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Guest–host interactions of a rigid organic molecule in porous silica frameworks

PNAS
This paper reports a systematic analysis of the structural, thermodynamic, and dynamic behavior on confinement of a rigid organic molecule in a series of...
31 months ago

Distribution and Mobility of Amines Confined in Porous Silica Supports Assessed via Neutron Scattering, NMR, and MD Simulations: Impacts on CO2 Sorption Kinetics and Capacities

ACS Publications
Distribution and mobility of amines confined in porous silica supports assessed via neutron scattering, NMR, and MD simulations: impacts on CO 2 sorption...
12 months ago

Layer-by-Layer Freezing of Nanoconfined Water

Nature
We report the freezing and melting behavior of water (D 2 O) nanoconfined in architected silica-based matrices including Vycor glass and mesoporous silica SBA-...
54 months ago

Confinement of Luminescent Guests in Metal–Organic Frameworks: Understanding Pathways from Synthesis and Multimodal Characterization to Potential Applications of LG@MOF Systems

ACS Publications
This review gives an authoritative, critical, and accessible overview of an emergent class of fluorescent materials termed “LG@MOF”, engineered from the...
29 months ago

Scale-dependent diffusion anisotropy in nanoporous silicon

Nature
This paper reports a joint experimental and simulation study of diffusion in such materials, covering displacements from molecular dimensions up to tens of...
92 months ago