2019-08-16 2020-11-10 Battelle Memorial Institute Textile composite having sorptive and reactive properties against toxic agents
WO2021071755A1 (en) 2019-10-07 2021-04-15 Exxonmobil Upstream Research Company Adsorption processes and systems utilizing step lift control of hydraulically actuated poppet valves
WO2021076594A1 (en) 2019-10-16 2021-04-22 Exxonmobil Upstream Research Company Dehydration processes utilizing cationic zeolite rho
WO2022156835A1 (en) * 2021-06-24 2022-07-28 Univerzita Palackeho V Olomouci Biochar-based composites for decontamination of chemical warfare agents
CN113577636B (en) * 2021-07-29 2023-01-03 西北民族大学 Preparation and application of oleophylic hydrophobic high-activity loaded microorganism asphalt porous material
CN114214832B (en) * 2021-11-19 2024-01-26 东华大学 Nanofiber material for protecting chemical weapon and preparation method and application thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4397907A (en) * 1981-06-22 1983-08-09 Hughes Aircraft Company Multi-purpose air permeable composites
US4565727A (en) * 1983-09-12 1986-01-21 American Cyanamid Co. Non-woven activated carbon fabric
US4748065A (en) * 1986-08-13 1988-05-31 E. I. Du Pont De Nemours And Company Spunlaced nonwoven protective fabric
US5972808A (en) * 1997-01-30 1999-10-26 Aqf Technologies Llc Fibrous structures with fine particles
US6057488A (en) * 1998-09-15 2000-05-02 Nantek, Inc. Nanoparticles for the destructive sorption of biological and chemical contaminants
US20030013369A1 (en) * 1999-07-19 2003-01-16 Soane David S. Nanoparticle-based permanent treatments for textiles

Family Cites Families (80)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3746655A (en) * 1969-02-07 1973-07-17 Calgon Corp Colored activated carbon
US3817860A (en) * 1969-12-03 1974-06-18 Univ Kansas State Method of disinfecting water and demand bactericide for use therein
JPS5216875B2 (en) * 1973-08-01 1977-05-12
US3886093A (en) * 1973-12-14 1975-05-27 Westvaco Corp Activated carbon with active metal sites and process for producing same
US3923655A (en) * 1974-12-09 1975-12-02 Vesmat Investments Level detection system
FI790530A (en) * 1978-02-21 1979-08-22 Siren M J O FILTER MATERIALS SAMT FOERFARANDE FOER FRAMSTAELLNING AV OCH ANVAENDNING AV DETSAMMA
US4238477A (en) * 1979-04-20 1980-12-09 Kansas State University Research Foundation Process of preparing homogeneous resin-polyiodide disinfectants
GR79403B (en) * 1982-11-24 1984-10-22 Bluecher Hubert
US4656153A (en) * 1983-02-28 1987-04-07 Standard Oil Company (Indiana) Active carbon containing a dispersion of a metal component and method for making same
US4569895A (en) 1984-10-30 1986-02-11 Minnesota Mining And Manufacturing Company Charge transfer media and process for making thereof
JPS62191040A (en) * 1986-02-17 1987-08-21 Nippon Denso Co Ltd Adsorbable carbon material and its production
US4797318A (en) * 1986-07-31 1989-01-10 Kimberly-Clark Corporation Active particle-containing nonwoven material, method of formation thereof, and uses thereof
US5032209A (en) 1987-03-16 1991-07-16 Minnesota Mining And Manufacturing Company Heat sealing of semicrystalline quasi-amorphous polymers
JPH0438790Y2 (en) * 1988-04-07 1992-09-10
US5014355A (en) * 1989-09-29 1991-05-14 Technical Innovations, Inc. Disposable environmental control suit
JP3044841B2 (en) 1991-06-15 2000-05-22 クラレケミカル株式会社 Activated carbon adhesive sheet manufacturing method
US5482773A (en) * 1991-07-01 1996-01-09 E. I. Du Pont De Nemours And Company Activated carbon-containing fibrids
US6184177B1 (en) * 1992-02-28 2001-02-06 Mhb Filtration Gmbh And Co. Kg Method of producing activated carbon particles from spent granular organic ion-exchange resin
ATE347807T1 (en) * 1992-09-16 2007-01-15 Triosyn Holding Inc METHOD FOR DISINFECTING AIR USING DISINFECTING IODINE RESIN AND SYSTEMS FOR DISINFECTING MICRO-ORGANISMS CONTAINED IN AIR
JP2818693B2 (en) * 1992-11-18 1998-10-30 ヘキスト・セラニーズ・コーポレーション Fibrous structure containing immobilized particulate matter and method for producing the same
US5549962A (en) 1993-06-30 1996-08-27 Minnesota Mining And Manufacturing Company Precisely shaped particles and method of making the same
