WO2007020442A3 - Organic dyestuffs, organic photovoltaic device, semiconductor crystal film and method of prodicing thereof - Google Patents
Organic dyestuffs, organic photovoltaic device, semiconductor crystal film and method of prodicing thereof Download PDFInfo
- Publication number
- WO2007020442A3 WO2007020442A3 PCT/GB2006/003069 GB2006003069W WO2007020442A3 WO 2007020442 A3 WO2007020442 A3 WO 2007020442A3 GB 2006003069 W GB2006003069 W GB 2006003069W WO 2007020442 A3 WO2007020442 A3 WO 2007020442A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- organic
- prodicing
- photovoltaic device
- crystal film
- semiconductor crystal
- Prior art date
Links
- 239000004065 semiconductor Substances 0.000 title abstract 5
- 238000013086 organic photovoltaic Methods 0.000 title abstract 3
- 239000013078 crystal Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 150000002894 organic compounds Chemical class 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 230000005693 optoelectronics Effects 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B3/00—Dyes with an anthracene nucleus condensed with one or more carbocyclic rings
- C09B3/60—Anthanthrones
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B17/00—Azine dyes
- C09B17/02—Azine dyes of the benzene series
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/045—Special non-pigmentary uses, e.g. catalyst, photosensitisers of phthalocyanine dyes or pigments
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/06—Preparation from carboxylic acids or derivatives thereof, e.g. anhydrides, amides, mononitriles, phthalimide, o-cyanobenzamide
- C09B47/065—Preparation from carboxylic acids or derivatives thereof, e.g. anhydrides, amides, mononitriles, phthalimide, o-cyanobenzamide having -COOH or -SO3H radicals or derivatives thereof, directly linked to the skeleton
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/06—Preparation from carboxylic acids or derivatives thereof, e.g. anhydrides, amides, mononitriles, phthalimide, o-cyanobenzamide
- C09B47/067—Preparation from carboxylic acids or derivatives thereof, e.g. anhydrides, amides, mononitriles, phthalimide, o-cyanobenzamide from phthalodinitriles naphthalenedinitriles, aromatic dinitriles prepared in situ, hydrogenated phthalodinitrile
- C09B47/0678—Preparation from carboxylic acids or derivatives thereof, e.g. anhydrides, amides, mononitriles, phthalimide, o-cyanobenzamide from phthalodinitriles naphthalenedinitriles, aromatic dinitriles prepared in situ, hydrogenated phthalodinitrile having-COOH or -SO3H radicals or derivatives thereof directly linked to the skeleton
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/08—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex
- C09B47/24—Obtaining compounds having —COOH or —SO3H radicals, or derivatives thereof, directly bound to the phthalocyanine radical
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B5/00—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings
- C09B5/62—Cyclic imides or amidines of peri-dicarboxylic acids of the anthracene, benzanthrene, or perylene series
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B57/00—Other synthetic dyes of known constitution
- C09B57/08—Naphthalimide dyes; Phthalimide dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B57/00—Other synthetic dyes of known constitution
- C09B57/12—Perinones, i.e. naphthoylene-aryl-imidazoles
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
- H01L31/0256—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/20—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising organic-organic junctions, e.g. donor-acceptor junctions
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/451—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising a metal-semiconductor-metal [m-s-m] structure
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/30—Coordination compounds
- H10K85/311—Phthalocyanine
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/60—Organic compounds having low molecular weight
- H10K85/615—Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
- H10K85/621—Aromatic anhydride or imide compounds, e.g. perylene tetra-carboxylic dianhydride or perylene tetracarboxylic di-imide
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/60—Organic compounds having low molecular weight
- H10K85/649—Aromatic compounds comprising a hetero atom
- H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
