It is shown that the confinement into the pores leads to fascinating new features of the guests, which are often not known for their bulk phases.
Sep 21, 2007 · It is shown that the confinement into the pores leads to fascinating new features of the guests, which are often not known for their bulk phases ...
In the last fifteen years several novel porous silica materials, which are periodically structured on the mesoscopic length scale, have been synthesized.
The review discusses, after a short introduction, the salient features of these materials and the applied NMR experiments to give the reader a basic knowledge ...
Our study demonstrates that the nanospace within mesoporous materials provides an amorphous environment that is better than vitrified bulk solvent for studying ...
Structure and dynamics of guest molecules confined in a mesoporous silica matrix: Complementary NMR and PDF characterisation · Chemistry, Materials Science · 2013.
Typical examples of these studies include NMR studies of small confined molecules inside zeolites [22,94,95,96] or mesoporous silica materials [45,97,98,99] and ...
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The combination of steric interactions, hydrogen bonds, and hydrophobic and hydrophilic interactions results in a fascinating phase behavior in the confinement.
Structural and dynamical properties of guest molecules confined in mesoporous silica materials revealed by NMR. G Buntkowsky, H Breitzke, A Adamczyk, F Roelofs, ...
Vyalikh and G. Findenegg Structural and Dynamical Properties of Guest Molecules confined in mesoporous Silica Materials revealed by NMR more Physical ...