US5482915A (en) * 1993-09-20 1996-01-09 Air Products And Chemicals, Inc. Transition metal salt impregnated carbon
US5712219A (en) * 1994-04-08 1998-01-27 Kansas State University Research Foundation Iron oxide magnesium oxide composites and method for destruction of cholrinated hydrocarbon using such composites
US5759939A (en) * 1994-04-08 1998-06-02 Kansas State University Research Foundation Composite metal oxide adsorbents
US5518624A (en) * 1994-05-06 1996-05-21 Illinois Water Treatment, Inc. Ultra pure water filtration
US5736473A (en) * 1994-09-14 1998-04-07 Kimberly-Clark Corp. Fibrous composite structure including particulates
US5639307A (en) * 1995-01-17 1997-06-17 Electrostatic Technology, Inc. Fiber bundle coating apparatus
US5965479A (en) * 1995-02-03 1999-10-12 Mitsubishi Chemical Corporation Activated carbon and process for producing the same
JP3629743B2 (en) * 1995-02-06 2005-03-16 栗田工業株式会社 Method for producing activated carbon
US5582913A (en) * 1995-08-23 1996-12-10 Hoechst Celanese Corporation Polyester/polyamide composite fiber
JP4002607B2 (en) 1995-08-24 2007-11-07 スリーエム カンパニー Method for producing particle-coated solid substrate
US5620643A (en) 1995-10-26 1997-04-15 Minnesota Mining And Manufacturing Company Process for producing fused particle agglomerates
JP3566821B2 (en) * 1995-11-14 2004-09-15 株式会社リコー Solid collection device
US6054488A (en) 1996-06-11 2000-04-25 3M Innovative Properties Company Medicinal aerosol formulations of formoterol
US5990373A (en) * 1996-08-20 1999-11-23 Kansas State University Research Foundation Nanometer sized metal oxide particles for ambient temperature adsorption of toxic chemicals
US6630106B1 (en) * 2001-03-13 2003-10-07 Selecto, Inc. Compositions and methods for controlling microorganism growth in water processing systems
US5989514A (en) * 1997-07-21 1999-11-23 Nanogram Corporation Processing of vanadium oxide particles with heat
US5952125A (en) * 1997-07-21 1999-09-14 Nanogram Corporation Batteries with electroactive nanoparticles
US6387531B1 (en) * 1998-07-27 2002-05-14 Nanogram Corporation Metal (silicon) oxide/carbon composite particles
US5962082A (en) 1997-08-19 1999-10-05 Aveka, Inc. Process for applying liquid coatings to solid particulate substrates
US6509285B1 (en) * 1997-09-15 2003-01-21 Patrick Yeh Fabric for moisture management
US6045650A (en) 1997-09-16 2000-04-04 Sunsmart, Inc. Hydrophilic materials and their method of preparation
JPH11166180A (en) * 1997-12-03 1999-06-22 Futaba Corp Phosphor and production thereof
US6060419A (en) 1998-01-05 2000-05-09 Sunoco, Inc. (R&M) Wells-Dawson type heteropolyacids, their preparation and use as oxidation catalysts
US6043184A (en) 1998-01-05 2000-03-28 Sunoco, Inc. (R&M) Heteropoly acids supported on polyoxometallate salts and their preparation
US5990348A (en) * 1998-01-05 1999-11-23 Sunoco, Inc. Conversion of alkanes to unsaturated carboxylic acids over heteroploy acids supported on polyoxometallate salts
US6713076B1 (en) * 1998-04-13 2004-03-30 Emory University Methods for removing a contaminant by a polyoxometalate-modified fabric or a polyoxometalate-modified cellulosic fiber and fabrics thereof
US6093236A (en) * 1998-05-30 2000-07-25 Kansas State University Research Foundation Porous pellet adsorbents fabricated from nanocrystals
JP2000007586A (en) * 1998-06-17 2000-01-11 Shimizu Corp Decomposition treatment of organochlorine-based gas and apparatus therefor
JP2000053532A (en) * 1998-08-04 2000-02-22 Shiseido Co Ltd Beatifying
US6087294A (en) * 1998-08-12 2000-07-11 Kansas State University Research Foundation Dispersion and stabilization of reactive atoms on the surface of metal oxides
US6417423B1 (en) 1998-09-15 2002-07-09 Nanoscale Materials, Inc. Reactive nanoparticles as destructive adsorbents for biological and chemical contamination
US6653519B2 (en) 1998-09-15 2003-11-25 Nanoscale Materials, Inc. Reactive nanoparticles as destructive adsorbents for biological and chemical contamination
US6224655B1 (en) * 1998-11-03 2001-05-01 Pierre Messier Biostatic air filter
JP4332915B2 (en) * 1998-11-13 2009-09-16 栗田工業株式会社 Environmental hormone-containing water treatment method and environmental hormone-containing water treatment apparatus