- H10K85/6572—Polycyclic condensed heteroaromatic hydrocarbons comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/60—Organic compounds having low molecular weight
- H10K85/649—Aromatic compounds comprising a hetero atom
- H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
- H10K85/6576—Polycyclic condensed heteroaromatic hydrocarbons comprising only sulfur in the heteroaromatic polycondensed ring system, e.g. benzothiophene
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/50—Photovoltaic [PV] devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/80—Constructional details
- H10K30/87—Light-trapping means
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/191—Deposition of organic active material characterised by provisions for the orientation or alignment of the layer to be deposited
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Abstract
The present invention relates generally to the field of organic chemistry and particularly to the organic semiconductor materials for organic photovoltaic devices. More specifically, the present invention is related to the synthesis of organic compounds and the manufacture of organic photovoltaic devices and semiconductor films based on these compounds. In one embodiment, these semiconductor films possess a high conductivity in the direction perpendicular to the organic semiconductor layer and are intended for the application in solar cells and in other organic optoelectronic devices. The organic compound has the general structural formula (I), where Het is a predominantly planar heterocyclic molecular system; B is a binding group; and p is the number in the range from 3 to 8.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0516800.0 | 2005-08-16 | ||
GBGB0516800.0A GB0516800D0 (en) | 2005-08-16 | 2005-08-16 | Organic compound, semiconductor crystal film and method of producing thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2007020442A2 WO2007020442A2 (en) | 2007-02-22 |
WO2007020442A3 true WO2007020442A3 (en) | 2007-05-18 |
Family
ID=35098401
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2006/003069 WO2007020442A2 (en) | 2005-08-16 | 2006-08-16 | Organic dyestuffs, organic photovoltaic device, semiconductor crystal film and method of prodicing thereof |
Country Status (2)
Country | Link |
---|---|
GB (2) | GB0516800D0 (en) |
WO (1) | WO2007020442A2 (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2433071A (en) * | 2005-12-05 | 2007-06-13 | Kontrakt Technology Ltd | Organic acids comprising planar conjugated heterocyclic molecular system, & photoelectric layer thereof with rodlike supramolecules for use in solar cell |
JP2010525381A (en) | 2007-04-19 | 2010-07-22 | ビーエーエスエフ ソシエタス・ヨーロピア | Pattern forming method on substrate and electronic device formed thereby |
WO2008155130A1 (en) * | 2007-06-21 | 2008-12-24 | Solar Evolution Systems Gmbh | Photovoltaic device |
KR20130004907A (en) * | 2010-02-19 | 2013-01-14 | 바스프 에스이 | Use of indanthrene compounds in organic photovoltaics |
EP2683726A1 (en) * | 2011-03-11 | 2014-01-15 | Merck Patent GmbH | Dinaphtho[2,3-a:2',3'-h]phenazines and their use as organic semiconductors |
TW201339138A (en) * | 2012-01-20 | 2013-10-01 | Univ Southern California | Synthesis of aza-acenes as novel n-type materials for organic electronics |
FR2989834A1 (en) * | 2012-04-20 | 2013-10-25 | Rhodia Operations | ACCEPTORS QUINONES FOR PHOTOVOLTAIC APPLICATION |
US20160211464A1 (en) * | 2013-08-23 | 2016-07-21 | Basf Se | New absorber for organic heterojunction solar cells |
US9244356B1 (en) | 2014-04-03 | 2016-01-26 | Rolith, Inc. | Transparent metal mesh and method of manufacture |
WO2015183243A1 (en) | 2014-05-27 | 2015-12-03 | Rolith, Inc. | Anti-counterfeiting features and methods of fabrication and detection |
CN111446372A (en) * | 2020-03-20 | 2020-07-24 | 杭州电子科技大学 | Wavy ITO transparent electrode and organic solar cell |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4624709A (en) * | 1982-10-13 | 1986-11-25 | Orient Chemical Industrie | Nigrosine dyes and process for preparing same |
DE3703513A1 (en) * | 1987-02-05 | 1988-08-18 | Langhals Heinz | Water-soluble perylene fluorescent dyes |
JPH05102506A (en) * | 1991-10-03 | 1993-04-23 | Ricoh Co Ltd | Photovoltaic element |
EP0887817A2 (en) * | 1997-06-23 | 1998-12-30 | SHARP Corporation | Photoelectric material using organic photosensitising dyes and manufacturing method thereof |