US6074437A (en) 1998-12-23 2000-06-13 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Bleaching with polyoxometalates and air or molecular oxygen
DE19912154C5 (en) 1999-03-17 2007-02-01 Carbotex Produktions-Und Veredelungsbetriebe Gmbh Process for the production of shaped activated carbon
DE19912153B4 (en) * 1999-03-18 2004-08-19 Carbotex Produktions-Und Veredelungsbetriebe Gmbh Process for the production of shaped high-performance adsorbents
US6723349B1 (en) * 1999-10-12 2004-04-20 Emory University Polyoxometalate materials, metal-containing materials, and methods of use thereof
US6296821B1 (en) * 1999-10-20 2001-10-02 Allied Signal Inc. Complex shaped fiber for particle and molecular filtration
DE10011223B4 (en) 2000-03-08 2005-02-10 Carbotex Produktions-Und Veredelungsbetriebe Gmbh Spherical high-performance adsorbents with microstructure and their use
US6235673B1 (en) 2000-04-05 2001-05-22 Eastman Chemical Company Carbonylation catalyst supported on a carbonized polysulfonated divinylbenzene-styrene copolymer
JP2001294846A (en) * 2000-04-14 2001-10-23 Ebara Corp Agent and method for decomposing dioxins
MY128157A (en) * 2000-04-20 2007-01-31 Philip Morris Prod High efficiency cigarette filters having shaped micro cavity fibers impregnated with adsorbent or absorbent materials
US6761761B1 (en) * 2000-04-24 2004-07-13 The United States Of America As Represented By The United States Department Of Energy Lower saccharide nanometric materials and methods
US6815383B1 (en) * 2000-05-24 2004-11-09 Kimberly-Clark Worldwide, Inc. Filtration medium with enhanced particle holding characteristics
US6458210B1 (en) 2000-05-24 2002-10-01 Nordson Corporation Electrostatic fluidized bed coating method and apparatus
US20020074292A1 (en) * 2000-09-26 2002-06-20 Andreas Schlegel Adsorption vessels
US6740406B2 (en) * 2000-12-15 2004-05-25 Kimberly-Clark Worldwide, Inc. Coated activated carbon
CN1330822C (en) * 2001-01-30 2007-08-08 宝洁公司 Coating compositions for modifying surfaces
US6673738B2 (en) * 2001-11-28 2004-01-06 K.K. Ueda Shikimono Kojyo Photocatalytic active carbon, colored photocatalytic active carbon, coloring active carbon, and deodorant and adsorption product using them
AU2003299455A1 (en) 2002-02-25 2004-05-25 Gentex Corporation Multu-functional protective textiles and methods for decontamination
US6706092B2 (en) * 2002-04-17 2004-03-16 Alliedsignal Inc. Chemical/Biological decontamination filter
US20030215355A1 (en) 2002-05-14 2003-11-20 Nanoscale Materials, Inc. Method and apparatus for control of chemical or biological warfare agents
CN101069752A (en) * 2002-05-20 2007-11-14 西奥多·A·M·阿尔茨 Air decontamination devices
US6860924B2 (en) 2002-06-07 2005-03-01 Nanoscale Materials, Inc. Air-stable metal oxide nanoparticles
US6843919B2 (en) * 2002-10-04 2005-01-18 Kansas State University Research Foundation Carbon-coated metal oxide nanoparticles
US6827766B2 (en) * 2002-10-08 2004-12-07 United States Air Force Decontaminating systems containing reactive nanoparticles and biocides
AU2003293370A1 (en) * 2002-12-05 2004-06-30 Usfilter Corporation Activated carbon for odor control and method for making same
US7018946B2 (en) * 2003-02-14 2006-03-28 Invista North America S.A.R.L. Fabric including polymer filaments having profiled cross-section

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4397907A (en) * 1981-06-22 1983-08-09 Hughes Aircraft Company Multi-purpose air permeable composites
US4565727A (en) * 1983-09-12 1986-01-21 American Cyanamid Co. Non-woven activated carbon fabric
US4565727B1 (en) * 1983-09-12 1989-01-24
US4748065A (en) * 1986-08-13 1988-05-31 E. I. Du Pont De Nemours And Company Spunlaced nonwoven protective fabric
US5972808A (en) * 1997-01-30 1999-10-26 Aqf Technologies Llc Fibrous structures with fine particles
US6057488A (en) * 1998-09-15 2000-05-02 Nantek, Inc. Nanoparticles for the destructive sorption of biological and chemical contaminants
US20030013369A1 (en) * 1999-07-19 2003-01-16 Soane David S. Nanoparticle-based permanent treatments for textiles

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