JP2000100484A (en) * | 1998-09-24 | 2000-04-07 | Fuji Xerox Co Ltd | Light semiconductor electrode, photoelectric conversion device and photoelectric conversion method |
US6049428A (en) * | 1994-11-18 | 2000-04-11 | Optiva, Inc. | Dichroic light polarizers |
US6150605A (en) * | 1998-09-22 | 2000-11-21 | Sharp Kabushiki Kaisha | Photovoltaic cell and manufacturing method thereof |
US20030232153A1 (en) * | 2002-06-07 | 2003-12-18 | Nazarov Victor V. | Sulfoderivatives of indanthrone, lyotropic liquid crystal system and anisotropic film on their base |
WO2004025705A2 (en) * | 2002-09-13 | 2004-03-25 | Optiva, Inc. | Organic photosensitive optoelectronic device |
US20040215015A1 (en) * | 2003-04-25 | 2004-10-28 | Nazarov Victor V. | Lyotropic liquid crystal systems based on perylenetetracarboxylic acid dibenzimidazole sulfoderivatives, related anisotropic films, and methods for making |
EP1526159A1 (en) * | 2002-07-29 | 2005-04-27 | Mitsubishi Paper Mills Limited | Organic dye, photoelectric transducing material, semiconductor electrode, and photoelectric transducing device |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5315129A (en) * | 1990-08-20 | 1994-05-24 | University Of Southern California | Organic optoelectronic devices and methods |
WO1994005025A1 (en) * | 1992-08-17 | 1994-03-03 | Sandoz Ltd. | Use of optical brighteners and phthalocyanines as photosensitizers |
US6677516B2 (en) * | 2001-01-29 | 2004-01-13 | Sharp Kabushiki Kaisha | Photovoltaic cell and process for producing the same |
WO2005123737A2 (en) * | 2004-06-14 | 2005-12-29 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Charge-transport materials, methods of fabrication thereof, and methods of use thereof |
-
2005
- 2005-08-16 GB GBGB0516800.0A patent/GB0516800D0/en not_active Ceased
-
2006
- 2006-08-16 GB GB0616259A patent/GB2430440A/en active Pending
- 2006-08-16 WO PCT/GB2006/003069 patent/WO2007020442A2/en active Application Filing
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4624709A (en) * | 1982-10-13 | 1986-11-25 | Orient Chemical Industrie | Nigrosine dyes and process for preparing same |
DE3703513A1 (en) * | 1987-02-05 | 1988-08-18 | Langhals Heinz | Water-soluble perylene fluorescent dyes |
JPH05102506A (en) * | 1991-10-03 | 1993-04-23 | Ricoh Co Ltd | Photovoltaic element |
US6049428A (en) * | 1994-11-18 | 2000-04-11 | Optiva, Inc. | Dichroic light polarizers |
EP0887817A2 (en) * | 1997-06-23 | 1998-12-30 | SHARP Corporation | Photoelectric material using organic photosensitising dyes and manufacturing method thereof |
US6150605A (en) * | 1998-09-22 | 2000-11-21 | Sharp Kabushiki Kaisha | Photovoltaic cell and manufacturing method thereof |
JP2000100484A (en) * | 1998-09-24 | 2000-04-07 | Fuji Xerox Co Ltd | Light semiconductor electrode, photoelectric conversion device and photoelectric conversion method |
US20030232153A1 (en) * | 2002-06-07 | 2003-12-18 | Nazarov Victor V. | Sulfoderivatives of indanthrone, lyotropic liquid crystal system and anisotropic film on their base |
EP1526159A1 (en) * | 2002-07-29 | 2005-04-27 | Mitsubishi Paper Mills Limited | Organic dye, photoelectric transducing material, semiconductor electrode, and photoelectric transducing device |
WO2004025705A2 (en) * | 2002-09-13 | 2004-03-25 | Optiva, Inc. | Organic photosensitive optoelectronic device |
US20040215015A1 (en) * | 2003-04-25 | 2004-10-28 | Nazarov Victor V. | Lyotropic liquid crystal systems based on perylenetetracarboxylic acid dibenzimidazole sulfoderivatives, related anisotropic films, and methods for making |
Non-Patent Citations (4)
Title |
---|
A.MENIKH ET AL.: "Spectroscopic and Electrochemical studies of N,N'-bis(decamethylcarboxylic)-3,4,9,10-perylene-bis(dicarboxyimide)", J.MOL.STRUCT., vol. 403, 1997, pages 189 - 197, XP009079607 * |
F.YUKRUK ET AL.: "Modulation of internal Charge Transfer (ICT) in a bay region Hydroxylated Perylenediimide (PDI) Chromophore", TETR.LETT., vol. 46, 2005, pages 5931 - 5933, XP002421951 * |
I.LUKAC: "Darstellung und Fluoreszenzverhalten von 2,3,4,4a,10a,11,12,13-Octahydro-1,4a,10a,14-tetraazaviolanthron Derivaten", CHEM.BER., vol. 116, 1983, pages 3524 - 3528, XP000881356 * |
S.GASPARD ET AL.: "Protonation des Phthalocyanines", J.CHEM.RES.MINIPRINT, 1979, pages 3072 - 3096, XP009079572 * |
Also Published As
Publication number | Publication date |
---|---|
WO2007020442A2 (en) | 2007-02-22 |
GB0516800D0 (en) | 2005-09-21 |
GB0616259D0 (en) | 2006-09-27 |
GB2430440A (en) | 2007-03-28 |
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